Sulfur Or Sulfur Containing Compound Sorbed Patents (Class 95/235)
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Publication number: 20130095561Abstract: The present invention provides a biological H2S removal system for the treatment of process gas, comprising: a housing that receives a process gas stream through a gas inlet, the housing comprising a plurality of layers through which the process gas stream flows while it is treated for H2S removal, and a gas outlet through which a treated gas stream exits; wherein air is added to the process gas stream prior to the process gas stream entering the housing.Type: ApplicationFiled: October 18, 2011Publication date: April 18, 2013Inventor: Jeffrey J. Grill
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Publication number: 20130095017Abstract: The present invention provides a biological H2S removal system for the treatment of process gas, comprising: a housing that receives a process gas stream through a gas inlet, the housing comprising a plurality of layers through which the process gas stream flows while it is treated for H2S removal, and a gas outlet through which a treated gas stream exits; wherein air is added to the process gas stream prior to the process gas stream entering the housing.Type: ApplicationFiled: November 26, 2012Publication date: April 18, 2013Inventor: Jeffrey J. Grill
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Patent number: 8419843Abstract: In one embodiment, a system includes a hydrogen sulfide (H2S) absorber, a first flash tank, a flash gas treatment column, and a CO2 absorber. The system also includes a first fluid path extending sequentially through the H2S absorber, the first flash tank, the flash gas treatment column, the H2S absorber, and the CO2 absorber.Type: GrantFiled: May 18, 2010Date of Patent: April 16, 2013Assignee: General Electric CompanyInventors: Arnaldo Frydman, Pradeep Stanley Thacker, Sachin Suhas Naphad
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Patent number: 8419832Abstract: The invention relates to a process for the purification of a gaseous mixture containing mercaptans and other acid gases comprising a stage of bringing said gaseous mixture into contact with an absorbent solution comprising an alkanolamine, a C2-C4 thioalkanol and water.Type: GrantFiled: January 16, 2007Date of Patent: April 16, 2013Assignee: Total S.A.Inventors: Serge Capdeville, Jean-Louis Peytavy, Georges Fremy, Didier Anglerot
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Patent number: 8394179Abstract: A method is described for treating a gas stream containing a flammable gas, such as hydrogen or a hydrocarbon gas. The gas stream is conveyed to a liquid ring pump (18), to which a gaseous oxidant and water are supplied. The water and the gas stream are discharged from the pump (18), with the discharged gas stream being subsequently separated from the liquid, and conveyed to a pyrolysis device (42) for pyrolysing the flammable gas and the oxidant. Any particulates and acidic species within the gas stream are retained by the water within the liquid ring pump to inhibit corrosion or blockage of the pyrolysis device (42). A filter or other device (40) may be provided to remove water from the gas stream before it enters the pyrolysis device (42).Type: GrantFiled: January 23, 2008Date of Patent: March 12, 2013Assignee: Edwards LimitedInventors: James Robert Smith, Gary Peter Knight
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Patent number: 8394180Abstract: A method of absorbing gases into a liquid comprising providing a stream of at least one desirable gas and at least one undesirable gas, exposing the gas stream to a liquid, so that the liquid absorbs more of the desirable gas than the undesirable gas, and releasing the liquid and gas mixture into an underground formation.Type: GrantFiled: February 14, 2008Date of Patent: March 12, 2013Assignee: Shell Oil CompanyInventors: Zaida Diaz, Raymond Nicholas French, Dean Chien Wang, Geoffrey Matthew Warren
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Patent number: 8388739Abstract: A method for treating natural gas using a vessel having a manifold for introducing gas in the vessel, a flow disperser above the manifold that prevents channeling of the gas, a spray system for spraying a treating liquid into an upwardly rising column of gas and, optionally, a liquid level controller for maintaining the level of a pool of treating liquid above the flow disperser.Type: GrantFiled: February 9, 2012Date of Patent: March 5, 2013Assignee: Valerus Compression Services, LPInventors: Edwin W. Cash, Thomas J. Bradley
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Patent number: 8388747Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: March 5, 2013Inventor: Donald Leo Stinson
