Sulfur In Acid Moiety Patents (Class 560/147)
  • Patent number: 4117154
    Abstract: Oxime-carbamates of fluorinated ketones of the formula ##STR1## in which X represents hydrogen or fluorine,R represents alkyl, cycloalkyl, phenyl or phenylalkyl, any of which can optionally be substituted,R.sup.1 and R.sup.2, which may be identical or different, each represent hydrogen, alkyl, alkenyl, alkynyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl or optionally substituted phenyl, andR.sup.2 can also represent the --SR.sup.3 grouping,R.sup.3 represents alkyl, halogenoalkyl, optionally substituted phenyl or alkoxycarbonyl, or represents a radical identical to that to which the --SR.sup.3 grouping is bonded, or represents the ##STR2## grouping, WHEREINR.sup.4 represents alkyl andR.sup.5 represents alkyl, dialkylamino or optionally substituted phenyl,And acid addition salts thereof, which possess insecticidal, acaricidal, nematicidal and fungicidal properties.
    Type: Grant
    Filed: July 12, 1977
    Date of Patent: September 26, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jorg Stetter, Ingeborg Hammann, Bernhard Homeyer, Wolfgang Behrenz
  • Patent number: 4096269
    Abstract: Novel N-haloalkanesulfenylcarbamoyloxime compounds have been found to have exceptional miticidal and insecticidal activity.
    Type: Grant
    Filed: May 20, 1976
    Date of Patent: June 20, 1978
    Assignee: Union Carbide Corporation
    Inventor: Themistocles Damasceno Joaquim D'Silva
  • Patent number: 4091006
    Abstract: A new series of substituted esters of 3-hydroxyindone compounds have been found to have exceptional miticidal and herbicidal activity.
    Type: Grant
    Filed: October 1, 1975
    Date of Patent: May 23, 1978
    Assignee: Union Carbide Corporation
    Inventors: John A. Durden, Jr., Anthony A. Sousa, John F. Stephen
  • Patent number: 4091024
    Abstract: New derivatives of amino acids which have the general formula ##STR1## are useful as angiotensin converting enzyme inhibitors.
    Type: Grant
    Filed: December 3, 1976
    Date of Patent: May 23, 1978
    Assignee: E. R. Squibb & Sons, Inc.
    Inventor: Miguel Angel Ondetti
  • Patent number: 4083863
    Abstract: Certain derivatives of cyclopropane carboxylic acid and their esters are useful and valuable intermediates for the preparation of broad spectrum pyrethroid type pesticides. The invention provides a novel method for the preparation of the derivatives of cyclopropane carboxylic acid and esters from stable sulfonium ylides.
    Type: Grant
    Filed: June 1, 1976
    Date of Patent: April 11, 1978
    Assignee: American Cyanamid Corporation
    Inventor: William Wayne Brand
  • Patent number: 4082790
    Abstract: Mercaptans are prepared by reacting an organic chloride or bromide with a mixture of H.sub.2 S and ammonia or an amine at a temperature of 0.degree. to 175.degree. C. under autogenous pressure. The reaction can be carried out in the presence of a polar solvent. For example, 3-chloropropyltrimethoxysilane is mixed with H.sub.2 S and ammonia in methanol and heated in a closed container at 100.degree. C. for 18 hours.
    Type: Grant
    Filed: March 10, 1975
    Date of Patent: April 4, 1978
    Assignee: Dow Corning Corporation
    Inventor: John L. Speier
  • Patent number: 4081598
    Abstract: This invention is directed to novel halogen-containing polythiols which impart improved flame retardancy to radiation cured thiol-ene compositions.
    Type: Grant
    Filed: May 16, 1977
    Date of Patent: March 28, 1978
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, David E. Kramm
  • Patent number: 4080364
    Abstract: Stabilizer mixtures that are capable of enhancing the resistance of polyolefins to degradation as a result of exposure to light and air, particularly at elevated temperatures, are obtained by reacting an .alpha.-olefin with an ester of a mercaptocarboxylic acid and a polyhydric alcohol, forming a reaction product of unknown structure containing thioether groups and carboxylic acid ester groups.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: March 21, 1978
    Assignee: Argus Chemical Corporation
    Inventors: Otto S. Kauder, Lawrence R. Brecker
  • Patent number: 4072687
    Abstract: 2-Amino-(2)-thiazoline-4-carboxylic acid is prepared by dehydrochlorinating S-(.beta.-carboxy-.beta.-chloroethyl) isothiourea by adding it to an aqueous medium maintained at a pH ranging from 5.5 to 7.5 with an alkali.
