Abstract: Disclosed is an apparatus for installing a carbon dioxide absorbent canister which comprises a body, a lifting member, and a lifting mechanism. The body comprises a breathing circuit and an adapter for connecting the carbon dioxide absorbent canister with the breathing circuit. The adapter is located at or near the bottom of the body. The lifting member comprises a base portion, a positioning portion beneath the adapter, and a connecting portion. The lifting mechanism has a force receiving portion and a force applying portion and which actuates the lifting member. Actuating the handle in the first direction causes the canister to be connected to the breathing circuit and to close the breathing circuit bypass. Turning the handle in a second direction actuates the canister to enable replacement of the canister and to cause the breathing bypass to open. The process can be achieved simply with one hand.

Abstract: The invention relates to gas adsorbents based on metal-organic microporous coordination polymers of the metallic bispyrmidinolate-type with a sodalite-type topology, having an adsorbent performance that is typical of crystalline microporous materials. The aforementioned materials also have a large accessible pore volume of between 25 and 45% of the total volume of the material with a monodispersion of pores having diameters of less than 1.3 nm. In addition, the materials have a high capacity for adsorption of small gases, such as carbon monoxide, carbon dioxide, hydrogen, nitrogen, methane, acetylene, etc., which is reversible such that, once said gases have been stored, they can be desorbed.

Abstract: The adsorption of CO2 from flue gas streams using temperature swing adsorption. Adsorbent contactors are used in the temperature swing adsorption unit that contain a plurality of substantially parallel channels comprised of or coated with an adsorbent material that is selective for adsorbing CO2 from flue gas.

Abstract: A method for storing, separating or controlled releasing of at least one substance, by up taking the at least one substance by a porous metal organic framework material formed by Mg2+ ions to which 5-tert-buthylisophthalate ions are coordinated to form a framework structure.

Abstract: The separation of a target gas from a mixture of gases using a thermal swing adsorption process wherein a thermal wave is used, primarily in the desorption step. The process of this invention enables one to separately remove multiple contaminants from a treated gaseous stream.

Abstract: The present invention relates to a novel method of purifying a gas stream contaminated by CO2, hydrocarbons and/or nitrogen oxides, in particular a gas stream based on air or a syngas, by adsorption on a bed of aggregated zeolitic adsorbent based on an LSX zeolite or LSX and X zeolites, of which at least 90% of the exchangeable cationic sites of the LSX zeolite or of the LSX/X zeolite blend are occupied by sodium ions, and the inert binder of which represents at most 5% of the weight of the adsorbent.

Abstract: A process for the reduction of carbon dioxide (or CO2) from various types of gas emitting sources containing carbon dioxide, including the reduction of carbon dioxide from industrial gas emitting sources via the use of an ion exchange material.

Abstract: The present invention provides methods and systems for carbon dioxide, hydrogen sulfide and other acid gases capture via adsorption at high pressure using mesoporous materials.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: A method and apparatus for extracting CO2 from air comprising an anion exchange material formed in a matrix exposed to a flow of the air, and for delivering that extracted CO2 to controlled environments. The present invention contemplates the extraction of CO2 from air using conventional extraction methods or by using one of the extraction methods disclosed; e.g., humidity swing or electro dialysis. The present invention also provides delivery of the CO2 to greenhouses where increased levels of CO2 will improve conditions for growth. Alternatively, the CO2 is fed to an algae culture.

Abstract: Hydrogen sulfide is removed from a hydrogen rich gas stream using adsorbents having a low loss of carbon dioxide adsorption capacity upon sulfur loading including high purity silica gels, titania or highly cross-linked, non-chemically reactive resins. The adsorbents may be used to adsorb both carbon dioxide and hydrogen sulfide, or may be used as a guard bed upstream of a separate carbon dioxide adsorbent.

Abstract: A process and device to capture of CO2 at its originating source, such as a power plant, is disclosed. Absorbent material is recharged by desorbing CO2, so that it may be sequestered or used in another application. Continual recharging results in loss of absorbent surface area, due to pore plugging and sintering of particles. Calcium oxide or calcium hydroxide was immobilized to a fibrous ceramic-based fabric substrate as a thin film and sintered, creating an absorbent material. The samples were characterized, showing continuous cyclic carbonation conversions between about 62% and 75% under mild calcination conditions at 750° C. and no CO2 in N2. Under the more severe calcination condition at 850° C. and 20 wt % CO2 in N2, yttria fabric was superior to alumina as a substrate for carbon dioxide capture and the reactivity of the calcium oxide absorbent immobilized to yttria was maintained at the same level in the 12 cycles.

