Carbon Bonded Directly To The Phosphorus Patents (Class 556/19)
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Publication number: 20110256404Abstract: Coated fluorescent semiconductor nanoparticles having an organic surface layer of multi-functional surface ligands that include a nanocrystal binding center and one or more covalently attached functional groups or reactive functional groups are described as well as water-dispersible nanoparticles having an organic surface layer or multi-functional surface ligands and methods for the preparation and use of such coated nanoparticles.Type: ApplicationFiled: September 30, 2009Publication date: October 20, 2011Inventors: Eric Tulsky, Eric Welch, Bruce Branchaud, Roman Rozhkov
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Patent number: 8039675Abstract: Catalysts suitable for asymmetric hydrogenation reactions are described comprising the reaction product of a group 8 transition metal compound, a chiral phosphine and a chiral diamine of formula (I) in which R1, R2, R3 and R4 are independently hydrogen, a saturated or unsaturated alkyl or cycloalkyl group, an aryl group or a urethane or sulphonyl group and R5, R6, R7 and R8 are independently hydrogen, a saturated or unsaturated alkyl or cycloalkyl group, or an aryl group, at least one of R1, R2, R3 and R4 is hydrogen and A is a linking group comprising one or two substituted or unsubstituted carbon atoms.Type: GrantFiled: January 29, 2010Date of Patent: October 18, 2011Assignee: Johnson Matthey PLCInventors: William Patrick Hems, Gabriela Alexandra Grasa
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Publication number: 20110245512Abstract: In one aspect, the present invention provides a contrast enhancement agent comprising an iron chelate having structure I and salts thereof wherein R1 is independently at each occurrence a hydroxy group, a C1-C3 hydroxyalkyl group, or a C1-C3 alkyl group, and b is 0-4; R2-R7 are independently at each occurrence hydrogen, a C1-C3 hydroxyalkyl group, or a C1-C3 alkyl group, with the proviso that at least one of R1-R7 is a hydroxy group or a C1-C3 hydroxyalkyl group; and wherein Q is one or more charge balancing counterions. Also provided are a metal chelating ligand having structure IX and medical formulations comprising the contrast enhancement agent I.Type: ApplicationFiled: November 30, 2010Publication date: October 6, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: Brian James Grimmond, Michael James Rishel, Rong Zhang, Jeannette Christine DePuy
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Patent number: 7998895Abstract: Transition metal complexes of selected monoanionic phosphine ligands, which also contain a selected Group 15 or 16 (IUPAC) element and which are coordinated to a Group 3 to 11 (IUPAC) transition metal or a lanthanide metal, are polymerization catalysts for the (co)polymerization of olefins such as ethylene and ?-olefins, and the copolymerization of such olefins with polar group-containing olefins. These and other nickel complexes of neutral and monoanionic bidentate ligands copolymerize ethylene and polar comonomers, especially acrylates, at relatively high ethylene pressures and surprisingly high temperatures, and give good incorporation of the polar comonomers and good polymer productivity. These copolymers are often unique structures, which are described.Type: GrantFiled: August 1, 2008Date of Patent: August 16, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Lin Wang, Elisabeth M. Hauptman, Lynda Kaye Johnson, Elizabeth Forrester McCord, Stephan J. McLain, Ying Wang
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Publication number: 20110172381Abstract: The present invention relates to a kind of novel carbene ligands and ruthenium catalysts, which is highly active and selective for ROMP and RCM reactions, respectively. It discloses the significant electronic and steric effect of different substituted carbene ligands on the catalytic activity and stability of corresponding carbene ruthenium complexes; some of novel ruthenium complexes in the invention can be broadly used as catalysts highly effectively and selective for ROMP and RCM reactions. The invention also relates to preparation of new ruthenium catalysts and the uses in metathesis. Moreover, the invention also provides effective methods of making various functional polymers by ROMP reaction in the presence of new ruthenium catalysts.Type: ApplicationFiled: January 8, 2010Publication date: July 14, 2011Applicant: ZANNA SCITECH CO., LTD.Inventor: Zheng-Yun James Zhan
