Elemental Metal Or Elemental Silicon(si) Patents (Class 75/567)
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Patent number: 11225442Abstract: Provided herein are VIS-IR powders comprising tin which show significantly higher visual intensity, reduced reaction temperature and particle temperature during and after oxidation reaction in air, and improved resistance to clumping when compared to comparable powders without tin. Methods of preparation of said VIS-IR powders are also disclosed.Type: GrantFiled: October 19, 2018Date of Patent: January 18, 2022Assignee: Armtec Defense Products Co.Inventors: Radana Dmitrovic, Willie Edward Benjamin, III, Rachel Hendrika Newell
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Publication number: 20130121870Abstract: A ferritic stainless steel comprising Cr: max 24 mass %, Ti: 200 to 1000 mass ppm, Zr: at least 200 mass ppm, whereby the Zr/Ti ratio is greater than 0.3, O: 10 to 150 mass ppm, N: at least 70 mass ppm, whereby the N/O ratio is greater than 1.5, C: max. 0.03 mass %, and balance Fe and residual elements.Type: ApplicationFiled: April 26, 2011Publication date: May 16, 2013Inventors: Keiji Nakajima, Jesper Janis, Andrey Karasev, Pär Jönsson, Stefan Jonsson
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Patent number: 8097207Abstract: Method for reducing the segregated seams of a steel which has high mechanical strength and high wear resistance and whose composition comprises by weight: 0.30%?C?1.42%; 0.05%?Si?1.5%; Mn?1.95%; Ni?2.9%; 1.1%?Cr?7.9%; 0.61%?Mo?4.4%; optionally V?1.45%, Nb?1.45%, Ta?1.45% and V+Nb/2+Ta/4?1.45%; less than 0.1% of boron, less than 0.19% of (S+Se/2+Te/4), less than 0.01% of calcium, less than 0.5% of rare earths, less than 1% of aluminum, less than 1% of copper; the balance being iron and impurities resulting from the production operation. The composition further complies with: 800?D?1150 with D=540(C)0.25+245(Mo+3V+1.5Nb+0.75Ta)0.30+125Cr0.20+15.8Mn+7.4Ni+18Si. According to the method, the molybdenum is completely or partially replaced with double the proportion of tungsten so that W>0.21%, and Ti, Zr, C are adjusted so that, after adjustment, Ti+Zr/2?0.2W, (Ti+Zr/2)×C?0.07, Ti+Zr/2?1.49% and D is unchanged at approximately 5%. Steel obtained and method for producing a steel workpiece.Type: GrantFiled: May 10, 2010Date of Patent: January 17, 2012Assignee: Industeel CreusotInventors: Jean Beguinot, Dominique Viale
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Patent number: 7794651Abstract: Method for reducing the segregated seams of a steel which has high mechanical strength and high wear resistance and whose composition comprises by weight: 0.30%?C?1.42%; 0.05%?Si?1.5%; Mn?1.95%; Ni?2.9%; 1.1%?Cr?7.9%; 0.61%?Mo?4.4%; optionally V?1.45%, Nb?1.45%, Ta?1.45% and V+Nb/2+Ta/4?1.45% ; less than 0.1% of boron, less than 0.19% of (S+Se/2+Te/4), less than 0.01% of calcium, less than 0.5% of rare earths, less than 1% of aluminum, less than 1% of copper; the balance being iron and impurities resulting from the production operation. The composition further complies with: 800?D?1150 with D=540(C)0.25+245 (Mo+3 V+1.5 Nb+0.75 Ta)0.30+125 Cr0.20+15.8 Mn+7.4 Ni+18 Si. According to the method, the molybdenum is completely or partially replaced with double the proportion of tungsten so that W>0.21%, and Ti, Zr, C are adjusted so that, after adjustment, Ti+Zr/2?0.2 W, (Ti+Zr/2)×C?0.07, Ti+Zr/2?1.49% and D is unchanged at approximately 5%. Steel obtained and method for producing a steel workpiece.Type: GrantFiled: May 12, 2005Date of Patent: September 14, 2010Assignee: Industeel CreusotInventors: Jean Beguinot, Dominique Viale
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Patent number: 7081172Abstract: A nodular graphite cast iron is provided, having a pearlite matrix, with high strength and high toughness. The nodular graphite cast iron consists essentially of, by weight %: from 3.0 to 4.6% of carbon; from 1.6 to 2.5% of silicon; from 0.2 to 0.6% of manganese; from 0.02 to 0.05% of magnesium; from 0.0004 to 0.090% of zirconium; at least one of tin and copper such that ? ranges from 0.01 to 0.06% where ? indicates a tin conversion amount defined by a summation of a weight % of the tin and 0.1× a weight % of the copper; and the balance of iron and inevitable foreign matters.Type: GrantFiled: October 14, 2003Date of Patent: July 25, 2006Assignee: Aisin Seiki Kabushiki KaishaInventors: Yasuhiro Enya, Francois Coderre, Yoshikazu Ibayashi, Masaru Matukura
