Iron(fe), Cobalt(co), Or Nickel(ni) Patents (Class 75/425)
  • Patent number: 8979976
    Abstract: A process for separating Co from Ni in an aqueous solution comprises subjecting the solution to extraction and using kinetic differences between Ni and Co in the extraction for achieving at least a partial separation of Co from Ni. This is effected by controlling the duration of the extraction so that a major portion of Co and a minor portion of Ni is extracted from the solution to produce a loaded extractant, enriched in Co and depleted in Ni compared to the feed solution, and a Co-depleted raffinate containing Ni. In a further embodiment, the invention utilizes kinetic differences between Ni and Co during striping for effecting separation of Ni and Co. The loaded extractant can be subjected to a bulk stripping or a selective stripping operation to obtain Co and Ni solutions from which Ni and Co can be recovered. The process may be incorporated in a hydrometallurgical process for the extraction of Ni and/or Co from an ore or concentrate containing Ni and Co.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: March 17, 2015
    Assignees: CESL Limited, Commonwealth Scientific and Industrial Research Organisation
    Inventors: David Llewellyn Jones, Tannice Marie McCoy, Keith Edward Mayhew, Chu Yong Cheng, Keith Raymond Barnard, Wensheng Zhang
  • Patent number: 8961649
    Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: February 24, 2015
    Assignee: Vale Canada Limited
    Inventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed
  • Patent number: 8911531
    Abstract: A hydrometallurgical plant for nickel laterite ore extraction having a plurality of treatment facility lines wherein the plant is capable of minimizing a decrease in throughput when line failure occurs and efficiently restoring normal operation status Each line of the treatment facility includes a pretreatment step, a leaching step, a solid-liquid separation step, a neutralization step, a zinc removal step, a sulfurization step and a detoxification step. The lines are coupled by pipelines, each having a valve, installed after the solid-liquid separation step for sending a liquid from the solid-liquid separation step to the neutralization step in each line and/or after the sulfurization step for sending a liquid from the sulfurization step to the detoxification step in each line.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: December 16, 2014
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Osamu Nakai, Toru Kitazaki, Shinichi Heguri, Yoshitomo Ozaki, Keisuke Shibayama
  • Patent number: 8470569
    Abstract: The present invention corresponds to a commercial production process of ferric sulfate whose plant can be installed scaled to the requirements of the process of application of the bio-produced ferric solution based on fayalite slag generated in copper smelting plants. No previous process has established as its method of industrial application the use of these smelter slags in the bio-production of ferric sulfate solutions at concentrations above 20 g/L, including a stage of acid-slag leaching in dynamic heaps with control of generated silica and subsequent precipitation of colloidal silica and other impurities in a stirred reactor in the invented process. The ferrous solution free of colloidal silica and other impurities is subjected to a process of bio-oxidization of the clean ferrous solution by microorganisms adapted to these metallurgical solutions.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: June 25, 2013
    Assignee: Biosigma S.A.
    Inventors: Enrique Anselmo Roman Espinoza, Héctor Dario Jordan Gutierrez, Leandro Mauricio Padilla Iglesias, Pedro Antonio Morales Cerda, Ricardo Badilla Ohlbaum
  • Publication number: 20100154593
    Abstract: A process for producing a metallic nickel product with a low iron content, including the steps of: (i) providing an acidic product liquor containing at least nickel and iron; (ii) subjecting said acidic product liquor to an ion exchange process wherein an ion exchange resin selectively absorbs said nickel and part of the iron from said product liquor; (iii) eluting the nickel and iron from said resin with an acidic solution to produce an eluate containing said nickel and iron. (iv) neutralising said eluate to a pH value in the range from 2.5 to 3.
    Type: Application
    Filed: August 22, 2007
    Publication date: June 24, 2010
    Applicant: BHP BILLITON SSM DEVELOPMENT PTY LTD
    Inventors: Ivan Ratchev, Houyuan Liu, Alexey Duarte, Harald Theowald Muller
  • Publication number: 20090241731
    Abstract: A method for recovering base metal values from oxide ore is provided by the present disclosure. The ore includes a first metal selected from the group consisting at least one of iron and aluminum and a second metal selected from the group consisting of at least one of nickel, cobalt and copper. The method includes the steps of: contacting the oxide ore with hydrogen chloride gas to obtain chlorides of the first and second metals and subjecting at least the first and second metals to pyrohydrolysis at a predetermined temperature to decompose the chlorides of the first metal into oxides. The method also includes the step of mixing the oxides of the first metal and the chlorides of the second metal in an aqueous solution to dissolve the chlorides of the second metal and recovering the dissolved ions of the second metal from the aqueous solution.
