By Ring Formation From Nonring Moiety, E.g., Aromatization, Etc. Patents (Class 585/407)
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Patent number: 11939541Abstract: In accordance with one or more embodiments herein, an integrated process for upgrading a hydrocarbon oil feed stream utilizing a delayed coker, steam enhanced catalytic cracker, and an aromatics complex includes solvent deasphalting the hydrocarbon oil stream; delayed coking the heavy residual hydrocarbons; hydrotreating the delayed coker product stream and the deasphalted oil stream to form a light C5+ hydrocarbon stream and a heavy C5+ hydrocarbon stream; steam enhanced catalytically cracking the light C5+ hydrocarbon stream; steam enhanced catalytically cracking the heavy C5+ hydrocarbon stream; passing at least a portion of the light steam enhanced catalytically cracked stream, the heavy steam enhanced catalytically cracked stream, or both to a product separator to produce a olefin product stream, a naphtha product stream, and a BTX product stream; and processing the naphtha product stream in the aromatics complex to produce benzene and xylenes.Type: GrantFiled: July 15, 2022Date of Patent: March 26, 2024Assignee: Saudi Arabian Oil CompanyInventors: Qi Xu, Aaron Chi Akah, Musaed Salem Al-Ghrami, Zhonglin Zhang
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Patent number: 11932920Abstract: Liquid metal degassing device comprising a chamber containing a liquid metal bath, a device for circulating a gas through a purification chamber and in that the purification chamber comprises a getter material configured to trap dihydrogen from the circulating gas. Method for degassing a liquid metal bath to reduce the hydrogen concentration of the liquid metal comprising the following steps a) Preparing a liquid metal bath, preferably an aluminum alloy b) Circulating a gas, c) Exchanging hydrogen from the circulating gas with the liquid metal such that the hydrogen dissolved in the liquid metal bath diffuses into the circulating gas and enriches the circulating gas with dihydrogen, d) Purifying the circulating gas enriched with dihydrogen in a purification chamber comprising a getter material configured to trap dihydrogen from the circulating gas.Type: GrantFiled: June 3, 2020Date of Patent: March 19, 2024Assignee: CONSTELLIUM ISSOIREInventors: Jocelyn Prigent, Philippe Jarry, Pierre Le Brun
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Patent number: 11879103Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes splitting the pyrolysis gasoline into a stream comprising non-aromatic hydrocarbons and a stream comprising paraffinic hydrocarbons and aromatic hydrocarbons; aromatizing the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons, thereby converting the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX); hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX; hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and processing the second stream comprising BTX in anType: GrantFiled: January 3, 2022Date of Patent: January 23, 2024Assignee: Saudi Arabian Oil CompanyInventors: Noor Nasser Al-Mana, Zhonglin Zhang, Sameer Al-Ghamdi, Omer Refa Koseoglu, Sohel Shaikh
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Patent number: 11851622Abstract: An integrated process for upgrading a hydrocarbon oil feed stream utilizing a gasification unit and steam enhanced catalytic cracker includes solvent deasphalting the hydrocarbon oil stream to form at least a deasphalted oil stream and heavy residual hydrocarbons, the heavy residual hydrocarbons including at least asphaltenes; processing the heavy residual hydrocarbons in a gasification unit to form syngas and gasification residue; hydrotreating the deasphalted oil stream to form a light C5+ hydrocarbon stream, and a heavy C5+ hydrocarbon stream; steam enhanced catalytically cracking the light C5+ hydrocarbon stream to form a light steam enhanced catalytically cracked product stream including olefins, benzene, toluene, xylene, naphtha, or combinations thereof; and steam enhanced catalytically cracking the heavy C5+ hydrocarbon stream to form a heavy steam enhanced catalytically cracked product including olefins, benzene, toluene, xylene, naphtha, or combinations thereof.Type: GrantFiled: July 15, 2022Date of Patent: December 26, 2023Assignee: Saudi Arabian Oil CompanyInventors: Aaron Chi Akah, Qi Xu, Musaed Salem Al-Ghrami, Zhonglin Zhang
