To Temper Or Strengthen The Glass Patents (Class 65/30.14)
  • Publication number: 20130128433
    Abstract: A 3-D glass enclosure comprises a generally planar glass base member, an encircling glass side wall member connected to the base member, and a generally planar glass cover member connected to the side wall member to form a unitary glass enclosure, the base, sidewall and cover members being made by reforming softened glass sheet preforms and subjecting the reformed members to ion-exchange strengthening, thus providing strong transparent enclosures for electronic devices such as tablet computers, cellphones, media players and televisions.
    Type: Application
    Filed: November 15, 2012
    Publication date: May 23, 2013
    Inventors: Thierry Luc Alain Dannoux, David Lathrop Morse
  • Publication number: 20130122254
    Abstract: A method for manufacturing a patterned layer of compressive stress on a glass substrate includes forming a mask having predetermined pattern on a surface of the glass substrate. The pattern includes a plurality of hollow area and a shelter area The glass substrate is tempered by a chemical tempering process to form a layer retaining compressive stress on the uncovered area of the glass substrate surface so that the patterned layer of compressive stress is formed on the surface of the glass substrate. The patterned layer is formed to at least one surface of the glass substrate. The patterned layer has a plurality of area retaining different surface compressive stress. The patterned layer includes high stress areas separated by a low stress area. The surface compressive stress difference between the areas is larger than 100 MPa, or the depth difference between the areas is larger than 5 ?m.
    Type: Application
    Filed: November 11, 2011
    Publication date: May 16, 2013
    Inventor: NAI-YUE LIANG
  • Publication number: 20130122284
    Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.
    Type: Application
    Filed: November 15, 2012
    Publication date: May 16, 2013
    Inventor: Timothy Michael Gross
  • Publication number: 20130122313
    Abstract: Alkali aluminosilicate glasses that are resistant to damage due to sharp impact and capable of fast ion exchange are provided. The glasses comprise at least 4 mol % P2O5 and, when ion exchanged, have a Vickers indentation crack initiation load of at least about 7 kgf.
    Type: Application
    Filed: November 15, 2012
    Publication date: May 16, 2013
    Inventor: Timothy Michael Gross
  • Publication number: 20130104602
    Abstract: A method for manufacturing obscured glass includes providing a glass substrate including a pre-obscured surface; applying a first harden process to the glass substrate to form a strength layer inward the pre-substrate surface; and applying a blasting process to the pre-obscured surface of the glass substrate to form an obscured layer inward the pre-obscured surface, wherein a thickness of the obscured layer is less than that of the strength layer.
    Type: Application
    Filed: April 13, 2012
    Publication date: May 2, 2013
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., FU TAI HUA INDUSTRY (SHENZHEN) CO., LTD.
    Inventors: SHYAN-JUH LIU, CHU-SHENG CHEN, XING-RONG XIAO
  • Publication number: 20130101798
    Abstract: A method for manufacturing a strengthened glass substrate includes: a chemical strengthening step of chemically strengthening a plate glass material by ion-exchange; and a shaping step of cutting the chemically strengthened plate glass material by etching. In the chemical strengthening step, the ion-exchange is performed to satisfy the condition of 7?Tave?50 [MPa], when the thickness of the plate glass material is denoted by t [?m], the thickness of the compressive stress layer by d [?m], the maximum compressive stress value of the compressive stress layer by F [MPa], the compressive stress integrated value of the compressive stress layer by X [MPa·?m], the thickness of the tensile stress layer by t2 [?m], the average tensile stress value of the tensile stress layer by Tave [MPa], and the relationships represented by equations X=F×d, t2=t?2d and Tave=X/t2 are satisfied.
    Type: Application
    Filed: August 22, 2012
    Publication date: April 25, 2013
    Applicant: HOYA CORPORATION
    Inventor: Kazuaki HASHIMOTO
  • Publication number: 20130086946
    Abstract: The invention is directed to a high strength, chemically toughened protective glass article, the glass article having a high damage tolerance threshold of at least 1500 g as measured by the lack of radial cracks when the load is applied to the glass using a Vickers indenter; preferably greater than 2000 g is measured by the lack of initiation of radial cracks when the load is applied to the glass using a Vickers indenter
    Type: Application
    Filed: December 4, 2012
    Publication date: April 11, 2013
    Inventors: Gregory Scott Glaesemann, James Joseph Price, Robert Sabia, Nagaraja Shashidhar
  • Publication number: 20130086945
    Abstract: A manufacturing method of a sheet glass material for magnetic disk, the method includes, dropping process for dropping a lump of molten glass; pressing process for sandwiching simultaneously the lump from both sides of the dropping path of the lump with surfaces of a pair of dies facing together, and performing press forming to the lump to obtain a sheet glass material, wherein at least one of the pair of dies has a concave shape with respect to the dropping path of the lump.
