Abstract: Disclosed is a dry CO2 capturing device with improved energy efficiency, which utilizes a difference in temperature between a regeneration operation of isolating CO2 from an sorbent containing CO2 absorbed therein and a pre-treatment operation of allowing H2O to be adsorbed to CO2. The dry carbon dioxide (CO2) capturing device, includes a recovery reactor for recovering CO2, a recovery cyclone for discharging a gas while separating the CO2-captured solid sorbent only, a regenerator for receiving the CO2-captured solid sorbent and separating CO2 captured in the solid sorbent, and a pre-treatment reactor for cooling the solid sorbent free from CO2, wherein a first heat exchanger is provided between the recovery cyclone and the regenerator to pass the CO2-captured solid sorbent therethrough, and a second heat exchanger is provided between the pre-treatment reactor and the regenerator to pass the solid sorbent free from CO2 therethrough.

Abstract: In various implementations, various feed gas streams which include hydrogen and carbon monoxide may be processed for conversion to product streams. For example, the feed gas stream may be processed using the Fischer-Tropsch process or a methanol synthesis process. Unconverted hydrogen and carbon monoxide can be recycled at high recovery and/or inert components removed to prevent build-up in the recycle system by using an arrangement of pressure swing adsorption systems designed to recover impure product gas streams.

Abstract: Methods are provided for forming zeolite crystals suitable for gas phase separations with transport characteristics that are stable over time. The zeolitic materials and/or corresponding methods of synthesis or treatment described herein provide for improved stability in the early stages of process operation for some types of gas phase separations. The methods allow for synthesis of DDR type zeolites that have reduced contents of alkali metal impurities. The synthetic methods for reducing the non-framework alkali metal atom or cation impurity content appear to have little or no impact on the DDR crystal structure and morphology.

Abstract: Systems and methods are provided for improving separation of gas phase streams using an adsorbent, such as 8-member ring zeolite adsorbents or DDR type zeolite adsorbents. Suitable gas phase streams can include at least one hydrocarbon, such as methane or a hydrocarbon containing at least one saturated carbon-carbon bond, and at least one additional component, such as CO2 or N2. The selectivity of the adsorbent is improved by selectivating the adsorbent with one or more barrier compounds. The presence of the barrier compounds is believed to alter the relative ability of potential adsorbates to enter into and/or move within the pores of the adsorbent.

Abstract: A method and apparatus for removing water vapor from the flue gas stream of an industrial process, including flue gas from a power station. The apparatus including a moisture transfer device, a cooling device, and an optional enthalpy exchange device. The method including running high volumes the flue gas through the moisture transfer device, the cooling device, and the enthalpy exchange device to remove substantially all of the water vapor from the flue gas stream. Also, a method and apparatus for capturing CO2 from flue gas with very low water vapor content. The apparatus including one or more towers packed with a solid sorbent, or including a liquid sorbent. The CO2 from the water vapor free CO2 stream is sorbed by the sorbent and captured for later use.

Abstract: A gas mask and breathing equipment is provided with a circuit for breathing gas and with a heat exchanger (7) cooled by an evaporating agent. The evaporating agent is introduced from an evaporating agent container (8) into the heat exchanger (7) via at least one group of spraying elements (9) and a gas delivery means (11) allows a gas volume flow to flow through the heat exchanger (7).

Abstract: The present invention are methods for removing preselected substances from a mixed flue gas stream characterized by cooling said mixed flue gas by direct contact with a quench liquid to condense at least one preselected substance and form a cooled flue gas without substantial ice formation on a heat exchanger. After cooling additional process methods utilizing a cryogenic approach and physical concentration and separation or pressurization and sorbent capture may be utilized to selectively remove these materials from the mixed flue gas resulting in a clean flue gas.

Abstract: Reduction of water, CO2 and N2O in an air stream comprising: passing said air stream at a feed temperature through a first adsorbent, whose Henry's Law selectivity for CO2/N2O is at least 12.5, and a second adsorbent, whose Henry's Law constant for CO2 is less than 1020 mmol/g/atom and whose Henry's Law selectivity for CO2/N2O is at most 5; and passing a heated regenerating gas at a temperature which is between 20° C. and 80° C. to at least the second adsorbent, and passing a second regenerating gas at a temperature less than the temperature of the heated regenerating gas to the first and second adsorbents in a direction opposite to the feed direction; the second adsorbent occupying from 25% to 40% of the total volume of the adsorbents, and the temperature of the heated regenerating gas being 10° C. to 60° C. higher than the feed temperature.

