Abstract: Plastic scrap, especially of polyolefin plastics, is converted to low pour point oils by thermal cracking in the liquid phase followed by catalytic conversion of the vaporous cracking products over an intermediate pore size zeolite such as ZSM-5.

Abstract: Pyrolytic reprocessing of plastic, rubber, or other hydrocarbon materials in which the resultant pyrolysis gas is brought in a cooling stage to a temperature just above the freezing point of water and to a pressure of approximately 0.8 to 1.4 bar of overpressure. The resultant condensate is then separated and heated to a normal storage temperature and the super atmospheric pressure on the condensate reduced to atmospheric pressure. The gas produced thereby comprising C.sub.4 hydrocarbon compounds is supplied to the pyrolysis process as special product gas. By means of this provision, the proportion of aromatic compounds in the pyrolysis gas is raised substantially.

Abstract: A process for the treatment of used rubber tires by vacuum pyrolysis in a reactor to produce liquid and gaseous hydrocarbons and a solid carbonaceous material is disclosed. According to the invention, the pyrolysis of the tires is carried out at a temperature in the range of about 360.degree. C. to about 415.degree. C., under a sub-atmospheric pressure of less than about 35 mm Hg and such that gases and vapors produced in the reactor have a residence time of the order of a few seconds. The process according to the invention enables one to increase the yield of the liquid hydrocarbons and lower the yields of the gaseous hydrocarbons and solid carbonaceous material, and to thereby produce hydrocarbon oils in substantially maximum yield. These hydrocarbon oils have a high calorific value and are thus suitable for use as heating fuel.

Abstract: Apparatus is disclosed for the thermal decomposition or pyrolysis of shredded vehicle tires. Interially of a pyrolysis chamber is mounted a hollow shaft which carries on at least a portion of its outer surface, a conveyor flight and a plurality of partial flights which compact, mix and stir the rubber shreds during the decomposing cycle. Undecomposed rubber, fiberglass, carbon and metal products are collected at the end of the decomposition chamber and the gaseous products of decomposition are separately collected and sent through a fractionator. Externally of the decomposition chamber is a screen type magnetic separator which removes the magnetic susceptible metal particles and the carbon passes through the rotating cylindrical screen. Undecomposed rubber, fiberglass and the like are removed from the screen and separately treated.

Abstract: A polymeric material containing solids in the form of metal and/or cord lumps is partially thermally decomposed to produce a suspension of the polymeric material containing solids in the form of metal and/or cord lumps. Then, the suspension with the solids is directed to a separator, which may be an inclined conveyor, where the solids and the suspension are separated. The separated polymeric material then is thermally decomposed completely. In the separator, the separated solids may be treated by flushing the solids on the conveyor with a preheated solvent, followed by applying steam to the solids and finally drying the solids on the conveyor. Thermal decomposition of the separated polymeric material is completed in a vertical distillation column having a lower liquid phase and an upper vapor-gas phase.

Abstract: A process for economically recovering carbon black, oil and fuel gas from vehicle tires is disclosed, for either whole tires or physically fragmented tires. The tires are washed to remove dirt and road film. The clean tires are dried and preheated with super-heat steam. The hot tires are pyrolyzed to partially devolatize a major portion of the hydrocarbons and produce a char that can be separated from the steel and fiber glass. The char is subsequently pyrolyzed with microwaves that elevate the tire temperature and devolatize the remaining hydrocarbons from the char as gas. The hot gases are cooled and partially condensed. The uncondensed gas is used as fuel. The condensed oil is sent to storage. The solid residue from the tire pyrolysis is char, fiberglass and steel. The char is mechanically separated from the glass and steel. The char is milled to break down agglomerates and subsequently pelletized and bagged. The steel and glass are discarded as trash.

