Sulfur Or Sulfur Containing Compound Sorbed Patents (Class 95/235)
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Patent number: 8088200Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.Type: GrantFiled: February 14, 2007Date of Patent: January 3, 2012Assignee: BASF SEInventors: Rupert Wagner, Randolf Hugo
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Publication number: 20110315014Abstract: A method for removing SOx (x=2 and/or 3) from gas using a solution having polyethylene glycol as the main ingredient. First, SOx in the gas is absorbed by the solution of polyethylene glycol. Second, the solution of polyethylene glycol which has absorbed SOx is regenerated by one or more of the heating, vacuum, ultrasonic, microwave or radiation methods, thereby releasing the by-products of sulfur dioxide and sulfur trioxide. The regenerated solution of polyethylene glycol is recycled. When the water content of the regenerated solution of polyethylene glycol is high enough to affect the desulfurization, it needs to be removed. Removal methods include heating and rectification, absorption using a water absorbent, or a combination of these methods. The polyethylene glycol solution is recycled after dehydration.Type: ApplicationFiled: February 10, 2010Publication date: December 29, 2011Applicants: BEIJING BOYUAN-HENGSHENG HIGH-TECHNOLOGY CO., LTD., PEKING UNIVERSITY, YONGFENG BOYUAN INDUSTRY CO., LTD.Inventors: Xionghui Wei, Fang Han, Jianbin Zhang, Pengyan Zhang, Daolong Gao, Jinfei Wang, Chuan Zou, Chun Hu
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Publication number: 20110296992Abstract: This invention relates to sulfur based compounds useful in methods of carbon dioxide or sulfur dioxide removal.Type: ApplicationFiled: March 11, 2011Publication date: December 8, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: MARK A. SCIALDONE
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Patent number: 8057579Abstract: A method and apparatus are provided for absorbing acid gases from a synthesis gas prior to combustion. In one embodiment, a vessel is provided for receiving a synthesis gas and a physical solvent. The vessel includes one or more membrane contactors that provide an interface for physical absorption of one or more acid gases from the synthesis gas into the physical solvent.Type: GrantFiled: November 10, 2008Date of Patent: November 15, 2011Assignee: General Electric CompanyInventor: Jennifer Lynn Molaison
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Publication number: 20110271835Abstract: Compositions and methods relating to aromatic imine compounds and methods of their use are described. The compounds are formed from aromatic aldehydes and amino or amino derivatives. The compounds and their derivatives are useful, for example, as hydrogen sulfide and mercaptan scavengers for use in both water and petroleum products.Type: ApplicationFiled: July 19, 2011Publication date: November 10, 2011Inventors: Gary Westlund, David Weller
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Patent number: 8038774Abstract: This invention involves ship flue gas desulphurization method and system. It employs seawater to reduce SO2 and other pollutant discharged by ship. The method includes seawater scrub, acidic seawater transfer, deacidification, and discharge processes. The system includes a scrubber and a water-saving deacidification device. Upper portion of the scrubber comprises a scrubbing section which is connected with scrubbing seawater pump by pipelines. Lower portion of the scrubber comprises a cooling section. One end of the scrubber links the ship engine smoke pipe by a scrubbing inlet pipe, and the other end links the scrubber to a scrubbing outlet pipe. The water-saving deacidification device lies below the scrubber and is connected with it. The water-saving deacidification device is coupled to a blending seawater pump, fan, and total drain pipe for discharging seawater after deacidification. This invention provides high desulphurization efficiency, and requires small seawater quantity.Type: GrantFiled: June 13, 2008Date of Patent: October 18, 2011Inventor: Sigan Peng
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Patent number: 8025860Abstract: Acid mist may be removed efficiently from a gas stream using at least one fiber bed mist eliminator operating at elevated pressure of typically at least 2 bar (0.2 MPa), e.g. at about 4 bar (0.4 MPa) to about 50 bar (5 MPa). The invention has particular application in methods for processing carbon dioxide flue gas in which SO2 and/or NOx contaminants are converted at elevated pressure to sulfuric acid condensate and/or nitric acid condensate respectively.Type: GrantFiled: July 8, 2010Date of Patent: September 27, 2011Assignee: Air Products and Chemicals, Inc.Inventor: Barry Wayne Diamond
