Heterocyclic Amine Dye Patents (Class 8/409)
  • Patent number: 7132543
    Abstract: The present disclosure relates to a novel a para-phenylenediamine derivative substituted with a pyrrolidinyl group of formula (I) and the addition salts thereof. The present disclosure also relates to a dyeing composition for keratin fibers comprising the paraphenylene derivative as at least one oxidation base, and to a process for dyeing keratin fibers and a multi-compartment kit using the claimed dye composition. Such a composition makes it possible to obtain a chromatic, powerful, unselective and fast coloration of keratin fibers.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: November 7, 2006
    Assignee: L'Oreal S.A.
    Inventors: Laure Ramos, Stéphane Sabelle
  • Patent number: 7128764
    Abstract: The object of the present patent application are 3-aminophenol derivatives of formula (I) or the physiologically tolerated, water-soluble salts thereof wherein R denotes a heterocyclic aromatic 5-membered ring of formula (Ia) and colorants based on a developer-coupler combination and containing these compounds.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: October 31, 2006
    Assignee: Wella AG
    Inventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
  • Patent number: 7122061
    Abstract: The present invention has for an object compounds of formula (I) and colorants containing these 4-aminobiphenyl-3-ol derivatives of general formula (I) for dyeing keratin fibers, particularly hair, wherein R1 and R2 independently of each other denote hydrogen, a halogen atom, a cyano group, a hydroxyl group, a C1–C4-alkoxy group, a C2–C4-hydroxyalkoxy group, a C1–C6-alkyl group, a nitro group, a trifluoromethyl group, a —C(O)H group, a —C(O)CH3 group, a —C(O)CF3 group, an —Si(CH3)3 group or a C1–6-hydroxyalkyl group or R1 and R2 together form an —O—CH2—O— bridge.
    Type: Grant
    Filed: May 13, 2003
    Date of Patent: October 17, 2006
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 7105032
    Abstract: A composition for dyeing keratin-containing fibers, particularly human hair, comprising 1,2-dihydropyrimidinium derivatives in combination with reactive carbonyl compounds and methods of employing this combination for dyeing keratin-containing fibers, for color restoration or shading keratin-containing fibers that are already dyed.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: September 12, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Wibke Gross, Sandra Mausberg, Horst Hoeffkes, Doris Oberkobusch
  • Patent number: 7091350
    Abstract: The invention relates to diaminopyrazole derivatives having the following structure (I), wherein R1 represents an alkyl or alkenyl radical bearing at least one substituent selected from among OR, NRR?, SR, SOR, SO2R, COOR, CONRR?, PO(OH)2, SO3X, NHCONRR, a non-cationic heterocycle, an aryl, a halogen. R2 and R3 are different from H and represent, independently of each other, an alkyl or alkenyl group; R2 and R3, together with the nitrogen atom to which they are attached, can form a heterocycle possibly comprising at least one other heteroatom selected from among N, O and S; R2 and R3 or the heterocycle that they form with the nitrogen to which they are attached can be substituted by at least one substituent defined above.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: August 15, 2006
    Assignee: L'Oreal
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 7077872
    Abstract: The object of the present patent application are agents for dyeing keratin fibers based on a developer-coupler combination and characterized in that they contain at least one 3-aminophenol derivative of formula (I) or a physiologically compatible, water-soluble salt thereof wherein R1 denotes a group of the formula ?or a group of the formula ?as well as novel 3-aminophenol derivatives.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: July 18, 2006
    Assignee: Wella AG
    Inventors: Cècile Pasquier, Patrick Wyss, Hans-Juergen Braun
  • Patent number: 7060112
    Abstract: The invention relates to a composition for oxidation dyeing of keratinous fibers, and in particular human keratinous fibers, such as hair, comprising, in a medium appropriate for dyeing, at least one oxidation base, 2-amino-4-N-(?-hydroxyethyl)aminoanisole as coupler, and at least an enzyme of the laccase type, as well as the dyeing method using this composition.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: June 13, 2006
    Assignee: L'Oreal
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 7060107
    Abstract: Compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, and (2) a combination comprising at least one cyclohomopolymer of dialkyldiallylammonium and at least one other particular quaternary polyammonium. Processes comprising such oxidation dyeing compositions.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: June 13, 2006
    Assignee: L'Oreal S.A.
