Dehalogenation Using Reactive Chemical Agents Able To Degrade (epo/jpo) Patents (Class 588/316)
  • Patent number: 11607485
    Abstract: A system including tubing and a filter configured to be fluidly coupled to a vacuum source and to a heater/cooler unit by the tubing. The filter includes a filter container having negative air pressure in the filter container provided by the vacuum source to pull aerosol from the heater/cooler unit into the filter container and eliminate and/or reduce the aerosol emitted from the heater/cooler unit.
    Type: Grant
    Filed: September 14, 2016
    Date of Patent: March 21, 2023
    Assignee: Sorin Group Italia S.r.l.
    Inventors: Stephen W. Berch, Thierry Dupoux, Elisa Maculan, Giampaolo Simonini
  • Patent number: 11150031
    Abstract: A heat transfer or storage medium containing a nitrate salt composition including at least one alkali metal nitrate and optionally alkaline earth metal nitrate; and, at least one alkali metal nitrite and optionally alkaline earth metal nitrite in an amount of 1.1 to 15.0 mol %. The molar amount of the alkali metal nitrite and optionally alkaline earth metal nitrite for a desired temperature is calculated by x nitrite = K 6 ? ( T ) K 6 ? ( T ) + P O ? ? 2 Xnitrite is the mole fraction of nitrite, K6(T) is the temperature-dependent equilibrium constant of the reaction nitrate ?nitrite+½ oxygen (NO3?? NO2?+½ O2), pO2 is the oxygen partial pressure and T is the temperature of the nitrate salt composition.
    Type: Grant
    Filed: April 20, 2017
    Date of Patent: October 19, 2021
    Assignee: BASF SE
    Inventors: Juergen Wortmann, Sabine Weiguny, Katharina Federsel, Matthias Hinrichs, Stephan Maurer
  • Patent number: 10618029
    Abstract: To provide an oxygen storage material that is capable of exhibiting an excellent oxygen storage capacity (OSC) even at a low temperature of about 300° C. and has a sufficiently high efficiency of use of cerium contained therein. An oxygen storage material including a ceria-zirconia-copper oxide-based composite oxide that contains cerium, zirconium, and copper, in which at least part of the copper is solid-dissolved in a composite oxide of the cerium and the zirconium, the ceria-zirconia-copper oxide-based composite oxide has a composition expressed by the following chemical formula (1): CexZryCuzO2-z??(1) where x, y, and z are numbers each satisfying conditions of x=0.3 to 0.7, y=0.15 to 0.7 (exclusive of y=0.7), z=0 to 0.15 (exclusive of z=0), and x+y+z=1, and a specific surface area of the ceria-zirconia-copper oxide-based composite oxide is 2 to 50 m2/g.
    Type: Grant
    Filed: June 7, 2018
    Date of Patent: April 14, 2020
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yoshihiro Goto, Akira Morikawa, Masahide Miura, Hiromasa Suzuki
  • Patent number: 10343060
    Abstract: Increasing a number of advertising impressions in a system configured to facilitate user interaction with an interactive environment containing one or more advertising targets is described. A scene of a portion of the simulated environment is displayed from a camera point of view (camera POV) on a video display. The scene may change as the camera POV changes in response to movement of the camera POV along a camera path during the user's interaction with the simulated environment. Modifying the camera path or a camera field of view can place more of an advertising target within the displayed scene to increase a likelihood of generating an advertising impression. The advertising target is characterized by a field of attraction of the camera POV that is customized to an angle of approach and speed of approach of the camera POV.
    Type: Grant
    Filed: October 24, 2017
    Date of Patent: July 9, 2019
    Assignee: SONY INTERACTIVE ENTERTAINMENT LLC
    Inventor: Gary M. Zalewski
  • Patent number: 9526936
    Abstract: Provided are a treatment method for an organic halogen compound, which allows the organic halogen compound to be efficiently decomposed without a large-scale treatment device or high operating cost, and a catalyst to be used for the treatment method. In the treatment method, an organic halogen compound is subjected to decomposition treatment by heating the organic halogen compound at a temperature of from 100° C. to 200° C. in the presence of a catalyst formed of copper oxide and hydrogen peroxide, to subject the organic halogen compound to a hydrothermal oxidation reaction utilizing a Fenton method.
