Sulfur-containing Patents (Class 8/587)
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Patent number: 8974548Abstract: A hair coloring composition comprising: a) dihydroxyacetone or a derivative thereof; b) from 0.2 to 10 wt % of the total composition of a cationic conditioning compound c) a sulphonic compound of formula: H2N—(CHR1}pS(—X)q—Y in which where p is an integer from 1 to 5, R1 is H or an alkyl group, X is O or S q is an integer from 0 or 1. Y is an alkyl group or hydroxyl group.Type: GrantFiled: September 24, 2012Date of Patent: March 10, 2015Assignee: Conopco, Inc.Inventors: Jinfang Wang, Xiaoxia Yang
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Patent number: 8852293Abstract: There is provided a compound represented by Formula (1), and a coloring composition including the compound: wherein, in Formula (1), R0 to R3 each independently represent a hydrogen atom or a substituent, and R0 and R1, R0 and L, or R1 and L may be combined with each other to form a ring, L represents a single bond or a divalent linking group, D represents a residue in which n hydrogen atoms are removed from a compound represented by Formula (2), n represents an integer of 1 or more, provided that when n represents an integer of 2 or more, a plurality of R0's to R3's and L's may be the same or different, the compound represented by Formula (1) has at least one ionic hydrophilic group, and in Formula (2), R4 to R24 each independently represent a hydrogen atom or a substituent.Type: GrantFiled: February 25, 2014Date of Patent: October 7, 2014Assignee: FUJIFILM CorporationInventor: Yoshihiko Fujie
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Patent number: 8840684Abstract: The invention relates to a process for dyeing and/or lightening keratin fibers such as the hair, using i) at least one cationic direct dye bearing a disulfide, thiol or protected thiol function especially of formula (I) as defined in the description and ii) water vapor. The invention also relates to the use i) of at least one cationic direct dye bearing a disulfide, thiol or protected thiol function combined with ii) water vapor, for dyeing and lightening keratin fibers, and to the use of water vapor for grafting onto keratin fibers dyes bearing a disulfide, thiol or protected thiol function. The process used and the use of thiol, protected thiol or disulfide dyes combined with water vapor makes it possible especially to obtain a long-lasting coloration on keratin fibers without the use of a reducing agent and without odor.Type: GrantFiled: December 5, 2011Date of Patent: September 23, 2014Assignee: l'orealInventor: Andrew Greaves
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Patent number: 8608809Abstract: An oxidative dyeing composition comprises at least one oxidative dye precursor comprising further at least two structurally different reducing agents wherein the first is selected from inorganic reducing agents and present at a concentration of at least 0.1% by weight calculated to the total composition, and the second is an organic reducing agent and/or its salts selected from thioglycolic acid, acetylcysteine and cysteine, and their salts, wherein the composition is substantially free of ascorbic acid and/or its salts.Type: GrantFiled: August 16, 2011Date of Patent: December 17, 2013Assignee: Kao Germany GmbHInventors: Sandra Schmelz, Jürgen Ehmig
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Patent number: 8597374Abstract: Compositions are provided for spray dyeing of a cellulosic, such as cotton, fabric or garment. The compositions include a reactive dye, a wetter, an alkali, and water. The present compositions are made by first mixing the reactive dye, the wetter, and the water to form a solution, and thereafter adding the alkali to the solution.Type: GrantFiled: April 4, 2011Date of Patent: December 3, 2013Assignee: HBI Branded Apparel Enterprises, LLCInventor: Ruth E. May
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Patent number: 8585780Abstract: The present invention relates to a laundry shading process with specific blue or violet bisazo-dyes alone or in combination with a photocatalyst. Further aspects of the invention are a composition comprising at least one photocatalyst and at least one of the specific bisazo-dyes. The composition is particularly useful for shading textiles during laundry. Further aspects of the invention are a detergent composition, a fabric softener composition containing these dyes or mixtures of these dyes and photocatalysts and novel blue or violet bisazo-dyes.Type: GrantFiled: May 13, 2013Date of Patent: November 19, 2013Assignee: BASF SEInventors: Carmen Araya Hernandez, Frank Bachmann, Hans Kramer, Wolfgang Schlenker, Deepak M. Rane