    Inventors: Cécile Bebot, Christine Rondeau, François Cottard, Francoise Boudy
  • Patent number: 7056354
    Abstract: The invention concerns compounds derived from diaminopyrazole of formula (I), wherein: Ar is a 5- or 6-membered heteroaromatic radical capable of being condensed with one or several heteroaromatic cycles each comprising 5 or 6 members, and their physiologically acceptable addition salts with and acid.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: June 6, 2006
    Assignee: L'Oreal
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 7044987
    Abstract: The invention relates to a dye composition that is useful for dyeing keratin fibres, containing at least one oxidation base and at least one coupler of the 6-alkoxy-2,3-diaminopyridine type in which the amino radical in position 2 is a monosubstituted amino radical, to the use of this composition for dyeing keratin fibres and to the dyeing process using this composition. The invention also relates to novel 6-alkoxy-2,3-diaminopyridine compounds that are useful as couplers.
    Type: Grant
    Filed: October 6, 2003
    Date of Patent: May 16, 2006
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 7029501
    Abstract: Provided is a hair dye composition containing a dissociative direct dye represented by the following formula (1): wherein, R1 to R4 each represents H or substituent, X represents OH or —NHSO2R5 (R5 representing an alkyl, aryl or heterocyclic group) and A represents a group of any one of formulas (Cp-1) through (Cp-12). The hair dye composition of the present invention is capable of strongly dyeing the hair with a vivid color tone without causing decomposition of the dye during the dyeing process, exhibits excellent resistance against sunlight, hair washing, perspiration, friction and heat, has a high stability against an alkali agent and an oxidizing agent, has a high dyeing property, and shows less color fade over time.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: April 18, 2006
    Assignees: Kao Corporation, Fuji Photo Film, Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Patent number: 7018426
    Abstract: The object of the invention is an agent for the oxidative dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formulas (I), (II) or (III) or its salt with organic or inorganic acids as well as (b) at least one resorcinol derivative of the general Formula (IV)
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: March 28, 2006
    Assignee: Wella AG
    Inventors: Manuela Javet, Christel Dousse
  • Patent number: 7014663
    Abstract: The invention concerns compounds derived from diaminopyrazole of formula (I), wherein: R1 is a linear or branched radical selected among C2, C3, C4 aminoalkyl radicals or C2, C3, C4 aminoalkenyl radicals, or one of the physiologically acceptable salts thereof. The invention also concerns compositions containing said compound for dyeing keratinous fibers and the method using said compositions.
    Type: Grant
    Filed: July 9, 2002
    Date of Patent: March 21, 2006
    Assignee: L'Oreal
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 7004980
    Abstract: Provided is a one-part air-oxidative hair dye composition containing (A) 5,6-dihydroxyindoline-2-carboxylic acid or a salt thereof, (B) an alkali agent selected from sodium hydroxide, potassium hydroxide, ammonia, guanidine, basic amino acids and carbonates, and (C) from 10 to 50 wt. % of a water compatible organic solvent, said composition being substantially free of an alkanolamine, and having a pH of from 8 to 12. This one-part air-oxidative hair dye composition has excellent hair dyeing power.
    Type: Grant
    Filed: November 6, 2002
    Date of Patent: February 28, 2006
    Assignee: Kao Corporation
    Inventors: Yoshinori Saito, Kenzo Koike
  • Patent number: 6974485
    Abstract: Use of an extract of the plant Myrsine africana in oxidation dyeing for dyeing keratin fibres, a novel composition comprising this plant extract, a process for the oxidation dyeing of keratin fibres using this composition, as well as the coloured products obtained using the composition.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: December 13, 2005
    Assignee: L'Oreal S.A.
    Inventors: Béatrice Belcour-Castro, Hervé Burgaud, Georges Hussler, Michel Seite
  • Patent number: 6951574
    Abstract: Primary intermediates for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): where R1 and R2 are each individually selected from a hydrogen atom, a C1 to C3 alkyl group, a C1 to C5 mono or dihydroxyalkyl group; phenyl or benzyl optionally substituted with an alkoxy group, or R1 and R2 together with the nitrogen atom to which they are attached form a piperazine, piperidine, imidazole, or morpholine ring.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: October 4, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan
  • Patent number: 6946005
    Abstract: Novel pyrrolidinyl-substituted para-phenylenediamine derivatives comprising a cationic radical, the dye compositions comprising them and the process for dyeing keratin fibers using these compositions, making it possible to obtain a chromatic, powerful, unselective and fast coloration of keratin fibers.
