From Synthetic Resin Or Rubber Patents (Class 585/241)
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Patent number: 12139676Abstract: Various embodiments of the present disclosure relate to methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil. The methods and system for producing refined hydrocarbons from waste plastic pyrolysis oil according to the embodiments of the present disclosure may minimize formation of an ammonium salt (NH4Cl) and may prevent an adhesion phenomenon of impurity particles in a reactor in a refining process of waste plastic pyrolysis oil containing impurities including chlorine and nitrogen. In addition, the methods and system for producing refined hydrocarbons according to embodiments of the present disclosure may have excellent refining efficiency and may implement a long-term operation of a process because deactivation of a catalyst used in the process is prevented, and may produce refined hydrocarbons having a low content of impurities and a low content of olefins, and solid coke, from waste plastic pyrolysis oil.Type: GrantFiled: February 7, 2024Date of Patent: November 12, 2024Assignees: SK INNOVATION CO., LTD., SK GEO CENTRIC CO., LTD.Inventors: Yong Woon Kim, Seo Yeong Kang, Soo Kil Kang, Min Gyoo Park, Young Moo Park, Min Woo Shin, Jae Hwan Lee, Jin Seong Jang, Sang Hwan Jo
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Patent number: 11952540Abstract: A method and apparatus for hydrocracking mineralized refuse pyrolysis oil. The method may use the following steps: (a) crushing and pyrolyzing mineralized refuse to obtain arene and alkane precursor biomass oil; (b) hydrogenating the arene and alkane precursor biomass oil obtained in step (a), and separating the obtained hydrocrackate to obtain arene and alkane; and (c) purifying, recovering and optimizing the arene and alkane obtained in step (b), and performing deep processing to produce naphtha, jet fuel, light diesel oil, and heavy diesel oil.Type: GrantFiled: June 16, 2020Date of Patent: April 9, 2024Assignee: East China University of Science and TechnologyInventors: Yulong Chang, Hualin Wang, Xia Jiang, Jianping Li, Jingyi Zhu, Pengbo Fu, Wei Yuan
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Patent number: 11939542Abstract: A system for processing plastic waste may include a feed line, a feed fractionator, a hydrotreater, a catalytic reforming unit, a heavy oil cracker, and a steam cracker. A pyrolyzed plastics feed is separated into light, medium, and heavy hydrocarbon streams. The hydrotreater removes sulfur, and the catalytic reforming unit produces a circular aromatic-rich stream. The heavy oil cracker generates cracked streams. The steam cracker produces a circular olefin stream from a cracked stream. A system for processing plastic waste may include the feed line, the feed fractionator, the hydrotreater, a medium hydrocarbon fractionator, the catalytic reforming unit, a full-range reforming unit, the heavy oil cracker, and the steam cracker. The medium hydrocarbon fractionator produces two hydrocarbon streams. The full-range naphtha reforming unit produces a second circular aromatic-rich stream.Type: GrantFiled: September 11, 2023Date of Patent: March 26, 2024Assignee: Chevron Phillips Chemical Company LPInventors: Bruce D. Murray, Scott G. Morrison, Kenneth Fountain, Steven R. Horlacher, Vincent D. Mcgahee, Reza Khankal, David Dockter
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Patent number: 11891519Abstract: Provided herein are asphalt compositions comprising asphalt, a carboxylated copolymer, a polyalkyleneimine, and a photoinitiator. The carboxylated copolymer present in the asphalt compositions can be a latex composition derived from a carboxylated styrene-butadiene copolymer. The carboxylated copolymer includes from 0.5% to 25% by weight carboxylic acid monomers. The carboxylated styrene-butadiene polymer and the asphalt can be present in a weight ratio of from 1:99 to 1:10. The polyalkyleneimine present in the asphalt compositions can be in an amount of greater than 0% to up to 10% by weight of the asphalt composition. The photoinitiator can include benzophenone and/or a derivative thereof. Tack coats meeting ASTM-D-977 standard comprising the asphalt compositions disclosed herein are also provided. The tack coat can have a tack-free time of 10 minutes or less. Methods of producing the asphalt compositions and tack coats are also disclosed.Type: GrantFiled: January 28, 2019Date of Patent: February 6, 2024Assignee: BASF SEInventors: Kostas S. Avramidis, James T. Andrews, William J. Kirk, Kimberly L. Walden, Arlis A. Kadrmas
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Patent number: 11879102Abstract: The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): ? · the coil outleType: GrantFiled: January 24, 2020Date of Patent: January 23, 2024Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Anthoni Van Zijl, Nicolas Goyheneix, Lara Galan-Sanchez, Christoph Roosen, Johan Pastwa, Safa Farajzadeh Bibalan