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Patent number: 8388737Abstract: A method and apparatus for recovering a gaseous component from an incoming gas stream is described. The incoming gas stream is contacted with a lean aqueous absorbing medium to absorb at least a portion of the gaseous component from the incoming gas stream to form a lean treated gas stream and a rich aqueous absorbing medium. At least a portion of the gaseous component is desorbed from the rich aqueous absorbing medium at a temperature to form an overhead gas stream and a regenerated aqueous absorbing medium. At least a portion of the overhead gas stream is treated to recover a condensate stream. At least a portion of the condensate stream is used to form a heated stream. At least a portion of the heated stream is recycled back to the desorbing step. Novel absorbing medium compositions to recover carbon dioxide and/or hydrogen sulfide are also described.Type: GrantFiled: May 29, 2008Date of Patent: March 5, 2013Assignee: University of ReginaInventors: Don Gelowitz, Paitoon Tontiwachwuthikul, Raphael Idem
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Patent number: 8387545Abstract: A method for introducing flue gas in a steam-assisted production facility into a vapor-liquid contactor. In this method the flue gas comprises boiler combustion products selected from at least one of commercial pipeline natural gas and produced gas. The flue gas is cooled with the vapor-liquid contactor to condense a portion of the water vapor in the flue gas to produce a water stream. The water stream is then recirculated and cooled in an air cooler to produce recirculating water exiting the bottom of the vapor-liquid contactor. A water slipstream is then taken off the recirculating water to be used as make-up water.Type: GrantFiled: July 15, 2010Date of Patent: March 5, 2013Assignee: ConocoPhillips CompanyInventors: Edward G. Latimer, Christopher R. Copeland, Ryan K. Davis, James Scinta, Dale L. Embry, David C. Lamont, Charles J. Murray, Ryan D. Donahe
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Patent number: 8377174Abstract: A gas sparger (30) is operative for supplying an oxidation gas containing oxygen to a tank (18) of a wet scrubber which is operative for removing sulphur dioxide from a process gas by means of a slurry (S). The gas sparger (30) is provided with at least a first liquid supply nozzle (38), which is located inside an oxidation gas supply duct (32) and is operative for spraying a liquid containing water towards a first oxidation gas supply nozzle (44). The oxidation gas supply duct (32) has a characteristic cross-sectional measure, such as a diameter (D), at said first oxidation gas supply nozzle (44). The first liquid supply nozzle (38) is located a distance (L1) of maximum 5 times said characteristic cross-sectional measure (D) from said first oxidation gas supply nozzle (44).Type: GrantFiled: February 5, 2009Date of Patent: February 19, 2013Assignee: ALSTOM Technology LtdInventors: Fredrik J. Brogaard, Rikard Hakansson
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Patent number: 8377403Abstract: Contemplated configurations and methods employ COS hydrolysis and a downstream H2S removal unit to produce a treated feed gas that is then further desulfurized in an absorber using two lean oil fluids. The so produced mercaptan enriched hydrocarbon fluid is fed to a distillation column that produces a light overhead vapor that is preferably combined with the treated feed gas and a sulfur rich bottom product that is in most cases preferably directly fed to a hydrocarbon processing unit comprising a hydrotreater. In further especially preferred aspects, the hydrocarbon processing unit produces at least one and more typically both of the two lean oil fluids, and the treated gas is optionally further processed to produce clean fuel gas in a hydrotreater for olefinic saturation and sulfur conversion using a lean oil recycle for reactor temperature control.Type: GrantFiled: July 30, 2007Date of Patent: February 19, 2013Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8361201Abstract: The hydrogen sulphide content of natural gas obtained from the extraction of sour-gas containing crude oil/ natural gas mixtures, is reduced by reducing the high pressure of a raw crude oil/ natural gas mixture to 70-130 bar, separating an outgassing raw gas from the crude oil, cooling the outgassed raw gas and simultaneously drawing off a liquid medium which condenses from the outgassing raw gas during cooling. The outgassed raw gas is subjected, after pressure reduction, to gas scrubbing by a physically active solvent. The laden solvent is directed to at least one pressure reduction step to obtain H2S outgas from the solvent. The pressure of the crude oil is further reduced in two subsequent steps to 20-40 bar and 2-15 bar and additional H2S rich raw gas streams are separated from the crude oil which outgas therefrom.Type: GrantFiled: May 24, 2006Date of Patent: January 29, 2013Assignee: UHDE GmbHInventors: Johannes Menzel, Georg Saecker
