Heterocyclic Amine Dye Patents (Class 8/409)
  • Patent number: 6719811
    Abstract: The use of indolines of formula (I): in which R1, R2, R3, R4 and R5 independently of one another represent hydrogen or C1-4 alkyl groups, or R4 and R5 together with the oxygen atoms to which they are attached may represent an alkylenedioxy group containing 1 to 4 carbon atoms, or their salts, as oxidation dye precursors gives natural brown hair colorings. The indolines of formula (I) are also suitable as couplers in oxidation hair dyes with a conventional primary intermediate, in which they result in a modification of the tints obtainable with the primary intermediate. They are used in conventional carriers, e.g., in gel or emulsion form, preferably mixed before use or on the hair with an oxidizing agent to develop the color.
    Type: Grant
    Filed: November 19, 1992
    Date of Patent: April 13, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Guenther Konrad, Iduna Matzik, Edgar Lieske
  • Patent number: 6716257
    Abstract: The new diaminopyrazole compounds are bridged 4,5-diaminopyrazole compounds or salts thereof.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: April 6, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Otto Goettel, Aline Pirrello, André Hayoz, Emmanuel Morand
  • Patent number: 6709468
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.) below: a.) contacting said hair, for a period of about 5 seconds to about 5 minutes with a recently made mixture of: i) part ai dye intermediates in water at alkaline pH with quaternary ammonium compounds; ii) part aii an oxidizing compound such as hydrogen peroxide in water at acidic pH; b.) rinsing said mixture from said hair with water; and wherein said number of treatments is between about 2 to about 30; and wherein said set time interval between each two consecutive treatments is between about 8 hours and 30 days.
    Type: Grant
    Filed: March 7, 2002
    Date of Patent: March 23, 2004
    Assignee: Unilever Home & Personal Care USA
    Inventors: Jitendra Patel, Gerald Patrick Newell, Elizabeth Kim, Fe P Pascual, Margie Fowler
  • Patent number: 6702863
    Abstract: A hairdye composition, characterized in that, indoline and/or indoline compound and laccase are compounded.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: March 9, 2004
    Assignee: Lion Corporation
    Inventors: Takeshi Onuki, Mutsumi Noguchi, Joji Mitamura
  • Patent number: 6699990
    Abstract: The present patent application relates to 3-(2,5-diaminophenyl)acrylamide derivatives of general formula (I) or to physiologically tolerated, water-soluble-salts thereof and to agents containing said compounds and used for oxidative dyeing of fibers.
    Type: Grant
    Filed: October 21, 2002
    Date of Patent: March 2, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6695887
    Abstract: Compositions for oxidation dyeing keratin fibers, such as human keratin fibers like hair, comprising, in a dyeing medium, (1) at least one oxidation dye, (2) at least one fatty alcohol comprising more than twenty carbon atoms, (3) optionally at least one fatty alcohol having at most twenty carbon atoms, (4) at least one oxyalkylenated nonionic surfactant with an HLB greater than 5, and (5) optionally at least one oxyalkylenated surfactant with an HLB at most equal to 5, in a proportion such that the weight ratio [(4)]/[(2)+(3)+(5)] is less than or equal to 1:1. Processes comprising such oxidation dyeing compositions.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: February 24, 2004
    Assignee: L'Oreal S.A.
    Inventors: François Cottard, Christine Rondeau
  • Patent number: 6692540
    Abstract: A subject-matter of the invention is a composition for the oxidation dyeing of keratinous fibers comprising at least one pyrazolo[1,5-a]pyrimidine as oxidation base and at least one pyridine coupler, and the oxidation dyeing process employing thus composition.
    Type: Grant
    Filed: April 26, 2000
    Date of Patent: February 17, 2004
    Assignee: L'Oreal S.A.
    Inventor: Marie-Pascale Audousset
  • Patent number: 6692538
    Abstract: The invention relates to the use of novel indole compounds as direct dyes in compositions intended for dyeing keratin materials, and, for example, compositions intended for dyeing human keratin fibers and including the hair, and in cosmetic compositions intended for making up the skin, the nails and the lips, to the dye compositions or make-up compositions comprising them and to the direct dyeing process using them, and processes of manufacturing said novel indole compounds.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: February 17, 2004
    Assignee: L'Oréal S.A.
