Plural Layers (e.g., Laminated Barrier, Etc.) Patents (Class 96/11)
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Patent number: 8257466Abstract: Hydrogen-producing fuel processing systems, hydrogen purification membranes, hydrogen purification devices, fuel processing and fuel cell systems that include hydrogen purification devices, and methods for operating the same. In some embodiments, operation of the fuel processing system is initiated by heating at least the reforming region of the fuel processing system to at least a selected hydrogen-producing operating temperature. In some embodiments, an electric heater is utilized to perform this initial heating. In some embodiments, use of the electric heater is discontinued after startup, and a burner or other combustion-based heating assembly combusts a fuel to heat at least the hydrogen producing region, such as due to the reforming region utilizing an endothermic catalytic reaction to produce hydrogen gas.Type: GrantFiled: November 14, 2011Date of Patent: September 4, 2012Assignee: Idatech, LLCInventors: David J. Edlund, William A. Pledger, R. Todd Studebaker
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Publication number: 20120204716Abstract: A porously coated, densely sintered ceramic membrane, which can be produced from a green membrane and subsequent sintering. The membrane is coated with ceramic material, which contains noble metals, which can be produced by application and subsequent thermal treatment. The noble metals are contained at a concentration of 2.5 to 5 mass percent.Type: ApplicationFiled: May 19, 2010Publication date: August 16, 2012Applicants: BORSIG PROCESS HEAT EXCHANGER GMBH, THYSSENKRUPP UHDE GMBHInventors: Steffen Schirrmeister, Bernd Langanke, Bjoern Hoting
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Patent number: 8241395Abstract: Disclosed are processes for preparing conductive glass-ceramic membranes and methods of using them in hydrogen or proton separation.Type: GrantFiled: June 11, 2008Date of Patent: August 14, 2012Assignee: Schott CorporationInventors: Mark J. Davis, Samuel David Conzone, Paula Vullo
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Publication number: 20120187046Abstract: Sulfur contaminants, such as elemental sulfur (S8), hydrogen sulfide and other sulfur components in fluids (e.g., air, natural gas, and other gases, as well as water and other liquids) are removed using a silicone-based chemical filter/bath. In one embodiment, a silicone-based chemical filter includes a membrane having a cross-linked silicone that is a reaction product of an olefin and a polyhydrosiloxane. For example, sulfur contaminants in air may be removed by passing the air through the membrane before the air enters a data center or other facility housing computer systems. In another embodiment, a silicone-based chemical bath includes a housing having an inlet port, an outlet port, and a chamber containing a silicone oil. For example, sulfur contaminants in air may be removed by passing the air through the silicone oil in the chamber before the air enters a data center or other facility housing computer systems.Type: ApplicationFiled: January 21, 2011Publication date: July 26, 2012Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Dylan J. Boday, Joseph Kuczynski, Robert E. Meyer, III, Timothy J. Tofil
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Patent number: 8226751Abstract: A composite membrane material characterized by comprising a hydrogen-permeable membrane which is selectively permeable to hydrogen and is formed by rolling to a thickness of 30 ?m or less which is difficult for the membrane by itself to retain its shape, and a shape-retention mesh which is disposed on at least one side of the hydrogen-permeable membrane and is composed of a wire of a high-melting metal which does not cause thermal diffusion into the hydrogen-permeable membrane, wherein the hydrogen-permeable membrane and the shape-retention mesh are superposed and subjected to a pleat processing in a non-bonded state so that they are separable and the hydrogen-permeable membrane has a surface area increased at least 3 times per unit area. This material is used to constitute a hydrogen separation element.Type: GrantFiled: September 15, 2006Date of Patent: July 24, 2012Assignee: Nippon Seisen Co., Ltd.Inventors: Hideomi Ishibe, Hiroyasu Taga
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Patent number: 8226750Abstract: A hydrogen purifier utilizing a hydrogen-permeable membrane to purify hydrogen from mixed gases containing hydrogen is disclosed. Improved mechanical support for the permeable membrane is described, enabling forward or reverse differential pressurization of the membrane, which further stabilizes the membrane from wrinkling upon hydrogen uptake.Type: GrantFiled: May 5, 2009Date of Patent: July 24, 2012Assignee: Genesis Fueltech, Inc.Inventor: Peter David DeVries
