To Temper Or Strengthen The Glass Patents (Class 65/30.14)
  • Patent number: 9595286
    Abstract: A magnetic-disk glass substrate has a circular center hole, a pair of main surfaces and an edge surface. The edge surface has a side wall surface and chamfered surfaces interposed between the side wall surface and the main surfaces, and a roundness of an edge surface on an outer circumferential side is 1.5 ?m or less. Also, a midpoint A between centers of two least square circle respectively derived from outlines in a circumferential direction respectively obtained at two positions spaced apart by 200 ?m in a substrate thickness direction on the side wall surface on the outer circumferential side, and centers B and C respectively derived from a respective one of two chamfered surfaces on the outer circumferential side in the substrate thickness direction, are located such that a sum of respective distances between A and B, and A and C, is 1 ?m or less.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: March 14, 2017
    Assignee: HOYA CORPORATION
    Inventors: Masanori Tamaki, Takeyoshi Takahashi, Masaaki Ueda
  • Patent number: 9567259
    Abstract: Described herein are various antimicrobial glass articles that have improved resistance to discoloration when exposed to harsh conditions. The improved antimicrobial glass articles described herein generally include a glass substrate that has a low concentration of nonbridging oxygen atoms, a compressive stress layer and an antimicrobial silver-containing region that each extend inward from a surface of the glass substrate to a specific depth, such that the glass article experiences little-to-no discoloration when exposed to harsh conditions. Methods of making and using the glass articles are also described.
    Type: Grant
    Filed: February 10, 2014
    Date of Patent: February 14, 2017
    Assignee: Corning Incorporated
    Inventors: Jaymin Amin, Nicholas Francis Borrelli, Timothy Michael Gross, Odessa Natalie Petzold, Wageesha Senaratne
  • Patent number: 9550695
    Abstract: A method of forming a shaped glass article includes placing a glass sheet on a mold such that a first glass area of the glass sheet corresponds to a first mold surface area of the mold and a second glass area of the glass sheet corresponds to a second mold surface area of the mold. The first glass area and the second glass area are heated such that the viscosity of the second glass area is 8 poise or more lower than the viscosity of the first glass area. A force is applied to the glass sheet to conform the glass sheet to the mold surface. During the heating of the second glass area, the first mold surface area is locally cooled to induce a thermal gradient on the mold.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: January 24, 2017
    Assignee: Corning Incorporated
    Inventors: Jacob Immerman, Thomas A. Keebler, John Robert Saltzer, Jr., Ljerka Ukrainczyk
  • Patent number: 9512035
    Abstract: Described herein are various antimicrobial glass articles that have improved strength and resistance to discoloration. The improved antimicrobial glass articles described herein generally include a glass substrate with a compressive stress layer and an antimicrobial silver-containing region that each extend inward from a surface of the glass substrate to a specific depth. In some embodiments, the compressive stress layer has a compressive stress at the surface of about 500 MPa or greater and the compressive stress decreases monotonically from the surface into the depth of the glass substrate. Methods of making and using the glass articles are also described and include forming a compressive stress layer and forming an antimicrobial silver-containing region by preferentially exchanging a plurality of silver cations in a silver-containing medium for a specific plurality of first cations ions in the glass substrate.
    Type: Grant
    Filed: May 28, 2014
    Date of Patent: December 6, 2016
    Assignee: Corning Incorporated
    Inventors: Jaymin Amin, Timothy Michael Gross, Odessa Natalie Petzold, Rostislav Vatchev Roussev
  • Patent number: 9359243
    Abstract: Embodiments of glass ceramic articles and precursor glasses are disclosed. In one or more embodiments, the glass-ceramic articles are transparent and include a nepheline phase and a phosphate phase. The glass-ceramic articles are colorless and exhibit a transmittance of about 70% or greater across the visible spectrum. The glass-ceramic articles may optionally include a lithium aluminosilicate phase. The crystals of the glass-ceramic articles may have a major cross-section of about 100 nm or less.
    Type: Grant
    Filed: May 8, 2015
    Date of Patent: June 7, 2016
    Assignee: CORNING INCORPORATED
    Inventors: George Halsey Beall, Charlene Marie Smith, Steven Alvin Tietjie
  • Patent number: 9359251
    Abstract: Glasses with compressive stress profiles that allow higher surface compression and deeper depth of layer (DOL) than is allowable in glasses with stress profiles that follow the complementary error function at a given level of stored tension. In some instances, a buried layer or local maximum of increased compression, which can alter the direction of cracking systems, is present within the depth of layer. Theses compressive stress profiles are achieved by a three step process that includes a first ion exchange step to create compressive stress and depth of layer that follows the complimentary error function, a heat treatment at a temperature below the strain point of the glass to partially relax the stresses in the glass and diffuse larger alkali ions to a greater depth, and a re-ion-exchange at short times to re-establish high compressive stress at the surface.
