Abstract: The use of indolines of formula (I):
in which R1, R2, R3, R4 and R5 independently of one another represent hydrogen or C1-4 alkyl groups, or R4 and R5 together with the oxygen atoms to which they are attached may represent an alkylenedioxy group containing 1 to 4 carbon atoms, or their salts, as oxidation dye precursors gives natural brown hair colorings. The indolines of formula (I) are also suitable as couplers in oxidation hair dyes with a conventional primary intermediate, in which they result in a modification of the tints obtainable with the primary intermediate. They are used in conventional carriers, e.g., in gel or emulsion form, preferably mixed before use or on the hair with an oxidizing agent to develop the color.
Type:
Grant
Filed:
November 19, 1992
Date of Patent:
April 13, 2004
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Guenther Konrad, Iduna Matzik, Edgar Lieske
Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below:
a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of:
i) part ai dye intermediates in water at alkaline pH with quaternary ammonium compounds;
ii) part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH;
b.) rinsing said mixture from said hair with water;
and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
Type:
Grant
Filed:
March 7, 2002
Date of Patent:
March 23, 2004
Assignee:
Unilever Home & Personal Care USA
Inventors:
Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
Abstract: The present patent application relates to 3-(2,5-diaminophenyl)acrylamide derivatives of general formula (I) or to physiologically tolerated, water-soluble-salts thereof
and to agents containing said compounds and used for oxidative dyeing of fibers.
Abstract: Compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, (2) at least one fatty alcohol comprising more than twenty carbon atoms, (3) optionally at least one fatty alcohol having at most twenty carbon atoms, (4) at least one oxyalkylenated nonionic surfactant with an HLB greater than 5, and (5) optionally at least one oxyalkylenated surfactant with an HLB at most equal to 5, in a proportion such that the weight ratio [(4)]/[(2)+(3)+(5)] is less than or equal to 1:1. Processes comprising such oxidation dyeing compositions.
Abstract: A subject-matter of the invention is a composition for the oxidation dyeing of keratinous fibers comprising at least one pyrazolo[1,5-a]pyrimidine as oxidation base and at least one pyridine coupler, and the oxidation dyeing process employing thus composition.
Abstract: The invention relates to the use of novel indole compounds as direct dyes in compositions intended for dyeing keratin materials, and, for example, compositions intended for dyeing human keratin fibers and including the hair, and in cosmetic compositions intended for making up the skin, the nails and the lips, to the dye compositions or make-up compositions comprising them and to the direct dyeing process using them, and processes of manufacturing said novel indole compounds.
Type:
Grant
Filed:
May 3, 2002
Date of Patent:
February 17, 2004
Assignee:
L'Oréal S.A.
Inventors:
Nicole Bonaventure, Patrick Gilard, Gilles Barre, Michel Dubois
Abstract: New substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or physiologically compatible water-soluble salts thereof,
are described as well as methods for preparing them. In addition, oxidation dye precursor compositions for dyeing keratin fibers, especially human hair, which each contain from 0.005 to 20 percent by weight of at least one of the new substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or their physiologically compatible water-soluble salts, are described. Methods for dyeing hair with ready-to-apply dye mixtures made by mixing these oxidation dye precursor compositions with an oxidizing agent, such as hydrogen peroxide solution, are also described.
Abstract: The invention concerns a composition for dyeing keratin fibers, in particular human keratin fibers such as hair comprising at least one pyrazolin-4,5-dione of formula (I) and at least one aromatic primary amine. Said composition enables the dyeing of keratin fibers without an oxidizing agent in shades which are strong, varied, resistant and less selective than those of prior art. The invention also concerns dyeing methods and devices using said composition.
Abstract: Compositions for the oxidation dyeing of keratin fibers, comprising, as oxidation base, at least one para-aminophenol, of formula (I) and/or at least one acid-addition salt thereof:
in which:
R1 represents a hydrogen atom, a linear or branched C1-C4 alkyl radical or a C1-C4 trifluoroalkyl radical,
R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl radical or a C1-C4 monohydroxyalkyl radical, and
X, Y and Z independently represent a carbon, nitrogen, oxygen or sulphur atom, wherein the bonds XY and YZ are single or double bonds;
a dyeing process using these compositions, novel para-aminophenols and a process for their preparation.
