Containing Boron(b) Or Nitrogen(n) Patents (Class 75/244)
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Patent number: 5092920Abstract: A sintered body for high-accuracy working tools is obtained by sintering powder mixture containing at least 45 percent by volume and not more than 60 percent by volume of cubic boron nitride powder having an average particle size of not more than 2 .mu.m and having a remainder formed of binder powder under a superhigh pressure. The binder contains at least 5 percent by weight and not more than 15 percent by weight of Al and at least 2 percent by weight and not more than 20 percent by weight of W, and has a binder remainder formed of a Ti compound or compounds. The atomic ratio of Ti contained in the binder to a transition metal element or elements belonging to any of the groups IVa, Va and/or VIa of the periodic table including Ti is at least 2/3 and not more than 97/100. In the structure of the sintered body, cubic boron nitride crystals are bonded with each other through bonding phases formed by the binder. When at least one or more Ti compounds are selected from a group of TiN.sub.z, Ti(C.sub.1-x N.sub.x).Type: GrantFiled: December 13, 1989Date of Patent: March 3, 1992Assignee: Sumitomo Electric Industries, Ltd.Inventors: Tetsuo Nakai, Mitsuhiro Goto, Tomohiro Fukaya
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Patent number: 5089354Abstract: A copper alloy composite material which comprises a copper alloy matrix and at least one additive selected from solid materials having self-lubricity and wear-resistant materials and uniformly dispersed in the alloy matrix is described. The composite material has improved wear resistance and anti-seizing properties.Type: GrantFiled: December 11, 1990Date of Patent: February 18, 1992Assignee: Chuetsu Metal Works, Co., Ltd.Inventors: Kunio Nakashima, Ryouichi Ishigane, Takayuki Tanaka, Ken-ichi Ichida
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Patent number: 5089047Abstract: A dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The granular hard phase consists essentially of a ceramic material selected from the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, and borides of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, boron, and mixtures thereof. The metal phase consists essentially of a combination of nickel and aluminum having a weight ratio of nickel to aluminum of from about 90:10 to about 70:30 and 0-5% by weight of an additive selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, or carbon, or combinations thereof. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure.Type: GrantFiled: December 20, 1990Date of Patent: February 18, 1992Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5085828Abstract: A rare earth-containing powder is pressed into a compact at ambient temperatures using a solid lubricant applied only to the die wall and/or a core. The solid lubricant is applied by suspending lubricant powder in a fluorinated hydrocarbon liquid.Type: GrantFiled: May 15, 1991Date of Patent: February 4, 1992Assignee: General Motors CorporationInventors: Jon C. Shain, James W. Herchenroeder
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Patent number: 5082433Abstract: Molded articles, particularly cams for camshafts of internal combustion engines, are subjected to high wear conditions. In order to make them resistant to wear, they are produced from a sintered alloy, which has been fabricated by powder metallurgical means. The alloy has a hardened matrix with interstitial copper and consists of 0.5 to 16% by weight of molybdenum, 1 to 20% by weight of copper, 0.1 to 1.5% by weight of carbon and, optionally, of admixtures of chromium, manganese, silicon and nickel totalling, at most, 5% by weight, the remainder being iron.Type: GrantFiled: December 17, 1990Date of Patent: January 21, 1992Assignee: Etablissement SupervisInventor: Karl Leithner
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Patent number: 5077246Abstract: A method for the preparation of ceramic composites containing at least aluminum oxide and aluminum boride, and the composite materials that result from the method. Intimate mixtures of finely-divided powdered aluminum metal and anhydrous boric oxide, with ratios (by weight) of about 0.5 to twenty parts of aluminum metal to one part of boric oxide, are subjected to a temperature to cause a complete reaction between the starting materials. If the ratio is above about 1.25 parts of aluminum to one part of boric oxide, the resultant product will include aluminum in addition to the aluminum oxide and aluminum boride. The ratio is selected to provide the desired hardness and toughness. Ratios between about 1 and 1.2 provide a composite having the highest hardness, with greater amounts of aluminum metal providing increased toughness. Several compositions are described, with hot pressing typically being used to provide the desired heating cycle.Type: GrantFiled: June 4, 1990Date of Patent: December 31, 1991Assignee: Apollo Concepts, Inc.Inventors: Samuel C. Weaver, Sally G. Padron
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Patent number: 5069713Abstract: A non-sintered permanent magnet is formed by a cold compacting technique or by resin bonding using particles of a stoichiometric alloy (e.g. R.sub.2 Fe.sub.14 B where R is at least one rare earth and/or yttrium, particularly La, Ce, Pr, ND or Y or a mixture thereof) which have been coated with a reaction product of the alloy or a non-magnetic metal such as Sn, Ga, Zn, Al, or Cu. The use of a stoichiometric alloy avoids the presence of a reactive grain boundary phase normally present in non-stoichiometric alloys.Type: GrantFiled: April 4, 1988Date of Patent: December 3, 1991Assignee: The University of BirminghamInventors: Ivor R. Harris, Syed H. Safi
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Patent number: 5068072Abstract: The present invention relates to a zirconia-based sintered body comprising TiN, TiO.sub.2 and ZrO.sub.2 and having electric conductivity and a process for the production thereof. The present invention provides a zirconia-based sintered body which has, at normal temperature, a mechanical strength of not less than 50 kg/mm.sup.2, a fracture toughness of not less than 4 MPam.sup.1/2, a Vickers hardness of not less than 1,000 kg/mm.sup.2 and a volume resistivity of not more than 1 .OMEGA.cm, and which is sinterable under normal pressure at low temperature, and a process for the production thereof.Type: GrantFiled: December 11, 1989Date of Patent: November 26, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Kazuo Horinouchi, Masahide Mouri, Isao Kameda