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Publication number: 20110170227Abstract: An anchor group anchors organic dielectric compounds used in the production of organically based capacitors. The capacitors referred to are those that can be produced in a parallel process on a prepeg or other common printed circuit board substrate without additional metallisation on copper. The pre-fabricated capacitor layer can then be built into the printed circuit board, thereby gaining on space and cost for the surface of the printed circuit board.Type: ApplicationFiled: September 2, 2009Publication date: July 14, 2011Applicant: Siemens AktiengesellschaftInventors: Günter Schmid, Dan Taroata
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Patent number: 7973109Abstract: A process for producing a crosslinked type or non-crosslinked type layered metal phosphonate compound including a reaction step of reacting two or more members selected from organic diphosphonic acids or monophosphonic acids, or derivatives thereof having predetermined conditions and a metal source capable of forming an ion of a hexacoordinate metal atom as a central atom (M) of a metal oxide octahedron upon reaction under the presence of a sulfuric acid catalyst, a crosslinked or non-crosslinked metal phosphonate compound obtained by the process, as well as a stock solution used for the synthesis of the crosslinked or non-crosslinked type layered metal phosphonate compound described above.Type: GrantFiled: March 24, 2008Date of Patent: July 5, 2011Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Shin-ichi Ogata, Yoshiaki Fukushima, Masaya Kawasumi
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Patent number: 7956206Abstract: A light emitting device comprising an anode, a cathode, a light emissive layer located between the anode and the cathode, said light emissive layer comprising a compound for emitting light, said compound comprising a metal complex and X, said metal complex containing a metal (M) and a phosphorous atom that is coordinated directly to M, and an aryl or heteroaryl group Ars that is directly bonded to the phosphorous atom, where Ars is substituted with X, and characterized in the X comprises an aryl or heteroaryl group.Type: GrantFiled: May 17, 2005Date of Patent: June 7, 2011Assignee: Cambridge Display Technology LimitedInventor: Scott Watkins
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Patent number: 7906669Abstract: The present invention concerns a metallocene-based phosphine ligand for use in enantioselective catalysis, the ligand having the Formula (I): Wherein M is a metal; Z is P or As; L is a suitable linker; R1 is selected from alkyl, alkoxy, alkylamino, cycloalkyl, cycloalkoxy, cycloalkylamino carbocyclic aryl, substituted and unsubstituted carbocyclic aryloxy, heteroaryl, heteroaryloxy, carbocyclic arylamino and heteroarylamino; X* is selected from (II): Wherein R, R2 and R3 are independently selected from optionally substituted branched- and straight-chain alkyl, cycloalkyl, heterocycloalkyl, carbocyclic aryl, and heteroaryl.Type: GrantFiled: January 13, 2006Date of Patent: March 15, 2011Assignee: Solvias AGInventors: Peter McCormack, Chen Weiping, John Whittall
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Publication number: 20110028718Abstract: A substituted paracyclophane is described of formula (I) wherein X1 and X2 are linking groups comprising between 2 to 4 carbon atoms, Y1 and Y2 are selected from the group consisting of hydrogen, halide, oxygen, nitrogen, alkyl, cycloalkyl, aryl or heteroaryl and Z is a substituted or unsubstituted alkyl group, aryl group or heteroaryl group. Preferably X1 and X2 are —(C2H4)— and Z is a substituted aryl group. The substituted paracyclophane provides transition metal catalysts that are useful in C—C and C—N bond formation and asymmetric hydrogenation reactions.Type: ApplicationFiled: August 21, 2008Publication date: February 3, 2011Applicant: Johnson Matthey Public Limited CompanyInventors: Jianliang Xiao, Jiwu Ruan
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Publication number: 20100267956Abstract: The invention relates to a compound of the formula (I) or the formula (II) in which: W is an oxygen atom or a radical of the formula NH; X is hydrogen or an alkaline cation or a C1-C8 alkyl or a —(CH2)n3—C(R4)(R5)(R6) radical; X and R on the one hand and X and R1 on the other hand may independently form an optionally substituted cycle with 5, 6 or 7 links. The invention also relates to complexes of said compounds with at least one metal selected from the group comprising copper, palladium, ruthenium, iridium and rhodium, and to a method for the synthesis of these compounds. These compounds and complexes can be used in various asymmetrical catalysis methods.Type: ApplicationFiled: October 17, 2008Publication date: October 21, 2010Inventors: Marc Mauduit, Diane Rix, Christophe Crevisy, Joanna Wencel
