Component Of Indefinite Molecular Weight Greater Than 150 Patents (Class 585/7)
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Patent number: 12180368Abstract: A thermal-conductive silicone composition containing: (A) a hydrolysable organopolysiloxane having an alkoxysilyl group; and (B) aluminum nitride particles having an average particle size of 0.5 ?m or more and 2.0 ?m or less and contained in an amount of 50 to 70 volume %. A content of coarse particles in the aluminum nitride particles is 1.0 volume % or less relative to the entire aluminum nitride particles, the coarse particles having particle sizes of 10 ?m or more according to a particle size distribution measurement method by laser diffraction. The thermal-conductive silicone composition has a heat conductivity of 1.3 W/mK or more according to a hot disc method. The present invention provides: a thermal-conductive silicone composition having high heat conductivity and being compressible to 10 ?m or less; and a production method of the thermal-conductive silicone composition.Type: GrantFiled: February 10, 2020Date of Patent: December 31, 2024Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Wataru Toya, Keita Kitazawa, Takahiro Yamaguchi
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Patent number: 9194576Abstract: The LED bulb has a body of silicone between the LED driver and the heat sink for transferring heat generated in the LED driver to the heat sink. The body of silicone is also disposed between the LED module and heat sink for transferring heal generated in the LED module to the heat sink.Type: GrantFiled: June 4, 2013Date of Patent: November 24, 2015Assignee: Component Hardware Group, Inc.Inventor: Xue Jun
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Publication number: 20140274836Abstract: A method for improving thermo-oxidative stability and elastomer compatibility in an apparatus lubricated with a lubricating oil by using as the lubricating oil a formulated oil including a lubricating oil base stock. The lubricating oil base stock includes a multi-aromatic base stock of the formula: R1—R2—(X—R2)n—R1 wherein each R1 is the same or different and is a terminal group, each R2 is the same or different and represents a substituted or unsubstituted aromatic moiety; each X is a linking moiety that is carbon-carbon single bond or a linking group, n is a number from 1 to 2000, and the ratio of the total number of aromatic ring carbon atoms to aliphatic carbon atoms in said formula is greater than 0.32:1. The multi-aromatic base stock has a kinematic viscosity greater than 20 mm2/s at 100° C.Type: ApplicationFiled: March 15, 2013Publication date: September 18, 2014Applicant: ExxonMobil Research and Engineering CompanyInventor: ExxonMobil Research and Engineering Company
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Patent number: 8809603Abstract: A method of producing a hydrocarbon fuel from a hydrocarbon-containing gas is disclosed and described. A hydrocarbon-containing gas is produced (10) containing from about 25% to about 50% carbon dioxide and can be reformed (12) with a steam gas to form a mixture of hydrogen, carbon monoxide and carbon dioxide. The reforming can be a composite dry-wet reforming or a tri-reforming step. The mixture of hydrogen, carbon monoxide and carbon dioxide can be at least partially converted (14) to a methanol product. The methanol product can be converted to the hydrocarbon fuel (18), optionally via UME synthesis (16). The method allows for effective fuel production with low catalyst fouling rates and for operation in an unmanned, self-contained unit at the source of the hydrocarbon-producing gas.Type: GrantFiled: February 15, 2013Date of Patent: August 19, 2014Assignee: Oberon Fuels, Inc.Inventors: Andrew Corradini, Jarod McCormick
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Patent number: 8734725Abstract: A system for producing enhanced wax alternatives, including a high shear device comprising a rotor and a stator, and configured to process petroleum wax and base oil with a hydrogen-containing gas under shearing conditions to form a feedstock, wherein at least one of the rotor and the stator comprises a toothed surface; and a reactor comprising a reactor inlet and a reactor outlet, and configured for hydrogenation of the feedstock for a time sufficient to produce enhanced hydrogenated products, wherein the high shear device is in fluid communication with the reactor, whereby the feedstock is transferable therebetween.Type: GrantFiled: May 1, 2013Date of Patent: May 27, 2014Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Publication number: 20140038872Abstract: Provided is a method of improving nitrile seal compatibility with a lubricating oil in an engine lubricated with the lubricating oil. The method includes using as the lubricating oil a formulated oil comprising a lubricating oil base stock as a major component and an alkylated aromatic base stock as a minor component. Nitrile