Plural Layers (e.g., Laminated Barrier, Etc.) Patents (Class 96/11)
  • Patent number: 8257466
    Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.
    Type: Grant
    Filed: November 14, 2011
    Date of Patent: September 4, 2012
    Assignee: Idatech, LLC
    Inventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
  • Publication number: 20120204716
    Abstract: A porously coated, densely sintered ceramic membrane, which can be produced from a green membrane and subsequent sintering. The membrane is coated with ceramic material, which contains noble metals, which can be produced by application and subsequent thermal treatment. The noble metals are contained at a concentration of 2.5 to 5 mass percent.
    Type: Application
    Filed: May 19, 2010
    Publication date: August 16, 2012
    Applicants: BORSIG PROCESS HEAT EXCHANGER GMBH, THYSSENKRUPP UHDE GMBH
    Inventors: Steffen Schirrmeister, Bernd Langanke, Bjoern Hoting
  • Patent number: 8241395
    Abstract: Disclosed are processes for preparing conductive glass-ceramic membranes and methods of using them in hydrogen or proton separation.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: August 14, 2012
    Assignee: Schott Corporation
    Inventors: Mark J. Davis, Samuel David Conzone, Paula Vullo
  • Publication number: 20120187046
    Abstract: Sulfur contaminants, such as elemental sulfur (S8), hydrogen sulfide and other sulfur components in fluids (e.g., air, natural gas, and other gases, as well as water and other liquids) are removed using a silicone-based chemical filter/bath. In one embodiment, a silicone-based chemical filter includes a membrane having a cross-linked silicone that is a reaction product of an olefin and a polyhydrosiloxane. For example, sulfur contaminants in air may be removed by passing the air through the membrane before the air enters a data center or other facility housing computer systems. In another embodiment, a silicone-based chemical bath includes a housing having an inlet port, an outlet port, and a chamber containing a silicone oil. For example, sulfur contaminants in air may be removed by passing the air through the silicone oil in the chamber before the air enters a data center or other facility housing computer systems.
    Type: Application
    Filed: January 21, 2011
    Publication date: July 26, 2012
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III, Timothy J. Tofil
  • Patent number: 8226751
    Abstract: A composite membrane material characterized by comprising a hydrogen-permeable membrane which is selectively permeable to hydrogen and is formed by rolling to a thickness of 30 ?m or less which is difficult for the membrane by itself to retain its shape, and a shape-retention mesh which is disposed on at least one side of the hydrogen-permeable membrane and is composed of a wire of a high-melting metal which does not cause thermal diffusion into the hydrogen-permeable membrane, wherein the hydrogen-permeable membrane and the shape-retention mesh are superposed and subjected to a pleat processing in a non-bonded state so that they are separable and the hydrogen-permeable membrane has a surface area increased at least 3 times per unit area. This material is used to constitute a hydrogen separation element.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: July 24, 2012
    Assignee: Nippon Seisen Co., Ltd.
    Inventors: Hideomi Ishibe, Hiroyasu Taga
  • Patent number: 8226750
    Abstract: A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.
    Type: Grant
    Filed: May 5, 2009
    Date of Patent: July 24, 2012
    Assignee: Genesis Fueltech, Inc.
    Inventor: Peter David DeVries
  • Patent number: 8221525
    Abstract: A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: July 17, 2012
    Assignee: Gas Technology Institute
    Inventors: Shiguang Li, Qinbai Fan
  • Publication number: 20120174790
    Abstract: A water vapor permeable membrane is provided comprising a dense layer and a support layer that are adjacent to each other, wherein the dense layer contains voids with a void length of 0.1 ?m or less and the dense layer has a thickness of 0.1 ?m or more and 2 ?m or less while in the support layer, void (a), i.e. the void with the largest length in the 2 ?m thick region measured from the boundary between the dense layer and the support layer into the support layer, has a length of 0.3 ?m or more and void (b), i.e. the void with the largest length in the region ranging between 2 ?m and 4 ?m measured from the boundary into the support layer, has a length of 0.5 ?m or more, the length of the void (b) being larger than that of the void (a). A water vapor permeable membrane having both a high water vapor permeability and a low air leakage is provided.
    Type: Application
    Filed: August 21, 2009
    Publication date: July 12, 2012
    Applicant: Toray Industries, Inc.
