Mineral Oil (petroleum) Fraction Patents (Class 585/13)
  • Patent number: 7592495
    Abstract: Compositions including blends of Group II and/or Group III base oils and alkkylated fused and/or polyfused aromatic compositions, such as alkylated naphthalenes are provided. The use of such compositions, which exhibit excellent additive solvency, thermo-oxidative stability, hydrolytic stability, and seal swell characteristics, as lubricants is disclosed.
    Type: Grant
    Filed: July 3, 2001
    Date of Patent: September 22, 2009
    Assignee: King Industries
    Inventors: Edward T. Hessell, Richard A. Abramshe, Lawrence V. Gallacher
  • Patent number: 7540952
    Abstract: The present invention relates to a thermo catalytic process to produce diesel oil from vegetable oils, in refineries which have two or more Catalytic Cracking (FCC) reactors. At least one reactor processes heavy petroleum or residue in conventional operation conditions while at least one reactor processes vegetable oils in proper operation conditions to produce diesel oil. This process employs the same catalyst employed in the FCC process, which processes conventional feedstocks simultaneously. This process transforms high heat content raw materials into fuel hydrocarbons. It may improve efficiency for the obtainment of highly pure products and may not yield glycerin, one by-product of the transesterification process. The diesel oil produced by said process may have superior qualities and/or a cetane number higher than 40. Once cracking conditions occur at lower temperatures, it may form a less oxidized product, which is consequently purer than those obtained by existent technology.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: June 2, 2009
    Assignee: Petroleo Brasileiro S.A. - Petrobras
    Inventors: Andrea De Rezende Pinho, Mauro Silva, Amilcar Pereira Da Silva Neto, Júlio Amilcar Ramos Cabral
  • Publication number: 20090093658
    Abstract: Process to blend a mineral derived hydrocarbon product and a Fischer-Tropsch derived hydrocarbon product by providing in a storage vessel of a marine vessel a quantity of mineral derived hydrocarbon product and Fischer-Tropsch derived hydrocarbon product such that initially the mineral derived hydrocarbon product is located substantially above the Fischer-Tropsch derived hydrocarbon product, transporting the combined products in the marine vessel from one location to another location, also referred to as the destination, and obtaining a blended product at arrival of the marine vessel at its destination.
    Type: Application
    Filed: April 11, 2006
    Publication date: April 9, 2009
    Inventors: Claire Ansell, Richard Hugh Clark, Richard John Heins
  • Patent number: 7494584
    Abstract: An energy efficient process scheme for a highly exothermic reaction-distillation system in which the reactor is external to the distillation column and the feed to the reactor is a mixture of at least one liquid product stream from the distillation column with or without other liquid/vapor reactants. The reactor is operated under adiabatic and boiling point conditions and at a pressure that results in vaporizing a portion of the liquid flow through the reactor due to the heat of reaction. Under these conditions, reaction temperature is controlled by reactor pressure. The pressure (and hence the temperature) is maintained at a sufficiently high level such that the reactor effluent can be efficiently used to provide reboil heat for the distillation column.
    Type: Grant
    Filed: August 27, 2007
    Date of Patent: February 24, 2009
    Assignee: Catalytic Distillation Technologies
    Inventors: Arvids Judzis, Abraham P. Gelbein, John R. Adams, Christopher C. Boyer
  • Patent number: 7404888
    Abstract: A process for reducing the metal corrosion of a hydrocarbonaceous liquid which causes corrosion as measured by NACE Standard TM0172-2001, said process comprising blending with the hydrocarbonaceous liquid at least 0.1 weight percent of an acidic Fischer-Tropsch product in sufficient proportion to produce a hydrocarbonaceous blend displaying reduced metal corrosion as measured by NACE Standard TM0172-2001 when compared to the hydrocarbonaceous liquid and a hydrocarbonaceous blend prepared by the process.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: July 29, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis J. O'Rear, Greg Hemighaus, Gunther H. Dieckmann
  • Patent number: 7348462
    Abstract: A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: March 25, 2008
    Assignee: Shell Oil Company
    Inventors: Laurent Alain Michel Fenouil, Brendan Dermot Murray, Paul Marie Ayoub
  • Patent number: 7320745
    Abstract: An energy efficient process scheme for a highly exothermic reaction-distillation system in which the reactor is external to the distillation column and the feed to the reactor is a mixture of at least one liquid product stream from the distillation column with or without other liquid/vapor reactants. The reactor is operated under adiabatic and boiling point conditions and at a pressure that results in vaporizing a portion of the liquid flow through the reactor due to the heat of reaction. Under these conditions, reaction temperature is controlled by reactor pressure. The pressure (and hence the temperature) is maintained at a sufficiently high level such that the reactor effluent can be efficiently used to provide reboil heat for the distillation column.
