Sulfur Or Sulfur Containing Compound Sorbed Patents (Class 95/235)
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Patent number: 6368385Abstract: A process and apparatus for the purification of a gas, in particular natural gas, in order to eliminate mercaptans without the use of gas adsorption or cryogenic expansion processes. Natural gas, dried and cooled, is supplied to an absorption column under pressure, producing a head product of a purified gas, and a base product supplied to a fractionating column which separates the most volatile compounds, free from mercaptans, from a gasoline fraction of the natural gas. The mercaptans are eliminated at the head of at least one distillation column, producing a base end product consisting of a mixture of C5 hydrocarbons, heavier than and free from volatile mercaptans, partially mixed with the most volatile recompressed compounds of the natural gas. This mixture is cooled and sent by reflux to the absorption column.Type: GrantFiled: July 26, 2000Date of Patent: April 9, 2002Assignee: TECHNIPInventor: Henri Paradowski
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Patent number: 6365099Abstract: A process and system for reducing the concentration of odorous contaminants, primarily hydrogen sulfide, in the vapor spaces of sewage handling and treatment systems, primarily the vapor spaces of sewage trunk lines, by injecting a fine spray, mist or fog of a dilute solution of hydrogen peroxide and a base selected from a group consisting of sodium hydroxide, potassium hydroxide, ammonium hydroxide and sodium carbonate to mix intimately with the vapor flow. The peroxide and base solutions may be pre-mixed and diluted with water and injected through atomizing nozzles utilizing compressed air as an atomizing fluid. The system may also provide for separate storage of the peroxide and base solutions, mixing of the peroxide and base solutions with dilution water with in-line mixing devices and direct injection with or without compressed air atomization into the vapor space.Type: GrantFiled: November 12, 1998Date of Patent: April 2, 2002Assignee: FMC CorporationInventors: Harry M. Castrantas, Scott W. Duggan
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Patent number: 6355092Abstract: The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapor) and/or water (vapor) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.Type: GrantFiled: November 9, 1999Date of Patent: March 12, 2002Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Ondersoek TMOInventors: Albert Edward Jansen, Paul Hubert Maria Feron, Jan Hendrik Hanemaaijer, Piet Huisjes
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Patent number: 6342091Abstract: A process for the removal of carbon dioxide, sulphur compounds, water and aromatic and higher aliphatic hydrocarbons from industrial gases. The sour gas components, water and hydrocarbons are removed from the gas to be treated by absorption at elevated operating pressure. At least one morpholine derivative is used as the absorbent. The absorbent laden with absorbed components is regenerated with the aid of a stripping gas. The stripping gas is generated by partial evaporation of the laden absorbent.Type: GrantFiled: January 21, 2000Date of Patent: January 29, 2002Assignee: Krupp Uhde GmbHInventors: Johannes Menzel, Oliver Tondorf
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Patent number: 6334886Abstract: A process is provided for removing CO2 and/or H2S from a gas mixture containing as impurities CO2 and/or H2S and at least one other impurity selected from the group consisting of a cyanide and ammonia. The process includes contacting at least a portion of the reflux stream from the overhead vapor from a stripping column of an acid gas removal solvent (i.e., alkanolamine) treatment plant with an anion exchange resin to remove corrosive impurities. The ion-exchanged reflux stream is then recycled to the top of the stripping column or into the bulk circulating acid gas removal solvent (i.e., alkanolamine) passing from the bottom of the stripping column.Type: GrantFiled: May 12, 2000Date of Patent: January 1, 2002Assignee: Air Products and Chemicals, Inc.Inventors: David Richard Barnes, Jr., Arthur Daniel Bixler
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Patent number: 6306248Abstract: A method for treating diverse pulp and paper products to produce a homogenous cellulosic feedstock comprises the steps of feeding diverse pulp and paper products into a vessel, introducing steam into the vessel while agitating the products, purging the gases from the vessel while agitating the products, sealing the vessel so that the vessel is pressure tight, saturating the products with steam at sufficient temperature and pressure to expand molecular structure of the products, while agitating the products, depressurizing the vessel to further enhance the molecular expansion of the products, and discharging the processed products. Alternatively, the method can be performed without purging the gases, if the temperature in the range of about 287° F. to about 312° F., and the pressure is in the range of about 40 to 65 psig.Type: GrantFiled: November 20, 1997Date of Patent: October 23, 2001Assignee: The University of Alabama in HuntsvilleInventor: Michael H. Eley
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Patent number: 6289988Abstract: The present invention provides a process for the management of H2S containing gas streams and high alkalinity water streams in which process the H2S is selectively removed from the gas stream and combusted to form an SO2 rich waste gas stream. The SO2 gas stream is then scrubbed with the water stream to substantially remove the SO2 from the gas while subsequent treatment of the water such as softening or settling is improved.Type: GrantFiled: March 24, 2000Date of Patent: September 18, 2001Assignee: ExxonMobil Research and Engineering CompanyInventors: Ronald Damian Myers, John Brenton MacLeod, Norman A. Chambers, Mainak Ghosh