    Inventors: Nicole Bonaventure, Patrick Gilard, Gilles Barre, Michel Dubois
  • Patent number: 6685751
    Abstract: New substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or physiologically compatible water-soluble salts thereof, are described as well as methods for preparing them. In addition, oxidation dye precursor compositions for dyeing keratin fibers, especially human hair, which each contain from 0.005 to 20 percent by weight of at least one of the new substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or their physiologically compatible water-soluble salts, are described. Methods for dyeing hair with ready-to-apply dye mixtures made by mixing these oxidation dye precursor compositions with an oxidizing agent, such as hydrogen peroxide solution, are also described.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: February 3, 2004
    Assignee: Wella Aktiengesellschaft
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6679923
    Abstract: The invention concerns a composition for dyeing keratin fibers, in particular human keratin fibers such as hair comprising at least one pyrazolin-4,5-dione of formula (I) and at least one aromatic primary amine. Said composition enables the dyeing of keratin fibers without an oxidizing agent in shades which are strong, varied, resistant and less selective than those of prior art. The invention also concerns dyeing methods and devices using said composition.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: January 20, 2004
    Assignee: L'Oreal S.A.
    Inventors: Laurent Vidal, Gérard Malle, Mireille Maubru
  • Patent number: 6673123
    Abstract: A shaped body is provided for preparing coloring compositions and for coloring keratin fibers. The shaped body contains at least one indole derivative, and/or at least one indoline derivative as a dye precursor. The shaped body is placed in a composition containing water to form a coloring composition that can be applied to keratin fibers.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: January 6, 2004
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Erik Schulze zur Wiesche, Detlef Hollenberg, Michael Dreja
  • Patent number: 6673122
    Abstract: Compositions for the oxidation dyeing of keratin fibers, comprising, as oxidation base, at least one para-aminophenol, of formula (I) and/or at least one acid-addition salt thereof: in which: R1 represents a hydrogen atom, a linear or branched C1-C4 alkyl radical or a C1-C4 trifluoroalkyl radical, R2 and R3 independently represent a hydrogen atom, a C1-C4 alkyl radical or a C1-C4 monohydroxyalkyl radical, and X, Y and Z independently represent a carbon, nitrogen, oxygen or sulphur atom, wherein the bonds XY and YZ are single or double bonds; a dyeing process using these compositions, novel para-aminophenols and a process for their preparation.
    Type: Grant
    Filed: October 24, 2000
    Date of Patent: January 6, 2004
    Assignee: L'Oréal
    Inventors: Jean Jacques Vandenbossche, Alain Lagrange
  • Patent number: 6669739
    Abstract: The object of the present invention is a preparation for coloring fibers, which is prepared before use by mixing an acidic component (A1), containing at least one enamine of Formula (I)/(Ia) with a component (A2), containing a Schiff's base of Formula (II) as well as a method for temporarily coloring fibers, for which the coloration, obtained with the aforementioned coloring agent, can be removed once again at any time by a sulfite-containing decolorizing agent.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: December 30, 2003
    Assignee: Wella Aktiengesellschaft
    Inventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
  • Patent number: 6660046
    Abstract: The invention concerns novel pyrazole derivatives comprising at least a cationic group Z, Z being selected among the quaternized aliphatic chains, aliphatic chains comprising at least a saturated quaternized cycle, and aliphatic chains comprising at least an unsaturated quaternized cycle, their use as oxidation base for dyeing keratin fibres, dyeing compositions containing them, and dyeing methods using them.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: December 9, 2003
    Assignee: L'Oreal S.A.
    Inventors: Eric Terranova, Alain Lagrange
  • Patent number: 6660045
    Abstract: The invention relates to a hair colorant comprised of a flowable, aqueous preparation of oxidation colorant intermediate products (A) and a flowable, aqueous oxidation agent preparation (B) which are mixed in a weight ratio A:B=1:2 to 2:1 to produce a gel-forming coloring batch immediately before applying on the hair. As supporting components in the oxidation colorant preparation, the hair colorant comprises 3.0 to 15 wt. % of a saturated or unsaturated, linear or branched alcohol with 8 to 36 C-atoms, 0.1 to 20 wt. % of a low-molecular water-soluble alcohol, 0.1 to 15 wt. % of a liquid fatty acid with 16 to 22 C-atoms in the form of a water-soluble soap, 0.1 to 20 wt. % of an addition product of 1 to 5 mole ethylene oxide on a linear fatty alcohol with 8 to 22 C-atoms and/or 0.1 to 15 wt. % of an optional alkoxylated amine. The oxidation agent preparation (B) preferably comprises 3 to 12 wt. % hydrogen peroxide, 0.1 to 5 wt. % of a water-soluble, synthetic tenside and 1 to 5 wt.