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: June 7, 2016
    Assignee: Corning Incorporated
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Timothy Michael Gross, Stephan Lvovich Logunov
  • Patent number: 9346703
    Abstract: Glasses comprising SiO2, Al2O3, and P2O5 that are capable of chemical strengthened by ion exchange and having high damage resistance. These phosphate-containing glasses have a structure in which silica (SiO2) is replaced by aluminum phosphate (AlPO4) and/or boron phosphate (BPO4).
    Type: Grant
    Filed: November 28, 2011
    Date of Patent: May 24, 2016
    Assignee: CORNING INCORPORATED
    Inventors: Dana Craig Bookbinder, Timothy Michael Gross, Marcel Potuzak
  • Patent number: 9292634
    Abstract: Methods for compensating for the warp exhibited by three-dimensional glass covers as a result of ion exchange strengthening are provided. The methods use a computer-implemented model to predict/estimate changes to a target three-dimensional shape for the 3D glass cover as a result of ion exchange strengthening. The model includes the effects of ion exchange through the edge of the 3D glass cover. In an embodiment, the inverse of the predicted/estimated changes is used to produce a compensated (corrected) mold which produces as-molded parts which when subjected to ion exchange strengthening have shapes closer to the target shape than they would have had if the mold had not been compensated (corrected).
    Type: Grant
    Filed: May 5, 2014
    Date of Patent: March 22, 2016
    Assignee: CORNING INCORPORATED
    Inventors: Izhar Zahoor Ahmed, Keith Raymond Gaylo, Jacob Immerman, John Richard Ridge, John Robert Saltzer, Jr., Ljerka Ukrainczyk
  • Patent number: 9290413
    Abstract: An aluminosilicate glass article having a high compressive stress layer. The glass article comprises at least about 50 mol % SiO2 and at least about 11 mol % Na2O, and has a layer under a compressive stress of at least about 900 MPa and the depth of layer that extends at least about 30 ?m from the surface of the glass article into the glass. A method of making such a glass article is also provided.
    Type: Grant
    Filed: June 26, 2012
    Date of Patent: March 22, 2016
    Assignee: CORNING INCORPORATED
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Patent number: 9221714
    Abstract: An apparatus for chemically toughening glass which can toughen the surface of the glass by inducing compressive stress on the glass surface through ion exchange and a method of chemically toughening glass using the same. The apparatus includes a chemical toughening bath which chemically toughens the glass; a transportation part which transports the glass from upstream of the chemical toughening bath through the chemical toughening bath to downstream of the chemical toughening bath; and a microwave generator disposed above the chemical toughening bath, the microwave generator radiating microwaves to the glass.
    Type: Grant
    Filed: October 31, 2013
    Date of Patent: December 29, 2015
    Assignee: SAMSUNG CORNING PRECISION MATERIALS CO., LTD.
    Inventors: Hoikwan Lee, Jaeho Lee, Kyungmin Yoon, Seo-Yeong Cho
  • Patent number: 9214180
    Abstract: The present invention relates to a method for manufacturing a glass substrate for an information recording medium having a high level of cleanness and superior smoothness. The manufacturing method includes a step for washing a disk-shaped glass plate with an acid washing liquid, a step for removing at least part of a surface layer, which is formed on the surface of the glass plate, by performing grinding with diamond abrasion grains, and a step for washing the surface with a neutral or alkaline washing liquid.
    Type: Grant
    Filed: April 29, 2014
    Date of Patent: December 15, 2015
    Assignee: HOYA CORPORATION
    Inventors: Yasuhiro Saito, Toshiaki Hashimoto, Yuriko Kudoh
  • Patent number: 9206079
    Abstract: The present invention aims to provide a chemically strengthened glass plate which has a good yield in a cutting process of the chemically strengthened glass plate and has sufficient strength. The chemically strengthened glass plate has a surface compressive stress of not less than 600 MPa at a surface of the chemically strengthened glass plate, and a compressive stress layer containing two types of stress patterns A and B. The stress pattern A is a stress pattern of a surface portion of the glass plate, and the stress pattern B is a stress pattern of an inside of the glass plate. The stress patterns satisfy the formula SA>SB where SA represents a slope of the stress pattern A and SB represents a slope of the stress pattern B when the stress patterns A and B are each approximated by a linear function.
