From Synthetic Resin Or Rubber Patents (Class 585/241)
  • Patent number: 12152200
    Abstract: Embodiments of the present disclosure relate to a method for producing refined hydrocarbons from waste plastics, the method including: a pretreatment process of pretreating waste plastics; a pyrolysis process of producing pyrolysis gas by introducing the waste plastics pretreated in the pretreatment process into a pyrolysis reactor; a lightening process of producing pyrolysis oil by introducing the pyrolysis gas into a hot filter; and a distillation process of distilling the pyrolysis oil to obtain refined hydrocarbons, wherein a liquid condensed in the hot filter is re-introduced into the pyrolysis reactor, and a system for producing refined hydrocarbons from waste plastics.
    Type: Grant
    Filed: January 15, 2024
    Date of Patent: November 26, 2024
    Assignees: SK INNOVATION CO., LTD., SK GEO CENTRIC CO., LTD.
    Inventors: Sang Hwan Jo, Soo Kil Kang, Yong Woon Kim, Min Gyoo Park, Min Woo Shin, Jin Seong Jang
  • Patent number: 12139676
    Abstract: Various embodiments of the present disclosure relate to methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil. The methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil according to the embodiments of the present disclosure may minimize formation of an ammonium salt (NH4Cl) and may prevent an adhesion phenomenon of impurity particles in a reactor in a refining process of waste plastic pyrolysis oil containing impurities including chlorine and nitrogen. In addition, the methods and system for producing refined hydrocarbons according to embodiments of the present disclosure may have excellent refining efficiency and may implement a long-term operation of a process because deactivation of a catalyst used in the process is prevented, and may produce refined hydrocarbons having a low content of impurities and a low content of olefins, and solid coke, from waste plastic pyrolysis oil.
    Type: Grant
    Filed: February 7, 2024
    Date of Patent: November 12, 2024
    Assignees: SK INNOVATION CO., LTD., SK GEO CENTRIC CO., LTD.
    Inventors: Yong Woon Kim, Seo Yeong Kang, Soo Kil Kang, Min Gyoo Park, Young Moo Park, Min Woo Shin, Jae Hwan Lee, Jin Seong Jang, Sang Hwan Jo
  • Patent number: 11952540
    Abstract: A method and apparatus for hydrocracking mineralized refuse pyrolysis oil. The method may use the following steps: (a) crushing and pyrolyzing mineralized refuse to obtain arene and alkane precursor biomass oil; (b) hydrogenating the arene and alkane precursor biomass oil obtained in step (a), and separating the obtained hydrocrackate to obtain arene and alkane; and (c) purifying, recovering and optimizing the arene and alkane obtained in step (b), and performing deep processing to produce naphtha, jet fuel, light diesel oil, and heavy diesel oil.
    Type: Grant
    Filed: June 16, 2020
    Date of Patent: April 9, 2024
    Assignee: East China University of Science and Technology
    Inventors: Yulong Chang, Hualin Wang, Xia Jiang, Jianping Li, Jingyi Zhu, Pengbo Fu, Wei Yuan
  • Patent number: 11939542
    Abstract: A system for processing plastic waste may include a feed line, a feed fractionator, a hydrotreater, a catalytic reforming unit, a heavy oil cracker, and a steam cracker. A pyrolyzed plastics feed is separated into light, medium, and heavy hydrocarbon streams. The hydrotreater removes sulfur, and the catalytic reforming unit produces a circular aromatic-rich stream. The heavy oil cracker generates cracked streams. The steam cracker produces a circular olefin stream from a cracked stream. A system for processing plastic waste may include the feed line, the feed fractionator, the hydrotreater, a medium hydrocarbon fractionator, the catalytic reforming unit, a full-range reforming unit, the heavy oil cracker, and the steam cracker. The medium hydrocarbon fractionator produces two hydrocarbon streams. The full-range naphtha reforming unit produces a second circular aromatic-rich stream.