    Type: Grant
    Filed: August 10, 2000
    Date of Patent: December 9, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)
    Inventors: Horst Hoeffkes, Bernd Meinigke, Norbert Schettiger, Konstantin Goutsis
  • Patent number: 6652600
    Abstract: Novel oxidation bases comprising a benzene nucleus and a guanidine chain, a process for their preparation, their use for the oxidation dyeing of keratin fibers, dye compositions containing them, and oxidation dyeing processes using them are described.
    Type: Grant
    Filed: January 29, 2001
    Date of Patent: November 25, 2003
    Assignee: L'Oreal S.A.
    Inventors: Thierry Bordier, Michel Philippe
  • Publication number: 20030213071
    Abstract: A method for the synthesis of 5-aryl-1,3,3,-trimethyl-2-methylene-indoline derivatives of Formula (I) or its salts of Formula (Ia) 1
    Type: Application
    Filed: December 4, 2002
    Publication date: November 20, 2003
    Inventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
  • Patent number: 6648924
    Abstract: Provided is a hair dye composition comprising a direct dye (1): A—CR1═N—NR2—B X−  (1) [wherein, A represents a group (2) or (3): (in which, R3, R4 and R5 each independently represents a (substituted) C1-6 alkyl group, ring C may have a substituent or may by cyclocondensed with an aromatic ring, R6 and R7 each independently represents a (substituted) C1-6 alkyl group, or may be coupled to form a heterocycle together with the adjacent nitrogen atom, Z represents a (substituted) C1-4 divalent linear hydrocarbon group and ring D may be cyclocondensed with an aromatic ring), B represents a (substituted) aromatic group, R1 represents H or a (substituted) C1-6 alkyl group, R2 represents H or a (substituted) C1-6 alkyl group or a (substituted) aromatic group or may form a heterocycle together with the C atom of the aromatic ring B, and X− represents an anion].
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: November 18, 2003
    Assignee: Kao Corporation
    Inventors: Hajime Miyabe, Kenichi Matsunaga, Yukihiro Ohashi, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6645258
    Abstract: The invention relates to novel compositions for the oxidation dyeing of keratin fibers, comprising at least one specific diaminopyrazole derivative, to the dyeing process using this composition, to novel diaminopyrazole derivatives and to a process for their preparation.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: November 11, 2003
    Assignee: L'Oreal, S.A.
    Inventors: Laurent Vidal, Agnès Burande, Gérard Malle, Michel Hocquaux
  • Patent number: 6638321
    Abstract: The invention relates to novel monobenzene oxidation bases containing at least one cationic group Z, Z being chosen from aliphatic chains containing at least one quaternized unsaturated ring, to their use for the oxidation dyeing of keratin fibers, to dye compositions containing them and to oxidation dyeing processes using them.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: October 28, 2003
    Assignee: L'Oreal
    Inventors: Alain Genet, Alain Lagrange
  • Patent number: 6635090
    Abstract: Compositions, methods, and kits for dyeing at least one keratin fiber, comprising at least one specific cationic compound and at least one compound chosen from specific aldehydes, specific ketones, quinones, diiminoisoindoline derivatives, and 3-aminoisoindolone derivatives, with the proviso that the inventive compositions do not comprise an oxidizing agent.
    Type: Grant
    Filed: October 3, 2000
    Date of Patent: October 21, 2003
    Assignee: L'Oreal, S.A.
    Inventors: Hervé Andrean, Alain Lagrange
  • Patent number: 6635091
    Abstract: Compositions for oxidation dyeing keratinous fibers, for example, human keratinous fibers such as hair, comprising at least one oxidation base and at least one coupler chosen from N-(2-hydroxybenzene)carbamate and N-(2-hydroxybenzene)urea compounds and their acid addition salts of formula (I) and processes comprising such compositions.
