Containing Boron(b) Or Nitrogen(n) Patents (Class 75/244)
  • Patent number: 4865645
    Abstract: The nuclear radiation metallic absorber contains a metallic copper alloy containing 0.05 to 50% of boron in weight, compared to the total alloy weight, preferably 0.05 to 10% boron in weight, compared to the total alloy weight. Moreover it may contain additional elements such as neutron absorbing elements, mechanical, physical and technological properties reinforcing elements, fibres or anti-corrosion elements.It may more specifically be used for neutron and .gamma. and X radiation absorption.
    Type: Grant
    Filed: January 30, 1989
    Date of Patent: September 12, 1989
    Inventor: Claude Planchamp
  • Patent number: 4863805
    Abstract: A rare earth-iron permanent magnet is comprised of compacted Re-B-R type alloy particles in which R represents at least one element selected from rare earth elements and yttrium. The magnet has a sealing agent filling voids between the compacted Fe-B-R type alloy particles and a coating layer formed on outer surfaces thereof. The coating layer is formed by coating the surfaces wrought in a desired magnet shape.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: September 5, 1989
    Assignee: Seiko Instruments Inc.
    Inventors: Teruo Suzuki, Matsuo Kishi, Katsuyoshi Muraishi, Kenichi Ogawa, Hiroshi Takashio
  • Patent number: 4861373
    Abstract: The present invention relates to an infiltrated ferrous powder metal part containing certain additives, yielding a radically improved unnotched impact strength without sacrificing tensile strength. Fatigue strength is also improved. In addition, improved dimensional control is obtained during infiltration. The microstructure is also improved, with smoothing or rounding of the formerly sharp angled copper filled pores. The invention also comprises the method of achieving these results.
    Type: Grant
    Filed: March 8, 1988
    Date of Patent: August 29, 1989
    Assignee: SCM Metal Products, Inc.
    Inventors: Erhard Klar, Mark Svilar, David F. Berry
  • Patent number: 4859410
    Abstract: A method to increase the volume fraction of magnetically aligned material in rare earth (RE), iron, boron type anisotropic permanently magnetic material includes forming an adaptively shaped fully dense substantially magnetically isotropic preform from relatively coarse powder particles of melt spun alloy with a very fine grain Re.sub.2 Fe.sub.14 B phase. The preform is heated and die upset to provide uniformity of strain in the perform as it is conformed to the die thereby to cause an increased percentage of the crystallites to be oriented along a crystallographically preferred magnetic axis which increases the energy product of a resultant magnet.
    Type: Grant
    Filed: March 24, 1988
    Date of Patent: August 22, 1989
    Assignee: General Motors Corporation
    Inventors: Earl G. Brewer, Robert W. Lee
  • Patent number: 4859254
    Abstract: A permanent magnet according to the present invention is characterized in that it is composed of an alloy comprising mainly of iron, and R (rare earth element including yttrium), cobalt, and boron, wherein the alloy is formed principally of ferromagnetic Fe-rich phase of tetragonal system and includes a nonmagnetic Laves phase. Compared with the prior rare earth-Fe based magnet, it has higher Curie temperature and has excellent magnetic characteristics, especially the temperature characteristics.
    Type: Grant
    Filed: September 10, 1986
    Date of Patent: August 22, 1989
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tetsuhiko Mizoguchi, Isao Sakai, Hiromi Niu, Koichiro Inomata
  • Patent number: 4859255
    Abstract: A magnetically anisotropic sintered permanent magnet of the FeCoBR system (R is sum of R.sub.1 and R.sub.2) wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2, and the balance of other rare earth elements exclusive of R.sub.1,said system consisting essentially of, by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B up to 35% of Co, and the balance being Fe. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W) may be present.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: August 22, 1989
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
  • Patent number: 4859238
    Abstract: Electrical contacts are formed from a silver-iron material which contains 3 to 30% by weight of iron and one or more of the components manganese, copper, zinc, antimony, bismuth oxide, molybdenum oxide, tungsten oxide or chromium nitride in amount totalling 0.05 to 5 weight percent, the balance being silver. These materials are suitable for forming electrical contacts of a wide variety. Tantalum is an optional component which may also be utilized particularly when 0.2 percent to 2 percent zinc is present.