    Type: Grant
    Filed: September 11, 2023
    Date of Patent: March 26, 2024
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Bruce D. Murray, Scott G. Morrison, Kenneth Fountain, Steven R. Horlacher, Vincent D. Mcgahee, Reza Khankal, David Dockter
  • Patent number: 11891519
    Abstract: Provided herein are asphalt compositions comprising asphalt, a carboxylated copolymer, a polyalkyleneimine, and a photoinitiator. The carboxylated copolymer present in the asphalt compositions can be a latex composition derived from a carboxylated styrene-butadiene copolymer. The carboxylated copolymer includes from 0.5% to 25% by weight carboxylic acid monomers. The carboxylated styrene-butadiene polymer and the asphalt can be present in a weight ratio of from 1:99 to 1:10. The polyalkyleneimine present in the asphalt compositions can be in an amount of greater than 0% to up to 10% by weight of the asphalt composition. The photoinitiator can include benzophenone and/or a derivative thereof. Tack coats meeting ASTM-D-977 standard comprising the asphalt compositions disclosed herein are also provided. The tack coat can have a tack-free time of 10 minutes or less. Methods of producing the asphalt compositions and tack coats are also disclosed.
    Type: Grant
    Filed: January 28, 2019
    Date of Patent: February 6, 2024
    Assignee: BASF SE
    Inventors: Kostas S. Avramidis, James T. Andrews, William J. Kirk, Kimberly L. Walden, Arlis A. Kadrmas
  • Patent number: 11879102
    Abstract: The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): ? · the coil outle
    Type: Grant
    Filed: January 24, 2020
    Date of Patent: January 23, 2024
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Anthoni Van Zijl, Nicolas Goyheneix, Lara Galan-Sanchez, Christoph Roosen, Johan Pastwa, Safa Farajzadeh Bibalan
  • Patent number: 11781073
    Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.
    Type: Grant
    Filed: November 8, 2022
    Date of Patent: October 10, 2023
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray, Jacob M. Hilbrich, Charles T. Polito
  • Patent number: 11739191
    Abstract: A system for continuously treating recycled polymeric material includes a hopper configured to feed the recycled polymeric material into the system. An extruder can turn the recycled polymeric material in a molten material. In some embodiments, the extruder uses thermal fluids, electric heaters, and/or a separate heater. The molten material is depolymerized in a reactor. In some embodiments, a catalyst is used to aid in depolymerizing the material. In certain embodiments, the catalyst is contained in a permeable container. The depolymerized molten material can then be cooled via a heat exchanger. In some embodiments, multiple reactors are used. In certain embodiments, these reactors are connected in series. In some embodiments, the reactor(s) contain removable static mixer(s) and/or removable annular inserts.
    Type: Grant
    Filed: June 29, 2021
    Date of Patent: August 29, 2023
    Assignee: GreenMantra Recycling Technologies Ltd.
    Inventors: Amalia Gil, Domenic Di Mondo, Radek Rybicki
  • Patent number: 11530359
    Abstract: A method for producing a vapor stream from waste plastic comprises providing a waste plastic feedstock into a reactor containing one or more residues produced from a previously heated source of waste plastic, and heating the waste plastic feedstock in the reactor to a temperature from about 125° C. to 500° C. to generate a vapor containing one or more hydrocarbons. The waste plastic feedstock can have a calcium to sodium mass ratio from about 0.0001 to 400 as measured by inductively-coupled plasma (ICP) spectrometry. The catalytic activity in the reactor may be provided through one or more constituent elements in the waste plastic feedstock or the one or more residues produced from the previously heated source of waste plastic.
    Type: Grant
    Filed: December 16, 2020
    Date of Patent: December 20, 2022
    Assignee: WASTE TECHNOLOGIES, LLC
    Inventors: Moinuddin Sarker, Anjuman Ara Begum
  • Patent number: 11518942
    Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.
    Type: Grant
    Filed: September 28, 2021
    Date of Patent: December 6, 2022
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray, Jacob M. Hilbrich, Charles T. Polito
  • Patent number: 11365357
    Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: June 21, 2022
    Assignee: Eastman Chemical Company
    Inventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
  • Patent number: 11326039
    Abstract: An embodiment provides a method for recycling tires, including: injecting, using a pump, a rubber material into a dissociating system, wherein the pump exerts a mechanical force upon the rubber material to reduce a size of the rubber material; within the dissociating system, creating a rubber material mixture, by: injecting a supercritical fluid to be mixed with the rubber material; heating, using a heat source, the rubber material mixture; and atomizing the rubber material mixture; and sending the resulting atomized rubber material mixture to a separating system to separate the rubber material mixture into different components. Other aspects are described and claimed.
