Abstract: Provided is a method of asbestos detoxification including: preparing asbestos which is a treatment target for detoxification and carbon dioxide; and pressing the asbestos and the carbon dioxide with a pressure of 1 to 5 GPa and treating the asbestos and the carbon dioxide at a temperature of 100 to 250° C., wherein since the asbestos is not subjected to chemical pre-treatment, as compared to the existing technologies in which the chemical pre-treatment is necessary, treatment cost may be reduced, and another concern for environmental contamination may be prevented in advance, and accordingly, the asbestos is appropriate for recycling through detoxification as well as waste treatment.

Abstract: This invention is in the field of systems and methods for controlling contamination in high purity environments. This invention relates generally to particulate filtering and treatment of molecular contamination and process gases in enclosures, such as cleanrooms, contamination controlled manufacturing environments, mini-environments, isolators, glove boxes and restricted air barrier systems (RABS). The invention is capable of chemically transforming molecular contamination and process gases into less reactive or inert reaction products while at the same time decreasing the level of biological and nonbiological particulates.

Abstract: The invention provides a method and apparatus for creating plasma particles and applying the plasma particles to a liquid. Liquid feedstock (e.g., water and/or hydrocarbons mixed with biomass) is pumped through a pipeline; the single-phase stream is then transformed into a biphasic liquid-and-gas stream inside a chamber. The transformation is achieved by transitioning the stream from a high pressure zone to a lower-pressure zone. The pressure drop may occur when the stream further passes through a device for atomizing liquid. Inside the chamber, an electric field is generated with an intensity level that exceeds the threshold of breakdown voltage of the biphasic medium leading to a generation of a plasma state. Furthermore, the invention provides an energy-efficient highly adaptable and versatile method and apparatus for sanitizing water using plasma particles to inactivate biological agents contaminating water.

Abstract: The present invention relates to a treatment by pulmonary delivery of a bioscavenger to animals as an effective antidote to prevent toxicity produced by exposure of an animal to nerve agents and other toxic substances.

Abstract: We have now discovered a novel process for the removal or extraction of metal species from a variety of solid, liquid or gas phase materials. Metal species may be removed by contacting the material suspected of containing one or more metals with a thiolated fatty acid or ester thereof for a period of time and under conditions effective for the sequestration of the metal species by the thiolated fatty acid or ester thereof. The thiolated fatty acid or ester thereof comprising sequestered metal species may then be separated and recovered from the treated material. Moreover, following the treatment of aqueous liquids or mixtures, or suspensions or dispersions of solids in aqueous liquids, the resultant thiolated fatty acid or ester thereof comprising the sequestered metal species is insoluble in water and forms a separate layer from the aqueous liquid phase, which layer may be readily removed.

Abstract: Methods and kits for decomposing organophosphorus compounds in non-aqueous media at ambient conditions are described. Insecticides, pesticides, and chemical warfare agents can be quickly decomposed to non-toxic products. The method comprises combining the organophosphorus compound with a non-aqueous solution, preferably an alcohol, comprising metal ions and at least a trace amount of alkoxide ions. In a first preferred embodiment, the metal ion is a lanthanum ion. In a second preferred embodiment, the metal ion is a transition metal.

Abstract: A method of recycling captured agglomerated soot captured by and collected from a diesel emission control after-treatment (DECAT) system, the method comprising collecting captured agglomerated diesel soot (CADS) as a feedstock, loading the CADS into a controlled thermochemical conversion (TCC) process reactor, employing time-phased heat and pressure in the controlled TCC process reactor until the CADS sufficiently decompose to reclaim solids, liquid fuels and gases, piping pyrolysis oils (tars) and vapors produced in the controlled TCC process reactor to chambers, cooling and condensing the pyrolysis oils and vapors into a liquid form, and recirculating a pyrolysis gas produced in the controlled TCC process reactor for use as a source of heat and power.

Abstract: According to one aspect of the invention, a method of converting an oxy halide salt into a halide dioxide in a reaction zone under certain conditions is provided. More specifically, the method includes generating chlorine dioxide from a stable composition comprising an oxy halide salt by introducing said composition to a reducing agent and minimum temperature within the reaction zone. According to another aspect of the invention, a composition for a stable chlorine dioxide precursor comprising an oxy halide salt is provided.