seal compatibility is improved as compared to nitrile seal compatibility achieved using a lubricating oil containing a minor component other than the alkylated aromatic base stock, e.g., an ester. A lubricating engine oil comprising a lubricating oil base stock as a major component and an alkylated aromatic base stock as a minor component. The alkylated aromatic base stock is present in an amount sufficient for the lubricating oil to exhibit improved nitrile seal compatibility as compared to nitrile seal compatibility achieved using a lubricating oil containing a minor component other than the alkylated aromatic base stock.Type: ApplicationFiled: July 22, 2013Publication date: February 6, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Douglas Edward Deckman, David Joseph Baillargeon, Anne M. Shough, Steven Michael Jetter
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Publication number: 20140038867Abstract: A method of improving air release in lubricant base stocks and lubricating oils is provided. The method includes providing a Group I base stock, a Group II base stock or a combination thereof and adding to the base stock an effective amount of C7 to C80 paraffin, wherein the lubricant base stock provides air release according to the ASTM D3427 test at least 20% lower than the same lubricant base stock not including the C7 to C80 paraffin. Also provided are lube base stocks and lubricating oils with improved air release and methods of making such base stocks and oils.Type: ApplicationFiled: July 22, 2013Publication date: February 6, 2014Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Charles Lambert Baker, JR., Beatrice Marie Gooding, Paul Carl Naegely
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Patent number: 8637438Abstract: A lubricating oil composition for internal combustion engines comprising a base oil containing at least one component selected from an ?-olefin oligomer having 16 to 40 carbon atoms obtained by oligomerizing ?-olefin(s) having 2 to 20 carbon atoms using a metallocene catalyst, and the hydrogenated derivative thereof; an ?-olefin oligomer having 16 to 40 carbon atoms derived from an ?-olefin dimer obtained using a metallocene catalyst, and the hydrogenated derivative thereof; and the like. The lubricating oil composition has an excellent low-temperature fluidity, a low evaporativity, and a good oxidation stability.Type: GrantFiled: November 14, 2006Date of Patent: January 28, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventor: Ryou Yamada
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Patent number: 8506888Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives, the system that includes a reactor having a reactor inlet and a reactor outlet; and a high shear device having a device inlet, a device outlet, a rotor, a stator, and a catalytic surface, wherein the device outlet is in fluid communication with the reactor inlet.Type: GrantFiled: November 13, 2012Date of Patent: August 13, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8491777Abstract: Embodiments disclosed herein describe a system for producing enhanced wax alternatives. The system comprises a reactor with at least one inlet and one outlet and at least one high shear mixing device with at least one inlet and one outlet. The at least one outlet of said high shear mixing device is in fluid communication with at least one inlet of said reactor. The high shear mixing device may comprise counter rotating rotors. The high shear mixing device may also comprise at least one catalytic surface. Embodiments disclosed herein also describe a method of producing enhanced wax alternatives. The method comprises (1) providing petroleum wax and base oil; (2) mixing said petroleum wax and base oil with a hydrogen-containing gas in a high shear device to form a feedstock; and (3) hydrogenating said feedstock for a time sufficient to produce enhanced hydrogenated products.Type: GrantFiled: January 22, 2010Date of Patent: July 23, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Patent number: 8491778Abstract: Embodiments disclosed herein describe method of producing hydrogenated products, the method that includes providing a wax and an oil; processing the wax and the oil with a gas under high shear conditions to form a high shear product; and hydrogenating the high shear product to produce hydrogenated products. The wax may be a petroleum wax comprising alkane hydrocarbons with formula CnH2n+2, wherein n=20-40.Type: GrantFiled: November 12, 2012Date of Patent: July 23, 2013Assignee: H R D CorporationInventors: Abbas Hassan, Gregory G. Borsinger, Rayford G. Anthony, Aziz Hassan
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Publication number: 20130123553Abstract: A lubricating oil composition of the invention contains longifolene represented by the following formula (1), that is, (1S,3aR,4S,8aS)-4,8,8-trimethyl-9-methylene-decahydro-1,4-methanoazulene.Type: ApplicationFiled: July 20, 2011Publication date: May 16, 2013Applicant: Idemitsu Kosan Co., Ltd.Inventors: Hiroki Sekiguchi, Toshiyuki Tsubouchi, Sumihiro Oda, Hidetoshi Koga
