Sulfur Or Sulfur Containing Compound Sorbed Patents (Class 95/235)
  • Patent number: 6368385
    Abstract: A process and apparatus for the purification of a gas, in particular natural gas, in order to eliminate mercaptans without the use of gas adsorption or cryogenic expansion processes. Natural gas, dried and cooled, is supplied to an absorption column under pressure, producing a head product of a purified gas, and a base product supplied to a fractionating column which separates the most volatile compounds, free from mercaptans, from a gasoline fraction of the natural gas. The mercaptans are eliminated at the head of at least one distillation column, producing a base end product consisting of a mixture of C5 hydrocarbons, heavier than and free from volatile mercaptans, partially mixed with the most volatile recompressed compounds of the natural gas. This mixture is cooled and sent by reflux to the absorption column.
    Type: Grant
    Filed: July 26, 2000
    Date of Patent: April 9, 2002
    Assignee: TECHNIP
    Inventor: Henri Paradowski
  • Patent number: 6365099
    Abstract: A process and system for reducing the concentration of odorous contaminants, primarily hydrogen sulfide, in the vapor spaces of sewage handling and treatment systems, primarily the vapor spaces of sewage trunk lines, by injecting a fine spray, mist or fog of a dilute solution of hydrogen peroxide and a base selected from a group consisting of sodium hydroxide, potassium hydroxide, ammonium hydroxide and sodium carbonate to mix intimately with the vapor flow. The peroxide and base solutions may be pre-mixed and diluted with water and injected through atomizing nozzles utilizing compressed air as an atomizing fluid. The system may also provide for separate storage of the peroxide and base solutions, mixing of the peroxide and base solutions with dilution water with in-line mixing devices and direct injection with or without compressed air atomization into the vapor space.
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: April 2, 2002
    Assignee: FMC Corporation
    Inventors: Harry M. Castrantas, Scott W. Duggan
  • Patent number: 6355092
    Abstract: The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapor) and/or water (vapor) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: March 12, 2002
    Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Ondersoek TMO
    Inventors: Albert Edward Jansen, Paul Hubert Maria Feron, Jan Hendrik Hanemaaijer, Piet Huisjes
  • Patent number: 6342091
    Abstract: A process for the removal of carbon dioxide, sulphur compounds, water and aromatic and higher aliphatic hydrocarbons from industrial gases. The sour gas components, water and hydrocarbons are removed from the gas to be treated by absorption at elevated operating pressure. At least one morpholine derivative is used as the absorbent. The absorbent laden with absorbed components is regenerated with the aid of a stripping gas. The stripping gas is generated by partial evaporation of the laden absorbent.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: January 29, 2002
    Assignee: Krupp Uhde GmbH
    Inventors: Johannes Menzel, Oliver Tondorf
  • Patent number: 6334886
    Abstract: A process is provided for removing CO2 and/or H2S from a gas mixture containing as impurities CO2 and/or H2S and at least one other impurity selected from the group consisting of a cyanide and ammonia. The process includes contacting at least a portion of the reflux stream from the overhead vapor from a stripping column of an acid gas removal solvent (i.e., alkanolamine) treatment plant with an anion exchange resin to remove corrosive impurities. The ion-exchanged reflux stream is then recycled to the top of the stripping column or into the bulk circulating acid gas removal solvent (i.e., alkanolamine) passing from the bottom of the stripping column.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: January 1, 2002
    Assignee: Air Products and Chemicals, Inc.
    Inventors: David Richard Barnes, Jr., Arthur Daniel Bixler
  • Patent number: 6306248
    Abstract: A method for treating diverse pulp and paper products to produce a homogenous cellulosic feedstock comprises the steps of feeding diverse pulp and paper products into a vessel, introducing steam into the vessel while agitating the products, purging the gases from the vessel while agitating the products, sealing the vessel so that the vessel is pressure tight, saturating the products with steam at sufficient temperature and pressure to expand molecular structure of the products, while agitating the products, depressurizing the vessel to further enhance the molecular expansion of the products, and discharging the processed products. Alternatively, the method can be performed without purging the gases, if the temperature in the range of about 287° F. to about 312° F., and the pressure is in the range of about 40 to 65 psig.