    Type: Grant
    Filed: January 19, 2005
    Date of Patent: January 22, 2008
    Assignee: Catalytic Distillation Technologies
    Inventors: Arvids Judzis, Jr., Abraham P. Gelbein, John R. Adams, Christopher C. Boyer
  • Patent number: 7241375
    Abstract: A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI?0.5(CH2>4)<15; and (b) BI+0.85(CH2>4)<45; as measured over the heavy hydrocarbon composition as a whole.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: July 10, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
  • Patent number: 7083713
    Abstract: A composition of lubricating base oil having a weight percent of all molecules with at least one aromatic function less than 0.30, a weight percent of all molecules with at least one cycloparaffin function greater than 10, and a ratio of weight percent of molecules with monocycloparaffins to weight percent of molecules with multicycloparaffins greater than 15.
    Type: Grant
    Filed: December 23, 2003
    Date of Patent: August 1, 2006
    Assignee: Chevron U.S.A. Inc.
    Inventors: Susan M. Abernathy, David C. Kramer, John M. Rosenbaum, Stephen J. Miller, Russell R. Krug
  • Patent number: 7067049
    Abstract: The present invention relates to formulated lubricant oils derived from a highly paraffinic basestock. The lubricating oils of the present invention achieve the extremely stringent viscosity requirements of SAE “0W” crossgraded engine oils and demonstrate an excellent combination of low-temperature performance and biodegradability not achievable by other formulations derived from other classes of basestocks.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: June 27, 2006
    Assignee: Exxonmobil Oil Corporation
    Inventors: David J. Baillargeon, Thomas R. Forbus, Jr., Kenneth R. Graziani, Gretchen R. Hall, Nancy M. Page, Richard F. Socha
  • Patent number: 6992049
    Abstract: The present invention provides a viscosity index improving lubricant additive which comprises an olefinic oligomer of about 2,000 to about 20,000 number average molecular weight having a viscosity of 75 to about 3,000 cSt at 100° C. and a hydrocarbyl aromatic which contains at least about 5% of its weight from aromatic moieties having a viscosity of about 3 to about 50 cSt at 100° C. where the weight ratio of hydrocarbyl aromatic component to olefin oligomer is from about 1:2 to about 50:1. In another aspect, the invention provides for a lubricating oil composition comprising a base oil and the instant viscosity index improving additive.
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: January 31, 2006
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Douglas E. Deckman, William L. Maxwell, William H. Buck, Mark D. Winemiller, David J. Baillargeon
  • Patent number: 6884531
    Abstract: Naphtha-based fuels which have less than 1 ppm of sulfur and in excess of 15%, by weight, of hydrogen and an aromatics content of less than 1%, by weight, have been found to be useful as a fuel source for vehicular fuel cells.
    Type: Grant
    Filed: May 20, 2002
    Date of Patent: April 26, 2005
    Assignee: Saudi Arabian Oil Company
    Inventors: Bashir Osama Dabbousi, Anwar Hasan Al-Khawajah, Gary Dean Martinie
  • Patent number: 6878263
    Abstract: Disclosed is a rubber process oil in which the content of polycyclic aromatics (PCAs) as determined by the IP 346 method is less than 3% by mass and which is rich in aromatic hydrocarbons, and a method for producing the same. The aniline point of the rubber process oil is 80° C. or less, and the % CA value as determined by ring analysis according to the Kurtz method is from 20 to 50%. The rubber process oil is produced by using extraction of lube oil fraction with a solvent having a selective affinity for aromatics. The extraction conditions are determined so that the extraction yield is regulated to a predetermined requirement defined by the PCAs content of the lube oil fraction. Alternatively, the extract is cooled to further separate into the extract and the raffinate, and the second raffinate is used for the rubber process oil.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: April 12, 2005
    Assignee: Japan Energy Corporation
    Inventors: Takashi Kaimai, Kazumitsu Fujihara, Yoshiyuki Morishima
  • Patent number: 6872693
    Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.
