Polymer Patents (Class 585/10)
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Patent number: 11407959Abstract: Described herein is a process, comprising: a) selecting an API Group II base stock with selected viscosity index and pour point; b) blending a base oil with the base stock, and c) adding to the base oil: i) a liquid ethylene propylene copolymer viscosity modifier that reduces a traction coefficient, and ii) an additive package, to make a driveline fluid that has a defined viscosity index and excellent shear stability. Also provided is a driveline fluid composition having the high viscosity index and excellent shear stability, comprising: a) a base oil comprising from 50 wt % to 100 wt % API Group II base stock; b) a liquid ethylene propylene copolymer viscosity modifier that reduces a traction coefficient; and c) an additive package. Further provided is a method for lubricating an axle or manual transmission by supplying the driveline fluid composition.Type: GrantFiled: July 28, 2016Date of Patent: August 9, 2022Assignees: The Lubrizol Corporation, Chevron U.S.A. Inc.Inventors: Hyun-Soo Hong, John Aleksonis Zakarian, Sona Sivakova, Tomoya Higuchi, Christopher Engel, Farrukh Qureshi
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Patent number: 11072759Abstract: Provided are: a lubricating oil composition containing a mineral oil (A) having a kinematic viscosity at 40° C. of 5 to 15 mm2/s and a flash point of 180° C. or higher, a synthetic oil (B) having a kinematic viscosity at 40° C. of 5 to 15 mm2/s and a flash point of 190° C. or higher, an amide compound (C) and a polyol ester compound (D), which has a low viscosity and fuel saving performance, which can be used in high-temperature environments, and which has excellent gear anti-seizing property and anti-shudder performance; and a lubrication method and a transmission using the lubricating oil composition.Type: GrantFiled: February 28, 2017Date of Patent: July 27, 2021Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Keiichi Narita
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Patent number: 10611980Abstract: A lubricant composition comprising a high-viscosity PAO lubricant base stock having a KV100 of at least 200 cSt and comprising multiple PAO molecules comprising at least 200 carbon atoms per molecule, wherein (i) each of the PAO molecules comprises multiple pendant groups; (i) the average pendant group length of all the pendant groups excluding one methyl on each of the PAO molecules among at least 90 mol % of all of the PAO molecules, if one or more methyl is present, is at least 6.0, and (iii) the concentration of the high-viscosity PAO base stock is no more than 75 wt % of the total weight of the lubricant composition. The lubricant composition exhibits provides a high degree of protection of gear surfaces as measured by ASTM D5182.Type: GrantFiled: December 19, 2017Date of Patent: April 7, 2020Assignee: ExxonMobil Chemical Patents Inc.Inventors: Wenning W. Han, Marco A. Calzada
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Patent number: 10240102Abstract: Disclosed herein are oligomerization processes using feedstocks containing 1-hexene to produce an oligomer product, and methods for recovering a heavy 1-hexene oligomer from the oligomer product and hydrogenating the heavy 1-hexene oligomer. The resultant hydrogenated heavy 1-hexene oligomer can be blended with other PAO's to form 100 cSt and 40 cSt lubricant compositions, which have viscosity index and pour point properties that are equivalent to or better than respective 100 cSt and 40 cSt 1-decene PAO's.Type: GrantFiled: March 16, 2017Date of Patent: March 26, 2019Assignee: Chevron Phillips Chemical Company, LPInventors: Brooke L. Small, Yemi Oyerinde, Russell J. Bak, Jeff C. Gee
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Patent number: 10151663Abstract: A leak detection system for a refrigerant circuit is provided. The refrigerant circuit is sealed and circulates a working fluid having a refrigerant (e.g., flammable refrigerant) and an oil. A reducing tag component is solubilized within the refrigerant. The leak detection system also includes a sensor for detecting the tag component if the refrigerant should leak from the refrigerant circuit. The sensor is highly sensitive to the tag component and thus enhanced detection is enabled. The tag component is stable in the working fluid and does not affect the flammability rating or performance of the refrigerant or oil. The tag component is present at a concentration of from about 50 ppm to about 35,000 ppm in the refrigerant. Methods of detecting leaks from refrigeration systems are also provided.Type: GrantFiled: September 14, 2016Date of Patent: December 11, 2018Assignee: Emerson Climate Technologies, Inc.Inventor: Marc Joseph Scancarello
