Dehalogenation Using Reactive Chemical Agents Able To Degrade (epo/jpo) Patents (Class 588/316)
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Patent number: 11607485Abstract: A system including tubing and a filter configured to be fluidly coupled to a vacuum source and to a heater/cooler unit by the tubing. The filter includes a filter container having negative air pressure in the filter container provided by the vacuum source to pull aerosol from the heater/cooler unit into the filter container and eliminate and/or reduce the aerosol emitted from the heater/cooler unit.Type: GrantFiled: September 14, 2016Date of Patent: March 21, 2023Assignee: Sorin Group Italia S.r.l.Inventors: Stephen W. Berch, Thierry Dupoux, Elisa Maculan, Giampaolo Simonini
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Patent number: 11150031Abstract: A heat transfer or storage medium containing a nitrate salt composition including at least one alkali metal nitrate and optionally alkaline earth metal nitrate; and, at least one alkali metal nitrite and optionally alkaline earth metal nitrite in an amount of 1.1 to 15.0 mol %. The molar amount of the alkali metal nitrite and optionally alkaline earth metal nitrite for a desired temperature is calculated by x nitrite = K 6 ? ( T ) K 6 ? ( T ) + P O ? ? 2 Xnitrite is the mole fraction of nitrite, K6(T) is the temperature-dependent equilibrium constant of the reaction nitrate ?nitrite+½ oxygen (NO3?? NO2?+½ O2), pO2 is the oxygen partial pressure and T is the temperature of the nitrate salt composition.Type: GrantFiled: April 20, 2017Date of Patent: October 19, 2021Assignee: BASF SEInventors: Juergen Wortmann, Sabine Weiguny, Katharina Federsel, Matthias Hinrichs, Stephan Maurer
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Patent number: 10618029Abstract: To provide an oxygen storage material that is capable of exhibiting an excellent oxygen storage capacity (OSC) even at a low temperature of about 300° C. and has a sufficiently high efficiency of use of cerium contained therein. An oxygen storage material including a ceria-zirconia-copper oxide-based composite oxide that contains cerium, zirconium, and copper, in which at least part of the copper is solid-dissolved in a composite oxide of the cerium and the zirconium, the ceria-zirconia-copper oxide-based composite oxide has a composition expressed by the following chemical formula (1): CexZryCuzO2-z??(1) where x, y, and z are numbers each satisfying conditions of x=0.3 to 0.7, y=0.15 to 0.7 (exclusive of y=0.7), z=0 to 0.15 (exclusive of z=0), and x+y+z=1, and a specific surface area of the ceria-zirconia-copper oxide-based composite oxide is 2 to 50 m2/g.Type: GrantFiled: June 7, 2018Date of Patent: April 14, 2020Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yoshihiro Goto, Akira Morikawa, Masahide Miura, Hiromasa Suzuki
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Patent number: 10343060Abstract: Increasing a number of advertising impressions in a system configured to facilitate user interaction with an interactive environment containing one or more advertising targets is described. A scene of a portion of the simulated environment is displayed from a camera point of view (camera POV) on a video display. The scene may change as the camera POV changes in response to movement of the camera POV along a camera path during the user's interaction with the simulated environment. Modifying the camera path or a camera field of view can place more of an advertising target within the displayed scene to increase a likelihood of generating an advertising impression. The advertising target is characterized by a field of attraction of the camera POV that is customized to an angle of approach and speed of approach of the camera POV.Type: GrantFiled: October 24, 2017Date of Patent: July 9, 2019Assignee: SONY INTERACTIVE ENTERTAINMENT LLCInventor: Gary M. Zalewski
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Patent number: 9526936Abstract: Provided are a treatment method for an organic halogen compound, which allows the organic halogen compound to be efficiently decomposed without a large-scale treatment device or high operating cost, and a catalyst to be used for the treatment method. In the treatment method, an organic halogen compound is subjected to decomposition treatment by heating the organic halogen compound at a temperature of from 100° C. to 200° C. in the presence of a catalyst formed of copper oxide and hydrogen peroxide, to subject the organic halogen compound to a hydrothermal oxidation reaction utilizing a Fenton method.Type: GrantFiled: November 1, 2013Date of Patent: December 27, 2016Assignee: OSAKA CITY UNIVERSITYInventor: Noritsugu Kometani
