Forming Optical Fiber Or Fiber Preform By Soot Buildup (i.e., Vapor Axial Deposition, Vad) Patents (Class 65/414)
  • Patent number: 11081851
    Abstract: An optical fiber, such as in some instances a high-power, diode-pumped, dual-clad, ytterbium-doped fiber amplifier (YDFAs), having a fundamental mode and at least one higher order mode, wherein the higher order mode or modes have mode areas that are substantially larger than a mode area of the fundamental mode.
    Type: Grant
    Filed: July 20, 2017
    Date of Patent: August 3, 2021
    Assignee: University of Rochester
    Inventors: John R. Marciante, Jordan P. Leidner
  • Patent number: 10934205
    Abstract: A method of manufacturing a glass core preform for optical fibres including providing a porous soot core preform having a central longitudinal hole extending axially therethrough and an a/b ratio of from 0.20 to 0.40; simultaneously dehydrating and doping with fluorine the soot core preform at a temperature of from 1000° C. to 1350° C. by exposing it to an atmosphere containing a chlorine-containing gas and a fluorine-containing gas, the content of the fluorine-containing gas in the atmosphere being of from 0.01% to 0.50% by volume, and simultaneously consolidating the soot core preform and closing the central longitudinal hole by exposing the soot core preform to an atmosphere substantially devoid of fluorine and of chlorine at a consolidation temperature of from 1500° C. to 1650° C., while reducing the pressure down the central hole, thereby forming a glass core preform.
    Type: Grant
    Filed: October 9, 2015
    Date of Patent: March 2, 2021
    Assignee: PRYSMIAN S.P.A.
    Inventors: Franco Cocchini, Antonio Adigrat
  • Patent number: 10927032
    Abstract: A system for controlling an ambient microgravity environment of a system for drawing optical fiber including a filter arranged to cleanse an environment from contaminants, a molecular sieve arranged in a series of at least one of meshes and baffles to dehumidify the environment, at least one of a pump and a fan to draw an environmental gas through the filter, through the molecular sieve and back in to an ambient environment and a housing in which the filter, molecular sieve and at least one of pump and fan reside.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: February 23, 2021
    Assignee: MADE IN SPACE, INC.
    Inventors: Jan Clawson, Robert White, Nate Pickslay, Michael Snyder, Geoffrey York Powers, Noah Paul-Gin
  • Patent number: 9527764
    Abstract: Provided is a quartz glass manufacturing method that involves using one or more burners, supplying hydrogen and oxygen to the one or more burners to generate an oxyhydrogen flame, introducing a silicide into the oxyhydrogen flame, forming a porous base material by depositing silicon dioxide generated from a flame hydrolysis reaction with the silicide, and heating and sintering the porous base material to form transparent glass, the method comprising supplying hydrogen that is stored or made at a normal temperature to the one or more burners; controlling a hydrogen flow rate using a measurement apparatus or control apparatus that performs measurement based on heat capacity of a gas; vaporizing liquid hydrogen stored in a low-temperature storage chamber, and supplying the vaporized liquid hydrogen to the one or more burners as backup hydrogen; switching from the hydrogen to the backup hydrogen; and when switching, adjusting the hydrogen flow rate to a value obtained by multiplying the hydrogen flow rate immedia
    Type: Grant
    Filed: May 19, 2014
    Date of Patent: December 27, 2016
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Dai Inoue, Takaaki Nagao, Hiroyuki Koide
  • Patent number: 9435917
    Abstract: Laser-processed gradient-index (GRIN) lenses and optical interface devices and assemblies that utilize the laser-processed GRIN lenses are disclosed. A GRIN lens assembly includes a cylindrical central section having a GRIN index profile, planar front and back surfaces, an outer surface, and a diameter D1 where 200 micrometers?D1?420 micrometers. An annular cladding of outer diameter D2 surrounds the central section outer surface and has front and back annular surfaces and a constant or a varying refractive index. One or both of the front and back annular surfaces may be curved. An optical fiber is optically coupled to the central section at the planar back surface. An optical interface device is formed by operably supporting at least one GRIN lens assembly with a support member. An optical interface assembly is formed by interfacing two optical interface devices.
    Type: Grant
    Filed: June 13, 2012
    Date of Patent: September 6, 2016
    Assignee: Corning Incorporated
    Inventors: Jeffery Alan DeMeritt, Davide Domenico Fortusini, Pushkar Tandon
  • Patent number: 9260339
    Abstract: A method of fabricating an optical fiber preform, capable of depositing glass particles with high deposition rate without reducing deposition efficiency and fabricating an optical fiber preform having little bubbles using a burner having a simple structure, is provided. In the invention, a mixed gas of a glass raw material gas with a combustion assisting gas is ejected from an annular nozzle of a burner having a coaxially multiple tube structure, and a burnable gas is ejected from an inner nozzle located inside the annular nozzle. Alternatively, a mixed gas of a glass raw material gas with a burnable gas may be ejected from an annular nozzle, and a combustion assisting gas is ejected from an inner nozzle located inside the annular nozzle. In each case of the above, the burnable gas and the combustion assisting gas, respectively, are ejected from outer nozzles located outside the annular nozzle.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: February 16, 2016
    Assignee: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Makoto Yoshida
  • Patent number: 9260338
    Abstract: One embodiment provides a porous glass body which is obtained by depositing plural deposited layers of glass fine particles on a starting material in a layered manner by relatively reciprocating a burner for glass-fine-particle synthesis and the starting material. In the porous glass body, a porosity in a layer at the deposited layers falls within a range of 40% to 90%, and the porosity in the layer decreases from a central side toward an outer side in a radial direction thereof.
