Forming Optical Fiber Or Fiber Preform By Soot Buildup (i.e., Vapor Axial Deposition, Vad) Patents (Class 65/414)
  • Patent number: 6047564
    Abstract: In a known process for the production of quartz glass bodies, SiO.sub.2 particles are deposited of the mantle surface of a cylindrical carrier rotating about its longitudinal axis, forming an elongated, porous preform, where the SiO.sub.2 particles are formed in a plurality of flame hydrolysis burners which are arranged in at least one burner row parallel to the longitudinal axis of the carrier and are moved at a preset translational speed forward and back between turnaround points at which points their direction of movement is reversed, and in which process the preform is sintered. In order to make available on this basis an easily accomplished process that makes it possible to manufacture a preform which is largely free of localized density variations, the invention proposes on the one hand that the base value of the surface temperature of the preform being formed be kept in a range between 1,050.degree. C. and 1,350.degree. C.
    Type: Grant
    Filed: March 3, 1998
    Date of Patent: April 11, 2000
    Assignee: Heraeus Quarzglas GmbH
    Inventors: Hartwig Schaper, Klaus Ruppert
  • Patent number: 6044664
    Abstract: An apparatus is provided for synthesizing a silica glass ingot. The appartus includes a stage having a target plate thereover, the target plate being rotatable relative to the stage around a predetermined vertical axis, and a furnace for reacting material gas with combustion gas to synthesize the silica glass ingot on the target plate; the furnace having an opening at its bottom. The appratus further includes an elevation system that moves the stage in a vertical direction parallel to the predetermined vertical axis so as to vertically move the target plate through the opening of the furnace, the elevation system supporting the stage from at least one side of the stage and lacking a structure directly below the stage that would substantially interfere with the vertical movement of the stage.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: April 4, 2000
    Assignee: Nikon Corporation
    Inventors: Shouji Yajima, Norihisa Yamaguchi, Kazuhiro Nakagawa, Hiroki Jinbo
  • Patent number: 6018964
    Abstract: A method for manufacturing quartz glass in a flame hydrolysis reaction inside a furnace, including the steps of mixing a gas containing Si, a combustion-supporting gas, and a combustible gas and discharging this mixed gas from a burner; producing a quartz glass powder by causing the mixed and discharged gases to react in a flame within the furnace while an opening area of an opening and shutting system of the furnace is controlled; and producing a quartz glass ingot by depositing and vitrifying the quartz glass powder on a target surface facing an interior of the furnace, wherein said producing step includes the step of controlling the opening area of the opening and shutting system of the furnace in accordance with the amount of growth of the ingot on the target surface.
    Type: Grant
    Filed: February 27, 1998
    Date of Patent: February 1, 2000
    Assignee: Nikon Corporation
    Inventors: Shouji Yajima, Hiroki Jinbo
  • Patent number: 6012305
    Abstract: An apparatus for producing an optical fiber porous glass preform using the VAD method which can stably produce a high quality optical fiber porous glass preform, wherein a target bar is only rotatably supported by a chuck and is not pulled upward, a lower tip of a soot body is detected by a laser and a photodetector, and a core burner and a cladding burner is lowered in response to the result detected. A tip position detecting drive and burners are synchronizingly lowered while the deposit of porous glass grows at the lower portion of the target bar.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: January 11, 2000
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Masahide Kuwabara, Tetsuro Wada, Yukio Komura
  • Patent number: 5979185
    Abstract: The present invention is directed to a method for making silica glass and silica glass preforms. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO.sub.2 is provided and introduced directly into the flame of a combustion burner, which converts the compound to silica, thereby forming finely divided amorphous soot. The soot is vaporized proximate the site where the liquid is converted into silica glass by atomizing the liquid, preferably with a stream of atomizing gas. A heater proximate the burner face and around the burner flame increases soot capture rate and allows for a reduction of the velocity of the atomizing gas. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass.