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Patent number: 6290754Abstract: A regenerative process for deacidification of a gas containing CO2 and liquid hydrocarbons including contacting the gas to be treated, in an absorption zone, with an absorbent liquid including methyldiethanolamine (MDEA) and an accelerator of absorption of CO2 by the amine, thereby producing a treated gas with reduced CO2 content and an absorbent liquid loaded with CO2, subjecting the loaded absorbent liquid to a regeneration treatment to release CO2 which it has bound, to produce 1) at least one acid gas fraction rich in CO2 and 2) at least one regenerated absorbent liquid; and recycling into the absorption zone the at least one regenerated absorbent liquid, wherein the overall liquid hydrocarbon content in the gas to be deacidified containing CO2 is greater than 14 liters of liquid hydrocarbons per million standard cubic meters of gas, and the activator combined with methyldiethanolamine in the absorbent liquid brought into contact with the gas containing CO2 and liquid hydrocarbons consists of at least oneType: GrantFiled: December 20, 1999Date of Patent: September 18, 2001Assignee: Elf Exploration ProductionInventors: Jean-Louis Peytavy, Serge Capdeville, Herve Lacamoire
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Patent number: 6291232Abstract: Anaerobic digestion system and process in which the raw digester gas containing methane and other gaseous components is cooled at atmospheric pressure in the presence of a liquid to a temperature at which the other gaseous components have a substantially higher solubility in the liquid than methane and are substantially all absorbed into the liquid, leaving pure, dry methane gas. That methane gas is then used in other parts of the system, including the digester and a refrigeration system for cooling the raw gas.Type: GrantFiled: October 8, 1999Date of Patent: September 18, 2001Inventor: Herman P. Miller, III
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Patent number: 6284024Abstract: The use of a turbulent contactor to absorb a selected gas component from a gas stream. The invention particularly applies to a method of removing selected gas components from a gas stream which includes: bringing the gas stream into contact with a liquid including a solvent or a reagent for the selected gas component in a turbulent contactor, the contactor including a gas inlet, a liquid inlet, an outlet leading to a venturi passage and a tube extending from the outlet back upstream, the tube being perforated and/or being spaced from the periphery of the outlet; subjecting the gas stream and liquid to turbulent conditions in the contactor thereby causing the gas component to be absorbed by the solvent or reagent.Type: GrantFiled: March 15, 2000Date of Patent: September 4, 2001Assignee: Den norske stats oljeselskap a.s.Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Finn P. Nilsen, Harald Linga
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Patent number: 6284023Abstract: A method for removing acid gas components from combustion gas and natural gas. The method includes bringing the gas mixture into contact with sea water and subjecting the gas mixture and sea water to turbulent mixing conditions. This causes the acid gas to be absorbed by the sea water. The sea water can be disposed of offshore without any detrimental effect on the environment.Type: GrantFiled: March 15, 2000Date of Patent: September 4, 2001Assignee: Den Norske Stats Oljeselskap A.S.Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Harald Linga, Finn P. Nilsen, Per H. Hanssen
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Patent number: 6280505Abstract: A method for removing acid gas components from combustion gas and natural gas. The method includes bringing the gas mixture into contact with sea water and subjecting the gas mixture and sea water to turbulent mixing conditions. This causes the acid gas to be absorbed by the sea water. The sea water can be disposed of offshore without any detrimental effect on the environment.Type: GrantFiled: March 15, 2000Date of Patent: August 28, 2001Assignee: Den Norske Stats Oljeselskap A.S.Inventors: Bernt H. Torkildsen, Martin Sigmundstad, Harald Linga, Finn P. Nilsen, Per H. Hanssen
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Patent number: 6273940Abstract: A system for eliminating mist from a flue gas while providing air toxic control includes a wet scrubber housing having an inlet at one of the housing for the entry of the flue gas and an outlet at an opposite end of the housing for the exit of the flue gas. Sprayers are located in the housing for spraying the flue gas with a cleaning liquid in order to remove contaminants from the flue gas. At least one heat exchanger is located in the housing above the sprayers in order to remove entrained contaminants from the flue gas by cooling the flue gas. The flue gas is channeled from the inlet past the collection trays, sprayers and heat exchanger prior to exiting the housing through the outlet. A mist eliminator is also provided for eliminating mist from the flue gas.Type: GrantFiled: December 1, 1995Date of Patent: August 14, 2001Assignee: The Babcock & Wilcox CompanyInventors: Gregory T. Bielawski, Pervaje A. Bhat, Dennis W. Johnson, Robert B. Myers
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Patent number: 6245128Abstract: A process for the reclamation of spent aqueous alkanolamine solutions by contacting a spent aqueous alkanolamine solution with a strong base ion exchange resin for time sufficient to sorb from the aqueous alkanolamine solution at least a portion of the accumulated ions and after a high concentration of ions accumulate on the resin, regenerating the strong base ion exchange resin by: a) purging the resin with water or nitrogen, b) contacting the strong base ion exchange resin with a sodium chloride solution for a time sufficient to remove the ions, c) purging the resin to remove the sodium chloride solution, d) contacting the resin with an alkali metal hydroxide solution, preferably sodium hydroxide, for a time sufficient to convert the resin to a substantially hydroxide form; and e) purging the resin, wherein the ion sorption capacity of the resin is maintained at a substantially constant value.Type: GrantFiled: June 15, 1999Date of Patent: June 12, 2001Assignee: Mobil Oil CorporationInventor: Joseph T. George, Jr.