    Type: Grant
    Filed: November 1, 2013
    Date of Patent: December 27, 2016
    Assignee: OSAKA CITY UNIVERSITY
    Inventor: Noritsugu Kometani
  • Patent number: 9132306
    Abstract: A method for mechanochemical treatment of solid wastes containing perfluorinated or polyfluorinated compounds is provided. It belongs to the field of environment-polluting wastes treatment, and comprises the following steps: mixing the solid waste containing perfluorinated or polyfluorinated compounds with the defluorination reagent under normal temperature and pressure conditions, putting the mixture into a planetary high-energy ball milling reactor; adopting the mechanochemical reaction to realize high-effective degradation and defluorination of perfluorinated or polyfluorinated compounds. When being adopted to degrade perfluorinated or polyfluorinated compounds, this method enjoys such advantages as simple treatment procedure, mild reaction conditions (conducted under normal temperature and pressure conditions), lower energy consumption and operating cost, complete degradation and defluorination of the target pollutants, completely inorganic and harmless end products and free of liquid or gas byproducts.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: September 15, 2015
    Assignee: TSINGHUA UNIVERSITY
    Inventors: Jun Huang, Kunlun Zhang, Xiaoling Yang, Gang Yu, Shubo Deng, Bin Wang, Yamei Hui, Haizhu Wang
  • Patent number: 8766030
    Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents in situ is achieved by delivering ferric ammonium citrate into the soils and/or water. The induction of ferric ammonium citrate into sulfate-rich reducing conditions initiates a combined abiotic and biotic mechanism for the dechlorination of subsurface contaminants. Initial and rapid removal of chlorinated solvents is achieved by way of reductive transformation, a mechanism utilizing the creation of an iron-bound soil mineral (pyrite) followed by stimulating conditions for enhanced biological natural attenuation.
    Type: Grant
    Filed: July 25, 2012
    Date of Patent: July 1, 2014
    Assignee: Innovative Environmental Technologies, Inc.
    Inventor: Michael Scalzi
  • Publication number: 20140155676
    Abstract: A treatment system and a method for removal of at least one halogenated compound, such as PCBs, found in contaminated systems are provided. The treatment system includes a polymer blanket for receiving at least one non-polar solvent. The halogenated compound permeates into or through a wall of the polymer blanket where it is solubilized with at least one non-polar solvent received by said polymer blanket forming a halogenated solvent mixture. This treatment system and method provides for the in situ removal of halogenated compounds from the contaminated system. In one embodiment, the halogenated solvent mixture is subjected to subsequent processes which destroy and/or degrade the halogenated compound.
    Type: Application
    Filed: May 16, 2013
    Publication date: June 5, 2014
    Inventors: Jacqueline W. Quinn, Christian A. Clausen, Cherie L. Yestrebsky
  • Patent number: 8722958
    Abstract: Provided is a method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis. More specifically, the method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis has been established by optimizing the characteristics of titanium oxide granules.
    Type: Grant
    Filed: August 18, 2009
    Date of Patent: May 13, 2014
    Assignee: Kusatsu Electric Co., Ltd.
    Inventor: Itsushi Kashimoto
  • Publication number: 20140081067
    Abstract: Various aspects of the present invention pertain to methods of sorption of various materials from an environment, including radioactive elements, chlorates, perchlorates, organohalogens, and combinations thereof. Such methods generally include associating graphene oxides with the environment. This in turn leads to the sorption of the materials to the graphene oxides. In some embodiments, the methods of the present invention also include a step of separating the graphene oxides from the environment after the sorption of the materials to the graphene oxides. More specific aspects of the present invention pertain to methods of sorption of radionuclides (such as actinides) from a solution by associating graphene oxides with the solution and optionally separating the graphene oxides from the solution after the sorption.
    Type: Application
    Filed: February 27, 2012
    Publication date: March 20, 2014
    Applicant: WILLIAM MARSH RICE UNIVERSITY
    Inventors: James M. Tour, Alexander Slesarev, Dmitry V. Kosynkin, Anna Y. Romanchuk, Stepan N. Kalmykov
  • Patent number: 8668832
    Abstract: Methods, apparatus and systems for treating wastewater onboard small marine vessels. A pre-determined volume of wastewater generated onboard the vessel is mixed with a larger volume of seawater. This mixture is disinfected and subjected to further oxidation. The excess oxidants are neutralized and the treated effluent is discharged overboard the vessel.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: March 11, 2014
    Assignee: Severn Trent de Nora, LLC
    Inventors: Rudolf Matousek, Dana Casbeer, David Hill, Rubin Bariya
  • Patent number: 8618021
    Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.
