Forming Optical Fiber Or Fiber Preform By Soot Buildup (i.e., Vapor Axial Deposition, Vad) Patents (Class 65/414)
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Patent number: 6619074Abstract: An apparatus for the production of a porous optical fiber preform preventing cracks in the preform and stabilizing quality over the longitudinal direction. The apparatus includes a reaction portion, a feed port for introducing a stream of gas, and a main exhaust port. A rotating mechanism is provided for mounting, rotating, and pulling up a seed rod for forming the porous optical fiber preform. A first burner emits a flame carrying fine particles of glass forming the core portion, and a second burner emits a flame carrying fine particles of glass forming the cladding portion. A portion adjusts the flow of the stream from the feed port to the main exhaust port so that the flames carrying the glass particles are not disturbed by the stream and so that the stream does not directly contact a fine glass particle deposit formed at a bottom end of the seed rod.Type: GrantFiled: August 29, 2000Date of Patent: September 16, 2003Assignee: The Furukawa Electric Co., Ltd.Inventors: Hiroyuki Wada, Toshihiro Mikami, Akihiro Kanao, Yukio Kohmura
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Publication number: 20030136154Abstract: In a method for manufacturing an optical fiber having a core portion for waveguiding lights, and a plurality of holes arranged around the core portion, the optical fiber is manufactured by puncturing the holes in a glass rod that is to become the optical fiber, by using an ultrasonic drill, and then drawing the glass rod with the holes to form the optical fiber.Type: ApplicationFiled: January 9, 2003Publication date: July 24, 2003Inventors: Katsusuke Tajima, Masaharu Ohashi, Kenji Kurokawa, Kazuhide Nakajima, Nobuyuki Yoshizawa
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Publication number: 20030115910Abstract: A method for manufacturing a preform, which is a base material of an optical fiber, comprising: forming porous-glass-base-material by accumulating glass particles; dehydrating the porous-glass-base-material by heating the porous-glass-base-material in an atmosphere of gas that contains chlorine; heating the porous-glass-base-material dehydrated by the dehydrating with a first heating temperature in an atmosphere of a first inert gas; and vitrifying the porous-glass-base-material by heating the porous-glass-base-material with a second heating temperature in an atmosphere of second inert gas.Type: ApplicationFiled: December 13, 2002Publication date: June 26, 2003Applicant: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroshi Oyamada, Tetsuya Otosaka
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Patent number: 6574991Abstract: An article of relatively pure silica, and a furnace and method of producing the article. The article is produced by collecting molten silica particles in a refractory furnace in which at least a portion of the refractory has been exposed to a halogen-containing gas to react with contaminating metal ions in the refractory.Type: GrantFiled: September 8, 2000Date of Patent: June 10, 2003Assignee: Corning IncorporatedInventors: Robert S. Pavlik, Jr., Lawrence H. Kotacska
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Patent number: 6574994Abstract: A method for manufacturing optical fiber preform and fiber. According to the method, a core cane segment is formed with a refractive index delta preferably between 0.2% and 3% that is most preferably formed by an OVD method. A sleeve is formed including at least one down-doped moat preferably having a refractive index delta between −0.1% and −1.2% and at least one up-doped ring preferably having a refractive index delta between 0.1% and 1.2%. The sleeve is formed by introducing glass precursor and dopant compounds into a cavity of a preferably silica glass tube (e.g., one of an MCVD and PCVD method). The core cane segment is inserted into the sleeve and the sleeve is collapsed onto the core cane segment to form a core-sleeve assembly. The core-sleeve assembly is again drawn into a cane and additional cladding is preferably formed thereon. Optical fiber may be drawn from the preform in a conventional draw apparatus.Type: GrantFiled: June 18, 2001Date of Patent: June 10, 2003Assignee: Corning IncorporatedInventors: Michael B. Cain, Liam R. dePaor, Robert B. Desorcie, Richard M. Fiacco, Cynthia B. Giroux
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Patent number: 6565823Abstract: The present invention is directed to a method for making fused silica glass. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO2 is provided and introduced directly into the flame of a combustion burner, thereby forming finely divided amorphous soot. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass. The invention further relates to an apparatus for forming fused silica from liquid, preferably halide-free, silicon-containing reactants which includes: a combustion burner which, in operation, generates a flame; an injector for supplying a liquid silicon-containing compound to the flame to convert the compound by thermal oxidative decomposition to a finely divided amorphous soot; and a receptor surface on which the soot is deposited.Type: GrantFiled: December 17, 1996Date of Patent: May 20, 2003Assignee: Corning IncorporatedInventors: Daniel W. Hawtof, Danny L. Henderson, Greg E. Smith, Eric H. Urruti