    Type: Grant
    Filed: September 27, 2012
    Date of Patent: December 8, 2015
    Assignee: CENTRAL GLASS COMPANY, LIMITED
    Inventors: Yu Matsuda, Tatsuya Tsuzuki, Naoki Mitamura, Tadashi Muramoto
  • Patent number: 9183866
    Abstract: A magnetic disk substrate having a flat main surface, an end face, and a chamfered face formed between the main surface and the end face. The substrate has an offset portion, present on the main surface within a range of 92.0 to 97.0% in a radial direction from a center of the substrate. A distance from the center of the substrate to the end face of the substrate in a radial direction is 100%, the offset portion being raised or lowered with respect to a virtual straight line connecting two points on the main surface, set at positions of 92.0% and 97.0%. A maximum distance from the virtual straight line to the offset portion in a direction perpendicular to the virtual straight line is a “maximum offset value.
    Type: Grant
    Filed: November 24, 2014
    Date of Patent: November 10, 2015
    Assignees: HOYA CORPORATION, HOYA GLASS DISK (Thailand) LTD.
    Inventors: Toshio Takizawa, Kraisorn Phandon, Kenichi Nishimori
  • Patent number: 9156726
    Abstract: Provided is a tempered glass substrate formed by a float method, comprising a bottom surface and a top surface, wherein a compression stress value of the bottom surface is larger than a compression stress value of the top surface.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: October 13, 2015
    Assignee: NIPPON ELECTRIC GLASS CO., LTD.
    Inventors: Hiroki Katayama, Masashi Tabe, Takuji Oka
  • Patent number: 9156732
    Abstract: A method for strengthening a housing comprises the following steps: providing a housing being made of colored glaze and having an initial temperature of about 480° C. to about 550° C.; and spraying the surface of the housing using a spray solution containing potassium nitrate, potassium silicate, diatomite, and water to create an exterior layer on the surface. The exterior layer contains K+ ions, and the concentration of the K+ ions gradually decreases from a maximum value in the area of the outside surface of the exterior layer to zero in the area of the inside of the housing.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: October 13, 2015
    Assignees: SHENZHEN FUTAIHONG PRECISION INDUSTRY CO., LTD., FIH (Hong Kong) Limited
    Inventors: Ren-Bo Wang, Xin-Wu Guan, Po-Feng Ho
  • Patent number: 9145333
    Abstract: Methods are disclosed for producing chemically-strengthened, borosilicate, glass articles. The articles are produced from batch components which are selected, at least in part, based on measured and/or estimated values for the coordination state of B2O3 in the glass. In this way, such chemical-strengthening properties as mutual diffusivity, maximum surface compressive stress, and/or indentation threshold can be improved.
    Type: Grant
    Filed: May 30, 2013
    Date of Patent: September 29, 2015
    Assignee: CORNING INCORPORATED
    Inventors: Matthew John Dejneka, John Christopher Mauro, Marcel Potuzak, Morten Mattrup Smedskjaer, Randall Eugene Youngman
  • Patent number: 9140543
    Abstract: Systems and methods for measuring the stress profile of ion-exchanged glass are disclosed, based on the TM and TE guided mode spectra of the optical waveguide formed in the ion-exchanged glass. The method includes digitally defining from the TM and TE guided mode spectra positions of intensity extrema, and calculating respective TM and TE effective refractive indices from these positions. The method also includes calculating TM and TE refractive index profiles nTM(z) and nTE(z) using either an inverse WKB calculation or a fitting process that employs assumed functions for nTM(z) and nTE(z). The method also includes calculating the stress profile S(z)=[nTM(z)?nTE(z)]/SOC, where SOC is a stress optic coefficient for the glass substrate. Systems for performing the method are also disclosed.