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Patent number: 8568492Abstract: A method of making a composition for spray application onto surfaces of a cotton fabric includes mixing together a wetter, a reactive dye and water to form a first solution, adding a thickener into the first solution for between about five minutes and sixty minutes to form a partial composition, and adding an alkali with the partial composition to complete the composition.Type: GrantFiled: April 5, 2011Date of Patent: October 29, 2013Assignee: HBI Branded Apparel Enterprises, LLCInventors: Ruth E May, Martin Bentham
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Patent number: 8562693Abstract: The invention relates to a dyeing composition comprising a fluorescent disulphide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulphide dyes and to their uses in the lightening of keratin materials. This composition allows a particularly persistent lightening effect to be obtained.Type: GrantFiled: November 19, 2012Date of Patent: October 22, 2013Assignee: L'OrealInventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
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Publication number: 20130139328Abstract: The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.Type: ApplicationFiled: August 15, 2011Publication date: June 6, 2013Applicant: BASF SEInventors: Sophie Marquais-Bienewald, Christian Cremer, Beate Frohling
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Patent number: 8398722Abstract: The invention relates to the dyeing of keratin materials using phenylpyrido[1,2-a]indolinium-derived thiol and disulfide fluorescent dyes. The invention relates to a dye composition comprising a phenylpyrido[1,2-a]indolinium-derived-chromophore thiol or disulfide dye and to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers, such as the hair, using said composition. It similarly relates to novel phenylpyrido[1,2-a]indolinium-derived-chromophore thiol dyes and to the uses thereof in lightening keratin materials. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.Type: GrantFiled: September 18, 2008Date of Patent: March 19, 2013Assignee: L'OrealInventors: Andrew Greaves, Nicolas Daubresse
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Patent number: 8328880Abstract: The invention relates to a dyeing composition comprising a fluorescent disulfide dye and to a method of dyeing keratin materials, with a lightening effect, that employs said composition. It likewise relates to new fluorescent disulfide dyes and to their uses in the lightening of keratin materials. The composition allows a particularly persistent lightening effect to be obtained.Type: GrantFiled: September 14, 2011Date of Patent: December 11, 2012Assignee: L'OrealInventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
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Patent number: 8324338Abstract: An oligomer removing agent for polyester-based fiber materials comprises a polyester copolymer which is obtained by polycondensation of a dibasic acid component containing 15-65 mol % of a sulfonate group-containing dibasic acid and a dihydric alcohol component containing polyethylene glycol with a molecular weight of 900-3500, and which has a 200° C. melt viscosity of 5000-23,000 mPa·s and has 10-40 mass % polyoxyethylene chains in the molecule. The oligomer removing agent is able to overcome the problems caused by deposition of polyester oligomers, when added to the dyeing bath in a dyeing step for polyester fiber materials or for fiber materials that are composites thereof with other fiber materials.Type: GrantFiled: January 21, 2011Date of Patent: December 4, 2012Assignee: Nicca Chemical Co., Ltd.Inventors: Masaaki Hosoda, Masatoshi Hayashi
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Patent number: 8298298Abstract: Solubility changeable dye compositions include a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic. A method of dying a substrate with such dye compositions includes contacting the dye with the substrate.Type: GrantFiled: July 11, 2012Date of Patent: October 30, 2012Assignee: Empire Development Technology LLCInventor: Seth Adrian Miller
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Patent number: 8293695Abstract: The present invention relates to a composition comprising at one photocatalyst and at least one azo dyestuff and/or at least one triphenylmethane dyestuff, which produces in the CIElab color coordinate system a relative hue angle of 220-320°, to a detergent composition, a fabric softener composition as well as to a shading.Type: GrantFiled: July 28, 2004Date of Patent: October 23, 2012Assignee: BASF SEInventor: Alfred Höhener
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Patent number: 8277519Abstract: A method of colouring a material, the method comprising the steps of: a)applying to the material a composition comprising a sulphur-containing nucleophile; and b)applying to the material a composition comprising a dye compound selected from a dye class other than the class of reactive dyes.Type: GrantFiled: September 10, 2009Date of Patent: October 2, 2012Assignee: Perachem LimitedInventors: Céline Gauché, Jamie Anthony Hawkes, David Malcolm Lewis