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Patent number: 5053074Abstract: A dense cermet article including about 80-90% by volume of a granular hard phase and about 5-20% by volume of a metal phase. The hard phase is a carbide, nitride, carbonitride, oxycarbide, oxynitride, or carboxynitride of a cubic solid solution selected from W-Ti, W-Hf, W-Nb, W-Ta, Zr-Ti, Hf-Ti, Hf-Zr, V-Ti, Nb-Ti, Ta-Ti, or Mo-Ti. The metal phase consists essentially of a combination of nickel and aluminum having a ratio of nickel to aluminum of from about 90:10 to about 70:30 by weight, and 0-5% by weight of an additive selected from titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, cobalt, boron, and/or carbon. The preferred hard phase is a cubic solid solution of tungsten and titanium. In the preferred metal phase, an amount of about 15-80% by volume of the metal phase component exhibits a Ni.sub.3 Al ordered crystal structure. The article may be produced by presintering the hard phase - metal phase component mixture in a vacuum or inert atmosphere at about 1475.Type: GrantFiled: December 20, 1990Date of Patent: October 1, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5051231Abstract: A method for the fabrication of a superplastic composite material having metallic aluminum reinforced with silicon nitride includes thoroughly mixing silicon nitride with metallic aluminum, pressure-sintering the resultant mixture, further heating and pressing the sintered mixture, hot extrusion-molding the resultant sintered article, subjecting the molded article, when necessary, to a heat treatment such as the T6 treatment thereby forming a superplastic composite material, and deforming the composite material in a temperature region in which the material exhibits superplasticity.Type: GrantFiled: September 14, 1990Date of Patent: September 24, 1991Assignees: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Tsunemichi Imai, Mamoru Mabuchi
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Patent number: 5051126Abstract: A cermet contains 70 to 95 volume percentage of a hard dispersed phase and 30 to 5 volume percentage of a binder phase comprising one or more metals in group VIII (the iron group), wherein the hard dispersed phase contains as its components transitional metals in group IVb, transitional metals in group Vb, W alone of transitional metals in group VIb, C, and N, and consists of two structurally different types of particles. One type of the particles are single phase particles constituting 5% to 50% of the hard dispersed phase, whereas the other type of the particles are dual phase particles constituting 95% to 5% of the same. The cermet is for use in tools such as coating tools, spike pins, hobs, reamers, screw drivers, and so forth.Type: GrantFiled: January 12, 1990Date of Patent: September 24, 1991Assignee: NGK Spark Plug Co., Ltd.Inventors: Hajime Yasui, Junichiro Suzuki
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Patent number: 5049183Abstract: A method of manufacturing a sintered machine part, by which the machine part can be manufactured to be sufficiently strong, wear and abrasion resistive, and durable against the fatigue caused by recursive impacts, without the heat treatments. In the method, a machine part composed of 0.1 to 0.8% of carbon by weight, 2 to 6% of nickel by weight, 0.6 to 1.6% of molybdenum by weight, 1 to 3% of copper by weight and balance iron is manufactured by mixing partially diffused alloy powder composed of 2 to 6% of nickel by weight, 0.4 to 0.6% of molybdenum by weight, 1 to 3% of copper by weight and balance iron with graphite powder amounting to 0.1 to 0.8% by weight and molybdenum simple powder having 2 to 7 .mu.m mean particle size amounting to 0.2 to 1% by weight, and then by compacting the mixed powder and sintering the compact.Type: GrantFiled: September 28, 1990Date of Patent: September 17, 1991Assignees: Hitachi Powdered Metals Co., Ltd., Honda Giken Kogyo Kabushiki KaishaInventors: Tsutomu Saka, Akira Fujiwara, Tadayuki Tsutsui, Osamu Murai, Kei Ishii
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Patent number: 5049208Abstract: A permanent magnet having high coercivity and energy product contains rare earth elements, boron, at least one element of Ti, V, Cr, Zr, Nb, Mo, Hf, Ta and W, and a blance of Fe or Fe and Co, and consists of a primary phase of substantially tetragonal grain structure, or a mixture of such a primary phase and an amorphous or crystalline rare earth element-poor auxiliary phase wherein the volume ratio of auxiliary phase to primary phase is smaller than a specific value.Type: GrantFiled: July 29, 1988Date of Patent: September 17, 1991Assignee: TDK CorporationInventors: Koichi Yajima, Osamu Kohmoto, Tetsuhito Yoneyama
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Patent number: 5041261Abstract: A method for manufacturing a dense cermet article including about 80-95% by volume of a granular hard phase and about 5-20% by volume of a metal binder phase. The hard phase is (a) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, carboxynitrides, borides, and mixtures thereof of the elements selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, and B, or (b) the hard refractory carbides, nitrides, carbonitrides, oxycarbides, oxynitrides, and carboxynitrides, and mixtures thereof of a cubic solid solution of Zr--Ti, Hf--Ti, Hf--Zr, V--Ti, Nb--Ti, Ta--Ti, Mo--Ti, W--Ti, W--Hf, W--Nb, or W--Ta. The binder phase is a combination of Ni and Al having a Ni:Al weight ratio of from about 85:15 to about 88:12, and 0-5% by weight of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Co, B, and/or C. The method involves presintering the hard phase/binder phase mixture in a vacuum or inert atmosphere at about 1475.degree.-1675.degree. C., then HIPing at about 1575.degree.-1675.degree. C.Type: GrantFiled: December 21, 1990Date of Patent: August 20, 1991Assignee: GTE Laboratories IncorporatedInventors: Sergej T. Buljan, Helmut Lingertat, Steven F. Wayne