    Type: Grant
    Filed: February 23, 2001
    Date of Patent: October 21, 2003
    Assignee: L'Oreal S. A.
    Inventors: Jean-Baptiste Saunier, Laurent Vidal
  • Publication number: 20030192131
    Abstract: The invention relates to a composition for the oxidation dyeing of keratin fibers, and in particular human keratin fibers such as the hair, comprising, in a medium which is suitable for dyeing, at least one substituted para-aminophenol as oxidation base, and/or 1,3-bis(&bgr;-hydroxyethyl)amino-2-methylbenzene and/or at least one of the addition salts thereof with an acid, as coupler, as well as to the dyeing process using this composition.
    Type: Application
    Filed: November 19, 1999
    Publication date: October 16, 2003
    Inventor: MARIE-PASCALE AUDOUSSET
  • Patent number: 6630004
    Abstract: An oxidation dyeing composition for keratinous fibers, in particular hair, comprising, as oxidation base, at least one compound of the formula: where n=0-11, R represents H, amino, a saturated or unsaturated, linear or branched C1-C6 alkyl or is a radical chosen from radicals defined in the specification.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: October 7, 2003
    Assignee: L'Oreal S.A.
    Inventors: Michel Philippe, Thierry Bordier
  • Publication number: 20030172468
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.
    Type: Application
    Filed: March 13, 2002
    Publication date: September 18, 2003
    Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Jitendra Patel, Frank Jones
  • Patent number: 6616707
    Abstract: The invention concerns a process for the oxidative dyeing of human hair, whereby an aqueous composition having a pH-value between 7.0 and 12.0 is applied to the hair, wherein this Composition (AB) was obtained by admixture of an oxidation dyestuff precursor Composition (A), which comprises at least one developing and at least one coupling substance as well as at least one or more specific metal compounds, having an alkaline pH-value, with a hydrogen peroxide Composition (B), having a pH-value in the acidic range and comprising 0.05 & to 5.0% by weight, calculated to the total composition, of 1-hydroxyethane-1,1-diphosphonic acid and/or the alkali or ammonium salts thereof.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: September 9, 2003
    Assignee: Goldwell GmbH
    Inventor: Heribert Lorenz
  • Patent number: 6616709
    Abstract: Provided is a hair dye composition containing a direct dye (1). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye after storage. wherein, ring A may represents a benzene ring which may have a substituent or the like, B represents an aryl or heterocyclic group, D represents N or CR4 (wherein R4 represents H or alkyl), E represents NR5, CR6R7 or CR6═CR7 (wherein R5 represents alkyl or the like, and R6 and R7 each represents H or alkyl) or, O or S, R1 represents alkyl or the like, and n stands for 0 or 1, with the proviso that at n=0, R2 and R5 form, when taken together with N—C—C, a heterocycle, or R2 is bonded to B, thereby forming a heterocycle and at n=1, R2 and R3 form, when taken together with C═D—N, a heterocycle, and X− represents an anion.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 9, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6616708
    Abstract: Provided is a hair dye composition containing a direct dye (1), (2) or (3). This hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a small change in the color tone of the dye even after storage. wherein, R1 represents a (substituted) aryl group, R2, R4 to R6, R8 and R9 each represents H, a (substituted) C1-6 alkyl group or a (substituted) aryl group, R3 and R7 each represents a (substituted) aryl group, R10 to R12 each represents a (substituted) C1-6 alkyl or (substituted) aryl group, rings A to G each represents a benzene ring which may be substituted by a (substituted) amino group, (substituted) C1-6 alkyl group, C1-6 alkoxy group or halogen atom or may further be cyclocondensed with a benzene ring, and X− represents an anion.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 9, 2003
    Assignee: Kao Corporation
    Inventors: Yukihiro Ohashi, Hajime Miyabe, Kenichi Matsunaga
  • Patent number: 6613102
    Abstract: The invention relates to a composition for dyeing keratin fibers, in particular human keratin fibers such as the hair, comprising at least one cationic direct dye of given formula and at least one thickening polymer chosen from nonionic guar gums, biopolysaccharide gums of microbial origin, gums derived from plant exudates, pectins, alginates, starches, and carboxyalkylcelluloses. The invention also relates to the dyeing processes and dyeing devices using the composition.