    Type: Application
    Filed: August 26, 2008
    Publication date: October 1, 2009
    Applicant: VALE INCO LIMITED
    Inventors: Antonio Clareti Pereira, Flavia Dutra Mendes, Tiago Valentim Berni, Ahmed Vahed
  • Publication number: 20040045405
    Abstract: The process of the present invention recovers platinum group metal(s), such as platinum and palladium, from PGM-containing materials containing base metals, such as copper and nickel. The process controls sulfur levels by using solvent extraction 306 to remove acid in the nickel recovery circuit. The acid product 326 can then be neutralized and/or recycled as desired.
    Type: Application
    Filed: September 6, 2002
    Publication date: March 11, 2004
    Inventor: James A. King
  • Patent number: 6524367
    Abstract: The present is a hydrometallurgical procedure for nickel and cobalt recovery, which involves leaching with ammonia-ammonium carbonate solution of the nickel and cobalt bearing mineral material, using a tubular reactors aid mineral material is previously submitted to processes such as selective reduction, cooling, new ammonia leaching, liquid/solid separation and/or nickel and/or cobalt extraction by solvent or ion-exchange resin, allowing the recovery of all the extractable nickel and up to the 130% cobalt extraction reported by the standard ammonia-ammonium leaching.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: February 25, 2003
    Assignee: Centro de Investigaciones Para la Industria Minero-Metalurgcia (CIPIMM)
    Inventors: Jose Castellanos Suarez, German A. Alvarez Villanueva, Ana Maria De La Cruz Fuxa, Pilar Martin Gonzalez, Isabel Lobaina Urtafe, Oscar Perez Laurencio, Milagros Escalona Rodiguez
  • Patent number: 6514311
    Abstract: A process of recovering metals from waste lithium ion batteries, wherein the waste batteries are calcined and sieved to generate an ash containing metals and metal oxides. The invented process includes subjecting the ash to a dissolution etching treatment, and a filtration treatment, and separately using a membrane electrolysis method to separate out metal copper and cobalt, wherein the acid generated on the cathode side in the electrolysis process can be recovered through a diffusion dialysis treatment. After electrolysis, the solution rich in lithium ion, after precipitating the metal impurities by adjusting the pH value, can be added with a carbonate ion to form a lithium carbonate.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: February 4, 2003
    Assignee: Industrial Technology Research Institute
    Inventors: Jiunn-Ren Lin, Chang Fan, I-Long Chang, Jer-Yuan Shiu
  • Patent number: 6274104
    Abstract: The invention relates to a method for recovering non-ferrous metals, particularly nickel, cobalt, copper, zinc, manganese and magnesium, from materials containing said metals by converting said non-ferrous metals into sulphates by means of melt and melt coating sulphation, i.e. by a thermal treatment under oxidizing conditions within a temperature range of 400 to 800° C., during which a reaction mixture is formed containing at least one said non-ferrous metal, iron(III)sulphate and alkali metal sulphate, and appropriate reaction conditions are selected to substantially prevent iron(III)sulphate from thermally decomposing to hematite, and finally, said non-ferrous metals are recovered as metallic compounds. In the method of the invention, a process is formed around the melt and melt coating sulphation, which comprises nine steps.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: August 14, 2001
    Inventors: Jussi Rastas, Pekka Saikkonen
  • Patent number: 6241803
    Abstract: A method for manufacturing reduced iron pellets comprises the steps of heating iron oxide pellets incorporating carbonaceous material to yield reduced iron pellets having an apparent density of not more than 4.0 g/cm3, cooling the hot reduced iron pellets by using water at an average cooling rate between 1,500° C./min and 500° C./min, when the surfaces of the reduced iron pellets are cooled from 650° C. to 150° C. The method described above does not require expensive facilities for processing briquettes and can manufacture the reduced iron pellets having high degree of metallization, superior crushing strength, and an apparent density of not more than 4.0 g/cm3.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: June 5, 2001
    Assignee: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventor: Kojiro Fuji
  • Patent number: 6193941
    Abstract: Besides a synthesis gas, a metallurgical raw material is to be produced from an oil containing heavy metals. To do this, the oil is partially oxidized and the heavy metal-containing soot is separated and burnt and the heavy metals thus occurring as ash can be taken to further processing, e.g. washing from the synthesis gas produced, using an aqueous washing solution.