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Patent number: 11766663Abstract: A nanocomposite catalyst includes a support, a multiplicity of nanoscale metal oxide clusters coupled to the support, and one or more metal atoms coupled to each of the nanoscale metal oxide clusters. Fabricating a nanocomposite catalyst includes forming nanoscale metal oxide clusters including a first metal on a support, and depositing one or more metal atoms including a second metal on the nanoscale metal oxide clusters. The nanocomposite catalyst is suitable for catalyzing reactions such as CO oxidation, water-gas-shift, reforming of CO2 and methanol, and oxidation of natural gas.Type: GrantFiled: June 10, 2020Date of Patent: September 26, 2023Assignee: Arizona Board of Regents on behalf of Arizona State UniversityInventors: Jingyue Liu, Xu Li
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Patent number: 11732200Abstract: The present invention relates to an integrated process for increasing the research octane number (RON) of FCC gasoline with simultaneous reduction in benzene content. In this process, benzene rich gasoline fraction is reacted with light olefin rich gaseous streams like FCC off gas/dry gas, coker off gas to produce alkyl aromatics using FCC catalyst system containing ZSM-5 zeolite. The catalyst is continuously drawn from the FCC regenerator by suitably placing the alkylation reactor in communication with the FCC regenerator. The product stream of the alkylation reactor is routed to main fractionator for separation of off gas and benzene lean gasoline. This integrated process not only improves the octane number of gasoline but also lowers the gasoline benzene content. Further the integrated alkylation reactor system acts as a heat sink lowering the FCC regenerator temperature and enables the FCC unit to process high CCR feeds.Type: GrantFiled: March 25, 2022Date of Patent: August 22, 2023Assignee: Indian Oil Corporation LimitedInventors: Sandup Tshering Bhutia, Vineeth Venu Nath, Arvind Wamandas Mahant, Bandaru Hari Venkata Prasad Gupta, Ram Mohan Thakur, Madhusudan Sau, Gurpreet Singh Kapur, Sankara Sri Venkata Ramakumar
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Patent number: 11649409Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes hydrotreating a stream comprising the pyrolysis gasoline, thereby producing a hydrotreated pyrolysis gasoline stream comprising paraffins; aromatizing the hydrotreated pyrolysis gasoline stream comprising paraffins, thereby producing a stream comprising benzene-toluene-xylenes (BTX); and processing the stream comprising BTX in an aromatics recovery complex, thereby producing the aromatic compounds from the pyrolysis gasoline.Type: GrantFiled: January 3, 2022Date of Patent: May 16, 2023Assignee: Saudi Arabian Oil CompanyInventors: Noor Nasser Al-Mana, Zhonglin Zhang, Omer Refa Koseoglu, Sohel Shaikh
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Patent number: 11639290Abstract: A system and method for dry reforming methane at elevated pressure in a dry reformer vessel, and increasing concentration of carbon dioxide in the feed to the dry reformer vessel in response to solid-carbon formation in the dry reformer vessel.Type: GrantFiled: June 4, 2020Date of Patent: May 2, 2023Assignee: Saudi Arabian Oil CompanyInventors: Bandar Al-Solami, Kunho Lee
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Patent number: 11542171Abstract: The present invention relates to a method for preparing ZSM-5 zeolite. The present invention can provide a method for preparing ZSM-5 zeolite comprising the steps of: preparing a first solution in a solution state by heating a mixture comprising a silica source, an alumina source, a neutralizing agent and a crystalline ZSM-5 nucleus; preparing a reaction mother liquid by mixing a second solution comprising salts into the first solution; and continuously crystallizing by continuously supplying the reaction mother liquid to a hydrothermal synthesis reactor, wherein formula [1] below is satisfied. 0.20?Wa/Wb?0.Type: GrantFiled: May 2, 2019Date of Patent: January 3, 2023Assignee: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGYInventors: Na Young Kang, Yong Ki Park, Chang Hwan Kim, Yu Jin Lee
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Patent number: 10889763Abstract: Disclosed are compositions for catalysts comprising a zeolite promoted by metal and or metal oxide. In some aspects, the metal and/or metal oxide comprise a mixture of two or more metal or metal oxides. In various aspects, the zeolite is a pentasil zeolite and/or a ZSM-5 type zeolite. Also disclosed are processes for making the disclosed heterogeneous catalysts comprising preparing a mixture of a zeolite and one or more metal salts, which can include use of incipient wetness impregnation methods. In various aspects, also disclosed are methods for direct, non-oxidative preparation of higher hydrocarbons from natural gas, including selective for high yield production of C6 and higher hydrocarbons. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.Type: GrantFiled: March 15, 2019Date of Patent: January 12, 2021Assignee: West Virginia UniversityInventor: Jianli Hu