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Patent number: 9745230Abstract: Methods for making alpha olefin oligomers and polyalphaolefins include a step of contacting a C4 to C20 alpha olefin monomer and a catalyst system containing a metallocene, a first activator comprising a solid oxide chemically-treated with an electron withdrawing anion, and a second activator comprising an organoaluminum compound. The alpha olefin oligomers and polyalphaolefins prepared with these catalyst systems can have a high viscosity index combined with a low pour point, making them particularly useful in lubricant compositions and as viscosity modifiers.Type: GrantFiled: April 7, 2016Date of Patent: August 29, 2017Assignee: Chevron Phillips Chemical Company LPInventors: Brooke L. Small, Kenneth D. Hope, Qing Yang, Albert P. Masino, Max P. McDaniel, Richard M. Buck, William B. Beaulieu, Eduardo J. Baralt, Eric J. Netemeyer, Bruce Kreischer
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Patent number: 9023191Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 9023190Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: May 5, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 8992762Abstract: A lubricating oil composition for an internal combustion engine contains: a base oil including a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPa·s or less and a NOACK of 12 mass % or less and a component (B) of a mineral oil having a viscosity index of 120 or more; and polyisobutylene having a mass average molecular weight of 500,000 or more. A content of the composition (A) is 25 mass % or more of a total amount of a lubricating oil.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Patent number: 8992763Abstract: A lubricating oil composition for an internal combustion engine contains a component (A) of a polyalphaolefin having a kinematic viscosity at 100 degrees C. of 5.5 mm2/s or less, a CCS viscosity at ?35 degrees C. of 3000 mPA·s or less and a NOACK of 12 mass % or less, and a component (B) of a mineral oil having a viscosity index of 120 or more. The component (A) is contained at a content of 10 mass % or more of a total amount of the composition.Type: GrantFiled: March 31, 2011Date of Patent: March 31, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuhiro Teshima, Motoharu Ishikawa
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Publication number: 20150011807Abstract: A highly efficient method for the conversion of a natural product into the high density fuel RJ-4 with concomitant evolution of isobutylene for conversion to fuels and polymers, more specifically, embodiments of the invention relate to efficient methods for the conversion of the renewable, linear terpene alcohol, linalool into a drop-in, high density fuel suitable for ramjet or missile propulsion.Type: ApplicationFiled: September 5, 2012Publication date: January 8, 2015Inventors: Benjamin G. Harvey, Heather A. Meylemans, Roxanne L. Quintana
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Patent number: 8846991Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.Type: GrantFiled: June 17, 2010Date of Patent: September 30, 2014Assignee: Dow Global Technologies LLCInventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. VanderLende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
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Patent number: 8795112Abstract: An oil-free chain is constructed by alternately connecting a pair of outer link plates connected using pins and a pair of inner link plates connected using oil-impregnated bushings into which the adjacent pins of the outer link plates adjacent to the inner link plates are fitted. The oil-impregnated bushings are impregnated with a lubricant having a kinematic viscosity in the range of ISO-VG grade 46 to 460, the weight % of an ingredient having the highest content among the elution ingredients obtained by the GPC method is 95 wt % or more, Mn is 800 or more and 2300 or less, and the ratio of Mw to Mn is 1.0 or more and 1.3 or less. Oil film breakage at the sliding portions of the bushings is suppressed from occurring and the oil film strength is high such that an oil-free chain has a sufficiently long abrasion elongation-resistant life.Type: GrantFiled: July 24, 2008Date of Patent: August 5, 2014Assignee: Tsubakimoto Chain Co.Inventor: Koji Tanaka
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Patent number: 8642524Abstract: The present invention is directed to a method for controlling soot induced viscosity increase in diesel engines, by using as the diesel engine lubricant an oil formulation comprising a base oil containing about 10 to 80 wt % GTL base stock and/or base oil and/or hydrodewaxed or hydroisomerized/catalytic (or solvent) dewaxed base stock and/or base oil in combination with 20 to 90 wt % conventional Group I petroleum derived base oil, said base oil being further combined with a polymeric viscosity modifier, and to the lubricating oil which effects such control over soot induced viscosity increase.Type: GrantFiled: October 11, 2012Date of Patent: February 4, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Heather M. Haigh, Brandon Thomas Weldon, Jason Zhisheng Gao