Abstract: Various aspects of the present invention pertain to methods of sorption of various materials from an environment, including radioactive elements, chlorates, perchlorates, organohalogens, and combinations thereof. Such methods generally include associating graphene oxides with the environment. This in turn leads to the sorption of the materials to the graphene oxides. In some embodiments, the methods of the present invention also include a step of separating the graphene oxides from the environment after the sorption of the materials to the graphene oxides. More specific aspects of the present invention pertain to methods of sorption of radionuclides (such as actinides) from a solution by associating graphene oxides with the solution and optionally separating the graphene oxides from the solution after the sorption.

Abstract: A method of deactivating an explosive composition provided in an explosive cartridge, which method comprises exposing the explosive composition to a deactivating agent that renders the explosive composition insensitive to detonation, wherein the deactivating agent is a plant.

Abstract: It is an object of the present invention to provide a method of detoxifying a methyl compound comprising arsenic etc., effectively and systematically. The method of detoxifying a methyl compound according to the present invention is characterized in that an organic halogenated compound is reacted with a methyl compound comprising at least one element selected from the groups comprising arsenic, antimony and selenium to convert the methyl compound into more harmless substances. Furthermore, in a preferred embodiment of the method of detoxifying a methyl compound according to the present invention, the method is characterized in that the element is arsenic.

Abstract: According to one aspect of the invention, a method of converting an oxy halide salt into a halide dioxide in a reaction zone under certain conditions is provided. More specifically, the method includes generating chlorine dioxide from a stable composition comprising an oxy halide salt by introducing said composition to a reducing agent and minimum temperature within the reaction zone. According to another aspect of the invention, a composition for a stable chlorine dioxide precursor comprising an oxy halide salt is provided.

Abstract: A method for treating a radioactive liquid waste containing a sodium salt, which includes: feeding a radioactive liquid waste containing at least one of sodium hydroxide, sodium hydrogencarbonate and sodium carbonate to an anode chamber in an electrolytic cell provided with an anode and a cathode on both sides of a permeable membrane, which is selectively permeable to sodium ions, and electrodialyzing the radioactive liquid waste; separating sodium ions permeated through the permeable membrane as sodium hydroxide from the radioactive liquid waste in a cathode chamber; separating a radioactive substance remaining in the anode chamber as a concentrated radioactive liquid waste; and recovering the separated sodium hydroxide and concentrated radioactive liquid waste, respectively.

Abstract: A process has been developed to selectively dissociate target molecules into component products compositionally distinct from the target molecule, wherein the bonds of the target molecule do not reform because the components are no longer reactive with each other. Dissociation is affected by treating the target molecule with light at a frequency and intensity, alone or in combination with a catalyst in an amount effective to selectively break bonds within the target molecule. Dissociation does not result in re-association into the target molecule by the reverse process, and does not produce component products which have a change in oxidation number or state incorporated oxygen or other additives because the process does not proceed via a typical reduction-oxidation mechanism. Target molecules include ammonia for waste reclamation and treatment, PCB remediation, and targeted drug delivery.

Abstract: The subject invention provides a potentially economically viable process for the destruction of small to large quantities of sulfur and nitrogen mustards and lewisite, their homologous/analogues, and similar chemical warfare agents at ambient conditions without producing any toxic by-products. The process uses the superoxide ion that is either electrochemically generated by the reduction of oxygen in deep eutectic solvents or chemically by dissolving Group 1 (alkali metals) or Group 2 (alkaline earth metals) superoxides, e.g. potassium superoxide, in deep eutectic solvents.

Abstract: Disclosed are methods for treating hazardous materials, such as those which result from an unwanted spill or leak, which comprise one or more of the steps or effects of: neutralizing the dispersed material; solidifying the dispersed material; immobilizing the material; and/or reducing the evolution of harmful or unwanted gaseous forms from the spillage, preferably using a binding agent which comprises a polyacrylate-polyacrylamide cross-linked copolymer.

Abstract: Winrows is a specific process which executes in synergy with Fill-A-Box©™ and Stat-Medicament-Disposal(c)™ removal of food waste (bio-waste) from landfills and water systems. It quantifies data by address/location by weight of food waste (bio-waste) that is then converted under cap and trade to carbon off-set credits for address/location through Greenebank(c)™. It is a converted 13 gallon collapsible garbage holder that has been modified to hold extra bags and a carbon filter. The food waste (bio-waste) is used in vermiculture, and composting. The liquid by-product and final product is harvested and sold and any excess is converted to swill for pig feed. Curbside pickup by Fill-A-Box©™ scans and weighs the bags and transmits data to Winrows database by address/location.