    Type: Grant
    Filed: February 28, 2014
    Date of Patent: February 16, 2016
    Assignee: SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Teruhiko Itou, Tomohiro Ishihara, Motonori Nakamura, Yuugo Kubo
  • Patent number: 9038423
    Abstract: A porous preform production apparatus having a reaction vessel which includes an upper deposition chamber having an air supply inlet and an exhaust outlet, a lower deposition chamber having an air supply inlet, and a top chamber disposed on top of the upper deposition chamber and adapted to lift and store a porous preform formed by deposition, characterized in that the floor of the upper deposition chamber is disposed at a height between the lower end of a straight body part and the deposition tip of the porous glass preform during deposition, and a connection opening which connects the upper deposition chamber with the lower deposition chamber, is provided on the floor of the upper deposition chamber, and that when the aperture diameter of the connection opening is designated as A and the diameter of the porous preform passing through the connection opening as B, the ratio B/A satisfies the expression 0.05?B/A?0.6.
    Type: Grant
    Filed: October 18, 2013
    Date of Patent: May 26, 2015
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Patent number: 8959957
    Abstract: Methods are described for manufacturing silica-based glass, in which silica precursor material is supplied to a synthesis flame in the form of an emulsion. The methods involve the steps of: forming an emulsion of an aqueous phase in a non-aqueous liquid silica precursor material; supplying the emulsion as a spray of droplets into a synthesis flame, whereby the precursor material is converted in the flame into a silica-containing soot; and collecting the soot on a substrate, either as a porous soot body for subsequent consolidation to glass or directly as a substantially pore-free glass.
    Type: Grant
    Filed: February 28, 2011
    Date of Patent: February 24, 2015
    Assignee: Heraeus Quartz UK Limited
    Inventors: Richard Benjamin Coapes, Alan Mundy, Ian George Sayce
  • Publication number: 20150040616
    Abstract: Provided is an optical fiber glass base material manufacturing method that includes flame polishing an outside of a starting base material that includes a core and a first cladding with an oxyhydrogen flame and then arranging a glass fine particle synthesis burner facing the starting base material, which rotates, moving the starting base material and the burner back and forth relative to each other along the starting base material, and depositing glass fine particles produced by hydrolysis of glass raw material in the oxyhydrogen flame as a porous glass layer of a second cladding, the method comprising synthesizing and depositing the glass fine particles under conditions in which a hydrogen flow rate during a first back and forth deposition pass performed immediately after supply of raw material is started is greater than a normal hydrogen flow rate.
    Type: Application
    Filed: April 2, 2014
    Publication date: February 12, 2015
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Hitoshi NAKAJIMA
  • Publication number: 20150033799
    Abstract: A glass particle deposit producing method capable of preventing the variation in the outside diameter of a glass particle deposit and enhancing the yield of a glass raw material is provided. A glass particle deposit is produced by mounting a starting rod 11 and a glass particle generating burner 22 inside a reaction vessel 2, introducing a glass raw material into the burner 22, subjecting the glass raw material to a flame decomposition reaction inside a flame formed by the burner 22 to generate glass particles, and depositing the generated glass particles on the starting rod 11. At this time, the dispersion angle of the glass raw material jetted from the burner 22 with respect to the center axis of the burner 22 is set to the range of 5 to 70 degrees.
    Type: Application
    Filed: December 27, 2013
    Publication date: February 5, 2015
    Inventors: Tomohiro Ishihara, Takashi Yamazaki
  • Patent number: 8919152
    Abstract: There is provided a method for manufacturing a porous glass base material by using a porous glass base material manufacturing burner having an oxidizing gas discharge port. The method includes supplying a gas mixture obtained by blending together an oxidizing gas and an inert gas to the oxidizing gas discharge port at a start of deposition of a glass fine particle, and increasing a flow rate of the oxidizing gas supplied to the oxidizing gas discharge port while decreasing a flow rate of the inert gas supplied to the oxidizing gas discharge port.
