Amine Patents (Class 8/196)
  • Patent number: 11452291
    Abstract: One aspect of the present invention is directed to a composition. The composition includes a dispersion inducer comprising: H3C—(CH2)n—CHmCHmR, where is a single or double carbon-carbon bond, m is 1 or 2, n is 2 to 15, and R is a carboxylic acid, a salt, an ester, or an amide, where the ester or amide is an isostere or biostere of the carboxylic acid. The composition additionally contains an additive component selected from one or more of the group consisting of biocides, surfactants, antibiotics, antiseptics, detergents, chelating agents, virulence factor inhibitors, gels, polymers, pastes, edible products, and chewable products. The composition is formulated so that when it is contacted with a biofilm produced by a microorganism, where the biofilm comprises a matrix and microorganism on a surface, the dispersion inducer selectively acts on the microorganism and has a suitable biological response without a required direct effect on the matrix to disperse the biofilm.
    Type: Grant
    Filed: May 13, 2020
    Date of Patent: September 27, 2022
    Assignee: The Research Foundation for The State University
    Inventor: David G. Davies
  • Patent number: 8986399
    Abstract: A process of covalently modifying a lignocellulosic material is provided. The process includes oxidizing a lignocellulosic material having hydroxyl groups with an oxidant to oxidize at least a portion of the hydroxyl groups to carboxylic acid groups, optionally activating the carboxylic acid groups with an activating agent to form activated carboxylic acid groups, and reacting the carboxylic acid groups or the activated carboxylic acid groups with a first nitrogen-containing reagent selected from amino acids, peptides, or protected derivatives thereof to provide a treated lignocellulosic material. The treated lignocellulosic materials thus prepared displays resistance to degradation.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: March 24, 2015
    Assignee: Empire Technology Development LLC
    Inventors: Sung-Wei Chen, Chris Rothfuss, John Choi
  • Publication number: 20140259458
    Abstract: Compositions and methods that preserve and enhance the brightness of pulp, and also improve the color of pulp or paper, when applied during different stages of a papermaking process, are disclosed. The compositions and methods maintain or enhance brightness, prevent yellowing, and enhance the performance of paper products. The compositions can include a mixture of reducing agents and can also include optical brighteners, chelants, polycarboxylates, or other additives. The mixture of reducing agents can include a borohydride, such as sodium borohydride, and any other reducing agent, such as a sulfite or bisulfite.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: Ecolab USA Inc.
    Inventors: Prasad Y. Duggirala, Sergey M. Shevchenko
  • Patent number: 8492326
    Abstract: The present invention relates to the use of an alkoxylate based on 2-propylheptylamine which has been alkoxylated with ethylene oxide, propylene oxide, butylene oxide, pentylene oxide, styrene oxide, cyclohexylene oxide and/or decylene oxide, and/or its quaternized derivative in cleaning compositions, as emulsifier, in the manufacture of fibers, for leather treatment, in printing inks, in formulations for construction chemistry or in formulations for flotation. Furthermore, the present invention relates to a mixture comprising at least one of the specified alkoxylates and also at least one surface-active substance and use thereof.
    Type: Grant
    Filed: June 27, 2011
    Date of Patent: July 23, 2013
    Assignee: BASF SE
    Inventors: Paul Klingelhoefer, Juergen Tropsch, Rolf-Dieter Kahl, Andreas Senf
  • Publication number: 20120297555
    Abstract: A process of covalently modifying a lignocellulosic material is provided. The process includes oxidizing a lignocellulosic material having hydroxyl groups with an oxidant to oxidize at least a portion of the hydroxyl groups to carboxylic acid groups, optionally activating the carboxylic acid groups with an activating agent to form activated carboxylic acid groups, and reacting the carboxylic acid groups or the activated carboxylic acid groups with a first nitrogen-containing reagent selected from amino acids, peptides, or protected derivatives thereof to provide a treated lignocellulosic material. The treated lignocellulosic materials thus prepared displays resistance to degradation.