Abstract: Porous metal organic frameworks formed by AlIII ions to which fumarate ions are coordinated to produce a framework structure; shaped bodies comprising such porous metal organic frameworks, and also the preparation and use thereof for the uptake of a substance for the purposes of its storage, controlled release, separation, chemical reaction or as support.

Abstract: Sorbent substrates for CO2 capture and methods for forming the same are disclosed. In one embodiment, a method for forming a sorbent substrate for CO2 capture may include forming a plurality of matrix rods from a sorbent material and forming a plurality of channel rods from a support material. The plurality of matrix rods may then be co-extruded with the plurality of channel rods to form a plurality of sorbent filaments comprising a matrix of the sorbent material in which channels of support material are positioned such that the channels extend in an axial direction of each of the plurality of sorbent filaments. The plurality of sorbent filaments may then be stacked to form a filament assembly in which the plurality of sorbent filaments are axially aligned. Thereafter, the plurality of sorbent filaments of the filament assembly may be bonded to one another to form the sorbent substrate.

Abstract: A system for removing carbon dioxide from an atmosphere to reduce global warming including an air extraction system that collects carbon dioxide from the atmosphere through a medium and removes carbon dioxide from the medium; a sequestration system that isolates the removed carbon dioxide to a location for at least one of storage and generation of a renewable carbon fuel; and one or more power supplying units that supply heat to the air extraction system to remove the carbon dioxide from the medium, at least one of the one or more power supplying units being a fossil fuel plant.

Abstract: Disclosed is a method for removing carbon dioxide from a gas stream, comprising placing the gas stream in contact with a resin, wetting the resin with water, collecting water vapor and carbon dioxide from the resin, and separating the carbon dioxide from the water vapor. The resin may be placed in a chamber or a plurality of chambers connected in series wherein the first chamber contains resin that was first contacted by the gas, and each successive chamber contains resin which has been wetted and carbon dioxide collected from for a greater period of time than the previous chamber, and so on, until the last chamber. Secondary sorbents may be employed to further separate the carbon dioxide from the water vapor.

Abstract: Provided herein are methods and apparatus for capturing or otherwise decreasing the amount of CO2 in an exhaust stream. The separation process for removing CO2 from a waste stream preferably operates substantially at atmospheric pressure and at a preselected temperature, and without the need of thermal swing regeneration. This novel elimination of the heat up and cool down periods allows the inventive cycle herein to be run faster, and more efficiently than in previously known systems. Further, in some examples herein, the heat of adsorption is used to provide the heat of regeneration.

Abstract: A sorbent article having a substrate having porous channel walls defining open channels, and an organic-inorganic hybrid sorbent material distributed on a surface of the porous channel walls, wherein the sorbent material is derived from an amino-functionalized alkoxysilane and a polyamine, wherein the sorbent material is present in an amount equal to or greater than 10 g/l, wherein at least some of the sorbent material resides in the porous channel walls and forms CO2 adsorption sites within the interior of the porous channel walls. The article may be useful, for example, for removing CO2 from a gas.

Abstract: New and useful system and method concepts are provided, for removing carbon dioxide from a flow of carbon dioxide laden air. More specifically, a sorbent structure is used in new and useful structures and techniques to bind carbon dioxide in a carbon dioxide laden air stream, and process heat is used to separate carbon dioxide from the sorbent structure and regenerate the sorbent structure.

Abstract: A ceramic material, methods for adsorbing and converting carbon dioxide are provided. The ceramic material is represented by a chemical formula M1xM2yOz, wherein M1 is selected from a group consisting of Nd, Sm, Gd, Yb, Sc, Y, La, Ac, Al, Ga, In, Tl, V, Nb, Ta, Fe, Co, Ni, Cu, Ca, Sr, Na, Li and K; M2 is selected from a group consisting of Ce, Zn, Ti, Zr and Si; O represents oxygen atom; x<0.5, y>0.5, x+y=1.0, z<2.0; and the ceramic material has an adsorption capacity of not less than 20 ?mol/g for CO2 at 50° C.