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Patent number: 8012441Abstract: The invention relates to a method for isolating hydrogen sulphide from coke-oven gas with the subsequent recovery of elemental sulphur in a Claus plant. The hydrogen sulphide is eliminated from the coke-oven gas by gas washing using an absorption liquid. During the regeneration of the loaded absorption liquid, hydrogen sulphide is accumulated in concentrated form and is fed to the Claus plant. Said Claus plant comprises a Claus boiler, a waste-heat boiler, in addition to a reactor, which forms an additional catalyst stage. According to the invention, the Claus plant is operated with a single reactor, which operates at a working temperature of below 250° C. The process gas that exits the reactor is returned after the deposition of elemental sulphur with a non-reacted residual concentration of hydrogen sulphide to the coke-oven gas that is to be cleaned, prior to the gas washing stage.Type: GrantFiled: May 10, 2003Date of Patent: September 6, 2011Assignee: Uhde GmbHInventor: Holger Thielert
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Patent number: 8007571Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: August 22, 2008Date of Patent: August 30, 2011Inventor: Donald Leo Stinson
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Patent number: 8007569Abstract: The invention relates to a method for removing hydrogen sulphide and other acidic gas components from pressurized technical gases by means of a physical detergent and for obtaining sulphur from hydrogen sulphide by using a Claus system. The hydrogen sulphide and the other acidic gas components are removed in an absorbent manner from the physical detergent, the physical detergent undergoes multi-step regeneration, said multi-step regeneration comprising at least one device for CO enrichment, a device for H2S enrichment, a device for CO2 stripping and a device for thermal regeneration. The various regeneration steps consist of various pressure steps and have a lower pressure than that of the absorption. A hydrogen sulphide rich Claus gas is withdrawn from one of the regeneration steps and is guided to a Claus system where sulphur is produced. The residual gas exiting from the Claus system is hydrated and is condensed under pressure, corresponding to one of the regeneration steps.Type: GrantFiled: July 12, 2004Date of Patent: August 30, 2011Assignee: Uhde GmbHInventors: Georg Saecker, Johannes Menzel
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Patent number: 7998446Abstract: A flue gas desulfurization process in which a SO2-containing flue gas stream is contacted with a recirculating stream of an aqueous medium containing concentrated sulfuric acid and hydrogen peroxide, to yield a desulfurized flue gas stream and to produce additional sulfuric acid in the aqueous medium. A portion of the recirculating aqueous sulfuric acid stream is diverted for recovery of the additional sulfuric acid as gypsum in a neutralization step, and the process parameters are adjusted so that the heat of reaction generated during the neutralization step is sufficient to evaporate the free water that is present and yield a gypsum product that is substantially dry.Type: GrantFiled: April 29, 2008Date of Patent: August 16, 2011Assignee: FMC CorporationInventors: Henry A. Pfeffer, William C. Copenhafer
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Patent number: 7993433Abstract: The invention relates to a new method for removing and recovering of acid gases from a gaseous mixture in an absorption plant by adding an organic acid to a stream of the rich absorbent in the desorber in order to release acid gas by shifting the acid gas equilibrium towards the gas side, and the organic acid is subsequently separated from the absorbent. With this method, the energy consumption of the process is substantially reduced. The invention also relates to an apparatus for performing this method.Type: GrantFiled: June 28, 2006Date of Patent: August 9, 2011Assignee: NTNU Technology Transfer ASInventors: Hallvard F. Svendsen, Finn Andrew Tobiesen, Thor Mejdell, Karl Anders Hoff, Olav Juliussen
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Patent number: 7988767Abstract: Contemplated configurations and methods for elemental sulfur removal from various gases, and especially well acid gases employ a hydrocarbon solvent that dissolves the sulfur to form a rich solvent and that is then regenerated by hydrotreating. Thus, sulfur is removed from the rich solvent as H2S that may then be processed (e.g., in Claus unit or absorption unit) while the regenerated solvent is routed back to the well and associated production pipes.Type: GrantFiled: August 28, 2007Date of Patent: August 2, 2011Assignee: Fluor Technologies CorporationInventors: Curt Graham, Robert Henderson, Richard B. Nielsen, Michael Debest
