Abstract: The present invention relates to cationically curable compositions for curing on a surface comprising a cationically curable component, an accelerator species comprising at least one vinyl ether functional group and an initiator component capable of initiating cure of the cationically curable component. The initiator comprises at least one metal salt, which is chosen so that it is reduced at the surface, and where the standard reduction potential of the initiator component is greater than the standard reduction potential of the surface, and where when the composition is placed in contact with the surface, the metal salt of the initiator component of the composition is reduced at the surface, thereby initiating cure of the cationically curable component of the composition. The accelerator species comprising at least one vinyl ether functional group greatly enhances the rate of cure. No catalytic component is required in the composition for efficient cure.
Type:
Grant
Filed:
May 22, 2009
Date of Patent:
December 6, 2011
Assignee:
Loctite (R&D) Limited
Inventors:
David Farrell, Ciaran B. McArdle, Michael Doherty
Abstract: This document provides components comprising a predetermined sealing surface and a curable composition thereon. The cured reaction product of the curable composition forms a seal having improved resistance to vapor permeation when exposed to hydrocarbon fluids and especially to hydrocarbon fluids comprising low molecular weight components, oxygenated compounds, polar compounds or blends containing polar and non-polar compounds such as alcohol and alcohol containing fuels.
Abstract: This invention relates to thermosetting resin compositions useful for mounting onto a circuit board semiconductor devices, such as CSPs, BGAs, LGAs and the like, each of which having a semiconductor chip, such as LSI, on a carrier substrate. The compositions of this invention are reworkable when subjected to appropriate conditions.
Type:
Grant
Filed:
December 20, 2007
Date of Patent:
November 8, 2011
Assignee:
Henkel Corporation
Inventors:
Philip T. Klemarczyk, Andrew D. Messana, Afranio Torres-Filho, Erin K. Yeager, Takahisa Doba
Abstract: The subject invention is a system for dispensing a controlled amount of fluid product from a dispensing container which includes a pneumatically driven dispensing actuator. This actuator includes a dispensing cylinder and a movable dispensing piston. The dispensing piston is movable under pneumatic pressure within the cylinder, the cylinder including a volume of hydraulic fluid under the pneumatic pressure acting against the dispensing piston to selectively prevent movement of the dispensing piston. The invention further includes a means for selectively reducing the volume of the hydraulic fluid in the dispensing cylinder to allow the controlled movement of the dispensing piston. The controlled movement of the dispensing piston causes controlled displacement of the fluid product from the dispensing container. Advantageously, with the subject invention, a force may be generated and applied to a plunger, which can be accurately controlled.
Abstract: The present invention relates to new cure accelerator systems for anaerobic curable compositions. These anaerobic cure systems include tetraalkyl ammonium oxidizing salts that are soluble in the (meth)acrylate component of the composition.
Abstract: A dispensing nozzle for a container with a long tapered nozzle body has a narrow tapered dispensing end and a wider base end. A passage for fluid runs from the base end to the dispensing end and through an outlet. The dispensing nozzle has a removable cap that fits over the dispensing nozzle when in the closed position which closes the dispensing nozzle's outlet with a penetrating plug located on the interior of the cap. The cap has a narrow closed end that has the penetrating plug on its interior side and the cap has a wider open end. The cap fits onto the nozzle in a tight fit when closed. The invention contemplates that the fluid in the container is strong glue, so that hardened glue makes removing the cap difficult. To solve this problem, the nozzle and the cap have two distinct sets of ramps that provide the initial separating force to twist the cap with respect to the nozzle in order to remove the cap easily and allow dispensation.
Abstract: The present invention is directed to photoinitiated cationic epoxy compositions including: (a) at least one substantially saturated epoxy material comprising at least two glycidyl ether groups; (b) about 0.1 to about 20 weight percent on a basis of total weight of the composition of at least one polymer comprising at least one vinyl chloride segment and at least one vinyl acetate segment; and (c) at least one cationic photoinitiator; and bonded substrates and methods of bonding including the same.
Type:
Grant
Filed:
August 3, 2006
Date of Patent:
October 4, 2011
Assignee:
Henkel Corporation
Inventors:
Philip T. Klemarczyk, Anthony F. Jacobine
Abstract: The present invention relates to prepregs, towpregs and preforms made from curable compositions of (a) benzoxazines, (b) a combination of adducts a first of which is prepared from hydroxy-containing compounds, isocyanate-containing compounds and phenolic compounds and the second of which is prepared from the first adduct and epoxy-containing compounds, (c) components reactive with the benzoxazine, such as epoxy resins, episulfide resins and oxetane resins, (d) tougheners, such as polyether sulfones, ATBN and core shell materials and (e) a silica component, where the silica has a mean particle diameter on the order of 10?9 meters.