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Patent number: 11781073Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.Type: GrantFiled: November 8, 2022Date of Patent: October 10, 2023Assignee: Chevron Phillips Chemical Company LPInventors: Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray, Jacob M. Hilbrich, Charles T. Polito
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Patent number: 11739191Abstract: A system for continuously treating recycled polymeric material includes a hopper configured to feed the recycled polymeric material into the system. An extruder can turn the recycled polymeric material in a molten material. In some embodiments, the extruder uses thermal fluids, electric heaters, and/or a separate heater. The molten material is depolymerized in a reactor. In some embodiments, a catalyst is used to aid in depolymerizing the material. In certain embodiments, the catalyst is contained in a permeable container. The depolymerized molten material can then be cooled via a heat exchanger. In some embodiments, multiple reactors are used. In certain embodiments, these reactors are connected in series. In some embodiments, the reactor(s) contain removable static mixer(s) and/or removable annular inserts.Type: GrantFiled: June 29, 2021Date of Patent: August 29, 2023Assignee: GreenMantra Recycling Technologies Ltd.Inventors: Amalia Gil, Domenic Di Mondo, Radek Rybicki
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Patent number: 11530359Abstract: A method for producing a vapor stream from waste plastic comprises providing a waste plastic feedstock into a reactor containing one or more residues produced from a previously heated source of waste plastic, and heating the waste plastic feedstock in the reactor to a temperature from about 125° C. to 500° C. to generate a vapor containing one or more hydrocarbons. The waste plastic feedstock can have a calcium to sodium mass ratio from about 0.0001 to 400 as measured by inductively-coupled plasma (ICP) spectrometry. The catalytic activity in the reactor may be provided through one or more constituent elements in the waste plastic feedstock or the one or more residues produced from the previously heated source of waste plastic.Type: GrantFiled: December 16, 2020Date of Patent: December 20, 2022Assignee: WASTE TECHNOLOGIES, LLCInventors: Moinuddin Sarker, Anjuman Ara Begum
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Patent number: 11518942Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.Type: GrantFiled: September 28, 2021Date of Patent: December 6, 2022Assignee: Chevron Phillips Chemical Company LPInventors: Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray, Jacob M. Hilbrich, Charles T. Polito
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Patent number: 11365357Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: GrantFiled: May 22, 2020Date of Patent: June 21, 2022Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Patent number: 11326039Abstract: An embodiment provides a method for recycling tires, including: injecting, using a pump, a rubber material into a dissociating system, wherein the pump exerts a mechanical force upon the rubber material to reduce a size of the rubber material; within the dissociating system, creating a rubber material mixture, by: injecting a supercritical fluid to be mixed with the rubber material; heating, using a heat source, the rubber material mixture; and atomizing the rubber material mixture; and sending the resulting atomized rubber material mixture to a separating system to separate the rubber material mixture into different components. Other aspects are described and claimed.Type: GrantFiled: January 5, 2018Date of Patent: May 10, 2022Assignee: SMART TIRE RECYCLING, INC.Inventor: Abdulhaq Alkhalidi
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Patent number: 11279631Abstract: A method for purifying an aqueous mixture is provided. The method can include at least partially crystallizing an aqueous mixture derived from a hydrocarbon process to provide a crystallized aqueous mixture. The aqueous mixture can comprise water and one or more contaminants to be separated from the water. The crystallized aqueous mixture can be separated into a contaminant-rich fraction and a water-rich fraction. Water can be recovered from the water-rich fraction and the one or more contaminants can be recovered from the contaminant-rich fraction.Type: GrantFiled: December 3, 2013Date of Patent: March 22, 2022Assignee: EFC Solutions Inc.Inventor: James D. Wrubel
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Patent number: 11220633Abstract: A continuous process for the cracking of a polymeric material, includes the continuous introduction of the polymeric material in a stream or bath of molten catalyst. A plant for the cracking of a polymeric material is also related and includes a closed circuit/environment containing a molten catalyst, and an element adapted to keep the molten catalyst in continuous motion.Type: GrantFiled: June 28, 2017Date of Patent: January 11, 2022Assignee: BIORENOVA SOCIETA' PER AZIONIInventors: Riccardo Reverso, Emanuele D'Abbondanza