    Type: Application
    Filed: May 25, 2011
    Publication date: November 29, 2012
    Inventors: Sung-Wei Chen, Chris Rothfuss, John Choi
  • Patent number: 7947750
    Abstract: Color is removed from polymeric material by a method which comprises contacting a dyed or pigmented polymer composition with a non-aqueous extraction solvent comprising a nitrogen containing organic base, an ammonium salt and an alkanol. The present method is readily applied to a process for recycling colored polyamide substrates such as dyed nylon fiber.
    Type: Grant
    Filed: April 8, 2008
    Date of Patent: May 24, 2011
    Assignee: BASF SE
    Inventors: Ronnie Ozer, Kevin R. Gerzevske
  • Patent number: 7935666
    Abstract: The present invention relates to a detergent composition having from 3 to 75 percent by weight of at least one surfactant; and from 0.01 to 5 percent by weight percent of a copolymer composed of from about 70 to 100 mole percent of at least one amine-functional monomer, and from about 30 to 0 mole percent of at least one hydrophobic ethylenically unsaturated monomer, wherein said amine-functional monomer is not a quaternized amine, and wherein said copolymer has been at least partially neutralized. The detergent composition having the copolymers provides color protection and anti-pill properties in laundry applications.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: May 3, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Klin A. Rodrigues, Martin Crossman
  • Patent number: 7615503
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: November 10, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin
  • Patent number: 7435266
    Abstract: Textile materials, including paper webs, treated with a polyvinylamine polymer and a second agent that interacts with the polyvinylamine polymer are disclosed. The second agent added with the polyvinylamine polymer can be, for instance, a polymeric anionic reactive compound or a polymeric aldehyde-functional compound. When incorporated into a paper web, the combination of the polyvinylamine polymer and the second agent provide improved strength properties, such as wet strength properties. In an alternative embodiment, the polyvinylamine polymer and the second polymer can be applied to a textile material for increasing the affinity of the textile material for acid dyes.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: October 14, 2008
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Tong Sun, Jeff Lindsay
  • Patent number: 7429545
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain dialkylhydroxyamine stabilizers, dialkylhydroxylamine stabilizer salts, nitrone stabilizers or amine oxide stabilizers. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: September 30, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood
  • Patent number: 7335234
    Abstract: Methods of enhancing repellency of fibers, carpet yarns and carpets are disclosed. Compositions used to enhance the repellency of fibers, carpet yarns and carpets are also disclosed.
    Type: Grant
    Filed: October 16, 2002
    Date of Patent: February 26, 2008
    Assignee: Columbia Insurance Company
    Inventor: Dennis J. Jones, Jr.
  • Patent number: 7316984
    Abstract: A textile product having arginine impared thereto; a process for producing the product; and a method for the pretreatment of a textile product. The textile product compensates for the water-retaining function of the horny layer and enhances metabolism. It hence has the effect of keeping the skin normal.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: January 8, 2008
    Assignee: Ajinomoto Co., Inc.
    Inventors: Ryouichi Higuchi, Nobuyoshi Kitamura, Sadakazu Hirose, Hideo Sukeda, Shiro Suzuki, Katsuya Anno
  • Patent number: 7147671
    Abstract: A silicone composition is provided which comprises at least one polysiloxane or siloxane oligomer functionalized with at least one amino group and at least three functional groups capable of cross-linking wherein the polysiloxane or siloxane oligomer imparts flame retardancy on a cellulose-containing substrate. Further embodiments of the present invention include a method for making and a cellulose-substrate comprising the aforementioned silicone composition.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: December 12, 2006
    Assignee: General Electric Company
    Inventors: Matthew David Butts, Kathryn Ann Shaffer
  • Patent number: 7141076
    Abstract: A hydrolizable polymer-containing textile article and method for producing the same is provided that has been chemically modified by treating the article with certain branched chain amines to reduce the strength of the fibers contained therein, thus rendering the article less prone to the formation of objectionable pill balls, thereby increasing wearer comfort and retaining the desired appearance of the article, and thereby extending the useful life of the article.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: November 28, 2006
    Assignee: Milliken & Company
    Inventor: William C. Kimbrell
  • Patent number: 7137999
    Abstract: A hydrolizable polymer-containing textile article and method for producing the same is provided that has been chemically modified by treating the article with certain branched chain amines to reduce the strength of the fibers contained therein, thus rendering the article less prone to the formation of objectionable pill balls, thereby increasing wearer comfort and retaining the desired appearance of the article, and thereby extending the useful life of the article.
