Abstract: Method for in situ reclamation of an area contaminated by organic compounds, comprising: introducing at least one chelating agent into said area; allowing said chelating agent to diffuse through said area; introducing at least one stabilizing agent; introducing an aqueous solution comprising at least one peroxide.

Abstract: The present invention relates generally to chemical and biological decontamination solutions and methods of using them. The invention is useful for decontaminating a wide range of compounds and organisms. In particular, the systems, methods, solutions, and formulations of the invention can be used to remove and/or neutralize organophosphates and other toxic chemicals, bacteria, bacterial spores, fungi, molds and viruses.

Abstract: An improved oxidization process may be used to oxidize a wide variety of feedstocks. Oxidation takes place in a reactor where the feedstock is mixed with an oxidizing acid, such as nitric acid. The reaction mixture may also include a secondary oxidizing acid such as sulfuric acid as well as water and/or dissolved and mechanically mixed oxygen gas. The reactor may be maintained at an elevated pressure such as at least approximately 2070 kPa or desirably at least approximately 2800 kPa. The temperature of the reaction mixture may be maintained at no more than 210° C.

Abstract: A method for remediating land contaminated by a combustible material, in particular, land contaminated with non-aqueous phase liquids (NAPLs), which includes the steps of locating a subterranean volume of combustible material such as a DNAPL in land to be remediated, and igniting the combustible material to combust the material and thereby remediate the land. By monitoring combustion of the material, combustion may be optimised by, for example, supplying an oxidant or a combustion suppressant.

Abstract: The invention relates to a method and an apparatus for treating exhaust gases comprising organosilicon components or accompanying substances. The invention more specifically relates to the use of bulk regenerator materials as storage materials allowing periodic removal, purification, and redelivery to the system. The invention solves the problem of clogged regenerator-storage materials during regenerative post-combustion of exhaust gases containing organosilicon components.

Abstract: A method for treating a nitric aqueous liquid effluent containing nitrates of metals or metalloids, comprising a step for calcination of the effluent in order to convert the nitrates of metals or metalloids into oxides of said metals or metalloids, at least one compound selected from the nitrates of metals or metalloids and the other compounds of the effluent leading upon calcination to a tacky oxide, and a dilution adjuvant comprising at least one nitrate of metal or metalloid leading upon calcination to a non-tacky oxide being added to the effluent prior to the calcination step in order to give a mixture of effluent and of dilution adjuvant.

Abstract: A method of reducing styrene emissions in aqueous cured-in-place pipe closed molding processes and other aqueous environments using a styrene reduction agent. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. Capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process in order to reduce the residual monomer content in either process or waste streams.

Abstract: The invention provides a novel method of detoxifying highly toxic chemicals, and treating surfaces contaminated, or potentially contaminated, with toxic chemical agents such as chemical warfare agents and/or industrial toxins. The methods utilizes a novel sorbent compound which comprises Mn(VII) mineral which can be either solid supported or non-solid supported. The Mn(VII) mineral can be provided in a number of different forms including creams, lotions, powders, liquids, slurries and aerosols.

Abstract: A hazardous gas abatement system decontaminates an exit gas stream containing global warming gases using an electrical heater and a water scrubber. One or more top flow hazardous gas inlets introduce hazardous gases into a heater compartment. Air or oxygen is introduced into a separate chamber for dynamic oxidation and cooling. The streams are mixed and oxygen reacts with the hazardous gases. Solid particulates from the reaction are removed by a filter in a quick disconnect bottom chamber. Filtered exhaust gases flow upward in an exhaust chamber surrounding the heater compartment and through water spray scrubbers. A cleaning ring mounted on an eccentric rod cleans particles from the outside of the internal heater, and the inside of the external heater. An air cylinder drives the eccentric rod and cleaning ring down and up between the heaters and stores the ring above the gas inlets.

Abstract: The present invention relates to a method for the degradation of pollutants in water and/or soil. More specific, the present invention relates to a method for the on-site decontamination or re-mediation of water and/or soil which are contaminated with organic compounds. Moreover, the invention relates to a method for forming a barrier against the spreading of a contamination with pollutants within the water and/or soil, especially within groundwater (aquifer). Further, the invention relates to means for use in these methods, and to the production of such means.