Type:
Grant
Filed:
October 24, 2000
Date of Patent:
January 6, 2004
Assignee:
L'Oréal
Inventors:
Jean Jacques Vandenbossche, Alain Lagrange
Abstract: A shaped body is provided for preparing coloring compositions and for coloring keratin fibers. The shaped body contains at least one indole derivative, and/or at least one indoline derivative as a dye precursor. The shaped body is placed in a composition containing water to form a coloring composition that can be applied to keratin fibers.
Type:
Grant
Filed:
June 14, 2002
Date of Patent:
January 6, 2004
Assignee:
Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
Inventors:
Erik Schulze zur Wiesche, Detlef Hollenberg, Michael Dreja
Abstract: The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II)
as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.
Abstract: The invention relates to a hair colorant comprised of a flowable, aqueous preparation of oxidation colorant intermediate products (A) and a flowable, aqueous oxidation agent preparation (B) which are mixed in a weight ratio A:B=1:2 to 2:1 to produce a gel-forming coloring batch immediately before applying on the hair. As supporting components in the oxidation colorant preparation, the hair colorant comprises 3.0 to 15 wt. % of a saturated or unsaturated, linear or branched alcohol with 8 to 36 C-atoms, 0.1 to 20 wt. % of a low-molecular water-soluble alcohol, 0.1 to 15 wt. % of a liquid fatty acid with 16 to 22 C-atoms in the form of a water-soluble soap, 0.1 to 20 wt. % of an addition product of 1 to 5 mole ethylene oxide on a linear fatty alcohol with 8 to 22 C-atoms and/or 0.1 to 15 wt. % of an optional alkoxylated amine. The oxidation agent preparation (B) preferably comprises 3 to 12 wt. % hydrogen peroxide, 0.1 to 5 wt. % of a water-soluble, synthetic tenside and 1 to 5 wt.
Type:
Grant
Filed:
August 10, 2000
Date of Patent:
December 9, 2003
Assignee:
Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
Inventors:
Horst Hoeffkes, Bernd Meinigke, Norbert Schettiger, Konstantin Goutsis
Abstract: The invention concerns novel pyrazole derivatives comprising at least a cationic group Z, Z being selected among the quaternized aliphatic chains, aliphatic chains comprising at least a saturated quaternized cycle, and aliphatic chains comprising at least an unsaturated quaternized cycle, their use as oxidation base for dyeing keratin fibres, dyeing compositions containing them, and dyeing methods using them.
Abstract: Novel oxidation bases comprising a benzene nucleus and a guanidine chain, a process for their preparation, their use for the oxidation dyeing of keratin fibers, dye compositions containing them, and oxidation dyeing processes using them are described.
Abstract: Provided is a hair dye composition comprising a direct dye (1):
A—CR1═N—NR2—B X− (1)
[wherein, A represents a group (2) or (3):
(in which, R3, R4 and R5 each independently represents a (substituted) C1-6 alkyl group, ring C may have a substituent or may by cyclocondensed with an aromatic ring, R6 and R7 each independently represents a (substituted) C1-6 alkyl group, or may be coupled to form a heterocycle together with the adjacent nitrogen atom, Z represents a (substituted) C1-4 divalent linear hydrocarbon group and ring D may be cyclocondensed with an aromatic ring), B represents a (substituted) aromatic group, R1 represents H or a (substituted) C1-6 alkyl group, R2 represents H or a (substituted) C1-6 alkyl group or a (substituted) aromatic group or may form a heterocycle together with the C atom of the aromatic ring B, and X− represents an anion].
Abstract: The invention relates to novel compositions for the oxidation dyeing of keratin fibers, comprising at least one specific diaminopyrazole derivative, to the dyeing process using this composition, to novel diaminopyrazole derivatives and to a process for their preparation.
Type:
Grant
Filed:
October 18, 2001
Date of Patent:
November 11, 2003
Assignee:
L'Oreal, S.A.
Inventors:
Laurent Vidal, Agnès Burande, Gérard Malle, Michel Hocquaux
Abstract: The invention relates to novel monobenzene oxidation bases containing at least one cationic group Z, Z being chosen from aliphatic chains containing at least one quaternized unsaturated ring, to their use for the oxidation dyeing of keratin fibers, to dye compositions containing them and to oxidation dyeing processes using them.