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Patent number: 8431012Abstract: The present invention is directed to a heavy hydrocarbon composition useful as a heavy lubricant oil base stock and to a heavy lubricant composition derived from the heavy lubricant oil base stock that remains clear and bright even after being cooled to room temperature and stored for an extended period of time.Type: GrantFiled: October 13, 2009Date of Patent: April 30, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Eric B. Sirota, Roland Saeger
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Patent number: 8425630Abstract: The invention includes a method of improving the combustion efficiency of a fuel-burning device. The method includes the steps of adding a low molecular weight polymer to the fuel of the fuel-burning device and burning the fuel with the polymer in the fuel-burning device. The invention also includes fuel compositions containing such polymers.Type: GrantFiled: January 18, 2011Date of Patent: April 23, 2013Assignee: Himmelsbach Holdings, LLCInventors: Paul F. Waters, John B. Waters
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Patent number: 8409728Abstract: An organic electroluminescence device includes an organic layer disposed between at least one pair of electrodes, wherein the organic layer includes at least one fluorescent compound selected from compounds represented by the following general formulae (1) and (2): wherein X1 to X16 each independently represents a hydrogen atom, a linear, branched or cyclic alkyl group having 1 to 20 carbon atoms, a linear, branched or cyclic alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon groups, a substituted or unsubstituted arylamino group having 6 to 30 carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 30 carbon atoms, a substituted or unsubstituted arylalkylamino group having 7 to 30 carbon atoms or a substituted or unsubstituted alkenyl group having 8 to 30 carbon atoms; a pair of adjacent groups represented by X1 to X2 and a pair of adjacent substituents to gType: GrantFiled: August 19, 2010Date of Patent: April 2, 2013Assignee: Ritdisplay CorporationInventors: Shih Pin Tseng, Ming Lei Chen, Cheng Feng Su
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Publication number: 20130055626Abstract: The present invention provides a liquid fuel composition comprising a distillation fraction of a component having at least one C4+ compound derived from a water-soluble oxygenated hydrocarbon prepared by a method comprising: providing water and a water-soluble oxygenated hydrocarbon comprising a C1+O1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase; providing H2; catalytically reacting in the liquid and/or vapor phase the oxygenated hydrocarbon with the H2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce an oxygenate comprising a C1+O1-3 hydrocarbon in a reaction stream; and catalytically reacting in the liquid and/or vapor phase the oxygenate in the presence of a condensation catalyst at a condensation temperature and condensation pressure to produce the C4+ compound, wherein the C4+ compound comprises a member selected from the group consisting of C4+ alcohol, C4+ ketone, C4+ alkane, C4+ alkene, C5+ cycloalkane, C5+ cycloalkene,Type: ApplicationFiled: August 24, 2012Publication date: March 7, 2013Applicants: VIRENT, INC., SHELL OIL COMPANYInventors: Joanna Margaret BAULDREAY, Paul George BLOMMEL, Randy Douglas CORTRIGHT, Richard John PRICE
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Patent number: 8378159Abstract: A method of producing a hydrocarbon fuel from a hydrocarbon-containing gas is disclosed and described. A hydrocarbon-containing gas is produced (10) containing from about 25% to about 50% carbon dioxide and can be reformed (12) with a steam gas to form a mixture of hydrogen, carbon monoxide and carbon dioxide. The reforming can be a composite dry-wet reforming or a tri-reforming step. The mixture of hydrogen, carbon monoxide and carbon dioxide can be at least partially converted (14) to a methanol product. The methanol product can be converted to the hydrocarbon fuel (18), optionally via DME synthesis (16). The method allows for effective fuel production with low catalyst fouling rates and for operation in an unmanned, self-contained unit at the source of the hydrocarbon-producing gas.Type: GrantFiled: December 17, 2009Date of Patent: February 19, 2013Assignee: Oberon Fuels, Inc.Inventors: Andrew Corradini, Jarod McCormick
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Publication number: 20130040867Abstract: A trunk piston engine lubricating oil composition is disclosed comprising (a) a major amount of a base stock containing at least 90% by weight saturated hydrocarbons; and (b) a base stock selected from the group consisting of (i) an ester base stock wherein the ester base stock is present in an amount greater than 10% by weight and no greater than about 45% by weight, based on the total weight of the lubricating oil composition, and (ii) an alkylated aromatic base stock.Type: ApplicationFiled: October 15, 2012Publication date: February 14, 2013Applicant: Chevron Oronite Technology B.V.Inventor: Wilhelmus Petrus Antonie Van Houten