Abstract: A method and system for the reduction of contamination in soil and groundwater is provided. A clathrate of ozone and a cyclic oligosaccharide can provide for an extended zone of influence due to, for instance, the improved stability of the ozone. The clathrate can include cyclodextrin and ozone and can improve the oxidative destruction of organic and inorganic contaminants.

Abstract: Method and composition for decomposing and detoxifying chemical warfare agents, organic toxic compounds (e.g., pesticides), and for removal of contaminants in materials including fuels. The method and composition are based on ferrate (VI). The ferrate is typically applied to a contaminated surface or volume with a phase transfer catalyst and/or with a carrier.

Abstract: Process for the destruction of toxic residues via oxidation in the presence of water and oxygen developed in homogenous phase at temperatures over 374° C. and pressure of at least 220 atmospheres and a continuous mobile unit easily transferred to treat effluents or contaminated media. This mobile unit is composed of a reactor, which includes pressurization, reaction, cooling, depressurization and sampling zones for the destruction of toxic residues like polychloride biphenyls (PCBs), pyridines, and other hazardous compounds.

Abstract: A reduced weight decontamination formulation that utilizes a solid peracid compound (sodium borate peracetate) and a cationic surfactant (dodecyltrimethylammonium chloride) that can be packaged with all water removed. This reduces the packaged weight of the decontamination formulation by ˜80% (as compared to the “all-liquid” DF-200 formulation) and significantly lowers the logistics burden on the warfighter. Water (freshwater or saltwater) is added to the new decontamination formulation at the time of use from a local source.

Abstract: A method is provided for decontaminating a surface that is susceptible to contamination by a contaminant by applying to the surface a coating which produces a decontaminating agent for the contaminant in response to a signal, connecting the electroactive coating to a source of a signal, and when the surface is contaminated, applying the signal to the electroactive coating, thereby producing one or more decontaminating agents which neutralize or destroy the contaminant. Coatings for practicing the method and articles that have been protected by the novel coatings are also provided.

Abstract: Provided is a method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis. More specifically, the method of decomposing plastic and organic waste by using titanium oxide granules which are easily separated from metals and inorganic substances, have a highly efficient decomposing capability, and have a characteristic of fine powder formation resistance during pyrolysis has been established by optimizing the characteristics of titanium oxide granules.

Abstract: A method for in-situ reduction of contaminants in soil.

Abstract: Process for recovering metals from metal-containing wastes and materials, characterized in that the metal-containing waste is preferably introduced continuously into a process chamber, treated thermally with continuous intensive mixing, the organic components are continuously removed and subsequently oxidized and the metal-containing components, preferably as metal conglomerates, and the further inorganic metal-free components are discharged essentially continuously from the process chamber and a plant for carrying out the process.

Abstract: Exemplary compositions, methods, and systems are disclosed that can be useful for reducing a concentration of a contaminant associated with a medium, which can be any substance or material, such as soil, water, air, and/or fluid. In one exemplary method, the medium is treated with Fe-MDGA and an oxidizing agent in amounts effective to oxidize at least a portion of the contaminant.

Abstract: To provide a method and apparatus for treating a waste gas containing fluorine-containing compounds, according to which PFCs can be decomposed efficiently even at low temperature, and moreover fluorine from the product of the decomposition can be recovered for reuse efficiently. An embodiment of the present invention relates to a method of treating a gas containing a fluorine-containing compound, comprising contacting the gas with a treatment agent comprising a mixture of aluminum hydroxide and calcium hydroxide.

Abstract: A method, apparatus, and system to apply a mineralizing agent to an asbestos containing material (ACM) after the ACM is reduced in size, particularly by spraying or injecting the mineralizing agent to a shredded ACM, is provided. The mineralizing agent may include a solution of alkali metal hydroxide, alkali metal silicate, alkali metal borate, alkaline earth borate, or mixtures thereof, which may be heated and mixed and is then delivered to the reduced size or shredded ACM using a piping system that injects the mineralizing agent downstream of an ACM shredding unit. The ACM treated with the mineralizing agent may be heated in a mineralizing furnace to convert the ACM to an essentially asbestos-free mineral. After removal from the mineralizing furnace, the mineralized material is moved to an atmosphere controlled environment where it is cooled gradually for further mineralization.