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Patent number: 6535679Abstract: In an optical fiber of this invention, the MFD is increased to effectively suppress the influence of nonlinear optical effects. A method of manufacturing the optical fiber effectively prevents bubble occurrence in a transparent preform, deformation of the preform, and flaws on the preform surface during the manufacture. The optical fiber has, from its center to the peripheral portion, a first core having a first refractive index n1, a second core having a second refractive index n2 (<n1), a first cladding having a third refractive index n3 (<n2), and a second cladding having a fourth refractive index n4 (>n3, <n2). The outer diameter of the second core is set to be 25 to 40 &mgr;m. Specifically, the refractive indices of the first and second claddings of the optical fiber preferably increase in the radial direction from the inner side thereof to the peripheral side thereof.Type: GrantFiled: January 15, 1998Date of Patent: March 18, 2003Assignee: Sumitomo Electric Industries, Ltd.Inventors: Yoshio Yokoyama, Akira Urano, Toshio Danzuka
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Patent number: 6523368Abstract: There is provided a dispersion-managed fiber preform and a fabricating method thereof preform by modified chemical vapor deposition (MCVD). A core and a clad having the refractive index distribution of an optical fiber with a positive dispersion value are uniformly deposited in a glass tube. The preform with the positive dispersion value is heated at every predetermined period with a torch and the heated preform portions are etched to have a negative dispersion value. Then, the preform alternately having positions with the positive dispersion value and positions with the negative dispersion value along the length direction is collapsed.Type: GrantFiled: January 16, 2001Date of Patent: February 25, 2003Assignee: Samsung Electronics Co., LTDInventors: Jae-Deuk Lee, Yong-Woo Park, Ghie-Hugh Song, Un-Chul Paek, Mun-Hyun Do
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Publication number: 20030019245Abstract: Natural or synthetic silica is deposited on a preform set into rotation in front of a plasma torch which moves back and forth substantially parallel to a longitudinal direction of the preform, a first feed duct feeds the plasma with grains of natural or synthetic silica while a second feed duct feeds the plasma with a fluorine or chlorine compound, preferably a fluorine compound, mixed with a carrier gas. Any sodium or lithium contained in the grains of natural or synthetic silica react with the fluorine or chlorine of the fluorine or chlorine compound, thereby making it possible to improve the optical quality of fibers drawn from a preform built up with natural or synthetic silica, and to do so at reduced cost.Type: ApplicationFiled: September 20, 2002Publication date: January 30, 2003Applicant: ALCATEL ALSTHOM COMPAGNIE GENERALE D'ELECTRICITEInventors: Alain Drouart, Benoit Gouez, Yves Lumineau, Pierre Ripoche, Jean-Forent Campion
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Publication number: 20030015004Abstract: In an apparatus for producing glass particles deposit according to the present invention, a plurality of glass particle synthesis burners are placed on a front face of a reaction vessel, and at least one exhaust port is provided on a rear face of the reaction vessel. Two wall faces extending from both sides of the exhaust port and being in contact with two side faces of the reaction vessel are provided so that its contained angle is 90 degrees or less. Assuming that the shorter distance between the shortest distance from a rotation axis of a target rod to the side face of the reaction vessel and the shortest distance from the rotation axis of the target rod to the wall face is L, and the outer diameter of the glass particles deposit deposited on the target rod is d, L is greater than d.Type: ApplicationFiled: July 18, 2002Publication date: January 23, 2003Applicant: Sumitomo Electric Industries, Ltd.Inventors: Motonori Nakamura, Takashi Yamazaki, Toshihiro Ooishi
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Publication number: 20030000260Abstract: A device for manufacturing a preform for optical fibers is described, comprising a chemical deposition chamber including at least one gripping member rotatably mounted about an axis Z-Z and adapted to hold at least one end of at least one elongated element constituting a substrate for chemical deposition for forming a preform for optical fibers. The chamber further includes at least one burner which is mobile along a direction substantially parallel to said axis Z-Z and suitable for depositing, on said at least one elongated element, a chemical substance for forming a preform, and at least one suction element arranged on the opposite side to said at least one burner with respect to said axis Z-Z and adapted to collect and discharge, from said chemical deposition chamber, exhaust chemical substances.Type: ApplicationFiled: June 24, 2002Publication date: January 2, 2003Inventors: Giacomo Stefano Roba, Franco Veronelli
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Publication number: 20020194877Abstract: Embodiments of the invention include a method for making optical fiber having reduced aging or hydrogen aging loss over the life of the fiber and optical fiber systems including such optical fibers. Improved silicon-oxygen stoichiometry during one or more preform manufacturing steps reduces the amount of Si defects generated in the optical fiber preform. Also, deuterium exposure of optical fiber drawn from the preform reduces the likelihood of having atomic defects such as Si defects in the optical fiber that, over time, attract and bond with hydrogen atoms to form molecules that contribute to increased water absorption loss. The inventive method produces optical fibers with improved transmission characteristics, e.g., optical fibers made by methods according to embodiments of the invention have transmission loss at 1385 nanometers that is less than 0.33 dB/km and the aging loss increase thereafter is less than 0.04 dB/km.Type: ApplicationFiled: June 26, 2001Publication date: December 26, 2002Inventors: Kai H. Chang, David Kalish, Thomas John Miller