    Type: Grant
    Filed: June 3, 1988
    Date of Patent: August 22, 1989
    Assignee: Degussa Aktiengesellschaft
    Inventors: Wolfgang Weise, Roger Wolmer, Peter Braumann
  • Patent number: 4851041
    Abstract: A compacted, single phase or multiphase composite article. Particles for use in the compacted article are produced by providing a precursor compound containing at least one or at least two metals and a coordinating ligand. The compound is heated to remove the coordinating ligand therefrom and increase the surface area thereof. It may then be reacted so that at least one metal forms a metal-containing compound. The particles may be consolidated to form a compacted article, and for this purpose may be used in combination with graphite or diamonds. The metal-containing compound may be a nonmetallic compound including carbides, nitrides and carbonitrides of a refractory metal, such as tungsten. Th metal-containing compound may be dispersed in a metal matrix, such as iron, nickel or cobalt.
    Type: Grant
    Filed: May 22, 1987
    Date of Patent: July 25, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Richard S. Polizzotti, Larry E. McCandlish
  • Patent number: 4849164
    Abstract: A sintering aid is disclosed for use in a powder metallurgical method for manufacturing an iron alloy article by compacting and sintering a predominantly iron powder mixture comprising carbon powder and a boron-containing additive, such as nickel boride. The sintering aid comprises an oxygen getter to inhibit boron oxidation that, if formed, is believed to retard carbon diffusion. The sintering aid also preferably includes a second constituent to produce, in combination with the getter, a melting point suitable for forming a transient liquid phase during the early stages of sintering. Preferred sintering aids include intermetallic iron titanium compounds, intermetallic ferro-vanadium compound and intermetallic nickel magnesium compound.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: July 18, 1989
    Assignee: General Motors Corporation
    Inventors: William F. Jandeska, Vadim Rezhets, Carlo Ligotti
  • Patent number: 4844754
    Abstract: High energy product, magnetically anisotropic permanent magnets are produced by hot working overquenched or fine grained, melt-spun materials comprising iron, neodymium and/or praseodymium, and boron to produce a fully densified, fine grained body that has undergone plastic flow.
    Type: Grant
    Filed: March 17, 1986
    Date of Patent: July 4, 1989
    Assignee: General Motors Corporation
    Inventor: Robert W. Lee
  • Patent number: 4840684
    Abstract: Isotropic permanent magnet formed of a sintered body having a mean crystal grain size of 1-160 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zv, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder metallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.
    Type: Grant
    Filed: December 30, 1983
    Date of Patent: June 20, 1989
    Assignee: Sumitomo Special Metals Co, Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
  • Patent number: 4838936
    Abstract: Spiral parts, such as orbiting and fixed scroll plates having involute wraps, for use in scroll compressors, the parts having low coefficient of thermal expansion and high tensile strength and Young's modulus, are formed by combining a self-lubricating power into aluminum raw material powder prior to compression and forging. As an alternative to and in conjunction with the foregoing, temperatures during preform heating and in the die for forging are controlled to be in respective ranges of 300.degree. to 500.degree. C. and 150.degree. to 500.degree. C. Aluminum alloy fine powder preferably has a particle diameter no larger than 350 .mu.m. The self-lubricating powder preferably forms 1 to 25% of the mix by volume, and contains at least one member selected from the group consisting of graphite, BN, and MoS.sub.2.
    Type: Grant
    Filed: May 23, 1988
    Date of Patent: June 13, 1989
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Kiyoaki Akechi
  • Patent number: 4836868
    Abstract: In an R-Fe-B permanent magnet produced by a process including a rapid cooling, a composition of{R.sub.a (Ce.sub.b La.sub.1-b).sub.1-a }x(Fe.sub.1-z Co.sub.z).sub.100-x-y-w B.sub.y M.sub.w(R is at least one rare earth element except for La and Ce but including Y, 5.5.ltoreq.x<12, 2.ltoreq.y<15, 0.ltoreq.z.ltoreq.0.7, 0<w.ltoreq.10, 0.80.ltoreq.a.ltoreq.1.00, 0.ltoreq.b.ltoreq.1, M is Zr, Nb, Mo, Hf, Ta, W, Ti, and/or V) is proposed. The presence of the M element increases a ((BH)max) to a value higher than that of a composition wherein x is higher than 12 and makes the magnet more easily magnetizable.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: June 6, 1989
    Assignee: TDK Corporation
    Inventors: Kohichi Yajima, Osamu Kohmoto, Tetsuhito Yoneyama
  • Patent number: 4830930
    Abstract: There are disclosed a surface refined sintered alloy body which comprises a hard phase containing at least one selected from the group consissting of carbides, carbonitrides, carbooxides, carbonitrooxides of the metals of the groups 4a, 5a and 6a of the periodic table and a binding phase containing at least one selected from iron group metals, characterized in that the concentration of the binding phase in the surface layer (of from 10 .mu.m to 500 .mu.m from the surface of the sintered alloy) is highest at the outermost surface thereof and approaches the concentration of the inner portion, the concentration of the binding phase decreasing from the outermost surface to a point at least 5 .mu.m from the surface; and a method for making the same by applying decarburization treatment at the surface of the sintered alloy at temperatures within the solid-liquid co-existing region of the binding phase after sintering or in the process of sintering.