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Patent number: 7985281Abstract: A device useful for separating gaseous pollutants, such as sulphur dioxide, from a gas by means of an absorption liquid is disclosed. The device includes a horizontal apertured plate mounted between an inlet and an outlet arranged for passage of a gas containing a gaseous pollutant therethrough. On an upper surface of the horizontal apertured plate is a flowing layer of absorption liquid. The separation of the gaseous pollutant from the gas is adjustable by varying the thickness of the flowing layer of absorption liquid by moving a throttle means to a position that provides the desired amount of resistance to the following layer of absorption liquid.Type: GrantFiled: December 5, 2006Date of Patent: July 26, 2011Assignee: ALSTOM Technology LtdInventor: Rikard Håkansson
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Patent number: 7976622Abstract: Absorption liquid recirculating pipes fitted with absorption tower (absorber) recirculating pumps corresponding to individual spray headers are inserted from the void tower portion inside absorption tower, near the liquid surface of liquid trapping portion (recirculation tank), in the interior of the absorption tower, erected vertically from substantially the center of the absorption tower and connected to respective spray headers provided in multiple stages along the direction of gas flow. Multiple nozzles of each of the spray headers are disposed mutually concentrically or rectangularly on a plane orthogonal to the direction of flue gas flow within the absorption tower.Type: GrantFiled: September 20, 2006Date of Patent: July 12, 2011Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Naoki Oda, Atsushi Katagawa, Hajime Okura
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Patent number: 7967896Abstract: The invention provides a process and system for regenerating a solvent used to remove carbon dioxide from feed gases, such as natural gas and synthesis gas. The invention employs one or more hydraulic turbochargers to transfer energy from a higher energy solvent stream to a lower energy solvent stream. This provides for a significant reduction in operating expenses.Type: GrantFiled: March 26, 2008Date of Patent: June 28, 2011Assignee: UOP LLCInventors: William J. Lechnick, Nagaraju Palla, Paul A. Sechrist, Lamar A. Davis, Michael R. Van de Cotte
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Patent number: 7967895Abstract: For regenerating the loaded washing (scrubbing) agent (6, 7) from a physical gas wash (T1), in which one or more gas components are removed, to a large extent selectively, from a gas mixture (1) to be purified at least in a first of at least two successive washing steps, the loaded washing agent (7) withdrawn from the first washing step is, independently of the remaining quantity of loaded washing agent (6), subjected to a regeneration step (T2a) for separating the gas components (11) which have been selectively removed from the raw gas in the first washing step.Type: GrantFiled: March 27, 2007Date of Patent: June 28, 2011Assignee: Linde AGInventors: Ulrich Prüssner, Horst Weiss
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Patent number: 7964025Abstract: Systems and techniques for the reclamation of carbon dioxide from boiler flue gas as well as for the liquefaction of the reclaimed carbon dioxide for well injection oil recovery are provided. A system can include a boiler, tower scrubber, carbon dioxide absorber, regenerator, reboiler, rectifying tower, condenser and mixing tank. Mixed gases of carbon dioxide and nitrogen for well injection may be reclaimed from boiler flue gas when steam is produced resulting in an increase of crude oil output increase while lessening environmental impact. Related systems, apparatus, methods, and articles are also described.Type: GrantFiled: November 14, 2007Date of Patent: June 21, 2011Assignee: Liaohe Petroleum Exploration Bureau, CNPCInventors: Fengshan Zhang, Yuanwen Gao
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Patent number: 7947242Abstract: A cement kiln chlorine/sulfur bypass system wherein the equipment cost is suppressed and the sulfur included in a combustion gas bled from a cement kiln is separated and effectively utilized. The cement kiln chlorine/sulfur bypass system comprises an air bleed means for bleeding a kiln exhaust gas passage, which runs from the end of the cement kiln to a bottom cyclone, of a part of the combustion gas, a separating means for separating dust in the gas bled by the air bleed means into coarse particles and fine particles, and a wet dust collector for collecting dust from the gas containing the fine particles separated by the separating means. The separating means is preferably a classifier in which the cut size is changeable. The wet dust collector is preferably a mixing scrubber.Type: GrantFiled: August 13, 2003Date of Patent: May 24, 2011Assignee: Taiheiyo Cement CorporationInventors: Shinichiro Saito, Naoki Ueno, Hiroshi Harada, Soichiro Okamura, Takayuki Suzuki