Abstract: A system for reducing carbon dioxide emissions from gasses generated in burning fossil fuel, includes a vessel, separator and reheater. The upper portion of the vessel receives downward flowing, first type solid particles capable of absorbing heat from upward flowing gasses and second type solid particles capable of capturing carbon dioxide from the gasses. The separator separates the second type solid particles with the captured carbon dioxide from the gasses discharged from the first vessel discharge, and directs the separated second type solid particles with the captured carbon dioxide to a separator discharge. The reheater directs the first type solid particles and the second type solid particles with the captured carbon dioxide in a downwardly flow to a first reheater discharge, such that heat from the first type solid particles causes the captured carbon dioxide to be released from the second type solid particles.

Abstract: A process for manufacturing a synthetic porous crystalline molecular sieve requires an aqueous reaction mixture comprising a source of X2O3 (X is a trivalent element), a source of YO2 (Y is a tetravalent element) and a source of MOH (M is an alkali metal). The H2O/MOH molar ratio is within the range of 70 to 126 and the source of X2O3 and YO2 is an amorphous material containing both X2O3 and YO2 and having YO2/X2O3 molar ratio of 15 or less. The molecular sieve products are useful as catalysts and/or absorbents. Such molecular sieves having MFI structure type, TON structure type or the structure type of zeolite beta and a composition involving the molar relationship (n) YO2:X2O3 wherein n is from 2 to less than 15 are novel compositions of matter.

Abstract: New and useful system and method concepts are provided, for removing carbon dioxide from a flow of carbon dioxide laden air. More specifically, a sorbent structure is used in new and useful structures and techniques to bind carbon dioxide in a carbon dioxide laden air stream, and process heat is used to separate carbon dioxide from the sorbent structure and regenerate the sorbent structure.

Abstract: The present invention discloses a method and an apparatus for reactivating lime-based sorbents and increasing the carbon dioxide-capture capacity of the sorbent in the combustion of carbon-containing fuels. The method of the present invention seeks to increase the carbon dioxide capture capacity of lime-based sorbents by applying concentrated or 100% carbon dioxide directly to a lime-based sorbent. Optionally, the lime-based sorbent may be pretreated using a hydration process after each process of carbon dioxide separation. The regenerated sorbent is carbonated in a presence of concentrated carbon dioxide and elevated temperatures. The invention is useful in reducing the need to add additional sorbent to maintain the carbonation/calcination cycle. The regenerative potential of the sorbent as manifested by the present invention leads to increased carbon dioxide-capture capacity of the sorbent.

Abstract: A method of producing a carbon dioxide product stream from a synthesis gas stream formed within a hydrogen plant having a synthesis gas reactor, a water-gas shift reactor, located downstream of the synthesis gas reactor to form the synthesis gas stream and a hydrogen pressure swing adsorption unit to produce a hydrogen product recovered from the synthesis gas stream. In accordance with the method the carbon dioxide from the synthesis gas stream by separating the carbon dioxide from the synthesis gas stream in a vacuum pressure swing adsorption system, thereby to produce a hydrogen-rich synthesis gas stream and a crude carbon dioxide stream and then purifying the crude carbon dioxide stream by a sub-ambient temperature distillation process thereby to produce the carbon dioxide product. A hydrogen synthesis gas feed stream to the hydrogen pressure swing adsorption unit is formed at least in part from the hydrogen rich stream.

Abstract: A method of separating a mixture of carbon dioxiode and hydrocarbon gas using a mixed-ligand, metal-organic framework (MOF) material having metal ions coordinated to carboxylate ligands and pyridyl ligands.

Abstract: A system for removing carbon dioxide from an atmosphere to reduce global warming including an air extraction system that collects carbon dioxide from the atmosphere through a medium and removes carbon dioxide from the medium; a sequestration system that isolates the removed carbon dioxide to a location for at least one of storage and which can increase availability of renewable energy or non-fuel products such as fertilizers and construction materials; and one or more energy sources that supply process heat to the air extraction system to remove the carbon dioxide from the medium and which can regenerate it for continued use.