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Patent number: 9132306Abstract: A method for mechanochemical treatment of solid wastes containing perfluorinated or polyfluorinated compounds is provided. It belongs to the field of environment-polluting wastes treatment, and comprises the following steps: mixing the solid waste containing perfluorinated or polyfluorinated compounds with the defluorination reagent under normal temperature and pressure conditions, putting the mixture into a planetary high-energy ball milling reactor; adopting the mechanochemical reaction to realize high-effective degradation and defluorination of perfluorinated or polyfluorinated compounds. When being adopted to degrade perfluorinated or polyfluorinated compounds, this method enjoys such advantages as simple treatment procedure, mild reaction conditions (conducted under normal temperature and pressure conditions), lower energy consumption and operating cost, complete degradation and defluorination of the target pollutants, completely inorganic and harmless end products and free of liquid or gas byproducts.Type: GrantFiled: September 13, 2012Date of Patent: September 15, 2015Assignee: TSINGHUA UNIVERSITYInventors: Jun Huang, Kunlun Zhang, Xiaoling Yang, Gang Yu, Shubo Deng, Bin Wang, Yamei Hui, Haizhu Wang
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Patent number: 8766030Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents in situ is achieved by delivering ferric ammonium citrate into the soils and/or water. The induction of ferric ammonium citrate into sulfate-rich reducing conditions initiates a combined abiotic and biotic mechanism for the dechlorination of subsurface contaminants. Initial and rapid removal of chlorinated solvents is achieved by way of reductive transformation, a mechanism utilizing the creation of an iron-bound soil mineral (pyrite) followed by stimulating conditions for enhanced biological natural attenuation.Type: GrantFiled: July 25, 2012Date of Patent: July 1, 2014Assignee: Innovative Environmental Technologies, Inc.Inventor: Michael Scalzi
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Publication number: 20140155676Abstract: A treatment system and a method for removal of at least one halogenated compound, such as PCBs, found in contaminated systems are provided. The treatment system includes a polymer blanket for receiving at least one non-polar solvent. The halogenated compound permeates into or through a wall of the polymer blanket where it is solubilized with at least one non-polar solvent received by said polymer blanket forming a halogenated solvent mixture. This treatment system and method provides for the in situ removal of halogenated compounds from the contaminated system. In one embodiment, the halogenated solvent mixture is subjected to subsequent processes which destroy and/or degrade the halogenated compound.Type: ApplicationFiled: May 16, 2013Publication date: June 5, 2014Inventors: Jacqueline W. Quinn, Christian A. Clausen, Cherie L. Yestrebsky
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Patent number: 8722958Abstract: Provided is a method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis. More specifically, the method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis has been established by optimizing the characteristics of titanium oxide granules.Type: GrantFiled: August 18, 2009Date of Patent: May 13, 2014Assignee: Kusatsu Electric Co., Ltd.Inventor: Itsushi Kashimoto
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Publication number: 20140081067Abstract: Various aspects of the present invention pertain to methods of sorption of various materials from an environment, including radioactive elements, chlorates, perchlorates, organohalogens, and combinations thereof. Such methods generally include associating graphene oxides with the environment. This in turn leads to the sorption of the materials to the graphene oxides. In some embodiments, the methods of the present invention also include a step of separating the graphene oxides from the environment after the sorption of the materials to the graphene oxides. More specific aspects of the present invention pertain to methods of sorption of radionuclides (such as actinides) from a solution by associating graphene oxides with the solution and optionally separating the graphene oxides from the solution after the sorption.Type: ApplicationFiled: February 27, 2012Publication date: March 20, 2014Applicant: WILLIAM MARSH RICE UNIVERSITYInventors: James M. Tour, Alexander Slesarev, Dmitry V. Kosynkin, Anna Y. Romanchuk, Stepan N. Kalmykov
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Patent number: 8668832Abstract: Methods, apparatus and systems for treating wastewater onboard small marine vessels. A pre-determined volume of wastewater generated onboard the vessel is mixed with a larger volume of seawater. This mixture is disinfected and subjected to further oxidation. The excess oxidants are neutralized and the treated effluent is discharged overboard the vessel.Type: GrantFiled: March 19, 2010Date of Patent: March 11, 2014Assignee: Severn Trent de Nora, LLCInventors: Rudolf Matousek, Dana Casbeer, David Hill, Rubin Bariya