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Patent number: 8246698Abstract: Disclosed herein are solubility changeable dye compositions, methods of preparing such compositions and methods of using them. The composition includes a dye component linked via a linker moiety to a stimulus responsive hydrophobic moiety which modulates the solubility of the dye, wherein the hydrophobic moiety is configured to be de-linked from the dye component on exposure to a stimulus and render the dye component more hydrophilic.Type: GrantFiled: December 22, 2010Date of Patent: August 21, 2012Assignee: Empire Technology Development LLCInventor: Seth Adrian Miller
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Patent number: 8203068Abstract: The present invention relates to a dye compound represented by the following formula (I), or a salt thereof: wherein R1, R2, R3, R4, D1, D2, B, and n are defined the same as the specification, and also relates to a photoelectric component using the same. The dye compound of the present invention is suitable for Dye-Sensitized Solar Cell (DSSC). Hence, the photoelectric characteristics of the DSSC can be improved by using the dye compound of the present invention.Type: GrantFiled: January 22, 2009Date of Patent: June 19, 2012Assignee: Everlight USA, Inc.Inventors: Ming-Si Wu, Wei-Cheng Tang
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Patent number: 8202326Abstract: A hair dye composition containing an organic compound having not more than 4 carbon atoms, which has both of a —SH group and a —NH2 group and does not have a —COOH group, and also containing at least one member selected from aromatic compounds in which given substituents are each attached to meta positions of a mononuclear benzene ring structure and ?-naphthol as a coupler of an oxidation dye intermediate, in which the blending amount of each member as the coupler is in a range from 0.01 to 0.5% by mass. An oxidation hair dye composition containing the hair dye composition. Wherein the hair dye composition and the oxidation hair dye composition are capable of preventing a change in the color tone of the hair dyeing even during long-term storage are provided.Type: GrantFiled: January 26, 2009Date of Patent: June 19, 2012Assignee: Hoyu Co., Ltd.Inventors: Masao Ito, Hisohisa Murakoshi, Junji Yamagata
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Patent number: 8070830Abstract: The invention relates to a dye composition comprising a thiol/disulfide fluorescent dye comprising a heterocycle, and to a dyeing process which has a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers such as the hair, using said composition. It similarly relates to novel thiol/disulfide fluorescent dyes and to uses thereof in lightening keratin materials. This composition makes it possible to obtain a particularly resistant and visible lightening effect on dark keratin fibers.Type: GrantFiled: March 23, 2007Date of Patent: December 6, 2011Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Nicolas Daubresse
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Publication number: 20110277249Abstract: Colored high-strength fibers of ultra-high-molecular-weight polyolefins and methods of dyeing the high-strength fibers are disclosed herein.Type: ApplicationFiled: May 14, 2010Publication date: November 17, 2011Inventors: Ferass Abuzaina, Ali Irfan
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Patent number: 8038732Abstract: The invention relates to a dye composition comprising a thiol/disulfide fluorescent dye comprising amino groups, and to a dyeing process which has a lightening effect on keratin materials, in particular keratin fibers, especially human keratin fibers such as the hair, using said composition. It similarly relates to novel thiol/disulfide fluorescent dyes and to uses thereof in lightening keratin materials. This composition makes it possible to obtain a particularly resistant and visible lightening effect on dark keratin fibers.Type: GrantFiled: March 23, 2007Date of Patent: October 18, 2011Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Nicolas Daubresse
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Patent number: 8038731Abstract: The invention relates to a method of dyeing and lightening keratin materials in the presence of a reducing agent, comprising applying to keratin materials, a dyeing composition comprising a fluorescent disulfide dye and simultaneously applying to the keratin materials at least one reducing agent.Type: GrantFiled: March 23, 2007Date of Patent: October 18, 2011Assignee: L'Oreal S.A.Inventors: Nicolas Daubresse, Andrew Greaves, Henri Samain
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Patent number: 8016895Abstract: wherein D is a chromophore; L is a linking group selected from SO2, NHCO, and NHSO2; Q is a hydrogen or halogen atom; and R is selected from C1-C4 alkyl, (CH2)nCOOH, (CH2)nCONH2, (CH2)nSO3H, (CH2)nCOOM, (CH2)nPO3H, (CH2)nOH, (CH2)nSSO3?, (CH2)nNR12, (CH2)nN+R1H2, (CH2)nNHCOR1, PhSSO3?, PhSO3H, PhPO3H, PhNR12, PhN+R13, (CH2)2CH(SH)R1(CH2)3COOH, and n is an integer in the range of 1 to 4 wherein within the same molecule each n is not necessarily the same integer; M is a cation of an alkaline earth metal, alkali metal, NH4+ or NR13+; and R1 is C1-C4 alkyl.Type: GrantFiled: March 10, 2009Date of Patent: September 13, 2011Assignee: Perachem LimitedInventors: Jamie Anthony Hawkes, David Malcolm Lewis, Celine Gauche