    Type: Grant
    Filed: January 16, 2012
    Date of Patent: December 31, 2013
    Assignee: Remediation Products, Inc.
    Inventors: Scott Noland, Bob Elliott
  • Publication number: 20130274535
    Abstract: The subject matter of the patent is a process technology concerning thermal degradation of plastic wastes containing PVC and other plastic waste with halogen content. The patent is characterised by grinding of the plastic waste to be treated, leading it into a dehalogenisation reactor with heavy oil fraction added forming a 1:0.3-0.
    Type: Application
    Filed: August 26, 2010
    Publication date: October 17, 2013
    Applicant: AHD VAGYONKEZELÖ ÉS TANÁCSADÓ KFT.
    Inventors: Viktor Csókai, Zoltán Szinay, Ádám Boday
  • Publication number: 20130041200
    Abstract: The present invention relates to the use of catalysts of general formula (I): (L1)M1-X-M2(L2) ??(I) wherein: M1 and M2, either identical or different, represent metal atoms; X represents a nitrogen atom; L1 and L2, either identical or different are coordinated with M1 and M2, respectively, and represent ligands of the tetradentate type, for catalytic oxidation of halogenated compounds.
    Type: Application
    Filed: April 6, 2011
    Publication date: February 14, 2013
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.), UNIVERSITE CLAUDE BERNARD LYON 1
    Inventors: Alexander Sorokin, Evgeny V. Kudrik
  • Patent number: 8354567
    Abstract: Described are method of treating a radioactive organic waste stream comprising: (a) mixing a radioactive organic waste stream comprising organic compounds and radionuclides with phosphoric acid to form a reaction mixture; (b) heating the reaction mixture to a desired temperature in the presence of an oxidant to oxidize organic compounds present in the waste stream, and removing oxidized organic compounds from the reaction mixture; (c) optionally, adding a reducing agent to the reaction mixture to form insoluble radioactive metal phosphate compounds comprising one or more of the radionuclides, and separating the insoluble radioactive metal phosphate compounds from the reaction mixture; (d) optionally, adding a fluorine compound to the reaction mixture to react with uranium that may be present in the reaction mixture to form uranium hexafluoride, and removing uranium hexafluoride from the reaction mixture; (e) adding ammonia to the reaction mixture to neutralize phosphoric acid and to form ammonium phosphate
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: January 15, 2013
    Inventors: David Donald Leavitt, Robert Dale Delano
  • Patent number: 8231851
    Abstract: An exhaust gas containing a perfluoride compound (PFC) and SiF4 is conducted into a silicon remover and brought into contact with water. A reaction water supplied from a water supplying piping and air supplied from an air supplying piping are mixed with the exhaust gas exhausted from the silicon remover. The exhaust gas containing water, air, and CF4 is heated at 700° C. by a heater. The exhaust gas containing PFC is conducted to a catalyst layer filled with an alumina group catalyst. The PFC is decomposed to HF and CO2 by the catalyst. The exhaust gas containing HF and CO2 at a high temperature exhausted from the catalyst layer is cooled in a cooling apparatus. Subsequently, the exhaust gas is conducted to an acidic gas removing apparatus to remove HF. In this way, the silicon component is removed from the exhaust gas before introducing the exhaust gas into the catalyst layer.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: July 31, 2012
    Assignees: Hitachi, Ltd., Hitachi Information & Control Solutions, Ltd., Hitachi Kyowa Engineering Co., Ltd.
    Inventors: Kazuyoshi Irie, Toshihiro Mori, Hisao Yokoyama, Takayuki Tomiyama, Toshihide Takano, Shin Tamata, Shuichi Kanno
  • Patent number: 8097559
    Abstract: The present invention provides a supported reactant for in situ remediation of soil and/or groundwater contaminated with a halogenated hydrocarbon consisting essentially of an adsorbent impregnated with zero valent iron, wherein the adsorbent is capable of adsorbing the halogenated hydrocarbon. In one embodiment, the adsorbent is activated carbon.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: January 17, 2012
    Assignee: Remediation Products, Inc.