    Inventors: Masahiro Osabe, Kazumi Tanaka, Hiroyuki Sugaya
  • Publication number: 20120174791
    Abstract: A method of forming a gas separation membrane including: depositing a first hydrophilic polymer solution; depositing on top of the first hydrophilic polymer solution a second, different hydrophilic polymer solution, thereby forming a two-layer polymer solution; forming the two-layer polymer solution into one of a forward osmosis membrane and a pressure retarded osmosis membrane by bringing the second, different hydrophilic polymer solution into contact with water to form the dense layer; coating one of the forward osmosis membrane and the pressure retarded osmosis membrane with a thin layer of a third, different, hydrophilic polymer more pH tolerant than the first and second hydrophilic polymer solutions to form a dense rejection layer thereon; and exposing one of the coated forward osmosis membrane and the coated pressure retarded osmosis membrane to a high pH solution. A gas separation membrane formed from the foregoing process.
    Type: Application
    Filed: January 11, 2012
    Publication date: July 12, 2012
    Inventor: John R. Herron
  • Publication number: 20120174772
    Abstract: In a device and a method for mixing and exchanging fluids, a first chamber is a mixing chamber with static mixing elements. First and second fluids flow through the first chamber in a mixing fluid flow direction. A second chamber adjacent the first chamber is a fluid feeding or discharge chamber through which the second fluid flows. A semipermeable membrane separates the volume of the first chamber from the volume of the second chamber. The membrane is impermeable to molecules or molecule agglomerations of the first fluid and permeable to molecules or molecule agglomerations of the second fluid. The membrane is made of a material or is coated with a material to which the molecules or molecule agglomerations of one of the two fluids have a lower affinity. Alternatively, or in addition, the membrane is elastic and spans a support wall with holes.
    Type: Application
    Filed: August 2, 2010
    Publication date: July 12, 2012
    Applicant: FRANZ HAAS WAFFEL- UND KEKSANLAGEN-INDUSTRIE GMBH
    Inventor: Alex Knobel
  • Publication number: 20120167768
    Abstract: A gas separation membrane system and a method of preparing such gas separation membrane system by providing a porous support upon which is supported a membrane layer comprising a first gas-selective material and having a membrane thickness and removing therefrom a substantial portion of the first gas-selective material from the membrane layer by the use of an ultra-fine abrasive to thereby provide the membrane layer having a reduced membrane thickness. A second gas-selective material is deposited upon the membrane layer having the reduced membrane thickness to provide an overlayer of the second gas-selective material having an overlayer thickness so as to thereby provide the gas separation membrane system having the membrane layer of the reduced membrane thickness and the overlayer of the overlayer thickness.
    Type: Application
    Filed: March 14, 2012
    Publication date: July 5, 2012
    Applicant: SHELL OIL COMPANY
    Inventors: Alan Anthony DEL PAGGIO, John Charles SAUKAITIS
  • Patent number: 8211539
    Abstract: A hydrogen separator comprising a porous substrate composed mainly of a ceramic having a large number of pores connecting from one surface of the substrate to other surface, and a hydrogen-separating layer made of a hydrogen permselective metal formed on the porous substrate via an intermediate layer made of an electron-conductive ceramic. The hydrogen separator hardly generates defects such as peeling, cracks or the like in the hydrogen-separating layer and is suitable for use even when the hydrogen separator is exposed to a heat cycle, used under high temperature conditions or/and used for long-term.
    Type: Grant
    Filed: February 18, 2011
    Date of Patent: July 3, 2012
    Assignee: NGK Insulators, Ltd.
    Inventors: Kenichi Noda, Osamu Sakai
  • Patent number: 8210360
    Abstract: Composite membranes that are adapted for separation, purification, filtration, analysis, reaction and sensing. The composite membranes can include a porous support structure having elongate pore channels extending through the support structure. The composite membrane also includes an active layer comprising an active layer material, where the active layer material is completely disposed within the pore channels between the surfaces of the support structure. The active layer is intimately integrated within the support structure, thus enabling great robustness, reliability, resistance to mechanical stress and thermal cycling, and high selectivity. Methods for the fabrication of composite membranes are also provided.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: July 3, 2012
    Assignee: Synkera Technologies, Inc.
    Inventors: Dmitri Routkevitch, Oleg G. Polyakov
  • Patent number: 8197578
    Abstract: A liquid degasser for a space device including a gas permeable material configured for contact with a flow of liquid to be de-gassed on one side and a vacuum on the other side, and wherein the gas permeable material allows gas in the liquid to diffuse to the vacuum to remove the gas from the liquid.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: June 12, 2012
    Assignee: Busek Company, Inc.