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Patent number: 7816548Abstract: The invention relates to a process for the preparation of a hydrocarbylated metal organic compound, comprising a hydrocarbyl group, a spectator ligand and optionally a ligand, by contacting a metal-organic reagent with a spectator ligand in the presence of at least 2 equivalents of a hydrocarbylating agent.Type: GrantFiled: August 3, 2004Date of Patent: October 19, 2010Assignee: DSM IP Assets B.V.Inventors: Edwin IJpeij, Felix Beijer, Henricus Arts, Gerardus Van Doremaele
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Publication number: 20100249226Abstract: Disclosed are a novel cyclotriphosphazene-platinum(II) complex conjugate anticancer agent, showing high selectivity to tumor tissues due to the enhanced permeability and retention effect in tumor tissues and a preparation method thereof.Type: ApplicationFiled: April 11, 2008Publication date: September 30, 2010Applicant: NANOHYBRID CO., LTDInventors: Youn-Soo Sohn, Ji-Young Yu, Yong-Joo Jun
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Publication number: 20100249425Abstract: The invention relates to a process for modifying an inorganic substrate, directed toward giving it antimicrobial properties, said process consisting in grafting in one or more steps onto a surface of said substrate groups with intrinsic antimicrobial properties or groups capable of releasing species with antimicrobial properties. The grafting is performed by means of an organophosphorus coupling agent. A subject of the invention is similarly a substrate obtained by this process, as well as diverse uses of such a substrate.Type: ApplicationFiled: December 21, 2006Publication date: September 30, 2010Applicants: Centre National De La Recherche Scientifique, Universite Montpellier II Sciences Et Techniques Du LanguedocInventors: Hubert Mutin, Gilles Guerrero, Julien Almaric
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Publication number: 20100216924Abstract: Mixed metal phosphonates are generally provided. The mixed metal phosphonate can generally have the composition: AB(RPO3)3, where A is Mg2+, Ca2+, Sr2+, Ba2+, Pb2+, La3+, or combinations thereof; B is Ti4+, Zr4+, Al3+, or combinations thereof; and R is an organic group (e.g., aryl group, an alkyl group, an alkenyl group, etc.). The mixed metal phosphonate can be combined with a polymeric material to form a polymeric film. Methods of making the mixed metal phosphonate by combining and reacting a metal oxide and an organophosphonic acid are also provided.Type: ApplicationFiled: February 15, 2010Publication date: August 26, 2010Applicant: UNIVERSITY OF SOUTH CAROLINAInventors: Arthur Peter Barber, III, Harry J. Ploehn, Hans-Conrad zur Loye
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Patent number: 7754907Abstract: Coordination complexes having at least two structural conformations are disclosed. The coordination complexes contain at least one metal center and at least one hemi-labile ligand, and change structural conformations due to the presence or absence of allosteric effectors. Methods of detecting an analyte using the coordination complexes are also disclosed.Type: GrantFiled: August 18, 2005Date of Patent: July 13, 2010Assignee: Northwestern UniversityInventors: Chad A. Mirkin, Nathan C. Gianneschi, Jungseok Heo
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Patent number: 7709659Abstract: Tetraphosphorous ligands are combined with transition metal salts to form catalysts for use in hydroformylation, isomerization-hydroformylation, hydrocarboxylation, hydrocyan-ation, isomerization-formylation, hydroaminomethylation and similar related reactions.Type: GrantFiled: April 17, 2009Date of Patent: May 4, 2010Assignee: The Penn State Research FoundationInventors: Xumu Zhang, Yongjun Yan
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Publication number: 20100099902Abstract: The present invention relates to biarylbisphosphines and intermediates thereof. Furthermore, the scope of the invention encompasses catalysts which can be prepared from the bisarylphosphines and their use in asymmetric syntheses.Type: ApplicationFiled: October 14, 2009Publication date: April 22, 2010Applicant: BOEHRINGER INGELHEIM INTERNATIONAL GMBHInventors: Dieter Arlt, Benjamin Meseguer
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Patent number: 7678933Abstract: The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound according to the present invention is configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge. The binuclear transition metal compound according to the present invention is configured such that the two bridged mononuclear transition metal compounds configured such that a cyclopentadienyl group and an amido or phosphorous group are bridged via a phenylene bridge are linked via a bridging group located at the phenylene bridge. According to the present invention, the mononuclear transition metal compound, the binuclear transition metal compound, the organic amine or phosphorous compound can be prepared in a simple manner by using suzuki-coupling reaction with a high yield.Type: GrantFiled: December 29, 2006Date of Patent: March 16, 2010Assignee: LG Chem, Ltd.Inventors: Choong-Hoon Lee, Eun-Jung Lee, Seung-Whan Jung, Jung-A Lee, Bo-Ram Lee, Bun-Yeoul Lee