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Patent number: 6733565Abstract: A technique for producing compacted graphite iron utilizes agglomerations, such as briquettes or tablets that include a sulfur-containing material such as iron sulfide. The agglomerations are free of chemical binders and utilize iron and aluminum metal powders and pressure for compaction on either roll presses or tablet machines. Addition of metal powders provides rapid dissolution of the alloy and improved heat transfer. Iron sulfide agglomerations also provide consistent and improved sulfur recoveries compared to granulated iron sulfide additions with little to no sulfur odor.Type: GrantFiled: April 24, 2002Date of Patent: May 11, 2004Inventor: Rodney L. Naro
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Patent number: 6428598Abstract: An additive composition for use in steel making, which comprises 84.8-99.3% by weight of an oxide component; 0.5-1.6% by weight of a metal component; and 0.04-0.07% by weight of a rare-earth element component is used in such a way that its four aliquots are each added in a blast furnace. The amount of the composition to be added is dependent on the steel to be produced. It is used at an amount of 15-17% by weight for special carbonic steel, at 18-20% by weight for special tool and die steel and at 21-25% by weight for special high-speed tool steel.Type: GrantFiled: April 27, 2000Date of Patent: August 6, 2002Inventor: Un Sik Seo
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Patent number: 6383249Abstract: A method and composition for removing sulfur from molten ferrous material, particularly molten pig iron. The desulfurization agent includes a magnesium particle coated with a heat absorbing compound. The heat absorbing compound absorbs heat around the magnesium particle to reduce the rate the magnesium particle vaporizes in the molten iron. The particle size of the magnesium particle is at least about twice the particle size of the heat absorbing compound. A bonding agent can be used to bond the particles of the heat absorbing compound to the particle of magnesium.Type: GrantFiled: June 11, 2001Date of Patent: May 7, 2002Assignee: Rossborough Manufacturing Co. LPInventors: Thomas H. Bieniosek, Gerald R. Zebrowski
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Patent number: 6355089Abstract: A carbon or low-alloy steel is provided with improved machinability. The carbon content of the steel is less than 1.5% and the sum of the alloy elements contained therein is less than 9%. The steel contains oxide and sulfide inclusions, and the chemical composition of the steel includes 0.1%≦Mn, 0.01%≦Al≦0.05%, 0.025%≦S≦0.3%, 0.002%≦Ca, O≦0.0015% by weight; the “KO oxides” cleanness index is less than 30, all the oxides are lime aluminates, and the average calcium content of type 2, type 3, type 4 and type 5 inclusions is less than 30%. A process of manufacturing such steel and an oxide-core wire for its manufacture are also provided.Type: GrantFiled: January 17, 2001Date of Patent: March 12, 2002Assignee: AscometalInventors: Philippe Damie, Christian Turrel
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Patent number: 6293988Abstract: A new technique for producing ferrosilicon free inoculating agents for gray and ductile irons utilizing oxy-sulfide forming elements combined with sulfur and oxygen and 1) mechanically pressed into an insert or tablet for placement into foundry sand molds or 2) a mixture of the same ingredients used as a loose or granular addition to molten iron. The inoculating agent is composed of 15 to 49% silicon, 7 to 22% calcium, 2.5 to 10% sulfur, 2 to 4% oxygen, 2.5 to 7.5% magnesium and 0.5 to 5% aluminum with the balance iron and incidental impurities, wherein the iron is the primary densification agent.Type: GrantFiled: August 4, 1998Date of Patent: September 25, 2001Inventor: Rodney Louis Naro
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Patent number: 6280497Abstract: A cored wire continuously formed by continuously inserting an extruded core inside a continuously roll formed sheath, the peripheral edges of the roll formed sheath joined by a continuous lock seam. Inspection of the partially formed lock seam at a designated process step serves to warn the user of malformed or defective lock seam portions in the finished cored wire.Type: GrantFiled: March 22, 2000Date of Patent: August 28, 2001Assignee: Minerals Technologies Inc.Inventors: Phillip Ronald King, Richard Shaddinger Baum