    Type: Grant
    Filed: May 3, 2012
    Date of Patent: September 22, 2015
    Assignee: CORNING INCORPORATED
    Inventors: Douglas Clippinger Allan, Karl William Koch, III, Rostislav Vatchev Roussev, Robert Anthony Schaut, Vitor Marino Schneider
  • Patent number: 9135682
    Abstract: Techniques described herein are generally related to high resolution image recovery of objects from digital holograms. The various described techniques may be applied to methods, systems, devices or combinations thereof. Some described methods for recovering an image may include receiving reference beam data that corresponds to a reference interference pattern and receiving hologram data corresponding to an object. The method may also include applying a cost function to the hologram data and the reference beam data to determine the object image data associated with the object. The cost function may include a smoothness constraint applied to the object image data. The cost function can be iteratively reduced to obtain object image data corresponding to the object and the obtained object image data can be processed to recover the image of the object from single shot holograms with image resolution greater than conventional holographic imaging system.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: September 15, 2015
    Assignee: Indian Institute of Technology Delhi
    Inventors: Kedar Bhalchandra Khare, Joby Joseph, Samsheerali Pothiyil Thottiparambil
  • Patent number: 9076480
    Abstract: Disclosed is a method of producing a glass substrate for an information recording medium including a precision polishing step of using a polishing material containing colloidal silica and performing precision polishing, under acidic conditions, on a glass material in which the amount of iron adhered on the surface is 0.5 ng/cm2 or less and the surface roughness Ra is 1 nm or less. Additionally disclosed is a glass substrate for an information recording medium produced by the foregoing method of producing a glass substrate for an information recording medium.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: July 7, 2015
    Assignee: Hoya Corporation
    Inventor: Hazuki Nakae
  • Publication number: 20150147576
    Abstract: A strengthened antimicrobial glass including greater from about 50.0 mol. % to about 65.0 mol. % SiO2, about 14.0 mol. % to about 22.0 mol. % Al2O3, about 14.0 mol. % to about 22.0 mol. % R2O, wherein R is an alkali metal, and about 4.0 mol. % to 10.0 mol. % P2O5. The glass may have a compressive stress layer having a thickness of greater than or equal to about 20 ?m to less than or equal to about 60 ?m and having a compressive stress of greater than or equal to about 700 MPa. The glass may have an antimicrobial activity greater than or equal to about 1.0 log kill at about 23° C. and about 40.0% relative humidity. A method for making the glass may include obtaining a glass article, strengthening the glass article by contact with a first ion-exchange liquid, and contacting the glass article with second ion-exchange liquid comprising an antimicrobial agent.
    Type: Application
    Filed: November 20, 2014
    Publication date: May 28, 2015
    Inventors: Dana Craig Bookbinder, Nicholas Francis Borrelli, Matthew John Dejneka, Timothy Michael Gross
  • Publication number: 20150147574
    Abstract: A method for generating various stress profiles for chemically strengthened glass. An alkali aluminosilicate glass is brought into contact with an ion exchange media such as, for example, a molten salt bath containing an alkali metal cation that is larger than an alkali metal cation in the glass. The ion exchange is carried out at temperatures greater than about 420° C. and at least about 30° C. below the anneal point of the glass.
    Type: Application
    Filed: November 13, 2014
    Publication date: May 28, 2015
    Inventors: Douglas Clippinger Allan, Xiaoju Guo, Guangli Hu, Gaozhu Peng
  • Publication number: 20150140325
    Abstract: Embodiments of glass composition including at least about 65 mol % SiO2, Al2O3 in the range from about 7 mol % to about 11 mol %, Na2O in the range from about 13 mol % to about 16 mol %; and a non-zero amount of one or more alkali earth metal oxides selected from MgO, CaO and ZnO, wherein the sum of the alkali earth metal oxides is up to about 6 mol %, are disclosed. The glass compositions can be processed using fusion forming processes and float forming processes and are ion exchangeable. Glass articles including such glass compositions and methods of forming such glass articles are also disclosed. The glass articles of one or more embodiments exhibit a Vickers indentation crack initiation load of at least 8 kgf.
    Type: Application
    Filed: November 14, 2014
    Publication date: May 21, 2015
    Inventors: Timothy Michael Gross, Xiaoju Guo, Charlene Marie Smith
  • Publication number: 20150140336
    Abstract: A white glass contains, in terms of mole percentage on the basis of the following oxides, from 50 to 80% of SiO2, from 0 to 10% of Al2O3, from 11 to 30% of MgO, from 0 to 15% of Na2O and from 0.5 to 15% of P2O5.
    Type: Application
    Filed: January 23, 2015
    Publication date: May 21, 2015
    Applicant: ASAHI GLASS COMPANY, LIMITED
    Inventors: Takahiro SAKAGAMI, Seiki OHARA, Junko MIYASAKA, Hiroyuki HIJIYA, Kazutaka ONO
  • Patent number: 9034469
    Abstract: A tempered glass substrate has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 70% of SiO2, 12 to 21% of Al2O3, 0 to 3.5% of Li2O, 10 to 20% of Na2O, 0 to 15% of K2O, and 0 to 4.5% of TiO2, wherein the tempered glass substrate has a plate thickness of 1.5 mm or less, and an internal tensile stress in the tempered glass substrate is 15 to 150 MPa.
    Type: Grant
    Filed: February 8, 2012
    Date of Patent: May 19, 2015
    Assignee: NIPPON ELECTRIC GLASS CO., LTD.
