Oxide Of Aluminum(al), Beryllium(be), Magnesium(mg), Alkaline Earth Metal, Scandium(sc), Yttrium(y), Lanthanide Metal, Actinide Metal, Titanium (ti), Zirconium(zr), Or Hafnium(hf) Patents (Class 75/235)
  • Patent number: 5350628
    Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: September 27, 1994
    Assignee: Matsushita Electric Industrial Company, Inc.
    Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
  • Patent number: 5326526
    Abstract: Sintered iron alloy composition and method of manufacturing the same, the sintered alloy composition comprising: about 1.5 to about 2.5% carbon by weight; about 0.5 to about 0.9% manganese by weight; about 0.1 to about 0.2% sulfur by weight; about 1.9 to about 2.5% chromium by weight; about 0.15 to about 0.3% molybdenum by weight; about 2 to about 6% copper by weight; not more than about 0.3% by weight of a metal element material comprising at least one member selected from the group consisting of tungsten and vanadium; an effective content of a first solid lubricant material comprising at least one member selected from the group consisting of magnesium metasilicate minerals and magnesium orthosilicate minerals; and balance iron. This alloy composition is preferably used for making machine parts, such as slide members of valve operating systems for internal combustion engines.
    Type: Grant
    Filed: September 30, 1991
    Date of Patent: July 5, 1994
    Assignees: Hitachi Powdered Metals Co., Ltd., Nissan Motor Co., Ltd.
    Inventors: Yutaka Ikenoue, Koichiro Hayashi, Makoto Kano, Akira Fujiki
  • Patent number: 5320782
    Abstract: Acicular or platy titanium suboxides, expressed by the general formula, TiOx where x is a positive real number less than 2, have a geometric anisotropy as an aspect ratio in the acicular or platy form of 3 or more, a higher specific surface area and a greater geometric anisotropy even in comparison on the basis of the same degree of reduction, and are capable of retaining their native configurations during the reduction. The resin mediums incorporated with the acicular or platy titanium suboxides have good electric properties, and a higher mechanical strength.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: June 14, 1994
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Haruo Okuda, Toshinobu Yamaguchi, Hideo Takahashi
  • Patent number: 5304426
    Abstract: A beryllium metal matrix phase includes up to 70% by volume of beryllium oxide single crystals dispersed therein. The composites are useful for electronics applications because of their light weight, high strength and effective thermal properties.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: April 19, 1994
    Assignee: Brush Wellman Inc.
    Inventor: Fritz C. Grensing
  • Patent number: 5303617
    Abstract: A Cu--Sn based sintered material, which has an improved corrosion-resistance, is provided by setting the Pb content at 1 to less than 10% and adding from 0.1 to 30% of a hard matter(s) selected from the groups (a), (b), (c) and (d). The hard matter is(a) Fe.sub.2 P, Fe.sub.3 P, FeB, Fe.sub.2 B and Mo.(b) Fe--Cr, Fe--Mn, Fe--Ni, Fe--Si, Fe--W, Fe--Mo, Fe--V, Fe--Ti, Fe--Nb, CuP, Cr, and W;(c) SiC, TiC, WC, B.sub.4 C, TiN, cubic BN, Si.sub.3 N.sub.4, SiO.sub.2, ZrO.sub.2, and Al.sub.2 O.sub.3 ;(d) Si--Mn, Cu--Si, and FeS.Most of said hard matter being dispersed in Cu particles, grain boundaries between Cu particles, and between the Cu and Pb particles.
    Type: Grant
    Filed: November 3, 1992
    Date of Patent: April 19, 1994
    Assignee: Taiho Kogyo Co., Ltd.
    Inventors: Eiji Asada, Hiromi Ogino
  • Patent number: 5302181
    Abstract: An oxide-dispersion-strengthened sintered alloy improved in oxidation resistance and compressive strength for use at high temperatures of at least 1350.degree. C. The alloy includes a matrix of a metal consisting substantially or predominantly of Cr, and 0.2 to 2.0% by weight of Y.sub.2 O.sub.3 uniformly dispersed in the matrix. The Y.sub.2 O.sub.3 as uniformly dispersed is up to 0.1 .mu.m in mean particle size.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: April 12, 1994
    Assignee: Kubota Corporation
    Inventors: Toshiaki Morichika, Takashi Onishi, Hiroshi Yamamoto, Koichi Yanai, Hiroyuki Araragi
  • Patent number: 5294239
    Abstract: In section bars and shaped bodies made of nickel-base superalloys having a structure consisting of columnar grains, a complete recrystallization cannot be effected unless the heating-up rate is kept below a maximum heating-up rate T.sub.max, which depends on the ratio V of one or more of the metal carbide-forming elements hafnium, niobium, tantalum, titanium and zirconium to one or both of the metal carbide-forming elements tungsten and molybdenum.