    Type: Grant
    Filed: March 27, 2003
    Date of Patent: September 20, 2005
    Assignee: L'Oreal S.A.
    Inventors: Stéphane Sabelle, Laure Ramos, Madeleine Leduc, Michel Philippe
  • Patent number: 6939382
    Abstract: The present, invention relates to novel 4,5-diaminopyrazole derivatives, to a composition for the oxidation dyeing of keratin fibers, and in particular of human keratin fibers, comprising, as oxidation base, at least one such derivative, and also to an oxidation dyeing process using this composition.
    Type: Grant
    Filed: January 6, 2003
    Date of Patent: September 6, 2005
    Assignee: L'Oreal S.A.
    Inventors: Thilo Fessmann, Eric Terranova
  • Patent number: 6936077
    Abstract: 1,3-Diamino-4-(aminomethyl)-benzene derivatives of the general Formula (I) or their physiologically tolerated, water-soluble salts, as well as agents for the oxidative dyeing of fibers, containing these compounds.
    Type: Grant
    Filed: October 19, 2001
    Date of Patent: August 30, 2005
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6923835
    Abstract: The invention relates to novel bis-para-phenylenediamine derivatives containing a pyrrolidyl group substituted with a cationic radical, to dye compositions containing them and to the process of dyeing keratin fibres using these compositions. The present invention makes it possible to obtain a chromatic, powerful, sparingly selective and colourfast coloration of keratin fibres.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: August 2, 2005
    Assignee: L'Oreal S.A.
    Inventors: Stéphane Sabelle, Laure Ramos, Madeleine Leduc
  • Patent number: 6916345
    Abstract: Dye compositions for dyeing keratin fibers, comprising at least one oxidation base and at least one coupler chosen from 6-alkoxy-2,3-diaminopyridine derivatives of formula (I) as defined herein and the addition salts thereof; the use of the compositions for dyeing keratin fibers; and the dyeing processes using the compositions; as well as at least one entity chosen from novel 6-alkoxy-2,3-diaminopyridine compounds and their addition salts thereof that are useful as couplers.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: July 12, 2005
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6916347
    Abstract: Primary intermediates for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): where R1 and R2 are each individually selected from a hydrogen atom, a C1 to C3 alkyl group, a C1 to C5 mono or dihydroxyalkyl group, phenyl or benzyl optionally substituted with an alkoxy group, or R1 and R2 together with the nitrogen atom to which they are attached form a piperazine, piperidine, imidazole, or morpholine ring.
    Type: Grant
    Filed: May 4, 2004
    Date of Patent: July 12, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan
  • Patent number: 6908493
    Abstract: Couplers for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): where R1 and R2 are each individually selected from a hydrogen atom, a C1 to C3 alkyl group, a C1 to C5 mono or dihydroxyalkyl group; phenyl or benzyl optionally substituted with an alkoxy group, or R1 and R2 together with the nitrogen atom to which they are attached form a piperazine, piperidine, imidazole, or morpholine ring.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: June 21, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan, James S. Anderson
  • Patent number: 6899739
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using the composition.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: May 31, 2005
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6893470
    Abstract: This invention concerns a ready-to-use composition for oxidation dyeing of keratinous fibres, and in particular human keratinous fibres such as hair comprising, in a suitable dyeing medium, at least a heterocyclic oxidation colouring agent, and at least an enzyme such as laccase, as well as the dyeing method using said composition.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: May 17, 2005
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6855174
    Abstract: Couplers for hair coloring compositions for oxidative dyeing of hair are compounds of the formula (1): wherein X is selected from halogen and R5SO4 where the halogen is preferably Cl, Br or I; R, R1 and R2 are each individually selected from C1 to C22 alkyl and C1 to C22 mono or dihydroxyalkyl, or two of R, R1 and R2 together with the nitrogen atom to which they are attached form a C3 to C6 saturated or unsaturated ring optionally containing in the ring one or more additional hetero atoms selected from O, S and N atoms; R3 and R4 are each individually selected from C1 to C6 alkyl, C1 to C6 hydroxyalkyl, C1 to C6 alkoxy, C1 to C6 aminoalkyl or R3 and R4 together form a C1 to C5 alkylene group; and R5 is selected from C1 to C22 alkyl and C1 to C22 mono or dihydroxyalkyl.