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Patent number: 7935323Abstract: The invention describes a system and method for hydrogen sulfide decontamination of natural gas using a scavenging reagent. The system uses a scavenging reagent within two reactors wherein the consumption of scavenging reagent is optimized by the control of flow of clean and partially-consumed scavenging reagent within and between the two reactors.Type: GrantFiled: October 17, 2008Date of Patent: May 3, 2011Assignee: Cody Liners Ltd.Inventors: Marc Schulz, Leonard McKeary
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Publication number: 20110088554Abstract: Process for removing acid gases from a gas stream, in particular from a natural gas stream, synthesis gas stream or the like, wherein the acid gases are absorbed from the gas stream by at least one absorbent. The absorbent used is a mixture of a physical scrubbing medium, a chemical scrubbing medium and water. The absorbent comprises more than 60% by weight of the physical scrubbing medium, wherein the physical scrubbing medium used is a morpholine derivative and a chemical scrubbing medium based on at least one aliphatic amine compound is used.Type: ApplicationFiled: June 26, 2009Publication date: April 21, 2011Inventor: Johannes Menzel
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Patent number: 7927403Abstract: The invention relates to a method for the absorption of acid gases, such as CO2 and H2S, from gas mixtures. According to the invention, acid gases are absorbed from a gas mixture by contacting this gas mixture with a liquid in which is dissolved so high a concentration of an amino acid or a salt thereof that a precipitate is formed. The contact takes place in a column of the packing-free type or a column suitable for processing slurries.Type: GrantFiled: May 7, 2003Date of Patent: April 19, 2011Assignee: Nederlandse Organisatie voor Natuurwetenschappelijk Onderzoek TNOInventors: Geert Frederil Versteeg, Paramasivam Senthil Kumar, Johannes Antonius Hogendoorn, Paul Hubert Maria Feron
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Publication number: 20110083592Abstract: An in-situ forced oxidation wet flue gas desulfurization apparatus, method and arrangement for utilization with oxy-fuel combustion power plants. The apparatus is a tower-like structure having a flue gas scrubbing zone and a reaction zone located subjacent to the gas scrubbing zone. A sulfur oxide absorbing liquid slurry is supplied to the gas scrubbing zone to react with and scrub the sulfur oxides from the flue gas. The partially reacted liquid slurry reagent and the scrubbed products drain into the reaction zone, rising to a set level. Oxidation air is introduced into the liquid slurry in the reaction zone to force the in-situ oxidation of sulfur compounds collected in the reaction zone.Type: ApplicationFiled: October 12, 2009Publication date: April 14, 2011Inventors: Dennis K. McDonald, Kevin J. Rogers
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Publication number: 20110084020Abstract: A method for removing methane from biogas is described. The method includes: (i) receiving biogas including methane and other components into a first tank; (ii) receiving water into the first tank; (iii) contacting the biogas with the water inside the first tank; (iv) dispensing methane gas from an outlet of the first tank; and (v) producing from the tank an effluent stream that includes other components of the biogas.Type: ApplicationFiled: October 9, 2009Publication date: April 14, 2011Inventor: Christopher OTT
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Patent number: 7922792Abstract: A neutralization/sequestration process is provided for concomitantly addressing capture and sequestration of both CO2 and SO2 from industrial gas byproduct streams. The invented process concomitantly treats and minimizes bauxite residues from aluminum production processes and brine wastewater from oil/gas production processes.Type: GrantFiled: March 12, 2008Date of Patent: April 12, 2011Assignee: U.S. Department of EnergyInventors: Yee Soong, Douglas E. Allen, Chen Zhu