    Type: Grant
    Filed: May 6, 1991
    Date of Patent: March 15, 1994
    Assignee: PM Hochtemperatur-Metall GmbH
    Inventors: Klaus Zoltzer, Klaus Lempenauer, Hellmut Fischmeister
  • Patent number: 5284615
    Abstract: The present invention presents a method of processing ferrous powder materials to produce small component parts exhibiting excellent soft magnetic properties, in particular, residual magnetic flux density. The processing steps involve, in part, mixing with a binder, dewaxing or presintering at a temperature higher than in the conventional dewaxing process, followed by final sintering and a further conversion sintering, at a temperature lower than in the conventional sintering process, to produce parts having density values of over 96% theoretical density and excellent soft magnetic properties. The invented method is suitable for producing small component parts having sufficient strength and excellent soft magnetic properties to make them suitable for miniaturized electrical and electronic equipment.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: February 8, 1994
    Assignee: Mitsubishi Materials Corporation
    Inventors: Koshiro Ueda, Mutsumi Moribayashi, Tohru Kohno
  • Patent number: 5279649
    Abstract: A coating composition comprises a slurry consisting essentially of an aluminum neutralized phosphate bonding solution and aluminum powder. The bonding solution advantageously contains a relatively small but essential amount of vanadium pentoxide and, preferably, magnesium. A process for forming the bonding solution component of the coating slurry includes equilibrating an aqueous phosphate solution with a small but controlled and necessary amount of solute aluminum prior to adding aluminum powder to form the slurry. The present invention overcomes the problem of bonding solutions which require environmentally disadvantageous chromates or molybdates.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: January 18, 1994
    Assignee: Solar Turbines Incorporated
    Inventors: Alvin R. Stetson, William D. Brentnall, Zaher Z. Mutasim, Lulu L. Hsu
  • Patent number: 5279638
    Abstract: A Cu-Sn based sintered material, having an improved wear-resistance is obtained by adding from 0.1 to 30% of at least one hard matter(s) selected from the groups consisting of (a), (b), and (c) wherein (a), (b) and (c) are:(a) Fe.sub.2 P, Fe.sub.3 P, FeB, Fe.sub.2 B, Mo, Co, Co-based self-fluxing alloy, and Ni-based self-fluxing alloy;(b) SiC, TiC, WC, B.sub.4 C, TiN, cubic BN, Si.sub.3 N.sub.4, SiO.sub.2, ZrO.sub.2, and Al.sub.2 O.sub.3 ; and(c) Si-Mn, Cu-Si, and FeS.
    Type: Grant
    Filed: February 26, 1991
    Date of Patent: January 18, 1994
    Assignee: Taiho Kogyo Co., Ltd.
    Inventors: Eiji Asada, Hiromi Ogino
  • Patent number: 5279191
    Abstract: A fully dense ceramic-metal body including about 40-68 v/o .alpha.-alumina; about 10-30 v/o of a granular, hard refractory carbide, nitride, or boride; about 20-40 v/o silicon carbide platelets or elongated grains; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing SiC phase is partially incorporated into the alumina grain, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the mixture as Ni powder and Al powder. The body may be used as a cutting tool for machining nickel superalloys or cast iron at speeds up to about 1000 sfm, feed rates up to about 0.012 in/rev, and depth of cut up to about 0.10 inches.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: January 18, 1994
    Assignee: GTE Valenite Corporation
    Inventor: Sergej-Tomislay Buljan
  • Patent number: 5279650
    Abstract: A seal coat composition comprises a slurry consisting essentially of an aluminum neutralized phosphate bonding solution and iron oxide (Fe.sub.2 O.sub.3) powder. The bonding solution advantageously contains a relatively small but essential amount of vanadium pentoxide and, preferably, magnesium. A process for forming the bonding solution component of the coating slurry includes equilibrating an aqueous phosphate solution with a small but controlled and necessary amount of solute aluminum prior to adding iron oxide powder to form the slurry. The present invention overcomes the problem of bonding solutions which require environmentally disadvantageous chromates or molybdates to neutralize the bonding solution prior to formation of the slurry.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: January 18, 1994
    Assignee: Solar Turbines Incorporated
    Inventors: Alvin R. Stetson, William D. Brentnall, Zaher Z. Mutasim, Lulu L. Hsu
  • Patent number: 5279906
    Abstract: An interconnection material of a solid oxide fuel cell for electrically connecting adjacent unit cells, each of which comprises one electrode, electrolyte and the other electrode. The interconnection material is made of a mixture of an alloy mainly containing nickel and chromium with oxide ceramics in an amount of 50 to 85 wt. % of the mixture. The interconnection material has a high electrical conductivity and good compatibility with other constituent materials of a solid oxide fuel cell.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: January 18, 1994
    Assignee: Yoshida Kogyo K.K.