    Inventors: Vladimir J. Hruby, Nate Demmons, Tom Roy, Doug Spence, Eric Ehrbar, Jurg Zwahlen, Charles Gasdaska
  • Patent number: 8197576
    Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.
    Type: Grant
    Filed: January 22, 2009
    Date of Patent: June 12, 2012
    Assignee: Renaissance Energy Research Corporation
    Inventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
  • Patent number: 8192524
    Abstract: Disclosed herein are processes for producing a CO2-depleted product gas stream. The processes involve feeding a natural gas feed stream comprising greater than about 10 vol % CO2 to at least one membrane unit comprising a plurality of polymer membranes to provide a CO2-rich permeate comprising at least 95 vol % CO2 and a CO2-depleted product gas stream. The polymer membranes comprise a crosslinked polyimide polymer having covalent ester crosslinks and have a CO2 permeance of at least 20 GPU and a CO2/CH4 selectivity of greater than 20, at 35 degrees C. and a feed pressure of 100 psia. Also disclosed herein is an apparatus incorporating the crosslinked polyimide polymer for producing a CO2-depleted product gas stream from a natural gas feed stream.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: June 5, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Daniel Chinn, Siji Okeowo, Jeff D. Euhus, Shabbir Husain
  • Patent number: 8182591
    Abstract: A vertically directed dryer unit (10) for compressed air, comprising a dryer cartridge (22) which, together with a housing (16, 18, 20), defines an inlet head area (92) and an outlet head area (72). A plurality of hollow membrane fibers (30) extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve (90) is provided between the outlet head area (72) and an outlet (74) of the drier unit. Said valve only opens when the pressure in the outlet head area (72) produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers (30) via a throttle element (70).
    Type: Grant
    Filed: September 27, 2005
    Date of Patent: May 22, 2012
    Assignee: Durr Dental GmbH & Co. KG
    Inventors: Alfred Deubler, Varleriu Fischer
  • Patent number: 8182590
    Abstract: A process for forming a porous nanoscale membrane is described. The process involves applying a nanoscale film to one side of a substrate, where the nanoscale film includes a semiconductor material; masking an opposite side of the substrate; etching the substrate, beginning from the masked opposite side of the substrate and continuing until a passage is formed through the substrate, thereby exposing the film on both sides thereof to form a membrane; and then simultaneously forming a plurality of randomly spaced pores in the membrane. The resulting porous nanoscale membranes, characterized by substantially smooth surfaces, high pore densities, and high aspect ratio dimensions, can be used in filtration devices, microfluidic devices, fuel cell membranes, and as electron microscopy substrates.
    Type: Grant
    Filed: May 1, 2006
    Date of Patent: May 22, 2012
    Assignee: University of Rochester
    Inventors: Christopher C. Striemer, Philippe M. Fauchet, Thomas R. Gaborski, James L. McGrath
  • Publication number: 20120118149
    Abstract: A manganese oxide contains M1, optionally M2, Mn and O. M1 is selected from the group consisting of In, Sc, Y, Dy, Ho, Er, Tm, Yb and Lu. M2 is different from M1, and M2 is selected from the group consisting of Bi, In, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. These ceramic materials are hexagonal in structure, and provide superior materials for gas separation and oxygen storage.
    Type: Application
    Filed: October 28, 2011
    Publication date: May 17, 2012
    Inventors: Bogdan Dabrowski, Steven Remsen
  • Patent number: 8177889
    Abstract: A gas removal device 1 includes a decompression chamber 2 with an inlet 11 and an outlet 12 through which a liquid to be degassed flows therein and thereout, and a degassing element 5 that is accommodated in the decompression chamber 2 while having one end connected to the inlet 11 and another end connected to the outlet 12, and that allows the liquid to be degassed entering into the inlet 11 to pass through the degassing element 5. The degassing element 5 includes a tube bundle 15 composed of a plurality of flexible gas-permeable tubes 151, and a tying member 16 tying the plurality of gas-permeable tubes 151 to form the tube bundle 15. The tube bundle 15 is bent in a shape of coil with multiple turns in such a manner that a portion tied by the tying member 16 is included in a bent portion BP.