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Patent number: 7918922Abstract: The invention provides a process for removal of hydrogen sulphide, iron pentacarbonyl and nickel tetracarbonyl from a feed synthesis gas stream, the process comprising the steps of: (a) removal of hydrogen sulphide and of iron pentacarbonyl by contacting the feed synthesis gas stream with an absorbing liquid comprising water, physical solvent and an amine, to obtain a synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl; (b) adsorption of nickel tetracarbonyl by contacting the synthesis gas stream depleted of hydrogen sulphide and depleted of iron pentacarbonyl with solid adsorbent comprising activated carbon to obtain solid adsorbent enriched in nickel tetracarbonyl and a purified synthesis gas stream.Type: GrantFiled: September 26, 2007Date of Patent: April 5, 2011Assignee: Shell Oil CompanyInventors: Rudolf Robert Gouman, Adriaan Johannes Kodde, Cornelis Jacobus Smit
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Patent number: 7909914Abstract: The present invention relates to a method of removing acid gases, notably carbonyl sulfide, contained in gaseous effluents, comprising: an acid gas absorption stage by contacting the gaseous effluent with an aqueous solution comprising 2-[2-amino-1-(aminomethyl)ethoxy]ethanol, and possibly another alkanolamine and an organic compound, and at least one aqueous solution regeneration stage. The method can comprise a second aqueous solution regeneration stage. The regeneration stages are carried out by expansion and/or thermal regeneration.Type: GrantFiled: July 11, 2008Date of Patent: March 22, 2011Assignee: IFPInventors: Renaud Cadours, Julia Magne-Drisch, Bruno Delfort
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Patent number: 7901488Abstract: Carbon dioxide and other acid gases are removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a matrix stripping configuration, less energy is consumed. The matrix stripping configuration uses two or more reboiled strippers at different pressures. The rich feed from the absorption equipment is split among the strippers, and partially regenerated solvent from the highest pressure stripper flows to the middle of sequentially lower pressure strippers in a “matrix” pattern. By selecting certain parameters of the matrix stripping configuration such that the total energy required by the strippers to achieve a desired percentage of acid gas removal from the gaseous stream is minimized, further energy savings can be realized.Type: GrantFiled: October 2, 2007Date of Patent: March 8, 2011Assignee: Board of Regents, The University of Texas SystemInventors: Gary T. Rochelle, Babatunde A. Oyenekan
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Patent number: 7901487Abstract: An acid gas such as carbon dioxide, hydrogen sulfide, or a mixture thereof is removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a multipressure stripper (51) that combines acid gas compression with stripping, less energy is consumed. The multipressure stripper is a multistage flash (52, 55, 59) in which the total vapor flow from each stage is compressed and fed to the bottom of the previous flash stage at a higher pressure. In this process, the heat in the water content of the vapor exiting each stage is utilized at a higher pressure in the previous stage. The described stripping process generates the acid gas at a higher pressure without operating the stripper at a higher temperature, thereby reducing the energy consumption of the system.Type: GrantFiled: March 4, 2004Date of Patent: March 8, 2011Assignee: Board of Regents, The University of Texas SystemInventor: Gary T. Rochelle
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Patent number: 7892324Abstract: Methods and systems for handling sour carbon dioxide (CO2) streams are provided. In one aspect, a method for sequestering an emissions-heavy gas includes removing at least a portion of an acid gas from a rich solvent in an acid gas stripper to create the emissions-heavy gas, and channeling the emissions-heavy gas to a storage system.Type: GrantFiled: October 10, 2007Date of Patent: February 22, 2011Assignee: General Electric CompanyInventors: Arnaldo Frydman, Pradeep Thacker, Sachin Naphad, Aaron John Avagliano
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Patent number: 7883569Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas; and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: February 12, 2007Date of Patent: February 8, 2011Inventor: Donald Leo Stinson
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Patent number: 7879135Abstract: Contemplated plants include an acid gas enrichment unit in which acid gas unsuitable for feeding into a Claus plant from an upstream acid gas removal unit is separated into a concentrated hydrogen sulfide stream that is fed to the Claus plant and a carbon dioxide stream that is compressed in a compressor before sequestration, further purification, and/or recycling to a gasification unit.Type: GrantFiled: April 20, 2006Date of Patent: February 1, 2011Assignee: Fluor Technologies CorporationInventors: Ravi Ravikumar, Gordon Sims, Harold Sandler
