Using Catalyst Patents (Class 585/651)
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Patent number: 8044254Abstract: A processing scheme and arrangement for enhanced olefin production involves cooling or treating an olefin cracking reactor effluent stream by contacting the olefin cracking reactor effluent stream with a quench oil stream in a single contact cooler contact zone to produce a cooled vapor stream and to form a heated quench oil stream. A pressure differential across the single contact cooler is less than about 3.5 kPa. The heated quench oil stream can be subsequently cooled and returned to the single contact cooler.Type: GrantFiled: March 16, 2009Date of Patent: October 25, 2011Assignee: UOP LLCInventor: Adam J. Kanyuh
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Publication number: 20110230697Abstract: Catalytic cracking processes such as fluidized catalytic cracking, naphtha cracking, and olefin cracking are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in the catalytic cracking of hydrocarbons.Type: ApplicationFiled: June 2, 2011Publication date: September 22, 2011Applicant: UOP LLCInventors: Christopher P. Nicholas, Deng-Yang Jan, Jaime G. Moscoso
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Patent number: 8002856Abstract: The present invention relates to a process for contacting a hydrocarbon and an oxygen-containing gas with a catalyst bed in a reactor at a space velocity of at least 10,000 h?1, said process being characterised in that a) the reactor has a polygonal internal cross-section at least in the section where the catalyst bed is held, b) the catalyst bed is made up of 2 or more layers of catalyst in the form of tiles of polygonal shape, said tiles have at least 4 sides, c) each layer of catalyst comprises at least 4 tiles which tessellate together to form said layer, and d) the edges where 2 tiles meet in one layer do not align with the edges where 2 tiles meet in an adjacent layer.Type: GrantFiled: December 20, 2006Date of Patent: August 23, 2011Assignee: Ineos Europe LimitedInventor: Vaughan Clifford Williams
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Patent number: 7973209Abstract: Processing schemes and arrangements for the catalytic cracking of a heavy hydrocarbon feedstock and obtaining light olefins substantially free of carbon dioxide via amine treatment and employing fractionation processing are provided.Type: GrantFiled: September 28, 2006Date of Patent: July 5, 2011Assignee: UOP LLCInventors: Gavin P. Towler, John P. Brady, William J. Lechnick, Michael A. Schultz
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Patent number: 7951987Abstract: The present invention relates to a thermal-cracking method of hydrocarbon using a hydrocarbon thermal-cracking apparatus including a tube type furnace having a radiation part for thermally cracking hydrocarbon feedstocks supplied together with steam and a convection part. A hydrocarbon thermal-cracking catalyst is packed in some or entire area of the tube placed in the radiation part of the tube type furnace, wherein the hydrocarbon thermal-cracking catalyst includes an oxide catalyst represented by CrZrjAkOx (wherein, 0.5?j?120 and 0?k?50, A is a transition metal, and x is a number corresponding to the atomic values of Cr, Zr, and A and the numbers of j and k). Therefore, it is possible to improve yield and selectivity of olefin, reduce fuel consumption due to an excellent heat transfer efficiency and extend decoking interval by reduced production of coke deposited to an inside wall of a tube, in steam cracking of hydrocarbon for producing olefin.Type: GrantFiled: July 2, 2008Date of Patent: May 31, 2011Assignee: LG Chem, Ltd.Inventors: Jun-seon Choi, Byoung-gi Park, Jin-do Kim, Hyune-jung Ryu
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Patent number: 7947860Abstract: Processing schemes and arrangements for application of a dividing wall separation column in the processing of an effluent resulting from FCC processing modified for increased light olefin production. The dividing wall separation column desirably splits a naphtha feedstock produced or resulting from such modified FCC processing to produce or form a light fraction containing C5-C6 compounds, an intermediate fraction containing C7-C8 compounds and a heavy fraction containing C9+ compounds.Type: GrantFiled: September 28, 2006Date of Patent: May 24, 2011Assignee: UOP LLCInventors: Michael A. Schultz, Keith A. Couch
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Patent number: 7943038Abstract: Processes for producing one or more olefins are provided. In one or more embodiments, a doped catalyst can be prepared by fluidizing one or more coked-catalyst particles in the presence of one or more oxidants to provide a fluidized mixture. At least a portion of the coke can be removed from the coked-catalyst particles to provide regenerated catalyst particles. One or more doping agents can be distributed throughout the fluidized mixture, depositing on the surface of the regenerated catalyst particles to provide doped catalyst particles. One or more hydrocarbon feeds can be fluidized with the doped catalyst particles to provide a reaction mixture which can be cracked to provide a first product containing propylene, ethylene, and butane.Type: GrantFiled: January 29, 2008Date of Patent: May 17, 2011Assignee: Kellogg Brown & Root LLCInventor: Pritham Ramamurthy