Abstract: A method of processing a volatile organic compound is provided, wherein a volatile organic compound contained in gas to be treated is adsorbed in an adsorbent; the thus-adsorbed volatile organic compound is desorbed with the aid of steam and mixed in the steam; and the steam containing the volatile organic compound is combusted. This method further includes: separating a vessel for the adsorption and desorption into an inner side room and an outer side room by means of a separation member part of which is formed of the adsorbent; thermally retaining the vessel for the adsorption and desorption; at the time of adsorption, supplying the gas to be treated to the inner side room and therefrom to the outer side room; and at the time of desorption, supplying the steam to the outer side room and therefrom to the inner side room.

Abstract: A porous crystalline material has a tetrahedral framework comprising a general structure, M1-IM-M2, wherein M1 comprises a metal having a first valency, wherein M2 comprises a metal having a second valency different from said first valency, and wherein IM is imidazolate or a substituted imidazolate linking moiety.

Abstract: The present invention relates to a new synthetise for the preparation of mesoporous structures including mesoporous materials with chiral morphologies and mesoporous materials with local or surface chirality. The method can be used for manufacturing controlled drug delivery devices, for example for delivery of folic acid, and fluorescent particles.

Abstract: The concentration of adsorbate in the feed gas to an on-stream bed of a cyclical swing adsorption process is monitored and the data processed to predict the time required to complete the on-stream mode of that bed and the purge flow rate and/or other regeneration mode operating condition of the concurrently off-stream bed is modified in response to changes in said predicted time whereby the regeneration mode of the off-steam bed is completed at the same time as the on-stream mode of the concurrent on-stream bed.

Abstract: The present invention provides a method for making a hybrid composition membrane comprising the steps of preparing a sol comprising at least one poly(amino-alcohol) and at least one alkoxy silane, casting the sol on a surface and drying the casted sol to form the hybrid composition membrane. The hybrid composition membrane may be used for capturing and separating CO2 and/or H2S from a gas sample.

Abstract: The invention provides a process for the activation of a magnesium or calcium sheet silicate hydroxide mineral comprising: (a) preheating magnesium or calcium sheet silicate hydroxide mineral particles to obtain preheated silicate hydroxide mineral particles; (b) activating the preheated silicate hydroxide mineral particles at elevated temperature to obtain at least hot activated mineral particles; and (c) cooling the hot activated mineral particles, wherein energy released during cooling in step (c) is used for preheating the magnesium or calcium sheet silicate hydroxide mineral particles in step (a) by heat-integration. The invention further provides an activated magnesium or calcium sheet silicate hydroxide mineral and a process for sequestration of carbon dioxide.

Abstract: An inventive adsorptive gas separation process is provided capable of producing a purified methane product gas as a light non-adsorbed product gas as opposed to a heavy desorbed exhaust gas component, from a feed gas mixture comprising at least methane, and carbon dioxide. In an embodiment of the invention, the feed gas mixture may comprise at least about 10% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide. In another embodiment of the invention, the feed gas mixture may comprise at least about 50% carbon dioxide, and the purified methane product gas may be desirably purified to contain less than about 5000 ppm carbon dioxide.

Abstract: A carbon dioxide-absorbing material containing lithium titanate, the lithium titanate comprising 70 mol % or more of Li4TiO4 and 30 mol % or less of Li2TiO3. Furthermore, the carbon dioxide-absorbing material is obtained by the method for producing a carbon dioxide-absorbing material described below. That is, the absorbing material is obtained by the production method which produces the same by mixing given raw materials such that the atomic ratio between lithium and titanium is from 3.5 to 5.0, and subjecting the resulting mixture to heat treatment. The method for absorbing carbon dioxide includes a carbon dioxide absorption step. The apparatus for absorbing carbon dioxide is provided with carbon dioxide absorption means that absorbs carbon dioxide in the carbon dioxide-absorbing material.