Abstract: Nano-size particles of calcium dioxide and magnesium dioxide for remediation of contaminated water or soil and processes for preparing and using nano-size particles of calcium dioxide and magnesium dioxide.

Abstract: Exemplary compositions, methods, and systems are disclosed that can be useful for reducing a concentration of a contaminant associated with a medium, which can be any substance or material, such as soil, water, air, and/or fluid. In one exemplary method, the medium is treated with Fe-MDGA and an oxidizing agent in amounts effective to oxidize at least a portion of the contaminant. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure.

Abstract: An improved oxidization process may be used to oxidize a wide variety of feedstocks. Oxidation takes place in a reactor where the feedstock is mixed with an oxidizing acid, such as nitric acid. The reaction mixture may also include a secondary oxidizing acid such as sulfuric acid as well as water and/or dissolved and mechanically mixed oxygen gas. The reactor may be maintained at an elevated pressure such as at least approximately 2070 kPa or desirably at least approximately 2800 kPa. The temperature of the reaction mixture may be maintained at no more than 210° C.

Abstract: The invention relates to a foaming decontaminating aqueous solution, characterized in that it comprises, by weight relative to the total weight of the composition: 0.1% to 20% of an organic or mineral water-soluble peroxidizing agent; 0.05% to 20% of an anionic surfactant; 0.

Abstract: A method for immobilizing metal in soil includes blending slag fines with soil to form a media. The slag fines immobilize metal present in the media and reduce leaching of the metal into water.

Abstract: A styrene reduction agent that effectively and economically reduces styrene emissions in Cured-In-Place Pipe, closed molding processes. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. Capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process in order to reduce the residual monomer content in either process or waste streams.

Abstract: Presented herein are compositions including a linear tenso-active surfactant which, upon contact and mechanical stirring of a hydrocarbon body, induces emulsification, resulting in oxidation of fatty acid aliphatic bodies. The compositions solve the problem of hydrocarbon pollution. The hydrocarbon decomposer and its by-products dissolve hydrocarbons present in polluted bodies such as clays, soils, water and sand. Methods of the invention create a residue that is a fertilizer, at room temperature and with no need for high pressure.

Abstract: The current invention encompasses a microemulsion having environmentally safe components, the microemulsion exhibiting optical clarity and stability over a wide range of temperatures. The microemulsion also forms a part of a decontaminant solution for treating chemical and biological contaminant agents, the solution preferably containing peroxycarboxylic acids generated from solids as the primary decontamination agent. The solution is a single phase emulsion that is both stable and effective over a broad range of temperatures, the range extending well below 0° C. There is also disclosed a microemulsion decontaminate solution having components that stabilize the included solid and peroxycarboxylic acids.

Abstract: A method for treating waste water is provided, in which a wastewater is treated through a distilling process to obtain a distilled liquid, and then a reactant is added into the distilled liquid during the distilled liquid flowing to a liquid collecting tank, such that the reactant reacts with the distilled liquid by utilizing the residual temperature of the distilled liquid to form a processed liquid. Meanwhile, a system for wastewater treatment is also provided, which includes a distillation unit, a guiding unit, a means for adding the reactant, and a collecting unit. Since the present invention utilizes the residual temperature of the distilled liquid for the need of the reaction, an additional heat source is unnecessary, such that the consumption of energy can be greatly reduced.

Abstract: A combination of a styrene reduction agent and a catalyst that effectively and economically reduces styrene emissions in Cured-In-Place Pipe, closed molding processes. The reduction agent generally comprises a calibrated mixture of salts including sodium chloride plus three persulfate salts: ammonium (APS), potassium (KPS), and sodium (NPS). These ingredients are combined in powder form and are compressed into soluble capsules containing calibrated amounts of the mixture. The capsule(s) may be prescribed through the use of software. The catalyst is hydrogen peroxide (H2O2). A calibrated amount of the styrene reduction agent capsule(s) are added to the cure water prior to starting the boiler equipment for the Cured-In-Place Pipe process, and this is followed by a calibrated amount of the H2O2 catalyst in order to reduce the residual monomer content in either process or waste streams.

Abstract: An improved method and compositions for treating organic compounds present in soil, groundwater and other environments is disclosed. The method involves the use of a composition comprising a solid state, water soluble peroxygen compound and zero valent iron.