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Patent number: 8642523Abstract: The present invention is directed to a method for improving the fuel efficiency of engine oil compositions by reducing the traction coefficient of the oil by formulating the oil using a blend of one or more first base stock(s) selected from Group II base stock, Group III base stock and Group IV base stock and a second base stock selected from polyisobutylene (PIB) and, preferably, additized with a detergent.Type: GrantFiled: January 28, 2011Date of Patent: February 4, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Kevin L. Crouthamel, Vincent M. Carey
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Publication number: 20130340325Abstract: Fouling components within a fluid may be prevented from accumulating when an additive contacts the fluid, e.g. by coating the wellbore with the additive prior to the production of the fluid or adding the additive directly to a produced fluid, etc. The additive may include, but is not limited to, a block copolymer having at least two components. The first component may be a charged monomer, and the second component may be a long chain fatty alcohol acrylate monomer. In one alternative embodiment, the fluid may be a hydrocarbon fluid, and the fouling components may be or include, but are not limited to wax, paraffins, asphaltene, resins, and combinations thereof.Type: ApplicationFiled: June 17, 2013Publication date: December 26, 2013Inventor: Richard Duffy
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Patent number: 8546306Abstract: The invention relates to an aqueous dispersion comprising microcapsules, the capsule wall of which is formed from radically polymerized monomers and the capsule core of which comprises at least one oil, in which the capsule core comprises at least one lipophilic surfactant and the continuous phase of the dispersion comprises at least one agrochemical. In addition, the invention relates to a process for the preparation of an aqueous dispersion by (i) providing an aqueous dispersion comprising microcapsules, the capsule wall of which is formed from radically polymerized monomers and the capsule core of which comprises at least one oil and at least one lipophilic surfactant (microcapsule crude dispersion), and (ii) mixing with at least one agrochemical.Type: GrantFiled: February 4, 2009Date of Patent: October 1, 2013Assignee: BASF SEInventors: Tatjana Levy, Marc Rudolf Jung, Rainer Berghaus, Hans-Peter Hentze, Tobias Joachim Koplin, Jurith Montag, Anke Reinold, Christian Sowa
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Publication number: 20130239465Abstract: The cold flow of middle distillate fuels may be improved by adding an effective improving amount of one or more alpha-olefin compositions. The compositions include, but are not necessarily limited to, polymers of alpha-olefins per se, copolymerized or grafted alpha-olefins with maleic anhydride, acrylic acid, vinyl acetate, alkyl acrylates, methacrylic acid, and/or alkyl methacrylates. These resulting copolymers or grafted polymers may be blended with alkylphenol-formaldehyde resins, which in turn may be blended with ethylene-vinyl acetate (EVA) copolymer. In a non-limiting example, the cold filter plugging point (CFPP) may be synergistically improved as compared with the expected additive effect of using the components separately.Type: ApplicationFiled: March 6, 2013Publication date: September 19, 2013Applicant: Baker Hughes IncorporatedInventors: Ben Morgan, John A. Schield, Paul J. Biggerstaff, Kimchi T. Phan, Jack Bradford Ward
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Patent number: 8530712Abstract: This disclosure relates to a liquid syndiotactic polyalphaolefin, sPAO, comprising one or more C4 to C24 monomers, said sPAO having: a) an rr triad content of 5 to 50% as measured by 13C NMR; b) an mr triad content of 25 to 60% as measured by 13C NMR, where the mr to mm triad ratio is at least 1.0; c) a pour point of Z ° C. or less, where Z=0.0648X?51.2, where X=kinematic viscosity at 100° C. as reported in centistokes (cSt); d) a kinematic viscosity at 100° C. of 100 cSt or more (alternatively 200 cSt or more); e) a ratio of mr triads to rr triad (as determined by 13C NMR) of less than 9; f) a ratio of vinylidene to 1,2-disubstituted olefins (as determined by 1H NMR) of less than 8; g) a viscosity index of 120 or more; and h) an Mn of 40,000 or less. This disclosure further relates to processes to make and use sPAOs, including those having any combination of characteristics a) to h).Type: GrantFiled: December 17, 2010Date of Patent: September 10, 2013Assignee: Exxonmobil Chemical Patents Inc.Inventors: Margaret M. Wu, Steven P. Rucker, Jo Ann M. Canich