    Type: Grant
    Filed: October 3, 2003
    Date of Patent: November 21, 2006
    Assignee: Milliken & Company
    Inventor: William C. Kimbrell
  • Patent number: 6984336
    Abstract: The invention concerns the treatment of clothes for dry wrinkle resistance, in particular in-wear wrinkle resistance. The clothes are treated with an amphoteric polymer and secured in the desired configuration, preferably during a process of ironing.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: January 10, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Markus Wilhelm Altmann, Bruno Albert Jean Hubesch, Heidi Simonne Mariette Soyez, Jürgen Detering, Ulrich Steuerle
  • Patent number: 6924259
    Abstract: The present invention relates to a detergent composition having from 3 to 75 percent by weight of at least one surfactant; and from 0.01 to 5 percent by weight percent of a copolymer composed of from 25 to 75 mole percent of at least one amine-functional monomer, and from 75 to 25 mole percent of at least one hydrophobic ethylenically unsaturated monomer, wherein said amine-functional monomer is not a quaternized amine, and wherein said copolymer has been at least partially neutralized. The detergent composition having the copolymers provides color protection and anti-pill properties in laundry applications.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 2, 2005
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Klein A. Rodrigues, Martin Crossman
  • Patent number: 6916402
    Abstract: Articles containing cellulose materials and treated with a chemical additive are disclosed. In accordance with the present invention, at least a portion of the cellulose containing the article is modified to include a first moiety. A chemical additive, such as softener or a humectant, is then chosen that includes a second moiety. When the chemical additive is applied to the article, the second moiety on the chemical additive forms a chemical linkage with the first moiety on the cellulose material. In this manner, the chemical additive becomes bonded to the cellulose material alleviating problems associated with retention. In one embodiment, the present invention is directed to the formation of tissue products, such as facial tissue, bath tissue and paper towels.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: July 12, 2005
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas G. Shannon, Gil Bernard Didier Garnier, Alberto Ricardo Negri, Mike T. Goulet
  • Patent number: 6913628
    Abstract: Novel waterborne vinyl copolymer dispersions useful as a fabric coating or treatment to improve the performance properties of textile products are disclosed and claimed. The compositions contain vinyl monomers, a vinyl silane and hydroxy fatty acid ester compounds having at least one double bond in their backbone featuring internally plasticizable and crosslinkable properties.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: July 5, 2005
    Assignee: University of Southern Mississippi
    Inventors: James M. Evans, Shelby F. Thames
  • Patent number: 6908976
    Abstract: A solution for forming a graft substrate containing a graft initiator, a catalyst for activating the graft initiator, a polymerizable silicon softener, and at least one additional prepolymer, each of the softener and the prepolymer which includes a functional group for reaction with an activated site on the substrate for grafting thereto and water. The treated fiber exhibits excellent crockfastness, color fastness, and abrasion resistance, strength, and has a soft hand.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: June 21, 2005
    Assignee: Healthtex Apparel Corp.
    Inventors: Mohan L. Sanduja, Carl Horowitz, Izabella Zilbert, Paul Thottathil, Gerald L. Williamson
  • Patent number: 6875508
    Abstract: A fiber capable of forming a metal chelate and a process for producing the same are disclosed, wherein the fiber is characterized in that at least one metal chelate-forming compound selected from the group consisting of aminodicarboxylic acids, aminocarboxylic acids, thiocarboxylic acids and phosphoric acid, which are reactive with a glycidyl group, is bonded to a molecule of a natural fiber or regenerated fiber through a crosslinkable compound having a reactive double bond and a glycidyl group in its molecule. There are also disclosed a method of capturing metal ions using the fiber and a metal chelate fiber which can effectively make use of the characteristics of the metals and can be easily discarded or incinerated.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: April 5, 2005
    Assignees: Chelest Corporation, Chubu Chelest Co., Ltd.