    Type: Grant
    Filed: July 8, 1999
    Date of Patent: September 2, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6605125
    Abstract: Provided is a hair dye composition comprising as a direct dye a compound represented by the following formula (1), (2), (3) or (4): [wherein, R1 and R1′ each independently represents a (substituted) C1-6 alkyl or a (substituted) aryl group; W and W′ each independently represents a group —A—NR2R3 or a (substituted) heterocyclic aromatic group; A and A′ each independently represents a divalent (substituted) aryl group; R2, R2′ and R3 each independently represents H, a (substituted) alkyl or a (substituted) aryl group, or R2, R2′ or R3 may be bonded to A or A′, thereby forming a heterocycle, R2 and R3, or R2 and R2′ are coupled to form a heterocycle, together with the adjacent atom; R4 to R6 each independently represents H, (substituted) alkyl or (substituted) alkenyl group; Q represents a divalent organic group; X represents a modified carboxy group, an —SO2—T— group (in which, T represents an alkyl, alkenyl or aryl)
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: August 12, 2003
    Assignee: Kao Corporation
    Inventors: Hajime Miyabe, Kenichi Matsunaga, Yukihiro Ohashi, Shintaro Totoki, Yoshinori Saito
  • Patent number: 6605124
    Abstract: The subject of the invention is novel compounds derived from naphth-1-ol comprising at least one cationic group, their use as coupler for the oxidation dyeing of keratinous fibres, compositions for the oxidation dyeing of keratinous fibres, and in particular human keratinous fibres such as hair, containing them in combination with at least one oxidation base, as well as methods of oxidation dyeing using them.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: August 12, 2003
    Assignee: L'Oreal S.A.
    Inventors: Jean-Jacques Vandenbossche, Laurent Vidal, Jean-Baptiste Saunier, Alain LaGrange
  • Patent number: 6602303
    Abstract: Compositions for oxidation dyeing of keratinous fibers, for example, human keratinous fibers such as hair, further such as human hair, comprising, in a medium suitable for dyeing, at least one oxidation dye, at least one cationic amphiphilic polymer comprising at least one fatty chain, and a combination comprising: (I) at least one compound chosen from oxyalkylenated and glycerolated fatty alcohols and (II) at least one hydroxylated solvent, wherein the hydroxylated solvent may have a molecular weight of less than 250, and wherein the weight ratio of (I) to (II) is greater than 1:1 and dyeing processes and devices, such as kits, comprising such compositions.
    Type: Grant
    Filed: August 13, 2001
    Date of Patent: August 5, 2003
    Assignee: L'Oreal S.A.
    Inventors: Florence Laurent, Delphine Allard
  • Patent number: 6602302
    Abstract: New substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or physiologically compatible water-soluble salts thereof, are described as well as methods for preparing them. In addition, oxidation dye precursor compositions for dyeing keratin fibers, especially human hair, which each contain from 0.005 to 20 percent by weight of at least one of the new substituted 2,5-diamino-1-aminomethylbenzene compounds of formula (I), or their physiologically compatible water-soluble salts, are described. Methods for dyeing hair with ready-to-apply dye mixtures made by mixing these oxidation dye precursor compositions with an oxidizing agent, such as hydrogen peroxide solution, are also described.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: August 5, 2003
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6600050
    Abstract: Diaminopyrazole derivatives of the general Formula (I) or their physiological tolerated, water-soluble salts with inorganic or organic acids, and agents, containing these compounds, for the oxidative dyeing of fibers.
    Type: Grant
    Filed: September 9, 2002
    Date of Patent: July 29, 2003
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6599329
    Abstract: The invention concerns a ready-to-use composition for oxidation dyeing of keratinous fibers, and in particular human keratinous fibers such as hair comprising, in a suitable dyeing medium, at least an oxidation base, 2-amino 3 hydroxy pyridine as coupling agent, and at least an enzyme such as laccase, as well as the method using said composition.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: July 29, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6599328
    Abstract: A ready-to-use composition for the oxidation dyeing of keratin fibers, and, in particular, human keratin fibers, such as the hair, having at least one oxidation dye, at least one oxidoreductase enzyme, and at least one specific salified or chemically modified chitosan, as well as to the oxidation dyeing process using this composition.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: July 29, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gregory Plos, Alain Lagrange
  • Publication number: 20030135936
    Abstract: There are provided novel preparations for tinting or dyeing hair which contain vitamin B6 derivatives.
