Benzene Ring Containing Patents (Class 568/607)
  • Patent number: 5576275
    Abstract: A sequential block copolymer of the formula:R.sup.1 X--[C.sub.y H.sub.2y O).sub.m)C.sub.x H.sub.2x O).sub.n --H](I)containing: (i) a moiety R.sup.1 X derived from a starter molecule having at least one active hydrogen wherein R.sup.1 X is either a C.sub.10 -C.sub.24 alkyl or a C.sub.9 -C.sub.24 alkaryl group, X is O, S or N, (ii) a polymeric block derived from at least one alkylene oxide of formula C.sub.x H.sub.x2 O wherein x is either 3 or 4, and (iii) a polymeric block derived from at least one alkylene oxide of formula C.sub.y H.sub.2y O wherein y is an integer in the range from 12 to 16, and wherein q is 1 when X is O or S, and q is 2 when X is N; and m and n are such that the molecular weight is in the range from 600 to 4000; and the (C.sub.y H.sub.2y O) polymeric block derived from the alkylene oxide of formula C.sub.y H.sub.2y O forms from 1 to 40% by weight of the copolymer, and the polymeric block derived from the alkylene oxide of formula C.sub.y H.sub.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: November 19, 1996
    Assignee: BP Chemicals Limited
    Inventor: John R. Moxey
  • Patent number: 5456847
    Abstract: There are disclosed low foaming, nonsilicone aqueous textile auxiliary compositions comprising(a) a reaction product of a nonionic surfactant of formula ##STR1## wherein R is an aliphatic radical of at least 8 carbon atoms,R.sub.1 is hydrogen, C.sub.1 -C.sub.8 alkyl, a cycloaliphatic radical of at least 5 carbon atoms, lower alkylphenyl or styryl,"alkylene" denotes an alkylene radical of 2 to 4 carbon atoms, and p is an integer from 2 to 60,with a compound which contains an acid water-solubilising group,(b) a nonionic surfactant of formula (1), and, optionally,(c) a hydrotropic agent.These textile auxiliary compositions are suitable for use as dispersants and for wetting and/or washing fibre materials.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: October 10, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Christian Guth, Albert Stehlin
  • Patent number: 5440060
    Abstract: The demands on the properties of pigments, in particular in the areas of emulsion paints and printing inks, which are continuously becoming more specific made it necessary to develop selective and environmentally safe dispersing and emulsifying agents and coupling auxiliaries.The compounds according to the invention are alkoxylation products prepared from fatty amine dialkylenediamines which, if desired, are linked to give recurring structural units by means of esterification with dicarboxylic acids and in which, preferably, the hydroxyl end groups of these fatty amine alkylenediamine alkoxylates have been esterified with fatty acids, aromatic carboxylic acids and/or resin acids and any hydroxyl groups still present have been converted to the corresponding mono-ester-containing anionic radicals by means of dicarboxylic acids and sulfites.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: August 8, 1995
    Assignee: Hoechst AG
    Inventors: Heinz Uhrig, Albert Munkel
  • Patent number: 5416240
    Abstract: Polyoxyalkylene glycols are prepared by a process in which tetrahydrofuran is polymerized with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals in the absence of water and in the presence of a monohydric alcohol or of a monocarboxylic acid with the aid of an anhydrous heteropoly acid catalyst, and the polyoxyalkylene glycol is liberated from the resulting polyoxyalkylene glycol monoethers or polyoxyalkylene glycol monoesters by cleavage of the monoether or monoester bond.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: May 16, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Weyer, Rolf Fischer, Gerhard Jeschek, Franz Merger, Herbert Mueller
  • Patent number: 5414143
    Abstract: Polyoxyalkylene glycol monoethers of monohydric alcohols are prepared by a process in which tetrahydrofuran or a mixture of tetrahydrofuran with a total of not more than 95 mol %, based on the amount of tetrahydrofuran used, of one or more comonomers from the group consisting of the cyclic ethers and acetals is polymerised in the absence of water and in the presence of a monohydric alcohol and of an anhydrous heteropoly acid catalyst.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: May 9, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans-Juergen Weyer, Rolf Fischer, Gerhard Jeschek, Herbert Mueller