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Patent number: 8221525Abstract: A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.Type: GrantFiled: July 16, 2010Date of Patent: July 17, 2012Assignee: Gas Technology InstituteInventors: Shiguang Li, Qinbai Fan
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Publication number: 20120174790Abstract: A water vapor permeable membrane is provided comprising a dense layer and a support layer that are adjacent to each other, wherein the dense layer contains voids with a void length of 0.1 ?m or less and the dense layer has a thickness of 0.1 ?m or more and 2 ?m or less while in the support layer, void (a), i.e. the void with the largest length in the 2 ?m thick region measured from the boundary between the dense layer and the support layer into the support layer, has a length of 0.3 ?m or more and void (b), i.e. the void with the largest length in the region ranging between 2 ?m and 4 ?m measured from the boundary into the support layer, has a length of 0.5 ?m or more, the length of the void (b) being larger than that of the void (a). A water vapor permeable membrane having both a high water vapor permeability and a low air leakage is provided.Type: ApplicationFiled: August 21, 2009Publication date: July 12, 2012Applicant: Toray Industries, Inc.Inventors: Masahiro Osabe, Kazumi Tanaka, Hiroyuki Sugaya
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Publication number: 20120174791Abstract: A method of forming a gas separation membrane including: depositing a first hydrophilic polymer solution; depositing on top of the first hydrophilic polymer solution a second, different hydrophilic polymer solution, thereby forming a two-layer polymer solution; forming the two-layer polymer solution into one of a forward osmosis membrane and a pressure retarded osmosis membrane by bringing the second, different hydrophilic polymer solution into contact with water to form the dense layer; coating one of the forward osmosis membrane and the pressure retarded osmosis membrane with a thin layer of a third, different, hydrophilic polymer more pH tolerant than the first and second hydrophilic polymer solutions to form a dense rejection layer thereon; and exposing one of the coated forward osmosis membrane and the coated pressure retarded osmosis membrane to a high pH solution. A gas separation membrane formed from the foregoing process.Type: ApplicationFiled: January 11, 2012Publication date: July 12, 2012Inventor: John R. Herron
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Publication number: 20120174772Abstract: In a device and a method for mixing and exchanging fluids, a first chamber is a mixing chamber with static mixing elements. First and second fluids flow through the first chamber in a mixing fluid flow direction. A second chamber adjacent the first chamber is a fluid feeding or discharge chamber through which the second fluid flows. A semipermeable membrane separates the volume of the first chamber from the volume of the second chamber. The membrane is impermeable to molecules or molecule agglomerations of the first fluid and permeable to molecules or molecule agglomerations of the second fluid. The membrane is made of a material or is coated with a material to which the molecules or molecule agglomerations of one of the two fluids have a lower affinity. Alternatively, or in addition, the membrane is elastic and spans a support wall with holes.Type: ApplicationFiled: August 2, 2010Publication date: July 12, 2012Applicant: FRANZ HAAS WAFFEL- UND KEKSANLAGEN-INDUSTRIE GMBHInventor: Alex Knobel
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Publication number: 20120167768Abstract: A gas separation membrane system and a method of preparing such gas separation membrane system by providing a porous support upon which is supported a membrane layer comprising a first gas-selective material and having a membrane thickness and removing therefrom a substantial portion of the first gas-selective material from the membrane layer by the use of an ultra-fine abrasive to thereby provide the membrane layer having a reduced membrane thickness. A second gas-selective material is deposited upon the membrane layer having the reduced membrane thickness to provide an overlayer of the second gas-selective material having an overlayer thickness so as to thereby provide the gas separation membrane system having the membrane layer of the reduced membrane thickness and the overlayer of the overlayer thickness.Type: ApplicationFiled: March 14, 2012Publication date: July 5, 2012Applicant: SHELL OIL COMPANYInventors: Alan Anthony DEL PAGGIO, John Charles SAUKAITIS