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Patent number: 8318846Abstract: An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition. The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending.Type: GrantFiled: November 10, 2006Date of Patent: November 27, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Yuichi Ito, Hidenari Nakahama, Kotaro Ichino
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Patent number: 8017684Abstract: Provided is a heat conductive silicone grease composition, including: (A) 100 parts by volume of an organopolysiloxane with a specific structure and with a kinematic viscosity at 25° C. of 10 to 10,000 mm2/s, (B) 0.1 to 50 parts by volume of an alkoxysilane with a specific structure, and (C) 100 to 2,500 parts by volume of a heat conductive filler. The composition exhibits high thermal conductivity, retains excellent fluidity meaning the composition exhibits favorable workability, and is capable of filling fine indentations, thereby reducing contact resistance and providing excellent heat radiation performance. Also, the durability, under conditions of high temperature and high humidity, of the composition is improved, thereby improving the reliability of the composition during actual use. Heat generated by a heat-generating body can be dissipated into a heat-radiating body by sandwiching the composition between the heat-generating body and the heat-radiating body.Type: GrantFiled: December 26, 2006Date of Patent: September 13, 2011Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Akihiro Endo, Kei Miyoshi, Kunihiro Yamada, Hiroaki Kizaki
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Patent number: 7998339Abstract: The invention relates to a process for producing a new type of high-quality hydrocarbon base oil of biological origin. The process of the invention comprises ketonisation, hydrodeoxygenation, and isomerization steps. Fatty acids and/or fatty acid esters based on a biological raw material are preferably used as the feedstock.Type: GrantFiled: December 11, 2006Date of Patent: August 16, 2011Assignee: Neste Oil OyjInventors: Jukka Myllyoja, Juha Jakkula, Pekka Aalto, Eija Koivusalmi, Johan-Fredrik Selin, Juha Moilanen
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Patent number: 7884256Abstract: Higher diamondoid derivatives capable of taking part in polymerization reactions are disclosed as well as intermediates to these derivatives, polymers formed from these derivatives and methods for preparing the polymers.Type: GrantFiled: December 17, 2004Date of Patent: February 8, 2011Assignee: Chevron U.S.A. Inc.Inventors: Shenggao Liu, Robert M. Carlson, Jeremy E. Dahl
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Patent number: 7682499Abstract: The invention provides for a mineral insulating oil having a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a mineral insulating oil having a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1.Type: GrantFiled: August 24, 2006Date of Patent: March 23, 2010Assignee: Shell Oil CompanyInventors: Steven Allen Holmes, Ronald Wayne Dever
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Publication number: 20090300971Abstract: The present invention generally relates to a method for producing a naphtha product from a renewable feedstock. The method includes hydrotreating the renewable feedstock to produce a hydrotreating unit heavy fraction that includes n-paraffins, and hydrocracking the hydrotreating unit heavy fraction to produce a hydrocracking unit product that includes the naphtha product. The method also includes separating the naphtha fraction and optionally recycling the hydrocracking unit heavy fraction through the hydrocracking unit. The present invention also relates to a biorenewable naphtha product suitable for use as feed stock for steam crackers and catalytic reforming units, and for use as fuel, or fuel blend stock.Type: ApplicationFiled: June 4, 2008Publication date: December 10, 2009Inventors: Ramin Abhari, H. Lynn Tomlinson, Gary Roth
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Patent number: 7534924Abstract: A hydrocarbon mixture containing modified polycyclic aromatic compounds or modified PAC having a chemical structure of mean molecular weight ranging between 300 and 10,000, the chemical structure being represented by formula (I): (A)x(PAC)y, wherein x and y are integers corresponding to the numbers of A or PAC units, selected such that x/y is equal to at least 1, preferably ranging between 1 and 50 and wherein A is a unit corresponding to a polymerizable monomer containing between 2 and 60 carbon atoms.Type: GrantFiled: April 2, 2003Date of Patent: May 19, 2009Assignee: Total Fina Elf FranceInventors: Guy Lemoine, Boulos Youssef, Claude Bunel, Yannick Jolivet, Jean-Marie Pinoche