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Publication number: 20130143782Abstract: Lubricating oil compositions, formulated to a preselected viscosity grade that demonstrate stay-in-grade capability in a diesel injector shear stability test, are provided. The compositions comprise a major amount of a base oil of lubricating viscosity and a minor amount of (i) a viscosity modifier (VM) or mixtures thereof having a low shear stability index (SSI) and (ii) a VM or mixtures thereof having an SSI greater than that of the VM from (i).Type: ApplicationFiled: October 31, 2012Publication date: June 6, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventor: EXXONMOBIL RESEARCH AND ENGINEERING
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Patent number: 8426659Abstract: This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.Type: GrantFiled: March 25, 2011Date of Patent: April 23, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Matthew W. Holtcamp, Charles J. Ruff, Donna J. Crowther, John R. Hagadorn, Patrick Brant
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Patent number: 8425630Abstract: The invention includes a method of improving the combustion efficiency of a fuel-burning device. The method includes the steps of adding a low molecular weight polymer to the fuel of the fuel-burning device and burning the fuel with the polymer in the fuel-burning device. The invention also includes fuel compositions containing such polymers.Type: GrantFiled: January 18, 2011Date of Patent: April 23, 2013Assignee: Himmelsbach Holdings, LLCInventors: Paul F. Waters, John B. Waters
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Patent number: 8415284Abstract: A lubricating oil composition and methods of operating an internal combustion engine to provide improved engine operation. The lubricating composition includes a major amount of oil of lubricating viscosity and a minor amount of at least one olefin copolymer having a number average molecular weight greater than about 10,000 up to about 300,000. The olefin copolymer is grafted with (A) a vinyl-substituted aromatic compound, and (B) a compound selected from the group consisting of a C5-C30 olefin, a polyalkylene compound, and mixtures thereof. A mole ratio of A/B in the reaction mixture ranges from about 0.25:1 to about 5:1. The lubricating composition optionally includes a minor amount of at least one non-grafted olefin copolymer, styrene-isoprene copolymer, methacrylate copolymer, or styrene butadiene copolymer have number average molecular weight greater than about 50,000 up to about 300,000.Type: GrantFiled: November 5, 2009Date of Patent: April 9, 2013Assignee: Afton Chemical CorporationInventor: Akhilesh Duggal
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Patent number: 8399390Abstract: The invention relates to industrial lubricant and grease compositions containing high viscosity index polyalphaolefins (HVI-PAO). The use of HVI-PAOs in industrial oils and greases application provides advantages in improved shear stability, wear property, foam property, energy efficiency and improved overall performance.Type: GrantFiled: June 29, 2005Date of Patent: March 19, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Margaret May-Som Wu, Andrew Jackson, Walter David Vann, James Thomas Carey, Norman Yang, Suzzy Chen Hsi Ho
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Patent number: 8399724Abstract: This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.Type: GrantFiled: March 25, 2011Date of Patent: March 19, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Donna J. Crowther, Matthew W. Holtcamp, John R. Hagadorn, Charles J. Ruff, George Rodriguez, Patrick Brant
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Patent number: 8389780Abstract: The invention is directed to polyalphaolefins (PAOs) and processes for forming PAOs. In one embodiment, the invention is to a process for forming a PAO comprising polymerizing C8-C12 ?-olefin monomers in the presence of hydrogen, a C8-C12 saturated hydrocarbon, e.g., a C8-C12 saturated straight-chain hydrocarbon, and a catalyst system in a reaction vessel, wherein the C8-C12 saturated straight-chain hydrocarbon has about the same number of carbon atoms as the C8-C12 ?-olefin monomers. The C8-C12 saturated straight-chain hydrocarbon optionally is derived from a crude PAO product formed by the process of the invention. The invention is also directed to reaction systems for performing the processes of the invention, to processes for controlling PAO viscosity based on residence time, and to the removal of spent catalyst using a solid adsorbent particles.Type: GrantFiled: December 17, 2010Date of Patent: March 5, 2013Assignee: Chemtura CorporationInventors: Daniel C. Knowles, Jesus R. Fabian, Vilan Kosover, Susan Ferrarotti, E. Brian Fox, Frank DeBlase