    Inventors: Nobuyoshi Nambu, Osamu Ito, Shiho Horiuchi, Takao Doi
  • Patent number: 6849156
    Abstract: A cationic cellulosic fibre containing between 1 and 30 cationic groups and between 0.1 and 20 aldehyde groups per 100 anhydroglucose units is a suitable basis for producing paper and tissue products without the necessity of using non-biodegradable cationic polymers as wet strength additives. The cationic cellulosic fibre can be obtained by oxidation of the fibre to introduce aldehyde groups, followed by reaction of part of the aldehyde groups with a nitrogen-containing reagent such as betaine hydrazide hydrochloride. The fibre is advantageously combined with an anionic polymer such as monoaldehyde carboxyl-starch or with anionic cyclodextrin.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: February 1, 2005
    Inventors: Arie Cornelis Besemer, Anne Mieke Yvonne Wilhelmina Verwilligen, Harm Jan Thiewes, Dorine Lisa Van Brussel-Verraest
  • Publication number: 20040123962
    Abstract: The disclosed invention is directed to pulp fibers suitable for forming a wet-laid paper product which include amino-functionality which is non-extractable in an aqueous phase. The pulp fibers may be prepared by applying an amino-functional additive to a fibrous web prior to the finishing operation at a pulp mill. The fibrous web may then be repulped at a papermaking machine to form a paper web which includes the amino-functionalized fibers of the present invention. A paper web formed of the amino-functionalized fibers may display unique and/or improved reactivity toward certain papermaking additives.
    Type: Application
    Filed: December 31, 2002
    Publication date: July 1, 2004
    Applicant: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas G. Shannon, David Moline
  • Publication number: 20040083556
    Abstract: According to the present invention, a cellulose fiber or a fiber product made of said cellulose fiber is contacted with a basic amino acid ester and thereafter heat treated, thereby there may be provided an antibacterial product which does not lose its antibacterial property even by being washed several times.
    Type: Application
    Filed: July 3, 2003
    Publication date: May 6, 2004
    Inventors: Masahiko Kurauchi, Kiyonori Furuta, Hiroyuki Sato
  • Patent number: 6673119
    Abstract: A hydrolizable polymer-containing textile article and method for producing the same is provided that has been chemically modified by treating the article with certain branched chain amines to reduce the strength of the fibers contained therein, thus rendering the article less prone to the formation of objectionable pill balls, thereby increasing wearer comfort and retaining the desired appearance of the article, and thereby extending the useful life of the article.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: January 6, 2004
    Assignee: Milliken & Company
    Inventor: William C. Kimbrell
  • Patent number: 6645255
    Abstract: A solution for forming a graft substrate containing a graft initiator, a catalyst for activating the graft initiator, a polymerizable silicon softener, and at least one additional prepolymer, each of the softener and the prepolymer which includes a functional group for reaction with an activated site on the substrate for grafting thereto and water. The treated fiber exhibits excellent crockfastness, color fastness, and abrasion resistance, strength, and has a soft hand.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: November 11, 2003
    Assignee: Healthtex Apparel Corp.
    Inventors: Mohan L. Sanduja, Carl Horowitz, Izabella Zilbert, Paul Thottathil, Gerald L. Williamson
  • Patent number: 6645256
    Abstract: A solution for forming a graft substrate containing a graft initiator, a catalyst for activating the graft initiator, a polymerizable silicon softener, and at least one additional prepolymer, each of the softener and the prepolymer which includes a functional group for reaction with an activated site on the substrate for grafting thereto and water. The treated fiber exhibits excellent crockfastness, color fastness, and abrasion resistance, and has a soft hand.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: November 11, 2003
    Assignee: Healthtex Apparel Corp.
    Inventors: Mohan L. Sanduja, Carl Horowitz, Izabella Zilbert, Paul Thottathil, Gerald L. Williamson
  • Patent number: 6638319
    Abstract: A solution for forming a graft substrate containing a graft initiator, a catalyst for activating the graft initiator, a polymerizable silicon softener, and at least one additional prepolymer, each of the softener and the prepolymer which includes a functional group for reaction with an activated site on the substrate for grafting thereto and water. The treated fiber exhibits excellent crockfastness, color fastness, and abrasion resistance, and has a soft hand.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: October 28, 2003
    Assignee: Healthtex Apparel Corp.