    Type: Grant
    Filed: April 7, 1988
    Date of Patent: May 16, 1989
    Assignee: Toshiba Tungaloy Co., Ltd.
    Inventors: Yasuro Taniguchi, Ko Sasaki, Mitsuo Ueki, Keiichi Kobori
  • Patent number: 4818481
    Abstract: Disclosed is a method for extruding fine grain aluminum mechanically alloyed powder material such that the resulting extruded product is substantially free of texture, which method comprises extruding a billet of the powder material having a mean grain size less than about 5 microns through a die having an internal contour which conforms substantially to the formula: ##EQU1## where R is the radius of the die contour at any given point x along the major axis of the die orifice from its entry plane, R.sub.o is the radius of the billet, and K is an arbitrary constant.
    Type: Grant
    Filed: March 9, 1987
    Date of Patent: April 4, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Michael J. Luton, Raghavan Ayer, Ruzica Petkovic-Luton, Joseph Vallone, Stephen Matras
  • Patent number: 4797155
    Abstract: A metal matrix composite is produced by plastically deforming a metal powder, either or after blending the powder with ceramic fibers, and compacting the mixture at elevated temperatures to achieve substantially full density. Imparting strain energy to the metal allows reduction of the compaction temperature to eliminate reaction between the fibers and the metal or degradation of the fibers. Silicon nitride fibers are thermodynamically superior for use in aluminum or titanium metal matrix composites, since silicon nitride fibers are more stable at the temperatures required for full compaction. Secondary phase reactions are avoided.
    Type: Grant
    Filed: February 27, 1987
    Date of Patent: January 10, 1989
    Assignee: The Boeing Company
    Inventor: K. Bhagwan Das
  • Patent number: 4793859
    Abstract: A process for producing a brazable ceramic composite by infiltrating silicon into a porous body at least partly composed of molybdenum to form at least about 5% by volume of a silicide of molybdenum in situ.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: December 27, 1988
    Assignee: General Electric Company
    Inventor: Charles R. Morelock
  • Patent number: 4793967
    Abstract: The present invention is directed to a cermet material comprising a matrix of aluminum alloy with ceramic particles distributed therein. The cermet is adapted for use as a semiconductor substrate and is manufactured using powder technology procedures. The cermet comprises from about 40 to about 60 volume % of aluminum or aluminum alloy, from an effective amount up to about 10 volume % of binder for enhancing bonding between the aluminum alloy and ceramic particles, and the balance essentially ceramic particles.
    Type: Grant
    Filed: December 31, 1987
    Date of Patent: December 27, 1988
    Assignee: Olin Corporation
    Inventors: Michael J. Pryor, Eugene Shapiro, Deepak Mahulikar
  • Patent number: 4792368
    Abstract: Magnetic materials comprising Fe, B, R (rare earth elements) and Co having a major phase of Fe-Co-B-R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B, no less than 50% Co, and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe-Co-B-R-M type materials and magnets.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: December 20, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Masato Sagawa, Setsuo Fujimura, Yutaka Matsuura
  • Patent number: 4781980
    Abstract: The present invention provides a copper powder for use in a conductive paste which allows the paste to possess excellent initial electrical conductivity, thermal resistance, and humidity resistance, and which enables the paste to maintain stable electrical conductivity for a long period of time. The copper powder of the present invention comprises a raw material copper powder; an anti-oxidization film comprising an organic acid salt of a higher aliphatic amine which is formed on the surface of the copper powder; and a surface film which comprises 0.2 to 10 parts by weight of a dispersing agent of a boron-nitrogen composite type and 0.1 to 10 parts by weight of at least one coupling agent of the group consisting of isopropyl-triisostearoyl-titanate and aceoalkoxy-aluminum-diisopropylate, relative to 100 parts by weight of the copper powder, and which is formed on the anti-oxidization film.
    Type: Grant
    Filed: March 23, 1987
    Date of Patent: November 1, 1988
    Assignee: Fukuda Metal Foil & Powder Co., Ltd.