  • Patent number: 5366517
    Abstract: A fuel additive composition comprising:(a) a poly(oxyalkylene) hydroxyaromatic ether having the formula: ##STR1## or a fuel-soluble salt thereof; where R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is hydrogen, alkyl having 1 to 30 carbon atoms, phenyl, aralkyl or alkaryl having 7 to 36 carbon atoms, or an acyl group of the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, or aralkyl or alkaryl having 7 to 36 carbon atoms; n is an integer from 5 to 100; and x is an integer from 0 to 10; and(b) a poly(oxyalkylene) amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene) amine soluble in hydrocarbons boiling in the gasoline or diesel fuel range.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: November 22, 1994
    Assignee: Chevron Research and Technology Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5356893
    Abstract: The invention provides compounds of formula (I): ##STR1## or a physiologically acceptable salt or solvate thereof wherein R.sup.1 represents a halogen or hydrogen atom or a C.sub.1-6 alkyl or C.sub.1-6 alkoxy group;R.sup.2 represents a phenyl group optionally substituted by one or two substituents;R.sup.3 represents the group ##STR2## R.sup.4 and R.sup.5, which may be the same or different, each independently represent a hydrogen atom or a halogen atom, or a group selected from hydroxy, C.sub.1-6 alkoxy or C.sub.1-6 alkyl.The compounds may be used in the treatment or prophylaxis of depression and other CNS disorders.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: October 18, 1994
    Assignee: Glaxo Group Limited
    Inventors: John Bradshaw, John W. Clitherow, Ian B. Campbell
  • Patent number: 5342903
    Abstract: A process for the preparation of adducts by reacting an alcohol with an epoxy compound in the presence of a catalyst, which comprises reacting an alcohol of formula I ##STR1## wherein A is an aliphatic, cycloaliphatic or araliphatic radical and r is a number from 1 to 10, with a mono- or diepoxide in the equivalent ratio of 1:20 to 20:1, based on the hydroxyl and epoxy groups, in the presence of a metal complex of formula II as catalyst[M.sup.n+ (L.sub.1).sub.x (L.sub.2).sub.y (L.sub.3.sup.m-).sub.z ][X.sup.k- ].sub.(n-zm)/k (II),whereinM is a metal of the main groups or subgroups of the Periodic Table of the Elements,L.sub.1 and L.sub.2 are weakly bonded, neutral, unidentale or multidentate ligands,L.sub.3 is a strongly bonded, non-replaceable neutral or anionic unidentale or multidentate ligand,X is an anion of the following formulae BF.sub.4.sup.-, PF.sub.6.sup.-, AsF.sub.6.sup.-, SbF.sub.6.sup.-, ClO.sub.4.sup.-, IO.sub.4.sup.-, NO.sub.3.sup.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: August 30, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Wolleb, Andreas Hafner, William M. Rolfe
  • Patent number: 5210322
    Abstract: A process for preparing ethers which comprises contacting a carboxylated ether with a metal oxide catalyst under conditions effective to produce the ether.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: May 11, 1993
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Stephen W. King, Kurt D. Olson
  • Patent number: 5196569
    Abstract: Trifluorovinyl ethers containing selected functional groups, and homo- and copolymers prepared from them, are disclosed, as well as intermediates useful in the preparation of the ethers.
    Type: Grant
    Filed: October 10, 1991
    Date of Patent: March 23, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ming-Hong Hung
  • Patent number: 5189204
    Abstract: 3-(2-Trifluoro-1-hydroxyethyl)propenyl benzyl ether or derivatives thereof having the formula ##STR1## wherein R is a substituted or not substituted phenyl group and a mark * shows an asymmetric carbon atom, and derivatives thereof are provided, which are useful as a material for preparing liquid crystal compound.