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Publication number: 20020197035Abstract: The invention includes inventive methods of treating a soot preform. One method includes heating a soot preform to a temperature of less than about 1000 ° C. and exposing the preform to a substantially halide free reducing agent. Preferred reducing agents include carbon monoxide and sulfur dioxide. Another inventive method of treating the preform includes exposing the preform, in a furnace, to a substantially non-chlorine containing atmosphere comprising carbon monoxide. The preform is heated to a temperature of at least about 1000° C. Preferably this method is incorporated into the process for making an optical fiber. An additional method of treating the preform includes doping the preform with fluorine and exposing the fluorine doped preform to a substantially chlorine free atmosphere comprising at least carbon monoxide at a temperature of at least 1100° C., thereby reacting excess oxygen present in the furnace.Type: ApplicationFiled: December 12, 2001Publication date: December 26, 2002Inventors: Kintu O. Early, Claude E. Lacy, Susan L. Schiefelbein, Sabyasachi Sen, Wanda J. Walczak, Joseph M. Whalen, Tiffany L. James, Hazel B. Matthews, Chukwuemeka B. Onuh
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Publication number: 20020189298Abstract: An apparatus for manufacturing an optical fiber soot according to a VAD method, in which a cross-section shape of a combustion nozzle of a side burner for heating a core portion is rectangular. A method for manufacturing an optical fiber soot using the apparatus.Type: ApplicationFiled: November 7, 2001Publication date: December 19, 2002Applicant: The Furukawa Electric Co, Ltd.Inventors: Kiyoshi Arima, Masahide Kuwabara, Sadayuki Toda
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Patent number: 6487879Abstract: This invention relates to production of high purity fused silica glass doped with titania using titanium chelates. Useful chelates include titanium acetylacetonate, and titanium ethyl acetoacetate among others.Type: GrantFiled: December 13, 1999Date of Patent: December 3, 2002Assignee: Corning IncorporatedInventors: Jeffrey L. Blackwell, David Dasher, A. Renee Sutton, Carlton M. Truesdale
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Publication number: 20020162363Abstract: An apparatus for manufacturing an optical fiber soot, which comprises a core partition having an opening portion at core burner side provided on a periphery of a core burner, in a reactor of the apparatus to be used in a conventional VAD method.Type: ApplicationFiled: September 28, 2001Publication date: November 7, 2002Applicant: The Furukawa Electric Co., Ltd.Inventors: Hiroyuki Wada, Kiyoshi Arima, Masahide Kuwabara, Sadayuki Toda
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Publication number: 20020162359Abstract: A method for making silica includes delivering a silica precursor comprising a pseudohalogen to a conversion site and passing the silica precursor through a flame to produce silica soot.Type: ApplicationFiled: May 4, 2001Publication date: November 7, 2002Inventors: David L. Tennent, Joseph M. Whalen
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Patent number: 6477305Abstract: A cylindrical glass body having a low water content centerline region and method of manufacturing such a cylindrical glass body for use in the manufacture of optical waveguide fiber is disclosed. The centerline region of the cylindrical glass body has a water content sufficiently low such that an optical waveguide fiber made from the cylindrical glass body of the present invention exhibits an optical attenuation of less than about 0.35 dB/km, and preferably less than about 0.31 dB/km at a measured wavelength of 1380 nm. A low water content plug used in the manufacture of such a cylindrical glass body, an optical waveguide fiber having a low water peak, and an optical fiber communication system incorporating such an optical waveguide fiber is also disclosed.Type: GrantFiled: April 11, 2000Date of Patent: November 5, 2002Assignee: Corning IncorporatedInventors: George E. Berkey, Dana C. Bookbinder, Richard M. Fiacco, Cynthia B. Giroux, Daniel W. Hawtof, Dale R. Powers, V. Srikant
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Patent number: 6473226Abstract: A silica glass member is provided for use in an optical system using light of a wavelength equal to or less than about 400 nm as a light source. The silica glass member has striae in a direction different from an optical axis of the optical system. The strength of the striae is equal to or less than about 2×10−6 in terms of refractive index differential.Type: GrantFiled: June 20, 2000Date of Patent: October 29, 2002Assignee: Nikon CorporationInventors: Hiroki Jinbo, Seishi Fujiwara
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Patent number: 6463761Abstract: Fused silica boules (19) having improved radial homogeneity are produced by controlling the air flow around the boule (19) during its formation. The boule is formed in a cup-like containment vessel (13) which collects silica particles from a plurality of burners (14). The containment vessel (13) rotates and oscillates relative to the burners (14) as the boule (19) is formed. The containment vessel (13) is bounded by a cup-like containment wall (22), and a shadow or air flow wall (130) is spaced apart from and surrounds the containment wall (22) forming a gap or air flow passage (175) therebetween. A radially-outwardly extending deflecting wedge portion (23) is formed at the upper extent of the containment wall (22) and at an outlet end of flow passage (175).Type: GrantFiled: October 3, 2001Date of Patent: October 15, 2002Assignee: Corning IncorporatedInventors: Floyd E. Marley, Mahendra K. Misra, Merrill F. Sproul