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Publication number: 20090116771Abstract: Disclosed is a lubricant composition comprising a base oil which contains 50% by mass or more of at least one of an ?-olefin oligomer and a hydrogenated product of an ?-olefin oligomer and in which the kinematic viscosity and the flash point satisfy the following relational equation (I): Flash point (° C.)?49×ln ?+90??(I) [provided that ? is a kinematic viscosity at 40° C.]. The lubricant composition contains a base oil which has little effect on a resin or elastomer because it is a nonpolar compound, in addition to having an extremely small amount of evaporation and a high flash point despite a low viscosity, and is suitable for various applications, in particular, as bearing oils.Type: ApplicationFiled: November 15, 2006Publication date: May 7, 2009Applicant: Idemitsu kosan co. LtdInventors: Hideto Kamimura, Katsumi Hashimoto
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Patent number: 7241375Abstract: A heavy hydrocarbon composition with utility as a heavy hydrocarbon base stock comprising at least 95 wt % paraffin molecules, of which at least 90 wt % are isoparaffin, containing hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity, as measured by ASTM D-445, is above 8 cSt, has an initial boiling point of least 850° F. (454° C.) and an end boiling point of at least 1000° F. (538° C.), wherein the branching index (BI), as measured by the percentage of methyl hydrogens, and the branching proximity (CH2>4), as measured by the percentage of recurring methylene carbons which are four or more carbon atoms removed from an end group or branch, of said isoparaffinic hydrocarbon molecules, are such that: (a) BI?0.5(CH2>4)<15; and (b) BI+0.85(CH2>4)<45; as measured over the heavy hydrocarbon composition as a whole.Type: GrantFiled: August 29, 2003Date of Patent: July 10, 2007Assignee: ExxonMobil Research and Engineering CompanyInventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Patent number: 7148388Abstract: In a process for preparing an olefinic hydrocarbon mixture comprising at least 5% by weight of mono-olefin oligomers of the empirical formula: CnH2n where n is greater than or equal to 6, a feedstock comprising n-butene and propylene in a molar ratio of about 1:0.01 to about 1:0.49 is contacted under oligomerization conditions with surface deactivated ZSM-23. The resultant mono-olefin oligomers comprise at least 20 percent by weight of olefins having at least 12 carbon atoms, wherein said olefins having at least 12 carbon atoms have an average of from about 0.8 to about 2.0 C1–C3 alkyl branches per carbon chain.Type: GrantFiled: March 28, 2003Date of Patent: December 12, 2006Assignee: ExxonMobil Chemical Patents Inc.Inventors: Stephen W. Beadle, Cesar M. Cheng-Guajardo, Carolyn B. Duncan, David Wayne Turner, Ramzi Y. Saleh
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Patent number: 7129197Abstract: One or more oligomers of an olefin are prepared in the presence of a single-site catalyst. Preferably, the olefin is an ?-olefin, and the oligomers are a poly-alpha-olefin (PAO). The PAO so prepared is completely or substantially free of tertiary hydrogen resulting from isomerization. Consequently, the PAO possesses improved biodegradability, improved oxidation resistance, and/or a relatively higher viscosity index. The PAO has many useful applications, such as a component of a lubricant.Type: GrantFiled: August 29, 2002Date of Patent: October 31, 2006Assignee: Shell Oil CompanyInventors: Wei Song, William J. Heilman
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Patent number: 6846778Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.). The branching index BI and the branching proximity CH2>4 of the isoparaffinic hydrocarbon molecules, are such that: BI?0.5(CH2>4)<15; and??(a) BI+0.85(CH2>4)<45;??(b) as measured over the hydrocarbon composition as a whole.Type: GrantFiled: October 8, 2002Date of Patent: January 25, 2005Assignee: ExxonMobil Research and Engineering CompanyInventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Publication number: 20040236167Abstract: A method is provided for synthesizing a polymer that has highly-functionalized chain-end moieties. The method functionalizes liquid rubber to terminate a metallic or organometallic initiated living polymer. After the living polymer has been terminated with the functionalized liquid rubber, the functionalities on the residue of the liquid rubber are preferably modified to yield more advantageous functionalities.Type: ApplicationFiled: February 18, 2004Publication date: November 25, 2004Inventors: Roderic P. Quirk, Jin-Ping Zhou