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Patent number: 7988739Abstract: A multi-component hair dye composition excellent in bleaching property and dyeing property including components (a), (b) and (c) which are mixed upon use:(a) one or more kinds of glycylglycine derivative represented by general formula (1) and having two or three amino acid residues, or salts thereof; [wherein X represents a bivalent hydrocarbon group having 1 to 4 carbon atoms which may be substituted with a hydroxyl group, or an amino acid residue; Y represents an amino acid residue, or a bivalent group represented by general formula (2): (wherein symbol -* represents a bond that binds to an adjacent carbonyl group or oxygen atom); R represents a hydrogen atom, or a monovalent hydrocarbon group having 1 to 4 carbon atoms in which the hydroxy group may be substituted; and m and n each represent 0 or 1, provided that when both m and n represent 1, X is not an amino acid residue]; (b) an alkali agent; and c) an oxidizing agent; wherein formula (I) is:Type: GrantFiled: October 10, 2008Date of Patent: August 2, 2011Assignee: Kao CorporationInventors: Masaki Fukuhara, Masayoshi Nojiri
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Patent number: 7967872Abstract: The present invention relates to thiol/disulphide azo quinolinium compounds for dyeing keratin fibres. The invention relates to a dye composition comprising a particular thiol/disulphide azo quinolinium chromophore-containing thiol or disulphide dye, and to a process for dyeing keratin fibres such as the hair, using said composition. It similarly relates to novel particular thiol/disulphide azo quinolinium chromophore-containing dyes and to the uses thereof in dyeing keratin fibres. The dyeing process according to the invention makes it possible to dye keratin fibres without damaging them, in a manner which is particularly persistent with respect to shampooing operations and common attacks. Moreover, the novel dyes according to the invention extend the colour range to violets and blues. This process also makes it possible to dye bleached keratin fibres in a strong and chromatic manner.Type: GrantFiled: September 8, 2008Date of Patent: June 28, 2011Assignee: L'Oreal S.A.Inventors: Nicolas Daubresse, Andrew Greaves
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Patent number: 7883550Abstract: A new and improved hair dye formula which is completely oleic acid free and has a high percentage water base including sodium lauryl sulfate, sodium lauryl sulfoacetate and disodium laureth sulfosuccinate along with a low percentage peroxide content for protecting consumers during the hair dye process.Type: GrantFiled: January 12, 2009Date of Patent: February 8, 2011Inventor: Jack Siracusa
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Patent number: 7811335Abstract: Disclosed are composition and method for dyeing keratin-containing fibers comprising or utilizing styryl sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R?1, R2, R?2, R3, R?3, W1, W?1, W2, W?2, W3, W?3, W4, W?4, Q, Q?, Y1 and Y2 are defined in claims and disclosure.Type: GrantFiled: June 7, 2006Date of Patent: October 12, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7803197Abstract: Disclosed are thiol dyes of formula (1) wherein L1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene, C2-C12alkenylene, C5-C10cycloalkylene, C5-C10arylene, or C5-C10arylene-C1-C10alkylene, which may by interrupted by —O—, —NH—, —S—, —CO—, o-SO2—; Y is the residue of an organic dye Z is a group of formula (1b) or —C?N; wherein A is O; S; or N-L2; B is L3; —OL3; —NL3L4; or —SL3; and L2, L3 and L4, independently from other are hydrogen; C1-C12alkyl; C5-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.Type: GrantFiled: August 8, 2007Date of Patent: September 28, 2010Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7789916Abstract: Disclosed are triarylmethane dye compounds of formula (2) wherein R8 is C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or the radical —NR6R7 or —OR8; B1 and B2, independently from each other are C6-C10aryl; or a 5-7-membered heterocyclic compound, which may be substituted by C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or by the radical —NR6R7 or —OR6; and R6 and R7 independently from each other are hydrogen; or C1-C12alkyl, which may be substituted by hydroxy or C6-C10aryl.Type: GrantFiled: September 27, 2006Date of Patent: September 7, 2010Assignee: Ciba CorporationInventors: Christian Cremer, Olof Wallquist