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Patent number: 6235961Abstract: An inline, high-shear mixer is provided in a cracked gas stream upstream of a caustic tower in an ethylene production unit. Spent caustic is withdrawn from the bottom of the caustic tower and pumped to the mixer, where the spent caustic mixes with and absorbs acid gas components from the cracked gas stream. The spent caustic is separated from the cracked gas, forming a partially treated cracked gas stream. The partially treated cracked gas stream is then fed to the caustic tower. Polymer deposition in the caustic tower is reduced because polymeric material is formed when the cracked gas stream is mixed with the spent caustic and is removed before the cracked gas stream is fed to the caustic tower.Type: GrantFiled: January 29, 1999Date of Patent: May 22, 2001Assignee: Stone & Webster Engineering CorporationInventor: Sabah A. Kurukchi
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Publication number: 20010001173Abstract: Method for purifying gas loaded with dust particles of various sizes, which method comprises the following steps:Type: ApplicationFiled: November 30, 2000Publication date: May 17, 2001Inventors: Jan Pieter Lotens, Jacob Hendrik Obbo Hazewinkel, Abraham Barend Van Der Giesen
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Patent number: 6210454Abstract: An apparatus for treating a gas containing hydrogen sulphide and sulphur dioxide, comprising a liquid-gas reactor-contactor (2), means (3) for supplying gas to be treated and means (1) for supplying an organic solvent containing a catalyst, means (25) for recovering sulphur an doutlet means (20) for a gaseous effluent containing sulphur in vapour form, the apparatus being characterized in that it comprises at least one means (7) for contacting and cooling the gaseous effluent, delivering a three-phase effluent, having an inlet connected to the effluent outlet means (20) and to means (6, 13) for recycling a cooling solvent, means (30) for separating said three-phase effluent connected to the cooling means, adapted to separate purified gas from sulphur and comprising means (17) for evacuating purified gas, means (15) for extracting sulphur and means (14) for recovering solvent connected to the means (6, 13) for recycling the cooling solvent.Type: GrantFiled: May 3, 1999Date of Patent: April 3, 2001Assignee: Institut Francais du PetroleInventors: Jean-Charles Viltard, Claude Dezael, Fabrice Lecomte
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Patent number: 6203598Abstract: This invention relates to a flue gas treating process including a heat recovery step for recovering heat from flue gas by means of a heat exchanger (4) and thereby cooling the flue gas, and a subsequent absorption step for bringing the flue gas into gas-liquid contact with an absorbing fluid (D) in absorption towers (12, 13) so as to remove at least SO2 present in the flue gas by absorption into the absorbing fluid (D), which is characterized, for example, in that a powder addition step for spraying a powder collectable in the absorption step into the flue gas is provided prior to the heat recovery step. This invention makes it possible to provide a flue gas treating process in which a countermeasure against SO3 present in flue gas can be easily achieved without resorting to ammonia injection and the flue gas can further be purified without the disadvantage of causing the injected substance to remain in the treated flue gas.Type: GrantFiled: February 8, 1999Date of Patent: March 20, 2001Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shigeo Hasegawa, Naohiko Ukawa, Susumu Okino, Koichiro Iwashita, Kazuaki Kimura, Atsushi Yoshioka, Yoshimitsu Kawanishi, Shoichi Onishi, Toru Takashina, Toyoshi Nakagawa
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Patent number: 6203599Abstract: The present invention provides a process for removing gas contaminants such as hydrogen sulfide and carbon dioxide from a product gas such as natural gas or synthesis gas. According to the invention the product gas is contacted with a solvent which includes dialkyl ethers of polyethylene glycols and water, and a high pressure recycle loop is utilized to desorb a portion the gas contaminants and co-absorbed product gas from the solvent. The solvent is provided with an amount of water sufficient to increase recovery of co-absorbed product gas while at the same time providing a reduced circulation rate requirement for the solvent and reduced re-compression and cooling requirements for the recycle gas.Type: GrantFiled: July 28, 1999Date of Patent: March 20, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Craig Norman Schubert, William I. Echt
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Patent number: 6174510Abstract: A process for the absorbing of a hot, dry gas stream of sulfur trioxide (SO3) in a stream of strong sulfuric acid. The process includes the steps of passing the hot, dry gas stream of SO3 into a sulfuric acid absorption tower above a packed bed held within the tower and below a liquid collection floor. A stream of strong sulfuric acid is introduced into the tower above the packed bed and allowed to pass cocurrently downwardly through the packed bed with the stream of SO3, thereby allowing the SO3 to be absorbed in the stream of strong sulfuric acid. The resulting concentrated sulfuric acid passes through a packing support into a lower plenum and the spent gas is fed upwardly through a gas conduit to an upper plenum located above the liquid collection floor and from there through a mist eliminator.Type: GrantFiled: August 27, 1999Date of Patent: January 16, 2001Inventor: Marcos D. Riano