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Patent number: 7939702Abstract: Disclosed is a process for increasing production of light olefinic hydrocarbons from hydrocarbon feedstock by catalytic cracking. In the process, an effective separation process structure and recycle method of light olefins are used not only to increase the productivity and efficiency of an overall process, thus effectively increasing the production of light olefins, but also to simplify the overall process.Type: GrantFiled: June 1, 2006Date of Patent: May 10, 2011Assignee: SK Energy Co., Ltd.Inventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang
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Patent number: 7932427Abstract: The present invention provides a process for the preparation of propylene from a hydrocarbon feed containing one or more C5 and/or C6 cycloalkanes, wherein the hydrocarbon feed containing one or more C5 and/or C6 cycloalkanes is contacted under cracking conditions with a one-dimensional zeolite having 10-membered ring channels and a silica to alumina ratio in the range from 1 to 500 wherein at least 50% w/w of the total amount of zeolite used is zeolite in the hydrogen form.Type: GrantFiled: May 16, 2007Date of Patent: April 26, 2011Assignee: Shell Oil CompanyInventors: Leslie Andrew Chewter, Michiel Johannes Franciscus Maria Verhaak, Jeroen Van Westrenen
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Patent number: 7902113Abstract: The present invention relates to an improved catalyst for direct conversion of methane to ethane and ethylene, a method for producing the catalyst and a process making use of the catalyst.Type: GrantFiled: September 6, 2005Date of Patent: March 8, 2011Assignee: Research Institute of Petroleum Industry (RIPI)Inventors: Saeed Zarrinpashne, Reza Ahmadi, Seyyed Madjid Zekordi
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Patent number: 7893311Abstract: The invention is to provide a catalyst excellent in product producibility and selectivity, and in coking degradation resistance and regeneration degradation resistance, which is for production of ethylene and propylene through catalytic conversion from a hydrocarbon material. The invention relates to a method for producing ethylene and propylene through catalytic conversion from an olefin, by contacting a hydrocarbon material with a zeolite-containing shaped catalyst satisfying the following requirements (1) to (6), in a reactor: (1) the zeolite is an intermediate pore-size zeolite having a pore size of from 5 to 6.5 angstroms, (2) the zeolite does not substantially contain a proton, (3) the zeolite contains at least one metal selected from the group consisting of metals belonging to the Group IB of the Periodic Table, (4) the zeolite-containing shaped catalyst comprises silica as a binder, (5) the zeolite-containing shaped catalyst has a side-crush strength of at least 2.Type: GrantFiled: September 14, 2006Date of Patent: February 22, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshikazu Takamatsu, Kouji Nomura
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Patent number: 7884257Abstract: The invention is to provide a catalyst for long-term, high-yield and stable production of ethylene and propylene in an efficient and simple method of catalytic conversion from a hydrocarbon material. The invention relates to a method for producing ethylene and propylene by contacting a hydrocarbon material that contains an olefin having from 4 to 12 carbon atoms in an amount of at least 20% by weight, with a zeolite-containing shaped catalyst satisfying the following requirements (1) to (4), in a reactor for catalytic conversion of that olefin: (1) the zeolite is an intermediate pore-size zeolite having a pore size of from 5 to 6.5 angstroms, (2) the zeolite does not substantially contain a proton, (3) the zeolite contains at least one metal selected from the group consisting of metals belonging to the Group IB of the Periodic Table, (4) the zeolite has a silica/alumina molar ratio (SiO2/Al2O3 molar ratio) of from 800 to 2,000.Type: GrantFiled: September 14, 2006Date of Patent: February 8, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Yoshikazu Takamatsu, Kouji Nomura
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Patent number: 7875756Abstract: A process for producing lower olefins is disclosed. The technical problem is to overcome the defects presented in the prior art including high reaction pressure, high reaction temperature, low yield and selectivity of lower olefins as the target products, poor stability and short life of catalyst, and limited suitable feedstocks. The disclosed process, which is carried out under the conditions of catalytic cracking olefins and adopts as a feedstock an olefins-enriched mixture containing one or more C4 or higher olefins and optionally an organic oxygenate compound, comprises the steps of: a) letting the feedstock contact with a crystalline aluminosilicate catalyst having a SiO2/Al2O3 molar ratio of at least 10, to thereby produce a reaction effluent containing lower olefins; and b) separating lower olefins from the reaction effluent; wherein, the reaction pressure is from ?0.1 MPa to <0 MPa.Type: GrantFiled: August 9, 2006Date of Patent: January 25, 2011Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Juntao Liu, Siqing Zhong, Wenwei Wu