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Patent number: 11180699Abstract: A system for producing primarily diesel with some heavy fuel from plastic feedstock is described. The feedstock is received into a pyrolizer. There are two zones in the pyrolizer—one where the temperature is elevated during conveyance, and a second where the temperature is maintained. A distillation vessel receives fuel oils from the pyrolizer and agitates the oils at high temperature. A hydrogenation vessel then mixes the fuel liquid with H2 at a high pressure while recirculating to and from an expansion vessel to create converted fuel oil. A diesel distillation tank receives the converted fuel oil and creates diesel gas, which is then condensed to form a usable diesel product. Any remaining fuel oil is sent the heavy fuel oil tank.Type: GrantFiled: June 30, 2020Date of Patent: November 23, 2021Assignee: Gen Tech PTD, LLCInventor: Richard A. Bingham
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Patent number: 11104851Abstract: Methods for depolymerization of a plastic polymer. An embodiment includes supplying a plastic polymer and aromatic bottoms from an aromatic recovery complex, the aromatic bottoms comprising C9+ aromatic compounds; dissolving the plastic polymer in the aromatic bottoms to obtain a dissolved plastic polymer solution comprising dissolved plastic polymer and C9+ aromatic compounds; and catalytically cracking the dissolved plastic polymer solution in the presence of a catalyst such that the dissolved plastic polymer and the C9+ aromatic compounds are cracked to obtain light products.Type: GrantFiled: January 29, 2020Date of Patent: August 31, 2021Inventors: Omer Refa Koseoglu, Robert Peter Hodgkins
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Patent number: 10947144Abstract: A Biorefinery System (BIOSYS) that effectively treats all human activity-derived waste (black water, grey water, and food waste streams) using biological systems and that produces as process by-products: recovered potable water, liberated free oxygen, edible protein cake (with and without lipids), soil amendments, and machinery lube oils. Additionally, the system captures and chemically binds carbon dioxide into microbial cells and associated by-products, thus producing recovered usable returned cabin air.Type: GrantFiled: October 14, 2019Date of Patent: March 16, 2021Assignee: University of Louisiana at LafayetteInventors: Mark E. Zappi, Daniel Gang, Emmanuel Revellame, Andrei Chistoserdov, Rafael Hernandez, Rakesh Bajpai, Wayne Sharp, Dhan Fortela
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Patent number: 10906209Abstract: The disclosed invention describes a novel approach to the utilization of the fine mineral matter derived from coal and/or coal refuse (a by-product of coal refining) to convert a non-biodegradable plastic into a biodegradable plastic. The fine mineral matter could also be based on volcanic basalt, glacial rock dust deposits, iron potassium silicate and other sea shore mined deposits. The conversion of the non-biodegradable plastic into biodegradable plastic in soil further increases nutrients availability in soil with the transition metals released as a result of biodegradation of the biodegradable plastic.Type: GrantFiled: September 16, 2019Date of Patent: February 2, 2021Assignee: Radical Plastics, Inc.Inventor: Yelena Kann
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Patent number: 10858593Abstract: A process for producing cumene comprising converting plastics to hydrocarbon liquid and pyrolysis gas; feeding hydrocarbon liquid to hydroprocessor to yield hydrocarbon product and first gas stream; feeding hydrocarbon product to reforming unit to produce reforming product, second gas stream, and hydrogen; separating reforming product into non-aromatics recycle stream and second aromatics stream (C6+ aromatics); recycling non-aromatics recycle stream to reforming unit; separating second aromatics stream into benzene, C7, C8, C9, C10, and C11+ aromatics; contacting C7, C9, and/or C10 aromatics with a disproportionation&transalkylation catalyst/H2 to yield benzene&xylenes; conveying C11+ aromatics to hydroprocessor; introducing pyrolysis gas, first and/or second gas stream to first separator to produce first propylene stream, first C2&C4 unsaturated stream, and saturated gas (H2 and C1-4 saturated hydrocarbons); introducing first C2&C4 unsaturated stream to metathesis reactor to produce second pType: GrantFiled: January 3, 2018Date of Patent: December 8, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Krishna Kumar Ramamurthy, Ravichander Narayanaswamy, Venkata Ramanarayanan Ganapathy Bhotla, Alexander Stanislaus, Santosh Ganji
