Carboxylic Acid Or Salt Thereof Patents (Class 8/594)
  • Patent number: 4647285
    Abstract: The invention relates to a process for printing cellulosic fibres or cellulose-containing blend fibres with reactive dyes or dye mixtures which contain a reactive dye and subsequent fixation, which comprises printing these materials with a print paste containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member and m is 1, 2, 3, 4, 5 or 6, and salts of aliphatic carboxylic acids having 3 to 18 carbon atoms, and subsequently fixing the print; and to the print pastes used and to their use for printing textile materials.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: March 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Scheibli, Alex Kanzig, Andres Schaub
  • Patent number: 4588411
    Abstract: The invention relates to long-shelflife print pastes containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member, and m is 1, 2, 3, 4, 5 or 6, and, per fibre-reactive radical X, at least twice the stoichiometric amount of an alkali metal acetate, and to their use for printing cellulosic fibres.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: May 13, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Scheibli, Alex Kanzig, Andres Schaub
  • Patent number: 4519803
    Abstract: In the printing of dyes onto substrates, the pretreatment of the substrates with low levels of calcium or sodium salts or other gelling/insolubilizing agents effectively reduces dye usage.
    Type: Grant
    Filed: June 1, 1983
    Date of Patent: May 28, 1985
    Assignee: KELCO/AIL International Limited
    Inventors: Kenneth Clare, Erle Hopkinson
  • Patent number: 4421516
    Abstract: An improved process for preparing discharge prints on textile materials containing hydrophobic fibers wherein at least one disperse dyestuff dischargeable to white is applied to the textile material in the form of a dyeing liquor of print paste and also contacted by a pattern-applied discharge resist print paste, and then the material is heat treated at 100.degree. to 230.degree. C., wherein the improvement comprises said discharge resist print paste having, under the heat treatment conditions, a pH value of zero to 3.
    Type: Grant
    Filed: March 10, 1983
    Date of Patent: December 20, 1983
    Assignee: Cassella Aktiengesellschaft
    Inventors: Theo Stahl, Ulrich Buhler
  • Patent number: 4411666
    Abstract: A process for dyeing polyolefin fiber materials, which comprises contacting a polyolefin fiber material obtained by melt-spinning a mixture of crystalline polyolefin and 0.1 to 30% by weight based on the weight of the polyolefin of a copolymer of ethylene and an aminoalkyl acrylate compound represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen atom or methyl group, R.sub.2 and R.sub.3 each represents hydrogen atom or an alkyl group having 1 to 4 carbon atoms, and n represents an integer from 1 to 4, or a blend product of the said polyolefin fiber material and a polyamide fiber material, with a dye bath containing an anionic dye and at least one carboxylic acid selected from the group consisting of benzoic acid, salicylic acid, p-chlorobenzoic acid and 5-chlorosalicylic acid.
    Type: Grant
    Filed: February 8, 1982
    Date of Patent: October 25, 1983
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shuhei Hashizume, Sadaharu Abeta, Tadayuki Ohmae, Hajime Nishibara
  • Patent number: 4367071
    Abstract: An ink composition for heat transfer printing comprising at least one of carbinol bases of basic dyes or their derivatives, a strong base, a binder and a solvent for dissolving the binder. This ink composition is excellent in storage stability because it contains a carbinol base of a basic dye or its derivative in isolated form as a coloring agent along with a strong base. By using this ink composition, a transfer sheet having high storage stability can be obtained.
    Type: Grant
    Filed: February 4, 1981
    Date of Patent: January 4, 1983
    Assignee: Dai Nippon Insatsu Kabushiki Kaisha
    Inventors: Shogo Mizuno, Kyoichi Shimomura, Michiaki Kobayashi
  • Patent number: 4328220
    Abstract: Non-dusting pulverulent or granulated dye preparations are provided which contain (1) an organic dye, (2) a non-ionic compound having a hydrotropic action and at least one of the components (3) or (4), component (3) being a reaction product of a fatty acid having 8 to 22 carbon atoms and 1 to 2 mols of diethanolamine and component (4) being a compound of the formula ##STR1## in which R is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms or a cycloaliphatic, aromatic or aliphatic-aromatic hydrocarbon radical having 10 to 22 carbon atoms, R.sub.1 is hydrogen or methyl, A is --0-- or ##STR2## X is the acid radical of an inorganic, oxygen-containing acid, the acid radical of a polybasic carboxylic acid or a carboxyalkyl radical and m is a number from 1 to 50, and (5) optionally further customary additives.