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Publication number: 20020146224Abstract: A multimode optical fiber having a first laser bandwidth greater than 220 MHz.km in the 850 nm window, a second laser bandwidth greater than 500 MHz.km in the 1300 nm window, a first OFL bandwidth of at least 160 MHz.km in the 850 nm window, and a second OFL bandwidth of at least 500 MHz.km in the 1300 nm window is disclosed. The multimode fiber is capable of operating in telecommunication systems employing both LED power sources and high power laser sources. Methods of making and testing the multimode optical fiber are also disclosed.Type: ApplicationFiled: June 3, 2002Publication date: October 10, 2002Inventors: John S. Abbott, Douglas E. Harshbarger
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Patent number: 6449986Abstract: In a method of manufacturing a porous glass preform for an optical fiber which preform is formed as a deposit of fine glass particles by using a burner, a method to prevent the contamination of any glass particles having failed to be properly deposited so that the generation of voids may be minimized in a transparent glass preform which is produced by heating the porous glass preform. An inert gas is caused to flow through the burner at a rate of at least 25 m/s before fine glass particles are formed by the hydrolysis and/or oxidation of a glass material in a flame produced by the burner supplied with a mixture of a gas of the glass material and a gas for combustion and are deposited on a rotating starting member. It is desirable to elevate the pressure of the inert gas above the atmospheric pressure by a device connected to the burner by a pipeline, and cause it to flow rapidly through the burner.Type: GrantFiled: November 5, 1999Date of Patent: September 17, 2002Assignee: Sumitomo Electric Industries, Ltd.Inventors: Takashi Sugiyama, Masahiko Matsui, Nobuyuki Hirano, Naoyuki Fukushima, Takao Kabaya
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Publication number: 20020102083Abstract: Optical waveguide fiber having low water peak as well as optical waveguide fiber preforms and methods of making optical waveguide fiber preforms from which low water peak and/or low hydrogen aged attenuation optical waveguide fibers are formed, including optical waveguide fiber and preforms made via OVD. The fibers may be hydrogen resistant, i.e. exhibit low hydrogen aged attenuation. A low water peak, hydrogen resistant optical waveguide fiber is disclosed which exhibits an optical attenuation at a wavelength of about 1383 nm which is less than or equal to an optical attenuation exhibited at a wavelength of about 1310 nm.Type: ApplicationFiled: December 14, 2001Publication date: August 1, 2002Inventors: George E. Berkey, Dana C. Bookbinder, Richard M. Fiacco, Dale R. Powers
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Patent number: 6405567Abstract: A reduced dispersion optical waveguide and methods of fabricating the same are implemented. The optical waveguide may be fabricated in commercially practicable units without having to predetermine its length in a particular application. The reduced dispersion optical waveguide prevents optical pulse overlap in optical waveguide transmission systems operating over long distances or at high data rates.Type: GrantFiled: February 4, 2000Date of Patent: June 18, 2002Assignee: International Business Machines CorporationInventors: Mitchell Levy Loeb, Samuel Elbert Wallace
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Publication number: 20020062666Abstract: A plurality of glass particle synthesizing burners are disposed opposite to a rotating starting rod. The starting rod and the glass particle synthesizing burners are relatively reciprocally moved to each other in parallel to the axial direction, so that glass particles synthesized by the burners are sequentially deposited on the surface of the starting rod. The movement is stopped and restarted repeatedly once or more than once during one reciprocal movement.Type: ApplicationFiled: November 29, 2001Publication date: May 30, 2002Inventors: Toshihiro Ooishi, Yuichi Ohga, Yoshio Yokoyama, Motonori Nakamura
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Patent number: 6378337Abstract: A method for preparing high-purity, bulk fused silica includes supplying silane gas, a gaseous fuel, and oxygen gas to a combustion burner. Silica particles are formed by passing the silane gas into a flame formed by the combustion reaction of the gaseous fuel with the oxygen gas while maintaining the ratio of the flow rate of the gaseous fuel to the flow rate of the silane gas no less than twelve and the ratio of the flow rate of the gaseous fuel to the flow rate of the oxygen gas no less than three. The silica particles formed are immediately deposited onto a hot bait to form a boule.Type: GrantFiled: September 15, 2000Date of Patent: April 30, 2002Assignee: Corning IncorporatedInventors: John T. Brown, Michael S. Dobbins, Christine E. Heckle, Robert E. McLay, Mahendra K. Misra, Dale R. Powers, Michael H. Wasilewski
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Patent number: 6374642Abstract: An apparatus for producing a glass soot includes a first a burner having a droplet-emitting first region, a gas-emitting second region surrounding the first region, and a gas-emitting third region surrounding the second region. The first region emits a glass-forming mixture, the second region emits an inert gas, and the third region emits a combination of oxygen and a combustible gas. The apparatus further includes a combustion area having a first section proximate the first burner and a second section distal from the first burner. A glass-forming mixture is at least partially vaporized in the first section of the combustion area. The apparatus further includes at least one secondary burner having gas-emitting fourth and fifth regions. The fourth region of the secondary burner emits oxygen and the fifth region of the secondary burner emits a combustible gas.Type: GrantFiled: March 15, 2000Date of Patent: April 23, 2002Assignee: Corning IncorporatedInventors: Jeffrey L. Blackwell, Lisa A. Moore, Huailiang Wei, Daniel W. Hawtof