Abstract: Compositions for oxidation dyeing keratinous fibers, for example, human keratinous fibers such as hair, comprising at least one oxidation base and at least one coupler chosen from N-(2-hydroxybenzene)carbamate and N-(2-hydroxybenzene)urea compounds and their acid addition salts of formula (I) and processes comprising such compositions.
Abstract: Compositions, methods, and kits for dyeing at least one keratin fiber, comprising at least one specific cationic compound and at least one compound chosen from specific aldehydes, specific ketones, quinones, diiminoisoindoline derivatives, and 3-aminoisoindolone derivatives, with the proviso that the inventive compositions do not comprise an oxidizing agent.
Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibers, and in particular human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one substituted para-aminophenol as oxidation base, and/or 1,3-bis(&bgr;-hydroxyethyl)amino-2-methylbenzene and/or at least one of the addition salts thereof with an acid, as coupler, as well as to the dyeing process using this composition.
Abstract: An oxidation dyeing composition for keratinous fibers, in particular hair, comprising, as oxidation base, at least one compound of the formula:
where n=0-11, R represents H, amino, a saturated or unsaturated, linear or branched C1-C6 alkyl or is a radical chosen from radicals defined in the specification.
Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.
Type:
Application
Filed:
March 13, 2002
Publication date:
September 18, 2003
Applicant:
Unilever Home & Personal Care USA, Division of Conopco, Inc.
Abstract: Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye after storage.
wherein, ring A may represents a benzene ring which may have a substituent or the like, B represents an aryl or heterocyclic group, D represents N or CR4 (wherein R4 represents H or alkyl), E represents NR5, CR6R7 or CR6═CR7 (wherein R5 represents alkyl or the like, and R6 and R7 each represents H or alkyl) or, O or S, R1 represents alkyl or the like, and n stands for 0 or 1, with the proviso that at n=0, R2 and R5 form, when taken together with N—C—C, a heterocycle, or R2 is bonded to B, thereby forming a heterocycle and at n=1, R2 and R3 form, when taken together with C═D—N, a heterocycle, and X− represents an anion.
Abstract: The invention concerns a process for the oxidative dyeing of human hair, whereby an aqueous composition having a pH-value between 7.0 and 12.0 is applied to the hair, wherein this Composition (AB) was obtained by admixture of an oxidation dyestuff precursor Composition (A), which comprises at least one developing and at least one coupling substance as well as at least one or more specific metal compounds, having an alkaline pH-value, with a hydrogen peroxide Composition (B), having a pH-value in the acidic range and comprising 0.05 & to 5.0% by weight, calculated to the total composition, of 1-hydroxyethane-1,1-diphosphonic acid and/or the alkali or ammonium salts thereof.
Abstract: Provided is a hair dye composition containing a direct dye (1), (2) or (3). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage.
wherein, R1 represents a (substituted) aryl group, R2, R4 to R6, R8 and R9 each represents H, a (substituted) C1-6 alkyl group or a (substituted) aryl group, R3 and R7 each represents a (substituted) aryl group, R10 to R12 each represents a (substituted) C1-6 alkyl or (substituted) aryl group, rings A to G each represents a benzene ring which may be substituted by a (substituted) amino group, (substituted) C1-6 alkyl group, C1-6 alkoxy group or halogen atom or may further be cyclocondensed with a benzene ring, and X− represents an anion.
Abstract: The invention relates to a composition for dyeing keratin fibers, in particular human keratin fibers such as the hair, comprising at least one cationic direct dye of given formula and at least one thickening polymer chosen from nonionic guar gums, biopolysaccharide gums of microbial origin, gums derived from plant exudates, pectins, alginates, starches, and carboxyalkylcelluloses. The invention also relates to the dyeing processes and dyeing devices using the composition.
Abstract: The subject of the invention is novel compounds derived from naphth-1-ol comprising at least one cationic group, their use as coupler for the oxidation dyeing of keratinous fibres, compositions for the oxidation dyeing of keratinous fibres, and in particular human keratinous fibres such as hair, containing them in combination with at least one oxidation base, as well as methods of oxidation dyeing using them.