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Patent number: 10703983Abstract: A method of processing of shredded rubber-containing waste involves its preliminary preparation, thermal decomposition in a furnace, separation of decomposition products into vapor-gas mixture and solid residue, and separation of a heavy hydrocarbon fraction from the vapor-gas mixture. Preliminary preparation of the waste is carried out by its blowing with water vapor until a waste temperature reaches 100° C., and thermal decomposition is carried out in residual oil in the starting phase, and afterwards in the atomized generated heavy hydrocarbon fraction and superheated water vapor, their weight ratio being (0.1-0.5):1. The heavy hydrocarbon fraction is separated from the vapor-gas mixture with water by atomizing it into the vapor-gas mixture flow at the rate of 5-15% of the mass flow rate of the mixture, while metal is extracted from the solid residue by magnetic separation, after which a product containing zinc oxide is separated by dielectric separation.Type: GrantFiled: August 21, 2019Date of Patent: July 7, 2020Inventor: Sergei P. Susekov
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Patent number: 10549455Abstract: The disclosed invention describes a novel approach to the utilization of the fine mineral matter derived from coal and/or coal refuse (a by-product of coal refining) to convert a non-biodegradable plastic into a biodegradable plastic. The fine mineral matter could also be based on volcanic basalt, glacial rock dust deposits, iron potassium silicate and other sea shore mined deposits. The conversion of the non-biodegradable plastic into biodegradable plastic in soil further increases nutrients availability in soil with the transition metals released as a result of biodegradation of the biodegradable plastic.Type: GrantFiled: March 6, 2019Date of Patent: February 4, 2020Assignee: Radical Plastics Inc.Inventor: Yelena Kann
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Patent number: 10537876Abstract: Use of a catalytic composition parameters comprising oxides of aluminum or oxidic compounds comprising aluminum and silicon with a molar ratio of aluminum to silicon of more than 1 in a process for the catalytic depolymerization of plastics waste.Type: GrantFiled: December 15, 2016Date of Patent: January 21, 2020Assignee: SOLVAY SAInventors: Stéphane Streiff, Marco Piccinini, Armin T. Liebens, Avelino Corma, Miriam Cerro-Alarcón, Jesús Mengual
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Patent number: 10457886Abstract: A process for converting a molten polymeric material is provided. The process includes effecting disposition of a molten polymeric material, having at least one carbon-carbon double bond, in sufficient proximity to a catalyst material within a reaction zone, to affect a reactive process that effects generation of a reaction product. The reactive process effects cleaving of at least one carbon-carbon double bond. The catalyst material includes [Fe—Cu—Mo—P]/Al2O3 prepared by binding a ferrous-copper complex to an alumina support to generate an intermediate material and reacting the intermediate material with a heteropolyacid.Type: GrantFiled: June 5, 2018Date of Patent: October 29, 2019Assignee: GreenMantra Recycling Technologies Ltd.Inventors: Anil Kumar, Pushkar Kumar
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Patent number: 10428277Abstract: A device for processing scrap rubber has a reactor with a screw conveyor disposed inside a heating chamber, a thermal decomposition unit, burners, a condenser, a cyclone filter, and devices for discharging solid residue and removing a gas-vapor mixture. The reactor has two sections connected in parallel. The thermal decomposition unit has screw conveyors in each section, the conveyors have axial heating pipes with a coil. Along the length of the conveyors plates are arranged at the corners of an equilateral triangle in contact with and perpendicular to the side surface of the heating tube. A cylinder furnace with an evaporator and a burner is connected to the ends of the pipes. An outlet of the condenser is connected to a liquid fraction separator, inlets of the coils are connected to an outlet of the evaporator, and an inlet of the evaporator is connected to an outlet from the separator.Type: GrantFiled: May 15, 2019Date of Patent: October 1, 2019Assignee: OOO “Nauchno-Proizvodstvennoe Obedinenie Innovatekh”Inventors: Aleksei S. Gradov, Evgeny S. Susekov, Sergei P. Susekov