    Inventors: Takayoshi Yoshimura, Masaki Sato, Toshio Arai
  • Patent number: 5271758
    Abstract: A dense cermet article including about 44-93% of a granular first hard phase, about 4-44% of a granular second hard phase, and about 2-20% of a metal phase, all expressed in % by volume. The first hard phase consists essentially of alumina and from 0% to less than 5% of one or more oxides selected from magnesia, zirconia, yttria, hafnia, and silica. The second hard phase consists essentially of a hard refractory carbide, nitride, or boride, or mixture or solid solution thereof. Preferred materials for inclusion in the second hard phase are titanium carbide, hafnium carbide, tantalum carbide, tantalum nitride, tungsten carbide, titanium diboride, and boron carbide. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 85:15 to about 88:12, and 0-5% of an additive selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, cobalt, boron, and/or carbon.
    Type: Grant
    Filed: May 13, 1991
    Date of Patent: December 21, 1993
    Assignee: Valenite Inc.
    Inventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
  • Patent number: 5248661
    Abstract: A ductile, high electrical conductivity composite is made, containing alkaline earth metal-copper oxide particles (14), having a gold coating (16), within a skeletal matrix of hyperconducting aluminum (22) enclosed by a metallic sheath (12).
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: September 28, 1993
    Assignee: Westinghouse Electric Corp.
    Inventors: Cecil J. Mole, Alan T. Male, Walter J. Carr, Jr., Clifford K. Jones
  • Patent number: 5238886
    Abstract: Ceramic bodies are bonded together via a layer of an oxidation reaction product of a molten metal, which metal is present in one or both of the ceramic bodies prior to bonding. At least one of the ceramic bodies comprises a ceramic product formed by the oxidation reaction of molten parent metal (e.g., alumina from molten aluminum) and grown as molten metal is transported through, and oxidized on the surface of, its own oxidation product. One or both of the ceramic bodies used in the bonding process contains surface-accessible channels of residual metal, i.e., metal channels which have resulted from molten-metal transport during the ceramic growth process. When the suitably assembled ceramic bodies are heated in the presence of an oxidant at a temperature above the melting point of the residual metal, molten metal at the surface of at least one of the ceramic bodies reacts with the oxidant to form a layer of oxidation reaction product, which may or may not incorporate at least one filler material.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: August 24, 1993
    Assignee: Lanxide Technology Company, LP
    Inventors: Stanley J. Luszcz, Andrew W. Urquhart, Marc S. Newkirk
  • Patent number: 5238507
    Abstract: A magnetic material is provided which includes a discrete phase including grains made of a first substance which comprises a magnetic metal; and a continuous phase including a thin coating film made of a second substance which comprises a dielectric or insulating substance. The thin coating film is formed on the surface of the grains and has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: August 24, 1993
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Ken Hirota, Mitsuo Satomi
  • Patent number: 5234487
    Abstract: Tungsten-titanium sputter targets of at least 95% theoretical density are provided with little or no .beta.(Ti, W) phase constituent. Such targets will minimize troublesome particulate emissions during sputter coating conditions.
    Type: Grant
    Filed: April 15, 1991
    Date of Patent: August 10, 1993
    Assignee: Tosoh SMD, Inc.