    Type: Application
    Filed: March 30, 2012
    Publication date: April 11, 2013
    Applicant: HOYA CORPORATION
    Inventors: Hideki ISONO, Hidekazu Tanino
  • Patent number: 8413464
    Abstract: The present invention provides a method for producing a glass substrate for a magnetic disk in which the occurrence of micro-waviness on the glass substrate is prevented in a cooling step after a chemically strengthening step so that the glass substrate has a significantly smooth principal surface, and provides a method for producing a magnetic disk in which head crash, thermal asperity failures, and the like are prevented, the flying height of a magnetic head can be decreased, and high-density recording is enabled.
    Type: Grant
    Filed: September 12, 2007
    Date of Patent: April 9, 2013
    Assignee: Hoya Corporation
    Inventors: Katsuyuki Iwata, Hideki Isono, Kenichiro Terada
  • Publication number: 20130071601
    Abstract: A cover glass element can extend to the edges of an electronic device while maintaining the optical flatness and thickness needed for the cover glass. A first glass sheet with the desired thickness and flatness can be thermally bonded to a second glass sheet machined to include an opening to be received by the edges of the electronic device. The resulting three-dimensional cover element forms a uni-body frame that is significantly stiffer than a single sheet of glass, and the larger surface area of the edge provides for enhances pressure distribution, particularly after chemical strengthening, thus enhancing the durability of the electronic device. Further, the thermal bonding process uses lower temperatures than processes such as slumping or pressing, which could potentially affect the flatness and optical clarity of the original sheet glass.
    Type: Application
    Filed: March 7, 2012
    Publication date: March 21, 2013
    Applicant: Amazon Technologies, Inc.
    Inventors: David N. Bibl, Leo B. Baldwin
  • Publication number: 20130061636
    Abstract: An ion-exchanged glass article manufacturing method includes an ion-exchange step of bringing a glass article with a composition containing Li into contact with a molten salt dissolved solution containing an alkali metal element having an ionic radius larger than an ionic radius of the Li contained in the glass article, thereby ion-exchanging the Li in the glass article with the alkali metal element in the molten salt dissolved solution. At least one kind of additive selected from the group consisting of NaF, KF, K3AlF6, Na2CO3, NaHCO3, K2CO3, KHCO3, Na2SO4, K2SO4, KAl(SO4)2, Na3PO4, and K3PO4 is added to the molten salt dissolved solution so that the ion-exchange step is carried out while the additive is in a solid state.
    Type: Application
    Filed: September 10, 2012
    Publication date: March 14, 2013
    Applicant: HOYA CORPORATION
    Inventors: Mitsugu IMAI, Kazuaki HASHIMOTO, Osamu SUGIHARA
  • Patent number: 8393175
    Abstract: Methods for extracting strengthened glass substrates from glass sheets are described herein. In one embodiment, the method for extracting strengthened glass substrates from glass sheets comprises forming a plurality of channel segments in the glass sheet. The plurality of channel segments may extend through the thickness of the glass sheet and are separated by remnant glass webs connecting the glass substrate to the glass sheet. The plurality of channel segments extend around a perimeter of the glass substrate. Thereafter, the glass sheet is strengthened by ion-exchange. The glass substrate is then separated from the glass sheet by severing the glass substrate from the remnant glass webs.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: March 12, 2013
    Assignee: Corning Incorporated
    Inventors: Jeffrey Todd Kohli, Robert Sabia
  • Publication number: 20130045375
    Abstract: An article comprising an ion-exchanged glass material that prevents sharp contact flaws from entering a central region of the material that is under central tension and thus causing failure of the material. The glass material may be a glass or glass ceramic having a surface layer under compression. In some embodiments, the depth of the compressive layer is greater than about 75 ?m. The greater depth of layer prevents flaws from penetrating the compressive layer to the region under tension.