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Patent number: 8318846Abstract: An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition. The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending.Type: GrantFiled: November 10, 2006Date of Patent: November 27, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Yuichi Ito, Hidenari Nakahama, Kotaro Ichino
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Publication number: 20120165580Abstract: A method for preparing a liquid polyolefin which includes contacting a feedstock comprising at least one olefin monomer with a catalyst system to produce a reactor effluent stream, filtering the reactor effluent stream, washing a created filter cake with a warm wash fluid comprising at least one hydrocarbon liquid, separating at least a portion of the wash fluid during the washing, sending said portion of the wash fluid through a distillation process, and recovering at least a portion of the liquid polyolefin that was in the filter cake. The catalyst system may be any conventional polyolefin catalyst system and, in any preferred embodiment of the invention, the catalyst system contains at least one activated metallocene catalyst. The reactor effluent stream comprises at least one liquid polyolefin, residual catalyst, and unreacted olefin monomer.Type: ApplicationFiled: January 17, 2012Publication date: June 28, 2012Inventors: Kenneth A. Bahler, Aaron L. Wetterlind, Patrick R. Ford, Derrick L. Laton
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Patent number: 8193135Abstract: Process for the preparation of viscosity index improver (V.I.I.) additives of lubricating oils which comprises a mixing treatment under high shear conditions of a composition comprising: (i) one or more EP(D)M polymers (ii) one or more polyvinylarene/conjugated hydrogenated polydiene/polyvinylarene block copolymers; and (iii) lubricating oil, (ii) being present in a concentration of 1.5 to 20% by weight whereas (iii) is present in a concentration ranging from 1.5 to 45% by weight.Type: GrantFiled: February 12, 2007Date of Patent: June 5, 2012Assignee: Polimeri Europa S.p.A.Inventor: Tiziano Tanaglia
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Patent number: 8105992Abstract: The invention relates to viscosity modifier polymers, concentrate and lubricant formulations utilizing a diblock polymer having one block A and one block B, block A contributing from 15 to 30% of the total chain length and block B from 70 to 85% of the total chain length, wherein block A comprises at least 93 wt % of ethylene and at least one other alpha-olefin and block B comprises an ethylene content between 40 and 75 wt % and at least one other alpha-olefin and wherein the resulting block copolymer has an average ethylene content of between about 60 wt % to 80 wt % ethylene, a fast Gaussian NMR relaxation signal between 17 and 22% and a slow exponential NMR relaxation signal between 58 and 68% of the total NMR relaxation signal, a SSI of at least 35% and a TE of at least 3.5 in order to obtain improvements in fuel economy.Type: GrantFiled: May 7, 2007Date of Patent: January 31, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jean-Roch Schauder, Kirk Alan Nass, Periagaram Srinivasan Ravishankar, Karine Vincent
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Publication number: 20110137091Abstract: In oligomerizing alpha-olefins to produce poly alpha-olefins, the feedstock consists of nonene, or a blend of alpha-olefins comprising nonene. The nonene comprising alpha-olefin feedstock and at least one catalyst are subjected to oligomerization or polymerization conditions in a reactor. Following reaction, the mixture may be subjected to distillations to removed unreacted alpha-olefins and dimers of the alpha-olefins. The resulting product may also be hydrogenated. The final product may also be fractioned to recover at least two fractions of poly alpha-olefins of differing nominal viscosities.Type: ApplicationFiled: November 8, 2010Publication date: June 9, 2011Inventors: Norman Yang, Phillip T. Matsunaga, Maria C.B. Goze
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Patent number: 7884256Abstract: Higher diamondoid derivatives capable of taking part in polymerization reactions are disclosed as well as intermediates to these derivatives, polymers formed from these derivatives and methods for preparing the polymers.Type: GrantFiled: December 17, 2004Date of Patent: February 8, 2011Assignee: Chevron U.S.A. Inc.Inventors: Shenggao Liu, Robert M. Carlson, Jeremy E. Dahl
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Patent number: 7851422Abstract: A quenching oil for reduced pressure quenching which comprises a base oil having a kinematic viscosity at 40° C. of 40 mm2/s or more and a vapor blanket breaking agent; and a method for quenching wherein the quenching oil is used and quenching is carried out while adjusting the pressure on the surface of the oil. The method allows the achievement of cooling characteristics over a wide range from those conventionally achieved by a cold oil to those by a hot oil, by the use of a single quenching oil.Type: GrantFiled: March 9, 2005Date of Patent: December 14, 2010Assignee: Idemitsu Kosan Co., Ltd.Inventors: Katsumi Ichitani, Makoto Takeishi