    Type: Grant
    Filed: June 25, 1991
    Date of Patent: February 23, 1993
    Assignee: Showa Shell Sekiyu Kabushiki Kaisha
    Inventors: Tomoya Kitazumo, Takashi Yamazaki, Hitoshi Iwatsubo
  • Patent number: 5183923
    Abstract: The invention concerns a method for the preparation of polyurethane, polyester, polyamide, and polyurea diols which contain essentially all primary hydroxyl groups without capping by ethylene oxide. The method comprises coupling an alkylene oxide adduct of propylene glycol t-butyl ether or butylene glycol t-butyl ether or its aminated derivative with organic diisocyanates or dibasic acids followed by cleavage of the t-butyl group with an acid catalyst.The resulting diol is useful in many types of urethane applications including foams, elastomers and coatings.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: February 2, 1993
    Assignee: Texaco Chemical Company
    Inventors: Michael Cuscurida, George P. Speranza
  • Patent number: 5106885
    Abstract: What is provided herein are radiation curable compositions containing(a) multifunctional vinyl ether monomers having the formula:X--R.sub.1 --Y.sub.1 --R.sub.2 --Y.sub.2).sub.n CH.dbd.CH.sub.2 ].sub.mwhereX is a 5-8 membered ring, saturated or unsaturated;R.sub.1 is a direct bond or C.sub.1 -C.sub.10 straight or branched chain alkylene;Y.sub.1 and Y.sub.2 are independently oxygen or sulfur;R.sub.2 is C.sub.2 -C.sub.10 straight or branched chain alkylene;n is 0-10; andm is 3-5;(b) a cationic initiator, and, optionally,(c) a polymerizable vinyl ether, epoxide, or acrylate oligomer.
    Type: Grant
    Filed: November 3, 1989
    Date of Patent: April 21, 1992
    Assignee: ISP Investments Inc.
    Inventors: Kou-Chang Liu, Fulvio J. Vara, James A. Dougherty
  • Patent number: 5104987
    Abstract: This invention relates to a process for the alkoxylation of an active hydrogen-containing compound comprising contacting the active hydrogen-containing compound with an alkylene carbonate in the presence of a mixed metal oxide catalyst under conditions effective to alkoxylate the active hydrogen-containing compound.
    Type: Grant
    Filed: September 20, 1990
    Date of Patent: April 14, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Stephen W. King
  • Patent number: 5097076
    Abstract: Addition products of phenylalkyl glycidyl ethers to polyalkylene glycol ethers of the formulaR-O Alkylene--O.sub.m H (1)their acid esters and salts thereof, wherein R is an aliphatic radical having at least 4 carbon atoms, "Alkylene" is an alkylene radical of 2 or 3 carbon atoms, and m is a number from 2 to 100.These products represent a novel class of non-ionic or anionic surfactants that are used as textile finishing agents, especially as emulsifiers, wetting agents, foaminhibitors or dyeing auxiliaries.
    Type: Grant
    Filed: June 26, 1990
    Date of Patent: March 17, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Dieter Reinehr, Rosemarie Topfl
  • Patent number: 5091588
    Abstract: Fluorinated styrene derivatives of the general formula: ##STR1## wherein n is an integer of 1 to 3 are novel. They form homopolymers and copolymers having water and oil repellency, chemical resistance and flexibility. They are prepared by reacting a halomethylstyrene with an alcohol having a perfluoropolyether group in the presence of a base.
    Type: Grant
    Filed: September 19, 1990
    Date of Patent: February 25, 1992
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Yasushi Yamamoto
  • Patent number: 4987271
    Abstract: A method for purifying a polyoxyalkylene alcohol, which comprises treating with a treating agent consisting essentially of a pH buffer, a polyoxyalkylene alcohol containing a double metal cyanide complex catalyst, synthesized by ring-opening polymerization of an alkylene oxide in the presence of said catalyst, and then removing the catalyst and the treating agent from the polyoxyalkylene alcohol.
    Type: Grant
    Filed: February 14, 1990
    Date of Patent: January 22, 1991
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Takashi Watabe, Hiromitsu Takeyasu, Takao Doi, Nobuaki Kunii
  • Patent number: 4985590
    Abstract: Disclosed are novel optically active benzene derivatives represented by the formula (I): ##STR1## wherein R represents an alkyl or alkoxyalkyl group having 1 to 20 carbon atoms, which group may contain a halogen; Z represents a hydrogen atom or a halogen atom; l and n each represents a number of 0 or 1; and * indicates asymmetric carbon atom, anda process for preparing the above optically active benzene derivative which comprises debenzylating an optically active benzyl derivative represented by the formula (II): ##STR2## wherein, R, Z, l, n and * have the same meanings as defined above, and A represents a hydrogen atom, a lower alkyl group, a lower alkoxyl group or a halogen atom.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: January 15, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masayoshi Minai, Takayuki Higashi
  • Patent number: 4985077
    Abstract: A watercolor ink contains a water-soluble dye, water, and at least one benzyl ether represented by the general formulas ##STR1## (wherein n.sub.1 stands for an integer of 3 to 15) and ##STR2## (wherein m stands for an integer of 1 to 15 and n.sub.2 for 0 or an integer of 1 to 14, providing that 1.ltoreq.m+n.sub.2 .ltoreq.15 is satisfied).