    Inventors: Mohan L. Sanduja, Carl Horowitz, Izabella Zilbert, Paul Thottathil, Gerald L. Williamson
  • Publication number: 20030157310
    Abstract: A textile product having arginine impared thereto; a process for producing the product; and a method for the pretreatment of a textile product. The textile product compensates for the water-retaining function of the horny layer and enhances metabolism. It hence has the effect of keeping the skin normal.
    Type: Application
    Filed: April 2, 2003
    Publication date: August 21, 2003
    Inventors: Ryouichi Higuchi, Nobuyoshi Kitamura, Sadakazu Hirose, Hideo Sukeda, Shiro Suzuki, Katsuya Anno
  • Patent number: 6607564
    Abstract: Provided are compounds and methods for modifying a material to change properties of the material, as well as a variety of products obtained using the methods. In one embodiment, a material comprising one or more modifiable functional groups is reacted with an activated hydrophobic acyl group in the presence of a hindered base, thereby to covalently attach the hydrophobic acyl group to the modifiable functional groups on the material. The material which is modified may be, for example, a carbohydrate, and the modifiable functional groups on the material may be hydroxyls. For example, materials such as cellulose may be modified by reacting it with a acid chloride or acid anhydride including a hydrophobic acyl group, in the presence of a hindered base, such as tripentylamine, to attach the hydrophobic acyl groups to the hydroxyls on the cellulose, thereby to increase the hydrophobicity of the cellulose.
    Type: Grant
    Filed: July 17, 2002
    Date of Patent: August 19, 2003
    Assignee: Nano-Tex, LLC
    Inventors: David S. Soane, David A. Offord
  • Publication number: 20030051834
    Abstract: The invention is directed to a method of making a heat and light stable carboxylated cellulose fiber whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of a catalytic amount of a hindered cyclic oxammonium salt as a primary oxidant and a peracid and halide salt as a secondary oxidant in an aqueous environment. The oxammonium compounds may be formed in situ from their corresponding amine, hydroxylamine, and nitroxyl compounds. The oxidized cellulose is then stabilized against D.P. loss and color reversion by further treatment with an oxidant such as sodium chlorite, a chlorine dioxide/hydrogen peroxide mixture, or a peracid under acidic conditions. Alternatively it may be treated with a reducing agent such as sodium borohydride. The method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially useful as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives.
    Type: Application
    Filed: June 6, 2001
    Publication date: March 20, 2003
    Inventors: S. Ananda Weerawarna, Joseph Lincoln Komen, Richard A. Jewell
  • Patent number: 6500215
    Abstract: A process is disclosed for treating textile materials with selected amine oxides in order to change the aesthetics and/or make the materials more receptive to dyes. In particular, the treatment causes cellulosic materials to become more cationic and thus more receptive to anionic dyes with or without stiffening. In a preferred embodiment, the process of the present invention is directed to treating fabrics containing cotton fibers but will work to a useful extent on wool, nylon and polyester. The process is carried out by contacting said fibers or fabric with selected amine oxide compositions. The amine oxide compositions can be padded onto the fabric or printed onto the fabric. If printed onto the fabric according to a particular design, the design then becomes visible on the fabric once dyed.
    Type: Grant
    Filed: July 11, 2000
    Date of Patent: December 31, 2002
    Assignee: Sybron Chemicals, Inc.
    Inventors: Robert B. Login, Otto Bella, Calvin McIntosh Wicker, Jr., Lynn Hosie
  • Patent number: 6485530
    Abstract: Provided are compounds and methods for modifying a material to change properties of the material, as well as a variety of products obtained using the methods. In one embodiment, a material comprising one or more modifiable functional groups is reacted with an activated hydrophobic acyl group in the presence of a hindered base, thereby to covalently attach the hydrophobic acyl group to the modifiable functional groups on the material. The material which is modified may be, for example, a carbohydrate, and the modifiable functional groups on the material may be hydroxyls. For example, materials such as cellulose may be modified by reacting it with an acid chloride or acid anhydride including a hydrophobic acyl group, in the presence of a hindered base, such as tripentylamine, to attach the hydrophobic acyl groups to the hydroxyls on the cellulose, thereby to increase the hydrophobicity of the cellulose.