    Type: Grant
    Filed: June 3, 1998
    Date of Patent: November 9, 1999
    Assignee: Corning Incorporated
    Inventors: Jeffery L. Blackwell, Xiaodong Fu, Daniel W. Hawtof, Danny L. Henderson
  • Patent number: 5970751
    Abstract: A method of producing, by flame hydrolysis, a fused silica glass containing titania which comprises delivering a mixture of a silica precursor and a titania precursor in vapor form to a flame, passing the vapor mixture through the flame to form SiO.sub.2 --TiO.sub.2 particles, and depositing the particles within a furnace where they melt to form a solid glass body.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: October 26, 1999
    Assignee: Corning Incorporated
    Inventors: John E. Maxon, Robert S. Pavlik, Jr., Daniel R. Sempolinski, Michael H. Wasilewski
  • Patent number: 5951730
    Abstract: Fused silica boules (19) having improved off-axis homogeneity are produced by controlling the air flow around the boule (19) during its formation. The boule is formed in a containment vessel (13) which collects soot from a plurality of burners (14). The containment vessel (13) rotates and oscillates relative to the burners (14) as the boule (19) is formed. Surrounding the containment vessel (13) is an air flow wall (130) which oscillates with the containment vessel (13). The air flow wall (130) is spaced from the containment vessel (13) by a gap (175) through which air flows during boule formation. The dimensions of this gap (175) remain constant as the boule is formed. Surrounding the air flow wall (130) is a stationary wall (160). The stationary wall (160) is spaced from the air flow wall (130) by a gap (165) whose dimensions change as the boule is formed. A motion accommodating seal (155) blocks air flow in this gap (165).
    Type: Grant
    Filed: May 1, 1998
    Date of Patent: September 14, 1999
    Assignee: Corning Incorporated
    Inventor: Paul M. Schermerhorn
  • Patent number: 5895515
    Abstract: In a soot-deposition container, raw material gas and at the tip of a starting glass rod, combustion gas, and carrier gas are supplied to a core-depositing burner and raw material gas, combustion gas, carrier gas, and gas for doping of fluorine are supplied to a cladding-depositing burner, thereby forming porous glass soot comprised of glass soot for core and glass soot for cladding. With growth of soot, the supply amount of the fluorine-doping gas is increased while supply amounts of the other gases are kept constant. Next, dehydration process and transparentizing process of soot are carried out to obtain a glass preform for optical fiber. Fabricated in this way is the glass preform for optical fiber having the silica glass portion doped with low-concentration fluorine with high uniformity in the growth direction.
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: April 20, 1999
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Shinji Ishikawa, Masumi Ito, Sumio Hoshino
  • Patent number: 5837024
    Abstract: An essentially cylindrical porous blank is formed by the deposition of SiO.sub.2 particles onto the lateral cylindrical surface of a cylindrical mandrel, rotating around its longitudinal axis; this blank is provided with a holding element of quartz glass in the form of a hollow body, which surrounds a section of the mandrel and which is at least partially embedded in the area of one of the ends of the blank. The blank is then sintered. In order to securely support even heavy blanks without complicated holding devices, the holding element is fused into the area of at least one of the ends of the blank during the deposition process by the maintenance of a high temperature.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: November 17, 1998
    Assignee: Heraeus Quarzglas GmbH
    Inventor: Heinz Fabian
  • Patent number: 5788730
    Abstract: A silicon-containing glass starting material is fed through a central area of a multi-nozzle burner head while the fuel gases are fed through an outer area surrounding the center. In a reaction zone near the burner head, fine SiO.sub.2 soot particles are formed, which are deposited on a carrier to build up a porous soot body, which is then sintered. During the process of building up the soot body, the fuel gas stream is varied to achieve a desired radial or axial density profile in the soot body. To separate the glass starting material from the fuel gas in the area extending from the burner head to the reaction zone, a barrier gas stream is provided between the burner gas stream and the stream of glass starting material. The burner head has a central, tubular nozzle and several ring nozzles arranged coaxially around it. Between the central nozzle and the ring nozzles, a ring-shaped barrier gas nozzle is provided, which has inner and outer boundary walls which are circular in radial cross section.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: August 4, 1998
    Assignee: Heraeus Quarzglas GmbH
    Inventors: Klaus Ruppert, Anton Steinkohl
  • Patent number: 5735921
    Abstract: The invention relates to the production of high purity fused silica glass which is highly resistant to 248 nm excimer laser-induced optical damage. In particular, this invention relates to a fused silica optical member or blank.