    Inventors: Charles E. Wickersham, Jr., John J. Mueller
  • Patent number: 5217583
    Abstract: A dimensionally stable combustion synthesis product of a composition containing at least 20% by weight of a particulate combustible material; at least 15% by weight of a particulate filler material capable of providing desired mechanical and electrical properties; and up to 35% by weight of a particulate inorganic binder having a melting point lower than the combustion synthesis temperature. Electrodes suitable for electrochemical processing are a preferred product form, particularly electrodes for use in the electrowinning of aluminum from its oxide.
    Type: Grant
    Filed: January 30, 1991
    Date of Patent: June 8, 1993
    Assignee: University of Cincinnati
    Inventors: Jainagesh A. Sekhar, Sarit B. Bhaduri
  • Patent number: 5214011
    Abstract: A process is presented for the fabrication of a metal/ceramic composite by a non-vapor phase oxidation of a molten metal by contacting said molten metal at an elevated temperature with a sacrificial ceramic preform. The shape of the preform is retained but the ceramic preform is reduced, oxidizing the molten metal. A preferred sacrificial ceramic preform is silica, but can also be, for example, mullite, titania or zirconia, and the preferred molten metal is aluminum or an aluminum alloy. Thus, for example, is produced from immersing a silica preform into molten aluminum alloy, an Al/Al.sub.2 O.sub.3 composite metal/ceramic article which does not contain silica or silicon and which is extremely tough.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: May 25, 1993
    Assignee: BFD, Incorporated
    Inventor: Michael C. Breslin
  • Patent number: 5209772
    Abstract: A dispersion-strengthened (DS) alloy, more particularly oxide-dispersion-strengthened (ODS) iron-based alloys which manifest resistant to oxidation at temperatures as high as 1300.degree. C. (approx. 2400.degree. F.) whereby the alloys are useful in the production of advanced aircraft gas turbine engine components and in demanding industrial applications.
    Type: Grant
    Filed: October 5, 1988
    Date of Patent: May 11, 1993
    Assignee: Inco Alloys International, Inc.
    Inventors: Raymond C. Benn, Gaylord D. Smith, John J. Fischer
  • Patent number: 5200392
    Abstract: An improved ceramic-plus-metal superconducting composition of YBa.sub.2 Cu.sub.3 O.sub.6+x plus substantially pure aluminum for ultimate use in making superconducting devices such as wires and tapes for utilization in motors, generators, electric circuits, etc.
    Type: Grant
    Filed: October 18, 1990
    Date of Patent: April 6, 1993
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: A. Srinivasa Rao, Om P. Arora
  • Patent number: 5198187
    Abstract: An improved method of forming a composite body of a metal, intermetallic or ceramic matrix reinforced with niobium filaments, particles, platelets or mixtures thereof, the method comprising admixing the niobium reinforcing material with powders of the matrix component elements, forming the admixture into a desired shape and converting the powders to a matrix reinforced with the niobium material, the improvement wherein the reinforcing material has a surface coating thereon of a compound Nb.sub.2 O.sub.5, wherein the compound NbO reacts during formation of the matrix with a portion of at least one of the powdered elements to form a barrier layer at the reinforcer-matrix interface to prevent further reaction between the reinforcer and the matrix component elements. Also disclosed is a method of treating niobium particles, filaments, platelets or mixtures thereof by exposing the surface thereof to molecular O.sub.2 at temperatures and pressure conditions such that the niobium and molecular O.sub.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: March 30, 1993
    Assignee: University of Florida
    Inventors: Lixion Lu, Atul B. Gokhale, Reza Abbaschian
  • Patent number: 5173107
    Abstract: The invention relates to a composite hard metal body of hard material, a binder and embedded reinforcing material, as well as to a process for the production of the composite hard metal body by methods of powder metallurgy.In order to create a composite hard metal body with improved toughness under load, improved hardness and a lower fracture susceptibility, the invention proposes to build in monocrystalline, preferably needle-shaped and/or platelet-shaped reinforcing materials, coated with an inert layer with respect to the binder metal phase and consisting of borides and/or carbides, and/or nitrides and/or carbonitrides of the elements of Groups IVa or Va or mixtures thereof and/or coated monocrystalline reinforcing material of SiC, Si.sub.3 N.sub.4, Si.sub.2 N.sub.2 O, Al.sub.2 O.sub.3, ZrO.sub.2, AlN and/or BN.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: December 22, 1992
    Assignee: Krupp Widia GmbH
    Inventors: Klaus Dreyer, Hans Kolaska
  • Patent number: 5160366
    Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.