    Type: Application
    Filed: August 14, 2012
    Publication date: February 21, 2013
    Inventor: Timothy Michael Gross
  • Publication number: 20130037308
    Abstract: A method of fabricating a reinforced glass cell including the following steps is provided. First, a mother glass having a plurality of glass cell predetermined regions is provided. A portion of the mother glass disposed on the outer edge of each glass cell predetermined region is removed, so as to form at least one through trench and at least one linking bridge. Herein, the through trench exposes the periphery section of each glass cell predetermined region, and the glass cell predetermined regions are formed as an entire patterned mother glass by the linking bridges. A reinforcing process is performed to the entire patterned mother glass, so that the exposed periphery sections of the glass cell predetermined regions are formed into reinforced sections. The linking bridges are removed so as to separate the glass cell predetermined regions having the reinforced sections to form a plurality of reinforced glass cells.
    Type: Application
    Filed: August 10, 2012
    Publication date: February 14, 2013
    Applicants: WINTEK CORPORATION, DONGGUAN MASSTOP LIQUID CRYSTAL DISPLAY CO., LTD.
    Inventors: Po-Hsien Wang, Hsuan-Yang Chen, Chi-Yu Chan, Jeng-Jye Hung
  • Publication number: 20130017380
    Abstract: Provided is a tempered glass having a compression stress layer in a surface thereof, comprising, as a glass composition in terms of mol %, 50 to 75% of SiO2, 3 to 13% of Al2O3, 0 to 1.5% of B2O3, 0 to 4% of Li2O, 7 to 20% of Na2O, 0 to 10% of K2O, 0.5 to 13% of MgO, 0 to 6% of CaO, and 0 to 4.5% of SrO, and being substantially free of As2O3, Sb2O3, PbO, and F.
    Type: Application
    Filed: August 8, 2012
    Publication date: January 17, 2013
    Inventors: Takashi MURATA, Takako TOJYO, Kosuke KAWAMOTO, Yuusuke TOMITA
  • Patent number: 8347651
    Abstract: A method is provided for separating or dividing strengthened glass articles, particularly strengthened glass sheets, into at least two pieces, one of which has a predetermined shape and/or dimension. A flaw is initiated in the glass at a depth that is greater than the depth of the strengthened surface layer of the glass, and a vent extending from the flaw is created at a vent depth that is greater than the depth of and outside the strengthened surface layer to at least partially separate the glass. In one embodiment, the vent is generated by treating the glass with a laser to heat the glass to a temperature in a range from about 50° C. below the strain point of the glass up to a temperature between the strain point and the anneal point of the glass. A glass article having at least one strengthened surface and at least one edge having an average edge strength of at least 200 MPa is also described.
    Type: Grant
    Filed: February 19, 2009
    Date of Patent: January 8, 2013
    Assignee: Corning Incorporated
    Inventors: Anatoli Anatolyevich Abramov, Sinue Gomez, Sergio Tsuda
  • Publication number: 20130004758
    Abstract: An aluminosilicate glass article having a high compressive stress layer. The glass article comprises at least about 50 mol % SiO2 and at least about 11 mol % Na2O, and has a layer under a compressive stress of at least about 900 MPa and the depth of layer that extends at least about 30 ?m from the surface of the glass article into the glass. A method of making such a glass article is also provided.
    Type: Application
    Filed: June 26, 2012
    Publication date: January 3, 2013
    Inventors: Matthew John Dejneka, Adam James Ellison, John Christopher Mauro
  • Publication number: 20120297829
    Abstract: To provide a method for producing chemically tempered glass, whereby frequency of replacement of the molten salt can be reduced. A method for producing chemically tempered glass, which comprises repeating ion exchange treatment of immersing glass in a molten salt, wherein the glass comprises, as represented by mole percentage, from 61 to 77% of SiO2, from 1 to 18% of Al2O3, from 3 to 15% of MgO, from 0 to 5% of CaO, from 0 to 4% of ZrO2, from 8 to 18% of Na2O and from 0 to 6% of K2O; SiO2+Al2O3 is from 65 to 85%; MgO+CaO is from 3 to 15%; and R calculated by the following formula by using contents of the respective components, is at least 0.66: R=0.029×SiO2+0.021×Al2O3+0.016×MgO?0.004×CaO+0.016×ZrO2+0.029×Na2O+0×K2O?2.