    Type: Grant
    Filed: May 24, 2000
    Date of Patent: March 29, 2005
    Assignee: The Lubrizol Corporation
    Inventor: Robert W. Cain
  • Patent number: 6846778
    Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.). The branching index BI and the branching proximity CH2>4 of the isoparaffinic hydrocarbon molecules, are such that: BI?0.5(CH2>4)<15; and??(a) BI+0.85(CH2>4)<45;??(b) as measured over the hydrocarbon composition as a whole.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: January 25, 2005
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
  • Patent number: 6833484
    Abstract: The present invention relates blended hydrocarbonaceous products comprising Fischer Tropsch derived products that resist oxidation and to methods of inhibiting oxidation in Fischer Tropsch products. The present invention also relates to Fischer Tropsch products containing an effective amount of a petroleum-derived hydrocarbonaceous product such that the Fischer Tropsch product resists oxidation.
    Type: Grant
    Filed: June 15, 2001
    Date of Patent: December 21, 2004
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dennis J. O'Rear
  • Patent number: 6803492
    Abstract: The invention relates to an additive for improving the cold-flow properties of crude and distillate oils, where the additive is obtainable by extraction of crude oil with supercritical gas.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: October 12, 2004
    Assignee: Clariant International Ltd.
    Inventors: Michael Feustel, Hans-Jörg Oschmann, Utha Kentschke
  • Publication number: 20040167368
    Abstract: A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.
    Type: Application
    Filed: February 27, 2004
    Publication date: August 26, 2004
    Inventors: Laurent Alain Michel Fenouil, Brendan Dermot Murray, Paul Marie Ayoub
  • Publication number: 20040167369
    Abstract: A process for preparing branched alkyl aromatic hydrocarbons, which process comprises contacting branched olefins with an aromatic hydrocarbon under alkylating conditions, which branched olefins have been obtained by a process which comprises dehydrogenating an isoparaffinic composition over a suitable catalyst which isoparaffinic composition has been obtained by hydrocracking and hydroisomerization of a paraffinic wax and which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being at least 0.
    Type: Application
    Filed: February 27, 2004
    Publication date: August 26, 2004
    Inventors: Laurent Alain Michel Fenouil, Brendan Dermot Murray, Paul Marie Ayoub
  • Publication number: 20040110997
    Abstract: A method for marking a liquid petroleum hydrocarbon; said method comprising adding to said liquid petroleum hydrocarbon at least one dye having an unsaturated cyclic nucleus comprising at least nine ring atoms, and having at least one (CN)2C═ substituent and at least one Ar—N═ substituent; wherein Ar is a substituted aryl group.
    Type: Application
    Filed: November 12, 2003
    Publication date: June 10, 2004
    Inventor: Kim Sang Ho
  • Publication number: 20040094453
    Abstract: A process for producing a lubricating base oil blend which comprises (a) recovering a Fischer-Tropsch derived distillate fraction characterized by a kinematic viscosity of about 2 cSt or greater but less than 3 cSt at 100 degrees C.; and (b) blending the Fischer-Tropsch derived distillate fraction with a petroleum derived base oil selected from the group consisting of a Group I base oil, a Group II base oil, a Group III base oil, and a mixture of two or more of any of the foregoing conventional base oils in the proper proportion to produce a lubricating base oil blend characterized as having a viscosity of about 3 or greater; also the base oil blends, finished lubricants, and their use in internal combustion engines.
    Type: Application
    Filed: November 20, 2002
    Publication date: May 20, 2004
    Inventors: Brent K. Lok, David Kramer, John M. Rosenbaum, Joseph Pudlak
  • Patent number: 6713438
    Abstract: High performance engine oils and other liquid lubricants comprise a liquid lubricant basestock of low viscosity from 1.5 to 12 cSt (100C) with two dissolved polymer components of differing molecular weights. The basestock is preferably a single PAO or blend of PAOs with a co-basestock component which is preferably an ester or an alkylated aromatic of comparable viscosity. The lower molecular weight polymer is highly viscoelastic in character and is preferably an HVI-PAO; this component in the lubricant which provides unexpectedly high film thickness and unexpectedly good wear protection under conditions where the second, higher molecular weight polymer may lose some or all of its thickening power. The use of the highly viscoelastic low molecular weight polymer in combination with the higher molecular weight thickener enables the production of very widely cross-graded engine oils, especially oils with a low temperature grading of 0W or better.