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Patent number: 5041399Abstract: A hard sintered body for tools is obtained by sintering under a superhigh pressure, a sinter powder mixture containing at least 20 percent by volume and not more than 70 percent by volume of cubic boron nitride powder and having a remainder formed of a binder powder mixture. The binder contains at least 2 percent by weight and not more than 20 percent by weight of Al and at least 2 percent by weight and not more than 20 percent by weight of W, and has a remainder formed of a Ti compound or compounds. The atomic ratio of Ti contained in the binder to a transition metal element or elements belonging to any of the groups IVa, Va and/or VIa of the periodic table including Ti is at least 2/3 and not more than 97/100. In the structure of the sintered body, cubic boron nitride crystals are bonded with each other through bonding phases formed by the binder. For forming the sintered body, at least one or more Ti compounds are selected from a group of TiN.sub.z, Ti(C,N).sub.z, TiC.sub.z, (Ti,M)N.sub.z, (Ti, M) (C,N).Type: GrantFiled: December 13, 1989Date of Patent: August 20, 1991Assignee: Sumitomo Electric Industries, Ltd.Inventors: Tomohiro Fukaya, Tetsuo Nakai, Mitsuhiro Goto
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Patent number: 5039633Abstract: Reactive ceramic-metal compositions are described that include a ceramic phase of at least 70 percent by volume, 95 percent of theoretical density and a metal phase that retains its chemical reactivity with the ceramic phase after the composition has been fully densified. The composition may be heat treated after densification to form additional ceramic phases in a controllable manner. Preferred ceramic metal compositions wherein the metal and ceramic components retain reactivity after densification include boron carbide ceramic and Al or Mg metals. The process employed in forming said compositions requires first forming a sintered porous body of the ceramic material followed by contacting with the metal component, which may be in chip or solid bar form. The system is then heated to the melting point of the metal and a pressure of at least 200 MPa is employed such that the porous body is filled with metal and the composition is substantially fully densified.Type: GrantFiled: September 14, 1989Date of Patent: August 13, 1991Assignee: The Dow Chemical CompanyInventors: Aleksander J. Pyzik, Robert T. Nilsson
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Patent number: 5036028Abstract: A high density metal-boride based ceramic sintered body consists essentially of component (A) at least one of TiB.sub.2, ZrB.sub.2, CrB.sub.2, HfB.sub.2, VB.sub.2, TaB.sub.2, NbB.sub.2, MnB.sub.2, MoB.sub.2, YB.sub.2, AlB.sub.2, MgB.sub.2, CrB, VB, TaB, NbB, MoB, HfB, YB, ZrB, HfB, TiB, MnB, W.sub.2 B.sub.5 and Mo.sub.2 B.sub.5, componet (B) 0.1 wt. %-10 wt. % based on the total amount of a metal binder comprising at least one of cobalt boride, nickel boride and iron boride, and component (C) 0.1 wt. %-10 wt. % based on the total amount of at least one of a double carbide comprising Ti, Zr, W and C, ZrCN, HfCN, or a double carbo-nitride comprising Ti, Zr, Hf and C, N.The sintered body is not easily oxidized and has extremely few pores and high shock resistance even using a fine grain raw material powder because component (C) has an oxygen removing effect during sintering.Type: GrantFiled: April 18, 1990Date of Patent: July 30, 1991Assignee: Agency of Industrial Science and TechnologyInventors: Tadahiko Watanabe, Tsuyoshi Doutsu, Kazuhisa Shobu, Yukio Kai
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Patent number: 5034282Abstract: Process for the powder-metallurgical production of work pieces, particularly tools, containing high-melting point carbides and/or carbonitrides homogeneously distributed in a matrix, in which an amount of elements of the IVa and Va groups, or secondary groups, of the periodic table is adjusted to at least 3 weight percent of the alloy, a low carbon and/or nitrogen concentration is established, and primary precipitates are prevented; and a desired carbon and/or nitrogen content is created by atomization of the melt into powder vaporizing medium.Type: GrantFiled: March 5, 1990Date of Patent: July 23, 1991Assignee: Boehler Gesellschaft m.b.H.Inventors: Bruno Hribernik, Gerhard Hackl
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Patent number: 5034146Abstract: The magnetic properties or, in particular, coercive force of a sintered permanent magnet composed of a light rare earth element, boron and iron can be greatly improved without affecting the residual magnetic flux by the admixture of a relatively small amount of additive elements including heavy rare earth elements, aluminum, titanium, vanadium, niobium and molybdenum. In the inventive magnets, the distribution of the additive element is not uniform but localized in the vicinity of the grain boundaries of the matrix particles. Such a localized distribution of the additive elements is obtain by sintering a powder mixture composed of a powder of an alloy of the base ingredients and a powder containing the additive element or elements.Type: GrantFiled: July 16, 1990Date of Patent: July 23, 1991Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Ken Ohashi, Yoshio Tawara
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Patent number: 5030277Abstract: A method for fabricating a titanium aluminide composite structure consisting of a filamentary material selected from the group consisting of silicon carbide, silicon carbide-coated boron, boron carbide-coated boron, titanium boride-coated silicon carbide and silicon-coated silicon carbide, embedded in an alpha-2 titanium aluminide metal matrix, which comprises the steps of providing a first beta-stabilized Ti.sub.3 Al powder containing a desired quantity of beta stabilizer, providing a second beta-stabilized Ti.sub.3 Al powder containing a sacrificial quantity of beta stabilizer in excess of the desired quantity of beta stabilizer, coating the filamentary material with the second powder, fabricating a preform consisting of the thus-coated filamentary materials surrounded by the first powder, and applying heat and pressure to consolidate the preform.The composite structure fabricated using the method of this invention is characterized by its lack of a denuded zone and absence of fabrication cracking.Type: GrantFiled: December 17, 1990Date of Patent: July 9, 1991Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Daniel Eylon, William C. Revelos, Paul R. Smith, Jr.