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Patent number: 6174498Abstract: An odor control system and method for removing unwanted odorous airborne constituents in which the gas stream is flowed through a compact, boxlike housing having a plurality of sequentially communicating treatment chambers. Gas stream pretreatment is accomplished in a first chamber, in fluid communication with a sump, as the gas flows through a packed bed wetted by suitable chemical reagents. After pretreatment, the gas stream is passed through downstream chambers, also utilizing wetted packed beds. These chambers are in fluid communication with a second, separate sump. Because of the first chamber/separate sump combination, influent gas treatment, by stages, can be accomplished. In this manner, different, contemporaneous chemical treatments are possible, within the single housing, with different chemical reagents utilized as needed. Such treatments are possible even in cases where otherwise incompatible chemical reagents are used.Type: GrantFiled: April 11, 1997Date of Patent: January 16, 2001Assignee: US Filter/RJ Environmental, Inc.Inventors: Roop C. Jain, Martin Scanlan
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Patent number: 6174507Abstract: The invention is a process for separating acid gases from synthesis gas and treating the resulting solids. A mixture comprising synthesis gas and acid gas is contacted with a fluid that reacts with said acid gas to form a particulate solid dispersed in a fluid. The slurry comprising fluid and particulate solid is filtered to separate the particulate solid from the fluid by means of a regenerable filter. The particulate solids are removed from the regenerable filter by back-washing with a back-washing fluid to form a pumpable slurry comprising a mixture of particulate solids and back-washing fluid. The slurry is gasified to form synthesis gas and vitrified solids.Type: GrantFiled: June 5, 1998Date of Patent: January 16, 2001Assignee: Texaco Inc.Inventors: Paul S. Wallace, Kay A. Johnson, Delome D. Fair
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Patent number: 6162282Abstract: A method for determining the efficiency of a carbon filter used to absorb hydrocarbons from organic solvents. A sample of the solution, used to remove CO.sub.2 and H.sub.2 S from natural hydrocarbon gases, is taken after it has passed through the carbon filter. A solution of an internal standard and carbon disulfide is added to the sample to concentrate the hydrocarbons into the solution. A second sample taken from the solution containing the concentrated hydrocarbons and is passed through a gas chromatograph which has a fast temperature ramp to measure the peak areas of the hydrocarbons and the internal standard. The concentration of the measured hydrocarbons are determined by comparing the peak area counts against that of the internal standard.Type: GrantFiled: May 10, 1999Date of Patent: December 19, 2000Assignee: Mobil Oil CorporationInventors: Clifford C. Walters, Constance L. Hellyer
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Patent number: 6154909Abstract: In a method for suppressing the formation of sulfuric acid aerosols in exhaust gas purification systems, the exhaust gas is presprayed with water so that the temperature does not drop below the dew point of sulfuric acid in the exhaust gas, with this spraying taking place upstream from the gas scrubber, upstream from a prescrubber present in addition to the gas scrubber or upstream from a heat exchanger which is in turn upstream from the scrubber, and the gaseous sulfuric acid is absorbed by the water before the temperature drops below the dew point of the sulfuric acid.Type: GrantFiled: August 16, 1999Date of Patent: December 5, 2000Assignee: Preussen Electra Engineering GmbHInventors: Hans-Joachim Dieckmann, Heinz Gutberlet
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Patent number: 6149713Abstract: The dust concentration of the flue gas leaving an electrostatic precipitator and introduced into an absorption tower of a desulfurizer is adjusted to a level of 100 to 500 mg/Nm.sup.3. At the same time, a dust slurry having a higher dust concentration is separated and withdrawn from the slurry within the aforesaid absorption tower, and then subjected to a solid-liquid separation treatment. Thus, solid matter containing dust at a high concentration is extracted and discharged out of the system of the desulfurizer.Type: GrantFiled: November 13, 1998Date of Patent: November 21, 2000Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Eiji Ochi, Takeo Shinoda, Toru Takashina, Susumu Okino