    Inventors: Masayoshi Yoshitake, Shigeru Kito, Jiro Yamamoto
  • Patent number: 4778649
    Abstract: A method of producing a material having a layer of ceramic as a first component, a layer of a metal as a second component and an intermediate layer lying between said layers and including said first and second components in continuous gradient ratios so that the properties of the material may change continuous, including a step of forming said intermediate layer by igniting a powder mixture of metallic and nonmetallic constitutive elements of said ceramic component and said metal component so as to cause a synthetic reaction in the powder mixture.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: October 18, 1988
    Assignees: Agency of Industrial Science and Technology, Daikin Industries, Ltd.
    Inventors: Masayuki Niino, Nobuyuki Yatsuyanagi, Jun Ikeuchi, Nobuhiro Sata, Tohru Hirano, Kanichiro Sumiyoshi
  • Patent number: 4777014
    Abstract: Self-supporting bodies are produced by reactive infiltration of a parent metal with a boron source typically resulting in a composite comprising a parent metal boride and metal. The mass to be infiltrated may contain one or more inert fillers admixed with the boron source to produce a composite by reactive infiltration, which composite comprises a matrix of metal and parent metal boride embedding the filler. The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing varying volume percents of ceramic, metal and/or porosity.
    Type: Grant
    Filed: March 7, 1986
    Date of Patent: October 11, 1988
    Assignee: Lanxide Technology Company, LP
    Inventors: Marc S. Newkirk, Michael K. Aghajanian, Danny R. White
  • Patent number: 4773950
    Abstract: A magnetically anisotropic sintered permanent magnet of the FeBR system in which R is sum of R.sub.1 and R.sub.2 wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2 and the balance of at least one of other rare earth elements exclusive of R.sub.1,said system comprising by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B, and the balance being Fe with impurities. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W,) may be present.
    Type: Grant
    Filed: September 15, 1983
    Date of Patent: September 27, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
  • Patent number: 4770703
    Abstract: A sintered stainless steel exhibiting improved resistance to stress corrosion cracking which comprises a matrix phase and a dispersed phase and a process for manufacturing same are disclosed. The dispersed phase is of an austenitic metallurgical structure and is dispersed throughout the matrix phase which is comprised of an austenitic metallurgical structure having a steel composition different from that of the dispersed phase or a ferrite-austenite duplex stainless steel.
    Type: Grant
    Filed: June 4, 1985
    Date of Patent: September 13, 1988
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Yoshio Tarutani, Takeo Kudo, Akira Seki, Masaru Nishiguchi
  • Patent number: 4770702
    Abstract: A rare earth-iron-boron alloy powder which consists essentially of:12.5 to 20 at % R wherein R.sub.1 is 0.05 to 5 at %, 4 to 20 at % B, and 60 to 83.5 at % Fe,wherein R.sub.1 is at least one heavy rare earth element selected from the group consisting of Gd, Tb, Dy, Ho, Er, Tm and Yb, 80 to 100 at % of R.sub.2 consists of Nd and/or Pr, the balance in the R.sub.2 being at least one element selected from the group consisting of rare earth elements including Y and except for R.sub.1, and R=R.sub.1 =R.sub.2 by atomic %, wherein a major phase of at least 80 vol % of the entire alloy coinsists of a tetragonal structure, and wherein oxygen does not exceed 10,000 ppm, carbon does not exceed 1000 ppm and calcium does not exceed 2000 ppm. The alloy powder is produced by directly reducing a mixture comprising rare earth oxide, iron and other ingredients or oxide thereof with a reducing agent Ca and CaCl.sub.2, putting the reduced product into water, then treating with water. Up to 35 at % Co may be substituted for Fe.
    Type: Grant
    Filed: January 20, 1988
    Date of Patent: September 13, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Naoyuki Ishigaki, Takaki Hamada, Setsuo Fujimura
  • Patent number: 4770723
    Abstract: Magnetic materials comprising Fe, B and R (rare earth elements) having a major phase of Fe--B--R intermetallic compound(s) of tetragonal system, and sintered anisotropic permanent magnets consisting essentially of, by atomic percent, 8-30% R (at least one of rare earth elements inclusive of Y), 2-28% B and the balance being Fe with impurities. Those may contain additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) providing Fe--B--R--M type materials and magnets.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: September 13, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Masato Sagawa, Setsuo Fujimura, Yutaka Matsuura
  • Patent number: 4770701
    Abstract: Amorphous metal-ceramic and microcrystalline metal-ceramic composites are synthesized by solid state reaction-formation methods. These metal-ceramic composites are characterized by a composition that ranges from about 75 to about 99.9 percent ceramic in about 0.1 to about 25 percent amorphous or microcrystalline metal binder phase.