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Publication number: 20100286457Abstract: A gear oil composition is provided. The composition comprises a synergistic blend of mineral oil base stock and polyalphaolefin (PAO) base stock for the oil composition to have a traction coefficient at a slide to roll ratio of 40 percent at 15 mm2/s. of 0.030 or less and a pressure viscosity coefficient of at least 16.0 at 80° C., 20 Newton load, and 1.1 m/s rolling speed. In one embodiment, the synergistic amount of PAO base stock ranges from 5 to 48 wt. % based on the total weight of the gear oil composition.Type: ApplicationFiled: June 23, 2010Publication date: November 11, 2010Inventors: Allan G. Hee, Trevor Miller
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Patent number: 7795365Abstract: The subject invention pertains to homogeneous liquid low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 10%, and a pour point, as measured by ASTM D97, of less than 50° C. The subject invention also pertains to homogeneous gel-like low molecular weight ethylene/alpha-olefin polymers having a number average molecular weight (Mn) as determined by gel permeation chromatography, of less than 25,000, a total crystallinity, as measured by DSC, of less than 50%, and a pour point, as measured by ASTM D97, of less than 90° C.Type: GrantFiled: October 1, 2003Date of Patent: September 14, 2010Assignee: Dow Global Technologies Inc.Inventors: Teresa P. Karjala, Selim Yalvac, Thomas Karjala, Daniel D. Vanderlende, Brian W. Kolthammer, James C. Stevens, Charles F. Diehl
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Patent number: 7741256Abstract: A lubricant composition contains poly-?-olefin oil having a kinematic viscosity of 1500 to 13000 mm 2/s (40° C.) as a base oil and from 45 to 50% by weight of a thickener composed of polytetrafluoroethylene. The lubricant composition may be used for lubricating an expandable shaft having a pair of shaft members filled with the lubricant composition to prevent stick-slip from occurring when a high surface pressure is applied thereto, thereby allowing consistent maintenance of good lubricating performance. Such an expandable shaft may be incorporated advantageously into a steering system as an intermediate shaft into an area between a steering shaft and a rack-and-pinion mechanism.Type: GrantFiled: March 8, 2007Date of Patent: June 22, 2010Assignee: JTEKT CorporationInventors: Fumiaki Kasahara, Satoshi Kakutani, Kazuto Minagawa
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Publication number: 20100062954Abstract: The invention provides a transmission fluid composition which has a kinematic viscosity as determined at 100° C. of 2 to 10 mm2/s and a viscosity index of 150 or higher and which satisfies a relationship between kinematic viscosity and NOACK evaporation loss amount represented by formula (I): X/3+Y?6.33??(I) (wherein X represents a kinematic viscosity (mm2/s) as determined at 100° C., and Y represents a NOACK evaporation loss amount (mass %) at 200° C. for one hour), and a transmission fluid composition containing, as a base oil, at least one species selected from among ?-olefin oligomers produced through oligomerization of an ?-olefin through a specific method and hydrogenation products of the oligomers. Such transmission fluid compositions exhibit a very small evaporation loss despite having low viscosity, and a long metal fatigue life (e.g.Type: ApplicationFiled: November 15, 2006Publication date: March 11, 2010Applicant: Idemitsu Kosan Co., LtdInventor: Hiroshi FUJITA
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Patent number: 7345017Abstract: An amphiphilic functional substance with lipophilicity, affinity for supercritical CO2, and if necessary hydrophilicity comprising an oligoolefin chain and a perfluoroalkyl group(s) at a single end thereof or at both ends thereof with or without the intervention of a poly(oxyalkylene) chain, which enables the utilization of supercritical CO2 as a reaction medium; a photopolymerizable functional substance comprising an oligoolefin chain and a reversible photopolymerization/dissociation group(s) at a single end thereof or at both ends thereof and a functional substance comprising a photo- and/or thermodissociable polymer obtained by photopolymerization of the aforementioned photopolymerizable functional substance, which can be utilized as recycle polymers; a hydrolyzable functional substance comprising a polymer obtained by chain-elongating plural oligoolefin chains through ester linkages, which can be utilized as a recycle polymer; and a functional substance capable of forming a microphase separation structureType: GrantFiled: January 18, 2007Date of Patent: March 18, 2008Assignee: San-El Kougyou CorporationInventor: Takashi Sawaguchi