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Patent number: 8618021Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.Type: GrantFiled: January 16, 2012Date of Patent: December 31, 2013Assignee: Remediation Products, Inc.Inventors: Scott Noland, Bob Elliott
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PROCESS FOR TERMICAL DEGRADATION OF PVC AND OTHER WASTES CONTAINING HALOGEN-CONTAINING POLYMER WASTE
Publication number: 20130274535Abstract: The subject matter of the patent is a process technology concerning thermal degradation of plastic wastes containing PVC and other plastic waste with halogen content. The patent is characterised by grinding of the plastic waste to be treated, leading it into a dehalogenisation reactor with heavy oil fraction added forming a 1:0.3-0.Type: ApplicationFiled: August 26, 2010Publication date: October 17, 2013Applicant: AHD VAGYONKEZELÖ ÉS TANÁCSADÓ KFT.Inventors: Viktor Csókai, Zoltán Szinay, Ádám Boday -
Publication number: 20130041200Abstract: The present invention relates to the use of catalysts of general formula (I): (L1)M1-X-M2(L2) ??(I) wherein: M1 and M2, either identical or different, represent metal atoms; X represents a nitrogen atom; L1 and L2, either identical or different are coordinated with M1 and M2, respectively, and represent ligands of the tetradentate type, for catalytic oxidation of halogenated compounds.Type: ApplicationFiled: April 6, 2011Publication date: February 14, 2013Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.), UNIVERSITE CLAUDE BERNARD LYON 1Inventors: Alexander Sorokin, Evgeny V. Kudrik
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Patent number: 8354567Abstract: Described are method of treating a radioactive organic waste stream comprising: (a) mixing a radioactive organic waste stream comprising organic compounds and radionuclides with phosphoric acid to form a reaction mixture; (b) heating the reaction mixture to a desired temperature in the presence of an oxidant to oxidize organic compounds present in the waste stream, and removing oxidized organic compounds from the reaction mixture; (c) optionally, adding a reducing agent to the reaction mixture to form insoluble radioactive metal phosphate compounds comprising one or more of the radionuclides, and separating the insoluble radioactive metal phosphate compounds from the reaction mixture; (d) optionally, adding a fluorine compound to the reaction mixture to react with uranium that may be present in the reaction mixture to form uranium hexafluoride, and removing uranium hexafluoride from the reaction mixture; (e) adding ammonia to the reaction mixture to neutralize phosphoric acid and to form ammonium phosphateType: GrantFiled: January 29, 2009Date of Patent: January 15, 2013Inventors: David Donald Leavitt, Robert Dale Delano
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Patent number: 8231851Abstract: An exhaust gas containing a perfluoride compound (PFC) and SiF4 is conducted into a silicon remover and brought into contact with water. A reaction water supplied from a water supplying piping and air supplied from an air supplying piping are mixed with the exhaust gas exhausted from the silicon remover. The exhaust gas containing water, air, and CF4 is heated at 700° C. by a heater. The exhaust gas containing PFC is conducted to a catalyst layer filled with an alumina group catalyst. The PFC is decomposed to HF and CO2 by the catalyst. The exhaust gas containing HF and CO2 at a high temperature exhausted from the catalyst layer is cooled in a cooling apparatus. Subsequently, the exhaust gas is conducted to an acidic gas removing apparatus to remove HF. In this way, the silicon component is removed from the exhaust gas before introducing the exhaust gas into the catalyst layer.Type: GrantFiled: September 16, 2002Date of Patent: July 31, 2012Assignees: Hitachi, Ltd., Hitachi Information & Control Solutions, Ltd., Hitachi Kyowa Engineering Co., Ltd.Inventors: Kazuyoshi Irie, Toshihiro Mori, Hisao Yokoyama, Takayuki Tomiyama, Toshihide Takano, Shin Tamata, Shuichi Kanno
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Patent number: 8097559Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.Type: GrantFiled: August 11, 2004Date of Patent: January 17, 2012Assignee: Remediation Products, Inc.Inventors: Scott Noland, Bob Elliott
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Patent number: 8092769Abstract: A process and apparatus are described for converting a feed that is substantially comprised of halogenated materials, and especially byproduct and waste chlorinated hydrocarbons as are produced from a variety of chemical manufacturing processes, to one or more higher value products via a partial oxidation reforming reaction step. These products can be in the form of a useful or salable acid product and/or a product synthesis gas comprised of carbon monoxide and hydrogen, or the reaction product including the same hydrogen halide, carbon monoxide and hydrogen components can be employed as a feed in the synthesis of a different useful or salable product.Type: GrantFiled: May 11, 2007Date of Patent: January 10, 2012Assignee: Dow Global Technologies LLCInventors: Dennis Wade Jewell, John P. Henley, Edward E. Timm, Tarver Gayle Snedecor, Jr., Leopoldo Salinas, III, Charles William Lipp, James Everett Clark