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Patent number: 10358603Abstract: A method for producing fuels such as liquid and solid fuels from waste materials comprising rubber or plastic waste, is disclosed. The method comprises the steps of: (a) grounding said waste material into chips or flakes, (b) transferring the chips or flakes via a transmission system to a viscous fluid disorder tank, (c) introducing a catalyst to the transferred chips or flakes in the tank, (d) heating the chips or flakes with catalyst using a heating jacket or a coil in a reservoir of the tank at a predetermined temperature, (e) mixing the molten chips or flakes with catalyst using a helical butterfly stirrer inside the reservoir at a predetermined time and temperature to decompose the waste material, and (f) filtering the decomposed waste material to produce the fuel. This method is simple, quick and economical for producing different characteristics of fuel without any environmental lesions and contamination.Type: GrantFiled: February 14, 2018Date of Patent: July 23, 2019Inventor: Somayeh Shayesteh Pour
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Patent number: 10332226Abstract: A parcel of land on which to site the plant is identified. The parcel of land is located such that about 3,500,000 to about 7,500,000 scrap tires per year are available for substantially regular and substantially continuous delivery to the plant, at a tipping fee of at least about $40.00 per ton. The plant is located on the parcel of land. One or more of synthesis gas, electricity, and steam produced by the plant are sold.Type: GrantFiled: July 29, 2009Date of Patent: June 25, 2019Assignee: GREENTIRE ENERGY LLCInventors: Jerome N. Block, Ulf Hansson, Nicholas Z. Hegedus
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Patent number: 9714385Abstract: The present invention relates to a process for the conversion of a low molecular weight polymeric byproduct obtained during production of high density polyethylene (HDPE), commonly known as low polymer wax (LPW) or polymer mud, into different products like different grades of paraffin wax, microcrystalline wax, lube and grease base stocks by a process comprising of thermal treatment in an inert atmosphere in the presence of organic peroxides or hydroperoxides and metal oxides. The end product depends upon the suitable selection of various process parameters like type of peroxides or hydroperoxides, metal oxides, temperature and duration of reaction.Type: GrantFiled: December 18, 2015Date of Patent: July 25, 2017Assignee: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCHInventors: Hayat Ullah Khan, Manisha Sahai, Sanat Kumar, Ajay Kumar, Gananath Doulat Thakre, Savita Kaul, Shrikant Madhusudan Nanoti, Bal Mukand Shukla, Madhukar Onkarnath Garg, Paulose Anthony Thrissokaran, Ajit Kumar Chaturvedi
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Patent number: 9556319Abstract: A process for devulcanizing EPDM rubber comprising the step of introducing sulfur-cured EPDM to an extruder, introducing from about 0.5 to about 20 wt % scavenging agent, based upon the total weight of the EPDM and scavenging agent, and mixing and masticating the EPDM at a temperature sufficient to at least partially devulcanize the sulfur-cured EPDM.Type: GrantFiled: September 27, 2013Date of Patent: January 31, 2017Assignee: Firestone Building Products Co., LLCInventors: Hao Wang, Michael J. Hubbard
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Patent number: 9394487Abstract: A multi-stage process and system for converting solid particulate biomass in a riser reactor having at least two different reaction zones. A lower reaction zone is configured to optimize pyrolysis of the biomass into pyrolysis products, while an upper reaction zone is configured to efficiently crack the pyrolysis products. The relative residence times and/or temperatures of the upper and lower reaction zones can be controlled to optimize product quality and yield.Type: GrantFiled: July 22, 2011Date of Patent: July 19, 2016Assignee: Inaeris Technologies, LLCInventors: Neil Wang, Liang Chen, Peter Loezos
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Patent number: 9212318Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.Type: GrantFiled: July 23, 2013Date of Patent: December 15, 2015Assignee: Saudi Basic Industries CorporationInventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
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Patent number: 9096801Abstract: A process and plant for the thermocatalytic conversion of waste materials into reusable fuels and a fuel produced by the process, involving the steps of delivering melted waste material (11) to one or more pyrolysis chambers (26) via heated and valved manifolds (22) and effecting pyrolysis of the waste material into a gascous state in an oxygen purged and pressure controlled environment. Pyrolytic gases are, then transferred to a catalytic converter (29) where the molecular structure of the gaseous material is altered in structure and form, with gases then transferred to one or more condensers (30a) to distil and cool gases in to their respective fractions. After post pyrolysis treatment, fuel fractions thon form a useable fuel.Type: GrantFiled: March 11, 2005Date of Patent: August 4, 2015Assignee: FUTURE ENERGY INVESTMENTS PTY LTDInventor: Garry Baker