    Type: Application
    Filed: April 20, 2012
    Publication date: November 29, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Jun Endo, Shusaku Akiba, Kazutaka Ono, Shigeki Sawamura
  • Patent number: 8312739
    Abstract: A method of chemically strengthening a glass. The method includes ion exchange of the glass in a first bath, followed by immersion in the second bath. The first bath is diluted with an effluent ion. The second bath has a smaller concentration of the effluent ion than the first bath. The method provides a compressive stress at the surface of the glass that is sufficient to arrest flaws introduced by contact forces at the surface of the glass while having sufficiently deep compressive depth-of-layer for high reliability.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: November 20, 2012
    Assignee: Corning Incorporated
    Inventors: Christopher Morton Lee, Lawrence George Mann, Jose Mario Quintal, Yongsheng Yan
  • Publication number: 20120282449
    Abstract: A glass article exhibiting improved resistance to fictive surface damage and a method for making it, the method comprising removing a layer of glass from at least a portion of a surface of the article that is of a layer thickness at least effective to reduce the number and/or depth of flaws on the surface of the article, and then applying a friction-reducing coating to the portion of the article from which the layer of surface glass has been removed.
    Type: Application
    Filed: May 5, 2011
    Publication date: November 8, 2012
    Inventor: Timothy Michael Gross
  • Publication number: 20120281292
    Abstract: Durable antireflective coatings and glass articles having such coatings are described herein. The antireflective coatings generally include a layer of nominally hexagonally packed nanoparticles that are partially embedded either in a surface of the glass article or in a binder that is on the surface of the glass article. Methods of making the antireflective coatings or layers and glass articles having such antireflective layers are also described.
    Type: Application
    Filed: April 5, 2012
    Publication date: November 8, 2012
    Inventors: Adra Smith Baca, Daniel Aloysius Nolan, Odessa Natalie Petzold, Mark Alejandro Quesada, Wageesha Senaratne
  • Publication number: 20120264585
    Abstract: To provide a method for producing chemically tempered glass, whereby the chemical tempering can be done at a low temperature and in a short time. A method for producing chemically tempered glass, which comprises chemically tempering glass for chemical tempering, comprising, as represented by mole percentage based on the following oxides, from 60 to 75% of SiO2, from 5 to 15% of Al2O3, from 1 to 12% of MgO, from 0 to 3% of CaO, from 0 to 3% of ZrO2, from 10 to 20% of Li2O, from 0 to 8% of Na2O and from 0 to 5% of K2O, and having a total content R2O of Li2O, Na2O and K2O of at most 25%, and a ratio Li2O/R2O of the Li2O content to R2O of from 0.5 to 1.0.
    Type: Application
    Filed: March 13, 2012
    Publication date: October 18, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Seiki OHARA, Kazutaka Ono, Tetsuya Nakashima
  • Publication number: 20120251827
    Abstract: A tempered glass substrate of the present invention is a tempered glass substrate, which has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 71% of SiO2, 3 to 21% of Al2O3, 0 to 3.5% of Li2O, 7 to 20% of Na2O, and 0 to 15% of K2O.
    Type: Application
    Filed: June 8, 2012
    Publication date: October 4, 2012
    Inventor: Takashi MURATA
  • Publication number: 20120240626
    Abstract: The present invention relates to a process for producing a chemically strengthened glass substrate for a display device, the process including a pre-heating step of pre-heating a glass to a pre-heating temperature and subsequently an ion exchange step of immersing the glass in a chemical strengthening liquid, in which the pre-heating temperature in the pre-heating step and a strain point of the glass satisfy: 220° C.?(strain point?pre-heating temperature).
    Type: Application
    Filed: March 23, 2012
    Publication date: September 27, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Syuji MATSUMOTO, Tsuguhide Isemura, Koji Nakagawa, Kazutaka Ono, Shusaku Akiba, Haruo Aizawa
  • Publication number: 20120236477
    Abstract: Embodiments disclosed therein generally pertain to selectively strengthening glass. More particularly, techniques are described for selectively strengthening cover glass, which tends to be thin, for electronic devices, namely, portable electronic devices.
    Type: Application
    Filed: September 16, 2011
    Publication date: September 20, 2012
    Inventor: Douglas J. Weber
  • Publication number: 20120236526
    Abstract: Apparatus, systems and methods for increasing the strength of glass are disclosed. The use of multi-bath chemical processing for a glass article can facilitate controlled chemical strengthening. Through multi-bath (or multi-step) chemical processing, differing levels of strengthening can be achieved for different portion of glass articles. The multi-bath chemical processing can be achieved through the use of successive chemical baths. Accordingly, glass articles that have undergone multi-bath chemical processing are able to be not only thin but also sufficiently strong and resistant to damage. The strengthened glass articles are well suited for use in consumer products, such as consumer electronic devices (e.g., portable electronic devices). In one embodiment, the glass member can pertain to a glass cover for a housing of an electronic device.
