Step At Less Than 300 Degrees C Using Nonmetallic Material Which Is Liquid Under Standard Conditions Is Reduction To Free Metal Patents (Class 75/420)
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Patent number: 9068242Abstract: The present invention provides a valuable metal leaching method and a valuable metal collection method, in each of which valuable metals can be leached efficiently, the amount of a reducing agent used can be reduced, and cost reduction can be achieved. In the present invention, a positive electrode material is immersed in an acidic solution together with a metal having a lower reduction potential than a reduction potential of hydrogen, whereby valuable metals are leached out from a positive-electrode active substance.Type: GrantFiled: January 27, 2012Date of Patent: June 30, 2015Assignee: SUMITOMO METAL MINING CO., LTD.Inventors: Hitoshi Ishida, Yukie Kawakami, Keiji Kudo, Satoshi Asano
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Patent number: 8961649Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.Type: GrantFiled: August 26, 2008Date of Patent: February 24, 2015Assignee: Vale Canada LimitedInventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed
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Patent number: 8871001Abstract: A method for leaching zinc from a zinc-bearing carbonate ore, the method comprising the steps of: subjecting the zinc-bearing carbonate ore to elevated temperatures of between about 300° C. and about 900° C. thereby producing a roasted ore; subjecting the roasted ore to an aqueous acid or alkali leach thereby producing an aqueous zinc solution; and subjecting the aqueous zinc solution to a zinc recovery step.Type: GrantFiled: February 19, 2010Date of Patent: October 28, 2014Assignee: Metaleach LimitedInventors: Matthew Leslie Sutcliffe, Garry Mervyn Johnston, Nicholas James Welham
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Patent number: 8734564Abstract: Provided are a magnesium-based alloy and a manufacturing method thereof. In the method, a magnesium alloy is melted into liquid phase, and an alkaline earth metal oxide is added into a molten magnesium alloy. The alkaline earth metal oxide is exhausted through surface reduction reaction between the melt and the alkaline earth metal oxide. Alkaline earth metal produced by the exhaustion reacts with Mg and/or other alloying elements in the magnesium alloy so that an intermetallic compound is formed. The magnesium prepared by the method is excellent in fluidity and hot-tearing resistance. To this end, the alkaline earth metal oxide added is CaO, and the added amount of CaO is 1.4 to 1.7 times the target weight of Ca to be contained in the final Mg alloy.Type: GrantFiled: March 24, 2011Date of Patent: May 27, 2014Assignee: Korea Institute of Industrial TechnologyInventors: Shae K. Kim, Jung-Ho Seo
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Patent number: 8709130Abstract: The invention provides a preparation method for producing metal zirconium industrially and producing low-temperature aluminum electrolyte as byproduct, which comprises the following steps: A) aluminum and fluorozirconate are put in a closed reactor, inert gas is fed into the reactor after evacuation, the reactor is heated up to 780° C. to 1000° C. and then the mixture in the reactor is stirred rapidly; and B) after reaction continues for 4 to 6 hours, the liquid molten at the upper layer is sucked out to obtain low-temperature aluminum electrolyte, and the product at the lower layer is subjected to acid dipping or distillation to remove surface residue to obtain metal zirconium.Type: GrantFiled: December 9, 2012Date of Patent: April 29, 2014Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.Inventors: Xuemin Chen, Jun Yang, Zhihong Li, Weiping Wu
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Patent number: 8475749Abstract: A method recovers noble metals from noble metal-containing compositions and includes steps of (i) providing a noble metal-containing composition containing an adsorption agent that is based on an inorganic material and is functionalized by organic groups and has at least one noble metal adsorbed to it, and (ii) ashing of the noble metal-containing composition provided in step (i) in order to adjust a residual carbon content of at most 10% by weight, relative to the total weight of the noble metal-containing composition after ashing, to obtain an ashed composition.Type: GrantFiled: March 15, 2012Date of Patent: July 2, 2013Assignee: Heraeus Precious Metals GmbH & Co. KGInventors: Joachim Kralik, Martin Stettner, Stefanie Fuchs Alameda
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Publication number: 20130025412Abstract: A method for leaching zinc from a zinc-bearing carbonate ore, the method comprising the steps of: subjecting the zinc-bearing carbonate ore to elevated temperatures of between about 300° C. and about 900° C. thereby producing a roasted ore; subjecting the roasted ore to an aqueous acid or alkali leach thereby producing an aqueous zinc solution; and subjecting the aqueous zinc solution to a zinc recovery step.Type: ApplicationFiled: February 19, 2010Publication date: January 31, 2013Applicant: Metaleach LimitedInventors: Matthew Leslie Sutcliffe, Garry Mervyn Johnston, Nicholas James Welham