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Patent number: 7674926Abstract: Dopant-group substituted (cyclo)silane compounds, liquid-phase compositions containing such compounds, and methods for making the same. Such compounds (and/or ink compositions containing the same) are useful for printing or spin coating a doped silane film onto a substrate that can easily be converted into a doped amorphous or polycrystalline silicon film suitable for electronic devices. Thus, the present invention advantageously provides commercial qualities and quantities of doped semiconductor films from a doped “liquid silicon” composition.Type: GrantFiled: October 1, 2004Date of Patent: March 9, 2010Assignee: Kovio, Inc.Inventors: Wenzhuo Guo, Vladimir K. Dioumaev, Brent Ridley, Fabio Zūrcher, Joerg Rockenberger, James Montague Cleeves
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Publication number: 20100029977Abstract: The present invention can provide a cyanation catalyst represented by the general formula (I): (in the formula (I), R1 through R4 are each an optionally substituted hydrocarbon group; R1 and R2 and/or R3 and R4 may form an optionally substituted carbon chain ring; R5 through R8 are each a hydrogen atom, or an optionally substituted hydrocarbon group; R5 and R6 and/or R7 and R8 may form an optionally substituted carbon chain ring; R9 and R10 are each a hydrogen atom, or an optionally substituted hydrocarbon group; W, X and Y each represent an optionally substituted binding chain; X and/or Y may be non-existent; M represents a metal or a metal ion; and ligands of M may each be located at any position).Type: ApplicationFiled: February 14, 2008Publication date: February 4, 2010Applicants: National University Corporation Hokkaido University, Mitsubishi Rayon Co., Ltd.Inventors: Takeshi Ohkuma, Nubuhito Kurono
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Publication number: 20090312561Abstract: The invention concerns metal complexes and their preparation, in particular a metal complex MLnXm, where M is a metal of group 8, 9 or 10 and X is a halide, HCO3—, NO3—, CO32— or carboxylate. n is a number equal to or less than the coordination number of the metal and m is 1 or 2 and is equal to the oxidation state of the metal. The ligand L may be a bidentate phosphine of formula (I), (II), (III) or (IV) as set out herein. The process of production comprises reacting an ammine compound of metal M with a complexing compound, which is preferably a phosphine.Type: ApplicationFiled: April 10, 2007Publication date: December 17, 2009Applicant: LUCITE INTERNATIONAL UK LIMITEDInventors: Graham Ronald Eastham, Neil Tindale
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Publication number: 20090270645Abstract: A process for extractively removing nickel(0) complexes having phosphorus ligands from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles by extraction by means of a hydrocarbon, a phase separation of the hydrocarbon and of the nitrile-containing solution into two phases being effected, by feeding at least one polar additive to the hydrocyanation effluent (feedstream) and/or to the extraction stage.Type: ApplicationFiled: March 28, 2007Publication date: October 29, 2009Applicant: BASF SEInventors: Gerd Haderlein, Tobias Aechtner, Michael Bartsch, Hermann Luyken, Peter Pfab, Jens Scheidel, Andreas Leitner
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Publication number: 20090198071Abstract: Tetraphosphorous ligands are combined with transition metal salts to form catalysts for use in hydroformylation, isomerization-hydroformylation, hydrocarboxylation, hydrocyan-ation, isomerization-formylation, hydroaminomethylation and similar related reactions.Type: ApplicationFiled: April 17, 2009Publication date: August 6, 2009Applicant: THE PENN STATE RESEARCH FOUNDATIONInventors: Xumu ZHANG, Yongjun Yan
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Publication number: 20090105481Abstract: Process for stereoselective hydrogenation by reacting racemic aldehydes or ketones having a stereogenic carbon atom in the position relative to the C(O) group and containing the structural element —(O)C—C—CH— by means of hydrogen in the presence of a base and a ruthenium complex containing a bidentate ligand having coordinating P and N atoms, a monophosphine ligand and anionic and/or uncharged ligands as homogeneous catalyst, with the charge being balanced by one or two monovalent acid anions or a divalent acid anion when uncharged ligands are present.Type: ApplicationFiled: March 8, 2007Publication date: April 23, 2009Inventors: Felix Spindler, Ulrike Nettekoven, Mauro Perseghini