    Type: Grant
    Filed: November 20, 1997
    Date of Patent: October 23, 2001
    Assignee: The University of Alabama in Huntsville
    Inventor: Michael H. Eley
  • Patent number: 6289988
    Abstract: The present invention provides a process for the management of H2S containing gas streams and high alkalinity water streams in which process the H2S is selectively removed from the gas stream and combusted to form an SO2 rich waste gas stream. The SO2 gas stream is then scrubbed with the water stream to substantially remove the SO2 from the gas while subsequent treatment of the water such as softening or settling is improved.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: September 18, 2001
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ronald Damian Myers, John Brenton MacLeod, Norman A. Chambers, Mainak Ghosh
  • Patent number: 6290754
    Abstract: A regenerative process for deacidification of a gas containing CO2 and liquid hydrocarbons including contacting the gas to be treated, in an absorption zone, with an absorbent liquid including methyldiethanolamine (MDEA) and an accelerator of absorption of CO2 by the amine, thereby producing a treated gas with reduced CO2 content and an absorbent liquid loaded with CO2, subjecting the loaded absorbent liquid to a regeneration treatment to release CO2 which it has bound, to produce 1) at least one acid gas fraction rich in CO2 and 2) at least one regenerated absorbent liquid; and recycling into the absorption zone the at least one regenerated absorbent liquid, wherein the overall liquid hydrocarbon content in the gas to be deacidified containing CO2 is greater than 14 liters of liquid hydrocarbons per million standard cubic meters of gas, and the activator combined with methyldiethanolamine in the absorbent liquid brought into contact with the gas containing CO2 and liquid hydrocarbons consists of at least one
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: September 18, 2001
    Assignee: Elf Exploration Production
    Inventors: Jean-Louis Peytavy, Serge Capdeville, Herve Lacamoire
  • Patent number: 6291232
    Abstract: Anaerobic digestion system and process in which the raw digester gas containing methane and other gaseous components is cooled at atmospheric pressure in the presence of a liquid to a temperature at which the other gaseous components have a substantially higher solubility in the liquid than methane and are substantially all absorbed into the liquid, leaving pure, dry methane gas. That methane gas is then used in other parts of the system, including the digester and a refrigeration system for cooling the raw gas.
    Type: Grant
    Filed: October 8, 1999
    Date of Patent: September 18, 2001
    Inventor: Herman P. Miller, III
  • Patent number: 6284024
    Abstract: The use of a turbulent contactor to absorb a selected gas component from a gas stream. The invention particularly applies to a method of removing selected gas components from a gas stream which includes: bringing the gas stream into contact with a liquid including a solvent or a reagent for the selected gas component in a turbulent contactor, the contactor including a gas inlet, a liquid inlet, an outlet leading to a venturi passage and a tube extending from the outlet back upstream, the tube being perforated and/or being spaced from the periphery of the outlet; subjecting the gas stream and liquid to turbulent conditions in the contactor thereby causing the gas component to be absorbed by the solvent or reagent.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: September 4, 2001
    Assignee: Den norske stats oljeselskap a.s.
    Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Finn P. Nilsen, Harald Linga
  • Patent number: 6284023
    Abstract: A method for removing acid gas components from combustion gas and natural gas. The method includes bringing the gas mixture into contact with sea water and subjecting the gas mixture and sea water to turbulent mixing conditions. This causes the acid gas to be absorbed by the sea water. The sea water can be disposed of offshore without any detrimental effect on the environment.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: September 4, 2001
    Assignee: Den Norske Stats Oljeselskap A.S.
    Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Harald Linga, Finn P. Nilsen, Per H. Hanssen
  • Patent number: 6280505
    Abstract: A method for removing acid gas components from combustion gas and natural gas. The method includes bringing the gas mixture into contact with sea water and subjecting the gas mixture and sea water to turbulent mixing conditions. This causes the acid gas to be absorbed by the sea water. The sea water can be disposed of offshore without any detrimental effect on the environment.
    Type: Grant
    Filed: March 15, 2000
    Date of Patent: August 28, 2001
    Assignee: Den Norske Stats Oljeselskap A.S.
    Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Harald Linga, Finn P. Nilsen, Per H. Hanssen
  • Patent number: 6273940
    Abstract: A system for eliminating mist from a flue gas while providing air toxic control includes a wet scrubber housing having an inlet at one of the housing for the entry of the flue gas and an outlet at an opposite end of the housing for the exit of the flue gas. Sprayers are located in the housing for spraying the flue gas with a cleaning liquid in order to remove contaminants from the flue gas. At least one heat exchanger is located in the housing above the sprayers in order to remove entrained contaminants from the flue gas by cooling the flue gas. The flue gas is channeled from the inlet past the collection trays, sprayers and heat exchanger prior to exiting the housing through the outlet. A mist eliminator is also provided for eliminating mist from the flue gas.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: August 14, 2001
    Assignee: The Babcock & Wilcox Company
    Inventors: Gregory T. Bielawski, Pervaje A. Bhat, Dennis W. Johnson, Robert B. Myers
  • Patent number: 6245128
    Abstract: A process for the reclamation of spent aqueous alkanolamine solutions by contacting a spent aqueous alkanolamine solution with a strong base ion exchange resin for time sufficient to sorb from the aqueous alkanolamine solution at least a portion of the accumulated ions and after a high concentration of ions accumulate on the resin, regenerating the strong base ion exchange resin by: a) purging the resin with water or nitrogen, b) contacting the strong base ion exchange resin with a sodium chloride solution for a time sufficient to remove the ions, c) purging the resin to remove the sodium chloride solution, d) contacting the resin with an alkali metal hydroxide solution, preferably sodium hydroxide, for a time sufficient to convert the resin to a substantially hydroxide form; and e) purging the resin, wherein the ion sorption capacity of the resin is maintained at a substantially constant value.