Type:
Grant
Filed:
August 18, 2009
Date of Patent:
October 4, 2011
Assignee:
Henkel Corporation
Inventors:
Wei Helen Li, Stanley L. Lehmann, Raymond S. Wong
Abstract: This invention relates to novel iminium salts, which may be in the form of ionic liquids, and a process for producing electron deficient olefins, such as 2-cyanoacrylates, using such an iminium salt, for instance in the form of an ionic liquid.
Abstract: The present invention relates to curable silicone compositions which include a fluorescent agent for detection purposes and which have a cure system which enables the silicone compositions to possess improved depth of cure. The silicone compositions are photocurable, and may also be moisture or heat curable.
Type:
Grant
Filed:
November 18, 2005
Date of Patent:
September 6, 2011
Assignee:
Henkel Corporation
Inventors:
Michael P. Levandoski, Hsien-Kun Chu, Richard Corrao
Abstract: The present invention provides one-component silicone compositions, particularly useful as sealants, having low modulus and high elongation, as well as good resistance to high temperatures and humidity, and methods for preparing these sealants. In particular, the present invention provides compositions including a chain-extended curable polyorganosiloxane, a high molecular weight silicone gum and a cure system. The compositions may be used, for example, in sealing the stitching of automotive airbags.
Abstract: This invention relates to a novel synthesis for the preparation of benzoxazine components from phenolic components, aldehyde components, and amine components in a solvent other than toluene.
Type:
Grant
Filed:
May 1, 2009
Date of Patent:
July 5, 2011
Assignees:
Henkel Corporation, Henkel AG & Co. KGaA
Inventors:
Andreas J. Taden, Puwei Liu, Alex C. Wong, Eric A. Parker
Abstract: The present invention relates to dual curing compositions, which cure with moisture and photo radiation, such as UV light, and methods for preparing and using same. In particular, the compositions of the present invention contain a polyether or polyester backbone, photocurable portion(s) and moisture curable portion(s). The photo curable portion is a urethane or carbamate linkage terminated with a (meth)acryloxyalkyl group. The moisture curable portion is either: (1) a portion terminated with a polyalkoxysilyl group; or (2) a portion having a urea linkage terminated with an alkylpolyalkoxysilyl group.
Type:
Grant
Filed:
July 22, 2005
Date of Patent:
June 14, 2011
Assignee:
Henkel Corporation
Inventors:
Anthony F. Jacobine, John G. Woods, Steven T. Nakos, Thomas Fay-Oy Lim
Abstract: Compositions for bonding substrate surfaces, particularly steel, aluminum, and urethane-primed galvanized steel, are disclosed. Desirably, the compositions include a stable emulsion including: (a) at least one curable (meth)acrylate component; (b) at least three different elastomeric polymers that are soluble and/or partially soluble in the (meth)acrylate component; and (c) optionally at least one elastomeric polymer that is not soluble in the (meth)acrylate component. Methods for preparing and methods for using these compositions also are disclosed.
Abstract: The present invention is directed to silicone formulations which are capable of being rapidly cured to tough elastomeric materials through exposure to UV radiation, and optionally through exposure to moisture as well. The cured products demonstrate high resistance to flammability and combustibility.
Abstract: The present invention relates to anaerobic cure systems containing enamines, their use as cure accelerators for anaerobic adhesive compositions, and anaerobic adhesive compositions including such enamine cure accelerators.
Abstract: This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-cured epoxy-based adhesive compositions with improved impact resistance and good adhesion to oily metal substrates.
Type:
Grant
Filed:
February 21, 2008
Date of Patent:
April 5, 2011
Assignees:
Henkel AG & Co. KGaA, Loctite (R&D) Limited
Inventors:
Rajat Agarwal, Olaf Lammerschop, Rainer Schoenfeld, Hubert K. Schenkel, Barry N. Burns, Matthew J. Holloway, Mary B. Ward, Martin J. Fitzpatrick, Jonathan P. Wigham
Abstract: The present invention provides visible light curing systems, methods for reducing health risks to individuals exposed to radiation curing systems, methods for bonding substrates and visible light curing compositions.
Type:
Grant
Filed:
December 19, 2005
Date of Patent:
March 29, 2011
Assignee:
Henkel Corporation
Inventors:
Mark M. Konarski, Edwin R. Perez, Eerik Maandi, Vic Kadziela, Steven J. Hemsen, Ronald E. Belek