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Patent number: 7867322Abstract: A gas cleaning system, which is operative for cleaning a process gas containing carbon dioxide and sulphur dioxide, comprises a combined cooling and cleaning system (16), and a CO2-absorber. The combined cooling and cleaning system (16) comprises a first gas-liquid contacting device (50) located upstream of the CO2-absorber and operative for cooling the process gas by means of a cooling liquid, and for absorbing into the cooling liquid sulphur dioxide of the process gas, such that a cooling liquid containing sulphate is obtained. The combined cooling and cleaning system (16) further comprises a second gas-liquid contacting device (94) located downstream of the CO2-absorber and operative for removing ammonia from the process gas, which has been treated in the CO2-absorber, by means of bringing the process gas containing ammonia into contact with the cooling liquid containing sulphate.Type: GrantFiled: January 17, 2008Date of Patent: January 11, 2011Assignee: ALSTOM Technology LtdInventor: Eli Gal
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Patent number: 7857891Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula (I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine Wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula (II) or at least one piperazine compound of formula (III) wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl group having from 1 to 6 carbon atoms or an hydroxyalkyl group having fType: GrantFiled: March 11, 2004Date of Patent: December 28, 2010Assignee: Dow Global Technologies Inc.Inventors: Craig N. Schubert, Arnold C. Ashcraft
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Publication number: 20100300290Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula R1O-(Alk-O)n—R2??(I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula R3NHR4OR6??(II) or at least one piperazine compound of formula wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl grType: ApplicationFiled: August 16, 2010Publication date: December 2, 2010Applicant: DOW GLOBAL TECHNOLOGIES INC.Inventors: Craig N. Schubert, Arnold C. Ashcraft
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Publication number: 20100288125Abstract: An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.Type: ApplicationFiled: October 9, 2009Publication date: November 18, 2010Inventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Erika Dengler
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Patent number: 7819952Abstract: In one aspect of the invention there is provided a gas scrubbing system for removing contaminants from a flow of fluid, comprising a container having an interior volume, an inlet for receiving the flow of fluid and an outlet for dispensing the stream of fluid, a treatment liquid, a porous medium positioned in the interior volume, between the inlet and outlet, said porous medium providing a high surface area to facilitate chemical interactions between the fluid flow and the treatment liquid and means to apply the treatment liquid onto the porous medium. A contact cell aspect of the porous medium and a method aspect are also provided.Type: GrantFiled: March 9, 2008Date of Patent: October 26, 2010Inventor: Dennis Saboe
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Patent number: 7819946Abstract: A differential absorption spectrum for a reactive gas in a gas mixture can be generated for sample absorption data by subtracting background absorption data set from the sample absorption data. The background absorption data can be characteristic of absorption characteristics of the background composition in a laser light scan range that includes a target wavelength. The differential absorption spectrum can be converted to a measured concentration of the reactive gas using calibration data. A determination can be made whether the background composition has substantially changed relative to the background absorption data, and new background absorption data can be used if the background composition has substantially changed. Related systems, apparatus, methods, and/or articles are also described.Type: GrantFiled: April 19, 2010Date of Patent: October 26, 2010Assignee: SpectraSensors, Inc.Inventors: Xin Zhou, Xiang Liu, Alfred Feitisch, Gregory M. Sanger