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: January 15, 1991
    Assignee: Taiho Industries Co., Ltd.
    Inventors: Osao Ise, Hideto Kanazawa, Masahiko Ishida
  • Patent number: 4962237
    Abstract: A catalytic process for polymerizing epoxides using active hydrogen initiators forming polyols having low unsaturation levels and high primary hydroxyl levels. The catalysts useful in this process are prepared from catalyst precursors exemplified by hydrotalcite. This process is more reactive with less acidic active hydrogen initiators. The polyols can be used in urethanes without removal of the catalyst.
    Type: Grant
    Filed: January 2, 1990
    Date of Patent: October 9, 1990
    Assignee: The Dow Chemical Company
    Inventor: David E. Laycock
  • Patent number: 4957986
    Abstract: Partially fluorinated polyesters are disclosed having increased biodegradability and water repellency. The incorporation of an ester group into the backbone of the partially fluorinated compound permits modification of the compound's physical properties.
    Type: Grant
    Filed: December 15, 1989
    Date of Patent: September 18, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Harry N. Cripps
  • Patent number: 4946984
    Abstract: This invention relates to the use of calcium sulfate as a catalyst in the preparation of alkoxylation products, i.e., condensation reaction products of alkylene oxides and organic compounds having at least one active hydrogen, that have beneficial, narrow molecular weight ranges.
    Type: Grant
    Filed: September 30, 1988
    Date of Patent: August 7, 1990
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventor: Charles F. Hauser
  • Patent number: 4943626
    Abstract: Polyether active hydrogen compounds having at least two terminal active hydrogen groups on primary carbon atoms are prepared by (a) forming polyoxyalkylene molecules each having at least one active hydrogen precursor, (b) linking at least two of the polyoxyalkylene molecules, and (c) converting the active hydrogen precursor groups to active hydrogen groups on primary carbon atoms. The polyoxyalkylene molecule is formed by exposing a reaction mixture comprising at least one alkylene oxide and at least one protective initiator to conditions effective for the polymerization of the alkylene oxides. Linking is accomplished at polyether chain ends distal to the protected active hydrogen precursor groups, such that the active hydrogen precursors remain on the linked polyether chains until they are converted to active hydrogen groups.
    Type: Grant
    Filed: July 29, 1988
    Date of Patent: July 24, 1990
    Assignee: The Dow Chemical Company
    Inventors: James E. McGrath, Youngtai Yoo, Robert B. Turner, Diane M. Lewis
  • Patent number: 4915875
    Abstract: Paramethyl-substituted hindered phenols are selectively oxidized by contacting with an oxidizing agent at elevated temperatures in the presence of a heterogeneous oxidative coupling catalyst. In the absence of an optional nucleophile the products comprise carbon-carbon oxidative coupling products. In the presence of a nucleophile, addition products result that may be further oxidized by continued exposure to the oxidizing agent to yield substituted p-hydroxybenzaldehydes.
    Type: Grant
    Filed: November 4, 1986
    Date of Patent: April 10, 1990
    Assignee: The Dow Chemical Company
    Inventors: Timothy R. Diephouse, Robert M. Strom
  • Patent number: 4902834
    Abstract: A process is disclosed for the preparation of capped polyoxyalkylene block polyethers with exceptionally low hydroxyl numbers and correspondingly high capping efficiency. This improvement is accomplished through the use of cesium hydroxide catalysis during oxyethylation.