    Type: Grant
    Filed: January 5, 2018
    Date of Patent: May 10, 2022
    Assignee: SMART TIRE RECYCLING, INC.
    Inventor: Abdulhaq Alkhalidi
  • Patent number: 11279631
    Abstract: A method for purifying an aqueous mixture is provided. The method can include at least partially crystallizing an aqueous mixture derived from a hydrocarbon process to provide a crystallized aqueous mixture. The aqueous mixture can comprise water and one or more contaminants to be separated from the water. The crystallized aqueous mixture can be separated into a contaminant-rich fraction and a water-rich fraction. Water can be recovered from the water-rich fraction and the one or more contaminants can be recovered from the contaminant-rich fraction.
    Type: Grant
    Filed: December 3, 2013
    Date of Patent: March 22, 2022
    Assignee: EFC Solutions Inc.
    Inventor: James D. Wrubel
  • Patent number: 11220633
    Abstract: A continuous process for the cracking of a polymeric material, includes the continuous introduction of the polymeric material in a stream or bath of molten catalyst. A plant for the cracking of a polymeric material is also related and includes a closed circuit/environment containing a molten catalyst, and an element adapted to keep the molten catalyst in continuous motion.
    Type: Grant
    Filed: June 28, 2017
    Date of Patent: January 11, 2022
    Assignee: BIORENOVA SOCIETA' PER AZIONI
    Inventors: Riccardo Reverso, Emanuele D'Abbondanza
  • Patent number: 11180699
    Abstract: A system for producing primarily diesel with some heavy fuel from plastic feedstock is described. The feedstock is received into a pyrolizer. There are two zones in the pyrolizer—one where the temperature is elevated during conveyance, and a second where the temperature is maintained. A distillation vessel receives fuel oils from the pyrolizer and agitates the oils at high temperature. A hydrogenation vessel then mixes the fuel liquid with H2 at a high pressure while recirculating to and from an expansion vessel to create converted fuel oil. A diesel distillation tank receives the converted fuel oil and creates diesel gas, which is then condensed to form a usable diesel product. Any remaining fuel oil is sent the heavy fuel oil tank.
    Type: Grant
    Filed: June 30, 2020
    Date of Patent: November 23, 2021
    Assignee: Gen Tech PTD, LLC
    Inventor: Richard A. Bingham
  • Patent number: 11104851
    Abstract: Methods for depolymerization of a plastic polymer. An embodiment includes supplying a plastic polymer and aromatic bottoms from an aromatic recovery complex, the aromatic bottoms comprising C9+ aromatic compounds; dissolving the plastic polymer in the aromatic bottoms to obtain a dissolved plastic polymer solution comprising dissolved plastic polymer and C9+ aromatic compounds; and catalytically cracking the dissolved plastic polymer solution in the presence of a catalyst such that the dissolved plastic polymer and the C9+ aromatic compounds are cracked to obtain light products.
    Type: Grant
    Filed: January 29, 2020
    Date of Patent: August 31, 2021
    Inventors: Omer Refa Koseoglu, Robert Peter Hodgkins
  • Patent number: 10947144
    Abstract: A Biorefinery System (BIOSYS) that effectively treats all human activity-derived waste (black water, grey water, and food waste streams) using biological systems and that produces as process by-products: recovered potable water, liberated free oxygen, edible protein cake (with and without lipids), soil amendments, and machinery lube oils. Additionally, the system captures and chemically binds carbon dioxide into microbial cells and associated by-products, thus producing recovered usable returned cabin air.
    Type: Grant
    Filed: October 14, 2019
    Date of Patent: March 16, 2021
    Assignee: University of Louisiana at Lafayette
    Inventors: Mark E. Zappi, Daniel Gang, Emmanuel Revellame, Andrei Chistoserdov, Rafael Hernandez, Rakesh Bajpai, Wayne Sharp, Dhan Fortela
  • Patent number: 10906209
    Abstract: The disclosed invention describes a novel approach to the utilization of the fine mineral matter derived from coal and/or coal refuse (a by-product of coal refining) to convert a non-biodegradable plastic into a biodegradable plastic. The fine mineral matter could also be based on volcanic basalt, glacial rock dust deposits, iron potassium silicate and other sea shore mined deposits. The conversion of the non-biodegradable plastic into biodegradable plastic in soil further increases nutrients availability in soil with the transition metals released as a result of biodegradation of the biodegradable plastic.