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Patent number: 8361424Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions in BS1: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution. According to the invention, an absorbent solution portion circulating in C1 is cooled in E2 in order to prevent demixing of the solution in column C1.Type: GrantFiled: September 23, 2009Date of Patent: January 29, 2013Assignee: IFPInventors: Pierre-Antoine Bouillon, Marc Jacquin, Ludovic Raynal
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Patent number: 8353980Abstract: An apparatus and process for removing acidic gases from flue gases produced by, for example, utility and industrial facilities. The acidic gases are removed as the flue gas flows upward through a contact zone within a passage, where the flue gas is contacted with an ammonium sulfate-containing scrubbing solution to absorb the acidic gases from the flue gas. The scrubbing solution and absorbed acidic gases therein are then accumulated, and ammonia and an oxygen-containing gas are injected into the accumulated scrubbing solution to react the absorbed acidic gases and produce ammonium sulfate. An acid solution is flowed across the passage above the contact zone of the passage, and the scrubbed flue gas is flowed upward through the acid solution to remove unreacted ammonia from the scrubbed flue gas. The acid solution is then removed from the passage after the acid solution has been contacted by the scrubbed flue gas.Type: GrantFiled: December 3, 2009Date of Patent: January 15, 2013Assignee: Marsulex Environmental Technologies CorporationInventor: David William Murphy
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Publication number: 20130008310Abstract: The present disclosure relates to a method for stripping acid gases, exemplified by carbon dioxide, from absorption media and/Alcohol selected from those having a boiling point lower than the boiling point of the absorption medium and/or adsorption medium.Type: ApplicationFiled: December 8, 2010Publication date: January 10, 2013Applicant: UNIVERSITY OF REGINAInventors: Adisorn Aroonwilas, Amornvadee Veawab
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Patent number: 8337792Abstract: Compositions and methods relating to aromatic imine compounds and methods of their use are described. The compounds are formed from aromatic aldehydes and amino or amino derivatives. The compounds and their derivatives are useful, for example, as hydrogen sulfide and mercaptan scavengers for use in both water and petroleum products.Type: GrantFiled: July 19, 2011Date of Patent: December 25, 2012Assignee: Guard Products LLCInventors: Gary Westlund, David Weller
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Patent number: 8337596Abstract: Hydrocarbyl substituted and unsubstituted polyethylene imines and polyacrylamide salts are absorption compositions and are useful in processes for the treatment of acid gas mixtures.Type: GrantFiled: August 1, 2006Date of Patent: December 25, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Frank Cheng-Yu Wang, Michael Siskin
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Patent number: 8323381Abstract: A two phase reactor includes a source of liquid reactant and a source of gas reactant. A chamber has an inlet coupled to the source of gas reactant and a flat jet nozzle coupled to the source of the liquid reactant.Type: GrantFiled: November 30, 2010Date of Patent: December 4, 2012Assignee: Neumann Systems Group, Inc.Inventors: William E. McDermott, David Kurt Neumann, Thomas Lee Henshaw
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Publication number: 20120297978Abstract: A method for removing impurities from a feed air gas stream prior to the stream being fed to a cryogenic distillation unit. The feed air gas stream contacts an ionic liquid which adsorbs the impurities from the air. The method can use one or more beds such as in pressure swing adsorption processes.Type: ApplicationFiled: December 2, 2010Publication date: November 29, 2012Inventors: Suling Zhai, Yaping Lu
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Patent number: 8303685Abstract: An improved acid gas regeneration and injection process wherein the separated acid gas stream emerging from a regenerator is compressed and injected into subsurface reservoir, the improvement comprising conducting the acid gas separation in the regenerator under pressure that exceeds 50 psia and does not exceed 300 psia.Type: GrantFiled: June 21, 2004Date of Patent: November 6, 2012Assignee: Dow Global Technologies LLCInventors: Craig N. Schubert, Timothy C. Frank