    Inventors: Scott Noland, Bob Elliott
  • Patent number: 8092769
    Abstract: A process and apparatus are described for converting a feed that is substantially comprised of halogenated materials, and especially byproduct and waste chlorinated hydrocarbons as are produced from a variety of chemical manufacturing processes, to one or more higher value products via a partial oxidation reforming reaction step. These products can be in the form of a useful or salable acid product and/or a product synthesis gas comprised of carbon monoxide and hydrogen, or the reaction product including the same hydrogen halide, carbon monoxide and hydrogen components can be employed as a feed in the synthesis of a different useful or salable product.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: January 10, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Dennis Wade Jewell, John P. Henley, Edward E. Timm, Tarver Gayle Snedecor, Jr., Leopoldo Salinas, III, Charles William Lipp, James Everett Clark
  • Patent number: 8084662
    Abstract: The invention provides a novel method of detoxifying highly toxic chemicals, and treating surfaces contaminated, or potentially contaminated, with toxic chemical agents such as chemical warfare agents and/or industrial toxins. The methods utilizes a novel sorbent compound which comprises Mn(VII) mineral which can be either solid supported or non-solid supported. The Mn(VII) mineral can be provided in a number of different forms including creams, lotions, powders, liquids, slurries and aerosols.
    Type: Grant
    Filed: May 9, 2005
    Date of Patent: December 27, 2011
    Assignee: ChK Group Inc.
    Inventors: Rajan K. Vempati, Edward R. Biehl, Ramesh S. Hegde, David Y. Son
  • Patent number: 8034156
    Abstract: A method for producing a decomposer of an organic halogenated compound comprises subjecting an iron powder produced beforehand to plastic deformation that gives the iron powder particles a flat shape. Further, an iron powder and a copper salt powder are mechanically mixed in a ball mill to produce a copper salt-containing iron particle powder in which the particles of the two powders are joined. In this case, the method for producing the decomposer of an organic halogenated compound is characterized in that the iron powder is mechanically deformed to give the particles a flat shape.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: October 11, 2011
    Assignee: Dowa Eco-System Co., Ltd.
    Inventors: Masami Kamada, Taishi Uehara
  • Patent number: 8034989
    Abstract: High temperature reaction of halogen-containing carbon, boron, silicon and nitrogen compounds with other compounds generates energy.
    Type: Grant
    Filed: August 26, 2005
    Date of Patent: October 11, 2011
    Inventors: Stephen L. Knupp, John L. Knupp
  • Patent number: 7955578
    Abstract: To provide a method and apparatus for treating a waste gas containing fluorine-containing compounds, according to which PFCs can be decomposed efficiently even at low temperature, and moreover fluorine from the product of the decomposition can be recovered for reuse efficiently. An embodiment of the present invention relates to a method of treating a gas containing a fluorine-containing compound, comprising contacting the gas with a treatment agent comprising a mixture of aluminum hydroxide and calcium hydroxide.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: June 7, 2011
    Assignee: Ebara Corporation
    Inventors: Yoichi Mori, Tadakazu Nishikawa, Masaaki Osato, Saburou Nagano, Yoshihiro Tanabe
  • Patent number: 7887880
    Abstract: A stabilized, chemically reactive, metallic nano-material effective for degradation of chlorinated organic compounds in soils, sediments and groundwater. The nano-material is composed of a magnetic metal nanoparticle and a carbohydrate stabilizer bound to the nanoparticle. The preferred metal nanoparticle is iron and the preferred carbohydrate stabilizer is either a starch or a water soluble cellulose such as sodium carboxymethyl cellulose. The nanoparticle may be either mono-metallic, bi-metallic or multi-metallic in nature, but is preferably bi-metallic wherein it is coated with a secondary catalytic metal coating, preferably palladium. A method of making the metallic nano-material is further disclosed wherein a solution of the metal nanoparticle and carbohydrate stabilizer is prepared, and the nanoparticle is then reduced under inert conditions.
    Type: Grant
    Filed: June 30, 2005
    Date of Patent: February 15, 2011
    Assignee: Auburn University
    Inventors: Dongye Zhao, Feng He
  • Patent number: 7862691
    Abstract: A method of decomposing waste plastics, organics, and particularly medical waste composed of a varieties of plastics is described.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: January 4, 2011
    Assignee: Kusatsu Electric Co., Ltd.
    Inventors: Tatsuo Kitamura, Yoshihide Kitamura, Itsushi Kashimoto
  • Publication number: 20100324352
    Abstract: To provide a good and simple method for decomposing and detoxifying a hardly decomposable fluorinated organic compound. Specifically, a fluorinated organic compound is decomposed by bringing an aqueous solution of the fluorinated organic compound into contact with a catalyst containing a metal oxide. The metal oxide may preferably be an oxide of at least one metal selected from the group consisting of Ni, Pd, Cu, Mn, Fe and Co, and more preferably be nickel oxide. The contact temperature is preferably within the range of from 0 to 100° C. Preferably, the fluorinated organic compound to be decomposed is an organic fluorocarboxylic acid, an organic fluorosulfonic acid or a salt thereof, which is used as a surfactant or an surface treatment agent.