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: May 4, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Beat Bruttel, Arthur Buhler
  • Patent number: 4322415
    Abstract: Stable concentrated liquid preparations of metal complex dyes are provided. These preparations contain (1) a metal complex dye, (2) a non-ionic compound having a hydrotropic action and at least one of components (3) or (4), component (3) being a reaction product of a fatty acid having 8 to 22 carbon atoms and 1 to 2 mols of diethanolamine and component (4) being a compound of the formula ##STR1## in which R is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms or a cycloaliphatic, aromatic or aliphatic-aromatic hydrocarbon radical having 10 to 22 carbon atoms, R.sub.1 is hydrogen or methyl, A is --O-- or ##STR2## X is the acid radical of an inorganic, oxygen-containing acid, the acid radical of a polybasic carboxylic acid or a carboxyalkyl radical and m is a number from 1 to 50, and (5) water, a water-soluble organic solvent having a boiling point of at least 80.degree. C. or a mixture of the two and (6) optionally conventional formulating agents.
    Type: Grant
    Filed: June 13, 1980
    Date of Patent: March 30, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Heinz Abel, Paul Hugelshofer, Arthur Buhler
  • Patent number: 4308025
    Abstract: A process for simultaneously bulking and dyeing linear polycarbonamide fibers which comprises treating the same with a solution of an alcohol containing a tinctorial amount of at least one dyestuff therein, and thereafter washing the treated fibers in hot water, soaping, and washing in hot and cold water and drying.
    Type: Grant
    Filed: August 12, 1980
    Date of Patent: December 29, 1981
    Assignee: Burlington Industries, Inc.
    Inventor: Samir Hussamy
  • Patent number: 4302199
    Abstract: A method for coloring hair comprising sequentially treating the hair with a solution of water soluble ferric ion salt and with a carboxylic acid solution.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: November 24, 1981
    Assignee: The Procter & Gamble Company
    Inventor: Prem S. Juneja
  • Patent number: 4289496
    Abstract: A finishing process for porous fibrous materials, especially for textiles, especially a dyeing process, in the presence of relatively small amounts of water and a foaming agent, is carried out at a liquor to material ratio of about 0.25:1 to 5:1. This water-saving finishing process leads to equal and level finishings especially important in the dyeing area.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: September 15, 1981
    Assignee: Sandoz Ltd.
    Inventor: Gordon H. Lister
  • Patent number: 4286955
    Abstract: An aqueous-based nylon fiber shrinking composition which can be formulated into a print paste is disclosed. The resulting print paste exhibits excellent viscosity stability and can be applied to nylon pile fabric to produce print-embossed pattern fabric.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: September 1, 1981
    Assignee: Armstrong Cork Company
    Inventor: Robert D. Lewis
  • Patent number: 4248594
    Abstract: Compositions of nickel salts of 4-hydroxybenzoic acids and esters of aliphatic or aromatic carboxylic acids, which esters have boiling points of at least about 250.degree. C. are useful for stabilizing polyolefins against degradation by heat and ultraviolet radiation and for rendering polyolefins dyeable.
    Type: Grant
    Filed: February 4, 1980
    Date of Patent: February 3, 1981
    Assignee: American Cyanamid Company
    Inventors: Robert J. Tucker, Joseph A. Hoffman
  • Patent number: 4245990
    Abstract: A process for producing solutions of salts of water-soluble carboxylic acids of cationic dyes or optical brighteners, the solutions of cationic dye salts or brighteners salts which are obtained by this process and which are miscible with water in any proportion, and the use of these solutions for preparing dye liquors and printing pastes for dyeing, optical brightening and printing of, in particular, synthetic textile materials, which process comprises reacting the halide of a cationic dye or brighteners, in an aqueous or anhydrous medium, with at least one water-soluble carboxylic acid in the presence of an epoxide compound having a minimum of 13 carbon atoms.