    Type: Grant
    Filed: September 16, 2019
    Date of Patent: February 2, 2021
    Assignee: Radical Plastics, Inc.
    Inventor: Yelena Kann
  • Patent number: 10858593
    Abstract: A process for producing cumene comprising converting plastics to hydrocarbon liquid and pyrolysis gas; feeding hydrocarbon liquid to hydroprocessor to yield hydrocarbon product and first gas stream; feeding hydrocarbon product to reforming unit to produce reforming product, second gas stream, and hydrogen; separating reforming product into non-aromatics recycle stream and second aromatics stream (C6+ aromatics); recycling non-aromatics recycle stream to reforming unit; separating second aromatics stream into benzene, C7, C8, C9, C10, and C11+ aromatics; contacting C7, C9, and/or C10 aromatics with a disproportionation&transalkylation catalyst/H2 to yield benzene&xylenes; conveying C11+ aromatics to hydroprocessor; introducing pyrolysis gas, first and/or second gas stream to first separator to produce first propylene stream, first C2&C4 unsaturated stream, and saturated gas (H2 and C1-4 saturated hydrocarbons); introducing first C2&C4 unsaturated stream to metathesis reactor to produce second p
    Type: Grant
    Filed: January 3, 2018
    Date of Patent: December 8, 2020
    Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
    Inventors: Krishna Kumar Ramamurthy, Ravichander Narayanaswamy, Venkata Ramanarayanan Ganapathy Bhotla, Alexander Stanislaus, Santosh Ganji
  • Patent number: 10703983
    Abstract: A method of processing of shredded rubber-containing waste involves its preliminary preparation, thermal decomposition in a furnace, separation of decomposition products into vapor-gas mixture and solid residue, and separation of a heavy hydrocarbon fraction from the vapor-gas mixture. Preliminary preparation of the waste is carried out by its blowing with water vapor until a waste temperature reaches 100° C., and thermal decomposition is carried out in residual oil in the starting phase, and afterwards in the atomized generated heavy hydrocarbon fraction and superheated water vapor, their weight ratio being (0.1-0.5):1. The heavy hydrocarbon fraction is separated from the vapor-gas mixture with water by atomizing it into the vapor-gas mixture flow at the rate of 5-15% of the mass flow rate of the mixture, while metal is extracted from the solid residue by magnetic separation, after which a product containing zinc oxide is separated by dielectric separation.
    Type: Grant
    Filed: August 21, 2019
    Date of Patent: July 7, 2020
    Inventor: Sergei P. Susekov
  • Patent number: 10549455
    Abstract: The disclosed invention describes a novel approach to the utilization of the fine mineral matter derived from coal and/or coal refuse (a by-product of coal refining) to convert a non-biodegradable plastic into a biodegradable plastic. The fine mineral matter could also be based on volcanic basalt, glacial rock dust deposits, iron potassium silicate and other sea shore mined deposits. The conversion of the non-biodegradable plastic into biodegradable plastic in soil further increases nutrients availability in soil with the transition metals released as a result of biodegradation of the biodegradable plastic.
    Type: Grant
    Filed: March 6, 2019
    Date of Patent: February 4, 2020
    Assignee: Radical Plastics Inc.
    Inventor: Yelena Kann
  • Patent number: 10537876
    Abstract: Use of a catalytic composition parameters comprising oxides of aluminum or oxidic compounds comprising aluminum and silicon with a molar ratio of aluminum to silicon of more than 1 in a process for the catalytic depolymerization of plastics waste.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: January 21, 2020
    Assignee: SOLVAY SA
    Inventors: Stéphane Streiff, Marco Piccinini, Armin T. Liebens, Avelino Corma, Miriam Cerro-Alarcón, Jesús Mengual
  • Patent number: 10457886
    Abstract: A process for converting a molten polymeric material is provided. The process includes effecting disposition of a molten polymeric material, having at least one carbon-carbon double bond, in sufficient proximity to a catalyst material within a reaction zone, to affect a reactive process that effects generation of a reaction product. The reactive process effects cleaving of at least one carbon-carbon double bond. The catalyst material includes [Fe—Cu—Mo—P]/Al2O3 prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material and reacting the intermediate material with a heteropolyacid.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: October 29, 2019
    Assignee: GreenMantra Recycling Technologies Ltd.