    Type: Application
    Filed: August 10, 2010
    Publication date: December 23, 2010
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Jumpei NOMURA, Yasuhiko Matsuoka
  • Patent number: 7812211
    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: October 12, 2010
    Assignee: King Saud University
    Inventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
  • Publication number: 20100256430
    Abstract: The invention provides a system and process for treating a raw material to reduce the level of a contaminant in the raw material or to form a raw product that can be used to produce a fuel. The system and process include means for pressurising a pumpable feedstock comprising the raw material to a pressure of between 100 and 350 bar, preferably using indirect pressurising means; heating the feedstock to a temperature of between 250° C. and 400° C. within a processing vessel to form a pressurised raw product stream; cooling the raw product stream within the processing vessel to an ambient or near ambient temperature; then depressurising the raw product stream before discharging the raw product from the system.
    Type: Application
    Filed: November 17, 2008
    Publication date: October 7, 2010
    Applicant: SOLRAY ENERGY LIMITED
    Inventor: Christopher Francis Bathurst
  • Publication number: 20100217063
    Abstract: PCBs are removed from contaminated media using a treatment system including zero-valent metal particles and an organic hydrogen donating solvent. The treatment system may include a weak acid in order to eliminate the need for a coating of catalytic noble metal on the zero-valent metal particles. If catalyzed zero-valent metal particles are used, the treatment system may include an organic hydrogen donating solvent that is a non-water solvent. The treatment system may be provided as a “paste-like” system that is preferably applied to natural media and ex-situ structures to eliminate PCBs.
    Type: Application
    Filed: May 13, 2009
    Publication date: August 26, 2010
    Applicant: USA as Represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Jacqueline W. Quinn, Christian A. Clausen, Cherie L. Geiger, Kathleen B. Brooks
  • Patent number: 7781638
    Abstract: A method, using a photocatalyst, to accelerate the reduction of semivolatile organic chemicals absorbed into porous, solid materials. The porous, solid material having absorbed one or more semivolatile organic contaminants. The photocatalytic material located on the surface of the porous, solid material is exposed to a light source, under aerobic conditions, which excites the photocatalyst and results in the reduction of the absorbed semivolatile organic chemical contaminants.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: August 24, 2010
    Assignee: University of North Dakota
    Inventors: Evguenii I. Kozliak, Wayne Seames
  • Patent number: 7767873
    Abstract: A method for dehalogenation detoxication of halogenated aromatic and/or cyclic compounds, based on the fact that at least one halogenated aromatic and/or cyclic compound is heated on a support matrix in a closed system at a temperature of 200 to 500° C. in the presence of copper in metallic form and/or in the form of copper compounds, a hydrogen donor, carbon and at least one additional reducing substance, capable of reducing cupric and cuprous ions to elemental copper at the above temperature.
    Type: Grant
    Filed: April 28, 2004
    Date of Patent: August 3, 2010
    Assignee: Zdravotni Ustav Se Sidlem V Ostrave
    Inventors: Vladimir Pekarek, Petr Hapala, Eva Fiserova
  • Patent number: 7763768
    Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.
    Type: Grant
    Filed: March 26, 2008
    Date of Patent: July 27, 2010
    Assignee: King Saud University
    Inventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
  • Patent number: 7723558
    Abstract: The present invention relates to a near-universal non-corrosive, non-toxic, environmentally safe and user friendly decontaminant capable of detoxifying organophosphorus (OP)-based G-type, V-type neurotoxic chemical warfare, sulfur-mustard, and related OP based hazardous industrial materials in a dry powder form. The decontaminant contains OPH enzyme, OPAA enzyme, DFPase enzyme, dehalogenase enzyme, quaternary ammonium salt, a pH control reagent, a fire-fighting agent, and a foaming agent. The decontaminant is mixed with available water for use.