    Type: Grant
    Filed: March 14, 1991
    Date of Patent: November 3, 1992
    Assignees: Sumico Management Planning Company, Ltd., Akira Shibata
    Inventor: Akira Shibata
  • Patent number: 5156804
    Abstract: Neutron absorbing refractory B.sub.4 C--Gd and Gd.sub.2 O.sub.3 --Gd cermets, B.sub.4 C--Gd and Gd.sub.2 O.sub.3 --Gd metal-matrix composites, and B.sub.4 C--Gd.sub.2 O.sub.3 ceramic-ceramic composites can be manufactured by applying fundamental thermodynamic and kinetic guidelines as processing principals.Three steps are involved in the fabrication of these new compositions of matter. First, the starting materials are consolidated into a compacted porous green body. Next, the green body is densified using the appropriate method depending on the class of material sought: cermet, metal-matrix composite, or ceramic-ceramic composite. Finally, either during the densification process or by subsequent heat treatment, new phase evolution is obtained via interfacial chemical reactions occurring in the microstructures.The existence of a new phase has been identified in B.sub.4 C--Gd and B.sub.4 C--Gd.sub.2 O.sub.3 composites.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: October 20, 1992
    Assignee: Thermal Technology, Inc.
    Inventors: Danny C. Halverson, Garth W. Billings, George M. Johnston
  • Patent number: 5149678
    Abstract: The present invention relates to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr composite body, by utilizing a post-treatment technique which may improve the oxidation resistance of the composite body. Moreover, the invention relates to novel products made according to the process. The novel process modifies at least a portion of a composite body by exposing said body to a source of second metal.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: September 22, 1992
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, William B. Johnson, Robert A. Rapp
  • Patent number: 5149361
    Abstract: A cermet alloy having a structure including a hard phase and a bonding phase which is composed of at least one ferrous metal, said bonding phase containing fine hard grains of a mean grain size not greater than 2000 .ANG. dispersed therein. The structure has a composition consisting of 10 to 70 wt % of TiCN, 5 to 30 wt % of WC, 5 to 30 wt % of NbC, 1 to 10 wt % of Mo.sub.2 C, 0.5 to 5 wt% of VC, 0.05 to 3 wt % of ZrC, 5 to 25 wt % of (Ni, Co), and not smaller than 2.5 wt% of total nitrogen and incidental impurities.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: September 22, 1992
    Assignees: Hitachi, Ltd., Hitachi Taga Engineering Co., Ltd.
    Inventors: Yusuke Iyori, Nobuhiko Shima
  • Patent number: 5143540
    Abstract: Substantially dense, void-free ceramic-metal composites are prepared from components characterized by chemical incompatibility and non-wetting behavior. The composites have a final chemistry similar to the starting chemistry and microstructures characterized by ceamic grains similar in size to the starting powder and the presence of metal phase. A method for producing the composites requires forming a homogeneous mixture of ceramic-metal, heating the mixture to a temperature that approximates but is below the temperature at which the metal begins to flow and pressing the mixture at such pressure that compaction and densification of the mixture occurs and an induced temperature spike occurs that exceeds the flowing temperature of the metal such that the mixture is further compacted and densified. The temperature spike and duration thereof remains below that at which significant reaction between metal and ceramic occurs. The method requires pressures of 60-250 kpsi employed at a rate of 5-250 kpsi/second.
    Type: Grant
    Filed: September 18, 1990
    Date of Patent: September 1, 1992
    Assignee: The Dow Chemical Company
    Inventors: Aleksander J. Pyzik, Irving G. Snyder, Jr., Robert R. McDonald, Alexander Pecnenik
  • Patent number: 5124119
    Abstract: A beryllium metal matrix phase includes up to 70% by volume of beryllium oxide single crystals dispersed therein. The composites are useful for electronics applications because of their light weight, high strength and effective thermal properties.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: June 23, 1992
    Assignee: Brush Wellman Inc.