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Patent number: 7342143Abstract: A method for the processing of a polyalphaolefin feedstock having a concentration of organic halide to thereby yield a polyalphaolefin end-product having a low concentration of organic halide. The method includes a hydrogenation step whereby the polyalphaolefin feedstock is contacted under suitable reaction conditions with a specific hydrogenation catalyst composition that is resistant to halide deactivation. The hydrogenation catalyst comprises a noble metal on a support material comprising silica and alumina. The hydrogenated polyalphaolefin feedstock is further processed to remove the hydrogen halide produced during the hydrogenation step to yield the polyalphaolefin end-product.Type: GrantFiled: September 9, 2004Date of Patent: March 11, 2008Assignee: Shell Oil CompanyInventors: Peter Birke, Kristi Ann Morris, Hans-Dieter Neubauer, Rainer Schoedel
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Patent number: 7163913Abstract: A polymer suitable for use as a viscosity index improver for lubricating oil compositions, which is at least one, at least partially hydrogenated linear or star-shaped random copolymer of isoprene and butadiene, in which at least 70 wt. % of the butadiene is incorporated into the polymer as 1,4 units and the weight ratio of isoprene addition product to butadiene addition product in the copolymer is in a range of from about 90:10 to about 70:30.Type: GrantFiled: July 1, 2003Date of Patent: January 16, 2007Assignee: Infineum International LimitedInventors: Stuart Briggs, Chin Chu
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Patent number: 7129197Abstract: One or more oligomers of an olefin are prepared in the presence of a single-site catalyst. Preferably, the olefin is an ?-olefin, and the oligomers are a poly-alpha-olefin (PAO). The PAO so prepared is completely or substantially free of tertiary hydrogen resulting from isomerization. Consequently, the PAO possesses improved biodegradability, improved oxidation resistance, and/or a relatively higher viscosity index. The PAO has many useful applications, such as a component of a lubricant.Type: GrantFiled: August 29, 2002Date of Patent: October 31, 2006Assignee: Shell Oil CompanyInventors: Wei Song, William J. Heilman
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Patent number: 7018962Abstract: A viscosity index (VI) improver concentrate containing at least one VI improver, from 0 to about 5 mass % of lubricating oil flow improver (LOFI) and diluent oil, wherein the diluent oil has a kv100 of at least about 3.0 cSt and a CCS at ?35° C. of less than 3700 cPs, and wherein at least about 98 mass % of the concentrate is composed of VI improver, LOFI and diluent oil.Type: GrantFiled: June 12, 2003Date of Patent: March 28, 2006Assignee: Infineum International LimitedInventors: Ricardo A. Bloch, Jai G. Bansal, Dean B. Clarke
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Patent number: 7015255Abstract: (a) A medium oil wherein a main component is a hydrocarbon, and the number of paraffinic carbon atoms is 70% or more with respect to a total number of carbon atoms, (b) a medium oil wherein a main component is a polybutene, (c) a medium oil wherein a main component is a mixture of hydrocarbons of the formula (1): CH3—C(CH3)2—[—CH2—C(CH3)2—]n—CH2—R ??(1) wherein R is —CH(CH3)2 or —C(CH3)?CH2, and n is 1 to 10, (d) a medium oil wherein a main component is a hydrocarbon prepared by a Fischer-Tropsch synthesis, or (e) a medium oil wherein a main component is a branched paraffinic hydrocarbon prepared by hydrogenolysis of a hydrocarbon prepared by a Fischer-Tropsch synthesis, and a process of producing dimethyl ether using the medium oil, are disclosed.Type: GrantFiled: February 29, 2000Date of Patent: March 21, 2006Assignee: JFE Holdings, Inc.Inventors: Keiji Tomura, Takashi Ogawa, Masami Ono, Keiichi Okuyama, Seiji Aoki, Tsutomu Shikada, Masatsugu Mizuguchi, Yotaro Ohno
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Patent number: 7012046Abstract: A composition including a polyalphaolefin and at least one alfol alcohol that function as drag reducing agent slurries and a process for the preparation of the drag reducing agent slurries are disclosed. The process includes contacting alpha olefin monomers with a catalyst in a reactant mixture to form a polyalphaolefin. The polyalphaolefin is combined with at least one alfol alcohol to form a drag reducing agent slurry. A process for reducing drag in a conduit is also disclosed.Type: GrantFiled: June 8, 2001Date of Patent: March 14, 2006Inventors: Gerald B. Eaton, Alan K. Ebert