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Patent number: 7868216Abstract: A process for producing high purity propylene comprises: a step for dimerizing ethylene to 1-butene; a step for hydroisomerizing 1-butene to 2-butenes; and a step for metathesis of 2-butenes by ethylene. Advantageously, the ethylene used to produce the 1-butene and ethylene for metathesis derive from a steam cracking unit. To increase propylene production, the process can use a steam cracking or FCC C4cut as an additional butene source.Type: GrantFiled: December 23, 2005Date of Patent: January 11, 2011Assignee: IFP Energies NouvellesInventors: Jean-Alain Chodorge, Christian Dupraz
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Publication number: 20100324348Abstract: Catalytic cracking processes such as fluidized catalytic cracking, naphtha cracking, and olefin cracking are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in the catalytic cracking of hydrocarbons.Type: ApplicationFiled: June 22, 2009Publication date: December 23, 2010Inventors: Christopher P. Nicholas, Deng-Yang Jan, Jaime G. Moscoso
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Publication number: 20100317909Abstract: A method for producing olefins using a carbon nanotube catalyst is disclosed. Initially, a hydrocarbon feedstock is received. The hydrocarbon feedstock, the carbon nanotube catalyst, and steam are mixed in a thermal cracking reactor. The mixture is heated in the thermal cracking reactor to a particular temperature. The olefins are then separated from the mixture. The carbon nanotube catalyst can include carbon nanotubes coated with M1xOy and modified with M2mOn. M1 can be either the element silicon or tungsten, x can be an integer that represents the oxidation number of M1, and y can an integer that represents the number of oxygen atoms required by the oxidation number of M1. M2 can be a metallic element, m can be an integer that represents the oxidation number of M2, and n can be an integer that represents the number of oxygen atoms required by the oxidation number of M2.Type: ApplicationFiled: August 19, 2010Publication date: December 16, 2010Inventors: KAMYAR KEYVANLOO, JAFAR TOWFIGHI DARIAN, ALI MOHAMADALIZADEH
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Patent number: 7820033Abstract: A process for increasing ethylene yield in a cracked hydrocarbon is provided. A hydrocarbon feed stream comprising at least 90% by weight of one or more C4-C10 hydrocarbons can be heated to provide an effluent stream comprising at least 10% by weight propylene. The effluent stream can be selectively separated to provide a first stream comprising heavy naphtha, light cycle oil, slurry oil, or any combination thereof and a second stream comprising one or more C4-C10 hydrocarbons. The second stream can be treated to remove oxygenates, acid gases, water, or any combination thereof to provide a third stream comprising the one or more C4-C10 hydrocarbons. The third stream can be selectively separated to provide a product stream comprising at least 30% by weight propylene. At least a portion of the product stream can be recycled to the hydrocarbon feed stream to increase ethylene yield in the effluent stream.Type: GrantFiled: April 30, 2007Date of Patent: October 26, 2010Assignee: Kellogg Brown & Root LLCInventors: Curtis N. Eng, Yonglin Yang
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Publication number: 20100256431Abstract: The present invention provides a process for the catalytic cracking of an olefin-rich feedstock which is selective towards light olefins in the effluent, the process comprising contacting a hydrocarbon feedstock containing one or more olefins, with a catalyst made of a phosphorus-modified zeolite (A), to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, wherein said phosphorous modified zeolite (A) is made by a process comprising in that order: selecting a zeolite with low Si/Al ratio (advantageously lower than 30) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870° C. for 0.01-200 h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.Type: ApplicationFiled: July 28, 2008Publication date: October 7, 2010Applicant: Total Petrochemicals Research FeluyInventors: Nikolai Nesterenko, Walter Vermeiren, Delphine Minoux, Sander Van Donk
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Publication number: 20100217059Abstract: The process of this invention represents an improved, low-energy method for recovering a purified ethylene product from the effluent of an autothermal cracking reactor. The process consists of a cracked gas chilling train, a front-end ethylene distributor, a demethanizer, and a C2 splitter. Hydrocarbons heavier than ethylene, including ethane, propylene, and propane are recycled in a single stream to the ATC reactor. Acetylene removal from the ethylene product can be accomplished either through a front-end hydrogenation unit or an acetylene extraction unit. This invention is particularly useful when the fresh hydrocarbon feed to the autothermal cracking reactor is ethane or a mixture of ethane and propane.Type: ApplicationFiled: July 28, 2005Publication date: August 26, 2010Inventors: Rian Reyneke, Michael J. Foral, Graeme Parker, Wayne W.Y. Eng