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Patent number: 8211539Abstract: A hydrogen separator comprising a porous substrate composed mainly of a ceramic having a large number of pores connecting from one surface of the substrate to other surface, and a hydrogen-separating layer made of a hydrogen permselective metal formed on the porous substrate via an intermediate layer made of an electron-conductive ceramic. The hydrogen separator hardly generates defects such as peeling, cracks or the like in the hydrogen-separating layer and is suitable for use even when the hydrogen separator is exposed to a heat cycle, used under high temperature conditions or/and used for long-term.Type: GrantFiled: February 18, 2011Date of Patent: July 3, 2012Assignee: NGK Insulators, Ltd.Inventors: Kenichi Noda, Osamu Sakai
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Patent number: 8210360Abstract: Composite membranes that are adapted for separation, purification, filtration, analysis, reaction and sensing. The composite membranes can include a porous support structure having elongate pore channels extending through the support structure. The composite membrane also includes an active layer comprising an active layer material, where the active layer material is completely disposed within the pore channels between the surfaces of the support structure. The active layer is intimately integrated within the support structure, thus enabling great robustness, reliability, resistance to mechanical stress and thermal cycling, and high selectivity. Methods for the fabrication of composite membranes are also provided.Type: GrantFiled: May 7, 2007Date of Patent: July 3, 2012Assignee: Synkera Technologies, Inc.Inventors: Dmitri Routkevitch, Oleg G. Polyakov
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Patent number: 8197578Abstract: A liquid degasser for a space device including a gas permeable material configured for contact with a flow of liquid to be de-gassed on one side and a vacuum on the other side, and wherein the gas permeable material allows gas in the liquid to diffuse to the vacuum to remove the gas from the liquid.Type: GrantFiled: July 25, 2007Date of Patent: June 12, 2012Assignee: Busek Company, Inc.Inventors: Vladimir J. Hruby, Nate Demmons, Tom Roy, Doug Spence, Eric Ehrbar, Jurg Zwahlen, Charles Gasdaska
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Patent number: 8197576Abstract: A CO2-facilitated transport membrane of excellent carbon dioxide permeability and CO2/H2 selectivity, which can be applied to a CO2 permeable membrane reactor, is stably provided. The CO2-facilitated transport membrane is formed such that a gel layer 1 obtained by adding cesium carbonate to a polyvinyl alcohol-polyacrylic acid copolymer gel membrane is supported by a hydrophilic porous membrane 2. More preferably, a gel layer supported by a hydrophilic porous membrane 2 is coated with hydrophilic porous membranes 3 and 4.Type: GrantFiled: January 22, 2009Date of Patent: June 12, 2012Assignee: Renaissance Energy Research CorporationInventors: Osamu Okada, Masaaki Teramoto, Reza Yegani, Hideto Matsuyama, Keiko Shimada, Kaori Morimoto
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Patent number: 8192524Abstract: Disclosed herein are processes for producing a CO2-depleted product gas stream. The processes involve feeding a natural gas feed stream comprising greater than about 10 vol % CO2 to at least one membrane unit comprising a plurality of polymer membranes to provide a CO2-rich permeate comprising at least 95 vol % CO2 and a CO2-depleted product gas stream. The polymer membranes comprise a crosslinked polyimide polymer having covalent ester crosslinks and have a CO2 permeance of at least 20 GPU and a CO2/CH4 selectivity of greater than 20, at 35 degrees C. and a feed pressure of 100 psia. Also disclosed herein is an apparatus incorporating the crosslinked polyimide polymer for producing a CO2-depleted product gas stream from a natural gas feed stream.Type: GrantFiled: January 29, 2009Date of Patent: June 5, 2012Assignee: Chevron U.S.A. Inc.Inventors: Daniel Chinn, Siji Okeowo, Jeff D. Euhus, Shabbir Husain
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Patent number: 8182591Abstract: A vertically directed dryer unit (10) for compressed air, comprising a dryer cartridge (22) which, together with a housing (16, 18, 20), defines an inlet head area (92) and an outlet head area (72). A plurality of hollow membrane fibers (30) extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve (90) is provided between the outlet head area (72) and an outlet (74) of the drier unit. Said valve only opens when the pressure in the outlet head area (72) produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers (30) via a throttle element (70).Type: GrantFiled: September 27, 2005Date of Patent: May 22, 2012Assignee: Durr Dental GmbH & Co. KGInventors: Alfred Deubler, Varleriu Fischer