    Type: Grant
    Filed: September 19, 2007
    Date of Patent: May 15, 2012
    Assignee: Nitto Denko Corporation
    Inventor: Hajime Ooya
  • Patent number: 8177883
    Abstract: A container having a plurality of walls, and at least one inlet and/or outlet, said container including an apparatus for controlling the composition of gases within the container, the apparatus including at least one sensor, at least one controller and at least one gas permeable membrane, through which membrane different gases can pass at different rates, said membrane dividing the container into a first region being for holding cargo and a second region defining a gas buffer region, and said membrane being permeable permitting for nitrogen, oxygen and carbon dioxide at different flow rates, wherein the buffer region is in communication with the ambient atmosphere through one or more vacuum pump(s).
    Type: Grant
    Filed: February 13, 2009
    Date of Patent: May 15, 2012
    Assignee: Maersk Container Industri A/S
    Inventors: Gert Jørgensen, Niels Nielsen Poulsen
  • Patent number: 8177890
    Abstract: A Pd alloy membrane and method of making are described.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: May 15, 2012
    Assignee: The Ohio State University
    Inventors: Krenar Shqau, Hendrik Verweij
  • Patent number: 8177884
    Abstract: A device for use in a fluid system includes a fuel channel for receiving fuel having dissolved gas therein. A gas permeable membrane supported by a porous support, the gas permeable membrane in communication with the fuel channel. A gas-removal channel adjacent the gas permeable membrane for receiving the dissolved gas from the fuel through the gas permeable membrane and the porous support.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: May 15, 2012
    Assignee: United Technologies Corporation
    Inventors: Wayde R. Schmidt, Haralambos Cordatos, Slade R. Culp
  • Patent number: 8172923
    Abstract: An apparatus and method for maintaining low gas velocity variation across a diffuser membrane during the vent-up of a vacuum chamber is disclosed. The diffuser membrane permeability and the pressure conditions across the membrane are chosen to minimize variation in gas flow velocity through the membrane during the vent-up cycle. This reduces re-distribution of particles from a vacuum chamber onto sensitive substrates in the vacuum chamber during vent-up from sub-atmospheric pressure to atmospheric pressure.
    Type: Grant
    Filed: January 21, 2009
    Date of Patent: May 8, 2012
    Assignee: Entegris, Inc.
    Inventors: Christopher Vroman, Marshall Randolph
  • Patent number: 8167983
    Abstract: The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: May 1, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Stefan Bernhardt, Rolf Schneider, Roland Wursche, Franz-Erich Baumann
  • Patent number: 8167982
    Abstract: A vertically directed dryer unit for compressed air, comprising a dryer cartridge which, together with a housing, defines an inlet head area and an outlet head area. A plurality of hollow membrane fibers extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve is provided between the outlet head area and an outlet of the drier unit. Said valve only opens when the pressure in the outlet head area produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers via a throttle element.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: May 1, 2012
    Assignee: Beko Technologies GmbH
    Inventors: Alfred Deubler, Valeriu Fischer
  • Patent number: 8167976
    Abstract: A gas separation membrane system and a method of preparing such gas separation membrane system by providing a porous support upon which is supported a membrane layer comprising a first gas-selective material and having a membrane thickness and removing therefrom a substantial portion of the first gas-selective material from the membrane layer by the use of an ultra-fine abrasive to thereby provide the membrane layer having a reduced membrane thickness. A second gas-selective material is deposited upon the membrane layer having the reduced membrane thickness to provide an overlayer of the second gas-selective material having an overlayer thickness so as to thereby provide the gas separation membrane system having the membrane layer of the reduced membrane thickness and the overlayer of the overlayer thickness.
    Type: Grant
    Filed: February 18, 2008
    Date of Patent: May 1, 2012
    Assignee: Shell Oil Company
    Inventors: Alan Anthony Del Paggio, John Charles Saukaitis
  • Patent number: 8163065
    Abstract: A carbon dioxide permeable membrane is described. In some embodiments, the membrane includes a body having a first side and an opposite second side; a plurality of first regions formed from a molten carbonate having a temperature of about 400 degrees Celsius to about 1200 degrees Celsius, the plurality of first regions forming a portion of the body and the plurality of first regions extending from the first side of the body to the second side of the body; a plurality of second regions formed from an oxygen conductive solid oxide, the plurality of second regions combining with the plurality of first regions to form the body and the plurality of second regions extending from the first side of the body to the second side of the body; and the body is configured to allow carbon dioxide to pass from the first side to the second side.