    Type: Grant
    Filed: August 30, 1988
    Date of Patent: February 20, 1990
    Assignee: BASF Corporation
    Inventors: Jay G. Otten, Roger A. Ott
  • Patent number: 4886917
    Abstract: Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: December 12, 1989
    Assignee: Union Carbide Chemicals and Plastics Company Inc.
    Inventors: Robert J. Knopf, Louis F. Theiling, Jr.
  • Patent number: 4879419
    Abstract: Hydroxyl terminated polyepichlorohydrin having a polydispersity of less than 1.2 and a molecular weight of at least 2000, and method of preparation using stannic chloride and strong carboxylic acid co-catalysts.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: November 7, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Birger Johannessen
  • Patent number: 4800186
    Abstract: A method of regenerating a deactivated fluorocarbonsulfonic acid polymer catalyst by contacting the deactivated catalyst with a solvent combination wherein a first solvent swells the structure of the polymer and the other acts as a diluent to modify the swelling action of the first. The combination dissolves the deactivating components.
    Type: Grant
    Filed: October 28, 1987
    Date of Patent: January 24, 1989
    Assignee: The Dow Chemical Company
    Inventor: Emmett L. Tasset
  • Patent number: 4774356
    Abstract: Polypropylene oxide having unsaturated end groups is prepared by polymerizing alkylene oxide in the presence of a complex catalyst prepared by reacting an organoaluminum compound with a porphyrin compound and an active hydrogen-containing compound and converting at least one hydroxyl end groups into an unsaturated end group(s), the prepared polymer having a narrow distribution of molecular weight.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: September 27, 1988
    Assignee: Kanegafuchi Chemical Industry Co., Ltd.
    Inventors: Shohei Inoue, Takuzo Aida, Michihide Honma, Katsuhiko Isayama
  • Patent number: 4757145
    Abstract: Compounds suitable for being used as lubricants, having general formula:(I) RO--(C.sub.3 F.sub.6 O).sub.m --(CFXO).sub.n --CFX--L,or(II) R"CFXO--(C.sub.3 F.sub.6 O).sub.x (CFXO).sub.y --(C.sub.2 F.sub.4 O).sub.z --CFX--L,whereR=--CF.sub.3, --C.sub.2 F.sub.5, --C.sub.3 F.sub.7X=F, --CF.sub.3R"=F, --CF.sub.3, --C.sub.2 F.sub.5m=an integer from 3 to 100n=a finite integer, or=zero, wherefore m+n ranges from 3 to 100, provided that, if n is finite, m/n ranges from 5 to 20 and R is preferably=CF.sub.3, if n=zero, R is preferably --C.sub.2 F.sub.5 or --C.sub.3 F.sub.7x=a finite integer, or=zeroy, z=finite integers, such that x+y+z ranges from 5 to 200, while (x+z)/y ranges from 5 to 0.5, provided that when x=zero, z/y ranges from 1 to 0.5 and y+z ranges from 5 to 200 n while X is is preferably F, and R"=LL=group Y-Z,where:Y=--CH.sub.2 O--, --CH.sub.2 --OCH.sub.2, --CF.sub.2, --CF.sub.
    Type: Grant
    Filed: March 26, 1987
    Date of Patent: July 12, 1988
    Assignee: Montedison S.p.A.
    Inventors: Gerardo Caporiccio, Ezio Strepparola, Mario A. Scarati
  • Patent number: 4754075
    Abstract: Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: June 28, 1988
    Assignee: Union Carbide Corporation
    Inventors: Robert J. Knopf, Louis F. Theiling, Jr.
  • Patent number: 4751012
    Abstract: Synthetic lubricants comprising 15 to 45 weight percent of an ester of a monohydric alcohol of 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms blended with 85 to 55 weight percent of one or more polyether polyols having a number average molecular weight from about 400 to 5000. The blends are compounded with antioxidants, corrosion inhibitors, and metal deactivators to produce a superior lubricant for reciprocating air compressors which gives a long life to the compressors.