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Patent number: 6808542Abstract: The invention provides photoluminescent markers consisting essentially of fluorene copolymers, which are colorless or nearly colorless to the naked eye and exhibit strong photoluminescence between about 380-800 nm upon exposure to ultra-violet radiation or laser light. The soluble fluorene copolymers described in this invention having a general formula as shown in Formula 1. where: R1 and R2 are C1-C24 linear or branched alkyl chain, n is the number of repeating unit, M is a co-monomer unit having structures chosen to impart distinct physical or chemical properties to the marker. Also provided in the present invention are methods of use of the markers for tagging solid or liquid products and methods to detect said markers.Type: GrantFiled: December 26, 2001Date of Patent: October 26, 2004Assignee: American Dye Source, Inc.Inventors: My T. Nguyen, Francois Raymond, Steven Xiao
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Publication number: 20040067856Abstract: A synthetic, isoparaffinic heavy hydrocarbon composition useful as a heavy lubricant base stock contains hydrocarbon molecules having consecutive numbers of carbon atoms, is a liquid at 100° C., at which temperature its kinematic viscosity is above 8 cSt and has respective initial and end boiling points of at least 850 and 1000° F. (454 and 538° C.).Type: ApplicationFiled: October 8, 2002Publication date: April 8, 2004Inventors: Jack Wayne Johnson, Adeana Richelle Bishop, William Berlin Genetti, Loren Leon Ansell, Rocco Anthony Fiato
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Patent number: 6627779Abstract: The invention provides methods for preparing a blended lube base oils comprising at least one highly paraffinic Fischer Tropsch lube base stocks and at least one base stock composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof. The use of base stocks composed of alkylaromatics, alkylcycloparaffins, or mixtures thereof improves the yield of lube base oils from Fischer Tropsch facilities, as well as provides moderate improvements in physical properties including additive solubility. The invention provides processes for obtaining such blended lube base oils using the products of Fischer Tropsch processes.Type: GrantFiled: October 19, 2001Date of Patent: September 30, 2003Assignee: Chevron U.S.A. Inc.Inventor: Dennis J. O'Rear
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Patent number: 6410810Abstract: A mixture of bis- and tris(fluoroaryl)borane compounds expressed by General Formula (1) below is handled in the form of a slurry made with a hydrocarbon solvent: where each of R1, R2, R3, R4 and R5 independently represents a hydrogen atom, a fluorine atom, a hydrocarbon group, or an alkoxy group provided that at least one of R1-R5 represents a fluorine atom, X represents a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, and wherein n represents 2 for the bis(fluoroaryl)borane compounds and 3 for the tris(fluoroaryl)borane compounds. Then, a hydrocarbon solution of the (fluoroaryl)borane compounds having a concentration of the tris(fluoroaryl)borane compounds in a range between 1 wt % and 1 wt % is prepared by dissolving the slurry into a hydrocarbon solvent in a virtually air-tight vessel.Type: GrantFiled: February 24, 2000Date of Patent: June 25, 2002Assignee: Nippon Shokubai Co., Ltd.Inventors: Hitoshi Mitsui, Tsunemasa Ueno, Ikuyo Ikeno, Naoko Hirano
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Patent number: 6255546Abstract: A functional fluid of low Brookfield Viscosity comprising a mixture of hydrocracked base stocks, optionally a minor amount of solvent neutral base stock, and additives.Type: GrantFiled: February 8, 2000Date of Patent: July 3, 2001Assignee: ExxonMobile Research and Engineering CompanyInventor: Albert Gordon Alexander
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Patent number: 6215033Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified, and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be blended with lower molecular weight components. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: December 11, 1998Date of Patent: April 10, 2001Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, John M. Klosek, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
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Patent number: 6103676Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated, functionalized, optionally modified and post treated. The dispersant substances include a copolymer of two different conjugated dienes. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. The polymers may be functionalized by hydroformylation followed by reductive amination. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: June 23, 1998Date of Patent: August 15, 2000Assignee: Mobil Oil CorporationInventors: Thomas S. Coolbaugh, Frederick C. Loveless, John E. Marlin, II, Demetreos N. Matthews