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Patent number: 7785376Abstract: A method to bind compounds (e.g., antibiotics) to natural or synthetic yarn or fabric, involving reacting the compounds with cyanuric chloride, a hydroxide base (e.g., NaOH), and deionized water to form reactive compounds; forming a dyebath composed of the reactive compounds, at least one nonioinic, cationic or anionic surfactant, salt (e.g., sodium sulfate), deionized water, and natural or synthetic yarn or fabric; heating the dyebath (generally for about 1 to about 100 minutes at a temperature of about 25° to about 100° C.); adding a hydroxide base (e.g., NaOH) to the dyebath and heating (generally for about 1 to about 100 at a temperature of about 80° to about 100° C.); rinsing the natural or synthetic yarn or fabric; placing the natural or synthetic yarn or fabric in deionized water and heating (generally for about 1 to about 100 minutes at a temperature of about 25° to about 100° C.); rinsing the natural or synthetic yarn or fabric; and drying the natural or synthetic yarn or fabric.Type: GrantFiled: November 19, 2008Date of Patent: August 31, 2010Assignee: The United States of America as represented by the Secretary of AgricultureInventors: David T. Chun, Gary R. Gamble
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Patent number: 7785375Abstract: Disclosed is a method of dyeing keratin-containing fibers comprising treating the fiber with at least one compound of formula (1), wherein R1, R2, R3, R4 independently from each other are hydrogen; hydroxy; —S—H; —S—C1-C12alkyl; halogen; C1-C12alkyl or C1-C12alkoxy, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy, —(CO)—H or —(CO)—C1-C5alkyl; —NR5R6; —NO2; —(CO)H or (CO)—C1-C5alkyl; C6-C12aryl, C6-C12aryl-C1-C4alkyl or C6-C12aryl-C1-C4alkoxy, wherein the aryl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, —(CO)—H or —(CO)—C1-C5alkyl; R5 and R6 independently from each other are hydrogen; hydroxy; C1-C12alkyl; hydroxy-C1-C12alkyl; —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C5alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; and An is an anion.Type: GrantFiled: June 21, 2006Date of Patent: August 31, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7780743Abstract: The invention relates to the dyeing of keratin materials using naphthylimide thiol/disulphide thiol fluorescent dyes, and to a dyeing process which has a lightening effect on keratin materials, in particular keratin fibres, especially human keratin fibres such as the hair, using said composition. It similarly relates to novel thiol/disulphide fluorescent dyes and to uses thereof in lightening keratin materials. This composition makes it possible to obtain a particularly resistant and visible lightening effect on dark keratin fibres.Type: GrantFiled: March 23, 2007Date of Patent: August 24, 2010Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Nicolas Daubresse
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Patent number: 7771490Abstract: Disclosed are thiol dyes of formula (I), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds.Type: GrantFiled: August 21, 2006Date of Patent: August 10, 2010Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
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Patent number: 7753966Abstract: It is to provide a hair dye stabilizer capable of stably storing a readily oxidizable compound in a hair dye, especially an oxidizing dye intermediate or a coupler and effective for remarkably improving the offensive odor problem. Furthermore, it is to provide a hair dye stabilizer giving improvement in damage on the hair, hardly irritating the skin, and free from adverse effects on the dyeing ability of the hair dye. As the active component constituting the hair dye stabilizer, a compound which is a mercapto-hydrocarbon compound and/or a thiol alcohol compound and does not contain a functional group reactive with a dye intermediate or a coupler is used. A readily oxidizable compound and the like in a hair dye can be stably stored by the use of an extremely small amount of the stabilizer.Type: GrantFiled: July 10, 2007Date of Patent: July 13, 2010Assignee: Takasago International CorporationInventors: Junko Nagano, Kazuki Sugiyama, Kyoko Hirano, Kunihide Hoshino, Takashi Aida
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Patent number: 7744657Abstract: The present disclosure relates to the dyeing of keratin materials using thiol/disulfide styryl tetrahydroquinolinium fluorescent dyes. Disclosed herein is a dye composition comprising a thiol/disulfide styryl tetrahydroquinolinium fluorescent dye and a dyeing process with, for instance, a lightening effect on keratin materials such as hair, using said composition. Disclosed herein are thiol fluorescent dyes and the uses thereof in lightening keratin materials. This composition can be used to obtain a lightening effect which can be resistant and visible on dark keratin fibers.Type: GrantFiled: September 19, 2008Date of Patent: June 29, 2010Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Nicolas Daubresse, Franco Manfre