Abstract: Composite materials for carbon dioxide (C02) capture that include: (1) a mesoporous carbon source; and (2) an in situ polymerized polymer that is associated with the mesoporous carbon source, where the in situ polymerized polymer is selected from the group consisting of thiol-based polymers, amine-based polymers, and combinations thereof. Methods of making the composite materials for C02 capture include: (1) associating a mesoporous carbon source with monomers, where the monomers are selected from the group consisting of thiol-based monomers, amine-based monomers, and combinations thereof; and (2) polymerizing the monomers in situ to form said composite materials. Further embodiments of the present invention pertain to methods of capturing C02 from an environment by associating the environment with one or more of the aforementioned composite materials.

Abstract: The invention is directed to processes and apparatuses for gas treatment, in particular for the purification of methane rich gas streams, such as gas obtained from the conversion from organic matter (“biogas”). In accordance with the present invention there is provided an apparatus and a process for producing a purified methane comprising gas stream (P) from a methane containing gas stream (A), comprising the steps of: (a) pressurising said methane containing gas stream (A) and subsequently cooling it, whereby a stream comprising condensed contaminants (C) and a methane comprising stream (B) are obtained; (b) optionally feeding said methane comprising stream (B) to an adsorption unit and/or a catalytic conversion unit, whereby the concentration of contaminants in stream (B) is further decreased; and (c) cooling the methane comprising stream (B) to a temperature which is sufficient to condensate CO2 from said stream (B), whereby said purified methane comprising gas stream (P) is obtained.

Abstract: Novel adsorbent contactors and methods are disclosed herein for use in temperature swing adsorption for gas separation applications, as well as for heat exchange applications.

Abstract: The invention relates to an increased efficiency high-capacity pressure and/or temperature swing adsorption process comprising: contacting a feedstream at a rate of more than 75 MSCFD with an adsorbent material under conditions sufficient for the adsorbent material to selectively adsorb at least one of the component gases in the feedstream, so as to form a first effluent; and selectively desorbing the adsorbed gas from the adsorption material, so as to form a second effluent The adsorption module can contain rotary valves both on the feed end and on the product end and a rotational member defining a central rotational axis, with the adsorption bed(s) oriented circumferentially thereto. The adsorption bed walls can be angled, the feed end cross-sectional area of the adsorption bed(s) can be larger than the product end, and/or the feed end rotary valve diameter of the module(s) can be larger than the product end.

Abstract: A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.

Abstract: A system for collecting carbon dioxide from a process gas including an adsorbent material for adsorbing carbon dioxide molecules from the process gas, a dielectric heater proximate the adsorbent material, and a vessel having an internal volume enclosing the adsorbent material and, optionally, the dielectric heater.

Abstract: The present invention relates generally to a composite adsorbent comprising at least a zeolite-containing CO2 removal adsorbent and 10% or more of a metal oxide having a heat capacity of at least 20 cal/mol-° K (83.7 J/(mol·K). The composite is preferably used in a multi-layered adsorption system in a cyclic adsorption process. The adsorption system comprises two or more layers wherein the first layer is at least a water vapor removal adsorbent, such as activated alumina, and the second layer is the novel composite adsorbent. The adsorption system is preferably used in a PSA prepurification process prior to cryogenic air separation.

Abstract: A sorbent article having a substrate having porous channel walls defining open channels, and an organic-inorganic hybrid sorbent material distributed on a surface of the porous channel walls, wherein the sorbent material is derived from an amino-functionalized alkoxysilane and a polyamine, wherein the sorbent material is present in an amount equal to or greater than 10 g/l, wherein at least some of the sorbent material resides in the porous channel walls and forms CO2 adsorption sites within the interior of the porous channel walls. The article may be useful, for example, for removing CO2 from a gas.