    Type: Application
    Filed: September 16, 2011
    Publication date: September 20, 2012
    Inventor: Douglas J. Weber
  • Publication number: 20120219792
    Abstract: To provide a glass substrate for a display cover glass not only having excellent strength and antibacterial properties but also having a high transparency and a high visible transmittance suitable as a cover glass for a display device. A glass substrate for a display cover glass, which comprises a surface compressive stress layer and an antibacterial substance-containing layer formed on the glass substrate surface, characterized by having a ratio (T1/T2) of the transmittance T1 at a wavelength of 428 nm to the transmittance T2 at a wavelength of 650 nm of the glass substrate of at least 0.95, and a transmittance at a wavelength of 428 nm of at least 86% when the thickness of the glass substrate is from 0.1 to 3.0 mm.
    Type: Application
    Filed: May 8, 2012
    Publication date: August 30, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Hiroyuki Yamamoto, Yusaku Matsuo
  • Publication number: 20120216569
    Abstract: The present disclosure is directed to a method for producing constancy of the ion-exchanged product stress profile through adjustment of ion-exchange conditions by taking account of the influence of salt bath poisoning on the bath's useful lifetime. The present disclosure is directed to a method of ion-exchange in which the salt bath temperature and salt bath time are adjusted as a function of the amount of alkali metal ions that exchange in the bath. That is, temperature and time are adjusted as a function of salt bath poisoning. Temperature is set to its highest value and time to its shortest value in the starting unpoisoned salt bath, those values chosen to hit target values of surface compressive stress and exchange depth of layer. Temperature is then reduced and time lengthened as salt bath poisoning proceeds, those changes chosen to maintain the same surface compressive stress and exchange depth of layer.
    Type: Application
    Filed: February 24, 2011
    Publication date: August 30, 2012
    Inventors: Douglas Clippinger Allan, Kenneth Edward Hrdina, William Rogers Rosch
  • Publication number: 20120216565
    Abstract: The present disclosure is directed to a method for producing constancy of the ion-exchanged product stress profile through adjustment of ion-exchange conditions by taking account of the influence of salt bath poisoning on the bath's useful lifetime. The present disclosure is directed to a method of ion-exchange in which the salt bath temperature and salt bath time are adjusted as a function of the amount of alkali metal ions that exchange in the bath. That is, temperature and time are adjusted as a function of salt bath poisoning. Temperature is set to its highest value and time to its shortest value in the starting un-poisoned salt bath, those values chosen to hit target values of surface compressive stress and exchange depth of layer. Temperature is then reduced and time lengthened as salt bath poisoning proceeds, those changes chosen to maintain the same surface compressive stress and exchange depth of layer.
    Type: Application
    Filed: February 1, 2012
    Publication date: August 30, 2012
    Inventors: Douglas Clippinger Allan, Kenneth Edward Hrdina, William Rogers Rosch
  • Publication number: 20120216570
    Abstract: This disclosure describes a process for strengthening, by ion-exchange, the edges of an article separated from a large glass sheet after the sheet has been ion-exchanged to strengthen by exposing only the one or a plurality of the edges of the separated article to an ion-exchange medium (for example without limitation, a salt, paste, frit, glass) while the glass surface is maintained at temperatures less than 200° C.
    Type: Application
    Filed: February 10, 2012
    Publication date: August 30, 2012
    Inventors: Anatoli Anatolyevich Abramov, Sinue Gomez, Lisa Anne Moore, Alexander Mikhailovich Streltsov, Sergio Tsuda, Jonathan E. Walter
  • Publication number: 20120214004
    Abstract: A glass substrate manufacturing method of this invention includes a first chemical strengthening process for chemically strengthening a plate-like glass member by ion exchange, a cutting process for cutting the plate-like glass member into small pieces after the first chemical strengthening process, thereby obtaining a plurality of glass substrates, and a second chemical strengthening process for chemically strengthening the glass substrates by ion exchange after the cutting process.
    Type: Application
    Filed: February 16, 2012
    Publication date: August 23, 2012
    Applicant: HOYA CORPORATION
    Inventors: Kazuaki HASHIMOTO, Tetsuo TAKANO
  • Publication number: 20120210749
    Abstract: A method of chemically strengthening a glass article having an antireflective coating in which the reflectance of the coating is not significantly degraded by chemical strengthening. The glass article having the antireflective coating is strengthened using an ion exchange medium that comprises potassium nitrate and at least about 5 wt % potassium nitrite. Also provided are a glass article having an antireflective surface that is not degraded by such ion exchange and an ion exchange medium comprising potassium nitrate and at least about 5 wt % potassium nitrite.