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Publication number: 20150141605Abstract: Processes for forming propylene from methanol are disclosed. The processes involve converting methanol to a product mixture comprising ethylene and propylene, separating the ethylene from the propylene, dimerizing a first portion of the ethylene to form a product mixture comprising 1-butylene, isomerizing the 1-butylene to form a mixture of cis and trans 2-butylene, and performing olefin metathesis on a second portion of the ethylene and the mixture of cis and trans 2-butylene. In one embodiment, the methanol is produced by converting syngas to methanol, and in one aspect of this embodiment, the syngas, or a portion thereof, is produced from renewable feedstocks. In this aspect, renewable propylene is produced. The propylene can be polymerized to form polypropylene or co- or terpolymers thereof, and when the propylene is made from renewable resources, the resulting polymer is a renewable polymer.Type: ApplicationFiled: May 3, 2013Publication date: May 21, 2015Inventor: David Bradin
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Patent number: 9024096Abstract: A process for converting triacylglycerides-containing oils into crude oil precursors and/or distillate hydrocarbon fuels is disclosed. The process may include reacting a triacylglycerides-containing oil-carbon dioxide mixture at a temperature in the range from about 250° C. to about 525° C. and a pressure greater than about 75 bar to convert at least a portion of the triacylglycerides to a hydrocarbon or mixture of hydrocarbons comprising one or more of isoolefins, isoparaffins, cycloolefins, cycloparaffins, and aromatics.Type: GrantFiled: December 11, 2012Date of Patent: May 5, 2015Assignee: Lummus Technology Inc.Inventor: Marvin I. Greene
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Patent number: 9005401Abstract: A system for tire distillation including an upper chamber, a first conveyor configured to transport a tire through the upper chamber, a lower chamber located beneath the upper chamber, the lower chamber that includes an ultrasonic purge chamber configured to radiate the tire with ultrasonic radiation, a microwave radiation chamber configured to radiate the tire with microwave radiation, and a second conveyor configured to transport the tire from the ultrasonic purge chamber to the microwave radiation chamber. The system further includes a vacuum system configured to maintain an atmosphere in the ultrasonic purge chamber and the microwave radiation chamber under a vacuum wherein the tire is preheated during conveyance through the upper chamber from heat produced in the lower chamber.Type: GrantFiled: February 17, 2010Date of Patent: April 14, 2015Assignee: Infinite Earth, Inc.Inventor: James C. Johnson
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Patent number: 9006505Abstract: A method for processing plastic waste, in particular polyolefins, and a device for processing plastic waste, in particular polyolefins, are used especially in the industrial utilization of plastic waste. The method consists in that a primarily refined charge after being fed into a reactor (6) is fluidized and cracked during forced progressive-rotational movement coinciding with heating. A gas-steam fraction obtained during a utilization process is continuously guided out to a cooling system whereas impurities are periodically guided out from the reactor (6) to a waste tank (22).Type: GrantFiled: April 9, 2009Date of Patent: April 14, 2015Assignee: Przedsiebiorstwo EKONAKS Sp. z o. o.Inventor: Wojciech Najman
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Publication number: 20150099285Abstract: The present invention relates to systems and methods for producing energy. Specifically, the present invention relates to systems and methods for producing energy, such as energy in the form of electricity, and fuels, such as, for example, biodiesel and/or cellulosic ethanol in a small scale energy center. Moreover, the systems and methods of the present invention provide for recovery of materials, such as in soil production and/or recycling.Type: ApplicationFiled: August 18, 2014Publication date: April 9, 2015Inventors: Steven M. Clements, Richard L. Clements
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Publication number: 20150094503Abstract: A hydropyrolysis catalyst and a process using that catalyst are described. The catalyst comprises a support and an active metal component wherein the catalyst is an eggshell type catalyst having the active metal component located in the outer portion of the support.Type: ApplicationFiled: November 12, 2012Publication date: April 2, 2015Inventors: Alan Anthony Del Paggio, Lawrence Stephen Kraus, Michael John Roberts, Celeste Jean McLeod, Terry Louise Marker, Larry Gordon Felix, Martin Brendan Linck