Abstract: An air compression system and method for an air separation plant in which air is compressed in a series of compression stages and a temperature swing adsorption unit adsorbs water vapor and carbon dioxide. The temperature swing adsorption unit is situated at a location of the compression stages such that air pressure upon entry into the adsorbent beds is between about 400 psia and about 600 psia. Each of the adsorbent beds of the unit have a minimum transverse cross-sectional flow area that will set the air velocity of the air to a level below that at which adsorbent bed fluidization would occur. Such operation allows fabrication costs of the adsorbent beds to be reduced because less adsorbent and smaller adsorbent beds are required while power consumption will be at a minimum.

Abstract: Described is an enhanced partially-aminated metal-organic framework comprising, or prepared from, metal cations and a synergistically effective ratio of a multi-carboxylic acid and an amino-substituted derivative of the multi-carboxylic acid, or the acceptable salts thereof, or any combination thereof; a manufactured article comprising the enhanced partially-aminated metal-organic framework; a method of preparing the enhanced partially-aminated metal-organic framework, and a method of using the enhanced partially-aminated metal-organic framework for separating carbon dioxide gas or other acid gas from an ad rem gas mixture.

Abstract: A system for capturing carbon dioxide from a shifted syngas is disclosed. The system may generally include a solid sorbent configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature. In addition, the system may include an absorption chamber configured to receive the shifted syngas at the first temperature and a regeneration chamber separate from the absorption chamber. The regeneration chamber may be maintained at the second temperature. The solid sorbent may be cycled between the absorption chamber and the regeneration chamber such that carbon dioxide from the shifted syngas is absorbed within the absorption chamber to produce a decarbonized fuel gas and released within the regeneration chamber to produce a carbon dioxide stream.

Abstract: A system for capturing carbon dioxide from flue gas exhausted from a burner. The system may generally include a solid sorbent configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature. In addition, the system may include a flue gas passage defining a flow path for the flue gas exhausted from the burner. The flow path may include an absorption zone in which the flue gas is at the first temperature and a regeneration zone in which the flue gas is at the second temperature. The solid sorbent may be cycled between the absorption zone and the regeneration zone such that carbon dioxide from the flue gas is absorbed by the solid sorbent within the absorption zone and released by the solid sorbent within the regeneration zone.

Abstract: A microbubble cleaning system includes a tank in which a solution into which a product is immersed to clean the product is stored; supplying means for putting microbubbles into the solution and supplying the solution that includes the microbubbles into the tank; oil separating apparatus that collects bubbles that have risen to a surface of the solution stored in the tank as a result of cleaning the product, as well as a portion of the solution that is near the surface of the solution, in order to separate oil from the solution; generating means for generating a surface flow of the solution near the surface of the solution in order to remove the bubbles that have risen to the surface of the solution in the tank; and removing means for removing carbon dioxide from air that is used to generate the microbubbles by the supplying means.

Abstract: A method is provided for forming a zeolitic imidazolate framework composition using at least one reactant that is relatively insoluble in the reaction medium. Also provided herein is a material made according to the method, designated either as EMM-19 or as EMM-19*, and a method of using same to adsorb and/or separate gases, such as carbon dioxide.

Abstract: A composition of matter, and method to make same, for a nano-based material including a nanocarbon support to which is attached an aliphatic amine. In particular, the composition of matter is an aliphatic amine-nanocarbon material that includes a nanocarbon (NC) support, such as C60, nano-graphite, graphene, nanocarbon ribbons, graphite intercalation compounds, graphite oxide, nano-coal, nanohorns, and combinations thereof, and further includes an aliphatic amine, such as polyethyleneimine (PEI).

Abstract: A system and System for removing CO2 from an input gas stream. The system comprises a carboniser segment configured such that a solid sorbent reacts therein with the input gas stream to remove CO2 from the input gas stream; a calciner segment configured such that the solid sorbent from the carboniser segment reacts therein to release the CO2 into a substantially pure gas stream; a heat exchanger unit for exchanging heat between the carboniser and calciner segments; a first conditioning unit for controlling a CO2 partial pressure in the carboniser segment; and a second conditioning unit for controlling a CO2 partial pressure in the calciner segment; wherein the first and second conditioning units are configured such that a difference between the CO2 partial pressures in the carboniser and calciner segments respectively is controlled such that heat is provided from the carboniser to the calciner through the heat exchanging unit.