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Patent number: 5026419Abstract: Anisotropic hot-worked permanent magnets are made from an R-T-B alloyed powder to which is added a combination internal lubricant including a carbon-based material such as graphite and a glass material such as glass from the B.sub.2 O.sub.3 --SiO.sub.2 --BiO.sub.3 glass system. The internal lubricant provides improved formability during the hot-working step, such as die-upsetting, and provides finished magnet products wherein the individual grains are more uniformly plastically deformed throughout the product.Type: GrantFiled: April 25, 1990Date of Patent: June 25, 1991Assignee: Hitachi Metals, Ltd.Inventors: Katsunori Iwasaki, Shigeho Tanigawa, Masaaki Tokunaga
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Patent number: 5022919Abstract: A complex boride cermet having high strength and high toughness, which comprises a hard phase composed mainly of a boride of (Mo.sub.1-x W.sub.x).sub.2 NiB.sub.2 formed by substituting a part of Mo of Mo.sub.2 NiB.sub.2 by W, and a matrix alloy phase composed mainly of Ni and containing Mo, and a complex boride cermet comprising a hard phase composed mainly of Mo.sub.2 NiB.sub.2 or (Mo.sub.1-x W.sub.x).sub.2 NiB.sub.2 and a matrix of an alloy phase composed mainly of Ni and containing Mo, which is characterized in that carbon or/and nitrogen, and optionally at least one metal selected from the metals of Groups 4B and 5B and Cr, are incorporated to further improve the strength and toughness. Such complex boride cermet has high strength and high toughness and maintains such properties even at elevated temperatures of from 600.degree. to 900.degree. C.Type: GrantFiled: May 16, 1989Date of Patent: June 11, 1991Assignee: Asahi Glass Company Ltd.Inventors: Yasuo Shinozaki, Noritoshi Horie, Kazuo Hamashima, Makoto Imakawa
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Patent number: 5017217Abstract: A method for manufacturing ceramic/metal or ceramic/ceramic composite articles is disclosed. The articles can be useful for the production of aluminum in fused salt electrolysis cells, as armor plates for the protection against projectiles, cutting tools, or in abrasion resistance applications. The temperature slope of the process if optimized such that one of the reactants in the manufacturing proceeds through peritectic decomposition at a heating rate of low temperature increase for desirably uniform temperature distribution over the reaction mixture. Then the temperature increase is greatly elevated to obtain a reaction sintering condition for avoiding grain growth of undesired reaction products. Elevated temperature reaction sintering conditions can be maintained to decompose undesired components before they are entrapped by the reaction product.Type: GrantFiled: August 21, 1990Date of Patent: May 21, 1991Assignee: Eltech Systems CorporationInventors: Thomas M. Clere, Gholamreza J. Abbaschian, Douglas J. Wheeler, Albert L. Barnes
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Patent number: 5015290Abstract: An improved ceramic-metal composite comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni.sub.3 Al.Type: GrantFiled: October 12, 1989Date of Patent: May 14, 1991Assignee: The Dow Chemical CompanyInventors: Terry N. Tiegs, Robert R. McDonald
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Patent number: 5009706Abstract: Rare-earth alloy anisotropic powders consist of, in atomic percent, over 12 percent and not more than 20 percent of R (R is at least one on neodymium and praseodymium or at least one of them and or more rare-earth elements), not less than 4 percent and not more than 10 percent of boron, not less than 0.05 percent and not more than 5 percent of copper and the rest that consists of iron and unavoidable impurities. Up to 20 percent of the iron contained is replaceable with cobalt. The alloy powders are made up of flat crystal grains having mean thickness h (the shortest measure), d not smaller than 0.01 .mu.m and not larger than 0.5 .mu.m and ratio d/h not smaller than 2, where d is the means measure of the grains taken at right angles to the widthwide direction thereof, and the alloy powders are magnetically anisotropic.Type: GrantFiled: July 18, 1990Date of Patent: April 23, 1991Assignee: Nippon Steel CorporationInventors: Hiroaki Sakamoto, Masahiro Fujikura, Toshio Mukai
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Patent number: 5009704Abstract: A nickel-based superalloy article formed from particles of the superalloy is processed to have a microstructure which is resistant to failure when processed using high strain thermomechanical processes. Articles having the desired microstrucuture are produced by hot isostatically pressing powder of the superalloy in a specified temperature range bounded by the incipient melting temperature as a minimum and the solvus temperature of stable high temperature phases. The compact is held under pressure in the specified temperature range to diffuse deleterious phases which exist as a result of the initial powder atomization operation. The powder compact thus formed can be processed using conventional processes to produce material for subsequent thermomechanical processing using high strain rate forging equipment and retain the benefits of chemical uniformity and cleanliness associated with traditional powder metal processes.Type: GrantFiled: June 28, 1989Date of Patent: April 23, 1991Assignee: Allied-Signal Inc.Inventor: Anthony Banik