    Type: Grant
    Filed: November 4, 1986
    Date of Patent: June 14, 1988
    Assignee: The Dow Chemical Company
    Inventors: Eldon L. Ward, Philip W. McGraw, Thomas J. Appleman
  • Patent number: 4739099
    Abstract: The invention provides a compound of formula (II): ##STR1## and the corresponding isomers and salts; in this formula, a equals 0 or 1; R.sub.1 and R.sub.2 represent, independently, H or a C.sub.1 -C.sub.4 alkyl group; R.sub.3 denotes --C.tbd.N; oxazolinyl; --CH.sub.2 OR.sub.4 (R.sub.4 =H, C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.6 mono- or poly-hydroxyalkyl, cyclopentyl or cyclohexyl, or --OR.sub.4 =tetrahydropyranyl); --COR.sub.5 (R.sub.5 =H, C.sub.1 -C.sub.4 alkyl, --NR'R" where R' and R" have various meanings); --OR.sub.6 (R.sub.6 =H, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.3 monohydroxyalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl with 2-5 OH groups), which has useful medicinal and cosmetic applications.
    Type: Grant
    Filed: September 30, 1985
    Date of Patent: April 19, 1988
    Assignee: L'Oreal
    Inventors: Gerard Lang, Serge Forestier, Alain Lagrange, Braham Shroot
  • Patent number: 4734535
    Abstract: Aliphatic chlorine compounds of the formulaX--R.sup.1 --Cl Iwhere R.sup.1 is alkylene which may be interrupted by one or more oxygen atoms and which may be substituted by halogen, alkyl or aryl, and X is hydrogen, chlorine or OR.sup.2, where R.sup.2 is alkyl, cycloalkyl, aryl or aralkyl, are prepared by decarboxylating chloroformic acid esters or diesters at elevated temperatures by decarboxylating in the presence of a quaternary ammonium or phosphonium salt as catalyst.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: March 29, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Greif, Knut Oppenlaender
  • Patent number: 4703114
    Abstract: Polyethers of the formula: ##STR1## wherein: R is the residue of a starting active hydrogen compound with removal of the active hydrogen atom, R.sub.1 is a C.sub.1 -C.sub.10 alkyl or aryl, R.sub.2 is a C.sub.1 -C.sub.10 alkyl, R.sub.3 is H, CH.sub.3, C.sub.2 H.sub.5 or phenyl, x is 5-100, y is 1-5, and z is 2-8 are less active than those having primary or secondary alcoholic function at terminals.
    Type: Grant
    Filed: August 9, 1985
    Date of Patent: October 27, 1987
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Shigeo Mori, Junichiro Matsumoto
  • Patent number: 4691048
    Abstract: The invention concerns a process for reducing carbonylation of an aldehyde wherein the aldehyde is used as hemiacetalester, the reaction being conducted in the presence of a catalyst consisting of a cobalt carbonyl complex.The hemiacetal-ester may be formed in situ by reacting an acetal with an anhydride of acid.The process preferentially yields alkylene-glycol mono-esters, free of esterified, for a ratio H.sub.2 /CO ranging from 1:1 to 3:1 and preferentially 2-alkoxy aldehydes, for a ratio H.sub.2 /CO ranging from 0.1:1 to 0.5:1.
    Type: Grant
    Filed: May 10, 1985
    Date of Patent: September 1, 1987
    Assignee: Institut Francais du Petrole
    Inventors: Francois Hugues, Dominique Commereuc, Yves Chauvin
  • Patent number: 4680358
    Abstract: A cationic ring-opening polymerization of a cyclic ether ("CE") in conjunction with an unsaturated alcohol (propagator) having a styryl or substituted styryl group, produces a polyether macromer having the styryl group near one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the CE to the OH group which is the propagating species. The CE is an alkylene oxide or an aliphatic or aromatic glycidyl ether; the propagator is a primary or secondary alcohol. The catalyst is a Friedel-Crafts acid, strong protic organic or inorganic acid, oxonium salt, or the like. Plural cyclic ethers may be (a) sequentially polymerized to form macromer block copolyethers, or, (b) polymerized randomly to form macromer copolyether copolymers. The cationically ring-opened macromer formed always contains a trace of a cyclic oligomer of the CE.