    Type: Grant
    Filed: May 4, 2004
    Date of Patent: February 15, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Yuh-Guo Pan, Gottfried Wenke
  • Patent number: 6849766
    Abstract: 1,4-Diamino-2-alkenylbenzene derivatives of general formula (I) or physiologically tolerated water-soluble salts thereof as well as agents for oxidative dyeing of fibers, containing these compounds.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: February 1, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6840965
    Abstract: The object of the invention are p-aminophenol derivatives of general formula (I) or physiologically tolerated, water-soluble salts thereof and oxidative coloring preparations based on a developer-coupler combination containing at least one p-aminophenol derivative of formula (I).
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: January 11, 2005
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6840966
    Abstract: The invention relates to a ready-to-use composition for the oxidation dyeing of keratin fibres, and in particular human keratin fibres such as the hair, comprising, in a medium which is suitable for dyeing, para-phenylenediamine as first oxidation base, at least one para-aminophenol as second oxidation base, 2-methyl-5-N-(?-hydroxyethyl)aminophenol as coupler and at least one enzyme of 2-electron oxidoreductase type in the presence of at least one donor for the said enzyme, and to the dyeing process using this composition.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: January 11, 2005
    Assignee: L'Oreal S.A.
    Inventors: Roland De La Mettrie, Jean Cotteret, Arnaud De Labbey, Mireille Maubru
  • Patent number: 6837908
    Abstract: Dyeing compositions for the dyeing of keratin fibers comprising at least one oxidation base chosen from formula (I), as defined herein and addition salts thereof. The use of the compositions for the dyeing of keratin fibers. Dyeing processes employing the compositions. Novel 2,5-diaminopyridine compounds and addition salts thereof and their use as oxidation bases.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: January 4, 2005
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Aziz Fadli
  • Patent number: 6835212
    Abstract: The agent for dyeing keratin fibers contains one or more aryl and/or benzyl alcohols, one or more oxidizing enzymes, especially vanillyl oxidase, derivatives of vanillyl oxidase or galactose oxidase, and a nucleophilic compound that forms a dye for dyeing keratin fibers in the presence of the alcohols and enzymes. A method for dyeing keratin fibers with this agent is also disclosed. Two-component kits for performing the method of dyeing keratin fibers include a first compenent (A) and a second component (B) separate from the first component. The first component (A) includes the nucleophilic compound, the alcohol and optionally the oxidizing enzyme. The second component (B) includes the oxidizing enzyme when it is not included in the first component or more alcohol.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: December 28, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: David Rozzell, Guido Sauter, Hans-Juergen Braun
  • Patent number: 6835213
    Abstract: Hair-coloring compositions comprise at least one self-coupling compound of Formula (1) wherein R is a moiety selected from H, C1-3 alkyl and C1-3 hydroxyalkyl; R1 is a C1-3 alkylene radical and R2 is selected from H and C1-3 alkyl radicals.
    Type: Grant
    Filed: October 23, 2002
    Date of Patent: December 28, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Mu-Ill Lim, Margaret Popp
  • Publication number: 20040237220
    Abstract: The invention relates to a dye composition comprising an oxidation base of the diaminopyrazole type and a pyrazolo-azole coupler.
    Type: Application
    Filed: March 26, 2004
    Publication date: December 2, 2004
    Inventors: Sylvain Kravtchenko, Alain Lagrange
  • Patent number: 6818023
    Abstract: A composition for coloring keratin fibers, containing an indoline, an indole, or a derivative thereof in combination with at least one amino acid or oligopeptide. The composition is useful for coloring human hair and restoring grey hair to its natural color. The formulation can be applied with atmospheric oxygen as the sole oxidizing agent.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: November 16, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Hoeffkes, Klaus Schumann, Winifried Neuhaus
  • Publication number: 20040221398
    Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibers, and in particular human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one substituted para-aminophenol as oxidation base, and/or 1,3-bis(&bgr;-hydroxyethyl)amino-2-methylbenzene and/or at least one of the addition salts thereof with an acid, as coupler, as well as to the dyeing process using this composition.
    Type: Application
    Filed: November 19, 1999
    Publication date: November 11, 2004
    Inventor: MARIE-PASCALE AUDOUSSET
  • Patent number: 6800097
    Abstract: The oxidation hair dye precursor composition contains from 0.005 to 20.0 percent by weight of at least one coupler compound and from 0.005 to 20.0 percent by weight of at least one developer compound, which includes at least one substituted 2-aminoalkyl-1,4-diaminobenzene compound of the formula (I): New substituted 2-aminoalkyl-1,4-diaminobenzene compound of formula (I) are also described.