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Patent number: 8182590Abstract: A process for forming a porous nanoscale membrane is described. The process involves applying a nanoscale film to one side of a substrate, where the nanoscale film includes a semiconductor material; masking an opposite side of the substrate; etching the substrate, beginning from the masked opposite side of the substrate and continuing until a passage is formed through the substrate, thereby exposing the film on both sides thereof to form a membrane; and then simultaneously forming a plurality of randomly spaced pores in the membrane. The resulting porous nanoscale membranes, characterized by substantially smooth surfaces, high pore densities, and high aspect ratio dimensions, can be used in filtration devices, microfluidic devices, fuel cell membranes, and as electron microscopy substrates.Type: GrantFiled: May 1, 2006Date of Patent: May 22, 2012Assignee: University of RochesterInventors: Christopher C. Striemer, Philippe M. Fauchet, Thomas R. Gaborski, James L. McGrath
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Publication number: 20120118149Abstract: A manganese oxide contains M1, optionally M2, Mn and O. M1 is selected from the group consisting of In, Sc, Y, Dy, Ho, Er, Tm, Yb and Lu. M2 is different from M1, and M2 is selected from the group consisting of Bi, In, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. These ceramic materials are hexagonal in structure, and provide superior materials for gas separation and oxygen storage.Type: ApplicationFiled: October 28, 2011Publication date: May 17, 2012Inventors: Bogdan Dabrowski, Steven Remsen
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Patent number: 8177889Abstract: A gas removal device 1 includes a decompression chamber 2 with an inlet 11 and an outlet 12 through which a liquid to be degassed flows therein and thereout, and a degassing element 5 that is accommodated in the decompression chamber 2 while having one end connected to the inlet 11 and another end connected to the outlet 12, and that allows the liquid to be degassed entering into the inlet 11 to pass through the degassing element 5. The degassing element 5 includes a tube bundle 15 composed of a plurality of flexible gas-permeable tubes 151, and a tying member 16 tying the plurality of gas-permeable tubes 151 to form the tube bundle 15. The tube bundle 15 is bent in a shape of coil with multiple turns in such a manner that a portion tied by the tying member 16 is included in a bent portion BP.Type: GrantFiled: September 19, 2007Date of Patent: May 15, 2012Assignee: Nitto Denko CorporationInventor: Hajime Ooya
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Patent number: 8177883Abstract: A container having a plurality of walls, and at least one inlet and/or outlet, said container including an apparatus for controlling the composition of gases within the container, the apparatus including at least one sensor, at least one controller and at least one gas permeable membrane, through which membrane different gases can pass at different rates, said membrane dividing the container into a first region being for holding cargo and a second region defining a gas buffer region, and said membrane being permeable permitting for nitrogen, oxygen and carbon dioxide at different flow rates, wherein the buffer region is in communication with the ambient atmosphere through one or more vacuum pump(s).Type: GrantFiled: February 13, 2009Date of Patent: May 15, 2012Assignee: Maersk Container Industri A/SInventors: Gert Jørgensen, Niels Nielsen Poulsen
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Patent number: 8177890Abstract: A Pd alloy membrane and method of making are described.Type: GrantFiled: June 26, 2009Date of Patent: May 15, 2012Assignee: The Ohio State UniversityInventors: Krenar Shqau, Hendrik Verweij
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Patent number: 8177884Abstract: A device for use in a fluid system includes a fuel channel for receiving fuel having dissolved gas therein. A gas permeable membrane supported by a porous support, the gas permeable membrane in communication with the fuel channel. A gas-removal channel adjacent the gas permeable membrane for receiving the dissolved gas from the fuel through the gas permeable membrane and the porous support.Type: GrantFiled: May 20, 2009Date of Patent: May 15, 2012Assignee: United Technologies CorporationInventors: Wayde R. Schmidt, Haralambos Cordatos, Slade R. Culp
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Patent number: 8172923Abstract: An apparatus and method for maintaining low gas velocity variation across a diffuser membrane during the vent-up of a vacuum chamber is disclosed. The diffuser membrane permeability and the pressure conditions across the membrane are chosen to minimize variation in gas flow velocity through the membrane during the vent-up cycle. This reduces re-distribution of particles from a vacuum chamber onto sensitive substrates in the vacuum chamber during vent-up from sub-atmospheric pressure to atmospheric pressure.Type: GrantFiled: January 21, 2009Date of Patent: May 8, 2012Assignee: Entegris, Inc.Inventors: Christopher Vroman, Marshall Randolph