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Patent number: 7754934Abstract: A process for efficiently and stably producing ethylene and propylene which comprises bringing a hydrocarbon feedstock comprising at least one C4-12 olefin into contact with a zeolite-containing catalyst to obtain a reaction mixture containing ethylene and propylene, separating the reaction mixture into a fraction comprising ingredients ranging from hydrogen to C3 hydrocarbons and a fraction comprising C4 and higher hydrocarbons, and recycling the C4 and higher hydrocarbons as they are to a reactor.Type: GrantFiled: July 15, 2005Date of Patent: July 13, 2010Assignee: Asahi Kasei Chemicals CorporationInventors: Takashi Tsunoda, Mitsuhiro Sekiguchi
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Patent number: 7737317Abstract: Processing schemes and arrangements are provided for the processing a heavy hydrocarbon feedstock via hydrocarbon cracking processing with selected hydrocarbon fractions being obtained via fractionation-based product recovery.Type: GrantFiled: September 28, 2006Date of Patent: June 15, 2010Assignee: UOP LLC.Inventors: Michael A. Schultz, Jason T. Corradi
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Publication number: 20100145127Abstract: A catalyst composition comprising on weight basis the following components: a) 30 to 99.5% of at least one intergrowth molecular sieve; b) 0 to 20% of a rare earth element or oxides thereof; c) 0 to 10% of at least one element from Group VA of the Periodic Table or oxides thereof; d) 0 to 10% of at least one element from Group IIIA of the Periodic Table or oxides thereof; e) 0 to 20% of at least one element from Group IB or IIB of the Periodic Table or oxides thereof; f) 0 to 20% of at least one element from Group IA or IIA of the Periodic Table or oxides thereof; and g) 0 to 65% of a binder, wherein the components b), c), d), e) and f) are supported on the component a), and contents of at least two of the components b), c), d), e) and f) are larger than zero, is described. A process for preparing said catalyst composition and a process for the production of olefins via catalytic cracking by using said catalyst composition are also described.Type: ApplicationFiled: April 3, 2008Publication date: June 10, 2010Inventors: Zaiku Xie, Ma Guangwei, Yang Weimin, Yao Hui, Yang Xiaqin
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Patent number: 7718840Abstract: Disclosed is a process for producing light olefins from hydrocarbon feedstock. The process is characterized in that a porous molecular sieve catalyst consisting of a product obtained by evaporating water from a raw material mixture comprising a molecular sieve with a framework of Si—OH—Al— groups, a water-insoluble metal salt, and a phosphate compound, is used to produce light olefins, particularly ethylene and propylene, from hydrocarbon, while maintaining excellent selectivity to light olefins. According to the process, by the use of a specific catalyst with hydrothermal stability, light olefins can be selectively produced in high yield with high selectivity from hydrocarbon feedstock, particularly full-range naphtha. In particular, the process can maintain higher cracking activity than the reaction temperature required in the prior thermal cracking process for the production of light olefins, and thus, can produce light olefins with high selectivity and conversion from hydrocarbon feedstock.Type: GrantFiled: June 27, 2006Date of Patent: May 18, 2010Assignees: SK Energy Co., Ltd., Korea Research Institute of Chemical TechnologyInventors: Sun Choi, Yong Seung Kim, Deuk Soo Park, Suk Joon Kim, Il Mo Yang, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Kwang An Ko, Na Young Kang
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Publication number: 20100105974Abstract: A process is presented for the selective catalytic cracking of naphtha to light olefins. The process includes contacting a naphtha feedstream with a mixture of catalysts to reduce the amount of recycle, and especially the recycle of light paraffins. The mixture of catalysts includes a first molecular sieve made up from a small pore zeolite having a pore index between 13 and 26, and a second molecular sieve made up from an intermediate pore zeolite having a pore index between 26 and 30.Type: ApplicationFiled: October 24, 2008Publication date: April 29, 2010Inventors: Gavin P. Towler, Hayim Abrevaya
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Patent number: 7691767Abstract: Provided are a catalyst which inhibits light paraffins form being produced in catalytic cracking of heavy hydrocarbons and which effectively produces olefins and a process in which the above catalyst is used to produce olefins from heavy hydrocarbons at a high yield. The catalyst is a catalytic cracking catalyst for catalytically cracking a hydrocarbon raw material, comprising (A) pentasil type zeolite modified with a rare earth element and zirconium and (B) faujasite type zeolite, and the process is a production process for olefin and a fuel oil, comprising bringing a heavy oil containing 50 mass % or more of a hydrocarbon fraction having a boiling point of 180° C. or higher into contact with the catalyst described above to crack it.Type: GrantFiled: January 17, 2007Date of Patent: April 6, 2010Assignees: Research Association of Refinery Integration for Group-Operation, Idemitsu Kosan Co., Ltd.Inventors: Kenichi Wakui, Kinsho Furusawa, Akio Suwa, Toshio Itoh, Hisao Nagashima