    Type: Grant
    Filed: May 12, 2009
    Date of Patent: December 30, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Patent number: 8869566
    Abstract: A method and apparatus for making an optical fiber preform. The apparatus has an outer wall and an inner wall. The outer wall surrounds the inner wall and the inner wall surrounds an inner cavity of the apparatus. A core rod is deposited in the inner cavity after which particulate glass material, such as glass soot, is deposited in the inner cavity around the core rod. The core rod has at least 10 percent of the final cladding soot already applied thereto. A radially inward pressure is applied against the particulate glass material to pressurize the particulate glass material against the core rod.
    Type: Grant
    Filed: August 25, 2011
    Date of Patent: October 28, 2014
    Assignee: Corning Incorporated
    Inventors: Martin Wade Allen, Steven Bruce Dawes, Robert Brett Desorcie, Nicolas LeBlond, Roger A Rose, Pushkar Tandon, Kochuparambil Vargheese, Li Yang
  • Patent number: 8869565
    Abstract: A method of producing optical fiber preform includes: forming a deposited layer by depositing glass particles on a periphery of a target element in a deposition mode while burning a mixed gas containing a glass source material gas, a flaming gas, and a supporting gas by use of a flaming burner; maintaining a state where the supporting gas flows at a flow velocity greater than or equal to a flow velocity at which a nozzle end of the supporting gas discharge nozzles does not glow while maintaining a pilot burner by allowing the flaming gas to flow to the seal gas discharge nozzle after a seal gas is replaced with the flaming gas in a case where a mode is changed from the deposition mode to a non-deposition mode; and replacing the flaming gas flowing to the flaming gas port with a purge gas.
    Type: Grant
    Filed: May 1, 2012
    Date of Patent: October 28, 2014
    Assignee: Fujikura Ltd.
    Inventors: Naritoshi Yamada, Shunichirou Hirafune
  • Patent number: 8840858
    Abstract: An apparatus for mixing a vaporized precursor with a gas for producing silica particles is provided. The apparatus includes a mixer housing, a precursor delivery chamber having an output in communication with the mixer housing for delivering a vaporized precursor in the mixer housing, and an oxidizing gas delivery chamber having an output in communication with the mixer housing for delivering an oxidizing gas to be mixed with the vaporized precursor. The apparatus further includes a flashback member disposed within the mixer housing and between the output of the precursor delivery chamber and the output of the oxidizing gas delivery chamber. The flashback member is located at a minimum distance from the output of the oxidizing gas delivery chamber defined by Lminimum (cm)=0.453 U (Re)?0.5567, wherein U is the flow rate in cm/sec of precursor and Re is the flow Reynolds number. The flashback member may include a tapered surface on at least one side to reduce recirculation of vaporized gas.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: September 23, 2014
    Assignee: Corning Incorporated
    Inventors: Lewis A Bernstein, Dana Craig Bookbinder, Jason A Dillard, Jennifer L Porter, Balram Suman, Pushkar Tandon
  • Patent number: 8820122
    Abstract: A titania-doped quartz glass suited as an EUV lithographic member is prepared by feeding a silicon-providing reactant gas and a titanium-providing reactant gas through a burner along with hydrogen and oxygen, subjecting the reactant gases to oxidation or flame hydrolysis to form synthetic silica-titania fine particles, depositing the particles on a rotating target, and concurrently melting and vitrifying the deposited particles to grow an ingot of titania-doped quartz glass. The target is retracted such that the growth front of the ingot may be spaced a distance of at least 250 mm from the burner tip.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: September 2, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Shigeru Maida, Hisatoshi Otsuka, Osamu Sekizawa, Naoki Yanagisawa
  • Publication number: 20140230494
    Abstract: A method of manufacturing quartz glass includes depositing soot generated by flame hydrolysis of a raw material gas to a starting member, while the starting member is raised and rotated, to form a soot deposition member that includes an effective portion having a substantially constant outer diameter, the effective portion to become a material of a glass product, an upper ineffective portion formed at an upper end of the effective portion, and a lower ineffective portion formed at a lower end of the effective portion, each of the ineffective portions having an outer diameter changing in a tapering form, wherein the depositing includes forming the lower ineffective portion while decreasing a peripheral speed of a surface of the starting member to a predetermined final peripheral speed in a ratio of 1.3 m/minute or below per second during a period after the effective portion is formed.
    Type: Application
    Filed: April 23, 2014
    Publication date: August 21, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventors: Dai Inoue, Makoto Yoshida
  • Publication number: 20140174135
    Abstract: A glass fine particle synthesis burner comprising a glass raw material gas emission path for emitting glass raw material; a ring-shaped combustible gas emission path for emitting combustible gas arranged outside the glass raw material emission path; a ring-shaped combustion aiding gas emission path for emitting combustion aiding gas arranged outside the combustible gas emission path; and small diameter nozzles for emitting the combustion aiding gas within the combustible gas emission path. In a cross section of the glass fine particle synthesis burner formed by cleaving orthogonal to a central axis thereof, when the glass fine particle synthesis burner is divided into two regions by a predetermined straight line passing through a center of the glass fine particle synthesis burner, a total area of the small diameter nozzles in one of the regions is greater than a total area of the small diameter nozzles in the other region.