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Patent number: 8167983Abstract: The present invention relates to compositions for producing membranes, the compositions comprising at least 0.1% by weight of highly branched polymer, at least 0.5% by weight of linear polymer and at least 30% by weight of solvent. The present invention additionally describes membranes obtainable from the compositions, and methods of producing these membranes.Type: GrantFiled: December 17, 2007Date of Patent: May 1, 2012Assignee: Evonik Degussa GmbHInventors: Matthias Seiler, Stefan Bernhardt, Rolf Schneider, Roland Wursche, Franz-Erich Baumann
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Patent number: 8167982Abstract: A vertically directed dryer unit for compressed air, comprising a dryer cartridge which, together with a housing, defines an inlet head area and an outlet head area. A plurality of hollow membrane fibers extend inside the cartridge between the two head areas, the wall material thereof being more permeable with respect to water vapor than air. An outlet valve is provided between the outlet head area and an outlet of the drier unit. Said valve only opens when the pressure in the outlet head area produces sufficient pressure for the provision of purging air. The purging air is fed to the outer surface of the membrane fibers via a throttle element.Type: GrantFiled: January 13, 2010Date of Patent: May 1, 2012Assignee: Beko Technologies GmbHInventors: Alfred Deubler, Valeriu Fischer
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Patent number: 8167976Abstract: A gas separation membrane system and a method of preparing such gas separation membrane system by providing a porous support upon which is supported a membrane layer comprising a first gas-selective material and having a membrane thickness and removing therefrom a substantial portion of the first gas-selective material from the membrane layer by the use of an ultra-fine abrasive to thereby provide the membrane layer having a reduced membrane thickness. A second gas-selective material is deposited upon the membrane layer having the reduced membrane thickness to provide an overlayer of the second gas-selective material having an overlayer thickness so as to thereby provide the gas separation membrane system having the membrane layer of the reduced membrane thickness and the overlayer of the overlayer thickness.Type: GrantFiled: February 18, 2008Date of Patent: May 1, 2012Assignee: Shell Oil CompanyInventors: Alan Anthony Del Paggio, John Charles Saukaitis
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Patent number: 8163065Abstract: A carbon dioxide permeable membrane is described. In some embodiments, the membrane includes a body having a first side and an opposite second side; a plurality of first regions formed from a molten carbonate having a temperature of about 400 degrees Celsius to about 1200 degrees Celsius, the plurality of first regions forming a portion of the body and the plurality of first regions extending from the first side of the body to the second side of the body; a plurality of second regions formed from an oxygen conductive solid oxide, the plurality of second regions combining with the plurality of first regions to form the body and the plurality of second regions extending from the first side of the body to the second side of the body; and the body is configured to allow carbon dioxide to pass from the first side to the second side.Type: GrantFiled: March 21, 2011Date of Patent: April 24, 2012Assignee: The Trustees of Columbia University in the City of New YorkInventors: Klaus S. Lackner, Alan C. West, Jennifer L. Wade
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Patent number: 8157900Abstract: Hydrogen-processing assemblies, components of hydrogen-processing assemblies, and fuel-processing and fuel cell systems that include hydrogen-processing assemblies. The hydrogen-processing assemblies include a hydrogen-separation assembly positioned within the internal volume of an enclosure in a spaced relation to at least a portion of the internal perimeter of the body of the enclosure.Type: GrantFiled: June 9, 2011Date of Patent: April 17, 2012Assignee: Idatech, LLCInventors: William A. Pledger, Vernon Wade Popham, R. Todd Studebaker, Kyle Taylor
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Patent number: 8157891Abstract: A membrane cartridge is manufactured by repeatedly folding and joining two strips of membrane to form a cross-pleated cartridge with a stack of openings or fluid passageways configured in an alternating cross-flow arrangement. The cartridge can be modified for other flow configurations including co-flow and counter-flow arrangements. Methods for manufacturing such cross-pleated membrane cartridges, as well as apparatus used in the manufacturing process are described. Cross-pleated membrane cartridges comprising water-permeable membranes can be used in a variety of applications, including in heat and water vapor exchangers. In particular they can be incorporated into energy recovery ventilators (ERVs) for exchanging heat and water vapor between air streams being directed into and out of buildings.Type: GrantFiled: January 14, 2009Date of Patent: April 17, 2012Assignee: DPoint Technologies Inc.Inventors: Greg Montie, James Franklin Dean, Curtis Mullen, Robert Hill