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Patent number: 10682634Abstract: A method of manufacturing a modified zeolite catalyst may include reacting a zeolite with a metal salt to form a zeolite/metal salt complex. The zeolite may be a ZSM-5 or ZSM-11. The method may include heating the zeolite/metal salt complex to form an intermediate modified zeolite, and reacting the intermediate modified zeolite with an acid. The method may include ion exchanging the intermediate modified zeolite following the reaction with the acid to form a modified zeolite catalyst.Type: GrantFiled: March 27, 2015Date of Patent: June 16, 2020Assignee: REACTION 35, LLCInventor: Peter K. Stoimenov
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Patent number: 10640436Abstract: Provided is a method for producing aromatic hydrocarbons from light alkanes. A light alkane feed is contacted with catalyst particles in each of reactors, wherein each of the reactors is a fluidized bed reactor and arranged in parallel with each other in a furnace. At least a portion of the alkane feed is converted to aromatic hydrocarbons using the catalyst particles, wherein the aromatic hydrocarbons form a part of a reactor effluent stream. The reactor effluent streams from each of the reactors are merged to form a first merged effluent stream. The first merged effluent stream is separated into the aromatic hydrocarbons, light hydrocarbons, and a fuel gas.Type: GrantFiled: December 29, 2017Date of Patent: May 5, 2020Assignee: KAINOS TECH INCORPORATEDInventor: Jin Ki Hong
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Patent number: 10487025Abstract: A method of preparing a bound zeolite support comprising: contacting a zeolite powder with a binder and water to form a paste; shaping the paste to form an wet extruded base; removing excess water from the wet extruded base to form an extruded base; contacting the extruded base with a fluorine-containing compound to form a fluorinated extruded base; calcining the extruded base to form a calcined fluorinated extruded base; washing the calcined fluorinated extruded base to form a washed calcined fluorinated extruded base; drying the washed calcined fluorinated extruded base to form a dried washed calcined fluorinated extruded base; and calcining the dried washed calcined fluorinated extruded base to form a bound zeolite support.Type: GrantFiled: December 21, 2016Date of Patent: November 26, 2019Assignee: Chevron Phillips Chemical Company LPInventor: An-Hsiang Wu
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Patent number: 10351787Abstract: Described herein are processes for the conversion of ethylene into CS+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.Type: GrantFiled: March 6, 2018Date of Patent: July 16, 2019Assignee: INVISTA North America S.a.r.l.Inventors: William M. Cross, Jr., Daniel Travis Shay, Rui Chi Zhang, Fang Zhang
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Patent number: 10184089Abstract: Described herein are processes for the conversion of ethylene into C5+ olefins, naphthenics, and aromatics via a dual catalyst reaction utilizing a dehydroaromatization catalyst.Type: GrantFiled: August 13, 2015Date of Patent: January 22, 2019Assignee: INVISTA NORTH AMERICA S.A.R.L.Inventors: William M. Cross, Jr., Daniel Travis Shay, Rui Chi Zhang, Fang Zhang
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Patent number: 9433936Abstract: Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.Type: GrantFiled: March 4, 2014Date of Patent: September 6, 2016Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Scott J. Weigel, Joseph Emmanuel Gatt, Darryl Donald Lacy, Randall D. Partidge, Kun Wang, Lei Zhang, Christine Nicole Elia
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Patent number: 9061961Abstract: Process for the direct amination of hydrocarbons to aminohydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one hydrocarbon and at least one aminating reagent to form a reaction mixture R comprising aminohydrocarbons and hydrogen and b) electrochemical separation of at least part of the hydrogen formed in the reaction from the reaction mixture R by means of a gastight membrane-electrode assembly having at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane, b1) reduced to hydrogen and/or b2) reacted with oxygen from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane to form water over the cathode catalyst on the permeate side.Type: GrantFiled: July 8, 2010Date of Patent: June 23, 2015Assignee: BASF SEInventors: Petr Kubanek, Alexander Panchenko, Andreas Fischer, Thomas Heidemann