Abstract: A process for recovery of the silica present in the separators located between the elements of lead-acid batteries characterized in that it comprises the following operations: a) washing the heavy plastics to remove the lead compounds and other foreign bodies, b) separating the plastics from the washing solution, c) lead recovery and regeneration of the washing solution, d) rinsing of the plastics, e) drying of the plastics, f) separation of the granular plastics from the thin plastics (polyethylene with silica filler, PVC, fabrics) by drawing them up in a flow of air making use of the shape effect, g) separation of the PVC and fabrics from the polyethylene with silica filler through fragmentation, h) pyrolysis of the polyethylene with silica filler, i) cracking of the pyrolysis gases and vapours in order to reduce their molecular weight and render them more suitable for handling and combustion to provide the heat necessary for pyrolysis, j) oxidation of the pyrolysis residue to remove carbonaceous residues a

Abstract: The present invention refers to a method and a system for the complete recycling of municipal solid wastes with minimal environmental impact and with the exploitation of the wasted solid recovery fuel (WSRF) for the production of electric energy and/or hydrogen. Those results are achieved by means of the gasification of the WSRF in a reactor where the volatile and the inorganic components are combusted separately thus allowing contemporary the further treatment of the synthesised gas and the recovery of mineral and metallic molten granulates.

Abstract: A method of degrading carbon nanomaterials includes mixing the carbon nanomaterials with a composition comprising a peroxide substrate and at least one catalyst selected from the group of an enzyme and an enzyme analog. The peroxide substrate undergoes a reaction in the presence of the catalyst to produce an agent interactive with the nanotubes to degrade the carbon nanomaterials. The peroxide substrate can, for example, be hydrogen peroxide or an organic peroxide.

Abstract: Methods and compositions for removing contaminants from soil and groundwater by extracting the contaminants and assisting the extraction by provision of an oxidant introduced prior to or simultaneously with a surfactant into the subsurface. Extractable contaminant can be extracted from the subsurface. The amount and/or distribution of contaminant in the subsurface can be characterized. The extracting of contaminant and the introducing of oxidant and surfactant can be coordinated to reduce contaminant to a target amount. A portion of the contaminant can be oxidizable.

Abstract: Industrial process for the treatment of RSW without selecting, that after being milled are added with sanitizing solutions, binders and hardeners which chemically immobilize them avoid the production of percolating liquids, leaching of heavy metals and generation of greenhouse gases. The resulting material—a grey, warm and malleable paste—forges, allowing diverse uses; it can be directly buried in the ground without special protections; can be used as construction material for urban furniture or architectural structures; or can be anchored in the ocean, building habitats of ocean ecosystems, if it is properly packaged in waterproof material.

Abstract: The present invention relates generally to chemical and biological decontamination solutions and methods of using them. The invention is useful for decontaminating a wide range of compounds and organisms. In particular, the systems, methods, solutions, and formulations of the invention can be used to remove and/or neutralize organophosphates and other toxic chemicals, bacteria, bacterial spores, fungi, molds and viruses.

Abstract: A decontamination formulation and method of making that neutralizes the adverse health effects of both chemical and biological compounds, especially chemical warfare (CW) and biological warfare (BW) agents, and toxic industrial chemicals. The formulation provides solubilizing compounds that serve to effectively render the chemical and biological compounds, particularly CW and BW compounds, susceptible to attack, and at least one reactive compound that serves to attack (and detoxify or kill) the compound. The formulation includes at least one solubilizing agent, a reactive compound, a sorbent additive, and water. A highly adsorbent sorbent additive (e.g., amorphous silica, sorbitol, mannitol, etc.) is used to “dry out” one or more liquid ingredients into a dry, free-flowing powder that has an extended shelf life, and is more convenient to handle and mix in the field.

Abstract: A method of performing soil decontamination including mechanically mixing the soil with solid oxidant prior to any addition of water and until an exothermic reaction between the oxidant and contaminants within the soil occur, adding only necessary water to obtain an homogeneous mix between the soil and the oxidant, and mechanically mixing the soil with the oxidant and the water for a predetermined period of time to allow the oxidant to at least partially oxidize the contaminants.