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Patent number: 7692057Abstract: The present invention provides a process for producing lower olefins by catalytic cracking a feedstock comprising an olefins-enriched mixture containing C4 or higher olefins and optionally an organic oxygenate compound. The technical problem mainly addressed in the present invention is to overcome the defects presented in the prior art including low yield and selectivity of lower olefins as the target products, and short regeneration period of catalyst.Type: GrantFiled: August 11, 2006Date of Patent: April 6, 2010Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Zaiku Xie, Juntao Liu, Weimin Yang, Siqing Zhong, Yanhui Yuan, Huiming Zhang
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Patent number: 7683231Abstract: A catalyst system capable of supporting combustion beyond the fuel rich limit of flammability comprising a catalytic component, a first support and a second support and wherein the catalytic component is present on both the first and the second support, and a process for the production of an olefin, said process comprising passing a mixture of a hydrocarbon and an oxygen-containing gas over said catalyst system to produce said olefin. The first support and the second support must differ in at least one of the following aspects: support material, support type and/or structural dimension.Type: GrantFiled: May 18, 2004Date of Patent: March 23, 2010Assignee: Ineos Europe LimitedInventors: Ian Allan Beattie Reid, Vaughan Clifford Williams
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Patent number: 7678954Abstract: In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9? hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.Type: GrantFiled: January 27, 2006Date of Patent: March 16, 2010Assignee: ExxonMobil Chemical Patents, Inc.Inventors: Keith H. Kuechler, Stephen Harold Brown, Helge Jaensch, Georges M. Mathys, Shifang Luo, Jane C. Cheng
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Publication number: 20100063341Abstract: The invention provides methods for converting hydrocarbons as starting material by industrial fixed-bed reaction processes with a zeolite shaped catalyst which has a low content of inorganic binder and a high pore volume and which shows high catalytic activity, long catalyst life and high crushing strength. A zeolite shaped catalyst used in the methods of the invention includes zeolite and an inorganic binder and is obtained by kneading zeolite, a starting material of an inorganic binder, shaping auxiliary(ies), organic polymer particles having an average diameter of 0.1 to 6 ?m and water into a kneaded product, and extruding, drying and calcining the kneaded product; and the zeolite shaped catalyst has a zeolite component content of not less than 60 wt % relative to the total weight, a pore volume of 0.4 to 1.0 ml/g, a half-volume pore diameter of 80 to 500 nm and a crushing strength of not less than 0.9 kg.Type: ApplicationFiled: March 17, 2008Publication date: March 11, 2010Applicant: MITSUI CHEMICALS, INC.Inventors: Phala Heng, Teruo Muraishi, Michiaki Umeno, Hirokazu Ikenaga
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Publication number: 20100063340Abstract: The invention is to provide a catalyst excellent in product producibility and selectivity, and in coking degradation resistance and regeneration degradation resistance, which is for production of ethylene and propylene through catalytic conversion from a hydrocarbon material. The invention relates to a method for producing ethylene and propylene through catalytic conversion from an olefin, by contacting a hydrocarbon material with a zeolite-containing shaped catalyst satisfying the following requirements (1) to (6), in a reactor: (1) the zeolite is an intermediate pore-size zeolite having a pore size of from 5 to 6.5 angstroms, (2) the zeolite does not substantially contain a proton, (3) the zeolite contains at least one metal selected from the group consisting of metals belonging to the Group IB of the Periodic Table, (4) the zeolite-containing shaped catalyst comprises silica as a binder, (5) the zeolite-containing shaped catalyst has a side-crush strength of at least 2.Type: ApplicationFiled: September 14, 2006Publication date: March 11, 2010Inventors: Yoshikazu Takamatsu, Kouji Nomura
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Patent number: 7663013Abstract: A porous solid acid catalyst for producing light olefins is prepared through pillaring and a solid state reaction of a raw material mixture. The catalyst is made of a porous material having a crystalline structure that is different from that of the raw material mixture. The catalyst exhibits excellent catalytic activity (i.e., conversion and selectivity) in the production of light olefins from hydrocarbon feeds such as full range naphthas.Type: GrantFiled: November 5, 2008Date of Patent: February 16, 2010Assignee: SK Energy Co., Ltd.Inventors: Sun Choi, Deuk Soo Park, Suk Joon Kim, Ahn Seop Choi, Hee Young Kim, Yong Ki Park, Chul Wee Lee, Won Choon Choi, Sang Yun Han, Jeong Ri Kim