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Patent number: 9035118Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and partially processing each feedstream in separate reactors. The processing includes passing the light stream to a combination hydrogenation/dehydrogenation reactor. The process reduces the energy by reducing the endothermic properties of intermediate reformed process streams.Type: GrantFiled: December 15, 2011Date of Patent: May 19, 2015Assignee: UOP LLCInventors: Manuela Serban, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
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Patent number: 9029618Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and partially processing each feedstream in separate reactors. The processing includes passing the light stream to a combination hydrogenation/dehydrogenation reactor. The process reduces the energy by reducing the endothermic properties of intermediate reformed process streams.Type: GrantFiled: December 15, 2011Date of Patent: May 12, 2015Assignee: UOP LLCInventors: Manuela Serban, Kurt M. Vanden Bussche, Mark D. Moser, David A. Wegerer
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Patent number: 9024097Abstract: A process for reforming hydrocarbons is presented. The process involves applying process controls over the reaction temperatures to preferentially convert a portion of the hydrocarbon stream to generate an intermediate stream, which will further react with reduced endothermicity. The intermediate stream is then processed at a higher temperature, where a second reforming reactor is operated under substantially isothermal conditions.Type: GrantFiled: December 15, 2011Date of Patent: May 5, 2015Assignee: UOP LLCInventors: Manuela Serban, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
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Patent number: 9024098Abstract: A process for the production of aromatics through the reforming of a hydrocarbon stream is presented. The process utilizes the differences in properties of components within the hydrocarbon stream to increase the energy efficiency. The differences in the reactions of different hydrocarbon components in the conversion to aromatics allows for different treatments of the different components to reduce the energy used in reforming process.Type: GrantFiled: December 15, 2011Date of Patent: May 5, 2015Assignee: UOP LLCInventors: Mark D. Moser, David A. Wegerer, Manuela Serban, Kurt M. VandenBussche
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Patent number: 9024099Abstract: A process is presented for the increasing the yields of aromatics from reforming a hydrocarbon feedstream. The process includes splitting a naphtha feedstream into a light hydrocarbon stream, and a heavier stream having a relatively rich concentration of naphthenes. The heavy stream is reformed to convert the naphthenes to aromatics and the resulting product stream is further reformed with the light hydrocarbon stream to increase the aromatics yields. The catalyst is passed through the reactors in a sequential manner.Type: GrantFiled: December 15, 2011Date of Patent: May 5, 2015Assignee: UOP LLCInventors: Mark D. Moser, Kurt M. VandenBussche, David A. Wegerer, Gregory J. Gajda
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Patent number: 8981169Abstract: A process for converting a gaseous hydrocarbon feed comprising methane to an aromatic hydrocarbon is integrated with liquefied natural gas (LNG) and/or pipeline gas production. The gaseous hydrocarbon feed is supplied to a conversion zone comprising at least one dehydroaromatization catalyst and is contacted with the catalyst under conversion conditions to produce a gaseous effluent stream comprising at least one aromatic compound, unreacted methane and H2. The gaseous effluent stream is then separated into a first product stream comprising said at least one aromatic compound and a second product stream comprising unreacted methane and H2. The second product stream is further separated into a methane-rich stream and a hydrogen-rich stream and at least part of the methane-rich stream is passed to LNG and/or pipeline gas production.Type: GrantFiled: July 18, 2011Date of Patent: March 17, 2015Assignee: ExxonMobil Chemical Patents Inc.Inventors: Larry L. Iaccino, Robert D. Denton, Garth M. Norman, James R. Lattner