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Publication number: 20090093607Abstract: A process for producing a crosslinked type or non-crosslinked type layered metal phosphonate compound including a reaction step of reacting two or more members selected from organic diphosphonic acids or monophosphonic acids, or derivatives thereof having predetermined conditions and a metal source capable of forming an ion of a hexacoordinate metal atom as a central atom (M) of a metal oxide octahedron upon reaction under the presence of a sulfuric acid catalyst, a crosslinked or non-crosslinked metal phosphonate compound obtained by the process, as well as a stock solution used for the synthesis of the crosslinked or non-crosslinked type layered metal phosphonate compound described above.Type: ApplicationFiled: March 24, 2008Publication date: April 9, 2009Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Shin-ichi Ogata, Yoshiaki Fukushima, Masaya Kawasumi
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Patent number: 7468451Abstract: Process for preparing halide metallocene compounds comprising the step of reacting the dialkyl derivative with a halogenating agent of formula R3xTLw wherein: L is chlorine, iodine or bromine; R3 is hydrogen or a hydrocarbon group; T is a metal of groups 2-14 of the periodic table of the elements; and x is ?1 so that x+w is equal to the oxidation state of the metal T.Type: GrantFiled: April 29, 2004Date of Patent: December 23, 2008Assignee: Basell Polyolefine GmbHInventors: Simona Guidotti, Davide Balboni
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Publication number: 20080234451Abstract: A ring-opening metathesis polymerisation (ROMP) reaction is disclosed in which a cyclic alkene compound is subjected to ROMP using a transition metal ROMP catalyst which has an alkyl moiety which is connected to the metal centre thereof through a double bond. The process includes the step of adding sufficient of an acyclic alkene having a carbon-carbon double bond capable of reacting with the catalytic metal moieties attached to the living end of each of the polymer chains generated in the ROMP reaction to end cap the polymer chains and to generate a stable olefin metathesis catalyst.Type: ApplicationFiled: December 5, 2005Publication date: September 25, 2008Applicant: Imperial Chemical Industries PLCInventors: Alan Michael Kenwright, David Mitchell Haigh, Ezat Khosravi
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Publication number: 20080213916Abstract: Coordination complexes having at least two structural conformations are disclosed. The coordination complexes contain at least one metal center and at least one hemi-labile ligand, and change structural conformations due to the presence or absence of allosteric effectors. Methods of detecting an analyte using the coordination complexes are also disclosed.Type: ApplicationFiled: August 18, 2005Publication date: September 4, 2008Applicant: Northwestern UniversityInventors: Chad A. Mirkin, Nathan C. Gianneschi, Jungseok Heo
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Publication number: 20080199731Abstract: The present invention relates to the use of copper(I) complexes of the formula I where X is nitrogen or a C—R group, R is alkyl or aryl, Ar is phenyl or naphthyl, each of which is optionally substituted by from one to three radicals selected from the group consisting of alkoxy, alkylthio, alkylamino, dialkylamino, alkoxycarbonyl, alkoxysulfonyl, halogen, cyano, carboxyl, hydroxysulfonyl and nitro, and the two optionally substituted phenyl or naphthyl radicals may be joined to one another by a chemical single bond via the carbon atoms in the ?- and ??-position relative to the phosphorus atom, n is 1, 2 or 3, and Y is halogen, cyano, thiocyanato, alkoxy, aryloxy, alkylthio, arylthio, alkylamino, dialkylamino, arylamino or diarylamino, in organic light-emitting diodes (OLEDs), The present invention further relates to light-emitting layers which comprise at least one copper(I) complex of the formula I, to OLEDs which comprise at least one copper(I) complex of the formula I or an inventive light-emittiType: ApplicationFiled: September 20, 2005Publication date: August 21, 2008Applicant: BASF AKTIENGESELLSCHAFTInventors: Arnd Vogler, Valeri Pawlowski, Hans-Werner Schmidt, Mukundan Thelakkat, Markus Bate
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Patent number: 7361786Abstract: The present invention relates to ligands of the general formula (I). In addition, a process for the production thereof and the use thereof are demonstrated.Type: GrantFiled: December 12, 2006Date of Patent: April 22, 2008Assignee: Degussa AGInventors: Armin Boerner, Jens Holz, Axel Monsees, Thomas Riermeier, Renat Kadyrov, Carsten A. Schneider, Uwe Dingerdissen, Karlheinz Drauz