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Patent number: 6376401Abstract: A synthetic silica glass having a high transmittance for vacuum ultraviolet rays, for example F2 excimer laser beam with a wavelength of 157 nm, a high uniformity and a high durability and useful for ultraviolet ray-transparent optical glass materials is produced from a high-purity silicon compound, for example silicon tetrachloride, by heat treating an accumulated porous silica material at a temperature not high enough to convert the porous silica material to a transparent silica glass in an inert gas atmosphere for a time sufficient to cause the OH groups to be condensed and removed from the glass, and exhibits substantially no content of impurities other than OH group a difference between highest and lowest fictional temperatures of 50° C.Type: GrantFiled: September 1, 1999Date of Patent: April 23, 2002Assignees: Tosoh Corporation, Nippon Silica Glass Co., Ltd., Yamaguchi Nippon Silica Glass Co., Ltd.Inventors: Shinichi Kondo, Takayuki Nakamura, Kazuhiko Fukuda, Naoyoshi Kamisugi, Nobu Kuzuu, Yoshinao Ihara, Hidetoshi Wakamatsu
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Patent number: 6376010Abstract: The present invention is directed to a silica forming feedstock and a method of making optical waveguides and optical waveguide preforms. The feedstock for use in the manufacturing of germanium doped silica glass products includes a siloxane and a germanium dopant component such as germanium alkoxide. The invention further relates to the manufacturing of optical waveguides and optical waveguide preforms using a fluid feedstock which includes a siloxane and germanium dopant component, preferably germanium alkoxide.Type: GrantFiled: June 16, 1998Date of Patent: April 23, 2002Assignee: Corning IncorporatedInventors: Jeffery Lynn Blackwell, Lisa Anne Moore, Carlton Maurice Truesdale
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Publication number: 20020043079Abstract: An apparatus for fabricating a soot preform for an optical fiber. The soot preform is fabricated by depositing glass particles on a starting rod capable of being rotated and pulled up. The apparatus comprises elements as follows. A reaction chamber is used for depositing the glass particles on the starting rod. An upper room is located above the reaction chamber for receiving the soot preform formed in the upper portion of the reaction chamber. At least one core burner is installed in the reaction chamber. A gas-supplying inlet is located in the top part of the sidewall of the reaction chamber closest to burner(s), and a gas-exhausting outlet is located in the top part of another sidewall opposite to the gas-supplying inlet. In addition, at least one cladding burner is installed in the reaction chamber.Type: ApplicationFiled: October 10, 2001Publication date: April 18, 2002Inventors: Dai Inoue, Go Ogino, Tetsuya Otosaka, Tadakatsu Shimada, Hideo Hirasawa
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Patent number: 6354112Abstract: A method and apparatus for producing a glass base material for an optical fiber. A material for an optical fiber and a reaction gas are jetted from a burner connected to a material line and a gas line toward a surface of a quartz substrate, in order to deposit a soot-like reaction product on the substrate at a predetermined position to thereby produce a glass base material for an optical fiber. Dry air is introduced into a reaction container in an amount of 4 to 8 times the amount of water vapor that is generated due to flame hydrolysis during the reaction.Type: GrantFiled: December 2, 1998Date of Patent: March 12, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yasuhiro Nakashima, Tadakatsu Shimada, Hideo Hirasawa
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Patent number: 6351972Abstract: There is disclosed a method for producing a synthetic fused silica member comprising vaporizing a raw material silane compound, hydrolyzing or oxidizing by combustion the vaporized silane compound in oxyhydrogen flame to form silica microparticles so that the silica microparticles should deposit on a rotating refractory carrier, and melting the silica microparticles during the deposition to form the synthetic fused silica member, wherein sulfur impurities are preliminarily removed from the raw material.Type: GrantFiled: July 8, 1999Date of Patent: March 5, 2002Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Hisatoshi Ohtsuka
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Publication number: 20020020193Abstract: A method for manufacturing a base material for an optical fiber, includes steps of: holding a bar material by a support member; and adjusting to reduce a difference between an axis of the bar material and a rotational axis of the support member. Furthermore, an optical fiber base material grasping apparatus for holding a bar material having an axis, includes: a support member having a center axis, the support member being rotatable around the center axis; and an adjusting mechanism for reducing a difference between the axis of the bar material and the central axis of the support member.Type: ApplicationFiled: December 1, 2000Publication date: February 21, 2002Inventors: Tadakatsu Shimada, Dai Inoue, Hiroshi Oyamada, Kazuhisa Hatayama, Hiroshi Machida, Tetsuya Otosaka, Fumio Saitoh, Yasuhiro Nakashima, Takeshi Kamio, Masami Terashima, Isao Arisaka, Shoichiro Kemmochi, Hideo Hirasama