    Type: Application
    Filed: December 16, 2013
    Publication date: June 26, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Yuhei URATA
  • Patent number: 8707741
    Abstract: A method of manufacturing an optical fiber preform by depositing glass fine particles onto a surface of a glass rod while the glass rod is reciprocated relative to a plasma torch, including: moving the glass rod in a first direction relative to the plasma torch while the plasma torch is applied to the glass rod and supplied at least with a dopant material and a glass material to deposit the glass fine particles onto the surface of the glass rod, in such a manner that a plasma power is set higher during a first time interval starting from a beginning of the movement of the glass rod in the first direction than during a second time interval starting from an end of the first time interval; and moving the glass rod in a second direction relative to the plasma torch, where the second direction is opposite to the first direction.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: April 29, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd
    Inventor: Tetsuya Otosaka
  • Publication number: 20140106094
    Abstract: Processes for the manufacture of a hollow cylindrical porous body of synthetic vitreous silica soot by outside vapour deposition on a mandrel are described, in which the temperature of the mandrel is controlled to be substantially constant throughout the deposition process. In preferred embodiments, the mandrel is composed of metal or metal alloy. Hollow ingots of pure or doped synthetic vitreous silica glass manufactured by such processes are also described.
    Type: Application
    Filed: April 3, 2012
    Publication date: April 17, 2014
    Applicant: HERAEUS QUARTZ UK LIMITED
    Inventors: Alan Mundy, Ian George Sayce
  • Patent number: 8695380
    Abstract: The present invention provides a quartz glass burner that can enhance the heating power of flame working without unnecessarily increasing the flow of combustion gas and improve the deposition efficiency on depositing glass particles onto a porous glass preform. The quartz glass burner has a large diameter outer tube, and a plurality of small diameter inner tubes enclosed in the outer tube, and a tip of the outer tube has a port defining member defining the outer shape of a combustion gas ejecting port that ejects combustion gas, and the port defining member protrudes from the inner circumference of the outer tube towards the center axis so as to block the outermost area including areas between the outer circumferences of a plurality of inner tubes forming the inner tube row and the inner circumference of the outer tube of the combustion gas flow path.
    Type: Grant
    Filed: September 19, 2011
    Date of Patent: April 15, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Publication number: 20140083140
    Abstract: To provide a method for manufacturing a porous glass deposition body for optical fiber without causing deposition unevenness or decreasing the yield, provided is a method of manufacturing a porous glass deposition body by blowing glass fine particles generated from a plurality of burners for glass fine particle synthesis onto a starting member that is moved vertically and rotated on a rotational axis that is a central axis of the starting member. The burners are arranged such that the central axis of each burner shares a plane with the rotational axis of the starting member, and at least two of the planes in which the central axis of one of the burners and the rotational axis of the starting member are arranged form a prescribed angle.
    Type: Application
    Filed: September 18, 2013
    Publication date: March 27, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Yuhei URATA
  • Publication number: 20140075998
    Abstract: A porous preform production apparatus having a reaction vessel which includes an upper deposition chamber having an air supply inlet and an exhaust outlet, a lower deposition chamber having an air supply inlet, and a top chamber disposed on top of the upper deposition chamber and adapted to lift and store a porous preform formed by deposition, characterized in that the floor of the upper deposition chamber is disposed at a height between the lower end of a straight body part and the deposition tip of the porous glass preform during deposition, and a connection opening which connects the upper deposition chamber with the lower deposition chamber, is provided on the floor of the upper deposition chamber, and that when the aperture diameter of the connection opening is designated as A and the diameter of the porous preform passing through the connection opening as B, the ratio B/A satisfies the expression 0.05?B/A?0.6.
    Type: Application
    Filed: October 18, 2013
    Publication date: March 20, 2014
    Applicant: SHIN-ETSU CHEMICAL CO., LTD.