    Type: Grant
    Filed: June 5, 2007
    Date of Patent: May 25, 2010
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Tu-Chen Cheng, Joseph J. DeFrank, Steven P. Harvey, Vipin K. Rastogi
  • Patent number: 7678353
    Abstract: Alkyl halides can be effectively scrubbed from gas streams containing them by passing the gas streams through dispersers having a very small pore size into an aqueous scrubbing liquid containing a nucleophile such as thiosulfate. Optionally, the addition of a water-soluble organic compound to the scrubbing liquid may increase the rate of destruction of the alkyl halide. Alkyl halides such as methyl bromide can be effectively scrubbed from enclosed spaces containing the halide, for example in enclosures used for fumigation.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: March 16, 2010
    Assignee: Value Recovery, Inc.
    Inventors: Peter J. Joyce, Roman Bielski
  • Publication number: 20100036189
    Abstract: The present invention relates to a process for dehalogenation of a halogenated hydrocarbon comprising: desorbing a halogenated hydrocarbon from a solid phase using a solvent; and dehalogenating the halogenated hydrocarbon in a solvent which comprises the solvent used in the desorption step.
    Type: Application
    Filed: November 29, 2007
    Publication date: February 11, 2010
    Applicant: ENVIRONMENTAL BIOTECHNOLOGY CRC PTY LIMITED
    Inventors: Matthew Joseph Lee, Ralf Cord-Ruwischi
  • Patent number: 7645386
    Abstract: Pure halogen salts of alkaline and/or alkaline earth metals or a mixture thereof are prepared by (I) hydrolytically heating a suspension of 1 part by weight of a halogenic, organic waste material in a comminuted state in 1-10 parts by weight of an aqueous medium in the presence of a base to a temperature ranging from 200-300° C. at a pressure sufficient to maintain the water in a liquid state for a period of time sufficient to convert substantially all the organically bound halogen present to inorganic halides, and (II) separating the hydrolysate obtained in step (I) into a solid hydrolysate fraction and a liquid hydrolysate fraction, (III) neutralizing the liquid hydrolysate with hydrohalogenic acid, (IV) adding a flocculent to the neutralized hydrolysate; (V) separating the material from step (IV) into a solid containing fraction and an aqueous solution; and (VI) nanofiltering the aqueous solution to obtain a retentate and a permeate, wherein the permeate is further treated to obtain the pure salts.
    Type: Grant
    Filed: April 17, 2006
    Date of Patent: January 12, 2010
    Inventor: Jan Procida
  • Patent number: 7531709
    Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents is achieved by stimulating anaerobic microorganisms and thus increasing the rate of biological mineralization of the solvents. This is accomplished by a treatment process consisting of colloidal suspension of metal powder, an organic hydrogen donor, chemical oxygen scavengers in solution with essential nutrients, and vitamin stimulants such as B2 and B12 delivered via compressed gases N or CO2 so as not to oxygenate an environment targeted for anaerobic processes. The treatment stimulates naturally occurring microorganisms while oxidizing dissolved phase target compounds via the surface action of the iron particles resulting in the breakdown of chlorinated solvents such as tetrachloroethene, trichloroethene, carbon tetrachloride and their daughter products.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: May 12, 2009
    Assignee: Innovative Environmental Technologies, Inc.
    Inventors: Michael Scalzi, Wade Meese
  • Patent number: 7525010
    Abstract: A process of washing plastics contaminated with polychlorinated biphenyls (PCBs) is provided to reduce the concentration of the PCBs. A two-step process includes a first washing step using a selected washing solution or solvent, such as, a non-flammable solvent, and followed by a second step using thermal desorption. The two-step process enables reducing the concentration of PCBs in polymers, such as recovered from shredder residue, for example, to as low as 0.253 PPM. One of the preferred solvents is Perchloroethylene.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: April 28, 2009
    Assignee: UChicago Argonne LLC
    Inventors: Bassam J. Jody, Joseph A. Pomykala, Jr., Edward J. Daniels, Jeffrey S. Spangenberger
  • Publication number: 20090054718
    Abstract: A method for producing a decomposer of an organic halogenated compound comprises subjecting an iron powder produced beforehand to plastic deformation that gives the iron powder particles a flat shape. Further, an iron powder and a copper salt powder are mechanically mixed in a ball mill to produce a copper salt-containing iron particle powder in which the particles of the two powders are joined. In this case, the method for producing the decomposer of an organic halogenated compound is characterized in that the iron powder is mechanically deformed to give the particles a flat shape.