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Patent number: 8084662Abstract: The invention provides a novel method of detoxifying highly toxic chemicals, and treating surfaces contaminated, or potentially contaminated, with toxic chemical agents such as chemical warfare agents and/or industrial toxins. The methods utilizes a novel sorbent compound which comprises Mn(VII) mineral which can be either solid supported or non-solid supported. The Mn(VII) mineral can be provided in a number of different forms including creams, lotions, powders, liquids, slurries and aerosols.Type: GrantFiled: May 9, 2005Date of Patent: December 27, 2011Assignee: ChK Group Inc.Inventors: Rajan K. Vempati, Edward R. Biehl, Ramesh S. Hegde, David Y. Son
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Patent number: 8034156Abstract: A method for producing a decomposer of an organic halogenated compound comprises subjecting an iron powder produced beforehand to plastic deformation that gives the iron powder particles a flat shape. Further, an iron powder and a copper salt powder are mechanically mixed in a ball mill to produce a copper salt-containing iron particle powder in which the particles of the two powders are joined. In this case, the method for producing the decomposer of an organic halogenated compound is characterized in that the iron powder is mechanically deformed to give the particles a flat shape.Type: GrantFiled: March 22, 2006Date of Patent: October 11, 2011Assignee: Dowa Eco-System Co., Ltd.Inventors: Masami Kamada, Taishi Uehara
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Patent number: 8034989Abstract: High temperature reaction of halogen-containing carbon, boron, silicon and nitrogen compounds with other compounds generates energy.Type: GrantFiled: August 26, 2005Date of Patent: October 11, 2011Inventors: Stephen L. Knupp, John L. Knupp
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Patent number: 7955578Abstract: To provide a method and apparatus for treating a waste gas containing fluorine-containing compounds, according to which PFCs can be decomposed efficiently even at low temperature, and moreover fluorine from the product of the decomposition can be recovered for reuse efficiently. An embodiment of the present invention relates to a method of treating a gas containing a fluorine-containing compound, comprising contacting the gas with a treatment agent comprising a mixture of aluminum hydroxide and calcium hydroxide.Type: GrantFiled: March 18, 2005Date of Patent: June 7, 2011Assignee: Ebara CorporationInventors: Yoichi Mori, Tadakazu Nishikawa, Masaaki Osato, Saburou Nagano, Yoshihiro Tanabe
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Patent number: 7887880Abstract: A stabilized, chemically reactive, metallic nano-material effective for degradation of chlorinated organic compounds in soils, sediments and groundwater. The nano-material is composed of a magnetic metal nanoparticle and a carbohydrate stabilizer bound to the nanoparticle. The preferred metal nanoparticle is iron and the preferred carbohydrate stabilizer is either a starch or a water soluble cellulose such as sodium carboxymethyl cellulose. The nanoparticle may be either mono-metallic, bi-metallic or multi-metallic in nature, but is preferably bi-metallic wherein it is coated with a secondary catalytic metal coating, preferably palladium. A method of making the metallic nano-material is further disclosed wherein a solution of the metal nanoparticle and carbohydrate stabilizer is prepared, and the nanoparticle is then reduced under inert conditions.Type: GrantFiled: June 30, 2005Date of Patent: February 15, 2011Assignee: Auburn UniversityInventors: Dongye Zhao, Feng He
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Patent number: 7862691Abstract: A method of decomposing waste plastics, organics, and particularly medical waste composed of a varieties of plastics is described.Type: GrantFiled: March 22, 2007Date of Patent: January 4, 2011Assignee: Kusatsu Electric Co., Ltd.Inventors: Tatsuo Kitamura, Yoshihide Kitamura, Itsushi Kashimoto