    Inventors: Anil Kumar, Pushkar Kumar
  • Patent number: 10428277
    Abstract: A device for processing scrap rubber has a reactor with a screw conveyor disposed inside a heating chamber, a thermal decomposition unit, burners, a condenser, a cyclone filter, and devices for discharging solid residue and removing a gas-vapor mixture. The reactor has two sections connected in parallel. The thermal decomposition unit has screw conveyors in each section, the conveyors have axial heating pipes with a coil. Along the length of the conveyors plates are arranged at the corners of an equilateral triangle in contact with and perpendicular to the side surface of the heating tube. A cylinder furnace with an evaporator and a burner is connected to the ends of the pipes. An outlet of the condenser is connected to a liquid fraction separator, inlets of the coils are connected to an outlet of the evaporator, and an inlet of the evaporator is connected to an outlet from the separator.
    Type: Grant
    Filed: May 15, 2019
    Date of Patent: October 1, 2019
    Assignee: OOO “Nauchno-Proizvodstvennoe Obedinenie Innovatekh”
    Inventors: Aleksei S. Gradov, Evgeny S. Susekov, Sergei P. Susekov
  • Patent number: 10358603
    Abstract: A method for producing fuels such as liquid and solid fuels from waste materials comprising rubber or plastic waste, is disclosed. The method comprises the steps of: (a) grounding said waste material into chips or flakes, (b) transferring the chips or flakes via a transmission system to a viscous fluid disorder tank, (c) introducing a catalyst to the transferred chips or flakes in the tank, (d) heating the chips or flakes with catalyst using a heating jacket or a coil in a reservoir of the tank at a predetermined temperature, (e) mixing the molten chips or flakes with catalyst using a helical butterfly stirrer inside the reservoir at a predetermined time and temperature to decompose the waste material, and (f) filtering the decomposed waste material to produce the fuel. This method is simple, quick and economical for producing different characteristics of fuel without any environmental lesions and contamination.
    Type: Grant
    Filed: February 14, 2018
    Date of Patent: July 23, 2019
    Inventor: Somayeh Shayesteh Pour
  • Patent number: 10332226
    Abstract: A parcel of land on which to site the plant is identified. The parcel of land is located such that about 3,500,000 to about 7,500,000 scrap tires per year are available for substantially regular and substantially continuous delivery to the plant, at a tipping fee of at least about $40.00 per ton. The plant is located on the parcel of land. One or more of synthesis gas, electricity, and steam produced by the plant are sold.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: June 25, 2019
    Assignee: GREENTIRE ENERGY LLC
    Inventors: Jerome N. Block, Ulf Hansson, Nicholas Z. Hegedus
  • Patent number: 9714385
    Abstract: The present invention relates to a process for the conversion of a low molecular weight polymeric byproduct obtained during production of high density polyethylene (HDPE), commonly known as low polymer wax (LPW) or polymer mud, into different products like different grades of paraffin wax, microcrystalline wax, lube and grease base stocks by a process comprising of thermal treatment in an inert atmosphere in the presence of organic peroxides or hydroperoxides and metal oxides. The end product depends upon the suitable selection of various process parameters like type of peroxides or hydroperoxides, metal oxides, temperature and duration of reaction.
    Type: Grant
    Filed: December 18, 2015
    Date of Patent: July 25, 2017
    Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Hayat Ullah Khan, Manisha Sahai, Sanat Kumar, Ajay Kumar, Gananath Doulat Thakre, Savita Kaul, Shrikant Madhusudan Nanoti, Bal Mukand Shukla, Madhukar Onkarnath Garg, Paulose Anthony Thrissokaran, Ajit Kumar Chaturvedi
  • Patent number: 9556319
    Abstract: A process for devulcanizing EPDM rubber comprising the step of introducing sulfur-cured EPDM to an extruder, introducing from about 0.5 to about 20 wt % scavenging agent, based upon the total weight of the EPDM and scavenging agent, and mixing and masticating the EPDM at a temperature sufficient to at least partially devulcanize the sulfur-cured EPDM.