    Inventor: Makoto YOSHIDA
  • Patent number: 8656743
    Abstract: A porous preform production apparatus having a reaction vessel which includes an upper deposition chamber having an air supply inlet and an exhaust outlet, a lower deposition chamber having an air supply inlet, and a top chamber disposed on top of the upper deposition chamber and adapted to lift and store a porous preform formed by deposition, characterized in that the floor of the upper deposition chamber is disposed at a height between the lower end of a straight body part and the deposition tip of the porous glass preform during deposition, and a connection opening which connects the upper deposition chamber with the lower deposition chamber, is provided on the floor of the upper deposition chamber, and that when the aperture diameter of the connection opening is designated as A and the diameter of the porous preform passing through the connection opening as B, the ratio B/A satisfies the expression 0.05?B/A?0.6.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: February 25, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Patent number: 8650912
    Abstract: A method for manufacturing quartz glass using a main burner having a multi-tube assembly having a center tube, a first enclosure tube surrounding the center tube, a second enclosure tube surrounding the first enclosure tube, a tubular shell surrounding the multi-tube assembly, and a plurality of nozzles disposed within the tubular shell, a double-tube assembly surrounding at least a forward opening of the main burner includes feeding silica-forming compound to the center tube, a combustion-supporting gas to the first enclosure tube and the nozzles, a combustible gas to the second enclosure tube and the tubular shell, and a combustion-supporting gas to the double-tube assembly, forming oxyhydrogen flame for hydrolyzing or decomposing the silica-forming compound to form silica, depositing the silica on the target, and melting and vitrifying the deposited silica into quartz glass.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: February 18, 2014
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hisatoshi Otsuka, Kazuo Shirota
  • Patent number: 8459063
    Abstract: A multi-nozzle type burner is used for producing a porous glass preform, the burner having small variations in deposition efficiency with the burner tip being not burned even when axial shift occurs at the concentric multi-tube part of the burner. The present invention provides a burner for producing a porous glass preform with a concentric multi-tube structure, comprising a glass material gas jet port in a center, a plurality of gas jet ports concentrically disposed outside the glass material gas jet port, and small-diameter gas jet ports which are disposed in a line or a plurality of lines concentrically to the glass material gas jet port so as to be enclosed in one of the gas jet ports other than the gas jet ports in the center and at an outermost side, the small-diameter gas jet ports in the same line having an identical focal length.
    Type: Grant
    Filed: April 22, 2011
    Date of Patent: June 11, 2013
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Publication number: 20130133377
    Abstract: A known method for producing synthetic quartz glass comprises the method steps of: forming a stream of a SiO2 feedstock material which contains octamethylcyclotetrasiloxane (D4) as the main component which has a reference molecular mass assigned to it, feeding the stream to a reaction zone in which the feedstock material is converted under formation of amorphous SiO2 particles by pyrolysis or hydrolysis into SiO2, depositing the amorphous SiO2 particles on a deposition surface while forming a porous SiO2 soot body, and vitrifying the SiO2 soot body while forming the synthetic quartz glass.
    Type: Application
    Filed: November 23, 2012
    Publication date: May 30, 2013
    Applicant: HERAEUS QUARZGLAS GMBH & CO. KG
    Inventors: Heinz Fabian, Juergen Roeper
  • Patent number: 8375749
    Abstract: A method for fabricating a porous silica preform includes the steps of supplying fuel gas for generating an oxyhydrogen flame to a glass synthesizing burner; supplying Gas A containing silicon and Gas B containing fluorine to the burner; synthesizing glass particles; and depositing the glass particles around a starting rod, in which when glass particles are deposited directly on the starting rod, a supply of Gas A and a supply of Gas B supplied to the burner are adjusted so that a ratio of the number of fluorine atoms to the number of silicon atoms in the gas supplied to the burner satisfies the following Formula (1): {(number of F atoms)/(number of Si atoms)}?0.1??(1).
    Type: Grant
    Filed: December 3, 2009
    Date of Patent: February 19, 2013
    Assignee: Fujikura Ltd.
    Inventors: Kentaro Ichii, Takakazu Gotoh, Naritoshi Yamada, Koichi Harada
  • Patent number: 8356494
    Abstract: A process for producing a porous quartz glass body containing hydrolyzing a metal dopant precursor and an SiO2 precursor in a flame of a burner to form glass fine particles, and depositing and growing the formed glass fine particles on a base material, in which the burner has at least two nozzles, and in which a mixed gas containing (A) a metal dopant precursor gas, (B) an SiO2 precursor gas, (C) one gas of H2 and O2, and (D) one or more gases selected from the group consisting of a rare gas, N2, CO2, a hydrogen halide and H2O, with a proportion of the gas (D) being from 5 to 70 mol %; and (E) the other gas of H2 and O2 of (C), are fed into different nozzles of the burner from each other.
    Type: Grant
    Filed: August 16, 2011
    Date of Patent: January 22, 2013
    Assignee: Asahi Glass Company, Limited
    Inventors: Takahiro Mitsumori, Yasutomi Iwahashi, Akio Koike
  • Patent number: 8336337
    Abstract: The invention relates to a method for producing a blank mold from synthetic quartz glass by using a plasma-assisted deposition method, according to which a hydrogen-free media flow containing a glass starting material and a carrier gas is fed to a multi-nozzle deposition burner. The glass starting material is introduced into a plasma zone by the deposition burner and is oxidized therein while forming SiO2 particles, and the SiO2 particles are deposited on a deposition surface while being directly vitrified. In order to increase the deposition efficiency, the invention provides that the deposition burner (1) focuses the media flow toward the plasma zone (4) by. A multi-nozzle plasma burner, which is suited for carrying out the method and which is provided with a media nozzle for feeding a media flow to the plasma zone, is characterized in that the media nozzle (7) is designed so that it is focussed toward the plasma zone (4). The focussing is effected by a tapering (6) of the media nozzle (7).