    Inventor: Takashi Murata
  • Publication number: 20150132579
    Abstract: Ion exchangeable glasses that comprise at least one of a transition metal oxide or a rare earth oxide and have compositions that simultaneously promote a surface layer having a high compressive stress and deep depth of layer or, alternatively, reduced ion exchange time.
    Type: Application
    Filed: May 28, 2013
    Publication date: May 14, 2015
    Inventors: Xiaoju Guo, John Christopher Mauro, Marcel Potuzak, Morten Mattrup Smedskjaer
  • Publication number: 20150114041
    Abstract: A method of making a strengthened glass article includes providing a flat glass article having a select contour and a glass surface covered by a protective coating layer. The protective coating layer is removed from the glass surface without touching the glass surface with any solid object. Immediately after the protective coating layer is removed from the glass surface, the flat glass article is subjected to an ion-exchange process to strengthen the flat glass article and improve the resistance of the flat glass article to subsequent damage.
    Type: Application
    Filed: May 8, 2013
    Publication date: April 30, 2015
    Applicant: Corning Incorporated
    Inventors: Thomas George Capek, Gregory Scott Glaesemann, Jeffrey Todd Kohli
  • Publication number: 20150116919
    Abstract: Apparatus, systems and methods for improving strength of a thin glass cover for an electronic device are disclosed. In one embodiment, the glass member can have improved strength by forming its edges with a predetermined geometry and/or by chemically strengthening the edges. Advantageously, the glass member can be not only thin but also adequately strong to limit susceptibility to damage. In one embodiment, the glass member can pertain to a glass cover for a housing for an electronic device. The glass cover can be provided over or integrated with a display, such as a Liquid Crystal Display (LCD) display.
    Type: Application
    Filed: December 30, 2014
    Publication date: April 30, 2015
    Inventors: Christopher Prest, Stephen Paul Zadesky
  • Publication number: 20150107303
    Abstract: Disclosed herein are methods for strengthening glass articles having strength-limiting surface flaws, together with strengthened glass articles produced by such methods, and electronic devices incorporating the strengthened glass articles. The methods generally involve contacting the glass articles with a substantially fluoride-free aqueous acidic treating medium for a time at least sufficient to increase the rupture failure points of the glass articles.
    Type: Application
    Filed: December 30, 2014
    Publication date: April 23, 2015
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Timothy Michael Gross
  • Publication number: 20150099130
    Abstract: Borosilicate glasses are disclosed having (in weight %) 66-76% SiO2, 0-8% Al2O3, 10-18% B2O3, 0-4% Li2O, 0-12% Na2O, 0-12% K2O, 1-1.5% Ag, 1.5-2.5% Cl? and 0.01-0.06% of a summed amount of CuO and NiO, wherein the glass composition is bleachable upon exposure to ultraviolet irradiation from a stable state color or shade to a lighter color or shade. Such reverse photochromic borosilicate glass compositions may be thermally darkenable. The borosilicate glasses may be strengthened via ion-exchange strengthening treatment. The borosilicate glasses may retain their reverse photochromic and thermally darkenable properties even after ion-exchange strengthening treatment.
    Type: Application
    Filed: October 7, 2014
    Publication date: April 9, 2015
    Inventors: John Christopher Mauro, Lynn Marie Thirion
  • Publication number: 20150099124
    Abstract: Glass-ceramics exhibiting a Vickers indentation crack initiation threshold of at least 15 kgf are disclosed. These glass-ceramics may be ion exchangeable or ion exchanged. The glass-ceramics include a crystalline and amorphous phases generated by subjecting a thin precursor glass article to ceramming cycle having an average cooling rate in the range from about 10° C./minute to about 25° C./minute. In one or more embodiments, the crystalline phase may comprise at least 20 wt % of the glass-ceramics. The glass-ceramics may include ?-spodumene ss as the predominant crystalline phase and may exhibit an opacity ?about 85% over the wavelength range of 400-700 nm for an about 0.8 mm thickness and colors an observer angle of 10° and a CIE illuminant F02 determined with specular reflectance included of a* between ?3 and +3, b* between ?6 and +6, and L* between 88 and 97.
    Type: Application
    Filed: October 3, 2014
    Publication date: April 9, 2015
    Inventors: Lionel Joel Mary Beunet, Marie Jacqueline Monique Comte, Allan Mark Fredholm, Qiang Fu, Anne Paris, Sophie Peschiera, Charlene Marie Smith
  • Publication number: 20150093581
    Abstract: An object is to devise a tempered glass substrate that has high mechanical strength and hardly undergoes breakage even though having a large size. A tempered glass substrate has a compressive stress layer in a surface thereof, and includes 1 piece/cm3 or less of devitrified stones containing Zr.