    Type: Grant
    Filed: March 21, 2011
    Date of Patent: April 24, 2012
    Assignee: The Trustees of Columbia University in the City of New York
    Inventors: Klaus S. Lackner, Alan C. West, Jennifer L. Wade
  • Patent number: 8157900
    Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: April 17, 2012
    Assignee: Idatech, LLC
    Inventors: William A. Pledger, Vernon Wade Popham, R. Todd Studebaker, Kyle Taylor
  • Patent number: 8157891
    Abstract: A membrane cartridge is manufactured by repeatedly folding and joining two strips of membrane to form a cross-pleated cartridge with a stack of openings or fluid passageways configured in an alternating cross-flow arrangement. The cartridge can be modified for other flow configurations including co-flow and counter-flow arrangements. Methods for manufacturing such cross-pleated membrane cartridges, as well as apparatus used in the manufacturing process are described. Cross-pleated membrane cartridges comprising water-permeable membranes can be used in a variety of applications, including in heat and water vapor exchangers. In particular they can be incorporated into energy recovery ventilators (ERVs) for exchanging heat and water vapor between air streams being directed into and out of buildings.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: April 17, 2012
    Assignee: DPoint Technologies Inc.
    Inventors: Greg Montie, James Franklin Dean, Curtis Mullen, Robert Hill
  • Publication number: 20120079944
    Abstract: There is described a process for producing carbon membranes suitable for gas separation, comprising the steps of: a) coating a porous substrate with a solution of at least one organic polymer which can be converted to a carbon membrane by pyrolysis, b) drying the polymer coating on the porous substrate by removing the solvent, c) pyrolyzing the polymer coating on the porous substrate to form the carbon membrane suitable for gas separation, it being possible to conduct any of steps a) to c) or the sequence of steps a) to c) more than once, and the pyrolysis in step c) being effected at a temperature higher than the baking temperature of the porous substrate.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 5, 2012
    Applicant: BASF SE
    Inventors: Hartwig VOß, Jörg Therre
  • Publication number: 20120079943
    Abstract: The use of solutions of ethylenically unsaturated polyesters for production of carbon membranes suitable for gas separation, and a process for producing carbon membranes suitable for gas separation, comprising the steps of: a) coating a porous substrate with a solution of ethylenically unsaturated polyester, b) drying the polyester coating on the porous substrate by removing the solvent, c) pyrolyzing the polyester coating on the porous substrate to form the carbon membrane suitable for gas separation, it being possible to conduct any of steps a) to c) or the sequence of steps a) to c) more than once.
    Type: Application
    Filed: September 30, 2011
    Publication date: April 5, 2012
    Applicant: BASF SE
    Inventors: Hartwig VOß, Jörg Therre
  • Patent number: 8147595
    Abstract: There is provided a membrane material for a gas holder having abrasion resistance and flex resistance usable as a gas holder, in addition to strength of a base fabric, and having high gas barrier properties. A membrane material for a gas holder, which is used in a gas holder for storing or recovering gas, includes at least 4 layers of a protective layer, a base fabric layer, a gas barrier layer and a protective layer laminated in this order.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: April 3, 2012
    Assignees: Teijin Fibers Limited, Skypia Co., Ltd.
    Inventors: Satoshi Nagase, Hiroyuki Mori, Mikio Kusaka, Yasuo Motoishi
  • Patent number: 8147596
    Abstract: A hydrogen-permeable film has a ceramic material of a nitride or oxide of a metal element belonging to group IVB, VB or VIB and hydrogen-permeable metal particles of at least one kind selected from palladium (Pd), niobium (Nb), vanadium (V), tantalum (Ta) and alloys thereof dispersed in the ceramic material. A ratio of the hydrogen-permeable metal particles in the hydrogen-permeable film is 20 to 70 mass %, and a thickness of the hydrogen-permeable film is 5 to 1,000 nm.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: April 3, 2012
    Assignee: Mikuni Corporation
    Inventor: Katsuhiko Fukui
  • Publication number: 20120073791
    Abstract: A core unit for an energy recovery system for exchanging heat and vapor between two independent intake and exhaust airstreams without intermixing thereof, the core unit having a fibrous microporous support substrate and a sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units, and wherein the sulfonated block copolymer is laminated on the microporous support substrate
    Type: Application
    Filed: September 29, 2010
    Publication date: March 29, 2012
    Inventor: Donn Dubois
  • Publication number: 20120067207
    Abstract: A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.