    Type: Application
    Filed: December 13, 2002
    Publication date: July 24, 2003
    Inventors: Astrid Kleen, Frank Naumann, Horst Hoeffkes
  • Publication number: 20030131423
    Abstract: The object of the invention is an agent for oxidatively dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formula (I), (II) or (III) or its salt with organic or inorganic acids, 1
    Type: Application
    Filed: October 8, 2002
    Publication date: July 17, 2003
    Inventors: Manuela Javet, Christel Dousse, Dominique Le Cruer
  • Patent number: 6592630
    Abstract: Provided is a hair dye composition containing a direct dye (1) or (2). The hair dye composition has markedly high hair dyeing power, has less color fade over time and undergoes a smaller change in the color tone of the dye after storage. [R1, R2 and R3 are the same or different and each independently represents a C1-3 alkyl group and benzene ring A or B may contain a nondissociative substituent].
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: July 15, 2003
    Assignee: Kao Corporation
    Inventors: Kenichi Matsunaga, Hajime Miyabe, Yukihiro Ohashi
  • Patent number: 6592633
    Abstract: The invention relates to a dye composition for keratin fibers, in particular for human keratin fibers such as the hair, having, in a medium suitable for dyeing, at least one cationic direct dye of given formula, and containing at least one specific cationic or amphoteric substantive polymer. The invention also relates to the dyeing processes and devices using the composition.
    Type: Grant
    Filed: May 25, 1999
    Date of Patent: July 15, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6592631
    Abstract: The p-aminophenol derivative compounds of formula (I), or their physiologically compatible water-soluble salts: are useful as developer compounds in oxidation dye compositions for keratin fibers. Oxidation dye compositions for keratin fibers, including hair, and methods of dyeing hair using the p-aminophenol derivative compounds are also described.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: July 15, 2003
    Assignee: Wella AG
    Inventors: Laurent Chassot, Hans-Juergen Braun
  • Patent number: 6579326
    Abstract: Compositions for the oxidation dyeing of keratin fibers, containing at least one oxidation base and at least one coupler chosen from indolizine derivative comprising at least one cationic group Z, Z being chosen from quaternized aliphatic chains, aliphatic chains comprising at least one quaternized saturated ring, and aliphatic chains comprising at least one quaternized unsaturated ring. Methods of using these cationic indolizine derivatives as couplers for the oxidation dyeing of keratin fibers, in combination with at least one oxidation base, and to dyeing processes using them. Some of these cationic indolizine derivatives are novel.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: June 17, 2003
    Assignee: L'Oreal S.A.
    Inventors: Philippe Breton, Fabienne Segala, Alain Lagrange
  • Patent number: 6576024
    Abstract: The invention relates to a cosmetic mixture for the oxidation tinting of keratin fibres, containing in a support material suitable for tinting keratin fibres (a) at least one laccase-type enzyme; (b) at least one polymer thickener selected from the group constituted by: (i) amphiphilic non-ionic polymers comprising at least one fatty chain and at least one hydrophilic unit; (ii) anionic amphiphilic polymers comprising at least one hydrophilic unit and at least one fatty chain unit; (iii) cross-linked acrylic acid homopolymers; (iv) cross-linked 2-acrylamide-2-methyl-propane sulfonic acid homopolymers and their cross-linked acrylamide copolymers, which are partially or fully neutralized; (v) ammonium acrylate homopolymers or ammonium acrylate and acrylamide copolymers; (vi) dimethylaminoethyl-methacrylate homopolymers quatemized by methyl chloride or dimethylaminoethyl-methacrylate copolymers quaternized by methyl chloride and acrylamide copolymers; (vii) non-ionic guar gums; (viii) scleroglucan gum (a biopoly
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: June 10, 2003
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 6572664
    Abstract: Compositions for oxidation dyeing of keratin fibers comprising at least one oxidation base and at least one coupler chosen from indolizine derivatives, methods for using the same for oxidation dyeing of keratin fibers, and compounds chosen from indolizine derivatives.