    Type: Grant
    Filed: September 27, 2013
    Date of Patent: January 31, 2017
    Assignee: Firestone Building Products Co., LLC
    Inventors: Hao Wang, Michael J. Hubbard
  • Patent number: 9394487
    Abstract: A multi-stage process and system for converting solid particulate biomass in a riser reactor having at least two different reaction zones. A lower reaction zone is configured to optimize pyrolysis of the biomass into pyrolysis products, while an upper reaction zone is configured to efficiently crack the pyrolysis products. The relative residence times and/or temperatures of the upper and lower reaction zones can be controlled to optimize product quality and yield.
    Type: Grant
    Filed: July 22, 2011
    Date of Patent: July 19, 2016
    Assignee: Inaeris Technologies, LLC
    Inventors: Neil Wang, Liang Chen, Peter Loezos
  • Patent number: 9212318
    Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.
    Type: Grant
    Filed: July 23, 2013
    Date of Patent: December 15, 2015
    Assignee: Saudi Basic Industries Corporation
    Inventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
  • Patent number: 9096801
    Abstract: A process and plant for the thermocatalytic conversion of waste materials into reusable fuels and a fuel produced by the process, involving the steps of delivering melted waste material (11) to one or more pyrolysis chambers (26) via heated and valved manifolds (22) and effecting pyrolysis of the waste material into a gascous state in an oxygen purged and pressure controlled environment. Pyrolytic gases are, then transferred to a catalytic converter (29) where the molecular structure of the gaseous material is altered in structure and form, with gases then transferred to one or more condensers (30a) to distil and cool gases in to their respective fractions. After post pyrolysis treatment, fuel fractions thon form a useable fuel.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: August 4, 2015
    Assignee: FUTURE ENERGY INVESTMENTS PTY LTD
    Inventor: Garry Baker
  • Publication number: 20150141605
    Abstract: Processes for forming propylene from methanol are disclosed. The processes involve converting methanol to a product mixture comprising ethylene and propylene, separating the ethylene from the propylene, dimerizing a first portion of the ethylene to form a product mixture comprising 1-butylene, isomerizing the 1-butylene to form a mixture of cis and trans 2-butylene, and performing olefin metathesis on a second portion of the ethylene and the mixture of cis and trans 2-butylene. In one embodiment, the methanol is produced by converting syngas to methanol, and in one aspect of this embodiment, the syngas, or a portion thereof, is produced from renewable feedstocks. In this aspect, renewable propylene is produced. The propylene can be polymerized to form polypropylene or co- or terpolymers thereof, and when the propylene is made from renewable resources, the resulting polymer is a renewable polymer.
    Type: Application
    Filed: May 3, 2013
    Publication date: May 21, 2015
    Inventor: David Bradin
  • Patent number: 9024096
    Abstract: A process for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels is disclosed. The process may include reacting a triacylglycerides-containing oil-carbon dioxide mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides to a hydrocarbon or mixture of hydrocarbons comprising one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics.
    Type: Grant
    Filed: December 11, 2012
    Date of Patent: May 5, 2015
    Assignee: Lummus Technology Inc.
    Inventor: Marvin I. Greene
  • Patent number: 9005401
    Abstract: A system for tire distillation including an upper chamber, a first conveyor configured to transport a tire through the upper chamber, a lower chamber located beneath the upper chamber, the lower chamber that includes an ultrasonic purge chamber configured to radiate the tire with ultrasonic radiation, a microwave radiation chamber configured to radiate the tire with microwave radiation, and a second conveyor configured to transport the tire from the ultrasonic purge chamber to the microwave radiation chamber. The system further includes a vacuum system configured to maintain an atmosphere in the ultrasonic purge chamber and the microwave radiation chamber under a vacuum wherein the tire is preheated during conveyance through the upper chamber from heat produced in the lower chamber.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: April 14, 2015
    Assignee: Infinite Earth, Inc.