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Patent number: 7312251Abstract: Stable rare earth tris (organophosphate) solutions comprise a rare earth tris (organophosphate) and a hydrocarbon solvent. From about 2% to about 10% rare earth element, preferably from about 3% to about 8%, is present in the solutions. The rare earth tris (organophosphate) solutions are stable from precipitation of the rare earth tris (organophosphate) for at least about fifteen (15) days, preferably for at least about twenty (20) days and most preferably at least about thirty (30) days. A process for preparing these solutions is described herein. A stabilizing additive, acid, glycol or mixtures thereof, is utilized to inhibit precipitation. The molar ratios of free acid, glycol and/or water to the rare earth element are controlled to inhibit precipitation.Type: GrantFiled: April 7, 2004Date of Patent: December 25, 2007Assignee: Rhodia Rare Earths, Inc.Inventors: Kenan Yunlu, Min He
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Patent number: 7268095Abstract: A compound of the formula Ia or Ib; where, in the formula Ia, E1 is O, S, Se, Te, NR, CR2, or PR; E2, E3 are each CR, N, or P; E4 is N, or P; E5 is OH, SH, NHR, OR?, SR?, or NRR?; E6 is NH, PH, NR?, or PR?; R5, R6 are each hydrogen or a linear, branched or cyclic alkyl radical or an aryl radical; R1, R2, R3, R4 are each hydrogen, a linear, branched or cyclic alkyl radical, an aryl radical, a halogen or a nitro group; R is hydrogen, a linear, branched or cyclic alkyl radical; R? is a linear, branched or cyclic alkyl radical; where at least one of the groups E5 and E6 contains a hydrogen atom; and in the formula Ib, the symbols E1, E4, E5, E6, R5, R6, R1, R2, R3, R4, R and R? are as defined in formula Ia; and E?2 and E?3 are each O, S, Se, Te, NR, CR2, or PR.Type: GrantFiled: November 3, 2003Date of Patent: September 11, 2007Assignee: Basell Polyolefine GmbHInventors: Peter Preishuber-Pflügl, Jun Okuda, Valentine Reimer, Marc Oliver Kristen
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Patent number: 7217828Abstract: Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.Type: GrantFiled: August 5, 2004Date of Patent: May 15, 2007Assignee: OXENO Olefinchemie GmbHInventors: Detlef Selent, Armin Boerner, Renat Kadyrov, Cornelia Borgmann, Dieter Hess, Klaus-Diether Wiese, Dirk Roettger
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Patent number: 7214746Abstract: This invention relates to metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is a substituted or unsubstituted indenyl ligand that is bonded to Y through the two position of the indenyl ring; A is bonded to Y, and is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E; Y is a phosphorus containing group that is bonded to both E and A, and is bonded via the phosphorus atom to E; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, oType: GrantFiled: March 11, 2005Date of Patent: May 8, 2007Assignee: ExxonMobil Chemical Patents Inc.Inventors: Alexander Z. Voskoboynikov, Denis N. Kazyulkin, Vyatcheslav V. Izmer, Alexey N. Ryabov, Jo Ann M. Canich
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Patent number: 7186784Abstract: There are disclosed a phosphorus-containing carboxylic acid derivative which has a group containing phosphorus atom and has in its molecule, a group represented by the following formula (1): wherein R1, R2 and R3 are each hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, and Y is oxygen atom or sulfur atom; a process for producing the derivative; and a flame retardant comprising the foregoing derivative as an effective ingredient. The present invention can provide the phosphorus-containing carboxylic acid derivative and a flame retardant which are each excellent in solubility in an organic solvent, compatibility with a variety of resins, stability and flame retardancy.Type: GrantFiled: September 20, 2002Date of Patent: March 6, 2007Assignee: NOF CorporationInventors: Toshinobu Fujimura, Kazunori Waki, Koji Sato, Shiro Mibae
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Patent number: 7115761Abstract: A process for preparing dihalide or monohalide metallocene compounds comprising contacting a compound of formula (II) (Cp)(ZR1m)n(A)rML?y (II) wherein Cp is a cyclopentadienyl radical; (ZR1m)n is a divalent bridging group between Cp and A; A is a cyclopentadienyl radical or O, S, NR2, PR2 wherein R2 is an hydrocarbon radical, M is zirconium, titanium or hafnium.Type: GrantFiled: September 27, 2005Date of Patent: October 3, 2006Assignee: Basell Polyolefine GmbHInventors: Luigi Resconi, Davide Balboni