    Type: Grant
    Filed: April 30, 1986
    Date of Patent: September 13, 1988
    Assignee: The Standard Oil Company
    Inventors: Richard S. Henderson, Michael A. Tenhover
  • Patent number: 4769070
    Abstract: High hardness and high toughness nitrogen-containing sintered hard alloys or cermets useful for cutting tools, in particular, high speed cutting are provided which comprises a hard dispersed phase consisting essentially of a mixed carbonitride of titanium and at least one element selected from the group consisting of Group IVa, Va, and VIa elements of Periodic Table, except titanium, and a binder metal phase consisting essentially of at least one metal selected from the group consisting of nickel and cobalt, and unavoidable impurities, the hard dispersed phase having previously been subjected to a solid solution forming treatment at a temperature of at least the sintering temperature before sintering.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: September 6, 1988
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Masaaki Tobioka, Yasuhiro Shimizu, Kazutaka Isobe, Nobuyuki Kitagawa, Toshio Nomura, Kunihiro Takahashi
  • Patent number: 4767474
    Abstract: Isotropic permanet magnet formed of a sintered body having a mean crystal grain size of 1-130 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B, no more than 50% of Co and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder meallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.
    Type: Grant
    Filed: December 30, 1983
    Date of Patent: August 30, 1988
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
  • Patent number: 4765848
    Abstract: In the rare earth-iron-boron permanent magnet, Ce and La decrease the magnetic properties when used alone but synergistically enhance iHc when used in combination.The composition provided by the present invention is generally expressed by [(Ce.sub.x La.sub.1-x).sub.y R.sub.1-y ].sub.z [(Fe.sub.1-u-w Co.sub.w M.sub.u).sub.1-v B.sub.v ].sub.1-z with a proviso of 0.4.ltoreq.x.ltoreq.0.9, 0.2<y.ltoreq.1.0, 0.05.ltoreq.z.ltoreq.0.3, 0.01.ltoreq.v.ltoreq.0.3, 0.ltoreq.u.ltoreq.0.2, 0.ltoreq.w.ltoreq.0.5, and M is at least one element selected from the group consisting of Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni, W, Cu, and Ag.
    Type: Grant
    Filed: December 27, 1985
    Date of Patent: August 23, 1988
    Assignee: Kaneo Mohri
    Inventors: Kaneo Mohri, Jiro Yamasaki
  • Patent number: 4764434
    Abstract: A polycrystalline diamond tool comprising a diamond layer is bonded to a support body having a complex, non-plane geometry by means of a thin more than 3 .mu.m continuous layer of a refractory material applied by PVD or CVD technique.
    Type: Grant
    Filed: June 26, 1987
    Date of Patent: August 16, 1988
    Assignee: Sandvik Aktiebolag
    Inventors: Sven B. Aronsson, Mats G. Waldenstrom
  • Patent number: 4762557
    Abstract: A high temperature, oxidation resistant alloy useful in high temperature, oxidizing environments such as those encountered in gas turbines, advanced jet engines, high temperature furnaces and glass melting and processing equipment, among others.The alloy is characterized by selecting a refractory alloy from the group consisting of molybdenum, tungsten, niobium and tantalum having dispersed therein a second phase additive of titanium nitride and a third phase additive of aluminum and titanium. Alternatively, the refractory metals may be molybdenum or tungsten and the second phase additive and third phase additive may be silicon nitride and silicon, or chromium nitride and chromium respectively.
    Type: Grant
    Filed: October 1, 1987
    Date of Patent: August 9, 1988
    Assignee: Battelle Memorial Institute
    Inventors: Vaidyanathan Nagarajan, Ian G. Wright
  • Patent number: 4761344
    Abstract: A rocker arm of a valve mechanism of an automotive internal combustion engine is composed of a rocker arm tip secured to a rocker arm main body. The rocker arm tip includes a sheet type sintered alloy adhered to a steel substrate. The sintered alloy includes a joining phase of martensite stainless steel, and a hard phase of boride and/or multiple boride of at least one, including iron, of elements capable of forming boride and/or multiple boride. The hard phase is homogeneously dispersed in the joining phase. The sintered alloy contains boron ranging from 3.0 to 5.0% by weight, and the hard phase ranging from 40 to 62% by weight. Additionally, the sintered alloy has a maximum grain size of the boride and/or multiple boride ranging not larger than 50 .mu.m, a Rockwell A-scale hardness number ranging not less than 80, and a deflective strength ranging not lower than 175 kgf/mm.sup.2.