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: March 30, 2004
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Raymond J. Bergstra, Andrew Jackson, William L. Maxwell, G. James Johnston, Robert A. Pache
  • Patent number: 6676827
    Abstract: A method for producing a lube basestock from a waxy feed is disclosed in which a feed containing to 50 wt % or more of wax is hydrotreated and stripped to lower the nitrogen and sulfur content of the feed. The feed is then hydroisomerized under conditions to 370° C. hydrocatalytically dewaxed with a catalyst comprising a mixture of a catalytically active metal on a zeolite dewaxing catalyst and an amorphous catalyst, or alternatively is solvent dewaxed and then hydrocatalytically dewaxed with the just described catalyst.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: January 13, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: William John Murphy, Ian Alfred Cody, Bernard George Silbernagel
  • Publication number: 20030236177
    Abstract: A fluid blend suitable for use as a lube basestock comprises two major components: (A) a copolymer made from ethylene with one or more alpha olefins, the copolymer (i) containing not more than 50 wt % ethylene; (ii) having a number average molecular weight of from 400 to 10,000; and (iii) a molecular weight distribution<3; and (B) a polyalphaolefin fluid or a hydroprocessed oil having a VI greater than 80.
    Type: Application
    Filed: February 14, 2003
    Publication date: December 25, 2003
    Inventors: Margaret May-Som Wu, Jon Edmond Randolph Stanat, Kyle D. Lawrence, Richard T. Spissell
  • Publication number: 20030226785
    Abstract: A method for producing a lube basestock from a waxy feed is disclosed in which a feed containing to 50 wt % or more of wax is hydrotreated and stripped to lower the nitrogen and sulfur content of the feed. The feed is then hydroisomerized under conditions to 370° C. hydrocatalytically dewaxed with a catalyst comprising a mixture of a catalytically active metal on a zeolite dewaxing catalyst and an amorphous catalyst, or alternatively is solvent dewaxed and then hydrocatalytically dewaxed with the just described catalyst.
    Type: Application
    Filed: January 15, 2003
    Publication date: December 11, 2003
    Inventors: William John Murphy, Ian Alfred Cody, Bernard George Silbernagel
  • Patent number: 6627779
    Abstract: The invention provides methods for preparing a blended lube base oils comprising at least one highly paraffinic Fischer Tropsch lube base stocks and at least one base stock composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof. The use of base stocks composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof improves the yield of lube base oils from Fischer Tropsch facilities, as well as provides moderate improvements in physical properties including additive solubility. The invention provides processes for obtaining such blended lube base oils using the products of Fischer Tropsch processes.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: September 30, 2003
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dennis J. O'Rear
  • Patent number: 6599864
    Abstract: The invention concerns a novel hydrocarbon base oil for lubricants, having a viscosity index not less than 130, comprising mainly long isoparaffinic hydrocarbon chains, branched over several carbon atoms. The invention is characterized in that said chains comprise a number of carbon atoms greater than 25 and have a ratio of the number of substituents consisting of at least two carbon atoms over the number of methyl-type substituents, not less than 0.9.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: July 29, 2003
    Assignee: Total Raffinage Distribution S.A.
    Inventor: Olivier Bertomeu
  • Patent number: 6528694
    Abstract: In order to provide an improvement in the mechanical shear force resistance of the admixture composition, comprising an oil solution of polyisobutylene, containing polyisobutylene having a viscosity average molecular weight in a range of 350,000 to 2,100,000 at a concentration in the range of 10 weight % to 90 weight % and an oil solution of star divinylbenzene-isoprene copolymer hydride being a viscosity index improver, containing star divinylbenzene-isoprene copolymer hydride having a viscosity average molecular weight in a range of 200,000 to 800,000 at a concentration in the range from 3 weight % to 90 weight %, and said oil solution of polyisobutylene mixes with a lubricant at a concentration in the range from 10 weight % to 90 weight % and said oil solution of star divinylbenzene-isoprene copolymer hydride mixes with the lubricant at a concentration in the range of 3 weight % to 90 weight %.
    Type: Grant
    Filed: May 9, 2002
    Date of Patent: March 4, 2003
    Assignee: Japan Pacific Enterprise, Inc.