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Patent number: 8926830Abstract: Processes for producing aromatics from a naphtha feedstream are provided. An exemplary process includes passing the feedstream to a fractionation unit, thereby generating a first stream including hydrocarbons having less than 8 carbon atoms and a second stream including hydrocarbons having at least 8 carbon atoms. The first stream is passed to a first reformer operated at a first set of reaction conditions to generate a first product stream. The first set of reaction conditions includes a first temperature and a first pressure. The second stream is passed to a second reformer operated at a second set of reaction conditions to generate a second product stream. The second set of reaction conditions includes a second temperature and a second pressure. The first pressure is lower than the second pressure.Type: GrantFiled: April 3, 2013Date of Patent: January 6, 2015Assignee: UOP LLCInventors: Gregory J. Gajda, Mary J. Wier, Clayton Colin Sadler
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Patent number: 8921634Abstract: A new family of aluminosilicate zeolites designated UZM-44 has been synthesized. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zinc, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 has catalytic properties for carrying processes involving contacting at least one low carbon number aliphatic hydrocarbon having from 1 to about 4 carbon atoms per molecule with the catalytic composite comprising UZM-44 to produce at least one aromatic hydrocarbon.Type: GrantFiled: December 11, 2013Date of Patent: December 30, 2014Assignee: UOP LLCInventors: Timur V. Voskoboynikov, Lisa M. King, Vincent G. Mezera, Christopher P. Nicholas, Mark A. Miller
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Patent number: 8906226Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 9, 2012Date of Patent: December 9, 2014Assignee: UOP LLCInventors: Gregory J. Gajda, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
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Patent number: 8889939Abstract: A process for dehydrocyclodimerization using a catalytic composite comprising at least one of a new family of aluminosilicate zeolites designated UZM-44 has been developed. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where “n” is the mole ratio of Na to (Al+E), M represents a metal or metals from zine, Group 1, Group 2, Group 3 and or the lanthanide series of the periodic table, “m” is the mole ratio of M to (Al+E), “k” is the average charge of the metal or metals M, T is the organic structure directing agent or agents, and E is a framework element such as gallium. UZM-44 has catalytic properties for carrying processes involving contacting at least one aliphatic hydrocarbon having from 2 to about 6 carbon atoms per molecule with the UZM-44 to produce at least one aromatic hydrocarbon.Type: GrantFiled: December 2, 2013Date of Patent: November 18, 2014Assignee: UOP LLCInventors: Christopher P. Nicholas, Mark A. Miller
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Patent number: 8871990Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting ethane with a dehyroaromatization aromatic catalyst which is comprised of about 0.005 to about 0.1% wt platinum, an amount of an attenuating metal which is no more than about 0.02% wt less than the amount of platinum, from about 10 to about 99.9% wt of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: GrantFiled: February 16, 2009Date of Patent: October 28, 2014Assignee: Shell Oil CompanyInventors: Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8859835Abstract: In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400° C.Type: GrantFiled: August 26, 2011Date of Patent: October 14, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kenneth R. Clem, Larry L. Iaccino, Mobae Afeworki, Juan D. Henao, Neeraj Sangar, Xiaobo Zheng, Lorenzo C. DeCaul
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Patent number: 8853480Abstract: When producing an aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst, the aromatic hydrocarbon is produced stably for a long time while maintaining a high aromatic hydrocarbon yield. In a process for producing an aromatic hydrocarbon by being equipped with a reaction step for obtaining the aromatic hydrocarbon by a contact reaction of a lower hydrocarbon with a catalyst and a regeneration step for regenerating the catalyst used in this reaction step, and by repeating the reaction step and the regeneration step, yield of the aromatic hydrocarbon is calculated at constant intervals of time. A yield as the standard is set up from this calculated yield. Based on the change of yield relative to this standard, the regeneration time of the regeneration step is prolonged. A threshold value is set up in the change of yield.Type: GrantFiled: June 24, 2011Date of Patent: October 7, 2014Assignee: Meidensha CorporationInventors: Yuji Ogawa, Hongtao Ma