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Patent number: 5007956Abstract: An assembled cam shaft including a steel cam shaft member, a journal member made of sintered material and a cam lobe. The sintered material consisting essentially of 0.5 to 4.0% by weight of carbon, 0.1 to 0.8% by weight of phosphorus, 5 to 50% by weight of copper, 1% by weight or less of manganese, 2% by weight or less of silicon, and the balance being iron and impurities.Type: GrantFiled: October 27, 1988Date of Patent: April 16, 1991Assignee: Nippon Piston Ring Co., Ltd.Inventors: Yoshiaki Fujita, Satoshi Kawai, Shunsuke Takeguchi
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Patent number: 5004498Abstract: A dispersion strengthened copper alloy containing a copper matrix, and dispersion particles dispersed in the copper matrix within a range of 0.5 to 6 vol %. In this alloy, an average diameter of a matrix region where the dispersion particles are not present is 0.3 .mu.m or less, and the total amount of solid solution elements contained in the copper matrix is determined such that, when this amount of the solid solution elements is added to pure copper, the electric conductivity of the matrix is lowered by 5% IACS or less.Type: GrantFiled: October 10, 1989Date of Patent: April 2, 1991Assignee: Kabushiki Kaisha ToshibaInventors: Keizo Shimamura, Kagetaka Amano, Tatsuyoshi Aisaka, Satoshi Hanai, Kohsoku Nagata
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Patent number: 5000779Abstract: The subject of this invention is the development of new alloys along with new processing approaches for the utilization of the alloys. A particular class of alloys comprises at least one noble metal selected from the group comprising gold, palladium, silver and copper and an amount of between about 0.20 weight percent and about 0.80 weight percent of at least one metalloid selected from the group of metalloids consisting of boron, phosphorous, silicon and lithium. Rapid solidification technology in powder fabrication and the addition of metalloids have been combined to produce a new class of palladium based alloys. The metalloid additions greatly increase the hardness, enhance the fine grain structure and aid sintering densification. Net-shape forming is a benefit derived from the characteristics of the new alloys.Type: GrantFiled: May 18, 1988Date of Patent: March 19, 1991Assignee: Leach & GarnerInventors: Randall M. German, Laura L. Bourguignon, Dwarika P. Agarwal, Shaji Faroog
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Patent number: 4999336Abstract: There is provided a substantially fully dense powdered metal composite comprising a highly conductive metal or metal alloy matrix having dispersed therein discrete microparticles of a refractory metal oxide and discrete macroparticles of a mechanical or physical property-conferring additive material. The respective components undergo minimal alloying or interdispersion because sintering is not utilized in forming the composite. These composites are characterized by high thermal or electrical conductivity and a desired property (controlled thermal expansion, high strength, wear and arc erosion resistance, or magnetic) attributable to the composite forming material, like refractory metal, alloy, or compound. The composites are useful in forming lead frames for integrated circuit chips, electric lamp lead wires, electrical contact members, and discrete component leads.Type: GrantFiled: June 17, 1988Date of Patent: March 12, 1991Assignee: SCM Metal Products, Inc.Inventors: Anil Nadkarni, Prasan K. Samal, James E. Synk
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Patent number: 4999050Abstract: This invention relates generally to materials and processes for making materials and, more particularly, to high performance boride dispersion strengthened materials, including alloy-modified, boride dispersion strengthened materials and techniques for making such materials.Type: GrantFiled: August 30, 1988Date of Patent: March 12, 1991Assignee: Sutek CorporationInventors: Luis E. Sanchez-Caldera, Arthur K. Lee, Nam P. Suh, Jung-Hoon Chun
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Patent number: 4995905Abstract: When V is added to an Nd--Fe--B sintered magnet so as to modify the minority phase such that B in excess of a stoichiometric composition of R.sub.2 Fe.sub.14 B compound-phase, essentially does not form RFe.sub.4 B.sub.4 -compound minority phases but forms a finely dispersed V--T--B compound minority phase (T is Fe, and in a case containing Co, T is Fe and Co), the coercive force (iHc) is enhanced to 15 kOe or more but becomes very sensitive to heat treatment temperature. This drawback is eliminated by the addition of from 0.01 to 1 at % of Cu.Type: GrantFiled: May 23, 1989Date of Patent: February 26, 1991Assignee: Masato SagawaInventor: Masato Sagawa
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Patent number: 4992234Abstract: An improved method is proposed for the preparation of a sintered permanent magnet of a rare earth-iron-boron alloy having remarkably improved magnetic properties and stability by the powder metallurgical process. The scope of the inventive method consists in the particle size classification of the alloy powder for compression molding into a powder compact to be sintered, by which particles having a finer particle diameter and, preferably, a coarser particle diameter than the respective critical values are removed so as to effectively prevent oxidation of the too fine particles and improving the magnetic orientation of the particles as well as the sintering behavior of the particles.Type: GrantFiled: July 19, 1990Date of Patent: February 12, 1991Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Ken Ohashi, Masanobu Shimao