    Type: Application
    Filed: December 4, 2014
    Publication date: April 2, 2015
    Inventors: Takashi MURATA, Takako TOJYO, Motokazu OGATA
  • Publication number: 20150079400
    Abstract: Alkali boroaluminosilicate glasses with high resistance to crack initiation and damage due to sharp impact are provided. The glass compositions have melting and forming temperatures that allow forming the glass into sheets via float-based processes while still allowing for the glass to be efficiently ion exchanged. The glass compositions contain MgO, and when ion exchanged, have a Vickers indentation crack initiation load of at least about 10-15 kgf.
    Type: Application
    Filed: September 9, 2014
    Publication date: March 19, 2015
    Inventors: Qiang Fu, Xiaoju Guo
  • Publication number: 20150074974
    Abstract: Disclosed are alkali aluminosilicate glasses having unexpected resistance to indentation cracking. The glasses obtain this high resistance as a result of a high level of surface compression accompanied by a shallow depth of layer. The advantaged glasses show greater resistance to radial crack formation from Vickers indentation than glasses with the same compressive stress, but higher depths of layer.
    Type: Application
    Filed: November 19, 2014
    Publication date: March 19, 2015
    Inventors: Jonathan David Pesansky, Chandan Kumar Saha, Trevor E. Wilantewicz
  • Patent number: 8978414
    Abstract: Disclosed herein are methods for strengthening glass articles having strength-limiting surface flaws, together with strengthened glass articles produced by such methods, and electronic devices incorporating the strengthened glass articles. The methods generally involve contacting the glass articles with a substantially fluoride-free aqueous acidic treating medium for a time at least sufficient to increase the rupture failure points of the glass articles.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: March 17, 2015
    Assignee: Corning Incorporated
    Inventors: Dana Craig Bookbinder, Richard Michael Fiacco, Timothy Michael Gross
  • Patent number: 8973401
    Abstract: The disclosure is directed to a chemically strengthened glass having antimicrobial properties and to a method of making such glass. In particular, the disclosure is directed to a chemically strengthened glass with antimicrobial properties and with a low surface energy coating on the glass that does not interfere with the antimicrobial properties of the glass. The antimicrobial has an Ag ion concentration on the surface in the range of greater than zero to 0.047 ?g/cm2. The glass has particular applications as antimicrobial shelving, table tops and other applications in hospitals, laboratories and other institutions handling biological substances, where color in the glass is not a consideration.
    Type: Grant
    Filed: August 3, 2011
    Date of Patent: March 10, 2015
    Assignee: Corning Incorporated
    Inventors: Nicholas Francis Borrelli, David Lathrop Morse, Wageesha Senaratne, Florence Verrier, Ying Wei
  • Publication number: 20150064473
    Abstract: Ion exchangeable glasses containing SiO2, Al2O3, Na2O, MgO, B2O3, and P2O5 are provided. The compressive stresses of these ion exchanged glasses are greater than 900 megapascals (MPa) at a depth of 45 or 50 microns (?m) with some glasses exhibiting a compressive stress of at least 1 gigaPascals (GPa). The ion exchange rates of these glasses are much faster than those of other alkali aluminosilicate glasses and the ion exchanged glass is resistant damage to impact damage. A method of ion exchanging the glass is also provided.
    Type: Application
    Filed: August 25, 2014
    Publication date: March 5, 2015
    Inventors: Matthew John Dejneka, Sinue Gomez, Timothy Micheal Gross, Xiaoju Guo
  • Publication number: 20150064474
    Abstract: Glass-ceramics and precursor glasses that are crystallizable to glass-ceramics are disclosed. The glass-ceramics of one or more embodiments include rutile, anatase, armalcolite or a combination thereof as the predominant crystalline phase. Such glasses and glass-ceramics may include compositions of, in mole %: SiO2 in the range from about 45 to about 75; Al2O3 in the range from about 4 to about 25; P2O5 in the range from about 0 to about 10; MgO in the range from about 0 to about 8; R2O in the range from about 0 to about 33; ZnO in the range from about 0 to about 8; ZrO2 in the range from about 0 to about 4; B2O3 in the range from about 0 to about 12, and one or more nucleating agents in the range from about 0.5 to about 12. In some glass-ceramic articles, the total crystalline phase includes up to 20% by weight of the glass-ceramic article.