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Patent number: 7731760Abstract: Disclosed are certain oxazine disulfide dyes useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.Type: GrantFiled: September 27, 2006Date of Patent: June 8, 2010Assignee: Ciba CorporationInventors: Christian Cremer, Olof Wallquist
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Patent number: 7727287Abstract: The present disclosure relates to a novel dye composition for the dyeing and/or lightening of keratin materials, such dye comprising a hemicyanin styryl chromophore thiol or disulfide dye of formula (I) or (II): the organic or mineral acid salts thereof, optical isomers and geometric isomers thereof, and the solvates thereof such as hydrates. The present disclosure further relates to a dyeing process with a lightening effect on keratin materials, in particular keratin fibers, including human keratin fibers such as the hair, using said composition. This composition makes it possible to obtain a coloring with a lightening effect which is particularly resistant and visible on dark keratin fibers.Type: GrantFiled: September 19, 2008Date of Patent: June 1, 2010Assignee: L'Oreal S.A.Inventors: Andrew Greaves, Nicolas Daubresse
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Patent number: 7717964Abstract: The disclosure relates to the dyeing of keratin materials using styryl hydroxy(cyclo)alkylamino thiol/disulfide fluorescent dyes. Disclosed herein is a dye composition comprising a styryl hydroxy(cyclo)alkylamino thiol/disulfide fluorescent dye and a dyeing process with, for example, a lightening effect on keratin materials such as hair, using said composition. Disclosed herein are novel thiol/disulfide fluorescent dyes and the uses thereof in lightening keratin materials. This composition makes it possible to obtain a lightening effect which can be resistant and visible on dark keratin fibers.Type: GrantFiled: September 19, 2008Date of Patent: May 18, 2010Assignee: L'Oreal S.A.Inventors: Nicolas Daubresse, Andrew Greaves, Franco Manfre
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Patent number: 7686850Abstract: Disclosed are nitro-sulfide dyes of formula (1), their salts, isomers, hydrates and other solvates, wherein R1, R2, R3, independently from each other are hydrogen; C1-C20alkyl or C1-C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; C3-C6cycloalkyl; —C(O)H; —C(O)—C1-C5alkyl; —C(O)OH; —C(O)O—C1-C5alkyl; halogen; NO2; OH; SH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2 or hydroxy; or a radical of formula (1a) —NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or —(CO)—H; —(CO)—C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, —NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, —NO2, carboxy or hydroxy; or a radical of formula (2); wherein at least one oType: GrantFiled: June 14, 2006Date of Patent: March 30, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Christian Cremer, Olof Wallquist
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Patent number: 7658769Abstract: An oxidation hair dye composition that provides an improved dyeing property. The oxidation hair dye composition comprises an oxidation dye, an alkaline chemical, and an oxidizing agent. The oxidation hair dye composition further comprises at least one selected from the group consisting of microbial hyaluronic acids and salts thereof.Type: GrantFiled: November 6, 2006Date of Patent: February 9, 2010Assignee: Hoyu Co., Ltd.Inventor: Tsuyoshi Nonogaki
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Patent number: 7658771Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).Type: GrantFiled: February 26, 2009Date of Patent: February 9, 2010Assignee: The Procter & Gable CompanyInventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
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Patent number: 7651538Abstract: A hair dye composition containing an azo dye (1) or a salt thereof, (wherein R1 to R4 represents H, aliphatic hydrocarbon group, aryl group, halogen atom, acyl group, cyano group, acylamino group, or the like, wherein R1 and R2, and/or R3 and R4 may be coupled to form a 5- or 6-membered ring; X represents C or N, with the proviso that when X represents C, n stands for 1, and when X represents N, n stands for 0; A1, A2, A3 and A4 each represents N or represents C substituted by Y or having H, with the proviso that at least one of A1, A2, A3 and A4 is a nitrogen atom; and Y represents a substituent with the proviso that m stands for an integer from 0 to 3).Type: GrantFiled: February 10, 2006Date of Patent: January 26, 2010Assignees: Kao Corporation, Fujifilm CorporationInventors: Masakazu Yamaguchi, Dominic Pratt, Yasuhiro Ishiwata