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Publication number: 20020005051Abstract: Methods, apparatus and precursors for producing substantially water-free silica soot, preforms and glass. The methods and apparatus make substantially water-free fused silica preforms or glass by removing water as a reaction product, removing water from the atmosphere, removing water from the transport process, or combinations thereof. In a first embodiment, substantially water-free soot, preforms or glass are achieved by using a hydrogen-free fuel, such as carbon monoxide, in the deposition process. In another embodiment, a soot producing burner has parameters that enable operation on a substantially hydrogen-free fuel. End burners, which minimize water production, are also described. Such water-free methods are useful in depositing fluorine-doped soot because of the low water present and the efficiency in which fluorine is incorporated. In another embodiment, glassy barrier layer methods and apparatus are described for minimizing dopant migration, especially fluorine.Type: ApplicationFiled: April 11, 2001Publication date: January 17, 2002Inventors: John T. Brown, Gerald E. Burke, Lisa C. Chacon, Steven B. Dawes, Adam J. Ellison, Daniel W. Hawtof, Anthony P. Luppino, V. Srikant, Pushkar Tandon, Christine L. Tennent, James P. Terrell, Joseph M. Whalen
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Patent number: 6336347Abstract: A process for producing a high-purity optical silica preform, comprising (a) vaporization of an organosilicon compound; (b) thermal decomposition of the said organosilicon compound in the vapor state, to give amorphous fused silica particles; (c) deposition of the said amorphous fused silica particles on a support, in which the said organosilicon compound has the formula (I) in which R1, R2, R3 and R4 have the meanings given in the text.Type: GrantFiled: December 27, 1999Date of Patent: January 8, 2002Assignee: Pirelli Cavi e Sistemi S.p.A.Inventors: Giacomo Stefano Roba, Marco Arimondi
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Patent number: 6334339Abstract: A hooded glass particulate synthesizing torch, provided with at least a glass particulate synthesizing torch body having a feedstock gas injection passage formed at the center of its front end, a combustible gas injection passage formed concentrically at the outer circumference of the feedstock gas injection passage, and a plurality of small diameter combustion aid gas injection passages formed in the combustible gas injection passage along the outer circumference of the feedstock gas injection passage and a hood projecting out at the outer circumference of the front end of the torch body, the torch hood satisfying 0.5≦D/L≦2.0, where, L is the focal distance, that is, a distance from a point P, to which the small diameter combustion aid gas injection passages are directed and on an extension of the center line of the torch body in front of the torch body, to the front end of the torch body, and D is the hood length, that is, the distance from the front end of the hood to the front end of the torch body.Type: GrantFiled: June 22, 2000Date of Patent: January 1, 2002Assignee: The Furukawa Electric Co., Ltd.Inventors: Akihiro Kanao, Toshihiro Mikami
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Publication number: 20010047666Abstract: In a method of manufacturing a porous glass preform for an optical fiber which preform is formed as a deposit of fine glass particles by using a burner, a method to prevent the contamination of any glass particles having failed to be properly deposited so that the generation of voids may be minimized in a transparent glass preform which is produced by heating the porous glass preform. An inert gas is caused to flow through the burner at a rate of at least 25 m/s before fine glass particles are formed by the hydrolysis and/or oxidation of a glass material in a flame produced by the burner supplied with a mixture of a gas of the glass material and a gas for combustion and are deposited on a rotating starting member. It is desirable to elevate the pressure of the inert gas above the atmospheric pressure by a device connected to the burner by a pipeline, and cause it to flow rapidly through the burner.Type: ApplicationFiled: November 5, 1999Publication date: December 6, 2001Inventors: TAKASHI SUGIYAMA, MASAHIKO MATSUI, NOBUYUKI HIRANO, NAOYUKI FUKUSHIMA, TAKAO KABAYA
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Publication number: 20010041038Abstract: There is provided a dispersion-managed fiber preform and a fabricating method thereof preform by modified chemical vapor deposition (MCVD). A core and a clad having the refractive index distribution of an optical fiber with a positive dispersion value are uniformly deposited in a glass tube. The preform with the positive dispersion value is heated at every predetermined period with a torch and the heated preform portions are etched to have a negative dispersion value. Then, the preform alternately having positions with the positive dispersion value and positions with the negative dispersion value along the length direction is collapsed.Type: ApplicationFiled: January 16, 2001Publication date: November 15, 2001Inventors: Jae-Deuk Lee, Yong-Woo Park, Ghie-Hugh Song, Un-Chul Paek, Mun-Hyun Do