    Type: Grant
    Filed: December 10, 1996
    Date of Patent: April 7, 1998
    Assignee: Corning Incorporated
    Inventors: Roger J. Araujo, Nicholas F. Borrelli, Christine L. Hoaglin, Charlene Smith
  • Patent number: 5696038
    Abstract: Oscillation/rotation patterns for improving the off-axis homogeneity of fused silica boules are provided. The patterns reduce the optical effects of periodic off-axis striae by decreasing the ratio of .DELTA.n.sub.striae to .DELTA.z.sub.striae, where .DELTA.n.sub.striae is the average peak-to-valley magnitude of the striae and .DELTA.z.sub.striae is their average peak-to-peak period. The oscillation/rotation patterns have long repeat periods and cause soot-producing burners to trace out substantially spiral-shaped patterns on the surface of the boule.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: December 9, 1997
    Assignee: Corning Incorporated
    Inventor: John E. Maxon
  • Patent number: 5676725
    Abstract: A method of manufacturing an optical fiber in which the deviation of a cutoff wavelength from a design value can be minimized. It is found that, upon diameter reduction of a porous core glass body by heat treatment, when the diameter reduction ratio is set to a value larger than 0.90, a "spike" in the refractive index distribution curve of a core can be prevented, and the deviation of the cutoff wavelength from the design value can be minimized. Therefore, there is provided a method comprising the first step of depositing fine SiO.sub.2 particles and fine GeO.sub.2 particles, which are produced by a core formation burner, to grow a porous core glass body from a distal end of a rotating starting rod in an axial direction, the second step of performing diameter reduction by heating the grown porous core glass body by heating means while growing the porous core glass body, and the third step of depositing fine SiO.sub.
    Type: Grant
    Filed: March 29, 1996
    Date of Patent: October 14, 1997
    Assignee: Sumitomo Electric Industries Ltd
    Inventors: Masumi Ito, Sumio Hoshino, Toshio Danzuka
  • Patent number: 5599371
    Abstract: A precision burner for oxidizing halide-free, silicon-containing compounds, such as, octamethyl-cyclotetrasiloxane (OMCTS), is provided. The burner includes a subassembly (13) which can be precisely mounted on a burner mounting block (107) through the use of an alignment stub (158), a raised face (162) on the burner mounting block (107), and a recess (160) in the back of the subassembly (13). The burner's face includes four concentric gas-emitting regions: a first central region (36, 90) from which exits a mixture of OMCTS and O.sub.2, a second innershield region (38, 92) from which exits N.sub.2, a third outershield region (40, 42, 94, 96) from which exits O.sub.2, and a fourth premix region (44, 98) from which exits a mixture of CH.sub.4 and O.sub.2. The burner provides more efficient utilization of halide-free, silicon-containing raw materials than prior burners.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: February 4, 1997
    Assignee: Corning Incorporated
    Inventors: Michael B. Cain, Robert B. Desorice, William J. Kiefer, Dale R. Powers
  • Patent number: 5558693
    Abstract: Low attenuation, low dispersion of optical waveguides are provided by a process initiating with axial deposition of a high velocity core soot stream impinging on, a target at a high angle of incidence relative to the axis of rotation of the target. A core cylinder is built up axially by relative movement between the soot stream and target during deposition, the movement being non-constant in order to maintain a substantially constant diameter with a constant deposition rate. A cladding layer is then built up by deposition of soot radially on the core. Subsequent drying and sintering provides a vitreous preform which may be drawn directly into optical waveguides. Alternatively, the sintered product may be drawn down to smaller rods, which then are covered with further deposited soot cladding to a desired final thickness, and after further drying and sintering may be drawn to optical waveguides.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: September 24, 1996
    Assignee: SpecTran Communications Fiber Technologies, Inc.