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Patent number: 6139605Abstract: A double-loop process for the removal of specified gas or gases from a process gas by absorption with a liquid absorbent for said specified gas or gases wherein the process gas is contacted counter-currently in a first absorption stage with semi-lean absorbent liquid and then in a second absorption stage with lean absorbent liquid to give a sweet process gas and the absorbed gases are stripped from the laden absorbent liquid in a first stage giving a semi-lean absorbent liquid. Part of the semi-lean absorbent is recycled to the first absorption stage while the remainder is subjected to further stripping by counter-current contact with an auxiliary gas that has a concentration of the specified gas or gases that is lower than the concentration of the specified gas or gases in the process gas to give the lean absorbent liquid which is recycled to the second absorption stage.Type: GrantFiled: August 10, 1999Date of Patent: October 31, 2000Assignee: Imperial Chemical Industries PLCInventors: Peter John Herbert Carnell, Hiren Krishnakant Shethna, Gavin Paul Towler, Edwin Stephen Willis
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Patent number: 6136071Abstract: A process for recovering volatile, generally bad smelling low molecular, low polar substances called VLC, contained in gas streams, by capturing the same by in contacting the gaseous environment with a calixarene or a resorcinol calixarene present in the form of particles, granules, as a coating or impregnation on or in a solid support, or as an organic or aqueous solution.Type: GrantFiled: August 27, 1998Date of Patent: October 24, 2000Assignee: Transdiffusia S.A.Inventors: Roger Lamartine, Philippe Choquard, Philippe Goreloff, Yvon Martelin
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Patent number: 6102987Abstract: A process for the removal of CO.sub.2 and sulfur compounds from natural gas and raw synthesis gas wherein N-formylmorpholine and N-acetylmorpholine mixtures are used as the desorbent at temperatures between -20.degree. C. and +40.degree. C. at pressures of 10 to 150 bar in a scrubbing operation. The acid gases are removed from the absorbent by flashing and the regenerated absorbent is recycled to the absorbent.Type: GrantFiled: September 29, 1998Date of Patent: August 15, 2000Assignee: Krupp Uhde GmbHInventors: Manfred Gross, Barbel Kolbe, Johannes Menzel, Werner Pohl
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Patent number: 6102377Abstract: Sulfur oxides (SO.sub.x) are scrubbed from combustion effluents with economies in capital and operating costs by virtue of an arrangement of spray header piping and nozzles which permits ease of access for service with reduced spacing (e.g., 0.5 to 1.25 meters) between spray levels. At least two spray levels in a spray zone include a plurality of spray header pipes arranged parallel to the other spray header pipes within a spray level and vertically parallel to spray header pipes in at least one adjacent spray level. Each of the spray levels includes a plurality of spray nozzles extending from said spray headers. A majority of nozzles in a reference spray level are positioned such that lines drawn between them form a pattern of squares with the nozzles located at the corners of the squares. And, a majority of nozzles in an adjacent spray level are positioned over the centers of squares defined by four nozzles in the reference spray level.Type: GrantFiled: February 26, 1997Date of Patent: August 15, 2000Assignee: ABB Environmental Services, Division of ABB Flakt, Inc.Inventor: Joseph V. Doughty
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Patent number: 6090356Abstract: This invention is an integrated process which removes acidic gases such as H.sub.2 S, COS and CO.sub.2 from raw synthesis gas. The H.sub.2 S and COS is concentrated and separately recovered. The separately recovered CO.sub.2 is used as a moderator with the purified syngas in a combustion turbine. The process comprises separating H.sub.2 S and COS from a raw synthesis gas by absorption with a liquid solvent, removing coabsorbed CO.sub.2 by stripping the solvent with nitrogen, separating the H.sub.2 S and COS from the solvent and recovering sulfur from the H.sub.2 S and COS. The energy value of the CO.sub.2 and its value as a diluent in reducing NO.sub.x is recovered by using the CO.sub.2 as a moderator during combustion of the purified synthesis gas in a gas turbine.Type: GrantFiled: September 10, 1998Date of Patent: July 18, 2000Assignee: Texaco Inc.Inventors: Frederick C. Jahnke, William P. Volk
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Patent number: 6083302Abstract: Sulfur oxides (SO.sub.x) are scrubbed from combustion effluents with greater system reliability when an improved mist eliminator of the invention is employed. The mist eliminator has at least one section, preferably two sections, with two passes followed by an extended trailing edge. This design is shown in tests to be as effective as four pass designs, while being easier to clean. Encrustation and plugging are greatly reduced.Type: GrantFiled: August 13, 1998Date of Patent: July 4, 2000Assignee: ABB Environmental Systems, division of ABB Flakt, Inc.Inventors: Wesley P. Bauver, II, David K. Anderson, William H. Kingston
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Patent number: 6051055Abstract: An exhaust gas desulfurization system includes a spray pipe which is provided with a plurality of nozzles in the lengthwise direction and whose one end is closed and arranged horizontally in an absorption tower through which the exhaust gas passes vertically. Absorbent slurry is fed from the other end of the spray pipe and is injected upward from the nozzles, by which absorbent slurry is brought into contact with the exhaust gas to perform treatment in the absorption tower. The flow passage on the closed end side of the pipe is present in a shape such that the flow passage cross-sectional area decreases toward the closed end.Type: GrantFiled: July 28, 1998Date of Patent: April 18, 2000Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Naohiko Ukawa, Toru Takashina, Susumu Okino, Kazuaki Kimura, Koichiro Iwashita, Kouji Ikeda, Heiji Tanaka