    Type: Application
    Filed: February 22, 2011
    Publication date: August 23, 2012
    Inventors: Jiangwei Feng, Kenneth Edward Hrdina, Yawei Sun
  • Patent number: 8245535
    Abstract: A method of strengthening glass plate is provided. A plasma treating process is performed on a glass plate so that a surface pore variation of the glass plate after the plasma treating process is reduced relative to the surface pore variation of the glass plate before the plasma treating process, wherein the surface pore variation is a variation degree of surface pores in different unit areas of the glass plate. In the mean time, a melted network crosslinking structure is formed on the surface of the glass plate. Based on the above-mentioned mechanisms, the glass plate is strengthened. The plasma treating process is conducive to strengthen the glass plate whether the plasma treating process is performed before or after the conventional chemical strengthening process.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: August 21, 2012
    Assignees: Applied Vacuum Coating Technologies Co., Ltd., Avct Optical Electronic Co., Ltd.
    Inventors: Chien-Min Weng, Tzu-Wen Chu, Chiao-Ning Huang, Fu-Jen Wang, Shih-Liang Chou, I-Wen Lee, Ching-Hsiu Cheng
  • Publication number: 20120196071
    Abstract: Strengthened glass substrate sheets and methods of fabricating glass panels from glass substrate sheets are disclosed. In one embodiment, a method includes forming at least one series of holes through a thickness of the glass substrate sheet, wherein the at least one series of holes defines a perimeter of the glass panel to be separated from the glass substrate sheet. The method further includes strengthening the glass substrate sheet by a strengthening process, and separating the glass panel from the glass substrate sheet along the at least one series of holes. At least a portion of one or more edges of the glass panel has an associated edge compressive layer. In another embodiment, a strengthened glass substrate sheet includes at least one series of holes that defines a perimeter of one or more glass panels to be separated from the strengthened glass substrate sheet.
    Type: Application
    Filed: February 1, 2011
    Publication date: August 2, 2012
    Inventors: Ivan A. Cornejo, Sinue Gomez, Lisa Anne Moore, Sergio Tsuda
  • Publication number: 20120188663
    Abstract: An aspect of the present invention relates to a glass substrate for a magnetic recording medium, which is comprised of glass with a glass transition temperature of equal to or greater than 600° C., an average coefficient of linear expansion at 100 to 300° C. of equal to or greater than 70×10?7/° C., a Young's modulus of equal to or greater than 81 GPa, a specific modulus of elasticity of equal to or greater than 30 MNm/kg, and a fracture toughness value of equal to or greater than 0.9 MPa·m1/2.
    Type: Application
    Filed: December 20, 2011
    Publication date: July 26, 2012
    Applicant: HOYA CORPORATION
    Inventors: Hideki ISONO, Kinobu OSAKABE, Katsuyuki IWATA, Mikio IKENISHI, Naomi MATSUMOTO
  • Publication number: 20120171497
    Abstract: A cover glass having a compressive-stress layer on the principal surfaces thereof, and having a glass composition containing 50% to 70% by mole of SiO2, 3% to 20% by mole of Al2O3, 5% to 25% by mole of Na2O, more than 0% by mole and less than or equal to 2.5% by mole of Li2O, 0% to 5.5% by mole of K2O, and 0% to less than 3% by mole of B2O3. Also disclosed is a method for producing a cover glass which includes: (i) preparing molten glass by melting a glass raw material; (ii) forming the prepared molten glass into a plate-like shape by a down-draw process and thereby obtaining a glass substrate; and (iii) forming a compressive-stress layer on the surface of the glass substrate.
    Type: Application
    Filed: December 28, 2011
    Publication date: July 5, 2012
    Applicants: HOYA CORPORATION, AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Satoshi AMI, Kazuaki HASHIMOTO, Tetsuo TAKANO
  • Publication number: 20120141760
    Abstract: A tempered glass substrate has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 70% of SiO2, 12 to 21% of Al2O3, 0 to 3.5% of Li2O, 10 to 20% of Na2O, 0 to 15% of K2O, and 0 to 4.5% of TiO2, wherein the tempered glass substrate has a plate thickness of 1.5 mm or less, and an internal tensile stress in the tempered glass substrate is 15 to 150 MPa.