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Patent number: 4990306Abstract: The invention relates to a method of producing a sintered Nd-Fe-B magnet which has a cylindrical or annular shape and is magnetized in radial directions with polar anisotropic orientation. In a cylindrical mold cavity filled with a Nd-Fe-B magnetic alloy powder a pulse of magnetic field is produced so as to cause polar anisotropic orientation of the magnetic powder with at least six poles distributed around the circumference, and a pulse-like pressure is applied to the powder in the mold cavity to compact the powder into a cylindrically shaped body while the pulse of magnetic field is lasting. The shaped body is sintered, and subsequently the side surface of the sintered body is abraded to remove projecting regions, which are attributed to anisotropic shrinkage during sintering, until the surface becomes accurately cylindrical.Type: GrantFiled: November 17, 1989Date of Patent: February 5, 1991Assignee: Shin-Etsu Chemical Co., Ltd.Inventor: Ken Ohashi
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Patent number: 4990180Abstract: A self-sustaining combustion synthesis process for producing hard, tough, lightweight, low exothermic potential product (LEPP)/high exothermic potential product (HEPP) composites is based on the thermodynamic dependence of adiabatic temperature and product composition on the stoichiometry of the LEPP and HEPP reactants. For lightweight products the composition must be relatively rich in the LEPP component. LEPP rich composites are obtained by varying the initial temperature of the reactants. The product is hard, porous material whose toughness can be enhanced by filling the pores with aluminum or other metal phases using a liquid metal infiltration process. The process can be extended to the formation of other composites having a low exothermic component.Type: GrantFiled: September 1, 1989Date of Patent: February 5, 1991Assignee: The United States of America as represented by the United States Department of EnergyInventors: Danny C. Halverson, Beverly Y. Lum, Zuhair A. Munir
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Patent number: 4990410Abstract: A surface refined sintered alloy with a burnt surface, comprising 75 to 95% by weight of a hard phase containing Ti, C and N as the essential components and otherwise comprising at least one of Zr, Hf, V, Nb, Ta, Cr, Mo and W and the balance of the alloy comprising a binder phase composed mainly of Co and/or Ni and inevitable impurities, wherein the sintered alloy satisfies at least two conditions selected from the group consisting of the following (1) to (3):(1) the average grain size of the hard phase in a surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.8 to 1.2-fold of the average grain size of the hard phase in the inner portion of the sintered alloy excluding the surface layer;(2) the average content of the binder phase in the surface layer to the inner portion of 0.05 mm from the burnt surface of the sintered alloy is 0.7 to 1.Type: GrantFiled: March 7, 1989Date of Patent: February 5, 1991Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Takeshi Saitoh, Tuyoshi Saito, Mitsuo Ueki, Hisashi Suzuki, Keiichi Kobori
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Patent number: 4985070Abstract: There are disclosed a high strength nitrogen-containing cermet which comprises 7 to 20% by weight of a binder phase composed mainly of Co and/or Ni, with the balance being a hard phase composed mainly of TiC, TiN and/or Ti(C,N) and inevitable impurities, wherein the hard phase comprises 35 to 59% by weight of Ti, 9 to 29% by weight of W, 0.4 to 3.5% by weight of Mo, 4 to 24% by weight of at least one of Ta, Nb, V and Zr, 5.5 to 9.5% by weight of N and 4.5 to 12% by weight of C; and a process for preparing the same which comprises via the formulating, mixing, drying, molding and sintering steps of Co and/or Ni powder, at least one powder of TiC, Ti(C,N) and TiN, WC powder, Mo and/or Mo.sub.2 C, and at least one powder of carbides of Ta, Nb, V and Zr, wherein the sintering step is carried out by elevating the temperature up to 1350.degree. C. in vacuum, with the nitrogen atmosphere being made 1 torr at 1350.degree. C.Type: GrantFiled: July 21, 1989Date of Patent: January 15, 1991Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Kozo Kitamura, Takeshi Saitoh, Mitsuo Ueki, Keiichi Kobori
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Patent number: 4983212Abstract: Disclosed are a cermet alloy having excellent wear resistance and strength at elevated temperatures, and a composite mechanical part containing a strong layer of any such cermet alloy formed on the outer or inner surface of an alloy base.The materials which are used for making rolls, dies, punches, etc. are required to have excellent toughness, impact resistance, high-temperature strength and wear resistances. The conventional ultrahard WC--Co alloys are, however, unsatisfactory in high-temperature strength, through they have a satisfactorily high level of wear resistance. The conventional cermet alloys are low in toughness and impact strength, though they have high oxidation resistance. There has not been availabe any alloy that satisfies all of the requirements as herein-above stated.Type: GrantFiled: June 23, 1989Date of Patent: January 8, 1991Assignee: Hitachi Metals, Ltd.Inventors: Yuusuke Iyori, Hidetoshi Yokoo