    Type: Grant
    Filed: June 15, 1999
    Date of Patent: June 12, 2001
    Assignee: Mobil Oil Corporation
    Inventor: Joseph T. George, Jr.
  • Patent number: 6235961
    Abstract: An inline, high-shear mixer is provided in a cracked gas stream upstream of a caustic tower in an ethylene production unit. Spent caustic is withdrawn from the bottom of the caustic tower and pumped to the mixer, where the spent caustic mixes with and absorbs acid gas components from the cracked gas stream. The spent caustic is separated from the cracked gas, forming a partially treated cracked gas stream. The partially treated cracked gas stream is then fed to the caustic tower. Polymer deposition in the caustic tower is reduced because polymeric material is formed when the cracked gas stream is mixed with the spent caustic and is removed before the cracked gas stream is fed to the caustic tower.
    Type: Grant
    Filed: January 29, 1999
    Date of Patent: May 22, 2001
    Assignee: Stone & Webster Engineering Corporation
    Inventor: Sabah A. Kurukchi
  • Publication number: 20010001173
    Abstract: Method for purifying gas loaded with dust particles of various sizes, which method comprises the following steps:
    Type: Application
    Filed: November 30, 2000
    Publication date: May 17, 2001
    Inventors: Jan Pieter Lotens, Jacob Hendrik Obbo Hazewinkel, Abraham Barend Van Der Giesen
  • Patent number: 6210454
    Abstract: An apparatus for treating a gas containing hydrogen sulphide and sulphur dioxide, comprising a liquid-gas reactor-contactor (2), means (3) for supplying gas to be treated and means (1) for supplying an organic solvent containing a catalyst, means (25) for recovering sulphur an doutlet means (20) for a gaseous effluent containing sulphur in vapour form, the apparatus being characterized in that it comprises at least one means (7) for contacting and cooling the gaseous effluent, delivering a three-phase effluent, having an inlet connected to the effluent outlet means (20) and to means (6, 13) for recycling a cooling solvent, means (30) for separating said three-phase effluent connected to the cooling means, adapted to separate purified gas from sulphur and comprising means (17) for evacuating purified gas, means (15) for extracting sulphur and means (14) for recovering solvent connected to the means (6, 13) for recycling the cooling solvent.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: April 3, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Jean-Charles Viltard, Claude Dezael, Fabrice Lecomte
  • Patent number: 6203598
    Abstract: This invention relates to a flue gas treating process including a heat recovery step for recovering heat from flue gas by means of a heat exchanger (4) and thereby cooling the flue gas, and a subsequent absorption step for bringing the flue gas into gas-liquid contact with an absorbing fluid (D) in absorption towers (12, 13) so as to remove at least SO2 present in the flue gas by absorption into the absorbing fluid (D), which is characterized, for example, in that a powder addition step for spraying a powder collectable in the absorption step into the flue gas is provided prior to the heat recovery step. This invention makes it possible to provide a flue gas treating process in which a countermeasure against SO3 present in flue gas can be easily achieved without resorting to ammonia injection and the flue gas can further be purified without the disadvantage of causing the injected substance to remain in the treated flue gas.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: March 20, 2001
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shigeo Hasegawa, Naohiko Ukawa, Susumu Okino, Koichiro Iwashita, Kazuaki Kimura, Atsushi Yoshioka, Yoshimitsu Kawanishi, Shoichi Onishi, Toru Takashina, Toyoshi Nakagawa
  • Patent number: 6203599
    Abstract: The present invention provides a process for removing gas contaminants such as hydrogen sulfide and carbon dioxide from a product gas such as natural gas or synthesis gas. According to the invention the product gas is contacted with a solvent which includes dialkyl ethers of polyethylene glycols and water, and a high pressure recycle loop is utilized to desorb a portion the gas contaminants and co-absorbed product gas from the solvent. The solvent is provided with an amount of water sufficient to increase recovery of co-absorbed product gas while at the same time providing a reduced circulation rate requirement for the solvent and reduced re-compression and cooling requirements for the recycle gas.