    Type: Application
    Filed: February 8, 2012
    Publication date: June 7, 2012
    Inventor: Takashi MURATA
  • Publication number: 20120141801
    Abstract: A tempered glass substrate used for a cover glass of a display has a compression stress layer on a surface thereof, and has a glass composition comprising, in terms of mass %, 40 to 71% of SiO2, 3 to 21% of Al2O3, 0 to 1% of Li2O, 7 to 20% of Na2O, 0 to 15% of K2O, 0 to 3% of SrO, 0.001 to 10% of ZrO2, and 0 to 4% of TiO2, wherein K2O/Na2O in terms of mass fraction is 0.25 to 2.
    Type: Application
    Filed: February 8, 2012
    Publication date: June 7, 2012
    Inventor: Takashi MURATA
  • Patent number: 8193128
    Abstract: The disclosed invention relates to a process of using molten salt ion exchange to treat particles such as spherically shaped soda-lime-silica glass particles. The treated particles may be used as proppants in hydrofractured oil and natural gas wells.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: June 5, 2012
    Assignee: The Penn State Research Foundation
    Inventors: John R. Hellmann, Barry E. Sheetz, Ryan P. Koseski
  • Publication number: 20120135195
    Abstract: Methods for separating glass articles from strengthened glass substrate sheets and strengthened glass substrate sheets are provided. In one embodiment, a method includes forming at least one groove on at least one surface of the glass substrate sheet and strengthening the glass substrate sheet by a strengthening process. The groove defines the glass article and partially extends through a thickness of the glass substrate sheet. The method further includes generating an initiation defect on the groove at an initiation location to cause a through crack to self-propagate through the glass substrate sheet along the groove, thereby separating the glass article from the glass substrate sheet. In another embodiment, a strengthened glass substrate sheet includes a strengthened glass having a glass article groove and an initiation groove on a surface, the glass article groove defining a glass article.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Inventors: Gregory Scott Glaesemann, Xinghua Li, Daniel Duane Strong
  • Publication number: 20120135848
    Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.
    Type: Application
    Filed: November 29, 2011
    Publication date: May 31, 2012
    Inventors: George Halsey Beall, Nicholas Francis Borrelli, Charlene Marie Smith, Steven Alvin Tietje
  • Publication number: 20120134025
    Abstract: A chemically-strengthened glass sheet including: a smooth first side; and a rough second side, wherein the compressive stress values of the smooth first-side and the rough second-side are substantially in equipoise. Methods of making and using the glass sheet, as defined herein, are disclosed. A display system that incorporates the glass sheet, as defined herein, is also disclosed.
    Type: Application
    Filed: October 11, 2011
    Publication date: May 31, 2012
    Inventor: Shandon Dee Hart
  • Patent number: 8187987
    Abstract: The invention relates to glass articles suitable for use as electronic device housing/enclosure or protective cover which comprise a glass material. Particularly, a housing/enclosure/cover comprising an ion-exchanged glass exhibiting the following attributes (1) radio, and microwave frequency transparency, as defined by a loss tangent of less than 0.03 and at a frequency range of between 15 MHz to 3.0 GHz; (2) infrared transparency; (3) a fracture toughness of greater than 0.6 MPa·m1/2; (4) a 4-point bend strength of greater than 350 MPa; (5) a Vickers hardness of at least 450 kgf/mm2 and a Vickers median/radial crack initiation threshold of at least 5 kgf, (6) a Young's Modulus ranging between about 50 to 100 GPa; (7) a thermal conductivity of less than 2.0 W/m° C., and (9) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.
    Type: Grant
    Filed: August 21, 2009
    Date of Patent: May 29, 2012
    Assignee: Corning Incorporated
    Inventors: Jaymin Amin, Matthew John Dejneka, Linda Ruth Pinckney, Katherine Rose Rossington, Robert Sabia
  • Publication number: 20120111056
    Abstract: Apparatus, systems and methods for improving chemical strengthening of glass are disclosed. In one embodiment, a mechanical stress can be induced on a glass article while undergoing chemical strengthening. In another embodiment, vibrations, such as ultrasonic vibrations, can be induced during chemical strengthening of a glass article. The use of mechanical stress and/or vibrations during chemically strengthening of a glass article can enhance the effectiveness of the chemical strengthening process. Accordingly, glass articles that have undergone chemical strengthening processing are able to be not only thin but also sufficiently strong and resistant to damage. The strengthened glass articles are well suited for use in consumer products, such as consumer electronic devices (e.g., portable electronic devices).