    Type: Application
    Filed: May 27, 2010
    Publication date: March 22, 2012
    Inventors: Paul Jason Williams, Brendan Dermot Murray
  • Patent number: 8137442
    Abstract: Process for producing at least one nanoporous layer of nanoparticles chosen from nanoparticles of a metal oxide, nanoparticles of metal oxides, and mixtures of said nanoparticles, on a surface of a substrate, in which at least one colloidal sol, in which said nanoparticles are dispersed and stabilized, is injected into a thermal plasma jet which sprays said nanoparticles onto said surface. Nanoporous layer and device, especially a separation device, comprizing said layer.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: March 20, 2012
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Bruno Pintault, David Guenadou, Luc Bianchi, Philippe Belleville, Karine Valle, Christophe Boscher, Joël Toulc'Hoat
  • Publication number: 20120060687
    Abstract: A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.
    Type: Application
    Filed: May 27, 2010
    Publication date: March 15, 2012
    Inventors: Brendan Dermot Murray, Paul Jason Williams
  • Patent number: 8133306
    Abstract: A gas diffusion substrate includes a non-woven network of carbon fibres, the carbon fibres are graphitised but the non-woven network has not been subjected to a graphitisation process. A mixture of graphitic particles and hydrophobic polymer is disposed within the network. The longest dimension of at least 90% of the graphitic particles is less than 100 ?m. A process for manufacturing gas diffusion substrates includes depositing a slurry of graphitised carbon fibres onto a porous bed forming a wet fibre network, preparing a suspension of graphitic particles and hydrophobic polymer, applying onto, and pulling the suspension into, the network, and drying and firing the network. Another process includes mixing a first slurry of graphitic particles and hydrophobic polymer with a second slurry of graphitised carbon fibres and liquid forming a third slurry, depositing the third slurry onto a porous bed forming a fibre-containing layer, and drying and firing the layer.
    Type: Grant
    Filed: June 15, 2005
    Date of Patent: March 13, 2012
    Assignees: Johnson Matthey Public Limited Company, Technical Fibre Products Limited
    Inventors: George Thomas Quayle, Julia Margaret Rowe, Jonathan David Brereton Sharman, Julian Andrew Siodlak, Nigel Julian Walker, Andrew James Fletcher
  • Patent number: 8118910
    Abstract: A layered filter membrane with improved anti-clogging characteristics is provided. In one embodiment, a filter membrane includes multiple polymer layers, each with different pore diameters formed by stretching the polymer layers. Furthermore, the multiple filter layers are coupled together before being stretched and the different pore sizes are formed during co-stretching of the filter layers.
    Type: Grant
    Filed: March 23, 2009
    Date of Patent: February 21, 2012
    Assignee: General Electric Company
    Inventors: Nusrat Farzana, David Kazemi
  • Patent number: 8118920
    Abstract: In various embodiments, a support system includes a multi-layer cover sheet with a number of layers. In certain embodiments, a source to move air inside and outside the multi-layer cover sheet can be provided. The source can include a source of positive pressure or negative pressure.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: February 21, 2012
    Assignee: KCI Licensing, Inc.
    Inventors: John H. Vrzalik, Alan L. Bartlett, Royce Johnson
  • Patent number: 8110027
    Abstract: An air separation module and blanket has an air separation module having an air inlet, an oxygen outlet and a nitrogen outlet. At least one tank has air separation elements for separating oxygen from air, and delivers the separated oxygen to the oxygen outlet, and delivers nitrogen to the nitrogen outlet. A resistance heating element is positioned between the blanket and the air separation module. Further, an inventive blanket for use with the air separation module is also disclosed and claimed.
    Type: Grant
    Filed: April 17, 2009
    Date of Patent: February 7, 2012
    Assignee: Hamilton Sundstrand Corporation
    Inventor: William Joseph Beeson
  • Patent number: 8110022
    Abstract: A hydrogen purifier utilizing a hydrogen permeable membrane, and a gas-tight seal, where the seal is uses a low temperature melting point metal, which upon heating above the melting point subsequently forms a seal alloy with adjacent metals, where the alloy has a melting point above the operational temperature of the purifier. The purifier further is constructed such that a degree of isolation exists between the metal that melts to form the seal and the active area of the purifier membrane, so that the active area of the purifier membrane is not corrupted. A method of forming a hydrogen purifier utilizing a hydrogen permeable membrane with a seal of the same type is also disclosed.