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Publication number: 20100324352Abstract: To provide a good and simple method for decomposing and detoxifying a hardly decomposable fluorinated organic compound. Specifically, a fluorinated organic compound is decomposed by bringing an aqueous solution of the fluorinated organic compound into contact with a catalyst containing a metal oxide. The metal oxide may preferably be an oxide of at least one metal selected from the group consisting of Ni, Pd, Cu, Mn, Fe and Co, and more preferably be nickel oxide. The contact temperature is preferably within the range of from 0 to 100° C. Preferably, the fluorinated organic compound to be decomposed is an organic fluorocarboxylic acid, an organic fluorosulfonic acid or a salt thereof, which is used as a surfactant or an surface treatment agent.Type: ApplicationFiled: August 10, 2010Publication date: December 23, 2010Applicant: ASAHI GLASS COMPANY, LIMITEDInventors: Jumpei NOMURA, Yasuhiko Matsuoka
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Patent number: 7812211Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.Type: GrantFiled: March 26, 2008Date of Patent: October 12, 2010Assignee: King Saud UniversityInventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
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Publication number: 20100256430Abstract: The invention provides a system and process for treating a raw material to reduce the level of a contaminant in the raw material or to form a raw product that can be used to produce a fuel. The system and process include means for pressurising a pumpable feedstock comprising the raw material to a pressure of between 100 and 350 bar, preferably using indirect pressurising means; heating the feedstock to a temperature of between 250° C. and 400° C. within a processing vessel to form a pressurised raw product stream; cooling the raw product stream within the processing vessel to an ambient or near ambient temperature; then depressurising the raw product stream before discharging the raw product from the system.Type: ApplicationFiled: November 17, 2008Publication date: October 7, 2010Applicant: SOLRAY ENERGY LIMITEDInventor: Christopher Francis Bathurst
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Publication number: 20100217063Abstract: PCBs are removed from contaminated media using a treatment system including zero-valent metal particles and an organic hydrogen donating solvent. The treatment system may include a weak acid in order to eliminate the need for a coating of catalytic noble metal on the zero-valent metal particles. If catalyzed zero-valent metal particles are used, the treatment system may include an organic hydrogen donating solvent that is a non-water solvent. The treatment system may be provided as a “paste-like” system that is preferably applied to natural media and ex-situ structures to eliminate PCBs.Type: ApplicationFiled: May 13, 2009Publication date: August 26, 2010Applicant: USA as Represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Jacqueline W. Quinn, Christian A. Clausen, Cherie L. Geiger, Kathleen B. Brooks
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Patent number: 7781638Abstract: A method, using a photocatalyst, to accelerate the reduction of semivolatile organic chemicals absorbed into porous, solid materials. The porous, solid material having absorbed one or more semivolatile organic contaminants. The photocatalytic material located on the surface of the porous, solid material is exposed to a light source, under aerobic conditions, which excites the photocatalyst and results in the reduction of the absorbed semivolatile organic chemical contaminants.Type: GrantFiled: August 22, 2005Date of Patent: August 24, 2010Assignee: University of North DakotaInventors: Evguenii I. Kozliak, Wayne Seames
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Patent number: 7767873Abstract: A method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds, based on the fact that at least one halogenated aromatic and/or cyclic compound is heated on a support matrix in a closed system at a temperature of 200 to 500° C. in the presence of copper in metallic form and/or in the form of copper compounds, a hydrogen donor, carbon and at least one additional reducing substance, capable of reducing cupric and cuprous ions to elemental copper at the above temperature.Type: GrantFiled: April 28, 2004Date of Patent: August 3, 2010Assignee: Zdravotni Ustav Se Sidlem V OstraveInventors: Vladimir Pekarek, Petr Hapala, Eva Fiserova
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Patent number: 7763768Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.Type: GrantFiled: March 26, 2008Date of Patent: July 27, 2010Assignee: King Saud UniversityInventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
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Patent number: 7723558Abstract: The present invention relates to a near-universal non-corrosive, non-toxic, environmentally safe and user friendly decontaminant capable of detoxifying organophosphorus (OP)-based G-type, V-type neurotoxic chemical warfare, sulfur-mustard, and related OP based hazardous industrial materials in a dry powder form. The decontaminant contains OPH enzyme, OPAA enzyme, DFPase enzyme, dehalogenase enzyme, quaternary ammonium salt, a pH control reagent, a fire-fighting agent, and a foaming agent. The decontaminant is mixed with available water for use.Type: GrantFiled: June 5, 2007Date of Patent: May 25, 2010Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Tu-Chen Cheng, Joseph J. DeFrank, Steven P. Harvey, Vipin K. Rastogi