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Patent number: 7115659Abstract: 2-Decarboxy-2-phosphinico prostaglandin derivatives are disclosed. These derivatives comprise a modified ?-chain and an ?-chain bonded to a ring structure. The modified ?-chain has a 2-decarboxy-2-phosphinico group. The derivatives can be used to treat a variety of pharmaceutical and cosmetic conditions.Type: GrantFiled: January 14, 2005Date of Patent: October 3, 2006Assignee: The Procter & Gamble CompanyInventor: Mitchell Anthony DeLong
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Patent number: 7094725Abstract: The present invention provides compounds of the formula wherein R is optionally substituted lower alkyl, cycloalkyl or aryl; R? is alkyl or aryl; n is zero or an integer of 1 or 2; or an enantiomer thereof; or an enantiomeric mixture thereof. The compounds of formula (I) are bridged C2-symmetric biphenyldiphosphine analogs and, thus, may be employed as ligands to generate chiral transition metal catalysts which may be applied in a variety of asymmetric reactions. The compounds of the present invention are easily accessible in high diastereomeric and optical purity according to the methods disclosed herein.Type: GrantFiled: July 9, 2004Date of Patent: August 22, 2006Assignee: The Hong Kong Polytechnic UniversityInventors: Albert Sun-Chi Chan, Liqin Qiu
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Patent number: 7087773Abstract: Group 4 metal constrained geometry complexes comprising tricyclic 4-arylsubstituted indenyl ligands, especially 1,5,6,7-tetrahydro-4-aryl-s-indacen-1-yl ligands, catalytic derivatives thereof, processes for preparing the same and their use as components of olefin polymerization catalysts are disclosed.Type: GrantFiled: May 22, 2003Date of Patent: August 8, 2006Assignee: Dow Global Technologies Inc.Inventors: David D. Graf, Roger L. Kuhlman
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Patent number: 7067685Abstract: The invention relates to phosphinites I of formulae (1) or (2), in which R1, R2, R5, R6, R7, R8, R9 independently represent hydrogen, an alkyl or alkylene group having 1 to 8 carbon atoms or an alkoxy group having 1 to 8 carbon atoms; R3 is H or methyl; R4 is i-propyl or t-butyl; X is F, Cl or CF3 and n is 1 or 2Type: GrantFiled: October 4, 2002Date of Patent: June 27, 2006Assignee: BASF AktiengesellschaftInventors: Michael Bartsch, Robert Baumann, Dagmar Pascale Kunsmann-Keitel, Gerd Haderlein, Tim Jungkamp, Marco Altmayer, Wolfgang Siegel, Ferenc Molnar
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Patent number: 7022866Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.Type: GrantFiled: October 1, 2002Date of Patent: April 4, 2006Assignee: BASF AktiengesellschaftInventors: Michael Bartsch, Robert Baumann, Dagmar Pascale Kunsmann-Keitel, Gerd Haderlein, Tim Jungkamp, Marco Altmayer, Wolfgang Siegel, Ferenc Molnar
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Patent number: 7019158Abstract: Chiral organometallic compounds are provided which comprise certain non-symmetrically substituted cyclopentadiene complexed to a transition metal. The cyclopentadiene has a second coordinating group which also complexes the transition metal and is attached to the cyclopentadiene by means of a chiral connecting chain. Preferred transition metals include rhodium, ruthenium, iridium, cobalt, iron, manganese, chromium, tungsten, molybdenum, nickel, palladium, or platinum. These chiral organometallic compounds find use in asymmetric synthesis to produce chiral compounds.Type: GrantFiled: August 2, 2002Date of Patent: March 28, 2006Assignee: Avecia LimitedInventor: Richard John Whitby
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Patent number: 6987196Abstract: A process for preparing dihalide or monohalide metallocene compounds comprising contacting a compound of formula (II) (Cp)(ZR1m)n(A)rML?y (II) wherein Cp is a cyclopentadienyl radical; (ZR1m)n is a divalent bridging group between Cp and A; A is a cyclopentadienyl radical or O, S, NR2, PR2 wherein R2 is an hydrocarbon radical, M is zirconium, titanium or hafnium, L? is an hydrocarbon radical, r ranges from 0 to 2 and y is equal to 4; with an halogenating agent selected from the group consisting of: T1Lw1 wherein T1 is a metal of groups 3–13 of the periodic table; L is halogen and w1 is equal to the oxidation state of the metal T1; T2Lw2 wherein T2 is a nonmetal element of groups 13–16 of the periodic table (new IUPAC version); and w2 is equal to the oxidation state of the element T2; O=T3Lw3 where T3 is a selected from the group consisting of C, P and S; O is an oxygen atom bonded to T3 trough a double bond; and w3 is equal to the oxidation state of the element T3 minus 2; R6C(O)L, wherein R6 is an hydrocarbonType: GrantFiled: April 3, 2002Date of Patent: January 17, 2006Assignee: Basell Polyolefine GmbHInventors: Luigi Resconi, Davide Balboni