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Patent number: 8845884Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 10, 2012Date of Patent: September 30, 2014Assignee: UOP LLCInventors: Gregory J. Gajda, Mary Jo Wier, Mark P. Lapinski, David A. Wegerer, Kurt M. VandenBussche, Mark D. Moser
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Patent number: 8809608Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting one or more lower alkanes with a dehydroaromatization aromatic catalyst which is comprised of 0.005 to 0.1% wt platinum, not more than 0.2% wt of an amount of an attenuating metal wherein the amount of platinum is not more than about 0.02% wt more than the amount of the attenuating metal, from about 10 to about 99.9% wt of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: GrantFiled: October 29, 2009Date of Patent: August 19, 2014Assignee: Shell Oil CompanyInventors: Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8772563Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting ethane with a dehyroaromatization aromatic catalyst which is comprised of about 0.005 to about 0.1 wt % platinum, an amount of gallium which is equal to or greater than the amount of the platinum, from about 10 to about 99.9 wt % of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: GrantFiled: February 16, 2009Date of Patent: July 8, 2014Assignee: Shell Oil CompanyInventors: Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8766026Abstract: A process is provided for producing aromatic hydrocarbons which comprises: (a) contacting a lower alkane feed with a solid particulate aromatic hydrocarbon conversion catalyst in a fixed bed reaction zone to produce aromatic hydrocarbons and other products, whereby the catalyst is at least partially deactivated by the formation of undesirable coke deposits, (b) periodically regenerating the catalyst under regeneration conditions, (c) separating aromatic hydrocarbons from the other products and unreacted lower alkanes, and (d) optionally recycling unreacted lower alkanes to the reaction zone wherein the fixed bed reaction zone additionally comprises a volume of a catalytically inactive solid.Type: GrantFiled: May 11, 2011Date of Patent: July 1, 2014Assignee: Shell Oil CompanyInventors: Ye Mon Chen, Mahesh Venkataraman Iyer, Karel Martin Kapoun, Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8754276Abstract: A reverse flow regenerative reactor having first and second zones, each having first and second ends, the first zone having a plurality of channels capable of separately conveying at least two components of a combustible gas mixture, a gas distributor configured for injecting the components of the combustible gas mixture into first zone, a combustion zone including a selective combustion catalyst disposed at or downstream of the second end of said channels for catalyzing combustion, wherein the second zone is positioned and situated to receive a combusted gas mixture. Processes usefully conducted in the reactor are also disclosed.Type: GrantFiled: August 10, 2012Date of Patent: June 17, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: John Scott Buchanan, Stephen Mark Davis, Frank Hershkowitz, John Slocum Coleman, Seth McConkie Washburn
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Patent number: 8742189Abstract: The present invention relates to a catalyst for dehydroaromatizing C1-C4-aliphatics, said catalyst being obtainable by twice treating a zeolite from the group of MFI and MWW with NH4-containing mixtures, in each case with subsequent drying and calcination. The catalyst comprises molybdenum and, if appropriate, as further elements, Cu, Ni, Fe, Co, Mn, Cr, Nb, Ta, Zr, V, Zn and/or Ga. The present invention further provides a process for dehydroaromatizing a mixture comprising C1-C4-aliphatics by conversion in the presence of the catalyst.Type: GrantFiled: April 8, 2009Date of Patent: June 3, 2014Assignee: BASF SEInventors: Frank Kiesslich, Joana Coelho Tsou, Bilge Yilmaz, Sebastian Ahrens, Thomas Heidemann, Veronika Will, Christian Bechtold
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Patent number: 8722950Abstract: The invention is for a process for producing propylene and hexene (along with ethylene, pentenes, product butenes, heptenes and octenes) by metathesis from butenes (iso-, 1- and cis and trans 2-) and pentenes and then aromatizing the hexenes (along with higher olefins, such as heptenes and octenes) to benzene (along with toluene, xylenes, ethylbenzene and styrene). Since the desired products of the metathesis reaction are propylene and hexene, the feed to the metathesis reaction has a molar ratio for 1-butene:2-butene which favors production of propylene and 3-hexene with the concentration of hexenes and higher olefins in the metathesis product being up to 30 mole %. An isomerization reactor may be used to obtain the desired molar ratio of 1-butene:2-butene for the feed composition into the metathesis reactor. After the metathesis reaction, of hexene and higher olefins are separated for aromatization to benzene and other aromatics.Type: GrantFiled: April 26, 2010Date of Patent: May 13, 2014Assignee: Saudi Basic Industries CorporationInventors: Jaap W. van Hal, Scott A. Stevenson, Jim Allman, David L. Sullivan, Travis Conant