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Patent number: 8298321Abstract: A river water utilizing flue gas desulfurization system 10 according to an embodiment of the present invention includes: a pre-treatment facility 13 that removes humic substances in river water 11 to produce makeup water 12; and a desulfurization apparatus 17 that brings sulfur content in flue gas 15 into contact with limestone gypsum slurry 16 in an apparatus body 14. The pre-treatment facility 13 includes a flocculant mixing basin 22 in which a flocculant 21 is added to the river water 11 to flocculate and remove the humic substances contained in the river water 11; and an activated carbon absorption unit 23 in which the humic substances contained in the river water 11 are absorbed and removed by way of activated carbon.Type: GrantFiled: November 25, 2009Date of Patent: October 30, 2012Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Nobuyuki Ukai, Takashi Yoshimoto, Tatsuto Nagayasu, Susumu Okino
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Patent number: 8292988Abstract: The invention relates to a washing column (T) for implementing a physical gas washing. Gas (1) is sent from the bottom to the top and washing agent (2) is sent from the top to the bottom through the washing column. At least two washing sections (WS1, WS2) are arranged on top of one another in the washing column (T). The top section (WS2) is bounded at the bottom by a riser base (K), from which a portion of the washing agent that is charged into the top washing section can be introduced as washing agent into the lower washing section (WS1). Another portion of the washing agent can be removed from the washing column (T) via a lateral drain (4). The top washing section (WS2) is connected to the lower washing section (WS1) by an overflow (U), via which charged washing agent from the riser base (K) can be introduced into the lower washing section (WS1).Type: GrantFiled: September 28, 2007Date of Patent: October 23, 2012Assignee: Linde AktiengesellschaftInventor: Andreas Seliger
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Patent number: 8287626Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.Type: GrantFiled: January 18, 2008Date of Patent: October 16, 2012Assignee: Total S.A.Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
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Vapor-liquid contacting apparatuses having a secondary absorption zone with vortex contacting stages
Patent number: 8268049Abstract: Vapor-liquid contacting apparatuses comprising both a primary absorption zone and a secondary absorption zone comprising a plurality of vortex contacting stages are described. The apparatuses provide improved heat and mass transfer between vapor and liquid phases in processes such as absorption, to selectively solubilize contaminants (e.g., acid gases) from an impure vapor (e.g., sour natural gas). Vortex contacting stage(s) in a zone of vapor-liquid contacting, such as a secondary or finishing absorption zone, are used following bulk absorption in a primary or main absorption zone.Type: GrantFiled: March 31, 2010Date of Patent: September 18, 2012Assignee: UOP LLCInventor: Lev Davydov -
Patent number: 8262776Abstract: A system and method for producing biofuel from pollutant-fed algae are disclosed. Specifically, the system includes a scrubber with a chamber for receiving a pollutant-contaminated fluid stream. Further, a scrubber solution is received in the chamber for scrubbing the pollutant-contaminated fluid stream. Also, the system includes a bioreactor that is provided with an input port to receive the scrubber solution with pollutants for use as nutrients to support algae cell growth. Further, the system includes an algae separator that removes the algae from the bioreactor and a device for processing the algae into biofuel. In order to recycle the scrubber solution, the algae separator is in fluid communication with the scrubber. With this arrangement, the effluence from the bioreactor may be recycled for use as the scrubber solution.Type: GrantFiled: October 13, 2006Date of Patent: September 11, 2012Assignee: General AtomicsInventors: David A. Hazlebeck, Eric H. Dunlop
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Publication number: 20120222557Abstract: Some embodiments described herein relate to ionic liquids comprising an anion of a heteraromatic compound such as optionally substituted pyrrolide, optionally substituted pyrazolide, optionally substituted indolide, optionally substituted phospholide, or optionally substituted imidazolide. Methods and devices for gas separation or gas absorption related to these ionic liquids are also described herein.Type: ApplicationFiled: November 3, 2010Publication date: September 6, 2012Applicant: UNIVERSITY OF NOTRE DAME DU LACInventors: William F. Schneider, Joan F. Brennecke, Edward J. Maginn, Elaine Mindrup, Burcu Gurkan, Erica Price, Brett Goodrich