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Publication number: 20150087871Abstract: A method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method comprises in broad embodiments the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. In some preferred embodiments, the method includes the step of commutating the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1.Type: ApplicationFiled: December 3, 2014Publication date: March 26, 2015Inventor: Moinuddin Sarker
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Patent number: 8987539Abstract: Acyclic monterpene alcohols, like linalool, to be converted through a series of highly efficient catalytic reactions a biogasoline blending component, and a drop-in biodiesel fuel.Type: GrantFiled: September 10, 2012Date of Patent: March 24, 2015Assignee: The United States of America as Represented by the Secretary of the NavyInventors: Michael E. Wright, Roxanne L. Quintana
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Publication number: 20150080625Abstract: Described herein are processes and related devices and systems for the conversion of higher hydrocarbons, such as in the form of waste plastics, petroleum sludge, slope oil, vegetable oil, and so forth, into lower hydrocarbons, which can be used as fuels or raw materials for a variety of industrial and domestic uses.Type: ApplicationFiled: November 20, 2014Publication date: March 19, 2015Inventors: Atul G. Kelkar, Prasad V. Bhat
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Publication number: 20150080624Abstract: A process and apparatus for producing hydrocarbon oil from the thermal decomposition of waste plastics in a continuous process which comprises melting of a waste plastic feedstock into an auger assisted melt reactor to remove chlorine and organics contained in the waste plastic, and transferring the melted waste plastic into an heated screw pyrolysis reactor which includes a transitional metal heat transfer medium. The hydrocarbon gas from the pyrolysis reactor is fed into a vessel containing metal trays for a second decomposition which is connected with an alkali treatment 2-step process gas reactor to remove acidic gases, and any inorganic solids. The hydrocarbon gases are separated by three separate condensers. The hydrocarbon fraction of the first condenser is recycled back into the pyrolysis reaction for further thermal treatment, and the hydrocarbon fractions are collected in the remaining condensers.Type: ApplicationFiled: September 15, 2014Publication date: March 19, 2015Inventors: Stephen B. Gephart, John C. Hill
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Patent number: 8969638Abstract: A styrene monomer reclamation process and system is described. The styrene monomer reclamation process includes providing a waste plastic. The waste plastic includes styrenic polymers. The waste plastic is formed into polymer particles. At least a portion of the polymer particles are dissolved in a solvent to form a polymer stream. The dissolved polymer particles are depolymerized to form a styrene monomer stream.Type: GrantFiled: September 28, 2011Date of Patent: March 3, 2015Assignee: Fina Technology, Inc.Inventors: Jon Tippet, James R. Butler, James Assef, John Ashbaugh, Jason Clark, Michel Duc, Jean-Bernard Cary
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Patent number: 8957269Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.Type: GrantFiled: January 29, 2010Date of Patent: February 17, 2015Assignee: Stora Enso OyjInventors: Ali Harlin, Tapani Penttinen, Jari Räsänen, Olli Aaltonen
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Publication number: 20150024277Abstract: An object of the present invention is to provide a carbonaceous material for a non-aqueous electrolyte secondary battery having excellent output characteristics and exhibiting excellent cycle characteristics, and a negative electrode using the same. The problem described above is solved by a carbonaceous material for a non-aqueous electrolyte battery having a true density of 1.4 to 1.7 g/cm3, an atom ratio (H/C) of hydrogen atoms to carbon atoms of at most 0.1, as determined by elemental analysis, an average particle size Dv50 of 3 to 35 ?m, a ratio Dv90/Dv10 of 1.05 to 3.00, and a degree of circularity of 0.50 to 0.95.Type: ApplicationFiled: February 6, 2013Publication date: January 22, 2015Inventors: Mayu Komatsu, Yasuhiro Tada, Naohiro Sonobe
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Patent number: 8927796Abstract: This invention discloses a process for making high viscosity index lubricating base oils having a viscosity index of at least 110 by co-feeding a ketone or a beta-keto-ester feedstock with a lubricant oil feedstock directly to a hydrocracking unit to produce a hydrocracked stream. Then at least a portion of the hydrocracked stream is treated under hydroisomerization conditions to produce a high viscosity index lubricating base oil. The process may involve bypassing a hydrotreating or hydrofinishing step, which may result in improved efficiency and economics in producing high viscosity index lubricating base oils.Type: GrantFiled: September 13, 2012Date of Patent: January 6, 2015Assignee: Chevron U.S.A. Inc.Inventors: Stephan Joseph Miller, Sven Ivar Hommeltoft, Saleh Ali Elomari