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Publication number: 20120079944Abstract: There is described a process for producing carbon membranes suitable for gas separation, comprising the steps of: a) coating a porous substrate with a solution of at least one organic polymer which can be converted to a carbon membrane by pyrolysis, b) drying the polymer coating on the porous substrate by removing the solvent, c) pyrolyzing the polymer coating on the porous substrate to form the carbon membrane suitable for gas separation, it being possible to conduct any of steps a) to c) or the sequence of steps a) to c) more than once, and the pyrolysis in step c) being effected at a temperature higher than the baking temperature of the porous substrate.Type: ApplicationFiled: September 30, 2011Publication date: April 5, 2012Applicant: BASF SEInventors: Hartwig VOß, Jörg Therre
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Publication number: 20120079943Abstract: The use of solutions of ethylenically unsaturated polyesters for production of carbon membranes suitable for gas separation, and a process for producing carbon membranes suitable for gas separation, comprising the steps of: a) coating a porous substrate with a solution of ethylenically unsaturated polyester, b) drying the polyester coating on the porous substrate by removing the solvent, c) pyrolyzing the polyester coating on the porous substrate to form the carbon membrane suitable for gas separation, it being possible to conduct any of steps a) to c) or the sequence of steps a) to c) more than once.Type: ApplicationFiled: September 30, 2011Publication date: April 5, 2012Applicant: BASF SEInventors: Hartwig VOß, Jörg Therre
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Patent number: 8147595Abstract: There is provided a membrane material for a gas holder having abrasion resistance and flex resistance usable as a gas holder, in addition to strength of a base fabric, and having high gas barrier properties. A membrane material for a gas holder, which is used in a gas holder for storing or recovering gas, includes at least 4 layers of a protective layer, a base fabric layer, a gas barrier layer and a protective layer laminated in this order.Type: GrantFiled: June 11, 2007Date of Patent: April 3, 2012Assignees: Teijin Fibers Limited, Skypia Co., Ltd.Inventors: Satoshi Nagase, Hiroyuki Mori, Mikio Kusaka, Yasuo Motoishi
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Patent number: 8147596Abstract: A hydrogen-permeable film has a ceramic material of a nitride or oxide of a metal element belonging to group IVB, VB or VIB and hydrogen-permeable metal particles of at least one kind selected from palladium (Pd), niobium (Nb), vanadium (V), tantalum (Ta) and alloys thereof dispersed in the ceramic material. A ratio of the hydrogen-permeable metal particles in the hydrogen-permeable film is 20 to 70 mass %, and a thickness of the hydrogen-permeable film is 5 to 1,000 nm.Type: GrantFiled: December 27, 2007Date of Patent: April 3, 2012Assignee: Mikuni CorporationInventor: Katsuhiko Fukui
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Publication number: 20120073791Abstract: A core unit for an energy recovery system for exchanging heat and vapor between two independent intake and exhaust airstreams without intermixing thereof, the core unit having a fibrous microporous support substrate and a sulfonated block copolymer having at least one end block A and at least one interior block B wherein each A block contains essentially no sulfonic acid or sulfonate ester functional groups and each B block is a polymer block containing from about 10 to about 100 mol percent sulfonic acid or sulfonate ester functional groups based on the number of monomer units, and wherein the sulfonated block copolymer is laminated on the microporous support substrateType: ApplicationFiled: September 29, 2010Publication date: March 29, 2012Inventor: Donn Dubois
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Publication number: 20120067207Abstract: A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.Type: ApplicationFiled: May 27, 2010Publication date: March 22, 2012Inventors: Paul Jason Williams, Brendan Dermot Murray
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Patent number: 8137442Abstract: Process for producing at least one nanoporous layer of nanoparticles chosen from nanoparticles of a metal oxide, nanoparticles of metal oxides, and mixtures of said nanoparticles, on a surface of a substrate, in which at least one colloidal sol, in which said nanoparticles are dispersed and stabilized, is injected into a thermal plasma jet which sprays said nanoparticles onto said surface. Nanoporous layer and device, especially a separation device, comprizing said layer.Type: GrantFiled: April 25, 2007Date of Patent: March 20, 2012Assignee: Commissariat a l'Energie AtomiqueInventors: Bruno Pintault, David Guenadou, Luc Bianchi, Philippe Belleville, Karine Valle, Christophe Boscher, Joël Toulc'Hoat