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Patent number: 7655826Abstract: This invention relates to a method of making an olefin from a dialkyl ether comprising (a) introducing an ether having a formula CxH2x+1CyH2y+1 into a thermal or catalytic cracking unit processing a hydrocarbon feedstock; and (b) decomposing at least a portion of the ether to form an olefin having a formula CxH2x and/or CyH2y and an alcohol having a formula CxH2x+1 and/or CyH2y+1OH, wherein x and y independently range from about 1 to about 30. This invention also relates to a method of reducing coking in a thermal or catalytic cracking unit comprising (a) introducing an ether, having a formula CxH2x+1OCyH2y+1, into the cracking unit processing a hydrocarbon feedstock in an amount effective to reduce coke formation relative to processing the hydrocarbon feedstock in the absence of the ether, wherein x and y independently range from about 1 to about 30.Type: GrantFiled: April 12, 2005Date of Patent: February 2, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Charles M. Yarbrough, Vijay Swarup, Patrick Joseph Maher, Albert Y Hu, Michael Walter Bedell
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Publication number: 20100022811Abstract: A selective catalytic cracking process of natural gas liquid fraction to light olefins and other products is described, the process includes placing in contact (within a reaction zone) said liquid fraction of natural gas, rich in C5+ paraffins, with an MFI type zeolitic catalyst in acid form, having a pore size of at least 4 Angstroms, a silica/alumina ratio of between 10 and 2000, and where the processing conditions involve a temperature of between 350° C. and 650° C., space velocity of between 2 and 100h?1 and atmospheric pressure, and afterwards carrying out the catalytic cracking to separate products, to recover a product enriched with light olefins, LPG fractions, and aromatics, and where the production of olefins is favored in conditions of higher space velocities, while the production of LPG fractions and aromatics are favored in conditions of lowered space velocities.Type: ApplicationFiled: October 2, 2009Publication date: January 28, 2010Applicant: PETROLEO BRASILEIRO S.A. - PETROBRASInventors: Eduardo Falabella SOUSA AGUIAR, Cláudio José DE ARAUJO MOTA, José Luiz FONTES MONTEIRO, Débora Prado BATISTA PEIXOTO, Adriano DO COUTO FRAGA, Ana Carlota BELIZARIO DOS SANTOS, Antonio Marcos FONSECA BIDART, Fernando Barbosa DE OLIVEIRA, Henrique Soares CERQUEIRA, Isabela Brito DOS SANTOS, Marcos DE FREITAS SUGAYA
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Patent number: 7601254Abstract: A process for the conversion of a hydrocarbon feedstock to produce olefins, aromatic compounds and ultra low sulfur diesel wherein the hydrocarbon feedstock is reacted in a fluid catalytic cracking (FCC) zone to produce olefins and light cycle oil. The effluent from the FCC is preferably separated to produce a stream comprising ethylene and propylene, a stream comprising higher boiling olefins and light cycle oil (LCO). The stream containing the higher boiling olefins is cracked to provide additional ethylene and propylene. The LCO is selectively hydrocracked to produce aromatic compounds and ultra low sulfur diesel.Type: GrantFiled: May 19, 2005Date of Patent: October 13, 2009Assignee: UOP LLCInventor: Christopher D. Gosling
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Patent number: 7579513Abstract: The invention concerns a process for producing propylene, especially from a light steam cracking and/or catalytic cracking cut, preferably comprising both butenes and pentenes, said process comprising a step for moving bed catalytic cracking with a catalyst regeneration loop. The catalyst comprises at least one zeolite with a zeolitic composition with a Si/Al ratio which is preferably less than 130. The invention can produce a high conversion with a good yield of propylene at a high space velocity, meaning that the volume of catalyst can be reduced.Type: GrantFiled: September 2, 2004Date of Patent: August 25, 2009Assignee: Institut Francais du PetroleInventors: Jean Luc Duplan, Sylvie Lacombe
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Publication number: 20090192343Abstract: Processes for producing one or more olefins are provided. In one or more embodiments, a doped catalyst can be prepared by fluidizing one or more coked-catalyst particles in the presence of one or more oxidants to provide a fluidized mixture. At least a portion of the coke can be removed from the coked-catalyst particles to provide regenerated catalyst particles. One or more doping agents can be distributed throughout the fluidized mixture, depositing on the surface of the regenerated catalyst particles to provide doped catalyst particles. One or more hydrocarbon feeds can be fluidized with the doped catalyst particles to provide a reaction mixture which can be cracked to provide a first product containing propylene, ethylene, and butane.Type: ApplicationFiled: January 29, 2008Publication date: July 30, 2009Inventor: PRITHAM RAMAMURTHY
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Patent number: 7563743Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).Type: GrantFiled: September 8, 2005Date of Patent: July 21, 2009Assignee: Institute Francais du PetroleInventors: Patrick Euzen, Alexandra Chaumonnot, Carole Bobin, Patrick Bourges, Christophe Gueret, Hugues Dulot