Abstract: A method of sterilizing a closed environment is provided in which a disinfection apparatus is placed into the closed environment; it then generates ozone to a predetermined ozone concentration, following which the humidity of the closed environment is rapidly increased. A catalytic converter then reduces the ozone concentration to safe levels. When the ozone concentration is reduced to a predetermined safe level, the disinfection apparatus signals.

Abstract: A drug deactivation system according to some embodiments includes at least one drug-retaining region of a drug delivery device and at least one energy source coupled to the at least one drug-retaining region. The at least one drug-retaining region may be configured to retain a drug. The at least one energy source may be configured to transmit energy to the drug. The drug is capable of being rendered ineffective in the presence of the transmitted energy.

Abstract: A polymeric hypernucleophilic catalyst is effective for hydrolytic destruction of chemical threat agents under mild conditions, e.g., near neutral pH and at ambient temperatures. The polymeric hypernucleophilic catalysts are particularly useful to affect rapid destruction of chemical threat agents on sensitive surfaces such as paint, metal, rubber, plastic, fabric, wood, and skin. Catalyst formulations such as creams, lotions, sprays, foams, powders, or gels, and articles such as filters, wipes, membranes, yarns, fabrics, and articles of clothing, may be used for detoxification of or prophylactic protection against chemical threat agents.

Abstract: The present invention discloses a method for solidifying and stabilizing waste acid including steps of condensing waste acid containing phosphoric acid to reduce the volume; mixing the condensed waste acid with waste acid containing fluoroboric acid to solidify and stabilize the mixed waste acid. The pH of the mixed acid is adjusted by adding barium hydroxide as a neutralizer. The efficiency of solidifying waste acid can be improved by partially granulating and by adding solidifying agent indirectly. The method of the present invention can prevent intensely exothermic reaction caused by adding solidifying agents. Furthermore, the method of the present invention is controlled in a temperature of 30 to 45° C. to improve the polymerization of the mixed waste acid so that the efficiency of solidification thereof can be also improved.

Abstract: The present application is concerned with compositions for providing phase-stable microemulsion decontamination formulations for treating surfaces, and in particular for treating surfaces contaminated with chemical and/or biological warfare agents.

Abstract: An adsorbent material comprising a metal organic phase and a porous silica phase is provided. The adsorbent material can be a synthesized from at least one porous silica material, one or more metal ions, and at least one organic linker comprising one or more multidentate functional groups capable of forming coordinate bonds with the metal ions. The porous silica can be an ordered mesoporous silica material. Methods of making the adsorbent material and methods of removing molecules from a fluid using the adsorbent material are also provided.

Abstract: A process has been developed to selectively dissociate target molecules into component products compositionally distinct from the target molecule, wherein the bonds of the target molecule do not reform because the components are no longer reactive with each other. Dissociation is affected by treating the target molecule with light at a frequency and intensity, alone or in combination with a catalyst in an amount effective to selectively break bonds within the target molecule. Dissociation does not result in re-association into the target molecule by the reverse process, and does not produce component products which have a change in oxidation number or state incorporated oxygen or other additives because the process does not proceed via a typical reduction-oxidation mechanism. Target molecules include ammonia for waste reclamation and treatment, PCB remediation, and targeted drug delivery.

Abstract: A recycling furnace and method are provided for processing potentially explosive precious metal-containing materials having organic fractions that combust with great energy, the furnace including a switching facility for alternating operation of a burning-off chamber of the furnace between: (A) pyrolysis or carbonization under protective furnace gas in an atmosphere comprising maximally 6 wt-% oxygen, and (B) oxidative combustion of the organic fractions including carbon. The furnace has indirect heating and a control that determines the end of the pyrolysis or carbonization by a sensor and controls the switching facility to supply air or oxygen to the interior of the furnace. Steps (A) and (B) are carried out sequentially in the furnace chamber, wherein neither the batch is changed, nor the furnace is opened. After the end of step (A) is determined, step (B) proceeds right after the pyrolysis or carbonization by supplying air or oxygen.

Abstract: Method for in situ reclamation of an area contaminated by organic compounds, comprising: introducing at least one chelating agent into said area; allowing said chelating agent to diffuse through said area; introducing at least one stabilizing agent; introducing an aqueous solution comprising at least one peroxide.

Abstract: The present invention relates to a treatment by pulmonary delivery of bioscavengers to animals as an effective antidote to prevent toxicity produced by exposure of an animal to nerve agents and other toxic substances.