Abstract: Disclosed herein is a dry regenerable sorbent for carbon dioxide capture from flue gas produced by fossil fuel-fired power plants including industrial boilers before being released to atmosphere or from fuel gas stream such as syngas produced by conversion of fossil fuel (e.g. gasification), by dry regenerable sorbent technology. The dry regenerable sorbent comprises: 70 wt % or less of an active component selected from solid compounds capable of being converted to metal carbonates; 70 wt % or less of a support selected from solid porous non-metallic materials capable of imparting a required specific surface area to the sorbent; and 70 wt % or less of an inorganic binder selected from cement-like, clay-like, and ceramic-like binders capable of imparting mechanical strength to the sorbent, the total weight of the solid raw materials being 100 wt %.

Abstract: An emergency oxygen mask includes: a respiration part worn on a user's face for supplying oxygen or discharging carbon dioxide or moisture using a pressure difference depending on respiration of the user; a carbon dioxide supply part for supplying the carbon dioxide and the moisture discharged from the respiration part through a carbon dioxide supply hole at a lower surface of the carbon dioxide supply part; an oxygen generating part engaged with an outer surface of the carbon dioxide supply part and having an upper open surface for reacting potassium dioxide in the carbon dioxide supply part with carbon dioxide or moisture to generate oxygen; an oxygen storage part for storing oxygen moved by an oxygen moving part; and filters attached to opposite sides of the oxygen moving part to remove carbon dioxide remaining in the oxygen stored in the oxygen storage part and to lower the temperature and humidity of the oxygen supplied to the respiration part.

Abstract: The present invention generally relates to a process for the formation of a CO2-selective absorption material and/or sulfur-selective absorption material. In one embodiment, the present invention relates to a process for the formation of a CO2-selective absorption material that comprises providing a solid material, providing an amine source, contacting the solid material with the amine source to absorb amine molecules on the surface of the solid material, and contacting the absorbing amine molecules on the solid material surface with a CO2 stream such that upon contact with the amine and the solid material, CO2 binds with the amine functional group of the amine molecule, reducing the potential for the interaction of the amine functional group with the solid surface and increasing amine sites available for CO2 capture.

Abstract: A method of separating a target component from a chemical mixture comprising contacting a chemical mixture with a microporous coordination polymer. The microporous polymer is described by the formula: [M2(C8H2O6)] where M is a transition metal, rare earth metal, or other element from the groups consisting of HA through VB.

Abstract: A membrane and method for separating carbon dioxide from a mixture of gases, where the membrane includes expanded polytetrafluoroethylene and polysiloxane. The membrane is highly stable and can separate carbon dioxide at high flux in harsh environments and high temperatures, such as exhaust gases from power plants.

Abstract: A CO2 control device and method for capturing CO2 from fluid flow, including: a flow-through apparatus and an CO2 absorbing filter treated with an alkaline material which is housed within the flow-through apparatus. The flow-through apparatus receives fluid flow and the CO2 from the fluid flow is absorbed by the CO2 absorbing filter. The absorbed CO2 is converted into CaCO3 which is combined with volcanic ash to form a useful cement material.

Abstract: A low-pressure multifunctional filter separates CO2 and other air pollutants from flue, coal, natural and other gas mixtures. The separation agent is a solid carbon-rich sorbent, such as coke, charcoal, coal or activated carbon, that captures CO2 and other air pollutants at lower temperatures and liberates them at higher temperatures. The sorbent is regenerated by heating with direct steam, hot CO2 or other source of thermal energy. The recovered CO2-rich product can be used for enhanced oil recovery, enhanced methane recovery, and subsequent storage in depleted oil and gas reservoirs.

Abstract: A sorbent structure comprising a continuous activated carbon body in the form of a flow-through substrate; and an additive provided on the flow-through substrate, wherein the additive is capable of enhancing the sorption of CO2 on the sorbent structure. Methods of making the sorbent structure, its use for CO2 capture, and methods for regenerating the structure for further use.

Abstract: The present application is directed to a method and system for preparing gaseous utility streams from gaseous process streams, nitrogen process streams, and other types of streams. The methods and systems may include at least one swing adsorption process including pressure swing adsorption, temperature swing adsorption, and rapid-cycle adsorption processes to treat gaseous streams for use in dry gas seals of rotating equipment such as compressors, turbines and pumps and for other utilities. The systems and processes of the present disclosure are further applicable to high pressure gaseous streams, for example, up to about 600 bar.