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Publication number: 20090182185Abstract: The present invention provides a method and apparatus for removing acetylene from a gasoeus mixture comprising hydrogen, methane, ethane, ethylene, acetylene, propane, propylene, butane, butenes, butadiene, and other C4 or higher hydrocarbons. The method of the invention utilizes a front-end acetylene removal unit (“ARU”) located after a charge gas compressor in which acetylene is selectively reduced. The method of the invention achieves selective reduction of acetylene by using a proprietary Chevron Phillips E series palladium based catalyst. The method of the invention also utilizes a novel startup procedure, a novel emergency shutdown procedure, a novel maximum cool down procedure, and a novel carbon monoxide monitoring procedure.Type: ApplicationFiled: March 27, 2009Publication date: July 16, 2009Applicant: Eastman Chemical CompanyInventors: James Michael Jordan, Kevin Hunter McGuire, Daryl Bitting, Randall Lloyd Lamirand, James Joseph Cerrato, Ronnie Paul Pertuit, George Michael McLeod, Yao-Ching Liu
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Publication number: 20090182184Abstract: The invention is to provide a catalyst for long-term, high-yield and stable production of ethylene and propylene in an efficient and simple method of catalytic conversion from a hydrocarbon material. The invention relates to a method for producing ethylene and propylene by contacting a hydrocarbon material that contains an olefin having from 4 to 12 carbon atoms in an amount of at least 20% by weight, with a zeolite-containing shaped catalyst satisfying the following requirements (1) to (4), in a reactor for catalytic conversion of that olefin: (1) the zeolite is an intermediate pore-size zeolite having a pore size of from 5 to 6.5 angstroms, (2) the zeolite does not substantially contain a proton, (3) the zeolite contains at least one metal selected from the group consisting of metals belonging to the Group IB of the Periodic Table, (4) the zeolite has a silica/alumina molar ratio (SiO2/Al2O3 molar ratio) of from 800 to 2,000.Type: ApplicationFiled: September 14, 2006Publication date: July 16, 2009Inventors: Yoshikazu Takamatsu, Kouji Nomura
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Patent number: 7560020Abstract: Tar is contacted with stripping agent, such as steam or tail gas, in a stripping tower. A product comprising deasphalted tar is recovered as overheads and a product comprising heavy tar is recovered as bottoms from the stripping tower.Type: GrantFiled: October 30, 2006Date of Patent: July 14, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Subramanian Annamalai, James N McCoy, Paul F Keusenkothen
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Patent number: 7550073Abstract: The present invention relates to new crystalline molecular sieve SSZ-70 prepared using a N,N?-diisopropyl imidazolium cation as a structure-directing agent, methods for synthesizing SSZ-70 and processes employing SSZ-70 in a catalyst.Type: GrantFiled: November 2, 2005Date of Patent: June 23, 2009Assignee: Chevron U.S.A., Inc.Inventors: Stacey I. Zones, Allen W. Burton, Jr.
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Patent number: 7547813Abstract: A catalyst composition suitable for reacting hydrocarbons such as in fluidized catalytic cracking (FCC) comprises an attrition-resistant particulate having at least 30% of an intermediate pore zeolite, kaolin, a phosphorous compound, and a high density unreactive component. An example of an unreactive component is alpha-alumina. The catalyst can also contain a reactive alumina of high surface area.Type: GrantFiled: September 23, 2008Date of Patent: June 16, 2009Assignee: BASF Catalysts LLCInventors: Gary M. Smith, Barry K. Speronello
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Publication number: 20090137857Abstract: A method for preparation of ethylene and propylene by catalytic cracking using a fluid-bed catalyst. The main technical problems to be solved are a relatively high reaction temperature, and low activities and poor selectivities of the catalyst at a low temperature, during the reaction for preparing ethylene and propylene by catalytically cracking naphtha. The fluid-bed catalyst is a composition of the chemical formula Mo1.0VaAbBcCdOx based on stoichiometric ratio. The method using the fluid-bed catalyst has satisfactorily solved the above-mentioned problems, and is useful in the industrial production of ethylene and propylene by catalytically cracking naphtha.Type: ApplicationFiled: February 3, 2009Publication date: May 28, 2009Inventors: Zaiku XIE, Hui Yao, Weimin Yang, Guangwei Ma, Jingxian Xiao, Liang Chen
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Patent number: 7537685Abstract: The present invention relates to new molecular sieve SSZ-71 prepared using a N-benzyl-1,4-diazabicyclo[2.2.2]octane cation as a structure-directing agent, methods for synthesizing SSZ-71 and processes employing SSZ-71 in a catalyst.Type: GrantFiled: November 2, 2005Date of Patent: May 26, 2009Assignee: Chevron U.S.A. Inc.Inventors: Cong-Yan Chen, Allen W. Burton, Jr., Ann J. Liang