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Patent number: 7632316Abstract: The present invention relates to dyes of the general formula (1) where M and X are each as defined in claim 1, dye mixtures comprising one or more of the dyes of the general formula (1) and also one or more further fiber-reactive dyes, processes for their preparation, their use and printing inks comprising same.Type: GrantFiled: May 24, 2006Date of Patent: December 15, 2009Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Meier, Uwe Reiher, Werner Hubert Russ, Günther Schwaiger
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Patent number: 7585332Abstract: The present invention relates to compositions for dyeing keratin fibers, and in particular human keratin fibers such as the hair, comprising at least one compound of styryl or imine type containing a heterocycle and at least one thiol compound. The present invention makes it possible in particular to obtain a chromatic and fast coloration of keratin fibers, especially with respect to shampooing. Moreover, the color obtained is visible even on dark hair without necessarily using an oxidizing composition. The invention also makes it possible to obtain a coloration which, under certain conditions, does not stain.Type: GrantFiled: October 15, 2007Date of Patent: September 8, 2009Assignee: L'Oreal S.A.Inventor: Grégory Plos
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Patent number: 7563289Abstract: Disclosed are thiol dyes of formula (1), wherein R1 is hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; X is C1-C12alkylene; C2-C12alkenylene; C5-C10cycloalkylene; C5-C10arylene; or C5-C10arylene-C1-C10alkylene; Y is the residue of an organic dye which corresponds to the formula (1a), wherein R2 is hydrogen; or C1-C5alkyl; R3 is a radical of formula (1a1): (1a2); or (1a3); or R2 and R3 together with the linking carbon atom C form a 6 to 10 membered carbocyclic ring which may optionally be a condensated aromatic system and may contain one or more than one hetero atom; and R4, R5 and R6 independently form each other are hydrogen, or C1-C5alkyl; Z is H; or a thio ester group of formula (1b), wherein A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and A is O; S; or N—R9; B is —OR7; —NR7R8, or —SR7; and R7, R8 and R9, independently from each other are hydrogen; C1-C12alkyl C6-C12aryl; or C6-C12aryl-C1-C12alkyl. The compounds are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.Type: GrantFiled: September 27, 2006Date of Patent: July 21, 2009Assignee: Ciba CorporationInventors: Victor Paul Eliu, Beate Fröhling, Achim Bührer
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Patent number: 7550016Abstract: Disclosed are compounds of formula.Type: GrantFiled: June 14, 2006Date of Patent: June 23, 2009Assignee: Ciba Specialty Chemicals Corp.Inventors: Christian Cremer, Olof Wallquist
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Patent number: 7517369Abstract: The present invention relates to dyes of formula (1) that are soluble in organic solvents, wherein Cat+ is an organic cation, to a process for their preparation and to their use in the production of colored plastics or polymeric color particles, printing colorants, printing pastes and printing inks.Type: GrantFiled: December 19, 2005Date of Patent: April 14, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Ruch, Ursula Luterbacher
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Patent number: 7513917Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).Type: GrantFiled: February 16, 2007Date of Patent: April 7, 2009Assignee: The Procter & Gamble CompanyInventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
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Patent number: 7513916Abstract: The present invention relates to agents for coloring keratin fibers which comprise at least one cationic azodye of the general formula (I).Type: GrantFiled: February 16, 2007Date of Patent: April 7, 2009Assignee: The Procter & Gamble CompanyInventors: Cécile Pasquier, Eric Tinguely, Markus Speckbacher, Annik Marguet, Hans-Jürgen Braun
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Patent number: 7507261Abstract: A hair dye composition which is provided by mixing a first-part agent containing an alkaline agent and a second-part agent containing an oxidizing agent upon application, comprising, after mixing, components (a) to (c) and an oxidative dye (d) as needed, wherein the pH after mixing is 8 to 12 and the content of component (a) is 0.1 to 20 wt. %: (a) a betaine compound represented by formula (1) and an acid-addition salt thereof: wherein R1, R2, R3, X, and Y are as defined; (b) an oxidizing agent; and (c) an ammonia or a salt thereof, which hair dye composition: suppresses the stripping of ammonia at the time of mixing a first-part agent and a second-part agent, thereby reducing the unpleasant odor of ammonia upon application; suppresses hair damage and deterioration of feeling without a pre-treatment; has excellent dying and bleaching effects; and uniformly dyes (bleaches) the hair from the root to the tip of the hair regardless of the degree of hair damage.Type: GrantFiled: December 27, 2006Date of Patent: March 24, 2009Assignee: Kao CorporationInventors: Yuko Nobuto, Masayoshi Nojiri