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Publication number: 20120216678Abstract: An absorbent composition for removing CO2 and/or H2S from a gas comprising a polyamine, a monoamine and water, wherein the polyamine comprises a polyamine having 3 to 5 amine functions and has a molecular weight of less than 200 g/mol; wherein the monoamine comprises a tertiary monoamine; and wherein the weight ratio of the polyamine having 3 to 5 amine functions to the tertiary monoamine is more than 1:1. A process wherein such an absorbent composition is used and a use of a tertiary monoamine as an accelerator for accelerating the removal of CO2 and/or H2S from a CO2 and/or H2S containing polyamine having 3 to 5 amine functions.Type: ApplicationFiled: August 11, 2010Publication date: August 30, 2012Inventors: Frank Haiko Geuzebroek, Armin Schneider, Renze Wijntje, Xiaohui Zhang
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Patent number: 8231713Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula R1O-(Alk-O)n—R2??(I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula R3NHR4OR6??(II) or at least one piperazine compound of formula wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl group having from 1Type: GrantFiled: August 16, 2010Date of Patent: July 31, 2012Assignee: Dow Global Technologies LLCInventors: Craig N. Schubert, Arnold C. Ashcraft
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Patent number: 8231706Abstract: A method for separating methane and carbon dioxide from biogas and a device are intended for purifying biogas, wherein carbon dioxide is separated off from the biogas. The method is distinguished by an energetically favorable mode of operation. The biogas is passed under atmospheric pressure and standard temperature into an absorption column. While the biogas ascends through a packed bed, which has a surface area of 600 to 1200 m2/m3, and at a space velocity of 5 to 40 Nm3/m3h, carbon dioxide present in the biogas is bound in a wash liquid by chemosorption. The purified methane gas is taken off at the top of the absorption column at a defined flow velocity. Carbon dioxide bound in the wash liquid is removed by desorption at a relatively high pressure of 2 to 30 bar and a temperature of at least 120° C. Biogas may be separated into methane and CO2.Type: GrantFiled: March 19, 2007Date of Patent: July 31, 2012Assignee: MT-Biomethan GmbHInventor: Lothar Günther
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Patent number: 8231719Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.Type: GrantFiled: June 12, 2006Date of Patent: July 31, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
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Publication number: 20120186993Abstract: A process for the absorption of one or more gas(es) selected from the group consisting of carbon dioxide, hydrogen sulfide, sulfur oxides, nitrogen oxides and carbon monoxide from a fluid, the process including: providing a fluid containing the selected gas(es); and an ionic liquid absorbent, the absorbent including the components: one or more anions; one or more metal species; and optionally one or more organic cations; and optionally one or more ligands; the absorbent components being selected such that the absorbent is in a liquid state at the operating temperature and pressure of the process; with the provisos that: when the anion contains in the same molecular entity: both an amine functional group and a sulfonate functional group; both an amine functional group and a carboxylate functional group; both a phosphine functional group and a sulfonate functional group; or both a phosphine functional group and a carboxylate functional group, the metal species is not an alkali metal or alkaline earth metal; theType: ApplicationFiled: July 29, 2010Publication date: July 26, 2012Applicant: COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATIONInventors: Junhua Huang, Thomas Rüther, Paul Feron, Zhengbo Zhang
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Publication number: 20120187046Abstract: Sulfur contaminants, such as elemental sulfur (S8), hydrogen sulfide and other sulfur components in fluids (e.g., air, natural gas, and other gases, as well as water and other liquids) are removed using a silicone-based chemical filter/bath. In one embodiment, a silicone-based chemical filter includes a membrane having a cross-linked silicone that is a reaction product of an olefin and a polyhydrosiloxane. For example, sulfur contaminants in air may be removed by passing the air through the membrane before the air enters a data center or other facility housing computer systems. In another embodiment, a silicone-based chemical bath includes a housing having an inlet port, an outlet port, and a chamber containing a silicone oil. For example, sulfur contaminants in air may be removed by passing the air through the silicone oil in the chamber before the air enters a data center or other facility housing computer systems.Type: ApplicationFiled: January 21, 2011Publication date: July 26, 2012Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III, Timothy J. Tofil