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Patent number: 4983231Abstract: There is provided a surface-treated magnetic powder that can form a resin-bonded permanent magnet with large magnetic force and a high maximum energy product, which magnetic properties do not decrease even after the long periods of time. The surface-treated magnetic powder is obtained by treating a magnetic powder made of an alloy that comprises a rare earth metal and iron with a treatment agent containing a alkali-modified silica particles as a major component, wherein the alkali-modified silica particles are obtained by reacting silica particles with a mean particle diameter of from 0.005 to 0.1 .mu.m with an alkali to modify only the surface portion of the silica particles by the alkali.Type: GrantFiled: May 18, 1989Date of Patent: January 8, 1991Assignee: Daihachi Chemical Industry Co., Ltd.Inventors: Hiroshi Yamanaka, Yasuhiro Nakamura
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Patent number: 4981511Abstract: A compound or composite powder which includes metallic or ceramic whiskers embedded in a metallic or ceramic matrix as host material, the whiskers have a length between 5.times.10.sup.-6 m and 2.times.10.sup.-4 m and diameters between 2.times.10.sup.-7 m and 1.times.10.sup.-5 m, and are embedded in the matrix with a volume proportion of whisker content between 1 to 50% (by volume), the reference being to a pore-free compacted compound/composite material; the whiskers being made of SiC, Si.sub.-3 N.sub.-4, Al.sub.-2 O.sub.-3 or ZrO.sub.-2 and are embedded in a ceramic matrix being Al.sub.-2 O.sub.-3, Al.sub.-2 O.sub.-3 +from 5 to 40% ZrO.sub.-2 +from 0 to 5% Y.sub.-2 O.sub.-3 or ZrO.sub.-2 with 3 to 15% Y.sub.-2 O.sub.-3 or Si-nitride or Si-carbide. Alternatively the whiskers are made of Si.sub.-3 N.sub.-4, Al.sub.-2 O.sub.-3, ZrO.sub.-2 or W and the matrix is made of W, Mo, Fe, Ni, Co, Cu or an alloy thereof.Type: GrantFiled: May 16, 1988Date of Patent: January 1, 1991Assignee: Dornier System GmbHInventors: Rainer Schmidberger, Tilman Haug, Reinhard Marquardt, Juergen Bocan
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Patent number: 4980122Abstract: A superplastic composite material is produced by thoroughly and homogeneously mixing particles or whiskers of silicon nitride and aluminum metal powder in a solvent, then removing the solvent from the resultant mixture, sintering the residual mixture at an elevated temperature, further compressing it at an elevated temperature, then hot extrusion-molding the compressed mixture thereby forming a shaped article, and heat-treating this shaped article.Type: GrantFiled: March 23, 1990Date of Patent: December 25, 1990Assignee: Agency of Industrial Science & Technology, Ministry of International Trade & IndustryInventors: Tsunemichi Imai, Mamoru Mabuchi
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Patent number: 4975130Abstract: Permanent magnet materials of the Fe--B--R type are produced by:preparing a metallic powder having a mean particle size of 0.3-80 microns and a composition of 8-30 at % R, 2-28 at % B, and the balance Fe,compacting, andsintering, at a temperature of 900-1200 degrees C. Co up to 50 at % may be present. Additional elements M (Ti, Ni, Bi, V, Nb, Ta, Cr, Mo, W, Mn, Al, Sb, Ge, Sn, Zr, Hf) may be present. The process is applicable for anisotropic and isotropic magnet materials.Type: GrantFiled: May 19, 1987Date of Patent: December 4, 1990Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Yutaka Matsuura, Masato Sagawa, Setsuo Fujimura
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Patent number: 4975129Abstract: A magnetically anisotropic sintered permanent magnet of the FeBR system in which R is sum of R.sub.1 and R.sub.2 wherein:R.sub.1 is Dy, Tb, Gd, Ho, Er, Tm and/or Yb, andR.sub.2 comprises 80 at % or more of Nd and Pr in R.sub.2 and the balance of at least one of other rare earth elements exclusive of R.sub.1,said system comprising by atomic percent, 0.05 to 5% of R.sub.1, 12.5 to 20% of R, 4 to 20% of B, and the balance being Fe with impurities. Additional elements M(Ti, Zr, Hf, Cr, Mn, Ni, Ta, Ge, Sn, Sb, Bi, Mo, Nb, Al, V, W,) may be present.Type: GrantFiled: September 27, 1988Date of Patent: December 4, 1990Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura, Hitoshi Yamamoto, Norio Togawa
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Patent number: 4973355Abstract: The invention relates to sintered hard metals having high cutting properties, particularly plastic deformation resistance at high temperatures, crater resistance and the like, suitable for use as cutting tools, wear resistant tools and materials for dies, and the method for producing the same. The invention has for an object to obtain both sintered hard metals having the aforesaid high properties by sintering metallic components comprising IVa group metals, VIa group metals or metals of both groups substituted by Va group metals up to 60 mol % respectively, a B-1 type solid solution hard phase consisting of non-metallic components of C, N and O, and a metallic bonding phase, in a CO gas atmosphere, and to sintered hard metals in which an uniform hardness is imparted to the surface and interior thereof by the method of sintering the said sintered hard metal in a CO gas atmosphere.Type: GrantFiled: October 31, 1988Date of Patent: November 27, 1990Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kunihiro Takahashi, Toshio Nomura, Takaharu Yamamoto