Abstract: A process for the production of liquid hydrocarbons from old tires, cable wastes, polyethylene wastes and/or polypropylene wastes, by which the waste products, in pulverized form, are treated at a temperature of 150.degree. to 500.degree. C. and a pressure 20 to 300 bar with a solvent which is liquid at 1 bar and 20.degree. C. to form a solvent phase charged with liquid hydrocarbons and a residue phase. The charged solvent phase is separated from the residue, and the separated charged solvent phase is resolved into its components by lowering of pressure and/or temperature, and by distillation.

Abstract: This invention relates to an apparatus and a method for pyrolytic decomposition of polymeric materials into lower molecular weight products involving the heat treatment of raw polymeric material within reactive conduits submerged in a fluidized bed furnace operated at pyrolizing temperatures.

Abstract: Method for traveling fluidized bed distillation of coarse ground tire scrap, rubber vulcanizate (also vulcanized rubber), in a mixture with coarse aggregate. The rubber and aggregates are charges to a vertical still equipped with power burners near the bottom to burn a portion of the carbonaceous residue and supply the needed heat for the distillation process. The volatile materials and the pyrolysis oil vapors are drawn at the top for recovery and processing. Fines are recovered and the aggregate still at elevated temperatures are recycled to the top of the column and reused again with additional ground rubber. Noncondensable gases resulting from the "pyrolysis oil" condensation and recovery system contain high heating value and can be used for combustion needs in the still, or for steam generation.

Abstract: Plastic scraps are subjected to thermal decomposition in the presence of zeolite type catalyst and converted into a liquid hydrocarbon oil.

Abstract: An apparatus comprises a reaction chamber provided with a charging hole, a branch pipe for discharging a suspension, and a branch pipe for withdrawing a vapor-gas phase which branch pipe is communicated with a condenser. The apparatus further includes a heater provided with a heat-exchanger for preheating a solvent, said heat-exchanger being introduced into said heater and communicated with said reaction chamber through nozzles adapted for jet feeding of the solvent into the reaction mass.At the outlet of the reaction chamber there is mounted a distillation column communicated with the branch pipe for discharging the suspension and provided in the upper portion thereof with a branch pipe for withdrawal of the vapor-gas phase, while in the lower portion thereof there is provided a branch pipe for discharging a distillation residue.

Abstract: The invention relates to a process for improving the pyrolytic conversion of waste selected from rubber and plastic to low molecular weight olefinic materials by employing basis salt catalysts in the waste mixture. The salts comprise alkali or alkaline earth compounds, particularly sodium carbonate, in an amount of greater than about 1 weight percent based on the waste feed.

Abstract: Pyrolytic apparatus for recycling discarded rubber tires and the like that includes an auto clave shell that is closed at both ends to provide a closed vessel and has an interior refractory lining enclosing a reactor chamber and in conjunction with the vessel forms a gas-oil separation chamber surrounding the lining, heat exchangers within the lining, burners exterior of the vessel for conducting heat to the heat exchangers, a compressor for withdrawing pyrolytic gas given off by the pyrolytic decomposition of tires in the reactor chamber and conducting it to a recovered gas storage tank and a line for conducting oil given off by the decomposition of tires in the reactor chamber to an oil storage tank. The vessel walls are of a sufficiently lower temperature than that in the reactor chamber that the oil condenses on the vessel walls.

Abstract: A method is provided for the continuous processing of coarse-grained waste rubber into a secondary rubber raw material, in which coarse-grained waste rubber having a particle size of 0.5 to 15 mm, preferably approx. 4 to 6 mm, in a layer of a thickness not exceeding the largest dimension of a single grain is exposed to a thermoshock without the access of oxygen at a temperature of 200.degree. to 900.degree.C., preferably 600.degree. to 800.degree. C., for a time of 5 to 200 seconds, preferably about 30 to 60 seconds, depending on the size of the particles and the desired structure of the product.

Abstract: Vulcanizable rubber stock based on diene rubber comprises oxidized oligomer derived from thermally decomposed rubber materials, which oligomer has a molecular weight of 450-86,000 and is contained in the compound in an amount of 5-68 parts by weight per 100 parts by weight of diene rubber.