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Patent number: 6017384Abstract: A nozzle arrangement in which the nozzles have a scrubber, especially for flow gas desulfurization, are laid in accordance with the following: (a) liquid concentrations of a component to be absorbed from a gas stream scrubbed in the column are measured above a plane of the nozzle assembly at N locations of a grid of equal area elements of a cross section of the column; (b) the N concentration values are compared with a predetermined value; (c) upon deviation of a measured concentration value from the predetermined value, a position of at least one of the nozzles is varied by selection of a length and location of an intermediate pipe section connecting the one of the nozzles to a respective branch pipe laterally thereon; and (d) repeating (a) through (c) until the concentration values measured above the plane are approximately equal except for at a wall region of the column.Type: GrantFiled: August 20, 1998Date of Patent: January 25, 2000Assignee: Lurgi Lentjes Bischoff GmbHInventor: Theo Risse
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Patent number: 6007604Abstract: A nozzle arrangement for a scrubbing column for a flue gas in desulfurization, in which the scrubbing column has a sump, a baffle-free zone above the sump and a nozzle arrangement above the absorption zone. The nozzles, preferably by selective connection of intermediate pipe sections are connected to a branch pipe system extending from a distributor. Flow density profiles are formed in predetermined cross sectional planes of the scrubbing column by the spray cones of the nozzles. In each of these cross sectional planes, the flow density profiles of different spray cones are superimposed on one another. The flow density profiles of different cross sectional planes are superimposed upon projection of them onto a one of the planes to form a flow density complete profile in this one plane over the entire cross section of the scrubbing column.Type: GrantFiled: August 14, 1998Date of Patent: December 28, 1999Assignee: Lurgi Lentjes Bischoff GmbHInventor: Theo Risse
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Patent number: 6001153Abstract: A method of treating a fluid containing at least methane and at least one acid gas and producing the acid gas or gases in liquid form. The method includes a step of regenerating the solvent, operated at a pressure whose value is at least equal to the bubble pressure of the mixture of acid gases produced in liquid form, a step in which the gaseous fraction from the regeneration step is rectified in a contact zone by separating at least some of the solvent from the gaseous fraction, a step in which the gaseous fraction from the modification step is cooled to a given temperature to cause at least some of the gaseous faction to condense forming at least one liquid fraction enriched with liquid acid gases and a step during which the liquid fraction of gases is separated from the remaining gaseous fraction.Type: GrantFiled: March 13, 1998Date of Patent: December 14, 1999Assignee: Institut Francais du PetroleInventors: Etienne Lebas, Alexandre Rojey
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Patent number: 6001154Abstract: The present invention provides a gas-liquid contact apparatus which can make the equipment more compact and reduce the cost while achieving high gas-liquid contact efficiency. In the apparatus of the present invention, an oxidation tank (2) is installed in proximity to an absorption tower (1), and an absorbing fluid (3) is stored in this oxidation tank (2). The level H of the absorbing fluid (3) is determined so as to be above the position of nozzles (7), whereby the absorbing fluid is spouted upward from the nozzles (7). Flue gas is introduced into the absorption tower (1) from a flue gas inlet section (8) and made to flow upward at a high velocity, so that the peaks of the spouted streams are raised above level H. The absorbing fluid (3) is caught by catcher device (11) installed at a position above level H, and returned to the oxidation tank (2) through a circulation pipe (12). An air pipe (20) is connected to the circulation pipe (12) so as to suck in air.Type: GrantFiled: May 6, 1998Date of Patent: December 14, 1999Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shinichiro Kotake, Kazuaki Kimura, Eiji Ochi, Toru Takashina, Susumu Okino
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Patent number: 5976222Abstract: A process for the separation and recovery of fluorochemicals from a gas stream containing a diluent gas and fluorochemicals by contact of the gas stream with a membrane system in combination with an adsorption system, the adsorption system used either before or after the membrane system.Type: GrantFiled: March 23, 1998Date of Patent: November 2, 1999Assignee: Air Products and Chemicals, Inc.Inventors: James Hsu-Kuang Yang, Iosif Chernyakov, Thomas Hsiao-Ling Hsiung, Alexander Schwarz