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Patent number: 6071863Abstract: Biodegradable polyalphaolefin fluids which are useful in functional fluid and lubricant compositions are oligomers of mixtures of C.sub.12 and C.sub.14 alphaolefins. The fluids have kinematic viscosities at 100.degree. C. of from 5 to 20 mm.sup.2 /s and a biodegradability as determined by the CEC L-33 A93 test of at least about 50 percent.Type: GrantFiled: March 2, 1999Date of Patent: June 6, 2000Assignee: BP Amoco CorporationInventors: Rainer Benda, John V. Bullen, Alan J. Plomer
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Patent number: 6043401Abstract: Catalysts and processes are described to make low molecular weight, essentially terminally-unsaturated, viscous poly(1-olefin) or copoly(1-olefin) having a high terminal vinylidine content from a feed stock containing one or more 1-olefin and other volatile hydrocarbon liquids using a Ziegler catalyst made from a Group IVb metallocene and an aluminoxane cocatalyst, particularly bis(cyclopentadienyl) and bis(indenyl) titanium(IV), zirconium(IV) or hafnium(IV) compounds and methylaluminoxane. A particularly useful feed stock is a refinery stream containing 1-olefins and isobutylene which is used to make polyisobutylene.Type: GrantFiled: January 15, 1998Date of Patent: March 28, 2000Assignee: BP Amoco CorporationInventors: Vahid Bagheri, Bruce Edward Firth, Frank Calabrese, Robert Scott Hensey
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Patent number: 5637783Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of a ring substituted styrene and a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled residual amounts of aromatic unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: June 7, 1995Date of Patent: June 10, 1997Assignee: Mobil Oil CorporationInventors: Ellen B. Brandes, Frederick C. Loveless
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Patent number: 5633415Abstract: The invention provides dispersants and dispersant viscosity index improvers which include polymers of conjugated dienes which have been hydrogenated and functionalized. The dispersant substances include compositions including a copolymer of two different conjugated dienes, a copolymer of a p-alkylstyrene and a conjugated diene, or a homopolymer of a conjugated diene. The polymers are selectively hydrogenated to produce polymers which have highly controlled amounts of unsaturation, permitting highly selective functionalization. Also provided are lubricant fluids, such as mineral and synthetic oils, which have been modified in their dispersancy and/or viscometric properties by means of the dispersant substances of the invention. Also provided are methods of modifying the dispersancy and/or viscometric properties of lubricating fluids such as mineral and synthetic lubricating oils. The dispersant substances may also include a carrier fluid to provide dispersant concentrates.Type: GrantFiled: June 7, 1995Date of Patent: May 27, 1997Assignee: Mobil Oil CorporationInventors: Ellen B. Brandes, Frederick C. Loveless
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Patent number: 5462680Abstract: This invention relates to novel compositions of matter comprising free radical adducts of a fullerene with one or more saturated hydrocarbons having a number average molecular weight ranging from about 200 to about ten million. Attachment of saturated hydrocarbons to as many as fourteen sites on the fullerene surface can be achieved via free radical initiated reactions. Fullerenes also add to saturated hydrocarbons with functional groups selected from the group consisting of hydroxy, carboxy, and carboalkoxy radicals in the presence of a free radical initiator. Said radical adducts of substantially saturated hydrocarbons with fullerenes react further with alkylamines and polyamines to produce new compositions. The radical adducts, and their aminated derivatives are useful as dispersants and viscosity modifiers in lubricants.Type: GrantFiled: April 19, 1994Date of Patent: October 31, 1995Assignee: Exxon Research & Engineering Co.Inventors: Stanley J. Brois, Abhimanyu O. Patil, Wolfgang W. Schulz, Chang S. Hsu, Richard T. Garner
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Patent number: 5420372Abstract: An alpha-olefin oligomer consisting essentially of repeating units having the structural formula: ##STR1## wherein x represents an integer from 3 to 11, inclusive; andy represents the number of repeating units in the oligomer such that the weight average molecular weight is from about 5,000 to about 20,000;said oligomer having from about 70 to 100 percent head-to-tail alignment of the repeating units of the oligomer. Preferably the weight average molecular weight of the oligomer is from 5,000 to about 10,000; and said oligomer is further characterized as having a dispersity of less than about 5.5, and a Z average molecular weight of less than about 24,000.Type: GrantFiled: December 30, 1992Date of Patent: May 30, 1995Assignee: Chevron Chemical CompanyInventors: David L. Beach, Paul G. Bercik, Neal E. Morganson