    Type: Application
    Filed: March 22, 2006
    Publication date: February 26, 2009
    Inventors: Masami Kamada, Taishi Uehara
  • Patent number: 7488863
    Abstract: The invention provides processes for decontamination of organic halides in asphalt-containing wastes, such as PCBs in asphaltic potting compounds. The processes may use hydrocarbon solvents to dissolve the asphaltic waste, and an alkali metal reactant, such as a sodium dispersion, to destroy the organic halides in the dissolved mixture.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: February 10, 2009
    Assignee: Powertech Labs, Inc
    Inventors: Ian Gordon Norman Wylie, Nicola Dominelli, Keith Cheuklap Lee
  • Publication number: 20090012346
    Abstract: The subject invention provides a potentially economically viable method for the preparation of hydrogen peroxide (H2O2) in deep eutectic solvents (DES). H2O2 is then used for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions in DES without producing any toxic by-products. Furthermore, H2O2 has been used for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions. H2O2 can be formed by either the electrochemical reduction of oxygen in DES in the presence of water or by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in DES in the presence of water, with/without chemicals used for the enhancement of the solubility of the metal superoxide in the DES, e.g. crown ethers.
    Type: Application
    Filed: March 26, 2008
    Publication date: January 8, 2009
    Applicant: King Saud University
    Inventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
  • Publication number: 20090012345
    Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of halogenated hydrocarbons, their homologous/analogues, and similar hazardous chemicals at ambient conditions using superoxide ion in deep eutectic solvents. The superoxide ion is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.
    Type: Application
    Filed: March 26, 2008
    Publication date: January 8, 2009
    Applicant: King Saud University
    Inventors: Inas Muen Al Nashef, Saeed M. Al Zahrani
  • Patent number: 7449156
    Abstract: A molten metal reactor (10) quickly entrains a feed material in the molten reactant metal (16) and provides the necessary contact between the molten reactant metal and the feed material to effect the desired chemical reduction of the feed material. The reactor (10) includes a unique feed structure (24) adapted to quickly entrain the feed material into the molten reactant metal (16) and then transfer the molten reactant metal, feed material, and initial reaction products into a treatment chamber (12). A majority of the desired reactions occur in the treatment chamber (12). Reaction products and unspent reactant metal are directed from the treatment chamber (12) to an output chamber (14) where reaction products are removed from the reactor. Unspent reactant metal (16) is then transferred to a heating chamber (15) where it is reheated for recycling through the system.
    Type: Grant
    Filed: April 2, 2004
    Date of Patent: November 11, 2008
    Assignee: Clean Technologies International Corporation
    Inventor: Anthony S. Wagner
  • Publication number: 20080255401
    Abstract: [OBJECT] To efficiently and assuredly making an object to be treated containing an agricultural chemical innoxious. [MEANS FOR SOLVING] The first pipe which alkali can be filled thereto is disposed to be capable of being inserted and pulled out to a first passage of the first processing chamber where agricultural chemicals are thermally decomposed. Accordingly, since a distance between the processing chamber and the alkali can be minimized, a zone where the thermally decomposed components of the agricultural chemicals are recomposed into agricultural chemicals or dioxins is almost eliminated. As a result, the contamination owing to the re-composition thereof can be prevented. In addition, since the first pipe can be readily exchanged, the throughput can be improved.
    Type: Application
    Filed: August 25, 2005
    Publication date: October 16, 2008
    Applicant: Hoei Shokai Co., Ltd.
    Inventors: Tsuyoshi Abe, Hitoshi Mizuno, Kazunori Suzuki
  • Publication number: 20080190865
    Abstract: A stabilized, chemically reactive, metallic nano-material effective for degradation of chlorinated organic compounds in soils, sediments and groundwater. The nano-material is composed of a magnetic metal nanoparticle and a carbohydrate stabilizer bound to the nanoparticle. The preferred metal nanoparticle is iron and the preferred carbohydrate stabilizer is either a starch or a water soluble cellulose such as sodium carboxymethyl cellulose. The nanoparticle may be either mono-metallic, bi-metallic or multi-metallic in nature, but is preferably bi-metallic wherein it is coated with a secondary catalytic metal coating, preferably palladium. A method of making the metallic nano-material is further disclosed wherein a solution of the metal nanoparticle and carbohydrate stabilizer is prepared, and the nanoparticle is then reduced under inert conditions.
    Type: Application
    Filed: June 30, 2005
    Publication date: August 14, 2008
    Inventors: Dongye Zhao, Feng He
  • Publication number: 20080177125
    Abstract: Emulsified systems of a surfactant-stabilized, biodegradable water-in-solvent emulsion with bimetallic particles contained with the emulsion droplets are useful at removing PCBs from ex situ structures. The hydrophobic emulsion system draws PCBs through the solvent/surfactant membrane. Once inside the membrane, the PCBs diffuse into the bimetallic particles and undergo degradation. The PCBs continue to enter, diffuse, degrade, and biphenyl will exit the particle maintaining a concentration gradient across the membrane and maintaining a driving force of the reaction.