    Type: Grant
    Filed: June 1, 2000
    Date of Patent: November 26, 2002
    Assignee: Nano-Tex, LLC
    Inventors: David S. Soane, David A. Offord
  • Patent number: 6464730
    Abstract: The present invention is generally directed to a process for making fabrics containing cotton fibers more aesthetically pleasing and resistant to staining by anionic dyes by derivatizing the cotton so that it exhibits a permanent anionic charge. By increasing the anionic charge of the fibers, the fibers become resistant to anionic coloring agents which may undesirably come into contact with the fibers and the fibers can absorb greater amounts of cationic softeners and biocides. Furthermore, the negative charges repel each other resulting in a fabric with greater loft and hydrophilicity. This results in greater smoothness, better hand, and more comfort. Besides being used to prevent the cross-staining of fabrics, the present invention can also be used to make carpet materials resistant to anionic staining agents.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: October 15, 2002
    Assignee: Sybron Chemicals, Inc.
    Inventors: Robert B. Login, Otto Bella, Calvin McIntosh Wicker, Jr., Lynn Hosie, David MacEwan, Robert Barile
  • Patent number: 6241780
    Abstract: This invention relates to a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition. The cellulosic substrates include, for example, paper oil- and air-filter stock, rayon nonwoven wipes, cellulosic laminating stock, cotton woven fabrics, and wood flakes suitable to be consolidated into flakeboard.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: June 5, 2001
    Assignee: Rohm and Haas Company
    Inventors: Charles Thomas Arkens, Scott Lind Egolf, Robert David Gleim, Oscar Hsien-Hsiang Hsu, Kenneth John Wiesinger
  • Patent number: 6168863
    Abstract: The present invention provides a novel fibrous chelate-forming material to which a capability of forming a chelate with metal is imparted by introducing a specific acyl group represented by the following general formula [1] or [2], and also discloses a novel process for producing a chelate-forming fiber, a process for sequestering with the same, and a filter capable of simultaneously removing impurities and metal ions in a fluid is imparted using the chelate-forming fiber. [wherein each symbol is as defined in the specification.
    Type: Grant
    Filed: October 22, 1999
    Date of Patent: January 2, 2001
    Assignees: Chelest Corporation, Chubu Chelest Co., Ltd.
    Inventors: Nobuyoshi Nambu, Osamu Ito, Shiho Sato
  • Patent number: 6156075
    Abstract: The present invention provides a metal chelate forming fiber in which a reactive functional group in a molecule in the surface of the fiber is substituted with an acyl group represented by the following formula [1]: ##STR1## (where R.sup.1, R.sup.2, and R.sup.3 respectively are a lower alkylene group, and n is an integer of 1 to 4.) The present also provides a method for preparing the fiber, and a process for treating waste water using the fiber where metal ions contained in the waste water are allowed to be captured by the acyl group.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: December 5, 2000
    Assignees: Chelest Corporation, Chubu Chelest Co., Ltd.
    Inventors: Nobuyoshi Nanbu, Osamu Ito, Koujirou Nagatsuka
  • Patent number: 6149549
    Abstract: The present invention is generally directed to a process for making fabrics containing cotton fibers more aesthetically pleasing and resistant to staining by anionic dyes by derivatising the cotton so that it exhibits a permanent anionic charge. By increasing the anionic charge of the fibers, the fibers become resistant to anionic coloring agents which may undesirably come into contact with the fibers. Furthermore, the negative charges repel each other resulting in a fabric with greater loft and porosity. This results in greater smoothness, better hand, and more comfort. Besides being used to prevent the cross-staining of fabrics, the present invention can also be used to make carpet materials resistant to anionic staining agents. Alternatively, it has also been discovered that an anionic derivative can be used to catalyze permanent press resins onto fabrics containing cellulosic fibers, also resulting in anionic cotton.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: November 21, 2000
    Assignee: Syborn Chemicals, Inc.
    Inventors: Robert B. Login, Otto Bella, Calvin McIntosh Wicker, Jr.
