Abstract: Oxime-carbamates of fluorinated ketones of the formula ##STR1## in which X represents hydrogen or fluorine,R represents alkyl, cycloalkyl, phenyl or phenylalkyl, any of which can optionally be substituted,R.sup.1 and R.sup.2, which may be identical or different, each represent hydrogen, alkyl, alkenyl, alkynyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl or optionally substituted phenyl, andR.sup.2 can also represent the --SR.sup.3 grouping,R.sup.3 represents alkyl, halogenoalkyl, optionally substituted phenyl or alkoxycarbonyl, or represents a radical identical to that to which the --SR.sup.3 grouping is bonded, or represents the ##STR2## grouping, WHEREINR.sup.4 represents alkyl andR.sup.5 represents alkyl, dialkylamino or optionally substituted phenyl,And acid addition salts thereof, which possess insecticidal, acaricidal, nematicidal and fungicidal properties.
Type:
Grant
Filed:
July 12, 1977
Date of Patent:
September 26, 1978
Assignee:
Bayer Aktiengesellschaft
Inventors:
Jorg Stetter, Ingeborg Hammann, Bernhard Homeyer, Wolfgang Behrenz
Abstract: Certain derivatives of cyclopropane carboxylic acid and their esters are useful and valuable intermediates for the preparation of broad spectrum pyrethroid type pesticides. The invention provides a novel method for the preparation of the derivatives of cyclopropane carboxylic acid and esters from stable sulfonium ylides.
Abstract: Mercaptans are prepared by reacting an organic chloride or bromide with a mixture of H.sub.2 S and ammonia or an amine at a temperature of 0.degree. to 175.degree. C. under autogenous pressure. The reaction can be carried out in the presence of a polar solvent. For example, 3-chloropropyltrimethoxysilane is mixed with H.sub.2 S and ammonia in methanol and heated in a closed container at 100.degree. C. for 18 hours.
Abstract: This invention is directed to novel halogen-containing polythiols which impart improved flame retardancy to radiation cured thiol-ene compositions.
Abstract: Stabilizer mixtures that are capable of enhancing the resistance of polyolefins to degradation as a result of exposure to light and air, particularly at elevated temperatures, are obtained by reacting an .alpha.-olefin with an ester of a mercaptocarboxylic acid and a polyhydric alcohol, forming a reaction product of unknown structure containing thioether groups and carboxylic acid ester groups.
Abstract: 2-Amino-(2)-thiazoline-4-carboxylic acid is prepared by dehydrochlorinating S-(.beta.-carboxy-.beta.-chloroethyl) isothiourea by adding it to an aqueous medium maintained at a pH ranging from 5.5 to 7.5 with an alkali.
Abstract: A new method of preparing trifluoromethylthioacetic acid using a tertiary phosphine in a sulfur extrusion of lower alkyl trifluoromethyldithioacetate with optional is situ alkaline hydrolysis of said acetate using a biphasic hydrolysis system in the presence of a phase transfer catalyst.
Abstract: A process is provided for the preparation of mercapto propionic acid esters and/or polythio dipropionic acid esters by reaction of an acrylic acid ester with hydrogen sulfide in the presence of a weakly basic amine as a catalyst, a polythiodipropionic acid ester as a reactive solvent, and added elemental sulfur.
Type:
Grant
Filed:
May 11, 1977
Date of Patent:
January 10, 1978
Assignee:
Witco Chemical Corporation
Inventors:
Shaul Gladstone, Srinivasa R. Rao, C. Joseph Rosshirt
Abstract: Ketoalkanesulfenylcarbamoyl and ketoalkanethiosulfenylcarbamoyl halides are useful intermediates in the preparation of pesticidally active carbamates.
Abstract: A pleuromutilin derivative which is 14-desoxy-14-thiocyanatoacetoxy-mutilin is useful as an animal feed additive to increase meat production and also finds application in veterinary medicine as an antibiotic.
Abstract: Symmetric azo-bis-mercapto compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are methyl or ethyl, R.sub.3 and R.sub.4 are the same or different alkylene having 1 to 4 carbon atoms, and n is 0 or 1, and a method for forming block copolymers of vinyl monomers in a two-step process employing such compounds as polymerization initiators.
Type:
Grant
Filed:
April 20, 1976
Date of Patent:
November 22, 1977
Assignee:
Rohm GmbH
Inventors:
Otto Hitzler, Horst Pennewiss, August Froelich, Gerhard Markert, Winfried Wunderlich
Abstract: A process is provided for the preparation of mercapto propionic acid esters and/or polythio dipropionic acid esters by reaction of an acrylic acid ester with hydrogen sulfide in the presence of a weakly basic amine base as a catalyst and a polythiodipropionic acid ester as a reactive solvent.
Type:
Grant
Filed:
September 19, 1975
Date of Patent:
October 4, 1977
Assignee:
Witco Chemical Corporation
Inventors:
Shaul Gladstone, Srinivasa R. Rao, C. Joseph Rosshirt
Abstract: This invention is directed to novel halogen-containing polythiols which impart improved flame retardancy to radiation cured thiol-ene compositions.