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Patent number: 5968346Abstract: A hydroprocessing process includes two hydroprocessing reaction stages, both of which produce a liquid and a vapor effluent, and a liquid-vapor contacting stage. The first stage vapor effluent contains impurities, such as heteroatom compounds, which are removed from the vapor by contact with processed liquid effluent derived from one or both reaction stages and, optionally, also liquid recovered from processed vapor. The first and contact stage liquid effluents are passed into the second stage to finish the hydoprocessing. The contact and second stage vapor effluents are cooled to recover additional hydroprocessed product liquid.Type: GrantFiled: September 16, 1998Date of Patent: October 19, 1999Assignee: Exxon Research and Engineering Co.Inventors: Henry Jung, Ramesh Gupta, Edward S. Ellis, William E. Lewis
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Patent number: 5964923Abstract: A process train for treating a gas stream containing methane, nitrogen, and at least one of water vapor, acid gas, C.sub.3+ hydrocarbons and aromatic hydrocarbons, the gas stream typically, but not necessarily, being natural gas. The treatment train includes separation of methane from nitrogen by means of membranes that preferentially permeate methane and reject nitrogen. Preferred processes include both a dehydration step and an NGL removal step to treat the gas before it passes to the methane/nitrogen membrane separation step. The process train can also include additional steps, such as an acid gas removal step, or a cryogenic methane/nitrogen separation step.Type: GrantFiled: July 14, 1997Date of Patent: October 12, 1999Assignee: Membrane Technology and Research, Inc.Inventor: Kaaeid A. Lokhandwala
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Patent number: 5961837Abstract: Water to be utilized is reacted with soda ash and lime to produce a less corrosive and foulant water. Reaction sludges are fed to a desulfurization unit, where SO.sub.x, NO.sub.x and CO.sub.2 abatement occurs; other industrial waste sludges and/or waters and/or gases can also be utilized in such connection. FIG. 1 is one of the possible process schemes of present invention.Type: GrantFiled: June 20, 1997Date of Patent: October 5, 1999Inventors: Marcello Ferrara, Maria Gabriella Scopelliti
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Patent number: 5928413Abstract: This invention provides a flue gas treating system and process which include a counterflow absorption tower and which can reduce the ammonia concentration in the treated flue gas to a low level.Type: GrantFiled: September 11, 1997Date of Patent: July 27, 1999Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Eiji Ochi, Kiyoshi Okazoe, Toru Takashina
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Patent number: 5879433Abstract: One or more contaminants selected from the group consisting of acidic gases, inert particulates, and mixtures thereof are removed from steam by contacting the contaminated steam with a nonaqueous sorbent such as crystalline molecular sieves, silica gels, soda ash, carbonaceous adsorbents, and amine liquid ion exchange resins.Type: GrantFiled: July 31, 1997Date of Patent: March 9, 1999Assignee: Union Oil Company of CaliforniaInventors: Darrell L. Gallup, Thomas S. Powell
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Patent number: 5861051Abstract: This invention relates to a process for the separation of carbon dioxide and hydrogen sulfide from gases using a promoted methyldiethanolamine (MDEA) solution. In one broad respect, this invention is a gas separation process, including contacting an aqueous treating solution with a sour gas stream that contains carbon dioxide and hydrogen sulfide under conditions such that the gas stream is sweetened, wherein the aqueous treating solution contains methyldiethanol amine and 2-(2-aminoethoxy)ethanol in a ratio of at least about 2:1; and wherein the process is conducted in the absence of a reclamation step. By practice of this invention, the amount of 2-(2-aminoethoxy)ethanol that is converted to urea(bis-(2-hydroxyethoxyethyl)urea (BHEEU)) is minimized which obviates the need for a reclamation (regeneration) unit.Type: GrantFiled: September 30, 1996Date of Patent: January 19, 1999Assignee: Huntsman Petrochemical CorporationInventors: James E. Critchfield, Wei-Yang Su, Thomas J. Kenney, Patrick E. Holub
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Patent number: 5851265Abstract: A process for the selective removal and recovery of sulfur dioxide from effluent gases is disclosed. The sulfur dioxide is recovered in a sulfur dioxide absorption/desorption cycle which utilizes a liquid solvent to selectively absorb sulfur dioxide from the effluent gas. The liquid solvent includes an organic phosphorous compound selected from phosphate triesters, phosphonate diesters, phosphinate monoesters and mixtures thereof. Preferably, the liquid solvent includes phosphonate diesters of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently aryl or C.sub.1 to C.sub.8 alkyl. The organic phosphonate diesters are substantially water immiscible, the solubility of water in the organic phosphonate diester being less than about 10 weight percent at 25.degree. C., and have a vapor pressure less than about 1 Pa at 50.degree. C. In accordance with a preferred embodiment, the liquid solvent include dibutyl butyl phosphonate.Type: GrantFiled: September 3, 1996Date of Patent: December 22, 1998Assignee: Monsanto CompanyInventors: Brian M. Burmaster, Donald R. McAlister