Abstract: An apparatus for concentration and deactivation of actinide nuclear materials having a pair of spaced apart electrodes made of a composite material including at least one oxide, at least one carbon-containing material and lead, a nuclear waste water stream flowing between the electrodes, and a DC power supply operably connected with the electrodes. When a voltage is applied to the spaced apart electrodes, nuclear cations in the nuclear waste water stream are attracted to one of the electrodes and anions in the nuclear waste water stream are attracted to the other of the electrodes, forming a substantially deionized water stream and a concentrated nuclear waste stream.

Abstract: High temperature reaction of halogen-containing carbon, boron, silicon and nitrogen compounds with other compounds generates energy.

Abstract: A waste processing system (10) evaluates the waste processing requirements of a waste producing entity (20, 30) and evaluates the waste processing capabilities of vendors (40, 60, 80), and manages the waste processing of waste components produced by a waste producing entity (20, 30) by selecting vendors (40, 60, 80) to service the waste producing entity (20, 30).

Abstract: Systems, methods and processes teach by specific examples how the cost of sequestering carbon dioxide (CO2) can be totally offset and turned into profits during coal powered electricity generation from revenue and co-benefits. The process is provided whereby fly ash-carbon mixtures, or de-volatilized coal char, or anthracite coal culm is co-fired in an air-cooled, slagging combustor with limestone or similar slag fluxing materials converts the ash into cementitious slag with properties similar to ground granulated blast furnace slag.

Abstract: The present invention relates to the use of lithium salts and/or magnesium salts for the precipitation of aluminum oxides present in aqueous media.

Abstract: The present invention relates to the use of lithium salts and/or magnesium salts for the precipitation of aluminum oxides present in aqueous media.

Abstract: A reuse apparatus of eutectic salt waste produced in an electro refining process and a method thereof is a technology that in order to collect the eutectic salt of the eutectic salt waste, oxidizes/precipitates nuclides (rare earth and TRU) within the eutectic salt waste, an oxygen dispersing method is used to perform a layer separation into the eutectic salt layer and the precipitate layer. Then, the precipitate layer and eutectic salt layer are separated and collected, so that the eutectic salt layer is directly reused and the eutectic salt within the precipitates is reused by separating and collecting it using distillation/condensation processes. The reuse apparatus of the eutectic salt waste and a method thereof thereby increases the collecting efficiency of the eutectic salt and allows the compositions of the collected eutectic salt to have the same compositions as the eutectic salt used in the electro refining process.

Abstract: An object of the present invention is to continuously feed an object to be treated to a high-pressure reactor which treats the object to be treated containing 10 mass % or more of water under high pressure, while preventing backflow of a high-pressure atmosphere from the high-pressure reactor. This is embodied by making a configuration such that the object to be treated is fed to the high-pressure reactor connected to a discharge port of a screw feeder which is provided with a feed unit for the object to be treated and the discharge port on one end side and the other end side respectively and forms a high-pressure atmosphere pressurized to, for example, 2 MPa or higher, while air-tightness between the high-pressure atmosphere and the one end side of the screw feeder is maintained by a sealing action of an accumulation compressed on the other end side of the screw feeder.

Abstract: Composition and process of encapsulation of sediment particles to reduce active pollutant components through surface charge modification.

Abstract: A method for in situ generation of a decontamination solution adapted to decontaminate mustard agents by oxidation and nerve agents by perhydrolysis, comprising the steps of generating a stable precursor solution of aqueous NH4HCO3 by bubbling CO2 and NH3 into a container of water; and adding a peroxide component to the precursor solution. The step of bubbling CO2 into a container of water may be accomplished by bubbling fossil fuel engine exhaust including CO2 directly into the container of water.

Abstract: A flexible process for the preparation and conditioning of sedimentary materials. The degree of decontamination of these dredged materials is enhanced by the use of chemical indicators. Based upon the level of contamination contained within this material the process is used to isolate the specific contamination and utilize a variable process to decontaminate these compounds. Not all of the compounds contained within the dredged sediment is treated the same way. The process is designed to isolate the composite of materials and treat each particle with a different process based upon its classification. Post treatment, this material may be combined and dewatered for a suitable use.

Abstract: It is an object to provide a method whereby with respect to a microorganism present in an environment contaminated with tetrachloroethylene (PCE) and trichloroethylene (TCE), capability of the microorganism to degrade contaminants can be judged promptly. In order to achieve the above-described object, a biological activity judging method according to the present invention is a method of judging capability of a contaminated environment to eliminate an organochlorine compound, in which using a DNA probe that allows a bacterium to be detected specifically, which has a degradation activity with respect to the organochlorine compound and/or a dechlorinated product thereof, the bacterium in the environment is detected. The present invention also provides a new type of polynucleotide that can be used as a DNA probe in the biological activity judging method according to the present invention.