Abstract: A process for the preparation of fuel oil, fuel gas and pyrolysis coke by heating to a temperature of 600.degree.-700.degree. C. a mixture of rubber, synthetic resin, brown coal and bentonite.

Abstract: An improvement in a process for the pyrolytic conversion of rubber and plastic waste to hydrocarbon products which results in reduced levels of nitrogen and sulfur impurities in these products. The improvement comprises pyrolyzing the waste in the presence of at least about 1 weight percent of salts, based on the weight of the waste, preferably chloride or carbonate salts, of zinc or copper (I).This invention was made under contract with or subcontract thereunder of the Department of Energy Contract #DE-AC02-78-ER10049.

Abstract: A process for the preparation of modified pitches and low boiling aromatics and olefins is described. Waste plastic which consists of polymeric chains of olefins is subjected to a thermal treatment in the presence of high boiling aromatics. The modified pitches may be used for the production of carbon articles of high value.

Abstract: A process for decomposing vulcanized rubber which comprises swelling 100 parts by weight of vulcanized rubber with 10-3000 parts by weight of an organic solution, and adding and mixing 0.1-20 parts by weight of an organic hydroperoxide (a) and of 0.001-1 mole equivalent per said (a) of at least one member (b) selected from the group consisting of copper salts, cobalt salts, and strongly alkaline compounds.

Abstract: An apparatus for pyrolyzing shredded tires including an oven having a discharge opening and a tote having a discharge snout corresponding to the opening, the tote being placed in the oven with the snout inserted into the opening, radiant heating tubes are provided in the oven in close proximity to the top and bottom of the tote to heat the shredded tires, the tote having an inclined top for directing gaseous vapors produced on heating the tires toward the snout, the gaseous vapors are drawn through a discharge duct assembly and condenser by a fan located at the exhaust from the condenser.

Abstract: A process and apparatus for recovering the material components of rubber tires, the process including the steps of shredding the rubber tires to a size capable of being transported, heating the shredded rubber pieces in an inert atmosphere to a temperature sufficient to vaporize the heat recoverable components of the tires, condensing the vaporizable components to liquify the oil and ammonia present, collecting the uncondensed gas, and recovering the carbon residue and metal remaining after cooling. The apparatus including a hot air oven having a plurality of hot air conduits defining a primary heating zone and a top wall configuration defining a gas collection zone and a tote bin formed by a closed container having an opening at one end and a top wall configuration conforming to the top wall of the oven.

Abstract: A method of making either a softener for rubber mixtures or a furnace fuel oil comprises the steps of heating a hydrocarbonaceous solvent and introducing thereinto waste from vulcanized or nonvulcanized rubbers under intensive stirring. Then the waste is thermally decomposed at a pressure of 5.multidot.10.sup.2 to 25.10.sup.5 n/m.sup.2, the hydrocarbonaceous solvent continuously circulating through the reaction mixture. The end product is separated from the formed suspension by distillation at a temperature of 200.degree. to 560.degree. C. and at a pressure of 10 to 2.multidot.10.sup.5 n/m.sup.2 in the presence of an inert gaseous agent.

Abstract: The process of the invention comprises heating coarsely cut or whole used or waste tires in an oven while spraying thereon a stream of heavy oil, recycling at least a part of this oil and discharging the oil formed by decomposition of the tires as output product.

Abstract: Residual products obtained in the catalytic dehydration of alpha-methylbenzyl alcohol are treated to recover increased quantities of ethylbenzene by a process which comprises thermally cracking the residual products in the substantial absence of hydrogen under elevated pressures.

Abstract: This invention relates to the conversion by way of decomposing a solid carbonaceous matter to acetylene. Specifically, the invention teaches selecting the operating conditions which will produce high yield at low cost. Specific values of heat and enthalpy for the carbonaceous matter and the gas are proposed in combination with specific particle sizes and reaction time. All of the foregoing contribute to producing acetylene at a commercially competitive cost.