    Type: Grant
    Filed: November 8, 1985
    Date of Patent: July 14, 1987
    Assignee: The B F Goodrich Company
    Inventor: Simon H. Yu
  • Patent number: 4665239
    Abstract: Polyethers having molecular weights of about 1000 to about 75,000 modified with alpha-olefin oxides having about 12 to about 18 carbon atoms exhibit increased thickening efficiency in aqueous systems. About 1 to about 20 percent by weight based upon the weight of the polyether is required, the proportion of alpha-olefin oxide modifier varying inversely with the molecular weight of the polyether. Modified polyethers, processes for the preparation of thickened aqueous systems, and thickened aqueous compositions are disclosed. The modified polyether thickening agents of the invention are particularly useful for thickening water or water-glycol mixtures which are useful as hydraulic fluids.
    Type: Grant
    Filed: May 31, 1984
    Date of Patent: May 12, 1987
    Assignee: BASF Corporation
    Inventors: Edward J. Panek, Pauls Davis
  • Patent number: 4648984
    Abstract: 2-benzyl-1-alkanol polyglycol ethers having the formula: ##STR1## in which R.sup.1 is a C.sub.6 to C.sub.22 alkyl group; R.sup.2 is a C.sub.2 -C.sub.6 alkylene group; and n is an integer from 1 to about 100.The products are produced by heating a mixture of a ratio of an alcohol having the formula:R.sup.1 --CH.sub.2 --CH.sub.2 OHwherein the symbol R.sup.1 has the same meaning as above with a ratio of from about 1 mole to about 10 moles, preferably 1 to 3 moles, of benzyl alcohol to a temperature of from about 180.degree. C. to 250.degree. C. in the presence of an alkali metal compound, and optionally a hydrogenation catalyst; separating the excess benzyl alcohol from the mixture and alkoxylating the alcohol thus obtained.The polyglycol ether are used as wetting agents, dispersants, emulsifiers and detergents.
    Type: Grant
    Filed: May 29, 1986
    Date of Patent: March 10, 1987
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst-Jurgen Krause, Andreas Syldatk, Eric Sung
  • Patent number: 4647413
    Abstract: Perfluoropolyether oligomers or block polymers, having a backbone with one or a plurality of perfluoropolyether segments each consisting essentially of (1) at least one perfluoroisopropyleneoxy unit, (2) a bis(perfluoromethyleneoxy-terminated) unit, and (3) a perfluoroethylidene unit terminating each segment, the backbone of the perfluoropolyether being terminated with COF and/or a functional or nonfunctional derivative thereof, said perfluoropolyethers being made by reacting a perfluoroaliphatic diacid fluoride with hexafluoropropylene epoxide to produce an acid fluoride-terminated perfluoropolyether adduct or oligomer which then can be photopolymerized to yield an acid fluoride-terminated perfluoropolyether block polymer. These oligomers and block polymers are useful as high temperature lubricants, hydraulic fluids, gaskets, adhesives and coatings as well as co-reactants wtih urethane in forming propellant binders.
    Type: Grant
    Filed: January 20, 1984
    Date of Patent: March 3, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Patricia M. Savu
  • Patent number: 4605784
    Abstract: Disclosed is a process for the preparation of ether-containing chlorides by reacting an ether-alcohol, ether-glycol or ether-polyglycol with a chlorinating agent such as thionyl chloride in the presence of a catalytic amount of a quaternary ammonium salt, the reaction being conducted at a temperature of about 25.degree. C. to about 90.degree. C.
    Type: Grant
    Filed: July 18, 1985
    Date of Patent: August 12, 1986
    Assignee: Eastman Kodak Company
    Inventors: Robert J. I. Eubanks, James G. Pacifici
  • Patent number: 4597906
    Abstract: Compounds of the formulaA[(Y--O).sub.x --Y--Z].sub.min which A is the radical of an oxaryl-modified (modified with an aryl group containing a hydroxyl group) fatty alcohol, i.e., the radical of an arylated fatty alcohol, or is the radical of an oxaryl-modified (again, modified with an aryl group containing a hydroxyl group) fatty acid or esterification product thereof, i.e., the radical of an arylated fatty acid or esterification product thereof, Y denotes identical or different groups of the formula--CH.sub.2 --CH.sub.2 -- or --CH.sub.2 --CH(CH.sub.3)--,Z denotes identical or different radicals of the formulae --OH, --O--CO--CH.dbd.CH--COOM and --O--CO--CH.sub.2 --CH(SO.sub.3 M)--COOM, in whichM is a cation,x is an integer of from 1 to 150 andm is a number of from 1 to 7,are suitable as interfacially active agents, in particular as dispersing agents, wetting agents, emulsifiers and dyeing auxiliaries.