    Type: Grant
    Filed: July 7, 2003
    Date of Patent: December 25, 2012
    Assignee: Heraeus Quarzglas GmbH & Co. KG
    Inventors: Richard Schmidt, Karsten Bräuer
  • Publication number: 20120320448
    Abstract: A frequency comb generator fabricated on a chip with elimination of a disadvantageous reflow process, includes an ultra-high Q disk resonator having a waveguide that is a part of a wedge structure fabricated from a silicon dioxide layer of the chip. The disk resonator allows generation of a frequency comb with a mode spacing as low as 2.6 GHz and up to 220 GHz. A surface-loss-limited behavior of the disk resonator decouples a strong dependence of pumping threshold on repetition rate.
    Type: Application
    Filed: June 15, 2012
    Publication date: December 20, 2012
    Inventors: Jiang LI, Hansuek LEE, Tong CHEN, Kerry VAHALA
  • Patent number: 8333090
    Abstract: A process for manufacturing an optical fiber, includes the steps of: a) producing a soot core preform by depositing a core material on a substrate; b) removing the substrate from the soot preform leaving an axial cavity along the longitudinal axis of the soot core preform; (c) drying and consolidating the soot core preform so as to obtain a glass core preform having an axial hole corresponding to the axial cavity; d) reducing a diameter of the axial hole; and e) stretching the glass core preform so as to substantially close the axial hole, wherein the process further includes the step of measuring at least one geometric characteristic of the axial hole of the glass core preform.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: December 18, 2012
    Assignee: Prysmian S.p.A.
    Inventors: Marco Ruzzier, Cristiano Ruocchio, Franco Cocchini, Antonio Adigrat
  • Patent number: 8316671
    Abstract: A known method for producing a hollow cylinder of synthetic quartz glass comprises the steps of: (a) providing an inner tube of synthetic quartz glass having an inner bore defined by an inner wall, (b) cladding the inner tube (3?) with an SiO2 soot layer (4?), and (c) sintering the SiO2 soot layer with formation of the hollow cylinder. Starting therefrom, to indicate a method in which on the one hand the sintering process is completed before the hollow cylinder is further processed together with the core rod, and in which on the other hand a complicated machining of the inner bore of the hollow cylinder of quartz glass is not required, the invention suggests that during sintering the surface temperature of the inner wall of the inner tube should be kept below the softening temperature.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: November 27, 2012
    Assignee: Heraeus Quarzglas GmbH & Co. KG
    Inventor: Michael Huenermann
  • Publication number: 20120279259
    Abstract: A method of producing optical fiber preform includes: forming a deposited layer by depositing glass particles on a periphery of a target element in a deposition mode while burning a mixed gas containing a glass source material gas, a flaming gas, and a supporting gas by use of a flaming burner; maintaining a state where the supporting gas flows at a flow velocity greater than or equal to a flow velocity at which a nozzle end of the supporting gas discharge nozzles does not glow while maintaining a pilot burner by allowing the flaming gas to flow to the seal gas discharge nozzle after a seal gas is replaced with the flaming gas in a case where a mode is changed from the deposition mode to a non-deposition mode; and replacing the flaming gas flowing to the flaming gas port with a purge gas.
    Type: Application
    Filed: May 1, 2012
    Publication date: November 8, 2012
    Applicant: FUJIKURA LTD.
    Inventors: Naritoshi YAMADA, Shunichirou HIRAFUNE
  • Patent number: 8268740
    Abstract: A fused silica glass having a refractive index homogeneity of less or equal to about 5 ppm over an aperture area of at least about 50 cm2. The fused silica glass is also substantially free of halogens and has an adsorption edge of less than about 160 nm. The glass is dried by exposing a silica soot blank to carbon monoxide before consolidation, reducing the combined concentration of hydroxyl (i.e., OH, where H is protium (11H) and deuteroxyl (OD), where D is deuterium (12H)) of less than about 20 ppm by weight in one embodiment, less than about 5 ppm by weight in another embodiment, and less than about 1 ppm by weight in a third embodiment.
    Type: Grant
    Filed: February 2, 2009
    Date of Patent: September 18, 2012
    Assignee: Corning Incorporated
    Inventors: Richard Michael Fiacco, Kenneth Edward Hrdina, Rostislav Radievich Khrapko, Lisa Anne Moore, Charlene Marie Smith
  • Patent number: 8261578
    Abstract: A method of making a fused silica article that is loaded with hydrogen. A fused silica glass near net shape part is provided and is loaded with a molecular hydrogen in a range from about 0.1×1017 molecules/cm3 up to about 1×1019 molecules/cm3. The thinner shape of the near net shape part enables the shape to be loaded more quickly than previous methods. A fused silica article loaded with hydrogen using the method is also described.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: September 11, 2012
    Assignee: Corning Incorporated
    Inventors: Kenneth Edward Hrdina, Michael A Mueller, Susan Schiefelbein
  • Patent number: 8230701
    Abstract: A method for forming a silica glass blank includes generating soot using an array of soot producing burners, directing the soot along a first direction onto a bait, collecting the soot on the bait, imparting relative oscillatory motion having a repeat period between the array of soot producing burners and the bait along a second direction orthogonal to the first direction while collecting the soot, and offsetting the relative oscillatory motion by a selected distance along the second direction after each repeat period.