Abstract: A process for conversion of conventional sand granules (or other particulates) to a ‘core-shell’ adsorbent granules in which GO (or GO-f) coating imparts nano structural features on the surface of the sand granules (or other particulates). Such materials are useful in a variety of engineering applications such as water purification, catalysis, capacitors, proppants, casting, and magnetic shielding.

Abstract: A method for processing a CO2-containing gas in order to reduce the carbon dioxide content thereof, includes contacting the gas with a compound of at least one rare earth element, whereby the carbon dioxide is adsorbed onto the compound and a carbon dioxide-depleted gas is thus obtained; such compound is more particularly an oxide, and the rare earth element is particularly selected from among cerium, lanthanum or praseodymium.

Abstract: Nanocomposite adsorbent materials and methods for their preparation and use are described. As an example, a polyaniline-graphite nanoplatelet nanocomposite may be used to adsorb carbon dioxide.

Abstract: A method for recycling a carbon-containing greenhouse gas emissions such as carbon dioxide and methane (natural gas) or a hydrocarbon homolog thereof. The method includes the steps of capturing the emissions, sequestering them in an underground or undersea storage area, withdrawing them from the storage area after storage therein, and converting them to carbon-containing compounds such as methanol, dimethyl ether and derived products. Greenhouse gases such as carbon dioxide and methane are chemically recycled to provide a permanent and inexhaustible supply of carbon-containing fuels or products, which subsequently can be combusted or used without increasing the carbon dioxide content of the atmosphere. The method is thus effective in neutralizing or reducing the carbon footprint due to human activities related to combustion or use of carbon-containing fuels while providing a repeatedly sustainable carbon source.

Abstract: The present invention relates to a porous metal-organic framework material comprising a bidentate organic compound bound by coordination to a metal ion, the metal ion being AlIII and the bidentate organic compound being 2,6-naphthalenedicarboxylate, wherein the X-ray diffractogram (XRD) of the framework material has a first reflection in the range from 6.5°<2?<7.5° and a second reflection in the range from 13.8°<2?<15.0°, the area of the first reflection being greatest in relation to the area of all reflections in the range from 2°<2?<70° and the area of the second reflection being second greatest, and the sum of the areas of the first and second reflections giving at least 50% in relation to the total area of all reflections in the range from 2°<2?<70°. The invention further relates to shaped bodies comprising such a framework material, processes for production of the framework material and also to the use of the framework material or of the proposed shaped body.

Abstract: A novel crystalline hybrid solid with a mixed organic-inorganic matrix is described which has a three-dimensional structure containing an inorganic framework with metallic centres based on zinc connected together via deprotonated organic ligands constituted by the entity —O2C—C6H2—(O)2—CO2. This novel solid is termed IM-21 and has an X-ray diffraction diagram as given below.

Abstract: In a method and an apparatus for separating at least one gaseous component from a waste gas of an installation for producing liquid pig iron, liquid primary steel products or sponge iron, in a first step, a stream of the waste gas passes through at least one adsorption separator at a first pressure, whereby the gaseous component is largely separated from the waste gas and, in a second step, the gaseous component is largely removed from the adsorption separator at a second pressure, which is lower than the first pressure. The method and apparatus are maintenance-free, cause low investment and energy costs and has a lower space requirement by a method in which the second pressure or the desorption pressure is generated by at least one jet pump, which is fed a stream of a propellant gas at a third pressure, which is higher than the second pressure.

Abstract: An acid-gas sorbent comprising an amine-composite. The present composite may comprise a first component comprising an amine compound at a concentration of from about 1 wt % to about 75 wt %; a second component comprising a hydrophilic polymer and/or a pre-polymer compound at a concentration of from about 1 wt % to about 30 wt %; and a third component comprising a cross-linking agent, and/or a coupling agent at a concentration of from about 0.01 wt % to about 30 wt %.

Abstract: Disclosed herein is a method and system for separating carbon dioxide (CO2) from a CO2 containing gas stream containing water vapor and additional impurities, for example, nitrogen, oxygen, sulfur oxides, nitrogen oxides, and mercury. The CO2 is captured by subjecting the CO2 gas feed stream to a temperature swing adsorption step. The temperature swing adsorption step comprises an adsorption step for producing a substantially dry carbon dioxide-depleted stream, and an adsorbent regeneration step comprising heating the adsorbent bed to produce a substantially water vapor-free carbon dioxide stream. Moisture from the gas stream containing CO2 is optionally removed by pressure swing adsorption, temperature swing adsorption, membrane separation, or absorption prior to CO2 capture.