Abstract: Provided is a hair dye composition comprising as a direct dye a compound represented by the following formula (1), (2), (3) or (4):
[wherein, R1 and R1′ each independently represents a (substituted) C1-6 alkyl or a (substituted) aryl group; W and W′ each independently represents a group —A—NR2R3 or a (substituted) heterocyclic aromatic group; A and A′ each independently represents a divalent (substituted) aryl group; R2, R2′ and R3 each independently represents H, a (substituted) alkyl or a (substituted) aryl group, or R2, R2′ or R3 may be bonded to A or A′, thereby forming a heterocycle, R2 and R3, or R2 and R2′ are coupled to form a heterocycle, together with the adjacent atom; R4 to R6 each independently represents H, (substituted) alkyl or (substituted) alkenyl group; Q represents a divalent organic group; X represents a modified carboxy group, an —SO2—T— group (in which, T represents an alkyl, alkenyl or aryl)
Abstract: New substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or physiologically compatible water-soluble salts thereof,
are described as well as methods for preparing them. In addition, oxidation dye precursor compositions for dyeing keratin fibers, especially human hair, which each contain from 0.005 to 20 percent by weight of at least one of the new substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or their physiologically compatible water-soluble salts, are described. Methods for dyeing hair with ready-to-apply dye mixtures made by mixing these oxidation dye precursor compositions with an oxidizing agent, such as hydrogen peroxide solution, are also described.
Abstract: Compositions for oxidation dyeing of keratinous fibers, for example, human keratinous fibers such as hair, further such as human hair, comprising, in a medium suitable for dyeing, at least one oxidation dye, at least one cationic amphiphilic polymer comprising at least one fatty chain, and a combination comprising: (I) at least one compound chosen from oxyalkylenated and glycerolated fatty alcohols and (II) at least one hydroxylated solvent, wherein the hydroxylated solvent may have a molecular weight of less than 250, and wherein the weight ratio of (I) to (II) is greater than 1:1 and dyeing processes and devices, such as kits, comprising such compositions.
Abstract: The invention concerns a ready-to-use composition for oxidation dyeing of keratinous fibers, and in particular human keratinous fibers such as hair comprising, in a suitable dyeing medium, at least an oxidation base, 2-amino 3 hydroxy pyridine as coupling agent, and at least an enzyme such as laccase, as well as the method using said composition.
Abstract: Diaminopyrazole derivatives of the general Formula (I) or their physiological tolerated, water-soluble salts with inorganic or organic acids,
and agents, containing these compounds, for the oxidative dyeing of fibers.
Abstract: A ready-to-use composition for the oxidation dyeing of keratin fibers, and, in particular, human keratin fibers, such as the hair, having at least one oxidation dye, at least one oxidoreductase enzyme, and at least one specific salified or chemically modified chitosan, as well as to the oxidation dyeing process using this composition.
Abstract: The object of the invention is an agent for oxidatively dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formula (I), (II) or (III) or its salt with organic or inorganic acids, 1
Type:
Application
Filed:
October 8, 2002
Publication date:
July 17, 2003
Inventors:
Manuela Javet, Christel Dousse, Dominique Le Cruer
Abstract: The p-aminophenol derivative compounds of formula (I), or their physiologically compatible water-soluble salts:
are useful as developer compounds in oxidation dye compositions for keratin fibers. Oxidation dye compositions for keratin fibers, including hair, and methods of dyeing hair using the p-aminophenol derivative compounds are also described.
Abstract: Provided is a hair dye composition containing a direct dye (1) or (2). The hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a smaller change in the color tone of the dye after storage.
[R1, R2 and R3 are the same or different and each independently represents a C1-3 alkyl group and benzene ring A or B may contain a nondissociative substituent].
Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer.
The invention also relates to the dyeing processes and devices using the composition.
Abstract: Compositions for the oxidation dyeing of keratin fibers, containing at least one oxidation base and at least one coupler chosen from indolizine derivative comprising at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains comprising at least one quaternized saturated ring, and aliphatic chains comprising at least one quaternized unsaturated ring. Methods of using these cationic indolizine derivatives as couplers for the oxidation dyeing of keratin fibers, in combination with at least one oxidation base, and to dyeing processes using them. Some of these cationic indolizine derivatives are novel.