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Patent number: 7531706Abstract: A process for producing olefin by catalytic cracking of hydrocarbon material characterized in employing zeolite of penta-sil type comprising rare earth elements and at least one of manganese or zirconium as a catalyst. It enables to produce light olefin such as ethylene, propylene, and so on with selectively high yield and with long term stability, by catalytic cracking of gaseous or liquid hydrocarbon as ingredients under lower temperature than the conventional method and suppressing by-product such as aromatic hydrocarbon or heavy substances.Type: GrantFiled: October 21, 2003Date of Patent: May 12, 2009Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kenichi Wakui, Yoshihiro Nakamura, Mitsuaki Hayashi
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Publication number: 20090112038Abstract: Systems and processes for producing one or more olefins are provided. A feed containing butane can be dehydrogenated to provide a first product containing butene. A refinery hydrocarbon can be cracked in a first riser of a fluidized catalytic cracker to provide a first effluent comprising ethylene, propylene, or a combination thereof. The first product can bypass an etherification reactor for converting isobutylene to methyl tert-butyl ether, and can be cracked in a second riser of the fluidized catalytic cracker to provide a second effluent comprising propylene, ethylene, and butane. The first and second effluents can be combined to provide a second product comprising ethylene, propylene, or a combination thereof, wherein the conditions in the first and second riser are independently selected to favor production of ethylene, propylene, or any combination thereof.Type: ApplicationFiled: October 30, 2007Publication date: April 30, 2009Inventor: Curtis N. Eng
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Publication number: 20090112039Abstract: Systems and processes for producing one or more olefins are provided. A feed containing C4 compounds can be dehydrogenated to provide a first product containing butene. At least a portion of the first product can be bypassed around a methyl-tert-butyl-ether production unit and cracked in a first cracker to provide a second product containing propylene, ethylene, and butane. A light hydrocarbon containing gas oils, full range gas oils, resid or any combination thereof can be cracked in a second cracker to provide a cracked hydrocarbon containing propylene, ethylene, and butane. An alkane can be cracked in a third cracker to provide cracked alkanes containing propylene, ethylene, and butane. The second product, cracked hydrocarbons, and cracked alkanes can be combined and separated to provide a third product containing propylene and a first recycle containing butane. At least a portion of the first recycle can be recycled to the first product prior to cracking.Type: ApplicationFiled: October 30, 2007Publication date: April 30, 2009Inventor: Curtis N. Eng
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Patent number: 7518027Abstract: A process for the production of a mono-olefin from a feedstock comprising a paraffinic hydrocabon which process comprises a) partially combusting at a pressure of at least (15) barg a mixture of the hydrocarbon feed and a molecular oxygen-containing gas in contact with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability where they are reacted to form a product comprising one or more mono-olefin(s), carbon monoxide and hydrogen and b) recovering the one or more olefin(s).Type: GrantFiled: February 6, 2003Date of Patent: April 14, 2009Assignee: Innovene Europe LimitedInventors: Andrew Lindsay Burns, David Charles Griffiths, William Terence Woodfin
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Patent number: 7491315Abstract: A dual riser FCC process is disclosed wherein first and second hydrocarbon feeds (5, 6) are supplied to the respective first and second risers (2, 4) to make an effluent rich in ethylene, propylene and/or aromatics. Where the hydrocarbon feeds are different, the respective risers can have different conditions to favor conversion to ethylene and/or propylene. A minor amount of a coke precursor (80, 82) can be added to one or both of the hydrocarbon feeds (5, 6) to reduce or eliminate the amount of supplemental fuel needed to heat balance the system. The different feeds, including the coke precursor and any recycle streams (36, 44) can be segregated by type to improve olefin yields, including an embodiment where the paraffinic feeds are supplied to one riser and the olefinic feeds to the other.Type: GrantFiled: August 11, 2006Date of Patent: February 17, 2009Assignee: Kellogg Brown & Root LLCInventors: Curtis N. Eng, Rik B. Miller
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Publication number: 20090023971Abstract: A catalyst composition suitable for reacting hydrocarbons such as in fluidized catalytic cracking (FCC) comprises an attrition-resistant particulate having at least 30% of an intermediate pore zeolite, kaolin, a phosphorous compound, and a high density unreactive component. An example of an unreactive component is alpha-alumina. The catalyst can also contain a reactive alumina of high surface area.Type: ApplicationFiled: September 23, 2008Publication date: January 22, 2009Inventors: Gary M. Smith, Barry K. Speronello