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Patent number: 6992049Abstract: The present invention provides a viscosity index improving lubricant additive which comprises an olefinic oligomer of about 2,000 to about 20,000 number average molecular weight having a viscosity of 75 to about 3,000 cSt at 100° C. and a hydrocarbyl aromatic which contains at least about 5% of its weight from aromatic moieties having a viscosity of about 3 to about 50 cSt at 100° C. where the weight ratio of hydrocarbyl aromatic component to olefin oligomer is from about 1:2 to about 50:1. In another aspect, the invention provides for a lubricating oil composition comprising a base oil and the instant viscosity index improving additive.Type: GrantFiled: January 28, 2003Date of Patent: January 31, 2006Assignee: ExxonMobil Research and Engineering CompanyInventors: Douglas E. Deckman, William L. Maxwell, William H. Buck, Mark D. Winemiller, David J. Baillargeon
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Patent number: 6989357Abstract: A composition including an alcohol absorbed polyalphaolefin that functions as a drag reducing agent and a process for the preparation of the drag reducing agent are disclosed. The process includes the steps of contacting alpha olefin monomers with at least one catalyst in a reactant mixture to form a polyalphaolefin. The polyalphaolefin is then contacted with at least one water insoluble alcohol for a period of time to provide an alcohol absorbed polyalphaolefin that is used as an improved drag reducing agent. Processes for reducing drag in a conduit are also disclosed.Type: GrantFiled: April 16, 2004Date of Patent: January 24, 2006Inventors: Gerald B. Eaton, Alan K. Ebert
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Patent number: 6969744Abstract: Disclosed is a method of preparing terminally functionalized telechelic polymers using a cationic living polymer product or a terminal tert-chloride chain end of a carbocationic quasiliving polymer product, which comprises quenching the polymer product with an N-substituted pyrrole to thereby functionalize the N-substituted pyrrole at the terminal reactive polymer chain end(s). Also disclosed are the terminal functionalized polyisobuyl N-substituted pyrrole compounds where the polyisobutyl group is substituted at the 2 and 3 position of the N-substituted pyrrole.Type: GrantFiled: June 19, 2003Date of Patent: November 29, 2005Assignees: University of Southern Mississippi, Chevron Oronite Company LLCInventors: Casey D. Stokes, Robson F. Storey, James J. Harrison
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Patent number: 6869917Abstract: The present invention relates to a fully formulated lubicants comprising poly ?-olefins (PAOs), prepared from a mixed ?-olefin feed, which exhibit superior Noack volatility at low pour points, and methods for preparing the fully formulated lubricants. The fully formulated lubricants include PAOs that include mixtures of 1-decene and 1-dodecene. The PAOs may be prepared by polymerization/oligomerization using an alcohol promoted BF3 in conjunction with a combination of co-catalysts.Type: GrantFiled: August 16, 2002Date of Patent: March 22, 2005Assignee: ExxonMobil Chemical Patents Inc.Inventors: Douglas E. Deckman, Mark D. Winemiller, William L. Maxwell, David J. Baillargeon, Norman Yang, Maria Caridad B. Goze
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Patent number: 6858765Abstract: A polyolefin wax for a coating material which includes an ethylene (co)polymer having a number-average molecular weight within the range of from 400 to 5000 as measured by gel permeation chromatography. The polyolefin wax has a volume average particle diameter in the range of from 0.3 ?m to 20 ?m wherein the relation between a particle diameter a (?m), in which the weight ratio of the large particle diameter side in weight particle-size distribution is 10%, and a particle diameter b (?m), in which the weight ratio of the small particle diameter side in weight particle size distribution is 10%, satisfies the a/b?4 and the relation between the crystallization temperature Tc (° C.), measured at a cooling rate of 2° C./min) as measured by differential scanning calorimetry (DSC) and the density D (kg/m3) as measured by the density gradient tube method satisfies the equation 0.501×D?366?Tc.Type: GrantFiled: October 23, 2002Date of Patent: February 22, 2005Assignee: Mitsui Chemicals, Inc.Inventor: Hideo Toyoda
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Publication number: 20040250467Abstract: Aviation fuel, such as jet fuel, blends and methods for improving cold flow properties of such fuels at extremely low temperatures are disclosed. Cold flow properties of, for example, JP-8+100 jet fuel, are improved by addition to the fuel of a polymer formed from polymerization of an &agr;-olefin monomer or monomers. Demonstratable cold flow improvement of such fuels at temperatures of about −53° C. and lower is shown.Type: ApplicationFiled: June 12, 2003Publication date: December 16, 2004Applicant: General Electric CompanyInventors: Fang Deng, William S. Carey, Sherif Eldin, Alan E. Goliaszewski