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Patent number: 7678353Abstract: Alkyl halides can be effectively scrubbed from gas streams containing them by passing the gas streams through dispersers having a very small pore size into an aqueous scrubbing liquid containing a nucleophile such as thiosulfate. Optionally, the addition of a water-soluble organic compound to the scrubbing liquid may increase the rate of destruction of the alkyl halide. Alkyl halides such as methyl bromide can be effectively scrubbed from enclosed spaces containing the halide, for example in enclosures used for fumigation.Type: GrantFiled: October 25, 2004Date of Patent: March 16, 2010Assignee: Value Recovery, Inc.Inventors: Peter J. Joyce, Roman Bielski
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Publication number: 20100036189Abstract: The present invention relates to a process for dehalogenation of a halogenated hydrocarbon comprising: desorbing a halogenated hydrocarbon from a solid phase using a solvent; and dehalogenating the halogenated hydrocarbon in a solvent which comprises the solvent used in the desorption step.Type: ApplicationFiled: November 29, 2007Publication date: February 11, 2010Applicant: ENVIRONMENTAL BIOTECHNOLOGY CRC PTY LIMITEDInventors: Matthew Joseph Lee, Ralf Cord-Ruwischi
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Patent number: 7645386Abstract: Pure halogen salts of alkaline and/or alkaline earth metals or a mixture thereof are prepared by (I) hydrolytically heating a suspension of 1 part by weight of a halogenic, organic waste material in a comminuted state in 1-10 parts by weight of an aqueous medium in the presence of a base to a temperature ranging from 200-300° C. at a pressure sufficient to maintain the water in a liquid state for a period of time sufficient to convert substantially all the organically bound halogen present to inorganic halides, and (II) separating the hydrolysate obtained in step (I) into a solid hydrolysate fraction and a liquid hydrolysate fraction, (III) neutralizing the liquid hydrolysate with hydrohalogenic acid, (IV) adding a flocculent to the neutralized hydrolysate; (V) separating the material from step (IV) into a solid containing fraction and an aqueous solution; and (VI) nanofiltering the aqueous solution to obtain a retentate and a permeate, wherein the permeate is further treated to obtain the pure salts.Type: GrantFiled: April 17, 2006Date of Patent: January 12, 2010Inventor: Jan Procida
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Patent number: 7531709Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents is achieved by stimulating anaerobic microorganisms and thus increasing the rate of biological mineralization of the solvents. This is accomplished by a treatment process consisting of colloidal suspension of metal powder, an organic hydrogen donor, chemical oxygen scavengers in solution with essential nutrients, and vitamin stimulants such as B2 and B12 delivered via compressed gases N or CO2 so as not to oxygenate an environment targeted for anaerobic processes. The treatment stimulates naturally occurring microorganisms while oxidizing dissolved phase target compounds via the surface action of the iron particles resulting in the breakdown of chlorinated solvents such as tetrachloroethene, trichloroethene, carbon tetrachloride and their daughter products.Type: GrantFiled: June 13, 2006Date of Patent: May 12, 2009Assignee: Innovative Environmental Technologies, Inc.Inventors: Michael Scalzi, Wade Meese
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Patent number: 7525010Abstract: A process of washing plastics contaminated with polychlorinated biphenyls (PCBs) is provided to reduce the concentration of the PCBs. A two-step process includes a first washing step using a selected washing solution or solvent, such as, a non-flammable solvent, and followed by a second step using thermal desorption. The two-step process enables reducing the concentration of PCBs in polymers, such as recovered from shredder residue, for example, to as low as 0.253 PPM. One of the preferred solvents is Perchloroethylene.Type: GrantFiled: October 31, 2006Date of Patent: April 28, 2009Assignee: UChicago Argonne LLCInventors: Bassam J. Jody, Joseph A. Pomykala, Jr., Edward J. Daniels, Jeffrey S. Spangenberger