    Type: Application
    Filed: May 14, 2011
    Publication date: May 10, 2012
    Inventor: Christopher Prest
  • Publication number: 20120111057
    Abstract: A strengthened glass article having a central tension that is below a threshold value above which the glass exhibits frangible behavior. The central tension varies non-linearly with the thickness of the glass. The glass article may be used as cover plates or windows for portable or mobile electronic devices such as cellular phones, music players, information terminal (IT) devices, including laptop computers, and the like.
    Type: Application
    Filed: November 4, 2011
    Publication date: May 10, 2012
    Inventors: Kristen L Barefoot, James Joseph Price, Jose Mario Quintal, Ronald Leroy Stewart
  • Patent number: 8166778
    Abstract: The invention relates to a pane that has undergone a chemical toughening operation so as to have an alkali-metal-ion concentration gradient from its surface over an exchange depth of at least 100 ?m, a surface stress of at least 200 MPa, and a strain point at the core of at least 550° C. The pane can be used especially in the field of domestic cooking, as a pyrolytic oven door, stove, fire guard, flue insert, and more generally for separating two gaseous atmospheres at different temperatures. The pane is particularly resistant to heat shocks.
    Type: Grant
    Filed: October 5, 2004
    Date of Patent: May 1, 2012
    Assignee: Saint-Gobain Glass France
    Inventor: Franck Marandon
  • Publication number: 20120085130
    Abstract: Apparatus, systems and methods for improving chemical strengthening behavior in glass members are disclosed. According to one aspect, a method for processing a glass part formed using a fusion process or a float process includes annealing the glass part and then chemically strengthening the glass part. Annealing the glass part includes at least heating the glass part at a first temperature, maintaining the first temperature, and cooling the glass part to a second temperature using a controlled cooling process. Chemically strengthening the glass part includes facilitating an ion exchange between ions included in the glass part and ions included in a chemical strengthening bath.
    Type: Application
    Filed: May 14, 2011
    Publication date: April 12, 2012
    Inventors: Matthew D. Hill, Michael Kane Pilliod, Christopher Prest, Douglas Weber, Spyros Michail, David Pakula
  • Publication number: 20120088067
    Abstract: Apparatus, systems and methods for reducing surface roughness on surface of a glass member using a non-contact polishing process are disclosed. According to one aspect, a method for processing a glass member suitable for use in a handheld electronic device includes obtaining the glass member and chemically strengthening the glass member. The glass member has at least one surface, and chemically strengthening the glass member increases roughness associated with the at least one surface. The method also includes applying a first non-contact polishing process to the glass member after chemically strengthening the glass member. Applying the first non-contact polishing process reduces the roughness associated with the at least one surface.
    Type: Application
    Filed: May 14, 2011
    Publication date: April 12, 2012
    Inventors: Benjamin M. Rappoport, Christopher Prest
  • Publication number: 20120083401
    Abstract: The disclosed cover glass is produced by etching a glass substrate that has been formed by a down-drawing process, and chemically strengthening the glass substrate to provide the glass substrate with a compressive-stress layer on the principal surfaces thereof. The glass substrate contains, as components thereof, 50% to 70% by mass of SiO2, 5% to 20% by mass of Al2O3, 6% to 30% by mass of Na2O, and 0% to less than 8% by mass of Li2O. The glass substrate may also contain 0% to 2.6% by mass of CaO, if necessary. The glass substrate has an etching characteristic in which the etching rate is at least 3.7 ?m/minute in an etching environment having a temperature of 22° C. and containing hydrogen fluoride with a concentration of 10% by mass.
    Type: Application
    Filed: September 28, 2011
    Publication date: April 5, 2012
    Applicants: HOYA CORPORATION, AVANSTRATE INC.
    Inventors: Akihiro KOYAMA, Mikiko MORISHITA, Satoshi AMI, Kazuaki HASHIMOTO, Tetsuo TAKANO
  • Publication number: 20120064306
    Abstract: A method for cutting a tempered glass includes the following steps. First, a shielding layer is formed on a part of a surface of a glass substrate, and a predetermined cutting path passes through the part of the surface. Then, a glass substrate is given an ion-exchange strengthening treatment, and the part of the surface covered by the shielding layer substantially does not undergo ion-exchange. Finally, the glass substrate is cut along the predetermined cutting path.
    Type: Application
    Filed: September 9, 2011
    Publication date: March 15, 2012
    Inventors: Hen-Ta KANG, Jeng-Jye Hung, Yung-Lin Chen