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Publication number: 20120060687Abstract: A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.Type: ApplicationFiled: May 27, 2010Publication date: March 15, 2012Inventors: Brendan Dermot Murray, Paul Jason Williams
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Patent number: 8133306Abstract: A gas diffusion substrate includes a non-woven network of carbon fibres, the carbon fibres are graphitised but the non-woven network has not been subjected to a graphitisation process. A mixture of graphitic particles and hydrophobic polymer is disposed within the network. The longest dimension of at least 90% of the graphitic particles is less than 100 ?m. A process for manufacturing gas diffusion substrates includes depositing a slurry of graphitised carbon fibres onto a porous bed forming a wet fibre network, preparing a suspension of graphitic particles and hydrophobic polymer, applying onto, and pulling the suspension into, the network, and drying and firing the network. Another process includes mixing a first slurry of graphitic particles and hydrophobic polymer with a second slurry of graphitised carbon fibres and liquid forming a third slurry, depositing the third slurry onto a porous bed forming a fibre-containing layer, and drying and firing the layer.Type: GrantFiled: June 15, 2005Date of Patent: March 13, 2012Assignees: Johnson Matthey Public Limited Company, Technical Fibre Products LimitedInventors: George Thomas Quayle, Julia Margaret Rowe, Jonathan David Brereton Sharman, Julian Andrew Siodlak, Nigel Julian Walker, Andrew James Fletcher
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Patent number: 8118910Abstract: A layered filter membrane with improved anti-clogging characteristics is provided. In one embodiment, a filter membrane includes multiple polymer layers, each with different pore diameters formed by stretching the polymer layers. Furthermore, the multiple filter layers are coupled together before being stretched and the different pore sizes are formed during co-stretching of the filter layers.Type: GrantFiled: March 23, 2009Date of Patent: February 21, 2012Assignee: General Electric CompanyInventors: Nusrat Farzana, David Kazemi
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Patent number: 8118920Abstract: In various embodiments, a support system includes a multi-layer cover sheet with a number of layers. In certain embodiments, a source to move air inside and outside the multi-layer cover sheet can be provided. The source can include a source of positive pressure or negative pressure.Type: GrantFiled: March 15, 2011Date of Patent: February 21, 2012Assignee: KCI Licensing, Inc.Inventors: John H. Vrzalik, Alan L. Bartlett, Royce Johnson
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Patent number: 8110027Abstract: An air separation module and blanket has an air separation module having an air inlet, an oxygen outlet and a nitrogen outlet. At least one tank has air separation elements for separating oxygen from air, and delivers the separated oxygen to the oxygen outlet, and delivers nitrogen to the nitrogen outlet. A resistance heating element is positioned between the blanket and the air separation module. Further, an inventive blanket for use with the air separation module is also disclosed and claimed.Type: GrantFiled: April 17, 2009Date of Patent: February 7, 2012Assignee: Hamilton Sundstrand CorporationInventor: William Joseph Beeson
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Patent number: 8110022Abstract: A hydrogen purifier utilizing a hydrogen permeable membrane, and a gas-tight seal, where the seal is uses a low temperature melting point metal, which upon heating above the melting point subsequently forms a seal alloy with adjacent metals, where the alloy has a melting point above the operational temperature of the purifier. The purifier further is constructed such that a degree of isolation exists between the metal that melts to form the seal and the active area of the purifier membrane, so that the active area of the purifier membrane is not corrupted. A method of forming a hydrogen purifier utilizing a hydrogen permeable membrane with a seal of the same type is also disclosed.Type: GrantFiled: April 16, 2009Date of Patent: February 7, 2012Assignee: Genesis Fueltech, Inc.Inventor: Peter David DeVries