    Type: Grant
    Filed: July 28, 1999
    Date of Patent: March 20, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Craig Norman Schubert, William I. Echt
  • Patent number: 6174510
    Abstract: A process for the absorbing of a hot, dry gas stream of sulfur trioxide (SO3) in a stream of strong sulfuric acid. The process includes the steps of passing the hot, dry gas stream of SO3 into a sulfuric acid absorption tower above a packed bed held within the tower and below a liquid collection floor. A stream of strong sulfuric acid is introduced into the tower above the packed bed and allowed to pass cocurrently downwardly through the packed bed with the stream of SO3, thereby allowing the SO3 to be absorbed in the stream of strong sulfuric acid. The resulting concentrated sulfuric acid passes through a packing support into a lower plenum and the spent gas is fed upwardly through a gas conduit to an upper plenum located above the liquid collection floor and from there through a mist eliminator.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: January 16, 2001
    Inventor: Marcos D. Riano
  • Patent number: 6174498
    Abstract: An odor control system and method for removing unwanted odorous airborne constituents in which the gas stream is flowed through a compact, boxlike housing having a plurality of sequentially communicating treatment chambers. Gas stream pretreatment is accomplished in a first chamber, in fluid communication with a sump, as the gas flows through a packed bed wetted by suitable chemical reagents. After pretreatment, the gas stream is passed through downstream chambers, also utilizing wetted packed beds. These chambers are in fluid communication with a second, separate sump. Because of the first chamber/separate sump combination, influent gas treatment, by stages, can be accomplished. In this manner, different, contemporaneous chemical treatments are possible, within the single housing, with different chemical reagents utilized as needed. Such treatments are possible even in cases where otherwise incompatible chemical reagents are used.
    Type: Grant
    Filed: April 11, 1997
    Date of Patent: January 16, 2001
    Assignee: US Filter/RJ Environmental, Inc.
    Inventors: Roop C. Jain, Martin Scanlan
  • Patent number: 6174507
    Abstract: The invention is a process for separating acid gases from synthesis gas and treating the resulting solids. A mixture comprising synthesis gas and acid gas is contacted with a fluid that reacts with said acid gas to form a particulate solid dispersed in a fluid. The slurry comprising fluid and particulate solid is filtered to separate the particulate solid from the fluid by means of a regenerable filter. The particulate solids are removed from the regenerable filter by back-washing with a back-washing fluid to form a pumpable slurry comprising a mixture of particulate solids and back-washing fluid. The slurry is gasified to form synthesis gas and vitrified solids.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: January 16, 2001
    Assignee: Texaco Inc.
    Inventors: Paul S. Wallace, Kay A. Johnson, Delome D. Fair
  • Patent number: 6162282
    Abstract: A method for determining the efficiency of a carbon filter used to absorb hydrocarbons from organic solvents. A sample of the solution, used to remove CO.sub.2 and H.sub.2 S from natural hydrocarbon gases, is taken after it has passed through the carbon filter. A solution of an internal standard and carbon disulfide is added to the sample to concentrate the hydrocarbons into the solution. A second sample taken from the solution containing the concentrated hydrocarbons and is passed through a gas chromatograph which has a fast temperature ramp to measure the peak areas of the hydrocarbons and the internal standard. The concentration of the measured hydrocarbons are determined by comparing the peak area counts against that of the internal standard.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: December 19, 2000
    Assignee: Mobil Oil Corporation
    Inventors: Clifford C. Walters, Constance L. Hellyer
  • Patent number: 6154909
    Abstract: In a method for suppressing the formation of sulfuric acid aerosols in exhaust gas purification systems, the exhaust gas is presprayed with water so that the temperature does not drop below the dew point of sulfuric acid in the exhaust gas, with this spraying taking place upstream from the gas scrubber, upstream from a prescrubber present in addition to the gas scrubber or upstream from a heat exchanger which is in turn upstream from the scrubber, and the gaseous sulfuric acid is absorbed by the water before the temperature drops below the dew point of the sulfuric acid.
    Type: Grant
    Filed: August 16, 1999
    Date of Patent: December 5, 2000
    Assignee: Preussen Electra Engineering GmbH
    Inventors: Hans-Joachim Dieckmann, Heinz Gutberlet
  • Patent number: 6149713
    Abstract: The dust concentration of the flue gas leaving an electrostatic precipitator and introduced into an absorption tower of a desulfurizer is adjusted to a level of 100 to 500 mg/Nm.sup.3. At the same time, a dust slurry having a higher dust concentration is separated and withdrawn from the slurry within the aforesaid absorption tower, and then subjected to a solid-liquid separation treatment. Thus, solid matter containing dust at a high concentration is extracted and discharged out of the system of the desulfurizer.
