Dehalogenation Using Reactive Chemical Agents Able To Degrade (epo/jpo) Patents (Class 588/316)
  • Patent number: 7252771
    Abstract: The invention relates to a process and a device for decontaminating waters, especially groundwaters, which are heavily and complexly polluted with organic halogen compounds (HHC), in which process the contaminated waters are pre-treated in order to convert low-volatility HHC into more readily volatile components, the halogenated hydrocarbons are subsequently transferred from the aqueous phase to the gaseous phase where complete conversion into halogen-free compounds takes place at elevated temperature by means of catalytic reductive dehalogenation.
    Type: Grant
    Filed: July 12, 2002
    Date of Patent: August 7, 2007
    Assignee: Helmholtz-Zentrum fur Umweltforschung GmbH-Ufz
    Inventors: Franz-Dieter Kopinke, Katrin MacKenzie, Robert Koehler, Holger Weiss, Peter Grathwohl, Christoph Schueth
  • Patent number: 7129388
    Abstract: Accelerated dechlorination of soil and water contaminated with chlorinated solvents is achieved by stimulating anaerobic microorganisms and thus increasing the rate of biological mineralization of the solvents. This is accomplished by a treatment process consisting of colloidal suspension of iron powder, polylactate ester such as glycerol tripolylactate, xylitol pentapolylactate, and sorbitol hexapolylactate, chemical oxygen scavengers in solution with essential nutrients, and vitamin stimulants such as B2 and B12 delivered via compressed gases N or C02 so as not to oxygenate an environment targeted for anaerobic processes. The treatment stimulates naturally occurring microorganisms while oxidizing dissolved phase target compounds via the surface action of the iron particles resulting in the breakdown of chlorinated solvents such as tetrachloroethene, trichloroethene, carbon tetrachloride and their daughter products.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: October 31, 2006
    Assignee: Innovative Environmental Technologies, Inc.
    Inventors: Michael Scalzi, Wade Meese
  • Patent number: 7034198
    Abstract: A conventional method of pyrolytically decomposing plastic to make low-molecular compounds is poor in efficiency of use of energy due to high heating temperatures (at least 600° C. and 800° C. at maximum). The invention provides that a functional powder is heated to a predetermined temperature and pieces of plastic to be disposed are caused to be contacted with the heated powder, the functional powder including a powder which does in an aqueous solution state show alkalinity, and a photo-catalyst effect powder.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: April 25, 2006
    Assignee: Osada Giken Co., Ltd.
    Inventors: Hideharu Osada, Tatsutoshi Shimabara
  • Patent number: 7005117
    Abstract: A method of removing harmful components of a perfluorocarbon gas or a perfluorocompound including the step of mixing at least one of a hydrocarbon gas and NH3 gas with an exhaust gas containing a perfluorocarbon or a perfluorocompound discharged from manufacturing equipment. The method also includes the step of thermally decomposing the resulting mixed gas in a non-oxidizing atmosphere.
    Type: Grant
    Filed: September 25, 2002
    Date of Patent: February 28, 2006
    Assignee: Kanken Techno Co., Ltd.
    Inventor: Hiroshi Imamura
  • Patent number: 6984768
    Abstract: A method for destroying halocarbons. Halocarbon materials are reacted in a dehalogenation process wherein they are combined with a solvent in the presence of a catalyst. A hydrogen-containing solvent is preferred which functions as both a solvating agent and hydrogen donor. To augment the hydrogen donation capacity of the solvent if needed (or when non-hydrogen-containing solvents are used), a supplemental hydrogen donor composition may be employed. In operation, at least one of the temperature and pressure of the solvent is maintained near, at, or above a critical level. For example, the solvent may be in (1) a supercritical state; (2) a state where one of the temperature or pressure thereof is at or above critical; or (3) a state where at least one of the temperature and pressure thereof is near-critical. This system provides numerous benefits including improved reaction rates, efficiency, and versatility.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: January 10, 2006
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Daniel M. Ginosar, Robert V. Fox, Stuart K. Janikowski