    Type: Grant
    Filed: December 21, 1978
    Date of Patent: January 20, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Loew, Walter Lang
  • Patent number: 4240793
    Abstract: A process for the preparation of a high-hiding, deeply colored pigmentary form of perylene-3,4,9,10-tetracarboxylic acid bis-(4'-ethoxyphenyl)-imide by heating the finely divided crude pigment, which is in the form of agglomerates, formed from primary particles of length 0.15 .mu.m or less, in cyclohexanone or a mixture of cyclohexanone and water at from 30.degree. to 200.degree. C., and isolating the pigment.
    Type: Grant
    Filed: September 13, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Aktiengesellschaft
    Inventor: Fritz Graser
  • Patent number: 4229177
    Abstract: This invention discloses compositions and methods for dyeing natural proteinaceous and synthetic polyamide fibers, particularly wool, silk and nylons, utilizing dye assistants effective with both acid and disperse dyes, such assistants being synergistic combinations of (a) dicyclopentenyl alcohol with (b) certain other materials, none of the components in either (a) or (b) being, in themselves, effective dye assistants for both acid and disperse dyes.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: October 21, 1980
    Assignee: Velsicol Chemical Corporation
    Inventors: Remus I. Lazar, Richard C. Reichel
  • Patent number: 4229176
    Abstract: A process for preventing oligomer deposits on dyeings produced on textile material consisting of or containing polyester fibers, which process comprises applying to said material during or after dyeing a phthalic acid ester of the formula ##STR1## wherein R is alkyl or alkenyl of 6 to 22 carbon atoms,X.sub.1 and X.sub.2, is hydrogen or methyl and the other is hydrogen,Z is hydrogen or alkyl of 1 to 4 carbon atoms, andn is 1 to 4.
    Type: Grant
    Filed: August 7, 1978
    Date of Patent: October 21, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Paul Schafer, Heinz Abel
  • Patent number: 4229172
    Abstract: Polyester or polyester blend textile material is dyed with a disperse dyestuff in the presence of a benzalketo derivative as a dyeing carrier.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: October 21, 1980
    Assignee: Sandoz Ltd.
    Inventors: Hans-Peter Baumann, Hans-Georg Karmann, Achim Wiedemann
  • Patent number: 4227880
    Abstract: Described is a process for the production of solid dustfree preparations of water-soluble dyes and optical brighteners, which process comprises subjecting the pulverulent dyes or optical brighteners, together with a melt or a solution of ethylene carbonate or propylene carbonate, to a dynamic treatment. The preparations obtained have in particular the advantage that the dust-binding effect is retained undiminished over a long period of time, and that they are completely soluble when used in aqueous baths of dyes or optical brighteners.
    Type: Grant
    Filed: April 14, 1978
    Date of Patent: October 14, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Helmut Hohenegger, Hanspeter Baumann, Urs Buchel
  • Patent number: 4227882
    Abstract: Change of color of grafted fiber or fibrous material having active hydrogen can be prevented by treating the fiber or fibrous material with a processing agent consisting mainly of a compound having the following general formula ##STR1## wherein M.sub.1 -M.sub.5 represent a hydrogen atom or alkali metal, and n represents 0 or 1.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: October 14, 1980
    Assignee: Kanebo, Ltd.
    Inventors: Toshio Saito, Masao Oguchi, Akio Kisaichi
  • Patent number: 4209298
    Abstract: Compositions and methods for dyeing natural proteinaceous and synthetic polyamide fibers, particularly wool, silk and nylons, utilizing dye assistants effective with both acid and disperse dyes, such assistants being a combination of (a) dibenzyl ether with (b) a compound of the formula: ##STR1## wherein x is selected from the group consisting of hydrogen, methyl and ethyl.
    Type: Grant
    Filed: June 5, 1978
    Date of Patent: June 24, 1980
    Assignee: Velsicol Chemical Corporation
    Inventors: Remus I. Lazar, Richard C. Reichel