    Type: Grant
    Filed: May 28, 2008
    Date of Patent: July 31, 2012
    Assignee: Corning Incorporated
    Inventors: Raymond D Groh, Brian Lee Harper, John Edward Maxon
  • Patent number: 8208775
    Abstract: A silica-based multi core optical fiber and a fabrication method for the same are provided, and include two or more cores of GeO2—SiO2 glass including an fluorine concentration not less than about 15 w % and a germanium concentration about 0.05 wt % to 2 wt %, in a core. A relative refractive index difference of a cladding and a core is not less than about 3%; and a ratio of a cladding diameter to a core diameter is about 1.02 to 3.0. A silica-based single core optical fiber is also provided, and includes a core having a germanium concentration not less than about 15 wt % and an fluorine concentration about 0.05 wt % to 2 wt %.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: June 26, 2012
    Assignee: Fujikura Ltd.
    Inventors: Manabu Kudou, Kazuyuki Hayashi, Takashi Tsumanuma
  • Patent number: 8196437
    Abstract: Core rod sections useable for production of finished optical fiber preforms are fabricated by inserting one or more core body pieces axially end-to-end inside a glass cylinder, thereby defining joints between adjacent ones of the inserted pieces. The cylinder is mounted with the contained core body pieces in the region of a furnace. The glass cylinder and core body pieces are heated together in the furnace, thereby elongating the cylinder and the core body pieces contained in the cylinder, and the cylinder collapses to form a finished core rod. Core rod sections are cut from the finished core rod at positions that coincide with the joints between the core body pieces. One or more of the cut core rod sections are useable for the production of optical fiber preforms.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: June 12, 2012
    Assignee: OFS Fitel, LLC
    Inventors: Eric L. Barish, Joseph P. Fletcher, III, Fengqing Wu
  • Patent number: 8079233
    Abstract: The present invention provides a burner for manufacturing a porous glass base material that has small-diameter gas discharge ports and that achieves uniform linear velocity at the gas discharge ports, a uniform reaction, and a stable flame, and improved deposition efficiency.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: December 20, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Makoto Yoshida
  • Patent number: 8037718
    Abstract: Method for manufacturing an optical fiber perform, which forms a glass fine particle deposition portion composed of glass fine particles on a glass rod, and suspends the glass fine particle deposition vertically into a heating furnace to heat, and transparentize, the glass fine particle deposition. The method comprises the following steps: forming a hazy portion before heating, by causing a surface portion of the glass rod to sublime and adhere to at least a portion of a region closer to one end of the glass rod than a region of the glass rod where the deposition portion is formed; forming the deposition portion by depositing the glass fine particles on the glass rod; and transparentizing the deposition portion by heating the glass fine particle deposition in a state where the proximal end of the glass rod where the hazy portion is formed is suspended vertically into the heating furnace.
    Type: Grant
    Filed: February 12, 2009
    Date of Patent: October 18, 2011
    Assignee: Fujikura Ltd.
    Inventor: Naritoshi Yamada
  • Patent number: 7992413
    Abstract: An object of the invention is to provide a process for producing a synthetic quartz glass while taking account of a refractive index distribution remaining in the synthetic quartz glass; a jig for use in the synthetic-quartz-glass production process; and a synthetic quartz glass for an optical member, produced by the process.
    Type: Grant
    Filed: August 16, 2007
    Date of Patent: August 9, 2011
    Assignee: Asahi Glass Company, Limited
    Inventor: Keigo Hino
  • Patent number: 7987686
    Abstract: There is provided a manufacturing apparatus of a porous glass base material which can prevent soot from being formed on an upper surface (ceiling) of the process chamber, and reduce the amount of soot that comes off the upper surface and falls. A manufacturing apparatus of a porous glass base material 4 deposits glass particles produced by subjecting a material gas to flame hydrolysis, onto a starting member 1 placed vertically. Here, a plurality of gas inlets 5 are provided in one or more lateral walls of a process chamber including a burner 2 for the deposition therein, in upper portions of the lateral walls and along a ceiling of the process chamber.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: August 2, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventor: Tetsuya Otosaka
  • Patent number: 7954340
    Abstract: When a synthetic quartz glass substrate is prepared from a synthetic quartz glass block, (I) the block has a hydrogen molecule concentration of 5×1017-1×1019 molecules/cm3, (II) the substrate has a hydrogen molecule concentration of 5×1015-5×1017 molecules/cm3, (III) the substrate has an in-plane variation of its internal transmittance at 193.4 nm which is up to 0.2%, and (IV) the substrate has an internal transmittance of at least 99.6% at 193.4 nm. The synthetic quartz glass substrate has a high transmittance and a uniform transmittance distribution, and is adapted for use with excimer lasers, particularly ArF excimer lasers.