    Inventor: Arnab Sarkar
  • Patent number: 5522007
    Abstract: A method of using a plasma to build up an optical fiber preform consists in injecting hydroxyl ions in a controlled manner into the build-up silica that is deposited on the preform. The invention is applicable to the manufacture of optical fibers, in particular monomode fibers.
    Type: Grant
    Filed: December 12, 1994
    Date of Patent: May 28, 1996
    Assignee: Alcatel Fibres Optiques
    Inventors: Alain Drouart, Benoit Gouez, Bernard Jouvenel, Yves Lumineau, Max Matau, Pierre Ripoche
  • Patent number: 5518516
    Abstract: In a method of forming a preform from which an optical fibre can be drawn, successive layers of matter (24, 28) are deposited by vapour deposition on a rotating cylindrical body (10) which is traversed by a heat source (15). For the deposition of at least two successive layers (24, 28), a rate of rotation of the body and/or a rate of traverse of the heat source is selected so as to generate in one of said layers a surface profile different to a surface profile generated in the other said layer.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: May 21, 1996
    Assignee: Pirelli General plc
    Inventor: Cheryl J. Garnham
  • Patent number: 5425795
    Abstract: An improvement is proposed in the process for the preparation of a porous silica glass preform as a precursor of optical fibers by the VAD method, in which fine silica particles produced by the flame hydrolysis of a silicon-containing compound are deposited on the lower end of a seed rod suspended at the lower end of a suspender rod rotated by a carriage in a vertical tubular reactor furnace to grow in the vertical direction. Instead of taking the fully grown porous preform out of the tubular furnace by pulling up as suspended on the suspender rod as is undertaken in the prior art, the seed rod is temporarily held by clamping with a holding device with disconnection from the suspender rod and the porous preform and seed rod are pulled up by a separate vertical driving device so that the overall height of the apparatus can be greatly decreased contributing to a reduction of the manufacturing cost of optical fibers of silica glass.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: June 20, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiroyuki Koide, Masami Terashima, Hideo Hirasawa, Kazuhiro Hamaguchi
  • Patent number: 5395413
    Abstract: A method of producing a fused silica product comprising introducing a silicon-containing, organometallic compound into a flame to form molten silica particles, and collecting the molten silica particles in a furnace having a crown and cup such that a fused silica product is obtained, wherein at least the furnace crown is formed from a porous, fired, zircon refractory having a sodium ion content of less than 30 ppm. The fused silica product produced by the method has a sodium ion contamination level below 100 parts per billion.
    Type: Grant
    Filed: December 16, 1993
    Date of Patent: March 7, 1995
    Assignee: Corning Incorporated
    Inventors: Daniel R. Sempolinski, Latha I. Swaroop
  • Patent number: 5356451
    Abstract: Disclosed is a method and apparatus for providing reactant vapors to a utilization site. The apparatus includes a vaporization chamber enclosed by top and bottom walls, side walls and first and second end walls. The first end wall is elevated with respect to the second end wall. The reactant is supplied in liquid form to a flow distributor that delivers the liquid to that portion of the bottom wall near the first end wall. The angle with which the bottom wall is inclined with respect to horizontal is sufficient to cause the liquid to flow down the bottom wall at a rate sufficient to form a film, the thickness of which is smaller than that thickness which would support a bubble during heating of the film. The surface is heated to a temperature greater than the boiling point of the liquid, thereby converting the liquid reactant to a vapor that is delivered to the vapor utilization site.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: October 18, 1994
    Assignee: Corning Incorporated
    Inventors: Michael B. Cain, Michael S. Dobbins
  • Patent number: 5338327
    Abstract: A glass preform for an optical fiber is flame abrased with an oxyhydrogen flame while vertically suspending and rotating the glass preform and relatively moving one or both of the glass preform and the oxyhydrogen flame, whereby a surface of the glass preform is smoothened.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: August 16, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yuichi Ohga, Toshio Danzuka, Masahide Saito, Kouji Amemiya, Hiroshi Yokota