Type:
Grant
Filed:
February 26, 2001
Date of Patent:
June 17, 2003
Assignee:
L'Oreal S.A.
Inventors:
Philippe Breton, Fabienne Segala, Alain Lagrange
Abstract: The invention relates to a cosmetic mixture for the oxidation tinting of keratin fibres, containing in a support material suitable for tinting keratin fibres (a) at least one laccase-type enzyme; (b) at least one polymer thickener selected from the group constituted by: (i) amphiphilic non-ionic polymers comprising at least one fatty chain and at least one hydrophilic unit; (ii) anionic amphiphilic polymers comprising at least one hydrophilic unit and at least one fatty chain unit; (iii) cross-linked acrylic acid homopolymers; (iv) cross-linked 2-acrylamide-2-methyl-propane sulfonic acid homopolymers and their cross-linked acrylamide copolymers, which are partially or fully neutralized; (v) ammonium acrylate homopolymers or ammonium acrylate and acrylamide copolymers; (vi) dimethylaminoethyl-methacrylate homopolymers quatemized by methyl chloride or dimethylaminoethyl-methacrylate copolymers quaternized by methyl chloride and acrylamide copolymers; (vii) non-ionic guar gums; (viii) scleroglucan gum (a biopoly
Abstract: Compositions for oxidation dyeing of keratin fibers comprising at least one oxidation base and at least one coupler chosen from indolizine derivatives, methods for using the same for oxidation dyeing of keratin fibers, and compounds chosen from indolizine derivatives.
Abstract: The invention concerns the use of indoline derivatives of formula (I):
in which R1, R2, R3, R4 and R5 independently of one another represent hydrogen or C1-4 alkyl groups, or R4 and R5 together with the oxygen atoms to which they are attached represent a C1-4 alkylenedioxy group, or of salts of such indoline derivatives, as additives to hair dyeing agents of the direct dyeing or primary intermediate/secondary intermediate type, thus producing hair dyeing with excellent color fastness characteristics.
Abstract: Primary intermediates useful hair coloring systems comprise 2-arylaminomethyl-4-aminophenols. The invention provides new 2-arylaminomethyl-4-aminophenol compounds of Formula (1):
wherein R is a moiety selected from formulae (2), (3) or (4)
wherein R1, R2, R3, R4 and R5 are each independently selected from a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a C1-C6 alkyl or haloalkyl group, a C1-C6 alkoxy or haloalkoxy group, and a nitrile group, and R6 is a hydrogen atom, a halogen atom, a C1-C4 alkyl or a C1-C4 alkoxy group.
Abstract: Disclosed are hair care compositions including a polyalkyleneglycol(n)alkylamine of formula (I), (II), or mixtures thereof, wherein each R is independently a saturated, unsaturated, straight or branched alkyl group having from 1 to about 30 carbon atoms, R′ is a saturated, unsaturated, straight or branched alkyl group having from 1 to about 4 carbon atoms, each m is 2 or 3, each n is 2 or 3, each x and each y are independently a number of 1 or more wherein the sum of each x and each y is from about 3 to about 9; and wherein X- is any safe and suitable salt forming anion selected from the group consisting of chloride, bromide, iodide, acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfonate, sulfate, alkylsulfate, alkyl sulfonate, glutamate aspartate, and mixtures thereof; and wherein the melting point of the polyalkyleneglycol(n)alkylamine is less than about 45° C.; and a gel matrix comprising a cationic surfactant, a solid fatty compound, and water.
Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.
Type:
Application
Filed:
July 17, 2002
Publication date:
April 24, 2003
Applicant:
Unilever Home & Personal Care USA, Division of Conopco, Inc.
Abstract: The present invention relates to a composition for dyeing keratin fibres, in particular human hair, containing, in a medium which is suitable for dyeing:
as coupler, at least one compound of formula:
or one of the addition salts thereof with an acid, in which:
R2 denotes, in particular, hydrogen, halogen, alkoxy, aryloxy, acetylamido, etc.
R1 and R3, which are independent, denote, in, particular: hydrogen, alkyl, aryl, a heterocycle, etc.
it being understood that when R2 and R1 simultaneously represent a hydrogen atom, then R1 is other than a hydrogen atom, a C1-C5 alkyl radical or a phenyl radical;
and at least one oxidation base.