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Publication number: 20100257781Abstract: Stack gases of a burner, such as a power plant or other combustion source, may be remediated by a captive algae farm cycling some portion of the stack gases through a scrubber, and ultimately out into a manifold feeding a farm composed of tubes hosting the growth of algae. Liquids from the scrubber, including water capturing volatile organic compounds, solid particulates, nitrogen compounds, sulfur compounds, carbon dioxide, and the like, remediate the water and feed the algae farm. Meanwhile, the vapors and other gases provide an environment rich in water vapor, nitrogen compounds acting as fertilizer, and carbon dioxide to feed the algae to promote increased rates of growth. The algae may be recycled as a fuel itself, or may be harvested for use as a soil amendment to enrich the organic content of soils.Type: ApplicationFiled: April 13, 2010Publication date: October 14, 2010Inventors: J. Clair Batty, Craig E. Cox, David A. Bell
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Patent number: 7811361Abstract: One exemplary embodiment can be a process for increasing an efficiency of an acid gas removal zone. The process can include sending a sour gas stream including at least one gas to a first absorber providing an overhead stream absorbing the at least one gas; withdrawing a side-stream from the first absorber and passing the side-stream through a holding tank, a side-stream fluid transfer device, and a side-stream chiller before returning the side-stream to the absorber; and passing the first absorber overhead stream to a pump-around circuit for a second absorber. Usually, the pump-around circuit may include a flash drum, a pump-around fluid transfer device and a pump-around chiller before providing a slipstream to the first absorber and another portion to the second absorber.Type: GrantFiled: June 30, 2009Date of Patent: October 12, 2010Assignee: UOP LLCInventors: William J. Lechnick, Lamar A. Davis, David Alden Bahr, Carla F. Roberts
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Patent number: 7789944Abstract: A treatment system to efficiently remove lead from dust contained in extracted cement kiln combustion gas while reducing facility and running costs. A treatment system 1 comprising: a probe 3 for extracting a part of combustion gas, while cooling it, from a kiln exhaust gas passage, which runs from an inlet end of a cement kiln to a bottom cyclone; a classifier 5 for separating coarse powder from dust contained in the combustion gas extracted by the probe 3; a wet dust collector 6 for collecting dust from the extracted gas containing fine powder discharged from the classifier 5; and devices 12, 13 for feeding sulfurizing agent for sulfurizing lead contained in the kiln exhaust gas to the wet dust collector 6, and others. From the sulfurizing-agent feeders 12, 13 are preferably added the sulfurizing agents to a circulation liquid tank 7 or a pump 9 for circulating slurry.Type: GrantFiled: September 20, 2005Date of Patent: September 7, 2010Assignee: Taiheiyo Cement CorporationInventors: Shinichiro Saito, Soichiro Okamura, Tsuyoshi Matsura
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Patent number: 7776299Abstract: A process for removal of SO2 in off-gases having a temperature of 30-150° C. and containing 0.001-1 vol % SO2 in which the SO2 is oxidised to H2 SO4 by spraying an aqueous solution of H2O2 into the off-gas upstream of an aerosol filter removing the produced sulphuric acid from the off-gas.Type: GrantFiled: December 4, 2003Date of Patent: August 17, 2010Assignee: Haldor Topsøe A/SInventors: Peter Schoubye, Kurt Agerbæk Christensen, Morten Thellefsen Nielsen
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Patent number: 7772449Abstract: The present invention provides a process for treating a hydrocarbon feed gas stream containing acid gases (CO2, H2S and mercaptans) by contacting the feed gas stream in a multi-section caustic tower, the bottom sections employing a recirculating caustic solution to remove the CO2 and H2S down to low single digits parts per million concentration and the upper sections employing a stronger caustic solution on a once-through basis to produce a mercaptans depleted gas stream.Type: GrantFiled: August 1, 2007Date of Patent: August 10, 2010Assignee: Stone & Webster Process Technology, Inc.Inventors: Sabah A. Kurukchi, Joseph M. Gondolfe, Ming Wang
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Publication number: 20100186590Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.Type: ApplicationFiled: January 28, 2010Publication date: July 29, 2010Applicant: BASF SEInventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Rupert Wagner, Ute Lichtfers, Erika Dengler