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Patent number: 8308843Abstract: A method and a device using pyrolysis for recycling used printed circuit board in which water (moisture) is introduced in the pyrolysis process and a fully sealed low pressure environment is established to ensure that no combustion happens in the pyrolysis process to enhance the safety of the process; pyrolysis gases generated in the process are concentrated and purified to provide useful fuels or chemical materials; therefore, the present invention can reduce process cost, improve recycling efficiency and provide processing device with high safety, thereby enhancing industry usability.Type: GrantFiled: May 26, 2010Date of Patent: November 13, 2012Inventor: Hsieh-Sen Wu
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Publication number: 20090241731Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.Type: ApplicationFiled: August 26, 2008Publication date: October 1, 2009Applicant: VALE INCO LIMITEDInventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed
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Patent number: 6835228Abstract: A process of recovering metals from waste lithium ion/Ni—H/Ni—Cd batteries, wherein the waste batteries are calcined and sieved to generate an ash containing metals and metal oxides. The process includes subjecting the ash to a first dissolution etching treatment, a first filtration treatment to obtain a filtrate containing Cd ions which are crystallized as cadmium sulfate, a second dissolution etching treatment for the filtered solid, and a second filtration treatment to obtain a second filtrate. Fe+3, Al+3 and rare earth metal ions in the second filtrate are precipitated as hydroxides by adding a base to the second filtrate. The remaining solution was extracted and counter-extracted to obtain aqueous solutions of Co and Ni ions, which were subjected separately to a electrolysis to deposit Co and Ni metals. Li ions in the residue solution from the electrolysis of Ni was precipitated as carbonate by adding a soluble carbonate salt.Type: GrantFiled: November 19, 2003Date of Patent: December 28, 2004Assignee: Industrial Technology Research InstituteInventors: Jiunn-Ren Lin, I-Long Chang, Yu-Lin Jiang, Jer-Yuan Shiu
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Publication number: 20020104406Abstract: The application discloses a process for upgrading a titaniferous material by removal of impurities contained in the material especially radionuclides. The process involves heating the titaniferous material to a temperature of less than 1300° C. to form a solid titaniferous phase and a liquid oxide or glassy phase in the presence of a material that promotes the formations of such phases, cooling the product at a rate that maintains the glassy phase in an amorphous state and leaching the solidified material with an acid or an alkali to remove the impurities. Materials that promote the formation of the desired phases include compounds of alkali metals and boron. Examples include borax, caustic soda, soda ash and silica.Type: ApplicationFiled: April 26, 2001Publication date: August 8, 2002Inventors: Michael John Hollitt, Ross Alexander McClelland, John Roger Tuffley
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Publication number: 20010039853Abstract: A treatment agent and method to introduce magnesium into ferrous material. The treatment agent includes a mixture of high melting temperature particles and magnesium particles. The content of high melting temperature particles in the particle mixture is present in an effective amount to inhibit the complete conversion of the magnesium particles into molten magnesium prior to the magnesium particles entering the ferrous material. The method describes the efficient treatment of molten ferrous material with these particles.Type: ApplicationFiled: June 12, 2001Publication date: November 15, 2001Applicant: Rossborough Manufacturing Co. L.P.Inventors: Thomas H. Bieniosek, Jerome P. Fahey
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Publication number: 20010017065Abstract: Transition metals may be recovered from a salt-containing mixture containing at least one transition metal compound, salts, and organic compounds by separating from the salt-containing mixture a mixture of the transition metal compound and the salts. This mixture, together with any organic impurities, is introduced into a combustion zone, and the flue gas/salt mixture leaving the combustion zone is quenched with water. The combustion residue, containing the transition metal, is separated from the resulting quench solution, dried, and converted to fresh catalyst.Type: ApplicationFiled: February 21, 2001Publication date: August 30, 2001Applicant: DEGUSSA-HUELS AKTIENGESELLSCHAFTInventors: Frank Bauer, Uwe Prange, Christoph Theis
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Patent number: 6193941Abstract: Besides a synthesis gas, a metallurgical raw material is to be produced from an oil containing heavy metals. To do this, the oil is partially oxidized and the heavy metal-containing soot is separated and burnt and the heavy metals thus occurring as ash can be taken to further processing, e.g. washing from the synthesis gas produced, using an aqueous washing solution.Type: GrantFiled: December 1, 1998Date of Patent: February 27, 2001Assignee: Krupp Uhde GmbHInventors: Michael Buxel, Heinz Jochen Keller
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Patent number: 5851490Abstract: An improved method for the recovery of metal and/or chemical values from an industrial waste stream containing zinc, cadmium, lead and/or iron compounds by heating the waste stream in a reducing atmosphere, treating the resultant fumes in an ammonium chloride solution, separating any undissolved components from the solution, adjusting the pH of the solution, if necessary, to less than about 6.3, displacing undesired metal ions from the solution using zinc metal, treating the solution to remove therefrom zinc compounds, adjusting the pH of the solution to about 6.5 to about 7.0, and further treating the zinc compounds and the undissolved components, as necessary, resulting in the zinc products and the optional iron-carbon feedstock.Type: GrantFiled: April 24, 1997Date of Patent: December 22, 1998Assignee: Metals Recycling Technologies Corp.Inventors: Allan S. Myerson, Micheal W. Cudahy