  • Patent number: 6048479
    Abstract: A process for manufacturing cellulose fibers or yarns with a reduced tendency to form fibrils includes treating fibers or yarns, which are washed after the filament forming process but not yet dried, with a cross-linking agent. The process includes treating the fibers or yarns with reactive polysiloxanes which are modified with amino, polyalkylene oxide, epoxy or carboxyl functional groups and which cross-link with themselves. The process is particularly suitable for fibers produced according to the NMMO process.
    Type: Grant
    Filed: July 1, 1997
    Date of Patent: April 11, 2000
    Assignee: Akzo Nobel NV
    Inventor: Abdulmajid Hashemzadeh
  • Patent number: 6042615
    Abstract: The invention relates to an indigo-dyed fabric which comprises at least one organopolysiloxane and at least one alkyl polyglycoside.
    Type: Grant
    Filed: May 27, 1998
    Date of Patent: March 28, 2000
    Assignee: Wacker-Chemie GmbH
    Inventors: Peter Habereder, Martina Obenhuber, Michael Geck
  • Patent number: 6033443
    Abstract: This invention relates to a process for treating Lyocell cellulose fibers, which comprises treating the Lyocell cellulose fiber with at least one compound of formula ##STR1## wherein X is --NR-- or --S--, A is an aliphatic radical containing 1 to 18 carbon atoms which is free of sulfo groups, or --X--A is hydroxy, and R is hydrogen or, independently of A, has the meaning of A.
    Type: Grant
    Filed: September 15, 1998
    Date of Patent: March 7, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Peter Aeschlimann
  • Patent number: 5981681
    Abstract: The present invention discloses non-hydrolyzable, block, (AB).sub.n A type, copolymers comprising alternating units of polysiloxane and amino-polyalkyleneoxide and provides a method for the preparation of these copolymers. Also provided is the use of these copolymers as softeners, in particular durable, hydrophilic textile softeners, which improve tactile properties of the textiles substrates treated with the commercial soil release finishes, without substantially detracting from their properties. The copolymers of the present invention have alternating units of polysiloxane [X(C.sub.a H.sub.2a O).sub.b R.sup.2 [(SiO(R.sup.1).sub.2 ].sub.c Si(R.sup.1).sub.2 R.sup.2 (C.sub.a H.sub.2a O).sub.b X] and polyalkyleneoxides [YO(C.sub.a H.sub.2a O).sub.d Y] wherein R.sup.1 is a C.sub.1 to C.sub.4 alkyl, preferably methyl, R.sup.
    Type: Grant
    Filed: June 17, 1998
    Date of Patent: November 9, 1999
    Assignee: Witco Corporation
    Inventor: Anna Czech
  • Patent number: 5882356
    Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: March 16, 1999
    Assignee: Courtaulds Fibres (Holdings) Limited
    Inventor: Christopher David Potter
  • Patent number: 5879410
    Abstract: A process for resin finishing textile containing cellulosic fiber comprises the steps of using a resin finishing agent chiefly containing a cellulose-reactive N-methylol compound having two or more functional groups and a reaction catalyst, mainly reacting only one functional group of the cellulose-reactive N-methylol compound with cellulose, water washing, again imparting reaction catalyst, drying, garment making, and heat treating. The process eliminates the conventional postcuring method drawbacks of loss of color fastness and discoloration owing to dye decomposition and formaldehyde increase by unreacted resin and residual reaction catalyst during long storage before heat treatment, and simultaneously achieves high crease-resistant property, shrink resistance, good feeling, excellent pleating property, and anti-puckering property.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: March 9, 1999
    Assignee: Nisshinbo Industries, Inc.