Abstract: A process for preparing viscosity index improvers for lubricating oils consisting of thermally cracking a solution of an olefin copolymer in mineral oil at a temperature of between 250.degree. C. and 350.degree. C. in an inert atmosphere said solution containing free radical scavengers.

Abstract: Living plants and animals synthesize and often accumulate a wide variety of organic materials having a molecular weight greater than 150. These include different chemical types such as natural hydrocarbons including rubbery substances, natural resins, and natural glycerides such as oils and fats. These substances, formed in the anabolic process, are collectively called "anabolites".This invention provides a process for catalytically converting certain anabolites to liquid hydrocarbons useful for the manufacture of fuels such as gasoline and chemicals such as para-xylene. Crystalline aluminosilicate zeolites having an effective pore size of greater than about 5 Angstrom units are useful catalysts.

Abstract: The invention is a process for economically recovering carbon black, oil and fuel gas from used tires. Used tires are physically fragmented. The fragments are pyrolized at slightly subatmospheric pressure in a reactor while process char is being recycled to increase heat transfer and avoid coke on heat transfer surfaces. Entrained char is separated from the vapor phase products of the pyrolysis, and the vapor phase products of the pyrolysis are then fractionated into oil and fuel gas. A preferred embodiment condenses reactor vapors in two stages at two temperature levels to separate dust from an oil-dust mixture, without water in the first stage and light oil in the second stage. The fuel gas can be compressed and burnt to provide process heat. The entrained char dust and some heavy oil is returned to the reactor. Solid phase pyrolysis products are stripped of trash and milled to carbon black.

Abstract: This invention relates to a process for hydrocracking a waste rubber such as used tires, used conveyor belts, used hoses etc., and more particularly to a process for hydrocracking such waste rubber with a specific catalyst obtained by mixing (1) a main catalyst of an iron compound with (2) an auxiliary catalyst of metal compounds of the Periodic Table, Group VI, based on a synergistic catalyst action with sulfur contained in said waste rubber so that said waste rubber is decomposed into an oil contents and carbon.

Abstract: The invention is a process for economically recovering carbon black, tar, oil and fuel gas from used tires. Used tires are physically sliced and fragmented. The fragments are pyrolized in an oxygen-limited, hydrocarbon vapor at subatmospheric pressure while being refluxed with process tar condensate. Vapor phase products of the pyrolysis are fractionated into tar, oil and fuel gas. The fuel gas can be compressed and burnt to provide process heat. Solid phase pyrolysis products are stripped of trash and milled to carbon black in an air swept roller mill. Carbon black is mechanically separated from the effluent air stream of the roller mill and formed into pellets that are dried in a series multi-stage fluid bed dryer.

Abstract: A process for producing hydrocarbons having about 10 to 50 carbon atoms with a high yield by subjecting a synthetic polyisoprene rubber to a thermally destructive distillation under a reduced pressure and further a process for producing squalane-like saturated hydrocarbons by catalytically reducing the distillate thus obtained from the synthetic polyisoprene rubber.

Abstract: A process for converting relatively ash-free solid polymeric wastes to more valuable liquid, solid, and gaseous products which comprises mixing rubber and/or plastic wastes at high temperatures in a refractory petroleum stream and catalytically cracking the mixture.

Abstract: A method for the production of carbon black which comprises the steps of pyrolyzing at a temperature range of from 250.degree. C. to 950.degree. C., a composition consisting of 0 to 100% scrap vulcanized rubber, 0 to 70% particulate and yarn polymeric resin wastes, and 0 to 50% coke-production, petroleum-refining and petrochemical-derived hydrocarbons to form a mixture of volatile products; recovering and condensing from the products a fraction of cyclic hydrocarbons having a correlation index in excess of 90; and injecting said cyclic hydrocarbon fraction as the feedstock to a carbon-black generating burner to form carbon black.