    Type: Grant
    Filed: May 15, 2002
    Date of Patent: October 5, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6797013
    Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibres, and in particular human keratin fibres such as the hair, comprising, in a medium which is suitable for dyeing, at least one heterocyclic oxidation base and at least one 3-aminopyridine derivative as direct dye, as well as to the dyeing process using this composition.
    Type: Grant
    Filed: January 5, 2000
    Date of Patent: September 28, 2004
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret, Mireille Maubru
  • Patent number: 6793687
    Abstract: The object of the invention is an agent for oxidatively dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formula (I), (II) or (III) or its salt with organic or inorganic acids, as well as (b) at least one pyrazol-5-one derivative of the general formula (IV), (V) or (VI), or its salt with organic or inorganic acids,
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: September 21, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Manuela Javet, Christel Dousse, Dominique Le Cruer
  • Patent number: 6790240
    Abstract: A shaped body is provided for preparing coloring compositions and for coloring keratin fibers. The shaped body contains at least one dye precursor, at least one oxidizing agent, and at least one alkalinizing agent. The shaped body is placed in a composition containing water to form a coloring composition that can be applied to keratin fibers.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: September 14, 2004
    Assignee: Henkel Kommanditgesellschaft aug Aktien
    Inventors: Erik Schulze zur Wiesche, Britta Bossmann, Detlef Hollenberg, Michael Dreja
  • Patent number: 6783559
    Abstract: The invention relates to a ready-to-use composition for the oxidation dyeing of keratin fibres, and in particular human keratin fibres such as the hair, comprising, in a medium which is suitable for dyeing, at least one first oxidation base chosen from para-phenylenediamine derivatives, double bases, ortho-aminophenols and heterocyclic bases, at least one second oxidation base chosen from para-aminophenols, at least one meta-aminophenol as coupler and at least one enzyme of 2-electron oxidoreductase type in the presence of at least one donor for the said enzyme, and to the dyeing process using this composition.
    Type: Grant
    Filed: June 30, 1999
    Date of Patent: August 31, 2004
    Assignee: L'Oreal S.A.
    Inventors: Roland De La Mettrie, Jean Cotteret, Arnaud De Labbey, Mireille Maubru
  • Patent number: 6780203
    Abstract: The present invention relates to a composition for the oxidation dyeing of keratin fibers, in particular human keratin fibers, such as the hair, having at least one oxidation base chosen from diaminopyrazoles and triaminopyrazoles, in combination with at least one meta-aminophenol which is halogenated ortho to the phenol, as coupler, and to the dyeing process using this composition with an oxidizing agent.
    Type: Grant
    Filed: April 13, 2000
    Date of Patent: August 24, 2004
    Assignee: L'Oréal S.A.
    Inventors: Mireille Maubru, Marie-Pascale Audousset
  • Patent number: 6780998
    Abstract: The oxidation hair dye precursor composition contains from 0.005 to 20.0 percent by weight of one or more coupler compounds and from 0.005 to 20.0 percent by weight of one or more developer compounds. The one or more developer compounds include at least one substituted 2-aminoalkyl-1,4-diaminobenzene compound of the formula (I): New substituted 2-aminoalkyl-1,4-diaminobenzene compounds of formula (I) are described.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 24, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6752839
    Abstract: Compositions for oxidation dyeing of keratin fibers, and in particular of human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one heterocyclic oxidation base chosen from pyrazoles, certain pyrimidines, pyrazolopyrimidines and the acid addition salts thereof, and at least one coupler chosen from 2-substituted 5-aminoalkylphenol derivatives and the acid addition salts thereof, as well as dyeing processes using these compositions.