    Type: Grant
    Filed: April 9, 1987
    Date of Patent: August 2, 1988
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Yoshihiro Maki, Makoto Kano, Akira Fujiki, Ichiro Tanimoto
  • Patent number: 4756752
    Abstract: A method for forming a high density body from a powder material of metallic and non-metallic compositions and combinations thereof comprising confining a quantity of the powder material in a flexible mold structure, subjecting the powder material in the mold structure to a predetermined pressure along one axis while confining the material against movement in directions normal to the axis so as to form a compact body of the powder material and subsequently heating the compact body to a predetermined temperature so as to further compact the body. A quantity of glass is heated so that it will flow and transmit pressure following which the heated body is immersed in the heated glass and the flowable glass is subjected to a pressure high enough to further compact the body. The resulting densified body is uniformly compressed in the directions of three mutually perpendicular axes extending through the body.
    Type: Grant
    Filed: November 4, 1987
    Date of Patent: July 12, 1988
    Assignee: Star Cutter Company
    Inventor: Lewis J. Barnard
  • Patent number: 4756753
    Abstract: An aluminum matrix composite containing evenly dispersed reinforcement particles in the aluminum matrix wherein the contents of oxygen and carbon are controlled so that their volume percentage is not larger than 20% and wherein the contents of the reinforcement particles, oxygen and carbon are controlled so that their volume percentage is not larger than 40%. The control of oxygen and carbon is effected by carrying out the main process at a non-oxidizing atmosphere and minimizing the addition of an anti-seizure agent required to facilitate the mechanical alloying treatment.
    Type: Grant
    Filed: August 26, 1987
    Date of Patent: July 12, 1988
    Assignee: Showa Aluminum Kabushiki Kaisha
    Inventor: Tsunemasa Miura
  • Patent number: 4756754
    Abstract: The present invention relates to a composite formed of a mixture of ceramic particles and at least two metallic components adhered together with a glassy phase. A first of the metallic components, in particle form, enhances the flow characteristics of the mixture where the second metallic component and the glass are in the molten condition. The final composite is a continuous phase of the second metallic component having particles of the first metallic component and glass coated ceramic particles distributed therein.
    Type: Grant
    Filed: March 6, 1987
    Date of Patent: July 12, 1988
    Assignee: Olin Corporation
    Inventor: Narendra N. SinghDeo
  • Patent number: 4755220
    Abstract: A material resistant to high temperature melts of metal and salt which comprises a composite material containing silicon nitride, silicon oxynitride, silicon dioxide and silicon prepared by(a) suspending silicon powder in SiO.sub.2 sol to form a pourable mass,(b) molding a workpiece from said mass,(c) hardening the molded workpiece, and(d) nitriding the hardened workpiece in a nitrogen atmosphere to form silicon nitride and silicon oxynitride to a degree that SiO.sub.2 and elemental silicon remain detectable in the nitrided workpiece,is useful as the material of construction for crucibles and tools for confining, handling and treating melts of metals or salts.
    Type: Grant
    Filed: November 6, 1987
    Date of Patent: July 5, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Woditsch, Werner Kannchen, Horst Lange, Ingo Schwirtlich
  • Patent number: 4755221
    Abstract: Composite powder particles which are essentially spherical in shape are disclosed which consist essentially of particles of a matrix phase which consists essentially of a metal selected from the group consisting of aluminum and aluminum based alloys and a reinforcement phase which is relatively uniformly dispersed in and bonded to the matrix, the reinforcement phase comprising titanium diboride.A process is disclosed for producing the above composite particles which involves entraining in a carrier gas a plurality of agglomerated powders, at least one of the powders supplying aluminum, at least one of the powders supplying titanium without boron and at least one of the powders supplying boron without titanium. The powders are fed through a high temperature zone to cause essentially complete melting and coalescence of the powders wherein at least a part of the titanium and at least a part of the boron combine to form titanium diboride and thereafter resolidified to form the composite powder particles.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: July 5, 1988
    Assignee: GTE Products Corporation
    Inventors: Muktesh Paliwal, Walter A. Johnson
  • Patent number: 4755712
    Abstract: A lead-in wire for use in an election lamp formed of molybdenum (undoped or doped with small amount of potassium and silicon) containing small amount of yttrium oxide and molybdenum boride is disclosed.
    Type: Grant
    Filed: December 9, 1986
    Date of Patent: July 5, 1988
    Assignee: North American Philips Corp.