    Inventor: Fritz C. Grensing
  • Patent number: 5118342
    Abstract: A partially hardened sintered body such as a rocker arm comprises powder forming a main body and a capsule-like powder composite disposed adjacent to the powder and composed of core particles made of a material harder than the powder and covering particles covering the core particles and made of the same material as the powder. The powder and the capsule-like powder composite are solidified into the partially hardened sintered body.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: June 2, 1992
    Assignee: Isuzu Motors Limited
    Inventors: Tadashi Kamimura, Akira Tsujimura
  • Patent number: 5114468
    Abstract: The present invention relates to a Cu-based sintered alloy which has a composition containing: Zn: 10-40%; Al: 0.3%-6% oxygen: 0.03-1%; any one selected, as an additional element from the group including at least one of Fe, Ni and Co: 0.1-5%, Mn: 0.1-5%, Si: 0.1-3%, and at least one of W and Mo: 0.1-3%; and the remainder including Cu and inevitable impurities. The alloy is superior in wear resistance particularly in air at temperatures ranging from the ordinary temperature to 400.degree. C., has high strength and high toughness, and further excels in the uniform temporal change characteristics with associated members, as evaluated by its friction coefficient. The invention relates also to parts for automotive equipment made of this Cu-base sintered alloy, such as synchronizer rings for transmission, valveguides for engines, bearings for turbo-chargers and so forth.
    Type: Grant
    Filed: March 23, 1990
    Date of Patent: May 19, 1992
    Assignee: Mitsubishi Materials Corporation
    Inventors: Hidetoshi Akutsu, Tohru Kohno, Masato Otsuki
  • Patent number: 5114505
    Abstract: A composite aluminum-base alloy having a mechanically alloyed matrix alloy. The matrix alloy has about 4-40 percent by volume aluminum-containing intermetallic phase. The aluminum-containing intermetallic phase includes at least one element selected from the group consisting of niobium, titanium and zirconium. The intermetallic phase is essentially insoluble in the matrix alloy below one half of the solidus temperature of the matrix alloy. The balance of the matrix alloy is principally aluminum. A stiffener of 5 to 30 percent by volume of the composite aluminum-base alloy is dispersed within the metal matrix.
    Type: Grant
    Filed: August 30, 1990
    Date of Patent: May 19, 1992
    Assignee: Inco Alloys International, Inc.
    Inventors: Prakash K. Mirchandani, Raymond C. Benn, Walter E. Mattson
  • Patent number: 5114469
    Abstract: A process for producing high-strength, substantially nonporous alloys by means of a three-component mixture, including admixing a first component of one or more low-melting temperature metals or alloys thereof, a second component of one or more high-melting temperature metals or alloys thereof, and a substantially inert third component of one or more refractory compounds, subjecting the mixture to changes in temperature so as to form a mixture capable of being shaped at a temperature well below the melting or decomposition temperature of the highest melting metal and the inert refractory compound.
    Type: Grant
    Filed: December 10, 1987
    Date of Patent: May 19, 1992
    Assignee: General Dynamics Corporation Air Defense Systems Division
    Inventor: Sam M. Weiman
  • Patent number: 5110349
    Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: May 5, 1992
    Assignee: Sandvik AB
    Inventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
  • Patent number: 5110688
    Abstract: The present invention relates to a method of fabricating various types of bearing materials and the bearing materials produced thereby. The processes of the invention may be used to produce porous self-lubricating bearings, laminated composite bearings (babbitt bearings) and bearings for high temperature application. The processes of the invention involve the use of micro-pyretic synthesis to achieve bearing materials with improved bearing properties, including higher bearing capacity and toughness.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: May 5, 1992
    Assignee: University of Cincinnati
    Inventors: Jainagesh A. Sehkar, A. K. Bhattacharya, Hung P. Li
  • Patent number: 5098870
    Abstract: This invention relates generally to a novel method of preparing self-supporting bodies and to the novel products made thereby. In its more specific aspects, this invention relates to a method of producing self-supporting bodies having controlled porosity and graded properties and comprising one or more boron-containing compounds, e.g., a boride or a boride and a carbide. The method comprises, in one embodiment, reacting a powdered parent metal, in molten form, with a bed or mass comprising a boron carbide material and, optionally, one or more inert fillers, to form the body. In another embodiment, both of a powdered parent metal and a body or pool of molten parent metal are induced to react with a bed or mass comprising a boron carbide material and, optionally, one or more inert fillers. in addition, combustible additives (e.g., gelatin, corn starch, wax, etc.) can be mixed with the bed or mass comprising a boron carbide material to aid in the porisity producing process.