    Type: Grant
    Filed: December 1, 1998
    Date of Patent: February 27, 2001
    Assignee: Krupp Uhde GmbH
    Inventors: Michael Buxel, Heinz Jochen Keller
  • Patent number: 5728197
    Abstract: Tungsten carbide cobalt and tungsten-containing materials are recycled using a single high-temperature oxidation with standard dilution chemistry. The scrap material is ground, oxidized, and subjected to an acid digestion, preferably in hydrochloric acid. This causes the cobalt to form cobalt chloride while the tungsten remains insoluble. The pH is then increased to about 7.0 which causes the cobalt chloride to form cobalt hydroxide which precipitates out of solution. The cobalt and tungsten are separated and dissolved in a high-pH ammonia solution which can then be spray dried to form a precursor powder for subsequent carburization to form tungsten carbide-cobalt powders.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: March 17, 1998
    Assignee: Nanodyne Incorporated
    Inventors: Purnesh Seegopaul, Li Wu
  • Patent number: 5578110
    Abstract: A method by which numerous gas generators from unused air-bags can be scrapped in an environmentally acceptable manner. The method consists ofa) heating the gas generator to actuate the generator to produce combustion gases and an actuated generator having water soluble contaminants thereon;b) washing the actuated generator with a water composition to remove the contaminants from the actuated generator to produce a washed generator and a contaminated water composition containing the contaminants;c) dividing the washed generator to produce divided generator parts;d) chemically treating the contaminated water composition to produce a purified water composition; ande) classifying the divided generator parts into classified generator parts.Optionally, the dividing step can occur before the washing step, or before and after the washing step. The classified generator parts and purified water can be disposed of in an environmentally acceptable manner.
    Type: Grant
    Filed: April 6, 1995
    Date of Patent: November 26, 1996
    Assignees: Daicel Chemical Industries, Ltd., Nomura Kohsan Co., Ltd.
    Inventors: Yuzaburo Nakasato, Mitsuhiko Fukabori, Takaaki Iwasaki, Humio Ayuta, Sumio Otsuka, Yoshitaka Miyawaki
  • Patent number: 5492554
    Abstract: The invention relates to a method for producing high-grade nickel matte and slag in a combination of a suspension smelting furnace and some other furnace without charge-type converting, so that at least part of the concentrate and/or ore fed into the process is first refined pyrometallurgically into nickel matte, which then is fed into the suspension smelting furnace, where the high-grade nickel matte proper is produced.
    Type: Grant
    Filed: December 7, 1994
    Date of Patent: February 20, 1996
    Assignee: Outokumpu Engineering Contractors Oy
    Inventors: Pekka Hanniala, Risto Saarinen, Olli Saarinen
  • Patent number: 5332414
    Abstract: The invention relates to a method for producing high-grade nickel matte and highly oxidized slag in a flash smelting furnace, and for reducing the slag from the flash smelting furnace and for sulfurating the created matte in an electric furnace. The matte created in the flash smelting furnace and in the electric furnace are both directly conducted to hydrometallurgical further treatment.
    Type: Grant
    Filed: June 11, 1993
    Date of Patent: July 26, 1994
    Assignee: Outokumpu Harjavalta Metals Oy
    Inventor: Tuula S. M. Makinen
  • Patent number: 5221325
    Abstract: A process for recovering silver oxide and metals from a spent silver oxide button cell. The process relates to a physical process which consists of a heating and a cooling process to separate the shell and the content (silver, silver oxide) of the spent silver oxide cell, so that silver oxide, silver and other metals such as zinc, iron and nickel can be recovered and reused.
    Type: Grant
    Filed: March 3, 1992
    Date of Patent: June 22, 1993
    Assignee: Industrial Technology Research Institute
    Inventors: Tyngbin Onlin, Bih-Shyang Huang, Pak-Hing Lee, Tei-Chih Cheau
  • Patent number: 5062887
    Abstract: A sponge refractory metal product, especially a zirconium metal sponge, that retains a residual quantity of magnesium chloride following subjection to an initial, conventional, distillation cycle is reprocessed by the addition of virgin magnesium in amount normally within the range of about 20% to about 60% of the weight of such sponge metal product and by passing it through re-distillation, including the steps of melting the added virgin magnesium and the sponge metal to open the otherwise closed pores thereof, lowering furnace temperature to solidify the molten magnesium, raising the temperature to vaporize and remove from the furnace the magnesium metal, and again raising the temperature to vaporize and remove from the furnace the initially entrapped magnesium chloride. Thereafter, it is preferable that the temperature be again raised to sinter together any loose particles of the sponge metal. It is believed that a eutectic of the sponge metal is formed during the process.
    Type: Grant
    Filed: February 8, 1991
    Date of Patent: November 5, 1991
    Assignee: Westinghouse Electric Corp.
    Inventors: Hani A. M. Abodishish, R. James Adams, Joseph B. White