    Type: Grant
    Filed: April 16, 2009
    Date of Patent: February 7, 2012
    Assignee: Genesis Fueltech, Inc.
    Inventor: Peter David DeVries
  • Patent number: 8110026
    Abstract: A gas diffusion barrier contains a polymer matrix and a functional graphene which displays no signature of graphite and/or graphite oxide, as determined by X-ray diffraction.
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: February 7, 2012
    Assignee: The Trustees of Princeton University
    Inventors: Robert Prud'Homme, Christopher O'Neil, Bulent Ozbas, Ilhan Aksay, Richard Register, Douglas Adamson
  • Patent number: 8105424
    Abstract: A hydrogen permeation/separation thin membrane including a Ni—Ti—Nb alloy. The Ni—Ti—Nb alloy is a cast foil material obtained by roll quenching and a refining heat treatment. The membrane has a thickness of 0.07 mm or less. The Ni—Ti—Nb alloy has the following: (a) a composition consisting of 10 to 47 atomic % of Nb, 20 to 52 atomic % of Ti, and a remainder containing 20 to 48 atomic % of Ni and inevitable impurities; and (b) an alloy structure where fine particles of a Nb-based solid solution alloy, in which Nb forms a solid solution with Ni and Ti in Nb, are dispersed in a basic structure made of a Ni—Ti(Nb) intermetallic compound formed of a solid solution of a Ni—Ti intermetallic compound, in which part of Ti thereof is replaced by Nb.
    Type: Grant
    Filed: March 8, 2007
    Date of Patent: January 31, 2012
    Assignee: Mitsubishi Materials Corporation
    Inventors: Koichi Kita, Kiyoshi Aoki, Kazuhiro Ishikawa
  • Patent number: 8101010
    Abstract: A porous structure sealed at both ends for use in a gas separation module; and a method for separating components of a gas stream.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: January 24, 2012
    Assignee: Corning Incorporated
    Inventors: Joel Edward Clinton, Curtis Robert Fekety, Yunfeng Gu, Zhen Song
  • Publication number: 20120012004
    Abstract: The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.
    Type: Application
    Filed: July 15, 2011
    Publication date: January 19, 2012
    Inventors: J. Douglas Way, Oyvind Hatlevik
  • Publication number: 20120012001
    Abstract: A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.
    Type: Application
    Filed: July 16, 2010
    Publication date: January 19, 2012
    Applicant: GAS TECHNOLOGY INSTITUTE
    Inventors: Shiguang Li, Qinbai Fan
  • Publication number: 20120006194
    Abstract: The present invention provides methods for making improved zeolite and crystalline silicoaluminophosphate (SAPO) membranes, in particular SAPO-34 membranes, on a porous support through improved removal of the organic structure-directing templating agent. A calcining step is performed in an oxygen free atmosphere, such as under a vacuum or inert gas, to remove the organic templating agent. By removing the templating agent in the absence of oxygen, the calcination step can remove a greater amount of the templating agent than comparable template removal steps conducted in the presence of oxygen and the calcination step can be conducted at significantly lower temperatures. The membranes of the present invention provide increased permeance while maintaining comparable selectivity for gas separations, particularly carbon dioxide (CO2) and methane (CH4) separations and separations at high temperatures.
    Type: Application
    Filed: April 28, 2011
    Publication date: January 12, 2012
    Applicant: The Regents of the University of Colorado, a body corporate
    Inventors: John L. Falconer, Richard D. Noble, Begum Tokay, Yanfeng Zhang
  • Patent number: 8092581
    Abstract: A gas separation membrane has: a polymeric microporous membrane which has a polyolefin as a main component, and which is manufactured by wet phase separation process, and has a porosity of 20 to 80%, an average pore diameter of 1 to 100 nm and a piercing strength at 100° C. of 2 to 50 N; and a gas-separating thin film, which is provided on at least one surface, and/or the interior of the polymeric microporous membrane, and which comprises a fluorine-containing gas-separating resin as a main component, and has an average thickness of 0.01 ?m to less than 0.4 ?m. The gas separation membrane having an oxygen-nitrogen separation factor not smaller than 1.4.
    Type: Grant
    Filed: April 25, 2007
    Date of Patent: January 10, 2012
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Sho Sugiyama, Takuya Hasegawa, Takahiko Kondo, Hidetoshi Masugi, Takashi Nozaki