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Patent number: 6894175Abstract: 2-Decarboxy-2-phosphinico prostaglandin derivatives are disclosed. These derivatives comprise a modified ?-chain and an ?-chain bonded to a ring structure. The modified ?-chain has a 2-decarboxy-2-phosphinico group. The derivatives can be used to treat a variety of pharmaceutical and cosmetic conditions.Type: GrantFiled: August 4, 2000Date of Patent: May 17, 2005Assignee: The Procter & Gamble CompanyInventor: Mitchell Anthony DeLong
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Ortho substituted chiral phosphines and phosphinites and their use in asymmetric catalytic reactions
Patent number: 6855657Abstract: 3,3?-Substituted chiral biaryl phosphine and phosphinite ligands and metal complexes based on such chiral ligands useful in asymmetric catalysis are disclosed. The metal complexes are useful as catalysts in asymmetric reactions, such as, hydrogenation, hydride transfer, allylic alkylation, hydrosilylation, hydroboration, hydrovinylation, hydroformylation, olefin metathesis, hydrocarboxylation, isomerization, cyclopropanation, Diels-Alder reaction, Heck reaction, isomerization, Aldol reaction, Michael addition, epoxidation, kinetic resolution and [m+n] cycloaddition. The metal complexes are particularly effective in Ru-catalyzed asymmetric hydrogenation of beta-ketoesters to beta-hydroxyesters and Ru-catalyzed asymmetric hydrogenation of enamides to beta amino acids.Type: GrantFiled: September 11, 2003Date of Patent: February 15, 2005Assignee: The Penn State Research FoundationInventor: Xumu Zhang -
Patent number: 6825369Abstract: A monocyclopentadienyl or substituted monocyclopentadienyl metal complex containing compound useful as a polymerization catalyst corresponding to the formula: CpMXn+A− wherein: Cp is an &eegr;5-substituted cyclopentadienyl group optionally covalently bonded to M through a substituent, said Cp being substituted in at least one occurrence with an alkoxy or aryloxy group; M is a metal of Group 3-10 or the Lanthanide Series of the Periodic Table bound in an &eegr;hu 5 bonding mode to the cyclopentadienyl or substituted cyclopentadienyl group; X each occurrence independently is selected from the group consisting of hydride, halo, alkyl, aryl, silyl, germyl, aryloxy, alkoxy, amide, siloxy, neutral Lewis base ligands and combinations thereof having up to 20 non-hydrogen atoms, and optionally one X together with Cp forms a metallocycle with M; R is alkyl or aryl of up to 10 carbons; n is one or two depending on the valence of M; and A is a noncoordinating, compatible anion of a Bronsted acid salt.Type: GrantFiled: March 10, 1994Date of Patent: November 30, 2004Assignee: The Dow Chemical CompanyInventors: James C. Stevens, David R. Neithamer
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Patent number: 6812306Abstract: Metal compounds of the formula I, where M is selected from among Ni and Pd in the oxidation state +II can be used for the polymerization or copolymerization of olefins. Supported catalysts for the polymerization and copolymerization of olefins can be obtained by application of one or more of the above-described ionic metal compounds to a support.Type: GrantFiled: January 2, 2003Date of Patent: November 2, 2004Assignee: BASF AktiengesellschaftInventors: Marc Oliver Kristen, Peter Hofmann, Frank Eisenträger
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Patent number: RE39532Abstract: The novel metallocenes of the formula I in which, preferably, M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, —(CR8R9)m—R7—(CR8R9)n— is a single- or multi-membered chain in which R7 may also be a (substituted) hetero atom, m+n is zero or 1, and R10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.Type: GrantFiled: July 17, 1997Date of Patent: March 27, 2007Assignee: Basell Polyolefine GmbHInventors: Andreas Winter, Martin Antberg, Walter Spaleck, Jürgen Rohrmann, Volker Dolle
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Patent number: RE39561Abstract: The novel metallocenes of the formula I in which, preferably, M1 is Zr or Hf, R1 and R2 are alkyl or halogen, R3 and R4 are hydrogen, R5 and R6 are alkyl or haloalkyl, —(CR8R9)m—R7—(CR8R9)n— is a single- or multi-membered chain in which R7 may also be a (substituted) hetero atom, m+n is zero or 1, and R10 is hydrogen, form, together with aluminoxanes as cocatalysts, a very effective catalyst system for the preparation of polyolefins of high stereospecificity and high melting point.Type: GrantFiled: July 17, 1997Date of Patent: April 10, 2007Assignee: Basell Polyoefine GmbHInventors: Andreas Winter, Martin Antberg, Walter Spaleck, Jürgen Rohrmann, Volker Dolle