    Inventor: James C. Johnson
  • Patent number: 9006505
    Abstract: A method for processing plastic waste, in particular polyolefins, and a device for processing plastic waste, in particular polyolefins, are used especially in the industrial utilization of plastic waste. The method consists in that a primarily refined charge after being fed into a reactor (6) is fluidized and cracked during forced progressive-rotational movement coinciding with heating. A gas-steam fraction obtained during a utilization process is continuously guided out to a cooling system whereas impurities are periodically guided out from the reactor (6) to a waste tank (22).
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: April 14, 2015
    Assignee: Przedsiebiorstwo EKONAKS Sp. z o. o.
    Inventor: Wojciech Najman
  • Publication number: 20150099285
    Abstract: The present invention relates to systems and methods for producing energy. Specifically, the present invention relates to systems and methods for producing energy, such as energy in the form of electricity, and fuels, such as, for example, biodiesel and/or cellulosic ethanol in a small scale energy center. Moreover, the systems and methods of the present invention provide for recovery of materials, such as in soil production and/or recycling.
    Type: Application
    Filed: August 18, 2014
    Publication date: April 9, 2015
    Inventors: Steven M. Clements, Richard L. Clements
  • Publication number: 20150094503
    Abstract: A hydropyrolysis catalyst and a process using that catalyst are described. The catalyst comprises a support and an active metal component wherein the catalyst is an eggshell type catalyst having the active metal component located in the outer portion of the support.
    Type: Application
    Filed: November 12, 2012
    Publication date: April 2, 2015
    Inventors: Alan Anthony Del Paggio, Lawrence Stephen Kraus, Michael John Roberts, Celeste Jean McLeod, Terry Louise Marker, Larry Gordon Felix, Martin Brendan Linck
  • Publication number: 20150087871
    Abstract: A method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method comprises in broad embodiments the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. In some preferred embodiments, the method includes the step of commutating the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1.
    Type: Application
    Filed: December 3, 2014
    Publication date: March 26, 2015
    Inventor: Moinuddin Sarker
  • Patent number: 8987539
    Abstract: Acyclic monterpene alcohols, like linalool, to be converted through a series of highly efficient catalytic reactions a biogasoline blending component, and a drop-in biodiesel fuel.
    Type: Grant
    Filed: September 10, 2012
    Date of Patent: March 24, 2015
    Assignee: The United States of America as Represented by the Secretary of the Navy
    Inventors: Michael E. Wright, Roxanne L. Quintana
  • Publication number: 20150080625
    Abstract: Described herein are processes and related devices and systems for the conversion of higher hydrocarbons, such as in the form of waste plastics, petroleum sludge, slope oil, vegetable oil, and so forth, into lower hydrocarbons, which can be used as fuels or raw materials for a variety of industrial and domestic uses.
    Type: Application
    Filed: November 20, 2014
    Publication date: March 19, 2015
    Inventors: Atul G. Kelkar, Prasad V. Bhat
  • Publication number: 20150080624
    Abstract: A process and apparatus for producing hydrocarbon oil from the thermal decomposition of waste plastics in a continuous process which comprises melting of a waste plastic feedstock into an auger assisted melt reactor to remove chlorine and organics contained in the waste plastic, and transferring the melted waste plastic into an heated screw pyrolysis reactor which includes a transitional metal heat transfer medium. The hydrocarbon gas from the pyrolysis reactor is fed into a vessel containing metal trays for a second decomposition which is connected with an alkali treatment 2-step process gas reactor to remove acidic gases, and any inorganic solids. The hydrocarbon gases are separated by three separate condensers. The hydrocarbon fraction of the first condenser is recycled back into the pyrolysis reaction for further thermal treatment, and the hydrocarbon fractions are collected in the remaining condensers.
    Type: Application
    Filed: September 15, 2014
    Publication date: March 19, 2015
    Inventors: Stephen B. Gephart, John C. Hill
  • Patent number: 8969638
    Abstract: A styrene monomer reclamation process and system is described. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream.
    Type: Grant
    Filed: September 28, 2011
    Date of Patent: March 3, 2015
    Assignee: Fina Technology, Inc.