    Type: Application
    Filed: August 27, 2014
    Publication date: March 5, 2015
    Inventors: Matthew John Dejneka, Qiang Fu, Timothy Michael Gross, Xiaoju Guo, Sumalee Likitvanichkul, John Christopher Mauro
  • Publication number: 20150064472
    Abstract: Ion exchangeable glasses having coefficients of thermal expansion (CTE) at least about 90×10?7 ° C.?1. The glasses undergo rapid ion exchange, for example, in a molten KNO3 salt bath to a depth of layer of greater than 30 microns in less than 2 hours at temperatures of 370° C. to 390° C. When ion-exchanged to a depth of layer between 30 to 50 microns, the glasses exhibit a Vickers median/radial crack initiation threshold exceeding 30 kilograms force (kgf). The glasses are fusion formable and, in some embodiments, compatible with zircon.
    Type: Application
    Filed: August 22, 2014
    Publication date: March 5, 2015
    Inventors: Timothy Michael Gross, Xiaoju Guo
  • Publication number: 20150052949
    Abstract: Impact-damage-resistant glass sheet comprising at least one chemically etched surface in combination with a tempering surface compression layer, the glass sheet exhibiting a high standardized ball drop failure height and a high flexural modulus of rupture strength, useful to provide damage-resistant glass cover sheets for consumer electronic video display devices, is provided by subjecting thin glass sheet to a combination of a surface tempering treatment and a surface etching treatment that improves strength while maintaining the optical glass sheet properties required for video display applications.
    Type: Application
    Filed: October 31, 2014
    Publication date: February 26, 2015
    Applicant: CORNING INCORPORATED
    Inventors: John Frederick Bayne, James Joseph Price, Daniel A. Sternquist, Jaymin Amin
  • Patent number: 8959953
    Abstract: There is a method for making. The method includes providing an untreated alkali aluminosilicate glass having an annealing point temperature that is at least about 580° C. The method also includes providing a mixed potassium and sodium salt bath having greater than about 50 mole % potassium salt and less than about 50 mole % sodium salt. The method also includes immersing the untreated glass in the mixed salt bath and maintaining the mixed salt bath with the immersed untreated glass within a temperature range from about 450° C. to less than the annealing point temperature of the untreated glass for a period greater than about 2 hours to produce a strengthened glass. The produced strengthened glass has a surface compression of at least about 100,000 psi and a compression case depth of at least about 600 microns.
    Type: Grant
    Filed: September 26, 2012
    Date of Patent: February 24, 2015
    Assignee: Saxon Glass Technologies, Inc.
    Inventor: Arun Kumar Varshneya
  • Publication number: 20150047393
    Abstract: According to one embodiment, a method of manufacturing a glass article having a three-dimensional shape includes heating a glass article blank to a temperature above a setting temperature and coupling the glass article blank to an open-faced mold. The open-faced mold includes a molding region that has a three-dimensional shape that generally corresponds to the shape of the glass article and has an anisothermal temperature profile within the molding region. The method further includes maintaining an anisothermal temperature profile along the glass article blank and cooling the glass article blank while the glass article blank is coupled to the molding region of the open-faced mold to set the shape of the glass article.
    Type: Application
    Filed: July 30, 2014
    Publication date: February 19, 2015
    Inventors: Weiwei Luo, Rohit Rai, Ljerka Ukrainczyk, Zheming Zheng, Sam Samer Zoubi
  • Publication number: 20150044445
    Abstract: A method for forming ion-exchanged regions in a glass article by contacting an ion source with at least one surface of the glass article, forming a first ion-exchanged region in the glass article by heating a first portion of the glass article with a laser, and forming a second ion-exchanged region in the glass article. Characteristics of the first ion-exchanged region may be different from characteristics of the second ion-exchanged region. A depth of the ion-exchanged region may be greater than 1 ?m. A glass article including a first ion-exchanged region, and a second ion-exchanged region having different characteristics from the first ion-exchanged region. The thickness of the glass article is less than or equal to about 0.5 mm.
    Type: Application
    Filed: August 1, 2014
    Publication date: February 12, 2015
    Inventors: Sean Matthew Garner, Ming-Jun Li, Xinghua Li
  • Publication number: 20150041435
    Abstract: Methods provide for post processing at least one flexible glass sheet with the step of providing the glass sheet with an initial shape. The method then further includes the step of flexing the glass sheet into a secondary shape from the initial shape. The method then further includes the step of post processing the glass sheet while biasing the glass sheet into the secondary shape. The method then still further includes the step of releasing the glass sheet to at least partially return to the initial shape.