    Type: Grant
    Filed: November 1, 1976
    Date of Patent: February 7, 1978
    Assignee: Ajinomoto Co., Inc.
    Inventors: Kazushi Togo, Fumihide Tamura, Naohiko Yasuda, Takehiko Ichikawa, Konosuke Sano, Keizo Matsuda, Koji Mitsugi
  • Patent number: 4069243
    Abstract: A new method of preparing trifluoromethylthioacetic acid using a tertiary phosphine in a sulfur extrusion of lower alkyl trifluoromethyldithioacetate with optional is situ alkaline hydrolysis of said acetate using a biphasic hydrolysis system in the presence of a phase transfer catalyst.
    Type: Grant
    Filed: May 24, 1976
    Date of Patent: January 17, 1978
    Assignee: SmithKline Corporation
    Inventor: Robert Michael DeMarinis
  • Patent number: 4067901
    Abstract: A process is provided for the preparation of mercapto propionic acid esters and/or polythio dipropionic acid esters by reaction of an acrylic acid ester with hydrogen sulfide in the presence of a weakly basic amine as a catalyst, a polythiodipropionic acid ester as a reactive solvent, and added elemental sulfur.
    Type: Grant
    Filed: May 11, 1977
    Date of Patent: January 10, 1978
    Assignee: Witco Chemical Corporation
    Inventors: Shaul Gladstone, Srinivasa R. Rao, C. Joseph Rosshirt
  • Patent number: 4066689
    Abstract: Ketoalkanesulfenylcarbamoyl and ketoalkanethiosulfenylcarbamoyl halides are useful intermediates in the preparation of pesticidally active carbamates.
    Type: Grant
    Filed: May 20, 1976
    Date of Patent: January 3, 1978
    Assignee: Union Carbide Corporation
    Inventor: Themistocles D. J. D'Silva
  • Patent number: 4060542
    Abstract: A pleuromutilin derivative which is 14-desoxy-14-thiocyanatoacetoxy-mutilin is useful as an animal feed additive to increase meat production and also finds application in veterinary medicine as an antibiotic.
    Type: Grant
    Filed: June 28, 1976
    Date of Patent: November 29, 1977
    Assignee: Biochemie Gesellschaft m.b.H.
    Inventor: Kurt Riedl
  • Patent number: 4059574
    Abstract: Symmetric azo-bis-mercapto compounds of the formula ##STR1## wherein R.sub.1 and R.sub.2 are methyl or ethyl, R.sub.3 and R.sub.4 are the same or different alkylene having 1 to 4 carbon atoms, and n is 0 or 1, and a method for forming block copolymers of vinyl monomers in a two-step process employing such compounds as polymerization initiators.
    Type: Grant
    Filed: April 20, 1976
    Date of Patent: November 22, 1977
    Assignee: Rohm GmbH
    Inventors: Otto Hitzler, Horst Pennewiss, August Froelich, Gerhard Markert, Winfried Wunderlich
  • Patent number: 4052440
    Abstract: A process is provided for the preparation of mercapto propionic acid esters and/or polythio dipropionic acid esters by reaction of an acrylic acid ester with hydrogen sulfide in the presence of a weakly basic amine base as a catalyst and a polythiodipropionic acid ester as a reactive solvent.
    Type: Grant
    Filed: September 19, 1975
    Date of Patent: October 4, 1977
    Assignee: Witco Chemical Corporation
    Inventors: Shaul Gladstone, Srinivasa R. Rao, C. Joseph Rosshirt
  • Patent number: 4048218
    Abstract: This invention is directed to novel halogen-containing polythiols which impart improved flame retardancy to radiation cured thiol-ene compositions.
    Type: Grant
    Filed: February 24, 1975
    Date of Patent: September 13, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Charles R. Morgan, David E. Kramm