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Patent number: 8927797Abstract: The method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method can comprise the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. The method can include the step of comminuting the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1. The method can also include the step of adding an effective amount of a cracking catalyst to the waste plastic prior to step 2.Type: GrantFiled: February 2, 2011Date of Patent: January 6, 2015Assignee: Natural State Research, Inc.Inventor: Moinuddin Sarker
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Patent number: 8921627Abstract: A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel or aviation boiling range fuel or fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is used as a non-flashing liquid quench stream to control the temperature of the hydrogenation and deoxygenation reactor.Type: GrantFiled: December 12, 2008Date of Patent: December 30, 2014Assignee: UOP LLCInventors: Paul A. Sechrist, Robert L. Bunting, Jr., Nicholas W. Bridge
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Publication number: 20140364663Abstract: A method of recycling a plastic includes decomposing the plastic in the presence of a catalyst to form hydrocarbons. The catalyst includes a porous support having an exterior surface and defining at least one pore therein. The catalyst also includes a depolymerization catalyst component disposed on the exterior surface of the porous support for depolymerizing the plastic. The depolymerization catalyst component includes a Ziegler-Natta catalyst, a Group IIA oxide catalyst, or a combination thereof. The catalyst further includes a reducing catalyst component disposed in the at least one pore.Type: ApplicationFiled: December 21, 2012Publication date: December 11, 2014Inventor: Swaminathan RAMESH
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Patent number: 8907150Abstract: A method of producing from a biomass mesitylene-isopentane fuel is provided. A biomass may be fermented to form acetone. The acetone is converted in a catalytic reactor to mesitylene and mesityl oxide. The mesitylene is separated in a phase separator and the organic face containing mesityl oxide is sent to a dehydration reactor, then to a demethylation reactor, and finally to a hydrogenation reactor from which isopentane is recovered. This isopentane is then mixed with the mesitylene to form the final mesitylene-isopentane fuel. The catalytic reaction with acetone employs catalysts of either niobium, vanadium or tantalum.Type: GrantFiled: August 25, 2011Date of Patent: December 9, 2014Assignee: Swift Fuels, LLCInventor: John J. Rusek
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Patent number: 8895790Abstract: A catalyst composition useful for producing olefins and aromatic compounds from a feedstock is formed from a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % or more by total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. The catalyst composition may be used in a method of producing olefins and aromatic compounds from a feedstock by introducing a hydrocarbon feedstock and the catalyst composition within a reactor, at least a portion of the reactor being at a reactor temperature of 550° C. or higher. The feedstock and catalyst composition are introduced into the reactor at a catalyst-to-feed (C/F) ratio of from 6 or greater.Type: GrantFiled: February 12, 2013Date of Patent: November 25, 2014Assignee: Saudi Basic Industries CorporationInventors: Ravichander Narayanaswamy, Krishna Kumar Ramamurthy, P. S. Sreenivasan
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Patent number: 8877992Abstract: Conversion of waste and other organic feedstock into sustainable energy, feed, fertilizer, and other useful products of reliable purities is accomplished using water, heat, and pressure. More specifically, the invention provides methods and apparatus that handle mixed streams of various feedstocks, e.g. agricultural waste, biological waste, municipal solid waste, municipal sewage sludge, and shredder residue, to yield gas, oil, specialty chemicals, and carbon solids that can be used as is or are further processed. Useful products can be diverted at various points of the process or internalized to enhance the efficiency of the system.Type: GrantFiled: June 17, 2008Date of Patent: November 4, 2014Assignee: AB-CWT LLCInventors: Brian S. Appel, Terry N. Adams, James H. Freiss, Craig T. Einfeldt, William F. Lange, Shannon M. Jones