    Type: Grant
    Filed: November 13, 1998
    Date of Patent: November 21, 2000
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Eiji Ochi, Takeo Shinoda, Toru Takashina, Susumu Okino
  • Patent number: 6139605
    Abstract: A double-loop process for the removal of specified gas or gases from a process gas by absorption with a liquid absorbent for said specified gas or gases wherein the process gas is contacted counter-currently in a first absorption stage with semi-lean absorbent liquid and then in a second absorption stage with lean absorbent liquid to give a sweet process gas and the absorbed gases are stripped from the laden absorbent liquid in a first stage giving a semi-lean absorbent liquid. Part of the semi-lean absorbent is recycled to the first absorption stage while the remainder is subjected to further stripping by counter-current contact with an auxiliary gas that has a concentration of the specified gas or gases that is lower than the concentration of the specified gas or gases in the process gas to give the lean absorbent liquid which is recycled to the second absorption stage.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: October 31, 2000
    Assignee: Imperial Chemical Industries PLC
    Inventors: Peter John Herbert Carnell, Hiren Krishnakant Shethna, Gavin Paul Towler, Edwin Stephen Willis
  • Patent number: 6136071
    Abstract: A process for recovering volatile, generally bad smelling low molecular, low polar substances called VLC, contained in gas streams, by capturing the same by in contacting the gaseous environment with a calixarene or a resorcinol calixarene present in the form of particles, granules, as a coating or impregnation on or in a solid support, or as an organic or aqueous solution.
    Type: Grant
    Filed: August 27, 1998
    Date of Patent: October 24, 2000
    Assignee: Transdiffusia S.A.
    Inventors: Roger Lamartine, Philippe Choquard, Philippe Goreloff, Yvon Martelin
  • Patent number: 6102987
    Abstract: A process for the removal of CO.sub.2 and sulfur compounds from natural gas and raw synthesis gas wherein N-formylmorpholine and N-acetylmorpholine mixtures are used as the desorbent at temperatures between -20.degree. C. and +40.degree. C. at pressures of 10 to 150 bar in a scrubbing operation. The acid gases are removed from the absorbent by flashing and the regenerated absorbent is recycled to the absorbent.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: August 15, 2000
    Assignee: Krupp Uhde GmbH
    Inventors: Manfred Gross, Barbel Kolbe, Johannes Menzel, Werner Pohl
  • Patent number: 6102377
    Abstract: Sulfur oxides (SO.sub.x) are scrubbed from combustion effluents with economies in capital and operating costs by virtue of an arrangement of spray header piping and nozzles which permits ease of access for service with reduced spacing (e.g., 0.5 to 1.25 meters) between spray levels. At least two spray levels in a spray zone include a plurality of spray header pipes arranged parallel to the other spray header pipes within a spray level and vertically parallel to spray header pipes in at least one adjacent spray level. Each of the spray levels includes a plurality of spray nozzles extending from said spray headers. A majority of nozzles in a reference spray level are positioned such that lines drawn between them form a pattern of squares with the nozzles located at the corners of the squares. And, a majority of nozzles in an adjacent spray level are positioned over the centers of squares defined by four nozzles in the reference spray level.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: August 15, 2000
    Assignee: ABB Environmental Services, Division of ABB Flakt, Inc.
    Inventor: Joseph V. Doughty
  • Patent number: 6090356
    Abstract: This invention is an integrated process which removes acidic gases such as H.sub.2 S, COS and CO.sub.2 from raw synthesis gas. The H.sub.2 S and COS is concentrated and separately recovered. The separately recovered CO.sub.2 is used as a moderator with the purified syngas in a combustion turbine. The process comprises separating H.sub.2 S and COS from a raw synthesis gas by absorption with a liquid solvent, removing coabsorbed CO.sub.2 by stripping the solvent with nitrogen, separating the H.sub.2 S and COS from the solvent and recovering sulfur from the H.sub.2 S and COS. The energy value of the CO.sub.2 and its value as a diluent in reducing NO.sub.x is recovered by using the CO.sub.2 as a moderator during combustion of the purified synthesis gas in a gas turbine.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: July 18, 2000
    Assignee: Texaco Inc.
    Inventors: Frederick C. Jahnke, William P. Volk
  • Patent number: 6083302
    Abstract: Sulfur oxides (SO.sub.x) are scrubbed from combustion effluents with greater system reliability when an improved mist eliminator of the invention is employed. The mist eliminator has at least one section, preferably two sections, with two passes followed by an extended trailing edge. This design is shown in tests to be as effective as four pass designs, while being easier to clean. Encrustation and plugging are greatly reduced.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: July 4, 2000
    Assignee: ABB Environmental Systems, division of ABB Flakt, Inc.