    Inventors: Yuichi Yanai, Masayoshi Oba, Yasushi Takagi, Tadashi Isogai
  • Patent number: 5858023
    Abstract: A method for the treatment of natural or synthetic fibers, such as wool, cotton, nylon or acrylic, so as to impart a softer handle, comprising treating the fibers with a polymer or prepolymer as defined. The method may be performed as either a continuous process or as a batch process.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: January 12, 1999
    Assignee: Precision Processes Textiles
    Inventors: Susan Bamford, David Longley Connell, Kenneth Michael Huddlestone
  • Patent number: 5856246
    Abstract: The invention concerns a thin film of a permanent hydrophobic and optionally oleophobic finish for polymer surfaces. The film is formed from at least one layer of a water-soluble polycation and cationic synthetic resin. For further improvement of the oleophobic and permanent hydrophobic properties the film can additionally contain a long-chain surfactant or an alkyl-substituted polyanion.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: January 5, 1999
    Inventors: Richard Witzko, Wolfgang Burger, Gudrun Petzold, Klaus Lunkwitz, Heide-Marie Buchhammer
  • Patent number: 5856544
    Abstract: Aminopolysiloxanes of the following structure Q.sub.2 RSiO-- (SiR.sub.2 O).sub.x -(SiRR.sup.1 O).sub.y -SiRQ.sub.2 wherein R is a monovalent hydrocarbon group having 1 to 10 carbon atoms including alkyl, aryl and aralkyl groups; R.sup.1 is CH.sub.2 --CH.sub.2 --C--(CH.sub.3).sub.2 --CH.sub.2 --NHR.sup.2, R.sup.2 is hydrogen, an alkyl of C.sub.1 -C.sub.6, an alkyl amine of C.sub.1 -C.sub.6, or an alkanolamine of C.sub.1 -C.sub.6 ; Q is R, R.sup.1, hydroxyl, or an alkoxy of C.sub.1 -C.sub.4. x can be zero or integer; y is an integer, with x+y being less than 1,100, for use in various applications, including softening textiles.
    Type: Grant
    Filed: April 14, 1997
    Date of Patent: January 5, 1999
    Assignee: OSi Specialties, Inc.
    Inventors: Anna Czech, Gerald J. Murphy, Curtis L. Schilling, Jr.
  • Patent number: 5824115
    Abstract: A cellulose fiber is immersed in a cellulose fiber dissolving agent such as tertiary amine-N-oxide, lithium chloride/N,N-dimethylacetoamide or N-methylmorpholine-N-oxide under conditions where the dissolving agent does not dissolve the cellulose fiber. Therefore, the water absorbing property and moisture absorbing and discharging property of the cellulose fiber can be improved without deteriorating the strength and feeling of the cellulose fiber.
    Type: Grant
    Filed: November 27, 1996
    Date of Patent: October 20, 1998
    Assignee: Kao Corporation
    Inventors: Yuichi Kubota, Eiichi Hoshino, Koji Aigami
  • Patent number: 5807956
    Abstract: The present invention discloses non-hydrolyzable, block, (AB).sub.n A type, copolymers comprising alternating units of polysiloxane and amino-polyalkyleneoxide and provides a method for the preparation of these copolymers. Also provided is the use of these copolymers as softeners, in particular durable, hydrophilic textile softeners, which improve tactile properties of the textiles substrates treated with the commercial soil release finishes, without substantially detracting from their properties.The copolymers of the present invention have alternating units of polysiloxane ?X(C.sub.a H.sub.2a O).sub.b R.sup.2 ?(SiO(R.sup.1).sub.2 !.sub.c Si(R.sup.1).sub.2 R.sup.2 (C.sub.a H.sub.2a O).sub.b X!and polyalkyleneoxides ?YO(C.sub.a H.sub.2a O).sub.d Y!wherein R.sup.1 is a C.sub.1 to C.sub.4 alkyl, preferably methyl, R.sup.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: September 15, 1998
    Assignee: OSi Specialties, Inc.
    Inventor: Anna Czech
  • Patent number: 5718728
    Abstract: This invention relates to a method for strengthening a cellulosic substrate by treating the substrate with a formaldehyde-free curable aqueous composition and curing the composition. The cellulosic substrates include, for example, paper oil- and air-filter stock, rayon nonwoven wipes, cellulosic laminating stock, cotton woven fabrics, and wood flakes suitable to be consolidated into flakeboard.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: February 17, 1998
    Assignee: Rohm and Haas Company
    Inventors: Charles Thomas Arkens, Scott Lind Egolf, Robert David Gleim, Oscar Hsien-Hsiang Hsu, Kenneth John Wiesinger