    Inventor: Shunsuke Chiga
  • Publication number: 20030000866
    Abstract: This invention relates to mineral oil based gear oils and transmission fluids which comprise a major amount of a mineral oil having an iodine number of less than 9 and where at least 55% of the saturates are aliphatic, and gear oil or transmission fluid additives. In one embodiment, the invention relates to a gear oil or transmission fluid composition comprising a major amount of lubricant basestock and at least one functional additive wherein a major amount of the lubricant basestock comprises a mineral oil having an iodine number of less than 9 and comprising at least 45% by weight of aliphatic saturates. These gear oils and transmission fluids have good viscosity and oxidation properties.
    Type: Application
    Filed: May 24, 2000
    Publication date: January 2, 2003
    Inventor: Robert W. Cain
  • Patent number: 6426322
    Abstract: A functional fluid base oil is described comprising a mixture of (1) one or more naphthenic base stocks, and (2) one or more conventional solvent neutral base stocks and (3) one or more hydrocracked base stocks. The functional fluid base oil can be additized by the addition of one or more performance additives. The fluid is especially usefull as a power steering fluid base oil.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: July 30, 2002
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Albert Gordon Alexander
  • Patent number: 6410810
    Abstract: A mixture of bis- and tris(fluoroaryl)borane compounds expressed by General Formula (1) below is handled in the form of a slurry made with a hydrocarbon solvent: where each of R1, R2, R3, R4 and R5 independently represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group provided that at least one of R1-R5 represents a fluorine atom, X represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, and wherein n represents 2 for the bis(fluoroaryl)borane compounds and 3 for the tris(fluoroaryl)borane compounds. Then, a hydrocarbon solution of the (fluoroaryl)borane compounds having a concentration of the tris(fluoroaryl)borane compounds in a range between 1 wt % and 1 wt % is prepared by dissolving the slurry into a hydrocarbon solvent in a virtually air-tight vessel.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: June 25, 2002
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hitoshi Mitsui, Tsunemasa Ueno, Ikuyo Ikeno, Naoko Hirano
  • Publication number: 20010049343
    Abstract: A functional fluid base oil is described comprising a mixture of (1) one or more naphthenic base stocks, and (2) one or more conventional solvent neutral base stocks and (3) one or more hydrocracked base stocks. The functional fluid base oil can be additized by the addition of one or more performance additives. The fluid is especially useful as a power steering fluid base oil.
    Type: Application
    Filed: February 7, 2001
    Publication date: December 6, 2001
    Inventor: Albert Gordon Alexander
  • Patent number: 6281173
    Abstract: A two-stroke motorcycle lubricant comprising a base oil having a viscosity at 100° C. of less than 8 cSt and a pour point below −30° C., preferably below −39° C. The two-stroke motorcycle lubricant further comprises a detergent system based on an ashless, oil-soluble amine. The two-stroke motorcycle lubricant exhibits high levels of cleanliness and low levels of exhaust smoke, whilst maintaining high load carrying capacity. The two-stroke motorcycle lubricant may be dyed.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: August 28, 2001
    Assignee: Castrol Limited
    Inventors: Yas Tanaka, Paul Fritz-Johnson, Howard Silver, David James Atkinson
  • Patent number: 6277269
    Abstract: A bitumen is rendered pipelineable by partially hydroconverting the bitumen and then adding sufficient diluent to the partially hydroconverted bitumen to provide a mixture having an API gravity at 15° C. of at least 19° and a viscosity at 40° C. in the range of about 35 to about 60 cP.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: August 21, 2001
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ronald Damian Myers, John Brenton MacLeod, Mainak Ghosh, Tapan Chakrabarty
  • Patent number: 6264826
    Abstract: A process is provided for preparing high quality Group II and Group III lubricating base oils from a sulfur containing feedstock using mild hydrotreating followed by isomerization/dewaxing followed by hydrogenation over a sulfur resistant hydrogenation catalyst.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: July 24, 2001
    Assignee: Chevron U.S.A Inc.
    Inventors: Jirong Xiao, Phil Winslow, James N. Ziemer
  • Patent number: 6245719
    Abstract: The present invention is a lubricant oil composition comprising a base oil as the major component which contains aromatic compounds at 1 wt % or less and paraffin and monocyclic naphthene compounds at 50 wt % or more as total content, and has a kinematic viscosity of 2 to 50 mm2/s at 100° C. and evaporated quantity of 16 wt % or less by the NOACK volatility test.