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Patent number: 6261339Abstract: In a method for desiliconizing pig iron prior to subsequent refining to steel molten steel slag after blast furnace tapping is charged onto the tapped pig iron bath, and optionally onto the blast furnace slag bath, in an amount corresponding to the Si content of the pig iron and the Fe and/or Cr oxide contents of the slag. The amount of steel slag is calculated such that the Si content of the pig iron is reduced to below 0.5% by weight at a simultaneous increase in the SiO2 content of the slag while reducing to liquid metals the Fe and/or Cr oxides of the slag. The slag-iron bath temperature is maintained at below 1500° C.Type: GrantFiled: February 9, 2000Date of Patent: July 17, 2001Assignee: “Holderbank” Financiere Glarus AGInventor: Alfred Edlinger
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Patent number: 6197088Abstract: A method of liquid iron production using high sulfur fuels is provided in which the level of sulfur in the iron is maintained below 0.1%. The low sulfur content is achieved even in the presence of high sulfur concentrations in the reducing gases and without the introduction of lime or limestone. According to one aspect, liquid iron in the fusion zone of a smelting system is saturated with carbon, thereby desulfurizing the liquid iron. The carbon saturation level is at least 4.5% carbon by weight and preferably, at least 5.0% carbon by weight. According to another aspect, the desulfurization of the liquid iron is enhanced by elevating the tapping temperatures to temperatures in excess of 1465° C., and preferably of about 1490° C. According to another aspect, the desulfurization process is supplemented by the presence of significant levels of silicon and/or manganese, both of which are highly soluble in the liquid iron.Type: GrantFiled: March 15, 1999Date of Patent: March 6, 2001Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 5782957Abstract: A process for treating iron-bearing material with a carbonaceous material to form a dry mixture, wherein the amount of carbonaceous material added exceeds the stoichiometric amount required to reduce the metal oxide to elemental metal. In one embodiment, the process also includes blending an organic binder with the dry mixture. The dry mixture is agglomerated to bond the dry mixture and form green compacts. The green compacts are loaded into a heated furnace and heated for about 5-12 minutes at a temperature of between about 2100.degree.-2500.degree. F. to reduce the iron oxide containing compacts to compacts containing elemental iron and an excess amount of carbonaceous material wherein the excess amount of carbonaceous material counteracts re-oxidation of the elemental iron. The reduced compacts are then discharged from the furnace.Type: GrantFiled: November 6, 1996Date of Patent: July 21, 1998Assignee: Maumee Research & Engineering, Inc.Inventors: Franklin G. Rinker, Deane A. Horne
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Patent number: 5609199Abstract: A method of manufacturing steel having Ca including the steps of adding Ca metal or alloy containing Ca to molten steel in a ladle that has been killed by adding a reducing agent, such as Al, to the molten steel in a predetermined quantity when or after the molten steel has been discharged from a converter, subjecting the molten steel to a vacuum degasification process, and supplying the molten steel to a mold through a tundish so that the molten steel is continuously cast, wherein Ca metal or alloy containing Ca is added to the molten steel in the tundish.Type: GrantFiled: June 12, 1995Date of Patent: March 11, 1997Assignee: Kawasaki Steel CorporationInventors: Yoshiei Kato, Seiko Nara, Kenichi Sorimachi
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Patent number: 5125963Abstract: The present invention relates to a method for monitoring and control of smeltmetallurgical processes, endothermic as well as exothermic ones, preferably pyrometallurgical processes, by means of optical spectrometry, whereby one first determines for each endothermic and exothermic smeltmetallurgical process and/or process step characteristic emissions or absorptions and identifies the atomic or molecular origin of the emissions/absorptions, that one during a running process records changes in the characteristic emissions/absorptions and relates these changes to the condition of the process and with reference hereto controls the process.Type: GrantFiled: October 8, 1991Date of Patent: June 30, 1992Assignee: Scandinavian Emission Technology AktiebolagInventors: Lars E. M. Alden, Erik W. Persson, Erik W. Wendt
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Patent number: 5085691Abstract: The invention contemplates smelting in a steelmaking unit a carbon-containing semiproduct, tapping it into a ladle, supplying to the ladle slag-forming materials, a reducer and thermally pretreated oxide materials containing alloying elements. The supply of said oxide materials is started after the tapping of the carbon-containing semiproduct in an amount of minimum 0.25 and maximum 0.5 by mass thereof, is carried out during the tapping of this semiproduct and completed before completing the tapping of the carbon-containing semiproduct. The supply of a reducer is carried out after the supply of said oxide materials and is completed before the end of the tapping of the carbon-containing semiproduct.Type: GrantFiled: February 23, 1990Date of Patent: February 4, 1992Inventors: Anatoly Y. Nakonechny, Manat Z. Tolymbekov, Alexandr G. Ponomarenko, Vladimir N. Radchenko, Alexandr A. Bulyanda, Vladimir G. Mizin, Gennady Z. Gizatulin, Jury F. Vyatkin
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Patent number: 4999053Abstract: A method of producing an alloy containing at least one major ingredient selected from the group consisting of iron (Fe), cobalt (Co), and Nickel (Ni) and having low contents of sulphur, oxygen, and nitrogen, comprises steps of:(a) holding a molten alloy in a container selected from the group consisting of a lime crucible, a lime crucible furnace, a converter and a ladle lined with a basic refractory consisting of 15-85% of calcium oxide (CaO), and 15-75% of magnesium oxide (MgO), wherein said alloy consists essentially of at least one major ingredient selected from the group consisting of iron (Fe), nickel (Ni), and cobalt (Co);(b) adding at least one additive, based on the molten alloy, into said molten alloy in an atmosphere selected from the group consisting of a non-oxidizing atmosphere and a vacuum, wherein said additive is selected from the group consisting of aluminum (Al), aluminum alloys, silicon and silicon alloys;(c) desulphurizing, deoxidizing and denitrifying said molten alloy under an atmosphereType: GrantFiled: November 27, 1989Date of Patent: March 12, 1991Assignees: Mitsui Engineering and Ship Building Co., Ltd., Metal Research CorporationInventors: Tohei Ototani, Toru Degawa, Kanicki Kusumoto, Makoto Ebata
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Patent number: 4978499Abstract: A soft steel for machine cutting with high machinability performances having a content of C.ltoreq.0.25%, a content of Mn of 0.8 to 1.5%, a content of P of .ltoreq.0.1%, a content of S of 0.15 to 0.40%, and a content of Si of 0.05 to 0.40%, expressed in percentages by weight. After finishing of the metal, the inclusions of manganese sulfide are surrounded by a plastic oxide layer of an average composition SiO.sub.2 : 35 to 45%; Al.sub.2 O.sub.3 : 10 to 20%; CaO: 15 to 25%; MnO: 10 to 20%. In producing this grade, after the addition of silicon and manganese, the liquid metal is agitated in the presence of a slag of a composition CaO: 20 to 55%; SiO.sub.2 : 35 to 65%; Al.sub.2 O.sub.3 : 15 to 40%; with a CaO %/SiO.sub.2 % ratio of about 1.Type: GrantFiled: December 1, 1989Date of Patent: December 18, 1990Assignee: UnimetalInventors: Gilles Pierson, Louis Payraudeau, Jean Bellot
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Patent number: 4957547Abstract: A process for continuously melting steel from largely already reduced iron containing material such as pig iron and/or scrap iron, in which process the melt is poured into a ladle for performing subsequent metallurgical steps. The metallurgical slag is, by adding flux, adjusted to20-77.2% FeO, preferably 25.7-50% FeO10-30% SiO.sub.22-15% Al.sub.2 O.sub.35-20% MgO0.13-6.45% MnO, perferably 0.5-5% MnO1-10% CaO0.1-5% Cr.sub.2 O.sub.3P+S traces.Type: GrantFiled: October 12, 1988Date of Patent: September 18, 1990Assignee: Voest-Alpine Stahl Donawitz Gesellschaft mbHInventors: Ludwig von Bogdandy, Gerhard Mitter, Otto Koller, Luzian Pochmarski, Christian Jaquemar, Hans-Jurgen Langhammer
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Patent number: 4943411Abstract: A process for treating molten cast iron with pure magnesium wherein a granular mixture of magnesium granules admixed with granules of refractory material is flooded with molten iron. By employing granular refractory material of controlled size in the granular mixture, the rate of absorption of magnesium into the iron melt may be effectively controlled so as to optimize magnesium introduction at minimal costs.Type: GrantFiled: November 2, 1989Date of Patent: July 24, 1990Assignee: Georg Fischer AGInventors: Ivo Henych, Rudolf Pavlovsky