Abstract: The current invention encompasses a microemulsion having environmentally safe components, the microemulsion exhibiting optical clarity and stability over a wide range of temperatures. The microemulsion also forms a part of a decontaminant solution for treating chemical and biological contaminant agents, the solution preferably containing peroxycarboxylic acids generated from solids as the primary decontamination agent. The solution is a single phase emulsion that is both stable and effective over a broad range of temperatures, the range extending well below 0° C. There is also disclosed a microemulsion decontaminate solution having components that stabilize the included solid and peroxycarboxylic acids.

Abstract: A system for treating carbon-containing or silicon-containing end-of-life material includes a reactor 10 for simultaneously supporting oxidation of the waste material and conversion of CO2 within the reactor. A metal oxide or metal is input to the reactor to convert the CO2 to a mineralized CO2 product. A cold trap 44 is provided for capturing exhaust gases from the reactor and returning condensate to the reactor, and a pump 50 maintains a desired vacuum or pressure within the reactor and the cold trap.

Abstract: A system for removing mercury from combustion gas. The system includes a combustion device, a stack, and a duct system that couples the combustion device to the stack. The system further comprises an injection system that is coupled to the duct system. The injection system injects sorbents including alkali-based sorbents and carbon-based sorbents into the duct system.

Abstract: Compositions, materials incorporating the compositions, and methods of use thereof, are disclosed. In one embodiment, the composition includes a metal nitrate selected from d-block metal nitrates and f-block metal nitrates and a metal salt having weakly bound counter anions. The metal of the metal salt having weakly bound counter anions is selected from a d-block metal and an f-block metal. Another embodiment of the composition includes a first polyoxometalate having a first metal selected from a d-block metal and an f-block metal and a second polyoxometalate having a second metal selected from a d-block metal and an f-block metal. The first metal being an open coordinate site of the first polyoxometalate. In addition, the first metal has a nitrate terminal ligand. The second metal being an open coordinate site of the second polyoxometalate. In addition, the second metal has a halide terminal ligand.

Abstract: Disclosed is a method, apparatus and system for the remediation of contaminated soils, groundwater and water. A combination of reagents such as persulfate and ozone or persulfate, ozone and hydrogen peroxide may be used to enhance destruction of organic contaminants. Reagents may be injected into the smear zone to trap and destroy volatile compounds that may otherwise escape treatment.

Abstract: Certain exemplary embodiments provide methods for reducing a concentration of a contaminant associated with a medium, which can be any substance or material, such as soil, water, air, and/or fluid. In one exemplary method, the medium is treated with a ferric chelate and an oxidizing agent in amounts effective to oxidize at least a portion of the contaminant.

Abstract: Decontamination formulations with an additive for enhancing mold remediation. The formulations include a solubilizing agent (e.g., a cationic surfactant), a reactive compound (e.g., hydrogen peroxide), a carbonate or bicarbonate salt, a water-soluble bleaching activator (e.g., propylene glycol diacetate or glycerol diacetate), a mold remediation enhancer containing Fe or Mn, and water. The concentration of Fe2+ or Mn2+ ions in the aqueous mixture is in the range of about 0.0001% to about 0.001%. The enhanced formulations can be delivered, for example, as a foam, spray, liquid, fog, mist, or aerosol for neutralization of chemical compounds, and for killing certain biological compounds or agents and mold spores, on contaminated surfaces and materials.

Abstract: A molecularly imprinted polymer and production process therefor and a process for selective treatment of poorly degradable and/or toxic compounds in liquids using the molecularly imprinted polymers. Such polymers and processes are required for selective removal and/or degradation of biological, poorly degradable pollutants or toxic compounds, for example from wastewaters. Consequently, a molecularly imprinted polymer suitable for the selective treatment of at least one poorly degradable and/or toxic compound is provided having a polymeric network which is made up of monomers and has cavities of predetermined size, wherein the cavities are arranged at predetermined spacings and have specific binding sites and/or patterns for the poorly degradable and/or toxic compounds.

Abstract: A composition including at least one peroxide-generating electrocatalyst, at least one peroxide-activation catalyst, and carbon.

Abstract: The present application is concerned with compositions for providing phase-stable microemulsion decontamination formulations for treating surfaces, and in particular for treating surfaces contaminated with chemical and/or biological warfare agents.