    Type: Grant
    Filed: October 20, 2000
    Date of Patent: June 22, 2004
    Assignee: L'Oreal
    Inventors: Florent Pastore, Alain Lagrange
  • Patent number: 6746493
    Abstract: Provided is a hair dye composition comprising a direct dye (1): A—CR1═N—NR2—B X−  (1) [wherein, A represents a group (2) or (3): (in which, R3, R4 and R5 each independently represents a (substituted) C1-6 alkyl group, ring C may have a substituent or may by cyclocondensed with an aromatic ring, R6 and R7 each independently represents a (substituted) C1-6 alkyl group, or may be coupled to form a heterocycle together with the adjacent nitrogen atom, Z represents a (substituted) C1-4 divalent linear hydrocarbon group and ring D may be cyclocondensed with an aromatic ring), B represents a (substituted) aromatic group, R1 represents H or a (substituted) C1-6 alkyl group, R2 represents H or a (substituted) C1-6 alkyl group or a (substituted) aromatic group or may form a heterocycle together with the C atom of the aromatic ring B, and X− represents an anion].
    Type: Grant
    Filed: April 10, 2003
    Date of Patent: June 8, 2004
    Assignee: Kao Corporation
    Inventors: Hajime Miyabe, Kenichi Matsunaga, Yukihiro Ohashi, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6743263
    Abstract: The present invention relates to a composition for coloring keratinaceous fibers and a method of using the same. The composition of the present invention contains (a) at least one pyrimidine derivative and (b) at least one compound selected from an m-phenylene derivative, an m-aminophenol derivative, a pyridine derivative, a resorcinol derivative, a methylenedioxybenzene derivative, or 3,4-diaminobenzoic acid or combinations thereof. The method of the present invention includes applying the coloring composition to keratin-containing fibers and subsequently rinsing the coloring composition from the fibers.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: June 1, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst Hoeffkes, Doris Oberkobusch, David Rose, Melanie Hitz
  • Patent number: 6740128
    Abstract: The object of the invention is a preparation for dyeing fibers, especially hair, which is prepared before use by mixing an acidic component (A1), containing at least an enamine of formula (I) or its acid addition salt of Formula (Ia) with an alkaline component (A2), containing at least one carbonyl compound and at least one primary amine, as well as a method for temporarily dyeing fibers, by means of which the coloration, obtained with the aforementioned dyeing preparation, is removed once again at any later time by a sulfite-containing decolorizing agent.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: May 25, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Manuela Javet, Catherine Mueller
  • Patent number: 6740129
    Abstract: A one-package post-foaming oxidation hair dye composition containing uricase, uric acid, at least one oxidation dye, and at least one post-foaming agent is provided. The oxidation hair dye composition is packaged in a single package, and foams after spreading on hair.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: May 25, 2004
    Assignee: Henkel Lion Cosmetics Co. Ltd.
    Inventors: Yoshio Tsujino, Masahiro Aoki
  • Patent number: 6733539
    Abstract: Compositions for oxidation dyeing of keratinous fibers, for example, human keratinous fibers such as hair, comprising, in a medium suitable for dyeing, at least one enzymatic oxidizing agent and at least one oxidation dye chosen from the pyridine compounds and acid addition salts, of formula (I) and processes comprising such compositions.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: May 11, 2004
    Assignee: L'Oreal S.A.
    Inventor: Grégory Plos
  • Patent number: 6733540
    Abstract: The invention relates to the field of the oxidation dyeing of keratinous fibres and in particular of human keratinous fibers, such as the hair. The invention relates more particularly to the use of certain 2-(sulphonylamino)phenols of following formula (I) as coupler in combination with oxidation dye precursors for the oxidation dyeing of the fibers.
    Type: Grant
    Filed: November 14, 2001
    Date of Patent: May 11, 2004
    Assignee: L'Oreal
    Inventors: Jean-Baptiste Saunier, Laurent Vidal
  • Patent number: 6730133
    Abstract: Compositions, such as ready-to-use compositions for oxidation dyeing of keratinous fibers, and in particular human keratinous fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one oxidation dye, and at least one enzymatic system, the enzymatic system comprising (i) at least one enzyme immobilized in at least one sol-gel matrix and optionally (ii) at least one suitable donor, wherein said at least one enzyme is chosen from 2-electron oxidoreductases, 4-electron oxidoreductases and peroxidases, with the proviso that when said at least one enzyme is chosen from 2-electron oxidoreductases, said at least one enzymatic system comprises at least one suitable donor, and with the proviso that when said at least one enzyme is chosen from peroxidases, said at least one enzymatic system further comprises at least one source of hydrogen peroxide chosen from hydrogen peroxide and at least one enzymatic system which generates hydrogen peroxide in situ, as well as to processes for dyeing
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: May 4, 2004
    Assignee: L'Oreal S.A.
    Inventors: Grégory Plos, Alain Lagrange