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Patent number: 8226754Abstract: An FGD system is provided which can be retrofitted on existing utility coal-fired boilers. The design is based on a horizontal co-current scrubber capable of generating a pressure rise across the absorber. Modifications to existing plant equipment are minimized by the co-current horizontal scrubber design. The system includes features, which eliminate much equipment typically associated with other FGD designs, and reduces the use of support equipment such as tanks, agitators, and pumps. It also minimizes or eliminates the need for new buildings.Type: GrantFiled: October 13, 2009Date of Patent: July 24, 2012Assignee: URS CorporationInventors: Jonas Klingspor, J. David Colley, Greg N. Brown
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Patent number: 8226748Abstract: A CO2 reducing system (10A) is constituted by a low-temperature CO2 reducing apparatus (11-1) that includes a low-temperature absorber (1006-1) that reduces at least one of CO2 and H2S by bringing flue gas (1002) including at least one of CO2 and H2S into contact with a low-temperature absorbing solution (1005-1), a low-temperature regenerator (1008-1) that regenerates a low-temperature rich solution (1007-1), a low-temperature rich-solution supply line (12-1) that feeds the low-temperature rich solution (1007-1) to the low-temperature regenerator (1008-1), and a low-temperature lean-solution supply line (13-1) that feeds a low-temperature lean solution (1009-1) to the low-temperature absorber (1006-1) from the low-temperature regenerator (1008-1); and a high-temperature CO2 reducing apparatus (11-2) that is arranged on a side at which the flue gas (1002) is discharged, and that has the same configuration as the low-temperature CO2 reducing apparatus (11-1).Type: GrantFiled: June 17, 2008Date of Patent: July 24, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Kouki Ogura, Yasuyuki Yagi
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Patent number: 8226842Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula R1O-(Alk-O)n—R2??(I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula R3NHR4OR6??(II) or at least one piperazine compound of formula wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl group having from 1Type: GrantFiled: August 16, 2010Date of Patent: July 24, 2012Assignee: Dow Global Technologies LLCInventors: Craig N. Schubert, Arnold C. Ashcraft
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Patent number: 8216346Abstract: The invention relates to a gas liquid contactor and effluent cleaning system and method and more particularly to an array of nozzles configured to produce uniformly spaced flat liquid jets with reduced linear stability. An embodiment of the invention is directed towards a stability unit used with nozzles of a gas liquid contactor and/or an enhancer for stable jet formation, and more particularly to reducing the stability of liquid jets formed from nozzles of the gas liquid contactor. Another aspect of the invention relates to operating the apparatus at a condition that reduces the stability of liquid jets, e.g., a droplet generator apparatus. Yet another aspect of the invention relates to operation of the apparatus with an aqueous slurry. Still another aspect of the invention is directed towards to an apparatus for substantially separating at least two fluids.Type: GrantFiled: November 19, 2010Date of Patent: July 10, 2012Assignee: Neumann Systems Group, Inc.Inventors: David Kurt Neumann, Andrew R. Awtry, Jason K. Brasseur, Keith R. Hobbs, Boris R. Nizamov, Thomas Lee Henshaw
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Publication number: 20120167766Abstract: A process and system for separating CO2 from a flue gas stream is disclosed. The process involves (a) contacting a flue gas stream containing water vapor and CO2 with an ionic absorbent under absorption conditions to absorb at least a portion of the CO2 from the flue gas stream and form a CO2-absorbent complex; wherein the ionic absorbent comprises a cation and an anion comprising an amine moiety; and (b) recovering a gaseous product having a reduced CO2 content.Type: ApplicationFiled: December 30, 2010Publication date: July 5, 2012Applicants: University of South Alabama, Chevron U.S.A.Inventors: Daniel Chinn, Russell Evan Cooper, Zunqing He, James H. Davis, JR., Kevin N. West, Hye Kyung Timken, Michael S. Driver