    Type: Grant
    Filed: April 2, 2009
    Date of Patent: June 7, 2011
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hisatoshi Otsuka, Kazuo Shirota, Osamu Sekizawa
  • Patent number: 7836728
    Abstract: An optical fiber preform is fabricated by inserting a number of core body pieces end-to-end inside a glass cylinder, wherein the pieces may have a cladding-to-core diameter (D/d) ratio within the range of one to four. The cylinder with the inserted core body pieces is mounted vertically on a furnace and heated so that the cylinder becomes elongated and its outside diameter collapses to form a core rod from which core rod sections with D/d ratios greater than five, can be cut. A soot overcladding is deposited on the circumference of a core rod section until the diameter of the deposited soot builds to a determined value. The core rod section with the deposited soot overcladding is consolidated to obtain a finished optical fiber preform. The preform preferably has a D/d ratio of about 15 or more, and an optical fiber may be drawn directly from the preform.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: November 23, 2010
    Assignee: OFS Fitel, LLC
    Inventors: Eric L. Barish, Joseph P. Fletcher, III, Fengqing Wu
  • Patent number: 7827824
    Abstract: A synthetic quartz glass substrate having (i) an OH concentration of 1-100 ppm and a hydrogen molecule concentration of 1×1016-1×1019 molecules/cm3, (ii) an in-plane variation of its internal transmission at wavelength 193.4 nm which is up to 0.2%, and (iii) an internal transmission of at least 99.6% at wavelength 193.4 nm is suited for use with excimer lasers.
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: November 9, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hisatoshi Otsuka, Kazuo Shirota, Osamu Sekizawa
  • Patent number: 7784306
    Abstract: An apparatus for and method of depositing material on a substrate, the method comprising the steps of: delivering from a first outlet a stream of droplets of a precursor liquid towards a substrate; applying an electric field between the first outlet and the substrate; and delivering from a second outlet a flow of fuel about the stream of droplets such as to provide an annular flame combustion region between the first outlet and the substrate through which at least a portion of the stream of droplets passes before reaching the substrate, whereby the precursor liquid is one or both of chemically reacted and decomposed to provide the deposited material.
    Type: Grant
    Filed: December 7, 1998
    Date of Patent: August 31, 2010
    Assignee: Innovative Materials Processing Technologies Limited
    Inventors: Kwang-Leong Choy, Issac Tsz Hong Chang
  • Patent number: 7647792
    Abstract: A method for fabricating a porous silica preform includes the steps of supplying fuel gas for generating an oxyhydrogen flame to a glass synthesizing burner; supplying Gas A containing silicon and Gas B containing fluorine to the burner; synthesizing glass particles; and depositing the glass particles around a starting rod, in which when glass particles are deposited directly on the starting rod, a supply of Gas A and a supply of Gas B supplied to the burner are adjusted so that a ratio of the number of fluorine atoms to the number of silicon atoms in the gas supplied to the burner satisfies the following Formula (1): {(number of F atoms)/(number of Si atoms)}?0.1 ??(1).
    Type: Grant
    Filed: November 9, 2004
    Date of Patent: January 19, 2010
    Assignee: Fujikura Ltd.
    Inventors: Kentaro Ichii, Takakazu Gotoh, Naritoshi Yamada, Koichi Harada
  • Patent number: 7629032
    Abstract: A plasma buildup method for building up an optical fiber perform. The method includes the steps of: providing a plasma torch having an outlet nozzle adjacent to a primary perform, wherein an interaction zone is defined between the outlet nozzle and the primary preform; feeding the plasma torch with a plasma-generating gas in the presence of a silica-based material so as to deposit a buildup material on the primary preform; and introducing a reducing element into the interaction zone, the reducing element reacting to induce reduction of the nitrogen oxides produced by interaction between nitrogen and oxygen in the presence of the plasma generated by the torch.
    Type: Grant
    Filed: December 2, 2003
    Date of Patent: December 8, 2009
    Assignee: Draka Comteq B.V.
    Inventors: André Appriou, Charles Truchot, Sabine Guina
  • Patent number: 7481077
    Abstract: A device including at least one gripping member, rotatably mounted about an axis Z-Z, adapted to hold at least one end of at least one elongated element for chemical vapour deposition for forming a preform. The device includes at least one burner being mobile along a direction substantially parallel to the axis Z-Z and adapted to deposit, on the elongated element, a chemical substance for forming a preform, and at least one suction element arranged on the opposite side of the burner on a portion of a wall of the device on the opposite side of the gripping member from the burner. At least one air suction member, mobile along direction Z, is provided with motion synchronous with respect to the burner. The wall with the air suction member has a pair of respective upper and lower tapes rigidly associated with the burner.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: January 27, 2009
    Assignee: Prysmian Cavi e Sistemi Energia S.r.l.
    Inventors: Giacomo Stefano Roba, Franco Veronelli