    Inventors: Mohammad Mujahid, Richard Conrad
  • Patent number: 4749545
    Abstract: This invention relates to metal matrix composites containing at least 40% v/v of a hard material such as SiC and a matrix of aluminium, magnesium or alloys of either. The invention also covers a method of making such composites by ball milling powders of the respective components. Other mixing techniques do not enable such a high proportion of hard material to be incorporated into the composite. The composites are useful to produce components resistant to wear.
    Type: Grant
    Filed: March 26, 1987
    Date of Patent: June 7, 1988
    Assignee: British Petroleum Co. p.l.c.
    Inventors: Alan R. Begg, Andrew D. Tarrant
  • Patent number: 4746363
    Abstract: Cermet body formed by reaction sintering at pressures ranging from subatmospheric to superatmospheric of admixed and shaped particulate exothermic reactants, which have maximum particle size substantially not greater than 150 .mu.m and can be elements, compounds, intermetallic compounds and/or alloys, in stoichiometric proportions to substantially form 40-95 mole percent of first phase or phases being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 2a, 3a exclusive of B, 4a, 2b, 3b including lanthanide and actinide series elements, 4b, 5b, 6b, 7b and 8, and 5-60 mole percent of second phase or phases being metal, alloy, intermetallic compound or combination thereof of one or more of the elements of Groups 3a exclusive of B, 4a, 2b, 4b, 5b, 6b, 7b, iron, cobalt and nickel, wherein the maximum grain size of the first phase or phases is substantially not greater than 10 .mu.m and which body contains 0 to 4 weight percent oxygen.
    Type: Grant
    Filed: June 19, 1987
    Date of Patent: May 24, 1988
    Assignee: Corning Glass Works
    Inventor: Thomas P. DeAngelis
  • Patent number: 4743299
    Abstract: The present invention is directed to a cermet material comprising a matrix of aluminum alloy with ceramic particles distributed therein. The cermet is adapted for use as a semiconductor substrate and is manufactured using powder technology procedures. The cermet comprises from about 40 to about 60 volume % of aluminum or aluminum alloy, from an effective amount up to about 10 volume % of binder for enhancing bonding between the aluminum alloy and ceramic particles, and the balance essentially ceramic particles.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: May 10, 1988
    Assignee: Olin Corporation
    Inventors: Michael J. Pryor, Eugene Shapiro, Deepak Mahulikar
  • Patent number: 4735656
    Abstract: An abrasive material comprised of a metal matrix and evenly distributed ceramic particulates, is made by mixing powder metal with the ceramic powder and heating to a temperature sufficient to melt most, but not all of the powder. In this way the ceramic does not float to the top of the material, yet a dense material is obtained. A nickel superalloy matrix will have at least some remnants of the original powder metal structure, typically some equiaxed grains, along with a fine dendritic structure, thereby imparting desirable high temperature strength when the abrasive material is applied to the tips of blades of gas turbine engines. Preferred matrices have a relatively wide liquidus-solidus temperature range, contain a melting point depressant, and a reactive metal to promote adhesion to the ceramic.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: April 5, 1988
    Assignee: United Technologies Corporation
    Inventors: Robert P. Schaefer, David A. Rutz, Edward Lee, Edward J. Johnson
  • Patent number: 4735770
    Abstract: By the inventive method, an amorphous material in powder form can be produced, whereby at least two starting components in powder form are mechanically alloyed by means of a milling process so that a boron component which cannot be alloyed mechanically can nevertheless be alloyed. According to the invention, a boron component in powder form is admixed to the starting components; this powder mixture is subjected to the milling process, an amorphous alloying component being formed from the starting components with embedded or deposited fine particles of the boron components; and the mixture powder so produced is subjected to an annealing treatment below the crystallization temperature of the amorphous alloy component for diffusing the boron into the amorphous alloy component.
    Type: Grant
    Filed: January 29, 1987
    Date of Patent: April 5, 1988
    Assignee: Siemens Aktiengesellschaft
    Inventors: Ludwig Schultz, Egon Hellstern
  • Patent number: 4734131
    Abstract: A permanent-magnet material having a composition represented by the following formula;R(Co.sub.1-X-Y-.alpha.-.beta. Fe.sub.X Cu.sub.Y M.sub..alpha. M'.sub.62)A(wherein X, Y, .alpha., .beta., and A respectively represent the following numbers:0.01.ltoreq.X, 0.02.ltoreq.Y.ltoreq.0.25, 0.001.ltoreq..alpha..ltoreq.0.15,0.0001.ltoreq..beta..ltoreq.0.001, and 6.0.ltoreq.A.ltoreq.8.3,providing that the amount of Fe to be added should be less than 15% by weight, based on the total amount of the composition, and R, M, and M' respectively represent the following constituents:R: At least one element selected from the group of rare earth elements,M: At least one element selected from the group consisting of Ti, Zr, Hf, Nb, V, and Ta, andM': B or B+Si),is disclosed.