    Type: Grant
    Filed: February 26, 2001
    Date of Patent: June 3, 2003
    Assignee: L'Oreal S.A.
    Inventors: Philippe Breton, Alain Lagrange
  • Patent number: 6569211
    Abstract: The invention concerns the use of indoline derivatives of formula (I): in which R1, R2, R3, R4 and R5 independently of one another represent hydrogen or C1-4 alkyl groups, or R4 and R5 together with the oxygen atoms to which they are attached represent a C1-4 alkylenedioxy group, or of salts of such indoline derivatives, as additives to hair dyeing agents of the direct dyeing or primary intermediate/secondary intermediate type, thus producing hair dyeing with excellent color fastness characteristics.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: May 27, 2003
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Iduna Matzik, Detlef Hollenberg, Mechthild Borgerding
  • Patent number: 6562080
    Abstract: Primary intermediates useful hair coloring systems comprise 2-arylaminomethyl-4-aminophenols. The invention provides new 2-arylaminomethyl-4-aminophenol compounds of Formula (1): wherein R is a moiety selected from formulae (2), (3) or (4) wherein R1, R2, R3, R4 and R5 are each independently selected from a hydrogen atom, a halogen atom, a hydroxy group, an amino group, a C1-C6 alkyl or haloalkyl group, a C1-C6 alkoxy or haloalkoxy group, and a nitrile group, and R6 is a hydrogen atom, a halogen atom, a C1-C4 alkyl or a C1-C4 alkoxy group.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: May 13, 2003
    Assignee: Clairol Incorporated
    Inventors: Mu-III Lim, Yuh-Guo Pan
  • Publication number: 20030084519
    Abstract: Disclosed are hair care compositions including a polyalkyleneglycol(n)alkylamine of formula (I), (II), or mixtures thereof, wherein each R is independently a saturated, unsaturated, straight or branched alkyl group having from 1 to about 30 carbon atoms, R′ is a saturated, unsaturated, straight or branched alkyl group having from 1 to about 4 carbon atoms, each m is 2 or 3, each n is 2 or 3, each x and each y are independently a number of 1 or more wherein the sum of each x and each y is from about 3 to about 9; and wherein X- is any safe and suitable salt forming anion selected from the group consisting of chloride, bromide, iodide, acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfonate, sulfate, alkylsulfate, alkyl sulfonate, glutamate aspartate, and mixtures thereof; and wherein the melting point of the polyalkyleneglycol(n)alkylamine is less than about 45° C.; and a gel matrix comprising a cationic surfactant, a solid fatty compound, and water.
    Type: Application
    Filed: August 23, 2002
    Publication date: May 8, 2003
    Inventor: Jian-Zhong Yang
  • Patent number: 6554871
    Abstract: The oxidation dye precursor-containing composition for oxidative dyeing of hair, includes from 0.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: April 29, 2003
    Assignee: Wella AG
    Inventor: Hans-Juergen Braun
  • Publication number: 20030074748
    Abstract: A method for permanently dyeing hair which comprises subjecting said hair to a number of treatments, having a set time interval between each two consecutive such treatments, wherein each treatment comprises steps a.) and b.
    Type: Application
    Filed: July 17, 2002
    Publication date: April 24, 2003
    Applicant: Unilever Home & Personal Care USA, Division of Conopco, Inc.
    Inventors: Jitendra Patel, Gerald Patrick Newell
  • Patent number: 6551360
    Abstract: The present invention relates to a composition for dyeing keratin fibres, in particular human hair, containing, in a medium which is suitable for dyeing: as coupler, at least one compound of formula: or one of the addition salts thereof with an acid, in which: R2 denotes, in particular, hydrogen, halogen, alkoxy, aryloxy, acetylamido, etc. R1 and R3, which are independent, denote, in, particular: hydrogen, alkyl, aryl, a heterocycle, etc. it being understood that when R2 and R1 simultaneously represent a hydrogen atom, then R1 is other than a hydrogen atom, a C1-C5 alkyl radical or a phenyl radical; and at least one oxidation base.
    Type: Grant
    Filed: December 29, 2000
    Date of Patent: April 22, 2003
    Inventors: Laurent Vidal, Gérard Malle