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Publication number: 20090054718Abstract: A method for producing a decomposer of an organic halogenated compound comprises subjecting an iron powder produced beforehand to plastic deformation that gives the iron powder particles a flat shape. Further, an iron powder and a copper salt powder are mechanically mixed in a ball mill to produce a copper salt-containing iron particle powder in which the particles of the two powders are joined. In this case, the method for producing the decomposer of an organic halogenated compound is characterized in that the iron powder is mechanically deformed to give the particles a flat shape.Type: ApplicationFiled: March 22, 2006Publication date: February 26, 2009Inventors: Masami Kamada, Taishi Uehara
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Patent number: 7488863Abstract: The invention provides processes for decontamination of organic halides in asphalt-containing wastes, such as PCBs in asphaltic potting compounds. The processes may use hydrocarbon solvents to dissolve the asphaltic waste, and an alkali metal reactant, such as a sodium dispersion, to destroy the organic halides in the dissolved mixture.Type: GrantFiled: June 27, 2007Date of Patent: February 10, 2009Assignee: Powertech Labs, IncInventors: Ian Gordon Norman Wylie, Nicola Dominelli, Keith Cheuklap Lee
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Publication number: 20090012346Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.Type: ApplicationFiled: March 26, 2008Publication date: January 8, 2009Applicant: King Saud UniversityInventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
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Publication number: 20090012345Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.Type: ApplicationFiled: March 26, 2008Publication date: January 8, 2009Applicant: King Saud UniversityInventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
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Patent number: 7449156Abstract: A molten metal reactor (10) quickly entrains a feed material in the molten reactant metal (16) and provides the necessary contact between the molten reactant metal and the feed material to effect the desired chemical reduction of the feed material. The reactor (10) includes a unique feed structure (24) adapted to quickly entrain the feed material into the molten reactant metal (16) and then transfer the molten reactant metal, feed material, and initial reaction products into a treatment chamber (12). A majority of the desired reactions occur in the treatment chamber (12). Reaction products and unspent reactant metal are directed from the treatment chamber (12) to an output chamber (14) where reaction products are removed from the reactor. Unspent reactant metal (16) is then transferred to a heating chamber (15) where it is reheated for recycling through the system.Type: GrantFiled: April 2, 2004Date of Patent: November 11, 2008Assignee: Clean Technologies International CorporationInventor: Anthony S. Wagner
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Publication number: 20080255401Abstract: [OBJECT] To efficiently and assuredly making an object to be treated containing an agricultural chemical innoxious. [MEANS FOR SOLVING] The first pipe which alkali can be filled thereto is disposed to be capable of being inserted and pulled out to a first passage of the first processing chamber where agricultural chemicals are thermally decomposed. Accordingly, since a distance between the processing chamber and the alkali can be minimized, a zone where the thermally decomposed components of the agricultural chemicals are recomposed into agricultural chemicals or dioxins is almost eliminated. As a result, the contamination owing to the re-composition thereof can be prevented. In addition, since the first pipe can be readily exchanged, the throughput can be improved.Type: ApplicationFiled: August 25, 2005Publication date: October 16, 2008Applicant: Hoei Shokai Co., Ltd.Inventors: Tsuyoshi Abe, Hitoshi Mizuno, Kazunori Suzuki
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Publication number: 20080190865Abstract: A stabilized, chemically reactive, metallic nano-material effective for degradation of chlorinated organic compounds in soils, sediments and groundwater. The nano-material is composed of a magnetic metal nanoparticle and a carbohydrate stabilizer bound to the nanoparticle. The preferred metal nanoparticle is iron and the preferred carbohydrate stabilizer is either a starch or a water soluble cellulose such as sodium carboxymethyl cellulose. The nanoparticle may be either mono-metallic, bi-metallic or multi-metallic in nature, but is preferably bi-metallic wherein it is coated with a secondary catalytic metal coating, preferably palladium. A method of making the metallic nano-material is further disclosed wherein a solution of the metal nanoparticle and carbohydrate stabilizer is prepared, and the nanoparticle is then reduced under inert conditions.Type: ApplicationFiled: June 30, 2005Publication date: August 14, 2008Inventors: Dongye Zhao, Feng He