    Inventors: Wesley P. Bauver, II, David K. Anderson, William H. Kingston
  • Patent number: 6051055
    Abstract: An exhaust gas desulfurization system includes a spray pipe which is provided with a plurality of nozzles in the lengthwise direction and whose one end is closed and arranged horizontally in an absorption tower through which the exhaust gas passes vertically. Absorbent slurry is fed from the other end of the spray pipe and is injected upward from the nozzles, by which absorbent slurry is brought into contact with the exhaust gas to perform treatment in the absorption tower. The flow passage on the closed end side of the pipe is present in a shape such that the flow passage cross-sectional area decreases toward the closed end.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: April 18, 2000
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Naohiko Ukawa, Toru Takashina, Susumu Okino, Kazuaki Kimura, Koichiro Iwashita, Kouji Ikeda, Heiji Tanaka
  • Patent number: 6017384
    Abstract: A nozzle arrangement in which the nozzles have a scrubber, especially for flow gas desulfurization, are laid in accordance with the following: (a) liquid concentrations of a component to be absorbed from a gas stream scrubbed in the column are measured above a plane of the nozzle assembly at N locations of a grid of equal area elements of a cross section of the column; (b) the N concentration values are compared with a predetermined value; (c) upon deviation of a measured concentration value from the predetermined value, a position of at least one of the nozzles is varied by selection of a length and location of an intermediate pipe section connecting the one of the nozzles to a respective branch pipe laterally thereon; and (d) repeating (a) through (c) until the concentration values measured above the plane are approximately equal except for at a wall region of the column.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: January 25, 2000
    Assignee: Lurgi Lentjes Bischoff GmbH
    Inventor: Theo Risse
  • Patent number: 6007604
    Abstract: A nozzle arrangement for a scrubbing column for a flue gas in desulfurization, in which the scrubbing column has a sump, a baffle-free zone above the sump and a nozzle arrangement above the absorption zone. The nozzles, preferably by selective connection of intermediate pipe sections are connected to a branch pipe system extending from a distributor. Flow density profiles are formed in predetermined cross sectional planes of the scrubbing column by the spray cones of the nozzles. In each of these cross sectional planes, the flow density profiles of different spray cones are superimposed on one another. The flow density profiles of different cross sectional planes are superimposed upon projection of them onto a one of the planes to form a flow density complete profile in this one plane over the entire cross section of the scrubbing column.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: December 28, 1999
    Assignee: Lurgi Lentjes Bischoff GmbH
    Inventor: Theo Risse
  • Patent number: 6001153
    Abstract: A method of treating a fluid containing at least methane and at least one acid gas and producing the acid gas or gases in liquid form. The method includes a step of regenerating the solvent, operated at a pressure whose value is at least equal to the bubble pressure of the mixture of acid gases produced in liquid form, a step in which the gaseous fraction from the regeneration step is rectified in a contact zone by separating at least some of the solvent from the gaseous fraction, a step in which the gaseous fraction from the modification step is cooled to a given temperature to cause at least some of the gaseous faction to condense forming at least one liquid fraction enriched with liquid acid gases and a step during which the liquid fraction of gases is separated from the remaining gaseous fraction.
    Type: Grant
    Filed: March 13, 1998
    Date of Patent: December 14, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Etienne Lebas, Alexandre Rojey
  • Patent number: 6001154
    Abstract: The present invention provides a gas-liquid contact apparatus which can make the equipment more compact and reduce the cost while achieving high gas-liquid contact efficiency. In the apparatus of the present invention, an oxidation tank (2) is installed in proximity to an absorption tower (1), and an absorbing fluid (3) is stored in this oxidation tank (2). The level H of the absorbing fluid (3) is determined so as to be above the position of nozzles (7), whereby the absorbing fluid is spouted upward from the nozzles (7). Flue gas is introduced into the absorption tower (1) from a flue gas inlet section (8) and made to flow upward at a high velocity, so that the peaks of the spouted streams are raised above level H. The absorbing fluid (3) is caught by catcher device (11) installed at a position above level H, and returned to the oxidation tank (2) through a circulation pipe (12). An air pipe (20) is connected to the circulation pipe (12) so as to suck in air.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: December 14, 1999
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shinichiro Kotake, Kazuaki Kimura, Eiji Ochi, Toru Takashina, Susumu Okino
  • Patent number: 5976222
    Abstract: A process for the separation and recovery of fluorochemicals from a gas stream containing a diluent gas and fluorochemicals by contact of the gas stream with a membrane system in combination with an adsorption system, the adsorption system used either before or after the membrane system.
    Type: Grant
    Filed: March 23, 1998
    Date of Patent: November 2, 1999
    Assignee: Air Products and Chemicals, Inc.