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Patent number: 8703099Abstract: The present invention provides compositions and methods for synthesizing labeled drugs. The present invention further provides methods for preventing or stopping prescription drug abuse for all agents registered as a Drug Enforcement Agency (DEA) schedule II through schedule V medications. According to the present invention, methods are provided for monitoring patient compliance with prescribed drug treatment. The present invention also provides methods for facilitating a replacement prescription when a patient is left without access to their prescribed drug. Furthermore, the present invention provides a method to improve employee compliance with an employer's drug policies via either a voluntary or compulsory system for enhanced drug testing.Type: GrantFiled: February 23, 2006Date of Patent: April 22, 2014Assignee: DR Pharma Nova, LLCInventors: Alan J. Reis, Christian Schafmeister
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Patent number: 8697926Abstract: Process for obtaining aromatic hydrocarbons from a stream containing at least one light hydrocarbon selected from the list comprising methane, ethane, ethylene, propane, propene, propylene, butane, butene or butadiene, which comprises putting said stream into contact with a catalyst, which comprises a catalytic material and a binder, in a fluidized bed reactor. Said reactor may have two reaction zones, an oxidizing zone and a reducing zone.Type: GrantFiled: June 19, 2009Date of Patent: April 15, 2014Assignee: Universidad de ZaragozaInventors: Miguel Menéndez Sastre, Javier Herguido Huerta, Carlos Téllez Ariso, Jaime Soler Herrero, María Pilar Gimeno Tolosa
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Patent number: 8692043Abstract: A process for producing aromatic hydrocarbons which comprises (a) contacting ethane with a dehyroaromatization aromatic catalyst which is comprised of 0.005 to 0.1% wt platinum, an amount of iron which is equal to or greater than the amount of the platinum, from 10 to 99.9% wt of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.Type: GrantFiled: February 18, 2009Date of Patent: April 8, 2014Assignee: Shell Oil CompanyInventors: Ann Marie Lauritzen, Ajay Madhav Madgavkar
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Patent number: 8609914Abstract: The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons in the presence of a catalyst under nonoxidative conditions, wherein at least some of the hydrogen formed in the conversion electrochemically removed is by means of a gas-tight membrane-electrode assembly.Type: GrantFiled: March 30, 2010Date of Patent: December 17, 2013Assignee: BASF SEInventors: Joana Coelho Tsou, Alexander Panchenko, Annebart Engbert Wentink, Sebastian Ahrens, Thomas Heidemann
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Patent number: 8604262Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 9, 2012Date of Patent: December 10, 2013Assignee: UOP LLCInventors: David A. Wegerer, Kurt M. Vanden Bussche, Mark D. Moser
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Patent number: 8575411Abstract: The invention relates to a process for converting aliphatic hydrocarbons having from 1 to 4 carbon atoms into aromatic hydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one aliphatic hydrocarbon having from 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to give a product stream P comprising aromatic hydrocarbons and hydrogen and b) electrochemical removal of at least part of the hydrogen formed in the reaction from the product stream P by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane on the permeate side, reacted with oxygen to form water over the cathode catalyst, with the oxygen originating from an oxygen-comprising stream O whiType: GrantFiled: March 29, 2010Date of Patent: November 5, 2013Assignee: BASF SEInventors: Joana Coelho Tsou, Alexander Panchenko, Annebart Engbert Wentink, Sebastian Ahrens, Thomas Heidemann