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Publication number: 20080177125Abstract: Emulsified systems of a surfactant-stabilized, biodegradable water-in-solvent emulsion with bimetallic particles contained with the emulsion droplets are useful at removing PCBs from ex situ structures. The hydrophobic emulsion system draws PCBs through the solvent/surfactant membrane. Once inside the membrane, the PCBs diffuse into the bimetallic particles and undergo degradation. The PCBs continue to enter, diffuse, degrade, and biphenyl will exit the particle maintaining a concentration gradient across the membrane and maintaining a driving force of the reaction.Type: ApplicationFiled: August 15, 2007Publication date: July 24, 2008Applicant: U.S.A as Represented by the Administrator of the National Aeronautics and Space AdInventors: Jacqueline Quinn, Christian Clausen, Cherie L. Geiger, Christina Coon, Laura B. Filipek, Cristina M. Berger, Kristen M. Milum
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Publication number: 20080156741Abstract: A purifying agent for purifying soil or ground water which comprises a water suspension containing iron composite particles comprising ?-Fe and magnetite, and having an average particle diameter of 0.05 to 0.50 ?m, an S content of 3500 to 10000 ppm and an Al content of 0.10 to 1.50% by weight, and polyaspartic acid or a salt thereof. The purifying agent is capable of decomposing aliphatic organohalogen compounds or aromatic organohalogen compounds contained in the soil or ground water in an efficient, continuous and economical manner.Type: ApplicationFiled: February 4, 2008Publication date: July 3, 2008Applicant: TODA KOGYO CORPORATIONInventors: Koji Kakuya, Masayuki Uegami, Junichi Kawano, Tomoko Okita, Kenji Okinaka, Andreas D. Jazdanian
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Publication number: 20080114198Abstract: In an iron powder for decomposition of organic chlorinated compounds, an iron powder having high decomposition performance in the treatment of a solid such as in a soil, and having low Ni content was required. An iron powder for decomposition of organic chlorinated compounds, comprising from 0.03 to 0.5% by weight of Ni and from 0.005 to 5% by weight of carbon, wherein particles having a particle size of less than 53 ?m occupies less than 40% by weight, is used. It is particularly preferable that Ni, carbon and iron are partially alloyed. When the iron powder for decomposition is used by mixing with, for example, an Ni-free iron powder, the total Ni content can be reduced without deterioration of decomposition performance to organic chlorinated compounds.Type: ApplicationFiled: July 17, 2007Publication date: May 15, 2008Applicant: TOSOH CORPORATIONInventors: Yoju SHIMIZU, Yasuyuki NAGAI
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Patent number: 7321073Abstract: A high temperature and high pressure process utilizes dehaloganation, oxidation, or similar reactions to chemically alter hazardous organic chemicals to render them non-hazardous. The method is particularly adaptable to the treatment of sediments in bodies of water and includes process steps to destroy contaminants such as PCBs in one product stream and to capture heavy metals for disposal in a smaller second product stream.Type: GrantFiled: March 12, 2004Date of Patent: January 22, 2008Inventor: John Woodworth
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Patent number: 7276640Abstract: Methods of reducing smoke levels in smoke-affected areas, reducing the level of toxic compounds produced by fires, fire suppression, and increasing flame retardancy. In particular, methods according to the present invention comprise dispersing nanocrystalline particles in the areas affected by smoke for sorption of smoke particulates and toxic compounds produced from a fire. The nanocrystalline particles are also effective for use in methods of fire suppression and flame retardancy.Type: GrantFiled: October 18, 2005Date of Patent: October 2, 2007Assignee: NanoScale CorporationInventors: Ravichandra S. Mulukutla, Paul S. Malchesky, Ronaldo Maghirang, John S. Klabunde, Kenneth J. Klabunde, Olga Koper
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Patent number: 7265254Abstract: Chlorine-containing waste is processed inside a heating device, an alkali metal compound and a calcium compound are given into the heating device while the temperature of a solid phase inside the heating device is maintained at 400 to 1500° C., chlorine that is contained in the chlorine-containing waste and that has not been bound by the alkali metal compound is bound in the solid phase by the calcium compound, and chlorine is converted into alkali metal chloride from calcium chloride generated in the course of the processing of the chlorine-containing waste.Type: GrantFiled: July 30, 2002Date of Patent: September 4, 2007Assignee: Taiheiyo Cement CorporationInventors: Yasushi Yamamoto, Hisanori Aoyama, Tomohisa Yoshikawa, Takemi Aizawa, Takamiki Tamashige, Norihiko Misaki, Michio Matsuno, Yoshimasa Muraoka