    Inventors: James Hsu-Kuang Yang, Iosif Chernyakov, Thomas Hsiao-Ling Hsiung, Alexander Schwarz
  • Patent number: 5968346
    Abstract: A hydroprocessing process includes two hydroprocessing reaction stages, both of which produce a liquid and a vapor effluent, and a liquid-vapor contacting stage. The first stage vapor effluent contains impurities, such as heteroatom compounds, which are removed from the vapor by contact with processed liquid effluent derived from one or both reaction stages and, optionally, also liquid recovered from processed vapor. The first and contact stage liquid effluents are passed into the second stage to finish the hydoprocessing. The contact and second stage vapor effluents are cooled to recover additional hydroprocessed product liquid.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: October 19, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Henry Jung, Ramesh Gupta, Edward S. Ellis, William E. Lewis
  • Patent number: 5964923
    Abstract: A process train for treating a gas stream containing methane, nitrogen, and at least one of water vapor, acid gas, C.sub.3+ hydrocarbons and aromatic hydrocarbons, the gas stream typically, but not necessarily, being natural gas. The treatment train includes separation of methane from nitrogen by means of membranes that preferentially permeate methane and reject nitrogen. Preferred processes include both a dehydration step and an NGL removal step to treat the gas before it passes to the methane/nitrogen membrane separation step. The process train can also include additional steps, such as an acid gas removal step, or a cryogenic methane/nitrogen separation step.
    Type: Grant
    Filed: July 14, 1997
    Date of Patent: October 12, 1999
    Assignee: Membrane Technology and Research, Inc.
    Inventor: Kaaeid A. Lokhandwala
  • Patent number: 5961837
    Abstract: Water to be utilized is reacted with soda ash and lime to produce a less corrosive and foulant water. Reaction sludges are fed to a desulfurization unit, where SO.sub.x, NO.sub.x and CO.sub.2 abatement occurs; other industrial waste sludges and/or waters and/or gases can also be utilized in such connection. FIG. 1 is one of the possible process schemes of present invention.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: October 5, 1999
    Inventors: Marcello Ferrara, Maria Gabriella Scopelliti
  • Patent number: 5928413
    Abstract: This invention provides a flue gas treating system and process which include a counterflow absorption tower and which can reduce the ammonia concentration in the treated flue gas to a low level.
    Type: Grant
    Filed: September 11, 1997
    Date of Patent: July 27, 1999
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Eiji Ochi, Kiyoshi Okazoe, Toru Takashina
  • Patent number: 5879433
    Abstract: One or more contaminants selected from the group consisting of acidic gases, inert particulates, and mixtures thereof are removed from steam by contacting the contaminated steam with a nonaqueous sorbent such as crystalline molecular sieves, silica gels, soda ash, carbonaceous adsorbents, and amine liquid ion exchange resins.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: March 9, 1999
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, Thomas S. Powell
  • Patent number: 5861051
    Abstract: This invention relates to a process for the separation of carbon dioxide and hydrogen sulfide from gases using a promoted methyldiethanolamine (MDEA) solution. In one broad respect, this invention is a gas separation process, including contacting an aqueous treating solution with a sour gas stream that contains carbon dioxide and hydrogen sulfide under conditions such that the gas stream is sweetened, wherein the aqueous treating solution contains methyldiethanol amine and 2-(2-aminoethoxy)ethanol in a ratio of at least about 2:1; and wherein the process is conducted in the absence of a reclamation step. By practice of this invention, the amount of 2-(2-aminoethoxy)ethanol that is converted to urea(bis-(2-hydroxyethoxyethyl)urea (BHEEU)) is minimized which obviates the need for a reclamation (regeneration) unit.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: January 19, 1999
    Assignee: Huntsman Petrochemical Corporation
    Inventors: James E. Critchfield, Wei-Yang Su, Thomas J. Kenney, Patrick E. Holub
  • Patent number: 5851265
    Abstract: A process for the selective removal and recovery of sulfur dioxide from effluent gases is disclosed. The sulfur dioxide is recovered in a sulfur dioxide absorption/desorption cycle which utilizes a liquid solvent to selectively absorb sulfur dioxide from the effluent gas. The liquid solvent includes an organic phosphorous compound selected from phosphate triesters, phosphonate diesters, phosphinate monoesters and mixtures thereof. Preferably, the liquid solvent includes phosphonate diesters of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently aryl or C.sub.1 to C.sub.8 alkyl. The organic phosphonate diesters are substantially water immiscible, the solubility of water in the organic phosphonate diester being less than about 10 weight percent at 25.degree. C., and have a vapor pressure less than about 1 Pa at 50.degree. C. In accordance with a preferred embodiment, the liquid solvent include dibutyl butyl phosphonate.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 22, 1998
    Assignee: Monsanto Company
    Inventors: Brian M. Burmaster, Donald R. McAlister
  • Patent number: 5797981
    Abstract: A method of treating a gas, for example, natural gas containing at least one hydrocarbon and at least one acid gas to remove the acid gas from the natural gas and to produce at least one concentrated acid gas, wherein the gas is subjected to at least two stages of absorption using polar solvents having different properties.