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Patent number: 5846290Abstract: A method for the production of Group IA salts during a process for the recycling of industrial waste streams containing Group IA compounds and iron and/or zinc compounds, by heating the waste stream in a reducing atmosphere, treating the exhaust fumes from the heating step with an ammonium chloride leaching solution resulting in a Group IA salt containing precipitate, and recovering the Group IA salts from the precipitate.Type: GrantFiled: April 18, 1997Date of Patent: December 8, 1998Assignee: Metals Recycling Technologies Corp.Inventors: Allan S. Myerson, Michael W. Cudahy
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Patent number: 5683488Abstract: A method for the recovery of iron products, specifically direct reduced iron and iron oxide suitable for use as the feedstock for steel mills, from industrial waste streams containing iron, by treating the waste streams with an ammonium chloride leaching solution, separating the undissolved precipitates comprising iron compounds from the leachant solution, and further treating the undissolved precipitants by elevated temperature roasting, resulting in the iron feedstocks.Type: GrantFiled: June 7, 1996Date of Patent: November 4, 1997Assignee: Metals Recycling Technologies Corp.Inventors: Allan S. Myerson, Charles A. Burrows, Paul R. DiBella
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Patent number: 5667555Abstract: A method for the removal of calcium byproducts created during the production of an iron-based feedstock suitable for use as the feedstock for steel mills, from industrial waste streams containing iron, by treating the waste stream with an ammonium chloride leaching solution, treating the leachant with a soluble ammonium salt in which the negative ion will form an insoluble compound with calcium, and separating the undissolved precipitates comprising iron compounds and calcium compounds from the leachant solution. The undissolved precipitants may be treated further by elevated temperature roasting, resulting in the iron-based feedstocks.Type: GrantFiled: February 21, 1996Date of Patent: September 16, 1997Assignee: Metals Recycling Technologies Corp.Inventors: Allan S. Myerson, Charles A. Burrows, Charles W. Sanzenbacher, Paul R. DiBella
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Patent number: 5667553Abstract: A method for the separation and recovery of metals selected from the group consisting of iron, cadmium, zinc, and lead, from raw material comprising a mixture of metals, which comprises the steps of heating the raw material to a temperature sufficient to substantially vaporize cadmium, zinc, and lead, and insufficient to substantially vaporize iron; separating secondary dust and vapors produced during the first step from the residual sinter mass, which mass comprises iron; slurrying the secondary dust in an aqueous solution of ammonia ammonium carbonate to dissolve zinc and cadmium; separating a zinc/cadmium bearing leach liquor from substantially insoluble lead containing particles by filtration; treating the zinc/cadmium bearing leach liquor to recover cadmium by adding metallic zinc to the leachate to produce a cadmium containing cement; separating the cement from the leach liquor; and removing ammonia from the leach liquor to precipitate basic zinc carbonate.Type: GrantFiled: May 10, 1996Date of Patent: September 16, 1997Assignee: Complete Recovery Process, LLCInventor: Joseph F. Keegel, Jr.
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Patent number: 5538532Abstract: A method for the separation and recovery of metals selected from the group consisting of iron, cadmium, zinc, and lead, from raw material comprising a mixture of metals, which comprises the steps of heating the raw material to a temperature sufficient to substantially vaporize cadmium, zinc, and lead, and insufficient to substantially vaporize iron; separating secondary dust and vapors produced during the first step from the residual sinter mass, which mass comprises iron; slurrying the secondary dust in an aqueous solution of ammonia ammonium carbonate to dissolve zinc and cadmium; separating a zinc/cadmium bearing leach liquor from substantially insoluble lead containing particles by filtration; treating the zinc/cadmium bearing leach liquor to recover cadmium by adding metallic zinc to the leachate to produce a cadmium containing cement; separating the cement from the leach liquor; and removing ammonia from the leach liquor to precipitate basic zinc carbonate.Type: GrantFiled: March 2, 1995Date of Patent: July 23, 1996Assignee: Complete Recovery ProcessInventor: Joseph F. Keegel, Jr.
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Patent number: 4895592Abstract: Sputtering targets and a method for preparing them by melting the components of a rare earth-transition metal alloy in an inert atmosphere in the inner section of a crucible assembly having inner and outer sections separating by thermally insulating material and cooling the melt in the inner section.Type: GrantFiled: December 14, 1987Date of Patent: January 23, 1990Assignee: Eastman Kodak CompanyInventors: Tukaram K. Hatwar, Paul D. Askins