Abstract: CO2 sorptive pellets and/or granules and their use for removing CO2 from CO2-containing gases and for producing hydrogen. CO2 sorptive pellets are suitable for use in fixed bed reactors and the like due to sufficient crush strength. CO2 sorptive granules are suitable for moving, ebullated, expanded and fluidized beds. The CO2 sorptive pellets and/or granules comprise calcium oxide and/or magnesium oxide and at least one binding agent such as calcium titanate, calcium aluminate, calcium zirconate, magnesium titanate, magnesium aluminate, and magnesium zirconate. A method for making the CO2-sorptive pellets is described. The CO2 sorptive pellets optionally comprise at Ni, Pd, Pt, and/or Rh.

Abstract: An improved process for the separation of carbon dioxide from the flue gas of an oxy-combustion power plant is provided. At least a first product stream and a second product stream are separated from a flue gas stream, wherein the pressure of the first product stream and the pressure of the second product stream are different. The first product stream is warmed and vaporized. The second product stream is then warmed and vaporized.

Abstract: The disclosure provides zeolitic frameworks for gas separation, gas storage, catalysis and sensors. More particularly the disclosure provides zeolitic frameworks (ZIFs). The ZIF of the disclosure comprises any number of transition metals or a homogenous transition metal composition.

Abstract: An improved carbon dioxide absorber for use in a closed circuit patient breathing system has a canister insertable in the breathing circuit for receiving recirculating breathing gases. The canister contains a pelletized CO2 absorbent material that removes the CO2 from the breathing gases passing through the absorber. A quantity of the CO2 absorbent material is treated with a chemical indicator such that the chemical indicator makes a color change indicative of the state of the absorptive capacity of the absorbent material. A separate quantity of the CO2 absorbent material is treated with a second chemical indicator. The second chemical indicator changes color to indicate the degree of dryness of the CO2 absorbent material. The second chemical indicator may comprise cobalt chloride and serves to indicate the potential for excessive heat generation and toxic gas generation conditions within the CO2 absorbent canister.

Abstract: Methods and systems are provided where a production gas stream including natural gas and carbon dioxide is separated downhole using dual reflux pressure swing adsorption with the natural gas being produced and the carbon dioxide being directed for downhole storage (sequestration).

Abstract: A sorbent system includes a porous polymer support and a sorbent within the porous polymer support. For example, the sorbent includes a tertiary amine, such as triethanolamine.

Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Abstract: Systems and methods for processing methane and other gases are disclosed. A representative method in accordance with one embodiment includes directing a first portion of a gas stream through a first adsorbent while exchanging heat between a second adsorbent and a third adsorbent. The method can further include directing a second portion of the gas stream through the third adsorbent while exchanging heat between the first and second adsorbents. The method can still further include directing a third portion of the gas stream through the second adsorbent while exchanging heat between the first and third adsorbents. In further particular aspects, the adsorbent can be used to remove carbon dioxide from a flow of methane. In other particular aspects, a heat exchange fluid that is not in direct contact with the adsorbents is used to transfer heat among the adsorbents.

Abstract: A system (10) for removing carbon dioxide from a process gas generated during the combustion of a fuel comprises at least one absorption vessel (12, 14) through which the process gas may be forwarded. The absorption vessel (12, 14) is provided with a sorbent material (50) which is operative for reversibly collecting carbon dioxide from the process gas being forwarded through the sorbent material (50). The sorbent material (50) comprises at least one amine, at least one carbon dioxide activating catalyst, and at least one porous material supporting the at least one catalyst and the at least one amine.

Abstract: The present invention generally relates to vacuum pressure swing adsorption (VPSA) processes and apparatus to recover carbon dioxide having a purity of approximately ?90 mole % from streams containing at least carbon dioxide and hydrogen (e.g., syngas). The feed to the CO2 VPSA unit can be at super ambient pressure. The CO2 VPSA unit produces three streams, a H2-enriched stream, a H2-depleted stream and a CO2 product stream. When the CO2 VPSA unit is installed between an SMR/shift reactor and a H2 PSA unit, hydrogen recovery is expected to be increased by extracting CO2, thereby increasing hydrogen partial pressure in the H2 PSA feed. The stream from the CO2 VPSA unit, normally used as fuel, is recycled as feed to increase CO2 recovery. The recovered CO2 can be further upgraded, sequestered or used in applications such as enhanced oil recovery (EOR).