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Patent number: 6314766Abstract: Fused silica boules (19) having improved radial homogeneity are produced by controlling the air flow around the boule (19) during its formation. The boule is formed in a cup-like containment vessel (13) which collects silica particles from a plurality of burners (14). The containment vessel (13) rotates and oscillates relative to the burners (14) as the boule (19) is formed. The containment vessel (13) is bounded by a cup-like containment wall (22), and a shadow or air flow wall (130) is spaced apart from and surrounds the containment wall (22) forming a gap or air flow passage (175) therebetween. A radially-outwardly extending deflecting wedge portion (23) is formed at the upper extent of the containment wall (22) and at an outlet end of flow passage (175).Type: GrantFiled: January 19, 2000Date of Patent: November 13, 2001Assignee: Corning IncorporatedInventors: Floyd E. Marley, Mahendra K. Misra, Merrill F. Sproul
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Patent number: 6306500Abstract: There is disclosed a method for producing a porous optical fiber base material comprising depositing fine glass powder on a rotating member, wherein pore size of the deposited fine glass powder is controlled, and preferably, mode of the pore size is controlled to be 0.1 to 1 &mgr;m, or wherein a total amount of absorbed H2O amount and OH group amount on the fine glass powder per square meter of fine glass powder surface area is controlled to be 3.5×10−5 to 7.5×10−5 g. Such porous optical fiber base materials have an improved weight of fine glass powder deposited on the member per batch, or an improved fine glass powder deposit efficiency, which may greatly contribute to improvement of production ability and reduction of production cost.Type: GrantFiled: July 28, 1999Date of Patent: October 23, 2001Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Haruyoshi Kuwabara, Tadakatsu Shimada, Hideo Hirasawa
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Patent number: 6301936Abstract: The object of the invention is to provide an apparatus for manufacturing a porous glass preform, which comprises a reaction vessel in which local stress concentration caused by expansion due to heat is prevented, and there is no fear of the occurrence of deformation or cracks. The apparatus of this invention manufactures the porous glass preform by depositing glass particles blown from a burner on the seed rod rotating around its axis, and this apparatus is characterized in that the reaction vessel is provided with a means for relieving concentration of stress due to thermal expansion of the reaction vessel.Type: GrantFiled: June 17, 1999Date of Patent: October 16, 2001Assignee: Sumitomo Electric Industries, Ltd.Inventors: Yuichi Ohga, Takashi Kogo
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Publication number: 20010018834Abstract: A process for producing synthetic quartz glass using a burner composed of a plurality of concentric nozzles involves the steps of feeding a silica-forming raw material gas and a fluorine compound gas to a reaction zone from a center nozzle, feeding oxygen gas from a second nozzle outside the center nozzle, and feeding oxygen gas and/or hydrogen gas from a third nozzle. The silica-forming raw material gas is hydrolyzed to form fine particles of silica, which particles are deposited on a rotatable substrate so as to form a porous silica matrix, which is then fused to give the quartz glass. The flow rate of the oxygen gas fed from the second nozzle and the flow rate of the raw material gas are controlled so as to provide a 1.1- to 3.5-fold stoichiometric excess of oxygen. The excess oxygen suppresses Si—Si bond formation in the quartz glass, enabling the production of synthetic quartz glass having a high transmittance in the vacuum ultraviolet region.Type: ApplicationFiled: December 27, 2000Publication date: September 6, 2001Inventors: Koji Matsuo, Hisatoshi Otsuka, Kazuo Shirota
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Publication number: 20010013232Abstract: A method and apparatus for producing a glass base material for an optical fiber. A material for an optical fiber and a reaction gas are jetted from a burner connected to a material line and a gas line toward a surface of a quartz substrate, in order to deposit a soot-like reaction product on the substrate at a predetermined position to thereby produce a glass base material for an optical fiber. Dry air is introduced into a reaction container in an amount of 2 to 30 times the amount of water vapor that is generated due to flame hydrolysis during the reaction.Type: ApplicationFiled: December 2, 1998Publication date: August 16, 2001Inventors: YASUHIRO NAKASHIMA, TADAKATSU SHIMADA, HIDEO HIRASAWA
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Patent number: 6266980Abstract: Disclosed is a method of minimizing re-wetting of a preform upon removal of the preform from the consolidation furnace and producing core cane and/or optical fiber therefrom. During removal, the consolidated preform and, in particular, the centerline aperture is exposed to a heavy inert gas, such as Argon, Krypton or Xenon. This reduces the amount of re-wetting thereby concomitantly improving attenuation of the optical fiber produced therefrom. This method produces beneficial attenuation reductions in the 1383 nm wavelength region.Type: GrantFiled: October 28, 1999Date of Patent: July 31, 2001Assignee: Corning IncorporatedInventors: Lisa N. Lemon, Stephen T. Wiggs
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Patent number: 6260385Abstract: A method and a burner for manufacturing silica-containing soot is disclosed. The method includes providing a liquid silicon-containing feedstock and a gas mixture and ejecting the liquid-gas mixture from an orifice into a combustion site to convert the silica-containing feedstock into silica containing soot. The burner includes a plurality of channels for delivering a gas to provide a flame, an effervescent atomizer for atomizing a liquid, silicon-containing feedstock and a rail for guiding the atomized liquid, silicon-containing feedstock into the burner flame. The method and burner can be used to produce silica-containing articles such as high purity fused silica optical members and waveguides.Type: GrantFiled: April 15, 1999Date of Patent: July 17, 2001Assignee: Corning IncorporatedInventors: Daniel R. Sempolinski, Michael H. Wasilewski, C. Charles Yu