Abstract: A drug deactivation system according to some embodiments includes at least one drug-retaining region of a drug delivery device and at least one energy source coupled to the at least one drug-retaining region. The at least one drug-retaining region may be configured to retain a drug. The at least one energy source may be configured to transmit energy to the drug. The drug is capable of being rendered ineffective in the presence of the transmitted energy.

Abstract: Apparatus, process and article for treating an aqueous solution containing a chemical contaminant. The process includes contacting an aqueous solution containing a chemical contaminant with an aggregate composition comprising an insoluble rare earth-containing compound to form a solution depleted of chemical contaminants. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from a cerium carbonate, cerium oxalate and/or a cerium salt. The aggregate composition can include more than 10.01% by weight of the insoluble rare earth-containing compound, and in a particular embodiment consists essentially of one or more cerium oxides, and optionally a binder and/or flow aid. Although intended for a variety of fluid treatment applications, such applications specifically include removing or detoxifying chemical contaminants in water.

Abstract: A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100° C.-200° C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry.

Abstract: An isolated and purified bacterium is provided which was isolated from a high-level radioactive waste site of mixed waste. The isolate has the ability to degrade a wide variety of organic contaminants while demonstrating high tolerance to ionizing radiation. The organism is uniquely suited to bioremediation of a variety or organic contaminants while in the presence of ionizing radiation.

Abstract: A waste collection device that includes a sweep that includes a plate and a handle, and a scoop that includes a receptacle and a handle.

Abstract: Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

Abstract: When microbial contamination is introduced into a room (20*) of an enclosure, such as a building, an HVAC system including supply ductwork (16) and a return ductwork (34) is decontaminated with hydrogen peroxide vapor. A decontamination controller (46) operates controllable baffles (22) at outlet registers (20), temporary controllable baffles (44) at inlet registers (30), and a blower system (10) to circulate hydrogen peroxide vapor from hydrogen peroxide vapor generators (42) through the ductwork in both forward and reverse directions. Further, at least portions of the baffles are closed to create dwell times in which the hydrogen peroxide vapor resides in the ductwork with minimal or turbulent flow.

Abstract: A disposal device for collecting bags for bodily fluids has a receptacle for receiving at least one collecting bag containing bodily fluid, a comminution unit (2) for comminuting the collecting bag, a fluid collecting basin (5) for receiving the bodily fluid, a particle collecting container (8) for receiving the comminuted collecting bag, and at least one decontamination unit (7) for the decontamination of the collecting bag and the bodily fluid.

Abstract: Hydrogen peroxide is vaporized (20) and mixed (30) with ammonia gas in a ratio between 1:1 and 1:0.0001. The peroxide and ammonia vapor mixture are conveyed to a treatment area (10) to neutralize V-type, H-type, or G-type chemical agents, pathogens, biotoxins, spores, prions, and the lip-,e. The ammonia provides the primary deactivating agent for G-type agents with the peroxide acting as an accelerator. The peroxide acts as the primary agent for deactivating V-type and H-type agents, pathogens, biotoxins, spores, and prions. The ammonia acts as an accelerator in at least some of these peroxide deactivation reactions.

Abstract: A vehicle braking system reduces particulate emissions resulting from wear of the brake pad and rotor during stopping or slowing of a vehicle. The rotor includes at least one friction surface, that has an outer coating of a corrosion and wear-resistant material. This outer coating can optionally include a first layer comprising a crystalline material and a second layer overlaying and contacting the first layer and comprising an amorphous material. The first layer and the second layer can optionally have an inter-layer period of less than 10 nm such that the structure of the outer coating is that of a superlattice. A brake member that includes a friction material is mounted to a caliper on the vehicle with the friction material disposed opposite the at least one friction surface so that the friction material reversibly engages with the outer coating of the corrosion and wear-resistant material when the braking system is operated to stop or slow the vehicle.

Abstract: A sterilization system that includes a sensor for determining the concentration of a liquid sterilant in a sterilant fluid. The sterilant fluid is comprised of a blend of sterilant fluids from a plurality of sterilant supplies. The concentration of the liquid sterilant differs in each of the sterilant supplies. The sensor allows a controllable concentration of liquid sterilant to be supplied to a vaporizer.