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Patent number: 8211213Abstract: The invention involves a process for maintaining a low level of carbon monoxide in a carbon dioxide product stream and also for keeping the carbon monoxide out of the fully shifted synthesis gas. The overall process is a process for treating both fully shifted and partially shifted or unshifted synthesis gas. The carbon monoxide is separately removed by a carbon monoxide stripping column and returned to the partially shifted or unshifted synthesis gas which can then undergo a shift reaction to convert the carbon monoxide to carbon dioxide.Type: GrantFiled: December 7, 2009Date of Patent: July 3, 2012Assignee: UOP LLCInventors: William J. Lechnick, Leonid Bresler, Nagaraju Palla
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Patent number: 8206489Abstract: The present invention relates to a method of deacidizing a gaseous effluent, wherein the following stages are carried out: a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds, b) separating the absorbent solution laden with acid compounds into two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds, c) regenerating the second fraction so as to release part of the acid compounds, d) mixing a predetermined amount of water with the first absorbent solution fraction obtained in stage b) or with the regenerated absorbent solution fraction obtained in stage c), then e) recycling the first absorbent solution fraction and the regenerated absorbent solution as the absorbent soluType: GrantFiled: December 19, 2006Date of Patent: June 26, 2012Assignee: Institut Francais du PetroleInventors: Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
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Publication number: 20120152119Abstract: A system and process are disclosed for selective removal and recovery of H2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.Type: ApplicationFiled: December 17, 2010Publication date: June 21, 2012Applicant: BATTELLE MEMORIAL INSTITUTEInventors: David J. Heldebrant, Phillip K. Koech, James E. Rainbolt, Mark D. Bearden, Feng Zheng
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Patent number: 8192530Abstract: A system (10) for regenerating a rich absorbent solution (26), the system including: an absorber (20) facilitating interaction between a process stream (22) and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream (28) and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid (60); and at least one mechanism (60a) to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator (34) regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.Type: GrantFiled: November 12, 2008Date of Patent: June 5, 2012Assignee: ALSTOM Technology LtdInventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala
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Publication number: 20120134905Abstract: A method of use of an ionic liquid for sorption of a gas having an electric multipole moment is provided, wherein the ionic liquid comprises an anion and a non-aromatic cation. In particular, the electric multipole moment may be an electric dipole moment and/or an electric quadrupole moment. The sorption may be an adsorption or an absorption. The ionic liquid may be a pure ionic liquid, i.e. a liquid substantially only containing anions and cations, while not containing other components, e.g. water. Alternatively a solution containing the ionic liquid and a solvent or further compound, e.g. water, may be used.Type: ApplicationFiled: June 22, 2010Publication date: May 31, 2012Applicant: VTU HOLDING GMBHInventor: Roland Kalb
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Patent number: 8172931Abstract: An absorbing tower is provided in its side wall with a gas entrance for introducing a combustion exhaust gas into the absorbing tower, and an absorbing liquid is sprayed from the nozzles of a spray header into the exhaust gas introduced to rise from the gas entrance. A trough is arranged in the side wall of the absorbing tower and above the gas entrance, and a nose having a horseshoe shape in a top plan view and extending into tower is disposed in the tower side wall portion of the gas entrance other than the portion arranging the trough and at the same or at substantially the same height as the portion of the trough. The absorbing liquid, which is sprayed from the nozzle and drops along the absorbing tower wall portion, is rescattered to the center portion of the absorbing tower excepting the entrance of the absorbing tower, so that the gas-liquid contact efficiency is improved while suppressing an increase in pressure loss, thereby to prevent the drift of the gas at the tower wall portion.Type: GrantFiled: September 19, 2007Date of Patent: May 8, 2012Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Takuro Ueda, Takanori Nakamoto, Atsushi Katagawa, Hajime Okura, Hiroshi Ishizaka