Abstract: An energy-efficient method of recovering carbon dioxide (CO2) in a high-pressure liquid state from a high-pressure gas stream. The method includes cooling, condensing, and/or separating CO2 from a high-pressure gas stream in two or more separation zones and further purifying the resulting sub-critical pressure liquid CO2 streams in a third purification zone to thereby provide purified CO2. The purified liquid CO2 may be pumped to above the critical pressure for further utilization and/or sequestration for industrial or environmental purposes.

Abstract: A particulate form carbon pyrolyzate adsorbent, having the following characteristics: (a) CO2 capacity greater than 105 cc/gram at one bar pressure and temperature of 273° Kelvin; (b) CO2 Working Capacity greater than 7.0 weight percent; (c) CO2 heats of adsorption and desorption each of which is in a range of from 10 to 50 kJ/mole; and (d) a CO2/N2 Henry's Law Separation Factor greater than 5. The carbon pyrolyzate material can be formed from a polyvinylidene chloride-based polymer or copolymer, or other suitable resin material, to provide an adsorbent that is useful for carbon dioxide capture applications, e.g., in treatment of flue gases from coal-fired power generation plants.

Abstract: A system for isolating a greenhouse gas from an exhaust gas includes a vessel having an inlet to receive an exhaust gas, and an outlet to discharge a process stream, an adsorbent contained in the vessel to selectively adsorb the greenhouse gas from the exhaust gas under suitable conditions, and a heat source to heat the adsorbent and desorb the adsorbed greenhouse gas therefrom to produce a process stream of greenhouse gas for release through the outlet.

Abstract: Provided is one of labels 101, 120, 130 and 140, top layer materials formed on a printing medium 201, 246 and 266, information-bearing media 301, 330, 350 and 360, a solid fuel 401, and a wristband clip 510, having the function of absorbing carbon dioxide to which a new carbon dioxide absorbent is added. Provided are also carbon dioxide reduction methods of absorbing carbon dioxide by burning the same.

Abstract: The method and system for methane separation and purification from a biogas includes collecting a raw Biogas gas stream having methane, carbon dioxide, water, sulfur compounds and non-methane organic compound (NMOC) constituents. The Biogas stream is fed into the intake of a liquid sulfur scrubber or a sulfur adsorber unit where the Biogas is separated into a main gas stream routed downstream in the system and a sulfur compounds stream removed from the system. The main gas stream is then processed by an NMOC absorber and further downstream, by an NMOC adsorber. NMOC produced by both NMOC processes is liquefied, removed from the system and stored. Upstream from the NMOC processes, the main gas stream is processed by at least one CO2, N2, O2 gas separation unit that produces a usable product stream of enriched methane gas, and an off-gas stream, which a VPSAU processes for venting and recycling.

Abstract: Embodiments are described that generally relate to the storage and release of a gas using piezoelectric materials.

Abstract: MOF (metal organic framework)-modified materials and methods of making and methods of using same. The MOFs are covalently bound to the materials. Examples of suitable materials include fibers and thin films. The MOF-modified materials can be made by forming MOFs in situ such that they are covalently bound to the materials. The MOF-modified materials can be used in methods where gases and/or toxic chemicals are absorbed.

Abstract: The invention relates to an adsorbent zeolite-based material comprising for 100 mass % an amount different from zero of a zeolite selected from X zeolites or LSX zeolites; the balance up to 100 mass % consisting of an amount different from zero of a cation-exchanged zeolite, said cation-exchanged zeolite being selected from cation-exchanged X zeolites and cation-exchanged LSX zeolites.

Abstract: The invention provides a process for producing purified natural gas from feed natural gas comprising water and carbon dioxide, the process comprising the steps of: (a) removing water from the feed natural gas to obtain natural gas depleted in water and comprising carbon dioxide; (b) contacting the natural gas obtained in step (a) with solid sorbent comprising a metal organic framework to remove at least part of the carbon dioxide, thereby obtaining the purified natural gas.