    Type: Grant
    Filed: July 23, 1990
    Date of Patent: March 24, 1992
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, William B. Johnson
  • Patent number: 5082826
    Abstract: A silver coated superconducting ceramic powder made by(1) coating the superconducting ceramic powder particles with AgNO.sub.3 ;(2) melting the AgNO.sub.3 so that it wets and forms a uniform coating over the surfaces of the particles; and(3) decomposing the AgNO.sub.3 to form a thin, uniform coating of silver metal on the surfaces of the particles.The product is a loose powder of superconducting ceramic particels which are uniformly coated with a thin layer of silver metal. The powder can be cold worked (e.g., swaged, forged, etc.) to form superconducting structures such as rods or wires.
    Type: Grant
    Filed: August 2, 1990
    Date of Patent: January 21, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: William A. Ferrando
  • Patent number: 5077246
    Abstract: A method for the preparation of ceramic composites containing at least aluminum oxide and aluminum boride, and the composite materials that result from the method. Intimate mixtures of finely-divided powdered aluminum metal and anhydrous boric oxide, with ratios (by weight) of about 0.5 to twenty parts of aluminum metal to one part of boric oxide, are subjected to a temperature to cause a complete reaction between the starting materials. If the ratio is above about 1.25 parts of aluminum to one part of boric oxide, the resultant product will include aluminum in addition to the aluminum oxide and aluminum boride. The ratio is selected to provide the desired hardness and toughness. Ratios between about 1 and 1.2 provide a composite having the highest hardness, with greater amounts of aluminum metal providing increased toughness. Several compositions are described, with hot pressing typically being used to provide the desired heating cycle.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: December 31, 1991
    Assignee: Apollo Concepts, Inc.
    Inventors: Samuel C. Weaver, Sally G. Padron
  • Patent number: 5074907
    Abstract: Enhanced crystallographic texture is developed in an alpha or alpha-beta titanium alloy having a dispersion of particles therein, by heating the alloy to essentially the all beta phase range and mechanically hot working the alloy in this range. The mechanical working is preferably accomplished by extrusion, rolling, or forging. The particles are stable during working, and prevent the formation of random texture in recrystallized beta phase grains at the working temperature. The particles are preferably oxides formed from rare earth elements such as erbium or yttrium, that are introduced into the alloy during manufacture. The alloys processed according to the invention are preferably prepared by powder metallurgy to achieve a uniform microstructure prior to working. A particularly suitable alpha-beta (but near alpha) titanium alloy contains aluminum, zirconium, hafnium, tin, columbium, molybdenum, tungsten, ruthenium, germanium, silicon, and erbium.
    Type: Grant
    Filed: August 16, 1989
    Date of Patent: December 24, 1991
    Assignee: General Electric Company
    Inventors: Richard A. Amato, Andrew P. Woodfield, Michael F. X. Gigliotti, Jr., John R. Hughes, Lee C. Perocchi
  • Patent number: 5068072
    Abstract: The present invention relates to a zirconia-based sintered body comprising TiN, TiO.sub.2 and ZrO.sub.2 and having electric conductivity and a process for the production thereof. The present invention provides a zirconia-based sintered body which has, at normal temperature, a mechanical strength of not less than 50 kg/mm.sup.2, a fracture toughness of not less than 4 MPam.sup.1/2, a Vickers hardness of not less than 1,000 kg/mm.sup.2 and a volume resistivity of not more than 1 .OMEGA.cm, and which is sinterable under normal pressure at low temperature, and a process for the production thereof.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: November 26, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazuo Horinouchi, Masahide Mouri, Isao Kameda
  • Patent number: 5057379
    Abstract: A coating for a heat engine part, particularly a turbo-machine part made of superalloy, comprises an electrophoretically deposited metallic structure of cellular form with uniformly disposed cells of predetermined size, the structure preferably being composed of M, Cr, Al, and Y, where M denotes Ni, Co, Fe and mixtures thereof. The cellular metallic structure is consolidated by a sintering treatment, which may be reactive, or metallization, preferably in the vapor phase, and the coating is completed by a ceramic material applied by plasma spraying.
    Type: Grant
    Filed: May 23, 1988
    Date of Patent: October 15, 1991
    Assignees: Societe Nationale d'Etude et de Construction de Moteurs d'Aviation "S.N.E.C.M.A.", Association pour la Recherche et le Developpement des Methodes et Processus Industriels A.R.M.I.N.E.S.