    Type: Grant
    Filed: August 6, 1999
    Date of Patent: June 12, 2001
    Assignee: Tonen Corporation
    Inventor: Atsuhisa Kobori
  • Patent number: 6222081
    Abstract: Ethylene copolymers with alpha-olefins utilizable as additives to increase the properties of middle distillates at low temperatures, obtainable by polymerization in the presence of catalysts comprising the reaction product between: 1) a bis-cyclopentadienyl derivative having the general formula: (Cp1Cp2)—M—(L2L3) containing groups with oxygen bound to the transition metal, wherein M is a metal from the IIIb group to the IIb group or of the lanthanides series of the periodic table of the elements; 2) a co-catalyst chosen from alumoxanes or boranes.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: April 24, 2001
    Assignee: Societa' Italiana Additivi Per Carburanti S.r.l.
    Inventors: Jeremy Burton, Paolo Falchi
  • Patent number: 6093861
    Abstract: The specification describes lubricating oil compositions containing an additive comprising normal paraffin and/or iso-paraffins and/or naphthenes each of which have from 10 to 20 carbon atoms. Compositions containing from 0.1 percent to 2 percent by volume are disclosed. The compositions are effective in reducing varnishing, sludging chemical by-products and glazing in an engine. The compositions are also useful in automatic transmissions fluid, gear oils and greases.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: July 25, 2000
    Inventor: Pieter Jan Dirk Muntz
  • Patent number: 6090989
    Abstract: A liquid hydrocarbon composition, containing paraffinic hydrocarbon components in which the extent of branching, as measured by the percentage of methyl hydrogens (BI), and the proximity of branching, as measured by the percentage of recurring methylene carbons which are four or more carbons removed from an end group or branch (CH.sub.2 >4), are such that:(a) BI-0.5(CH.sub.2 >4)>15; and(b) BI+0.85(CH.sub.2 >4)<45as measured over said liquid hydrocarbon composition as a whole.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: July 18, 2000
    Assignee: Mobil Oil Corporation
    Inventors: Jeffrey C. Trewella, Thomas R. Forbus, Jr., Zhaozhong Jiang, Randall D. Partridge, Suzanne Elaine Schramm
  • Patent number: 6039771
    Abstract: An energy fortified diesel fuel is provided containing a hydrocarbon additive wherein greater than 50% vaporizes at or above about 650.degree. F. and diesel fuel of which about 90% of the diesel fuel vaporizes at or below about 640.degree. F. or about 95% of the diesel fuel vaporizes at or below about 698.degree. F. This energy fortified diesel fuel is made by distilling a heavy hydrocarbon fraction such as slurry oil or heavy cycle oil obtained from an FCC unit or a heavy hydrocarbon fraction obtained from a steam cracker unit at a temperature of between about 500 and 750.degree. F. and at a pressure of between about 1 mm Hg and 10 psig to remove contaminants, removing distillate from this distillation, and mixing the distillate with diesel fuel, wherein about 90% of the diesel fuel vaporizes at or below about 640.degree. F. or about 95% of the diesel fuel vaporizes at or below about 698.degree. F., to form an energy fortified diesel fuel.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: March 21, 2000
    Assignee: KRC-GP, Inc.
    Inventors: Charles W. Selvidge, Dennis A. Vauk
  • Patent number: 6034042
    Abstract: The present invention includes star polymers which can be used as viscosity index improvers in oil compositions formulated for high performance engines. The star polymers have tetrablock copolymer arms of hydrogenated polyisoprene-polybutadiene-polyisoprene with a block of polystyrene and which provide excellent low temperature performance in lubricating oils, exhibit good thickening efficiency, and are finishable as polymer crumb.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: March 7, 2000
    Assignee: Shell Oil Company
    Inventor: Robert Barnett Rhodes
  • Patent number: 6034040
    Abstract: Lubricating oil compositions having excellent thermal and oxidative stability, wear control, copper corrosion control and compatibility with seal materials comprising a mineral oil having a) a Viscosity Index of greater than 110 and an aniline point of greater than 110.degree. C. and/or b) a linear+single ring paraffin content of greater than 68 wt %, and at least one polymer selected from olefin (co) polymer(s), polyalkyl (meth) acrylate(s) and mixtures thereof. The lubricating oil compositions are particularly useful as manual transmission and axle lubricants.