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Patent number: 8546627Abstract: The present invention is directed to renewable compositions derived from fermentation of biomass, and integrated methods of preparing such compositions.Type: GrantFiled: April 6, 2012Date of Patent: October 1, 2013Assignee: Gevo, Inc.Inventors: Patrick R. Gruber, Matthew W. Peters, Josefa M. Griffith, Yassin Al Obaidi, Leo E. Manzer, Joshua D. Taylor, David E. Henton
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Publication number: 20130231511Abstract: Methods for treating or rejuvenating a spent catalyst are disclosed. Such methods can employ a step of halogenating the spent catalyst, followed by decoking the halogenated spent catalyst.Type: ApplicationFiled: March 5, 2012Publication date: September 5, 2013Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventor: An-Hsiang Wu
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Publication number: 20130231512Abstract: Methods for treating or rejuvenating a spent catalyst are disclosed. Such methods can employ a step of halogenating the spent catalyst, followed by decoking the halogenated spent catalyst. The halogenation step can utilize fluorine and chlorine together, or fluorine and chlorine can be applied sequentially.Type: ApplicationFiled: February 4, 2013Publication date: September 5, 2013Applicant: Chevron Phillips Chemical Company LPInventor: An-Hsiang Wu
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Patent number: 8487152Abstract: The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons, comprising the steps of: a) converting a reactant stream E which comprises at least one aliphatic hydrocarbon having 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to a product stream P comprising aromatic hydrocarbons and hydrogen, and b) electrochemically removing at least some of the hydrogen formed in the conversion from the product stream P by means of a gas-tight membrane-electrode assembly which has at least one selectively proton-conducting membrane and, on each side of the membrane, at least one electrode catalyst, at least some of the hydrogen being oxidized to protons over the anode catalyst on the retentate side of the membrane, and the protons, after passing through the membrane, on the permeate side over the cathode catalyst, are partly, in b1) reduced to hydrogen with application of a voltage, and partly, in b2) reacted with oxyType: GrantFiled: March 30, 2010Date of Patent: July 16, 2013Assignee: BASF SEInventors: Joana Coelho Tsou, Alexander Panchenko, Annebart Engbert Wentink, Sebastian Ahrens, Thomas Heidemann
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Publication number: 20130157840Abstract: This disclosure provides a molecular sieve composition having a first and second crystalline molecular sieve, made by the method comprising: (a) providing a reaction mixture comprising at least one source of ions of tetravalent element Y, at least one source of alkali metal hydroxide, water, optionally at least one seed crystal, and optionally at least one source of ions of trivalent element X, the reaction mixture having the following molar composition: Y:X2=2 to infinity, preferably from about 2 to about 1000, OH?:Y=0.001 to 2, preferably from 0.1 to 1, M+:Y=0.001 to 2, preferably from 0.Type: ApplicationFiled: February 18, 2013Publication date: June 20, 2013Applicant: ExxonMobil Chemical Patents Inc.Inventors: Wenyih Frank Lai, Robert Ellis Kay
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Patent number: 8461404Abstract: A prolongated silica bound zeolite support comprising from about 85 wt % to about 95 wt % zeolite. A catalyst composition comprising a prolongated silica bound zeolite supporting at least one Group VIII metal and at least one halide. A process of making a prolongated silica bound zeolite support comprising mixing a zeolite, a prolongated silica, and water to form a mixture, and shaping the mixture into the prolongated silica bound zeolite support. A process of making a prolongated silica bound zeolite catalyst comprising mixing a zeolite, a prolongated silica, and water to form a mixture, shaping the mixture into a prolongated silica bound zeolite support, and adding one or more catalytic compounds to the prolongated silica bound zeolite support to form the prolongated silica bound zeolite catalyst.Type: GrantFiled: February 16, 2011Date of Patent: June 11, 2013Assignee: Chevron Phillips Chemical Company LPInventor: Gyanesh P. Khare
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Publication number: 20130144093Abstract: The present invention generally relates to a method for sequestering carbon dioxide. Biomass is converted into paraffinic hydrocarbons. The paraffinic hydrocarbons are steam cracked into olefins. The olefins are polymerized into non-biodegradable polyolefins.Type: ApplicationFiled: January 24, 2013Publication date: June 6, 2013Inventor: Ramin Abhari