    Type: Grant
    Filed: December 27, 1983
    Date of Patent: July 1, 1986
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Heinz Uhrig, Klaus Ehl, Reinhold Deubel
  • Patent number: 4593142
    Abstract: Catalysts comprising mixtures of HF and metal alkoxides and mixed metal alkoxides produce a sharply peaked alkoxylation distribution during the alkoxylation of organic materials.
    Type: Grant
    Filed: February 21, 1984
    Date of Patent: June 3, 1986
    Assignee: Vista Chemical Company
    Inventor: Kang Yang
  • Patent number: 4587365
    Abstract: The instant invention relates to a process which comprises modifying a conventional polyoxyalkylene polyol by capping all the hydroxyl groups of the polyol with benzyl, aryl, substituted benzyl, substituted aryl or alkyl groups having 1 to 4 carbon atoms. This process comprises reacting the conventional polyoxyalkylene polyol with an alkali metal methoxide followed by reaction with an alkali metal hydride which in turn is followed by reaction with an organic halide.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: May 6, 1986
    Assignee: BASF Corporation
    Inventor: Michael J. Anchor
  • Patent number: 4585592
    Abstract: In polyoxybutylene polyoxyalkylene glycols obtained by copolymerization of tetrahydrofuran with a 1,2-alkylene oxide in the presence of a compound containing reactive hydrogen and under the catalytic action of a bleaching earth, the content of oligomeric cyclic ethers is reduced by distillation under reduced pressure at above 200.degree. C. after first treating the copolymer with oxygen or an oxygen-containing gas (air) at a temperature of from 20.degree. to 110.degree. C.
    Type: Grant
    Filed: February 28, 1985
    Date of Patent: April 29, 1986
    Assignee: BASF Aktiengesellschaft
    Inventor: Herbert Mueller
  • Patent number: 4568774
    Abstract: Catalysts producing a sharply peaked alkoxylation distribution during the alkoxylation of organic materials comprise mixtures of BF.sub.3 and metal alkyls or metal alkoxides, SiF.sub.4 and metal alkyls or metal alkoxides, or mixtures of these catalysts.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: February 4, 1986
    Assignee: Vista Chemical Company
    Inventor: Kang Yang
  • Patent number: 4504685
    Abstract: Hydroxyl compounds are oxyalkylated by contacting them with an alkylene oxide, such as ethylene oxide or propylene oxide, in the presence of a perfluorocarbon polymer containing pendant sulfonic acid groups.
    Type: Grant
    Filed: August 19, 1980
    Date of Patent: March 12, 1985
    Assignee: Varen Technology
    Inventor: Ronald J. Vaughan
  • Patent number: 4468527
    Abstract: A fluoroaliphatic radical- and aliphatic chlorine-containing alcohol containing more than 25 weight percent carbon-bonded fluorine in the form of fluoroaliphatic radicals and at least one aliphatic chlorine, an ester of said alcohol and a carboxycylic acid being useful in the treatment of carpet.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: August 28, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Kalyanji U. Patel
  • Patent number: 4431845
    Abstract: A method for the preparation of hydroxyl-terminated poly(haloalkylene ethers) is disclosed wherein a catalyst system comprising a fluorinated acid and a polyvalent tin compound is utilized.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: February 14, 1984
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Chung I. Young, Loren L. Barber, Jr.
  • Patent number: RE33658
    Abstract: Synthetic lubricants comprising 15 to 45 weight percent of an ester of a monohydric alcohol of 4 to 18 carbon atoms with one or more aromatic or alkane dicarboxylic acids having 4 to 18 carbon atoms blended with 85 to 55 weight percent of one or more polyether polyols having a number average molecular weight from about 400 to 5000. The blends are compounded with antioxidants, corrosion inhibitors, and metal deactivators to produce a superior lubricant for reciprocating air compressors which gives a long life to the compressors.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: August 6, 1991
    Assignee: The Dow Chemical Company
    Inventors: Eldon L. Ward, Philip W. McGraw, Thomas J. Appleman