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Patent number: 4973356Abstract: The present invention relates to a method of preparing an alloy for use as a cutting tool material comprising hard principles and binder phase by which a uniform distribution of the hard principles in the binder phase is obtained, and the resulting product.Type: GrantFiled: October 23, 1989Date of Patent: November 27, 1990Assignee: Sandvik ABInventors: Peder von Holst, Hakan Morberg, Rolf Oskarsson
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Patent number: 4971624Abstract: Erosion and abrasion resistant refractory metal carbide articles are provided having multiphase alloy of borides including titanium boride, binder metal boride, and titanium-binder metal-refractory metal borides by diffusion of titanium initially to convert the refractory metal carbide to its constitutents which are then reacted with boron, forming a new added surface in replacement of the original article surface, and bridging the original surface locus.Type: GrantFiled: December 22, 1988Date of Patent: November 20, 1990Inventors: Eugene V. Clark, George K. Sievers
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Patent number: 4968347Abstract: A high energy rare earth-ferromagnetic metal permanent magnet is disclosed which is characterized by improved intrinsic coercivity and is made by forming a particulate mixture of a permanent magnet alloy comprising one or more rare earth elements and one or more ferromagnetic metals and forming a second particulate mixture of a sintering alloy consisting essentially of 92-98 wt. % of one or more rare earth elements selected from the class consisting of Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and mixtures of two or more of such rare earth elements, and 2-8 wt. % of one or more alloying metals selected from the class consisting of Al, Nb, Zr, V, Ta, Mo, and mixtures of two or more of such metals. The permanent magnet alloy particles and sintering aid alloy are mixed together and magnetically oriented by immersing the mixture in an axially aligned magnetic field while cold pressing the mixture.Type: GrantFiled: November 22, 1988Date of Patent: November 6, 1990Assignee: The United States of America as represented by the United States Department of EnergyInventors: Ramamoorthy Ramesh, Gareth Thomas
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Patent number: 4968348Abstract: A titanium-based metal matrix microcomposite material. About 1% to about 25% by weight TiB.sub.2 is substantially uniformly incorporated in a titanium-based alloy matrix. The microcomposite material is formed by sintering at a temperature selected to preclude diffusion of TiB.sub.2 into the matrix. The microcomposite material may be used in a process for cladding a macrocomposite structure.Type: GrantFiled: November 28, 1989Date of Patent: November 6, 1990Assignee: Dynamet Technology, Inc.Inventors: Stanley Abkowitz, Harold L. Heussi, Harold P. Ludwig, David M. Rowell, Stephen A. Kraus
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Patent number: 4966626Abstract: A sintered ferro alloy comprises 5 to 25 wt % of one or two elements selected from Mo and W, 2 to 10 wt % of Cr, 0.1 to 0.9 wt % of Si, less than or equal to 0.7 wt % of Mn, less than or equal to 0.05 wt % of P, 0.5 to 2.0 wt % of C, 0.5 to 2.0 wt % of B, 0.1 to 7.0 wt % of at least one element selected from borides of La, Ce, Nd, Sm, Eu, Gd, Yb, Y or Sc, residual Fe, and contaminants. Also the alloy may comprise less than or equal to 20 wt % of at least one element selected from V, Nb, Ta, Ti, Zr, Hf, Co or Ni, if necessary. The alloy is produced by mixing the above mentioned components and pressurizing them in an Fe matrix, then sintering the pressurized mixture at 1150.degree. C. to 1260.degree. C. for 60 min. and reheating after sintering. This alloy has wear and heat resistance and can be utilized as valve seats for internal combustion engines in automotive vehicles.Type: GrantFiled: June 28, 1989Date of Patent: October 30, 1990Assignees: Nissan Motor Company, Limited, Hitachi Powdered Metals Company, LimitedInventors: Akira Fujiki, Yoshiteru Yasuda, Hiroyuki Endo, Yutaka Ikenoue, Keitaro Suzuki
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Patent number: 4965044Abstract: The present invention relates to a method of sintering ceramics and ceramics obtained by said method. According to the present invention, the synthesis and sintering of ceramics can be simultaneously carried out by utilizing the reaction heat generated when at least one metallic element selected from metallic elements of IIb, IVb, Vb and VIb groups of the Periodic Table is combined with at least one nonmetallic element such as B, C N and Si without heat or by preliminarily heating the ceramics at temperatures remarkably lower than the usual sintering temperature ceramics thus-produced are superior in abrasion resistance and corrosion resistance.Type: GrantFiled: August 11, 1989Date of Patent: October 23, 1990Assignees: I. Sumitomo Electric Industries, Ltd., Yoshinari Miyamoto, Osamu Yamada, Mitsue KoizumiInventors: Yoshinari Miyamoto, Osamu Yamada, Mitsue Koizumi, Osamu Komura, Eiji Kamijo, Masaaki Honda, Akira Yamakawa