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Patent number: 7758673Abstract: The present invention relates to a process for removing carbon dioxide and optionally hydrogen sulphide and/or COS from a gas stream containing these compounds by washing the gas with an aqueous washing solution containing water, sulfolane and a secondary or tertiary amine derived from ethanolamine. More particularly the invention relates to the process described above, the process being carried out in the presence of a primary or secondary amine compound in an amount between 0.5 and 15 wt. % based on water, sulfolane and amine. The invention further relates to an absorbent liquid to be used in the above process.Type: GrantFiled: January 14, 2003Date of Patent: July 20, 2010Assignee: Shell Oil CompanyInventors: Theodorus Johannes Brok, Rudolf Johannes Mathilda Groenen, Jeanine Marie Klinkenbijl, Mariette Catharina Knaap
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Patent number: 7749309Abstract: Disclosed is a method for deacidifying a fluid stream containing acidic gases as contaminants, according to which the fluid stream is brought into intimate contact with a washing liquid in at least one absorption step. Said washing liquid represents an aqueous solution containing a) tertiary aliphatic alkanolamines (alkanolamine A), at least 30 percent by weight of said tertiary aliphatic alkanolamines being 3-dimethylamino-1-propanol, and b) secondary aliphatic amines (activator B), at least 20 percent by weight of said secondary aliphatic amines being piperazin. The fluid stream which has been essentially purified of the acidic gases is then separated from the washing liquid that is loaded with acidic gases.Type: GrantFiled: March 4, 2003Date of Patent: July 6, 2010Assignee: BASF AktiengesellschaftInventors: Norbert Asprion, Christoph Grossmann
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Publication number: 20100154637Abstract: The invention relates to a process for the purification of a gaseous mixture containing mercaptans and other acid gases comprising a stage of bringing said gaseous mixture into contact with an absorbent solution comprising an alkanolamine, a C2-C4 thioalkanol and water.Type: ApplicationFiled: January 16, 2007Publication date: June 24, 2010Inventor: SERGE CAPDEVILLE
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Patent number: 7736420Abstract: The invention relates to an improvement in apparatus and process for the formation of a complex of Lewis acidic or Lewis basic gases in a reactive liquid of opposite character and for the breaking (fragmentation) of said complex associated with the recovery of the Lewis gas therefrom. The improvement resides in forming finely divided droplets of reactive liquid and controlling the temperature, pressure and concentration of said Lewis gas of opposite character to provide for (a) the formation of said complex between said gas and reactive liquid or (b) the breaking of said complex and the recovery of the atomized droplets of reactive liquid.Type: GrantFiled: May 19, 2006Date of Patent: June 15, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Wayne Thomas McDermott, Philip Bruce Henderson, Daniel Joseph Tempel, Ronald Martin Pearlstein, James Joseph Hart, Rosaleen Patricia Morris-Oskanian, Diwakar Garg
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Publication number: 20100132556Abstract: Methods of sequestering carbon dioxide (CO2) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.Type: ApplicationFiled: February 2, 2010Publication date: June 3, 2010Inventors: Brent R. Constantz, Andrew Youngs, Philip Brian Tuet, Sidney Omelon, Kasra Farsad, Ryan J. Gilliam, Valentin Decker, Donald W. Kirk, J. Douglas Way, Allen J. Bard, Robert Danziger, Miguel Fernandez, Cecily Ryan
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Patent number: 7727311Abstract: Installation for gas treatment by a liquid phase comprising a) a column (C) that comprises means (1) for introducing gas at one end of said column, means (9) for drawing off gas from the other end of column (C) and, from upstream to downstream in the direction of circulation of the liquid phase: a first internal (2) that comprises means for distribution of a liquid phase, a first bed (6) that comprises a packing or catalytic particles, a second internal (3) that comprises means for separating liquid/gas mixture (19, 20) that is obtained from first bed (6), first means (32, 4) for collecting and evacuating the separated liquid phase, means (100) for passing through internal (3) of the treated gas, and distribution means (31, 101) of a liquid phase with said gas, a second bed (8), second means (10) for collecting and evacuating the liquid phase at the lower outlet of column (C), b) Means for recycling the collected liquid phase.Type: GrantFiled: September 12, 2005Date of Patent: June 1, 2010Assignee: Institut Francais du PetroleInventors: Ludovic Raynal, Eric Lemaire, Jean-Louis Ambrosino