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Patent number: 8110026Abstract: A gas diffusion barrier contains a polymer matrix and a functional graphene which displays no signature of graphite and/or graphite oxide, as determined by X-ray diffraction.Type: GrantFiled: October 6, 2006Date of Patent: February 7, 2012Assignee: The Trustees of Princeton UniversityInventors: Robert Prud'Homme, Christopher O'Neil, Bulent Ozbas, Ilhan Aksay, Richard Register, Douglas Adamson
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Patent number: 8105424Abstract: A hydrogen permeation/separation thin membrane including a Ni—Ti—Nb alloy. The Ni—Ti—Nb alloy is a cast foil material obtained by roll quenching and a refining heat treatment. The membrane has a thickness of 0.07 mm or less. The Ni—Ti—Nb alloy has the following: (a) a composition consisting of 10 to 47 atomic % of Nb, 20 to 52 atomic % of Ti, and a remainder containing 20 to 48 atomic % of Ni and inevitable impurities; and (b) an alloy structure where fine particles of a Nb-based solid solution alloy, in which Nb forms a solid solution with Ni and Ti in Nb, are dispersed in a basic structure made of a Ni—Ti(Nb) intermetallic compound formed of a solid solution of a Ni—Ti intermetallic compound, in which part of Ti thereof is replaced by Nb.Type: GrantFiled: March 8, 2007Date of Patent: January 31, 2012Assignee: Mitsubishi Materials CorporationInventors: Koichi Kita, Kiyoshi Aoki, Kazuhiro Ishikawa
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Patent number: 8101010Abstract: A porous structure sealed at both ends for use in a gas separation module; and a method for separating components of a gas stream.Type: GrantFiled: May 28, 2009Date of Patent: January 24, 2012Assignee: Corning IncorporatedInventors: Joel Edward Clinton, Curtis Robert Fekety, Yunfeng Gu, Zhen Song
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Publication number: 20120012004Abstract: The invention relates to thin, hydrogen-permeable, sulfur-resistant membranes formed from multi-layers of palladium or palladium-alloy coatings on porous, ceramic or metal supports, methods of making these membranes, methods of repairing layers of these membranes and devices that incorporate these membranes.Type: ApplicationFiled: July 15, 2011Publication date: January 19, 2012Inventors: J. Douglas Way, Oyvind Hatlevik
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Publication number: 20120012001Abstract: A method of oxygen enrichment in which a gaseous mixture containing O2 molecules and N2 molecules is provided to a feed side of a SAPO molecular sieve, oxygen enrichment membrane having pore sizes suitable for discriminating between O2 molecules and N2 molecules, resulting in selective transport of the O2 molecules through the membrane to a permeate side of the membrane. Also disclosed is a method for producing the membrane.Type: ApplicationFiled: July 16, 2010Publication date: January 19, 2012Applicant: GAS TECHNOLOGY INSTITUTEInventors: Shiguang Li, Qinbai Fan
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Publication number: 20120006194Abstract: The present invention provides methods for making improved zeolite and crystalline silicoaluminophosphate (SAPO) membranes, in particular SAPO-34 membranes, on a porous support through improved removal of the organic structure-directing templating agent. A calcining step is performed in an oxygen free atmosphere, such as under a vacuum or inert gas, to remove the organic templating agent. By removing the templating agent in the absence of oxygen, the calcination step can remove a greater amount of the templating agent than comparable template removal steps conducted in the presence of oxygen and the calcination step can be conducted at significantly lower temperatures. The membranes of the present invention provide increased permeance while maintaining comparable selectivity for gas separations, particularly carbon dioxide (CO2) and methane (CH4) separations and separations at high temperatures.Type: ApplicationFiled: April 28, 2011Publication date: January 12, 2012Applicant: The Regents of the University of Colorado, a body corporateInventors: John L. Falconer, Richard D. Noble, Begum Tokay, Yanfeng Zhang
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Patent number: 8092581Abstract: A gas separation membrane has: a polymeric microporous membrane which has a polyolefin as a main component, and which is manufactured by wet phase separation process, and has a porosity of 20 to 80%, an average pore diameter of 1 to 100 nm and a piercing strength at 100° C. of 2 to 50 N; and a gas-separating thin film, which is provided on at least one surface, and/or the interior of the polymeric microporous membrane, and which comprises a fluorine-containing gas-separating resin as a main component, and has an average thickness of 0.01 ?m to less than 0.4 ?m. The gas separation membrane having an oxygen-nitrogen separation factor not smaller than 1.4.Type: GrantFiled: April 25, 2007Date of Patent: January 10, 2012Assignee: Asahi Kasei Chemicals CorporationInventors: Sho Sugiyama, Takuya Hasegawa, Takahiko Kondo, Hidetoshi Masugi, Takashi Nozaki