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Patent number: 8167975Abstract: A system is provided that prevents inhibition of adsorption of Hg and other heavy metals by activated carbon or other heavy metal adsorbent due to prior adsorption of sulfur trioxide (SO3) in an exhaust gas containing SO3. As it has been found that while SO3 is adsorbed, the adsorption of SO3 precedes the adsorption of Hg and other heavy metals onto activated carbon, a basic substance injection system is disposed along an exhaust gas flow channel at an upstream side of an activated carbon injection system, thereby attaining effective removal of Hg and other heavy metals from the exhaust gas by adsorption thereof onto surface pores of the activated carbon. The SO3 concentration after removal by basic substance conversion is computed from the SO3 concentration before removal, and the activated carbon injection rate can be controlled based on the concentration after removal.Type: GrantFiled: April 11, 2008Date of Patent: May 1, 2012Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Jun Shimamura, Takanori Nakamoto, Toshio Katsube, Hirofumi Kikkawa, Hiroyuki Nosaka, Takayuki Saitou, Yoshinori Taguchi, Hiroshi Ishizaka
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Patent number: 8152900Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.Type: GrantFiled: October 25, 2010Date of Patent: April 10, 2012Assignee: SpectraSensors, Inc.Inventors: Xin Zhou, Xiang Liu, Alfred Feitisch, Gregory M. Sanger
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Patent number: 8152903Abstract: Hindered cyclic polyamines and their salts are absorbents useful in acid gas treatment processes.Type: GrantFiled: July 21, 2006Date of Patent: April 10, 2012Assignee: ExxonMobile Research & Engineering CompanyInventors: Michael Siskin, Alan R Katritzky, Edmund J. Mozeleski, Frank Cheng-Yu Wang
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Patent number: 8147593Abstract: An absorbing solution according to the present invention is an absorbing solution that absorbs CO2 or H2S in gas or both of CO2 and H2S. The absorbing solution is formed by adding desirably 1 to 20 weight percent of tertiary monoamine to a secondary-amine composite absorbent such as a mixture of secondary monoamine and secondary diamine. Consequently, it is possible to control degradation in absorbing solution amine due to oxygen or the like in gas. As a result, it is possible to realize a reduction in an absorption loss, prevention of malfunction, and a reduction in cost. This absorbing solution is suitably used in an apparatus for removing CO2 or H2S or both of CO2 and H2S.Type: GrantFiled: April 3, 2006Date of Patent: April 3, 2012Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Tomio Mimura, Yasuyuki Yagi, Kouki Ogura, Masaki Iijima, Toru Takashina, Hiroshi Tanaka, Takuya Hirata
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Publication number: 20120012002Abstract: To develop a means for effectively utilize terpene compounds contained in tree leaves, whereby branches and leaves cut in tree thinning and pruning can be effectively utilized as a resource. For this purpose, provided are a monoterpene component-rich essential oil containing 90% or more of monoterpene components; a method for producing the monoterpene component-rich essential oil which includes subjecting coniferous leaves to microwave steam distillation and collecting a distillate thus obtained; and a method for removing environmental pollutants which includes bringing the monoterpene component-rich essential oil into contact with atmosphere containing the environmental pollutants.Type: ApplicationFiled: February 26, 2010Publication date: January 19, 2012Applicant: Japan Aroma Laboratory Co., Ltd.Inventors: Toshihiko Kaneko, Yuichi Tanaka, Tatsuro Ohira, Naoyuki Matsui
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Patent number: 8092582Abstract: An absorbing tower provided with plural spray headers (3) which each have a plurality of spray nozzles (5) and are arranged in a multi-stage state in the flow direction of exhaust gas, in which an absorption liquid containing a slurry of limestone or lime is sprayed through the nozzles (5) to absorb and remove sulfur oxide contained in exhaust gas, wherein each spray nozzle (5) is of an annular spray type (a hollow cone type) and the spray nozzles (5) in the neighborhood of the tower wall have such a structure that the fluid is sprayed radially at spray angles of 50 to 80° with the direction counter to the flow of exhaust gas as the center, while the nozzles (5) in the central part of the tower have such a structure that the fluid is sprayed radially at spray angles of 80 to 130° with the direction counter to the flow thereof as the center.Type: GrantFiled: March 27, 2007Date of Patent: January 10, 2012Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Takuro Ueda, Atsushi Katagawa, Hiroshi Ishizaka