    Inventors: Dominique M. M. Fayeulle, Jean-Paul Henon, Rene J. Morbioli
  • Patent number: 5053074
    Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: October 1, 1991
    Assignee: GTE Laboratories Incorporated
    Inventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
  • Patent number: 5041261
    Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: August 20, 1991
    Assignee: GTE Laboratories Incorporated
    Inventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
  • Patent number: 5041159
    Abstract: An improved method of forming a nickel plaque wherein an assemblage of particles of a nickel alloy are oxidized and sintered in a preselected atmosphere such that the alloying material is exclusively substantially internally oxidized and the resultant product sintered to provide a sintered porous plaque containing nickel metal and oxidized alloying material.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: August 20, 1991
    Assignee: Energy Research Corporation
    Inventors: Joel D. Doyon, Lawrence M. Paetsch, Mark Benedict, D. Lynn Johnson
  • Patent number: 5039476
    Abstract: A method for the production of a metallic powder molding material is disclosed which comprises a step of imparting mechanical energy due to at least one of such physical actions as vibration, pulverization, attrition, rolling, shocks, agitation, and mixing a metallic particles in a vessel whose interior is held under vacuumized atmosphere or an atmosphere of inert gas thereby enabling the metallic particles to contact each other and acquire improvement in surface quality and a step of hot molding the metallic particles thereby producing a molding material.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: August 13, 1991
    Assignee: Ube Industries, Ltd.
    Inventors: Mitsuru Adachi, Akio Okamoto, Hideki Iwai, Yoshiharu Waku
  • Patent number: 5026680
    Abstract: A Ca carbonate powder, a Sr carbonate powder, and a Cu oxide powder are mixed in predetermined proportions, and sintered at a first predetermined temperature into a Ca-Sr-Cu--O oxide sintered body. A Bi oxide powder and a Pb oxide powder are mixed in predetermined proportions, and are sintered at a second predetermined temperature into a Bi--Pb--O oxide sintered body. The obtained Ca--Sr--Cu--O oxide sintered body and Bi--Pb--O oxide sintered body are crushed, and the resulting Ca--Sr--Cu--O oxide powder and Bi--Pb--O oxide powder are mixed in predetermined proportions. The resulting mixed powder is sintered at a third predetermined temperature into a Bi--Pb--Sr--Ca--Cu--O superconductive oxide sintered body, which is crushed into a powder of a Bi-based superconductive oxide containing Pb. A sintered body of the Bi-based superconductive oxide containing Pb is formed from the Bi-based superconductive oxide powder.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: June 25, 1991
    Assignee: Mitsubishi Metal Corporation
    Inventors: Tadashi Sugihara, Takuo Takeshita, Yukihiro Ohuchi
  • Patent number: 5019539
    Abstract: This invention relates generally to a novel method of preparing self-supporting bodies and to the novel products made thereby. In its more specific aspects, this invention relates to a method of producing self-supporting bodies comprising one or more boron-containing compounds, e.g., a boride or a boride and a carbide, by reacting, in one embodiment, a powdered parent metal, in molten form, with a bed or mass comprising a boron carbide material and, optionally, one or more inert fillers, to form the body. In another embodiment, both of a powdered parent metal and a body or pool of molten parent metal are induced to react with a bed or mass comprising a boron carbide material, and, optionally, one or more inert fillers.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: May 28, 1991
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, William B. Johnson
  • Patent number: 5011529
    Abstract: A cured sintered porous metal structure comprising aluminum and aluminum alloys is presented comprising an aluminum oxide durable surface integral to the structure. The surface layer is enhanced in aluminum while the underlying structure is thereby depleted in aluminum. The structure exhibits surface and interfacial durability.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: April 30, 1991
    Assignee: Corning Incorporated
    Inventors: Kathryn E. Hogue, Srinivas H. Swaroop, Raja R. Wusirika
  • Patent number: 5006163
    Abstract: A novel, nickel-base, high temperature alloy body preferably containing about 20% chromium, 6 to 7% aluminum to provide phase, 1.5 to 2.5% molybdenum, 3 to 4.5% tungsten, additional strengthening elements and oxidic yttrium in finely dispersed form. The alloy body has an elongated crystal structure and is characterized by high strength along with excellent hot corrosion and oxidation resistance.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: April 9, 1991
    Assignee: Inco Alloys International, Inc.
    Inventors: Raymond C. Benn, Jeffrey M. Davidson, Kenneth R. Andryszak