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Patent number: 5797981Abstract: A method of treating a gas, for example, natural gas containing at least one hydrocarbon and at least one acid gas to remove the acid gas from the natural gas and to produce at least one concentrated acid gas, wherein the gas is subjected to at least two stages of absorption using polar solvents having different properties.Type: GrantFiled: November 7, 1997Date of Patent: August 25, 1998Assignee: Intitut Francais du PetroleInventors: Jean-Claude Collin, Joseph Larue, Alexandre Rojey
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Patent number: 5785901Abstract: An object of this invention is to provide a gas-liquid contact apparatus for use in wet flue gas desulfurizers and the like which is equipped with lightweight and inexpensive header pipes having excellent wear resistance and corrosion resistance and hence exhibits high reliability and economical efficiency. To this end, there is provided a gas-liquid contact apparatus wherein one or more header pipes having attached thereto a plurality of spray nozzles for spouting a slurry upward are disposed in the main body of a tower through which a gas flows, characterized in that the header pipes are made of a fiber-reinforced resin composite material and the outer surface thereof or the outer and inner surfaces thereof are formed of a corrosion-resistant and wear-resistant layer of a resin containing ceramic particles.Type: GrantFiled: May 21, 1997Date of Patent: July 28, 1998Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shigeo Hasegawa, Noohiko Ukawa, Kenji Iwasaki, Tamotsu Higuchi, Koichiro Iwashita
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Patent number: 5782958Abstract: A process for the dehydration, deacidification and stripping of a gas, characterized in that:(a) at least one fraction of the gas is contacted with an aqueous phase containing methanol, the resultant gas being thus charged with methanol being withdrawn from stage (a);(b) the gas withdrawn from stage (a) is contacted with a mixture of solvents comprising methanol, water, and a solvent heavier than methanol, the gas leaving stage (b) being thus at least in part freed of the acid gases which it contained initially;(c) the mixture of solvent obtained from stage (b) is at least in part generated by special reduction and/or heating while liberating at least part of the acid gases, the mixture of solvent being at least partially regenerated, or being at the outlet of stage (c) recycled through stage (b); and(d) the gas obtained from (stage b) is refrigerated while producing at least an aqueous phase containing methanol which is at least in part recycled through stage (a).Type: GrantFiled: December 30, 1996Date of Patent: July 21, 1998Assignee: Institut Francais du PetroleInventors: Alexandre Rojey, Etienne Lebas, Joseph Larue, Ari Minkkinen
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Patent number: 5753012Abstract: A method of operating an apparatus for the cleaning of industrial waste gases and especially power plant flue gases. The gases are fed through a quencher to a first scrubber with its own recirculation and upstream of a second scrubber having its own recirculation and aerosols of halogen compounds which are eliminated by providing the quencher is part of a prescrubber or by forming the downstream scrubber with a wet electrostatic precipitator.Type: GrantFiled: October 23, 1996Date of Patent: May 19, 1998Assignee: Krupp Koppers GmbHInventors: Bernhard Firnhaber, Michael Lang, Cort Starck, Wolfgang Schulte
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Patent number: 5735936Abstract: The process comprises a cold absorption step 2 for removing acid gas from natural gas using a solvent phase at a pressure P.sub.2 which delivers a purified gas 5; a step for depressurizing and separating resultant acidic solvent phase containing hydrocarbons (lines 4, 11), at a pressure P.sub.12 which is lower than pressure P.sub.2 in a column-heat exchanger 12 which delivers a purified gaseous effluent 13 overhead and a further solvent phase at the bottom (line 17) which is enriched in hydrogen sulphide; and a solvent phase regeneration step carried out in a distillation column 18 at a pressure P.sub.18 and no higher than pressure P.sub.12. A gas 29 containing essentially hydrogen sulphide which is depleted in hydrocarbons is recovered from column 18 and is a suitable feed for a Claus plant for eliminating H.sub.2 S. The regenerated hot solvent phase 20 indirectly exchanges heat with the cold acidic solvent phase from absorber 2 or separator 6. It is then recycled to the absorbent after cooling.Type: GrantFiled: April 18, 1996Date of Patent: April 7, 1998Assignee: Institut Francais du PetroleInventors: Ari Minkkinen, Joseph Larue, Pierre Capron
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Patent number: 5728186Abstract: Fluid gases are stripped clean of gaseous and particulate pollutants as they pass rapidly up the stack of an industrial or electric power generation plant by a battery of rapidly rotated air foil spokes arrayed in two sets interleaved and revolving around a common central axis, a single motor providing the power that maintains the cleaning operation as long as flue gas flows toward discharge to the atmosphere.Type: GrantFiled: October 11, 1996Date of Patent: March 17, 1998Inventor: Kjartan A. Jonsson