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Patent number: 6189339Abstract: A method for producing a silica glass for photolithography, which comprises the following steps: jetting a starting material gas, an oxygen gas and a hydrogen gas from a burner and depositing and consolidating silica glass powder on a target to form an ingot having a growing direction, where the ingot is grown in such a manner that at least a part of glass synthesis face on the ingot having the silica glass powder deposited and consolidated is a plane substantially perpendicular to the growing direction of the ingot, thereby to obtain the ingot having a portion in which striae are substantially perpendicular to the growing direction of the ingot; and cutting out of the ingot the portion in which the striae are substantially perpendicular to the growing direction of the ingot, thereby to obtain a silica glass having striae which are substantially parallel to each other and are planar.Type: GrantFiled: March 28, 1996Date of Patent: February 20, 2001Assignee: Nikon CorporationInventor: Hiroyuki Hiraiwa
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Patent number: 6145345Abstract: The deposition rate of MCVD processes is enhanced by applying at least a first and a second independently controlled heat source to a plurality of reactants which are used to form deposited particulate matter. The first heat source is adjusted so as to provide at least a specified rate of reaction for the reactants, and the second source is adjusted so as to provide at least a specified deposition rate for the particulate matter.Type: GrantFiled: June 5, 1998Date of Patent: November 14, 2000Assignee: Lucent Technologies Inc.Inventors: Stanley F. Marszalek, Katherine Theresa Nelson, Kenneth Lee Walker, Kim Willard Womack, Man Fei Yan
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Patent number: 6145344Abstract: Proposed is an improvement in the VAD process for the preparation of a porous silica glass preform for double-core optical fibers by using three oxyhydrogen flame burners installed one above the other in a flame hydrolysis chamber in which a porous silica glass body consisting of the center core portion formed by the lowermost burner, side core portion formed by the middle burner and the cladding layer formed by the uppermost burner is gradually pulled up as it grows under rotation. Different from conventional procedures in which the extension of the nozzle axis of each of the burners intersects with the rotation axis of the growing body, the extension of the nozzle axis of the middle burner for the side core is displaced in a horizontal direction by a limited distance not to intersect nor to be in parallel with the rotation axis in the invention. By this means, an improvement is obtained in the uniformity of distribution of the refractive index in the side core which otherwise is remarkably disordered.Type: GrantFiled: August 2, 1994Date of Patent: November 14, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hiroshi Oyamada, Hiroyuki Koide, Goh Ogino, Hideo Hirasawa
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Patent number: 6131415Abstract: A singlemode optical fiber 700 having very low loss at 1385 nm, and a practical method for making same are disclosed. A core rod 20 is fabricated using vapor axial deposition to have a deposited cladding/core ratio (D/d) that is less than 7.5. The core rod is dehydrated in a chlorine- or fluorine-containing atmosphere at about 1200.degree. C. to reduce the amount of OH present to less than 0.8 parts per billion by weight, and then consolidated in a helium atmosphere at about 1500.degree. C. to convert the porous soot body into a glass. The consolidated core rod is elongated using an oxygen-hydrogen torch that creates a layer of OH ions on the surface of the rod that are largely removed by plasma etching. Finally, the core rod is installed in a glass tube 40 having a suitably low OH content. Thereafter, the tube is collapsed onto the rod to create a preform 60. Conventional methods are employed for drawing an optical fiber from the preform and applying one or more protective coatings 75, 76.Type: GrantFiled: June 20, 1997Date of Patent: October 17, 2000Assignee: Lucent Technologies Inc.Inventors: Kai Huei Chang, David Kalish, Thomas John Miller, Michael L. Pearsall
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Patent number: 6079225Abstract: In a known method, a quartz glass preform is produced by supplying a glass-forming base material in liquid form to an injection nozzle of a multi-nozzle flame deposition burner, vaporizing or gasifying the liquid glass-forming base material in the deposition burner, mixing the vaporized or gasified glass-forming base material with a gas containing oxygen under creation of SiO.sub.2 particles in a chemical reaction, deposition of the SiO.sub.2 particles on a substrate under creation of a porous preform and sintering of the preform. In this method, expensive devices such as pumps and ultrasonic vaporizers are needed for the vaporization of the liquid glass-forming base material; in addition, these devices are subject to mechanical wear and chemical attack and furthermore, they require extensive maintenance and due to their size result in a great height of construction.Type: GrantFiled: June 18, 1998Date of Patent: June 27, 2000Assignee: Heraeus Quarzglas GmbH & Co. KGInventors: Klaus Ruppert, Anton Steinkohl