    Type: Grant
    Filed: July 21, 1987
    Date of Patent: March 29, 1988
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Tomohisa Arai, Naoyuki Sori, Seiki Sato, Nobuo Uchida
  • Patent number: 4734253
    Abstract: A sintered magnet of Fe-B-rare earth alloy having an axis of easy magnetization oriented at an angle to a major axis can be directly produced from the alloy material by (a) press molding the material in an applied magnetic field into a compact of the dimensions determined by taking into account factors of shrinkage expected in X, Y and Z directions, and (b) sintering the compact.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: March 29, 1988
    Assignee: TDK Corporation
    Inventors: Kazuo Sato, Shinichi Yamashita
  • Patent number: 4731117
    Abstract: An age-hardenable, corrosion-resistant, nickel-base fully dense article of compacted prealloyed particles. The article has a fine, uniformly distributed gamma-prime phase for strength and hardness. The alloy consists essentially of, in weight percent, carbon 0.05 max, chromium 15 to 25, molybdenum 6.5 to 10, columbuium 4 to 6.5, iron 9 max, aluminum 0.2 to 0.8, nitrogen 0.05 max, titanium, 0.6 max, and balance nickel. The alloy article has an absence of interstitial phases at prior particle boundaries and may be age-hardened to a minimum room-temperature 0.2% offset yield strength of 120,000 psi.
    Type: Grant
    Filed: November 4, 1986
    Date of Patent: March 15, 1988
    Assignee: Crucible Materials Corporation
    Inventors: John E. Stulga, Frank J. Rizzo
  • Patent number: 4731116
    Abstract: Sputter targets and a process for producing sputter targets are provided, comprised of carbides and/or nitrides and/or borides of refractory metals. In a first step, a dense composite body is produced comprised of one or more carbides and/or nitrides and/or borides of the metals of Groups IV A-VI A of the periodic table and a metallic binding agent comprised of one or more metals of the iron group of the periodic table. This composite body in the form of a shaped blank is machined, if necessary, and the binding agent is removed by chemical or electrochemical treatment. The sputter target as so produced has excellent mechanical strength and high thermal shock resistance. Levels of contaminating elements and the residual metallic binding agent are extremely low, meeting the requirements typically placed on sputter targets.
    Type: Grant
    Filed: December 18, 1986
    Date of Patent: March 15, 1988
    Assignee: Schwarzkopf Development Corporation
    Inventor: Erich Kny
  • Patent number: 4731118
    Abstract: A copper or copper alloy infiltrated ferrous powder metal part, and method for making the same, characterized as having after infiltration an overall density of at least 7.50 g/cm.sup.3 and a diffusion depth of copper into the steel matrix of less than about 4 micrometers as determined by chemical etching or less than about 8 micrometers as determined by electron dispersive X-ray analysis (EDXA), wherein said ferrous metal is plain carbon steel having a combined carbon content in the range of about 0.15% to about 1.25%, or a low alloy steel.
    Type: Grant
    Filed: November 28, 1986
    Date of Patent: March 15, 1988
    Assignee: SCM Metal Products, Inc.
    Inventors: Mark Svilar, Erhard Klar
  • Patent number: 4729789
    Abstract: A process of making a composite of a sintered layer on a metal core member, such as an extruder screw having a sintered hard layer on a steel core, by charging a green compact sintering powder material into a space between an inner surface of a compressible mold and an outer surface of a mold core, sealing the compressible mold with the green compact material and the mold core therein, isostatic pressing the sealed compressible mold with the green compact material and the mold core therein, removing the mold core from the isostatically pressed green compact thus forming a cavity therein, inserting a metal core in the cavity in the isostatically pressed green compact with the metal core having a smaller transverse cross-section than the previously removed mold core and shrinking and bonding the isostatically pressed green compact onto the metal core by heating the isostatically pressed green compact and the metal core to a temperature at which the isostatically pressed green compact is sintered resulting in sh
    Type: Grant
    Filed: May 21, 1987
    Date of Patent: March 8, 1988
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Tsuneyuki Ide, Kazunori Nakano, Masaru Inoue, Yoshikazu Kondo