    Type: Application
    Filed: August 15, 2007
    Publication date: July 24, 2008
    Applicant: U.S.A as Represented by the Administrator of the National Aeronautics and Space Ad
    Inventors: Jacqueline Quinn, Christian Clausen, Cherie L. Geiger, Christina Coon, Laura B. Filipek, Cristina M. Berger, Kristen M. Milum
  • Publication number: 20080156741
    Abstract: A purifying agent for purifying soil or ground water which comprises a water suspension containing iron composite particles comprising ?-Fe and magnetite, and having an average particle diameter of 0.05 to 0.50 ?m, an S content of 3500 to 10000 ppm and an Al content of 0.10 to 1.50% by weight, and polyaspartic acid or a salt thereof. The purifying agent is capable of decomposing aliphatic organohalogen compounds or aromatic organohalogen compounds contained in the soil or ground water in an efficient, continuous and economical manner.
    Type: Application
    Filed: February 4, 2008
    Publication date: July 3, 2008
    Applicant: TODA KOGYO CORPORATION
    Inventors: Koji Kakuya, Masayuki Uegami, Junichi Kawano, Tomoko Okita, Kenji Okinaka, Andreas D. Jazdanian
  • Publication number: 20080114198
    Abstract: In an iron powder for decomposition of organic chlorinated compounds, an iron powder having high decomposition performance in the treatment of a solid such as in a soil, and having low Ni content was required. An iron powder for decomposition of organic chlorinated compounds, comprising from 0.03 to 0.5% by weight of Ni and from 0.005 to 5% by weight of carbon, wherein particles having a particle size of less than 53 ?m occupies less than 40% by weight, is used. It is particularly preferable that Ni, carbon and iron are partially alloyed. When the iron powder for decomposition is used by mixing with, for example, an Ni-free iron powder, the total Ni content can be reduced without deterioration of decomposition performance to organic chlorinated compounds.
    Type: Application
    Filed: July 17, 2007
    Publication date: May 15, 2008
    Applicant: TOSOH CORPORATION
    Inventors: Yoju SHIMIZU, Yasuyuki NAGAI
  • Patent number: 7321073
    Abstract: A high temperature and high pressure process utilizes dehaloganation, oxidation, or similar reactions to chemically alter hazardous organic chemicals to render them non-hazardous. The method is particularly adaptable to the treatment of sediments in bodies of water and includes process steps to destroy contaminants such as PCBs in one product stream and to capture heavy metals for disposal in a smaller second product stream.
    Type: Grant
    Filed: March 12, 2004
    Date of Patent: January 22, 2008
    Inventor: John Woodworth
  • Patent number: 7276640
    Abstract: Methods of reducing smoke levels in smoke-affected areas, reducing the level of toxic compounds produced by fires, fire suppression, and increasing flame retardancy. In particular, methods according to the present invention comprise dispersing nanocrystalline particles in the areas affected by smoke for sorption of smoke particulates and toxic compounds produced from a fire. The nanocrystalline particles are also effective for use in methods of fire suppression and flame retardancy.
    Type: Grant
    Filed: October 18, 2005
    Date of Patent: October 2, 2007
    Assignee: NanoScale Corporation
    Inventors: Ravichandra S. Mulukutla, Paul S. Malchesky, Ronaldo Maghirang, John S. Klabunde, Kenneth J. Klabunde, Olga Koper
  • Patent number: 7265254
    Abstract: Chlorine-containing waste is processed inside a heating device, an alkali metal compound and a calcium compound are given into the heating device while the temperature of a solid phase inside the heating device is maintained at 400 to 1500° C., chlorine that is contained in the chlorine-containing waste and that has not been bound by the alkali metal compound is bound in the solid phase by the calcium compound, and chlorine is converted into alkali metal chloride from calcium chloride generated in the course of the processing of the chlorine-containing waste.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: September 4, 2007
    Assignee: Taiheiyo Cement Corporation
    Inventors: Yasushi Yamamoto, Hisanori Aoyama, Tomohisa Yoshikawa, Takemi Aizawa, Takamiki Tamashige, Norihiko Misaki, Michio Matsuno, Yoshimasa Muraoka