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Patent number: 5315053Abstract: A lubricating oil composition comprising a normally liquid alpha-olefin oligomer consisting essentially of repeating units having the structural formula: ##STR1## wherein x represents an integer from 3 to 11, inclusive; andy represents the number of repeating units in the oligomer such that the weight average molecular weight is from about 5,000 to about 20,000;said oligomer having from about 70 to 100 percent head-to-tail alignment of the repeating units of the oligomer. Preferably the weight average molecular weight of the oligomer is from 5,000 to about 10,000; and said oligomer is further characterized as having a dispersity of less than about 5.5, and a Z average molecular weight of less than about 24,000.Type: GrantFiled: July 6, 1993Date of Patent: May 24, 1994Assignee: Chevron Research CompanyInventors: David L. Beach, Paul G. Bercik, Neal E. Morganson
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Patent number: 5208403Abstract: Lubricant compositions comprise blends or mixtures of low viscosity, 3-8 cS e.g. about 5 cS(100.degree. C.), HVI lube basestock with higher viscosity, 15 cS+e.g. 30+ cS(100.degree. C.) HVI PAO lube basestock produced from slack wax by thermal cracking to alpha olefins followed by Lewis acid catalyzed oligomerization of the alpha olefin mixture to lube base stock. Blending these components in appropriate proportions produces lube basestock having viscosities in the range of 8-15 cS (100.degree. C.) from which material suitable for the formulation of 10W-30 automobile engine lube can be produced. The blends are notable for exhibiting high VI values greater than that of either component of the blend.Type: GrantFiled: April 28, 1992Date of Patent: May 4, 1993Assignee: Mobil Oil CorporationInventors: J. Scott Buchanan, Margaret M. Wu
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Patent number: 5208402Abstract: Internal combustion engine liquid fuels are produced by the mixing of a natural gasoline component and at least one octane-enhancing component. The mix is weathered during the blending operation to remove light-weight hydrocarbons comprising one- to four-carbon components. The light-weight hydrocarbons, which preferably constitute less than 3 percent of the blended fuel, can be recovered to generate power to run the process. The liquid fuel mixture is formulated to produce a desired octane rating, an environmentally acceptable vapor pressure, and a mix which, when burned in an internal combustion engine, produces a minimum amount of pollutants.Type: GrantFiled: September 5, 1991Date of Patent: May 4, 1993Assignee: Interstate Chemical, Inc.Inventor: Ewert J. A. Wilson
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Patent number: 5180863Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.Type: GrantFiled: June 17, 1991Date of Patent: January 19, 1993Assignee: Mobil Oil CorporationInventor: Thomas R. Forbus
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Patent number: 5177276Abstract: An alpha-olefin oligomer consisting essentially of repeating units having the structural formula: ##STR1## wherein x represents an integer from 3 to 11, inclusive; andy represents the number of repeating units in the oligomer such that the weight average molecular weight is from about 5,000 to about 20,000;said oligomer having from about 70 to 100 percent head-to-tail alignment of the repeating units of the oligomer. Preferably the weight average molecular weight of the oligomer is from 5,000 to about 10,000; and said oligomer is further characterized as having a dispersity of less than about 5.5, and a Z average molecular weight of less than about 24,000.Type: GrantFiled: November 4, 1988Date of Patent: January 5, 1993Assignee: Chevron Research CompanyInventors: David L. Beach, Paul G. Bercik, Neal E. Morganson
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Patent number: 5157176Abstract: A preferred embodiment of the process and apparatus for recycling used automobile rubber tires is described in which small pieces of rubber tires are progressively fed into a vertical reactor of the counter-flow type in which the material progressively descends downward through the reactor with process gases passing upward through the downwardly decending material to decompose and volatilize the rubber material. At the lower portion of the vessel, oxygen-bearing gas is injected into the reactor to burn a portion of the rubber carbon to generate hot combustion gases that ascend upwardly to pyrolitically decompose the rubber pieces, and to volatilize such material. The amount of oxygen is controlled in an oxygen-deficient manner to maintain the temperature in the combustion zone at a temperature of less than 500.degree. F. The gases and volatilized rubber materials and oils are removed from the reactor at a temperature of approximately 350.degree. F.Type: GrantFiled: July 26, 1990Date of Patent: October 20, 1992Inventor: Joseph H. Munger