    Type: Grant
    Filed: August 3, 1998
    Date of Patent: March 7, 2000
    Assignee: Ethyl Corporation
    Inventors: Nubar Ozbalik, Sanjay Srinivasan, Vincent James Gatto
  • Patent number: 5906727
    Abstract: Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt.% to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: May 25, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Robert Jay Wittenbrink, Steven Earl Silverberg, Daniel Francis Ryan
  • Patent number: 5858935
    Abstract: Power transmitting fluids, especially automatic transmission fluids, possess improved properties such as antiwear, durability, antioxidation, and shift-time performance by incorporation of high viscosity polyalphaolefins.
    Type: Grant
    Filed: December 12, 1996
    Date of Patent: January 12, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventors: Raymond F. Watts, Manoj Tandon
  • Patent number: 5858932
    Abstract: Lubricating oil composition for internal combustion engines includes a base oil containing (A) 30-98% by weight of a mineral oil having a kinematic viscosity of 2-30 mm.sup.2 /sec at 100.degree. C. and a viscosity index of not less than 100 and (B) 2-70% by weight of poly-.alpha.-olefin, and zinc dithiophosphate in an amount corresponding, as reduced to the amount of P (phosphorus), to 0.02-0.15 parts by weight with respect to 100 parts by weight of the base oil. The composition of the present invention is advantageously used as lubricating oil composition for internal combustion engines, exerting excellent effects in terms of the consumption of the oil composition, fuel consumption rate, and sealing characteristics of rubber.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: January 12, 1999
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Masashi Dasai, Masahiko Kido, Hiroshi Fujita
  • Patent number: 5833839
    Abstract: Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt. % to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: November 10, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Robert Jay Wittenbrink, Steven Earl Silverberg, Daniel Francis Ryan
  • Patent number: 5767331
    Abstract: A copolymer of ethylene and an alpha-olefin having an ethylene content of from 30 to 90 mole %, a number average molecular weight of from 300 to 30,000 and a molecular weight distribution defined by a Q value (the ratio of the weight average molecular weight to the number average molecular weight) of not more than 3 and a Z value (the ratio of the maximum value of the molecular weight to the minimum value of the molecular weight when the molecular weight is measured by gel permeation chromatography) of from 15 to 200. The said copolymer can be produced by a process comprising copolymerizing ethylene with an alpha-olefin in the liquid phase in the presence of a polymerization catalyst composed of a combination of a soluble vanadium compound and an organoaluminum compound in the co-presence of hydrogen, characterized in that(a) the copolymerization is carried out in a continuous manner,(b) the concentration of the vanadium compound in the polymerization system is maintained at 0.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: June 16, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidekuni Oda, Tatuo Kinoshita, Akiyoshi Shimizu
  • Patent number: 5747596
    Abstract: Gel-free dispersant additives for lubricating and fuel oil compositions comprise at least one adduct of (A) .alpha.-olefin homopolymer or interpolymer of 700 to 10,000 number average molecular weight, free radically grafted with an average of from about 0.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: May 5, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert Dean Lundberg, David John Lohse
  • Patent number: 5714656
    Abstract: Composition of lubricating oil which comprises: a) a greater portion of synthetic lubricating component or a mixture of synthetic lubricating component and a mineral base for lubricating oils, the synthetic lubricating component being prepared by the oligomerization and subsequent hydrogenation and the possible removal of low-boiling by-products, of a composition of olefins basically consisting of:1) a mixture of n-olefins having a content of olefins from C.sub.14 to C.sub.17, preferably from C.sub.15 to C.sub.16, of at least 80%, preferably greater than 85%,2) alpha olefins from C.sub.15 to C.sub.17, preferably basically C.sub.16, the content of the alpha olefin (2) being from 5 to 25% by weight, preferably from 10 to 20%, with respect to the sum of (1)+(2).
    Type: Grant
    Filed: November 5, 1996
    Date of Patent: February 3, 1998
    Assignee: Condea Augusta S.P.A.
    Inventors: Massimo Ciali, Rosanna Ontano, Pierino Radici, Armando Marcotullio, Paolo D'Antona
  • Patent number: 5578237
    Abstract: Gel-free dispersant additives for lubricating and fuel oil compositions comprise at least one adduct of (A) .alpha.-olefin homopolymer or interpolymer of 700 to 10,000 number average molecular weight, free radically grafted with an average of from about 0.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: November 26, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Lundberg, David J. Lohse