    Inventors: Jon Tippet, James R. Butler, James Assef, John Ashbaugh, Jason Clark, Michel Duc, Jean-Bernard Cary
  • Patent number: 8957269
    Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: February 17, 2015
    Assignee: Stora Enso Oyj
    Inventors: Ali Harlin, Tapani Penttinen, Jari Räsänen, Olli Aaltonen
  • Publication number: 20150024277
    Abstract: An object of the present invention is to provide a carbonaceous material for a non-aqueous electrolyte secondary battery having excellent output characteristics and exhibiting excellent cycle characteristics, and a negative electrode using the same. The problem described above is solved by a carbonaceous material for a non-aqueous electrolyte battery having a true density of 1.4 to 1.7 g/cm3, an atom ratio (H/C) of hydrogen atoms to carbon atoms of at most 0.1, as determined by elemental analysis, an average particle size Dv50 of 3 to 35 ?m, a ratio Dv90/Dv10 of 1.05 to 3.00, and a degree of circularity of 0.50 to 0.95.
    Type: Application
    Filed: February 6, 2013
    Publication date: January 22, 2015
    Inventors: Mayu Komatsu, Yasuhiro Tada, Naohiro Sonobe
  • Patent number: 8927796
    Abstract: This invention discloses a process for making high viscosity index lubricating base oils having a viscosity index of at least 110 by co-feeding a ketone or a beta-keto-ester feedstock with a lubricant oil feedstock directly to a hydrocracking unit to produce a hydrocracked stream. Then at least a portion of the hydrocracked stream is treated under hydroisomerization conditions to produce a high viscosity index lubricating base oil. The process may involve bypassing a hydrotreating or hydrofinishing step, which may result in improved efficiency and economics in producing high viscosity index lubricating base oils.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: January 6, 2015
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stephan Joseph Miller, Sven Ivar Hommeltoft, Saleh Ali Elomari
  • Patent number: 8927797
    Abstract: The method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method can comprise the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. The method can include the step of comminuting the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1. The method can also include the step of adding an effective amount of a cracking catalyst to the waste plastic prior to step 2.
    Type: Grant
    Filed: February 2, 2011
    Date of Patent: January 6, 2015
    Assignee: Natural State Research, Inc.
    Inventor: Moinuddin Sarker
  • Patent number: 8921627
    Abstract: A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel or aviation boiling range fuel or fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is used as a non-flashing liquid quench stream to control the temperature of the hydrogenation and deoxygenation reactor.
    Type: Grant
    Filed: December 12, 2008
    Date of Patent: December 30, 2014
    Assignee: UOP LLC
    Inventors: Paul A. Sechrist, Robert L. Bunting, Jr., Nicholas W. Bridge
  • Publication number: 20140364663
    Abstract: A method of recycling a plastic includes decomposing the plastic in the presence of a catalyst to form hydrocarbons. The catalyst includes a porous support having an exterior surface and defining at least one pore therein. The catalyst also includes a depolymerization catalyst component disposed on the exterior surface of the porous support for depolymerizing the plastic. The depolymerization catalyst component includes a Ziegler-Natta catalyst, a Group IIA oxide catalyst, or a combination thereof. The catalyst further includes a reducing catalyst component disposed in the at least one pore.
    Type: Application
    Filed: December 21, 2012
    Publication date: December 11, 2014
    Inventor: Swaminathan RAMESH
  • Patent number: 8907150
    Abstract: A method of producing from a biomass mesitylene-isopentane fuel is provided. A biomass may be fermented to form acetone. The acetone is converted in a catalytic reactor to mesitylene and mesityl oxide. The mesitylene is separated in a phase separator and the organic face containing mesityl oxide is sent to a dehydration reactor, then to a demethylation reactor, and finally to a hydrogenation reactor from which isopentane is recovered. This isopentane is then mixed with the mesitylene to form the final mesitylene-isopentane fuel. The catalytic reaction with acetone employs catalysts of either niobium, vanadium or tantalum.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: December 9, 2014
    Assignee: Swift Fuels, LLC
    Inventor: John J. Rusek
  • Patent number: 8895790
    Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: November 25, 2014
    Assignee: Saudi Basic Industries Corporation
    Inventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan