Abstract: The present disclosure provides a method for co-extraction of vanadium, titanium and chromium from vanadium slag. The method selectively reduces pyroxene and fayalite wrapped on spinel through low-temperature hydrogen reduction, iron removal by ferric chloride, and low-temperature leaching of the vanadium slag by oxalic acid, thereby destroying a structure of the spinel, dissociating a spinel phase and a silicate phase, and fully exposing the spinel phase. The method also directly leaches the vanadium slag at a low temperature by acidity and strong complexation of the oxalic acid, and destroys the structure of the spinel, such that vanadium, titanium, chromium and oxalate are complexed into a solution to co-extract vanadium, titanium and chromium. The present disclosure extracts vanadium, titanium and chromium from the vanadium slag, with a leaching rate each being greater than 99%.

Abstract: A process for recovering metal from a process material comprising the metal and a component that is more volatile than the metal, which process comprises: transporting the process material in a retort provided in a furnace, the retort being operated under vacuum and at a temperature sufficient to cause sublimation of the component from the process material thereby producing purified metal; depositing the component that has been sublimed on a cool surface; removing purified metal from the retort; and removing deposited component from the cool surface.

Abstract: Disclosed herein is a method for producing a titanium-aluminium alloy containing less than about 15 wt. % aluminium. The method comprises a first step in which an amount of titanium subchlorides at or in excess of the stoichiometric amount required to produce the titanium-aluminium alloy are reduced by aluminium to form a reaction mixture comprising elemental titanium, and then a second step in which the reaction mixture comprising elemental titanium is heated to form the titanium-aluminium alloy. The reaction kinetics are controlled such that reactions resulting in the formation of titanium aluminides are minimised.

Abstract: A method for producing metal powder is provided the comprising supplying a molten bath containing a reducing agent, contacting a metal oxide with the molten bath for a time and at a temperature sufficient to reduce the metal in the metal oxide to elemental metal and produce free oxygen; and isolating the elemental metal from the molten bath.

Abstract: A process for producing titanium metal sponge from an exothermic reaction between titanium tetrachloride vapor and molten magnesium vapor, and reclaiming reactive metals from by-products of the exothermic reaction.

Abstract: A metallic article made of metallic constituent elements is fabricated from a mixture of nonmetallic precursor compounds of the metallic constituent elements. The mixture of nonmetallic precursor compounds is chemically reduced to produce an initial metallic material, without melting the initial metallic material. The initial metallic material is consolidated to produce a consolidated metallic article, without melting the initial metallic material and without melting the consolidated metallic article.

Abstract: The present invention is generally directed towards a method for producing a solid metallic composition by reacting a gaseous metal halide with a reducing agent are described. In one embodiment, the method includes reacting a gaseous metal halide with a reducing agent in a manner effective to form a nonsolid reaction product, wherein the metal halide has the formula MXi, in which M is a metal selected from a transition metal of the periodic table, aluminum, silicon, boron, and combinations thereof, X is a halogen, i is greater than 0, and the reducing agent is a gaseous reducing agent selected from hydrogen and a compound that releases hydrogen, and combinations thereof; and solidifying the reaction product, thereby forming a metallic composition comprising M that is substantially free from halides. The invention may be used to produce high-purity metallic compositions, particularly titanium particles and alloys thereof for use in powder metallurgy applications.

Abstract: A metallic article made of metallic constituent elements is fabricated from a mixture of nonmetallic precursor compounds of the metallic constituent elements. The mixture of nonmetallic precursor compounds is chemically reduced to produce an initial metallic material, without melting the initial metallic material. The initial metallic material is consolidated to produce a consolidated metallic article, without melting the initial metallic material and without melting the consolidated metallic article.

Abstract: Titanium metal is produced using titanium dioxide as the starting material. A molten metal collection pool is first prepared in a reaction vessel from zinc and calcium. A molten salt mixture is then added to the vessel comprised of a mixture of calcium chloride and calcium fluoride. The titanium oxide starting material is then added along with additional calcium and the contents are mechanically stirred while maintaining at a temperature of about 800.degree. C. The titanium reacts spontaneously with the calcium, producing titanium powder and calcium oxide. The titanium becomes embedded in the molten zinc pool and settles to the bottom of the vessel, where it is removed and the titanium separated from the zinc by vacuum distillation or a suitable electrochemical process. The same process applies for producing zirconium from zirconium dioxide.

Abstract: A process for producing titanium slag which is low in radioactivity wherein molten titanium slag, produced by smelting ilmenite in the presence of a reductant in a DC electric arc furnace, is separated from molten iron, boron in an amount which is less than 2.5% equivalent B.sub.2 O.sub.3 of the slag is blended with the molten slag which thereafter is allowed to cool to form a glassy phase which contains the bulk of the radioactive elements of the slag before being crushed to particles below about 1 mm, whereafter the radioactive elements are leached to leave a titanium slag product which is low in radioactivity.

Abstract: A method of producing a non-metal element or a metal or an alloy thereof from a halide or mixtures thereof. The halide or mixtures thereof are contacted with a stream of liquid alkali metal or alkaline earth metal or mixtures thereof in sufficient quantity to convert the halide to the non-metal or the metal or alloy and to maintain the temperature of the reactants at a temperature lower than the sintering temperature of the produced non-metal or metal or alloy. A continuous method is disclosed, particularly applicable to titanium.

Abstract: A method of producing a non-metal element or a metal or an alloy thereof from a halide or mixtures thereof. The halide or mixtures thereof are contacted with a stream of liquid alkali metal or alkaline earth metal or mixtures thereof in sufficient quantity to convert the halide to the non-metal or the metal or alloy and to maintain the temperature of the reactants at a temperature lower than the lesser of the boiling point of the alkali or alkaline earth metal at atmospheric pressure or the sintering temperature of the produced non-metal or metal or alloy. A continuous method is disclosed, particularly applicable to titanium.

Abstract: In situ formation of metal-ceramic oxide microstructures is carried out on a starting oxide phase containing at least a most noble metallic component (e.g., iron) and a least noble metallic component (e.g. manganese) and subjecting the starting oxide phase to a temperature and oxygen partial pressure and for a time period to cause reduction of only part of the most noble metallic component to elemental metal.

Abstract: A continuous method is provided for purifying and recovering transition metals such as neodymium and zirconium that become reactive at temperatures above about 500.degree. C. that comprises the steps of contacting the metal ore with an appropriate fluorinating agent such as an alkaline earth metal fluosilicate to form a fluometallic compound, and reducing the fluometallic compound with a suitable alkaline earth or alkali metal compound under molten conditions, such as provided in an induction slag metal furnace. The method of the invention is advantageous in that it is simpler and less expensive than methods used previously to recover pure metals, and it may be employed with a wide range of transition metals that were reactive with enclosures used in the prior art methods and were hard to obtain in uncontaminated form.