    Type: Application
    Filed: July 30, 2014
    Publication date: February 12, 2015
    Inventors: Jianqiang Gu, Jean-Marc Martin Gerard Jouanno, William Brashear Mattingly, III, Wenchao Wang, Yoshiki Yamashita, Rui Zhang
  • Publication number: 20150044473
    Abstract: A method of manufacturing a tempered glass substrate includes: melting glass raw materials blended so as to have a glass composition including, in terms of mass %, 40 to 71% of SiO2, 3 to 23% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O; forming the resultant molten glass into a sheet shape; and performing ion exchange treatment in a KNO3 molten salt, the KNO3 molten salt having a controlled concentration of Na ions, to form a compressive stress layer in a surface of the glass.
    Type: Application
    Filed: July 8, 2013
    Publication date: February 12, 2015
    Inventors: Takashi Murata, Takako Tojyo
  • Publication number: 20150044474
    Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.
    Type: Application
    Filed: October 23, 2014
    Publication date: February 12, 2015
    Inventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
  • Patent number: 8950215
    Abstract: Apparatus, systems and methods for reducing surface roughness on surface of a glass member using a non-contact polishing process are disclosed. According to one aspect, a method for processing a glass member suitable for use in a handheld electronic device includes obtaining the glass member and chemically strengthening the glass member. The glass member has at least one surface, and chemically strengthening the glass member increases roughness associated with the at least one surface. The method also includes applying a first non-contact polishing process to the glass member after chemically strengthening the glass member. Applying the first non-contact polishing process reduces the roughness associated with the at least one surface.
    Type: Grant
    Filed: May 14, 2011
    Date of Patent: February 10, 2015
    Assignee: Apple Inc.
    Inventors: Benjamin M. Rappoport, Christopher Prest
  • Publication number: 20150030834
    Abstract: Embodiments are directed to strengthened glass articles comprising a thickness t?1 mm (1000 ?m), an inner region under a central tension CT (in MPa), and at least one compressive stress layer adjacent the inner region and extending within the strengthened glass article from a surface of the strengthened glass article to a depth of layer DOL (in ?m), wherein the strengthened glass article is under a compressive stress at the surface CSs (in MPa), wherein the strengthened glass article is an alkali aluminosilicate glass article comprising 0-5 mol % Li2O, and at least 3 mol % Al2O3, and wherein the DOL?70 ?m, and a CSs/DOL ratio?2.5 MPa/?m.
    Type: Application
    Filed: July 25, 2014
    Publication date: January 29, 2015
    Inventors: Laurence Ralph Morey, Jonathan David Pesansky, Kevin Barry Reiman, Benjamin Allen Stevens, Brina Paul Strines
  • Publication number: 20150030838
    Abstract: A glass sheet, the composition of which is of the lithium aluminosilicate type and includes at most 1% by weight of sodium oxide, the thickness of which is at most 2 mm, having a surface region under compression obtained by ion exchange and a central region under tension, such that the flexural stress at break in a ring-on-tripod test is at least 50 MPa, after Vickers indentation under a load of 120 N.
    Type: Application
    Filed: March 13, 2013
    Publication date: January 29, 2015
    Inventors: Julien Sellier, Rene Gy, Stephanie Pelletier
  • Publication number: 20150013389
    Abstract: A toughened glass fabrication method in which the productivity of a large toughened glass and the strength variation of the toughened glass can be improved and a toughened glass fabricated thereby. The toughened glass fabrication method includes the steps of mounting jigs on an upper surface and an undersurface of a raw glass such that an injection space through which a gel-type salt mixture is to be injected is defined between each of the jigs and the raw glass, injecting the gel-type salt mixture into the injection spaces, and heat-treating the raw glass on which the jigs are mounted.
    Type: Application
    Filed: July 8, 2013
    Publication date: January 15, 2015
    Inventors: Sang Yoon Oh, Jong Taek Kim, JiYoung Kim, HwaYeon Lee, Jin Sung Lim
  • Publication number: 20150017412
    Abstract: A tempered glass according to one embodiment of the present invention is a tempered glass having a compression stress layer in a surface thereof, the tempered glass including as a glass composition, in terms of mass %, 45 to 75% of SiO2, 10 to 25% of Al2O3, 0 to 10% of B2O2, 0 to 8% of MgO, 0 to 20% of SrO+BaO, and 0 to 14% of Na2O. Herein, the term “SrO+BaO” refers to the total amount of SrO and BaO.
    Type: Application
    Filed: February 19, 2013
    Publication date: January 15, 2015
    Inventors: Takashi Murata, Takako Tojyo, Masato Muguruma, Kosuke Kawamoto