    Type: Grant
    Filed: November 7, 1997
    Date of Patent: August 25, 1998
    Assignee: Intitut Francais du Petrole
    Inventors: Jean-Claude Collin, Joseph Larue, Alexandre Rojey
  • Patent number: 5785901
    Abstract: An object of this invention is to provide a gas-liquid contact apparatus for use in wet flue gas desulfurizers and the like which is equipped with lightweight and inexpensive header pipes having excellent wear resistance and corrosion resistance and hence exhibits high reliability and economical efficiency. To this end, there is provided a gas-liquid contact apparatus wherein one or more header pipes having attached thereto a plurality of spray nozzles for spouting a slurry upward are disposed in the main body of a tower through which a gas flows, characterized in that the header pipes are made of a fiber-reinforced resin composite material and the outer surface thereof or the outer and inner surfaces thereof are formed of a corrosion-resistant and wear-resistant layer of a resin containing ceramic particles.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: July 28, 1998
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shigeo Hasegawa, Noohiko Ukawa, Kenji Iwasaki, Tamotsu Higuchi, Koichiro Iwashita
  • Patent number: 5782958
    Abstract: A process for the dehydration, deacidification and stripping of a gas, characterized in that:(a) at least one fraction of the gas is contacted with an aqueous phase containing methanol, the resultant gas being thus charged with methanol being withdrawn from stage (a);(b) the gas withdrawn from stage (a) is contacted with a mixture of solvents comprising methanol, water, and a solvent heavier than methanol, the gas leaving stage (b) being thus at least in part freed of the acid gases which it contained initially;(c) the mixture of solvent obtained from stage (b) is at least in part generated by special reduction and/or heating while liberating at least part of the acid gases, the mixture of solvent being at least partially regenerated, or being at the outlet of stage (c) recycled through stage (b); and(d) the gas obtained from (stage b) is refrigerated while producing at least an aqueous phase containing methanol which is at least in part recycled through stage (a).
    Type: Grant
    Filed: December 30, 1996
    Date of Patent: July 21, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Alexandre Rojey, Etienne Lebas, Joseph Larue, Ari Minkkinen
  • Patent number: 5753012
    Abstract: A method of operating an apparatus for the cleaning of industrial waste gases and especially power plant flue gases. The gases are fed through a quencher to a first scrubber with its own recirculation and upstream of a second scrubber having its own recirculation and aerosols of halogen compounds which are eliminated by providing the quencher is part of a prescrubber or by forming the downstream scrubber with a wet electrostatic precipitator.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: May 19, 1998
    Assignee: Krupp Koppers GmbH
    Inventors: Bernhard Firnhaber, Michael Lang, Cort Starck, Wolfgang Schulte
  • Patent number: 5735936
    Abstract: The process comprises a cold absorption step 2 for removing acid gas from natural gas using a solvent phase at a pressure P.sub.2 which delivers a purified gas 5; a step for depressurizing and separating resultant acidic solvent phase containing hydrocarbons (lines 4, 11), at a pressure P.sub.12 which is lower than pressure P.sub.2 in a column-heat exchanger 12 which delivers a purified gaseous effluent 13 overhead and a further solvent phase at the bottom (line 17) which is enriched in hydrogen sulphide; and a solvent phase regeneration step carried out in a distillation column 18 at a pressure P.sub.18 and no higher than pressure P.sub.12. A gas 29 containing essentially hydrogen sulphide which is depleted in hydrocarbons is recovered from column 18 and is a suitable feed for a Claus plant for eliminating H.sub.2 S. The regenerated hot solvent phase 20 indirectly exchanges heat with the cold acidic solvent phase from absorber 2 or separator 6. It is then recycled to the absorbent after cooling.
    Type: Grant
    Filed: April 18, 1996
    Date of Patent: April 7, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Ari Minkkinen, Joseph Larue, Pierre Capron
  • Patent number: 5728186
    Abstract: Fluid gases are stripped clean of gaseous and particulate pollutants as they pass rapidly up the stack of an industrial or electric power generation plant by a battery of rapidly rotated air foil spokes arrayed in two sets interleaved and revolving around a common central axis, a single motor providing the power that maintains the cleaning operation as long as flue gas flows toward discharge to the atmosphere.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: March 17, 1998
    Inventor: Kjartan A. Jonsson