Patents by Inventor Naoko Kihara
Naoko Kihara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6811897Abstract: There is disclosed an organic electro luminescence display device comprising a two-dimensional array of pixels comprising organic electro luminescence elements capable of emitting a of color or different plural colors, each of the organic electro luminescence elements being provided with an anode, a cathode, a polymeric luminescence layer located between the anode and the cathode, and a hole injection layer. The hole injection layer is constituted by solid matters containing a donor molecule comprising polythiophene and/or a derivative thereof, and an acceptor molecule comprising polystyrenesulfonic acid and/or a derivative thereof, a concentration of sulfate ion in the hole injection layer is 125 ppm or less, and components having a molecular weight of 110,000 or less is 35% or less based on an entire solid matters, the molecular weight being converted as sodium polystyrenesulfonate in an aqueous gel permeation chromatography measured by using UV of 254 nm in wavelength.Type: GrantFiled: March 25, 2003Date of Patent: November 2, 2004Assignee: Kabushiki Kaisha ToshibaInventors: Katsuyuki Naito, Naoko Kihara, Rei Hasegawa, Shintaro Enomoto, Yutaka Nakai, Kazushige Yamamoto, Hiroki Iwanaga, Kimito Sakai, Yasushi Mori
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Publication number: 20040189194Abstract: Provided is an organic EL display including a substrate, anodes arranged on one major surface of the substrate, an insulating separator layer covering the major surface of the substrate and having through-holes in the positions of the anodes, organic emitting layers disposed on the anodes, buffer layers disposed between the anodes and the organic emitting layers, and a cathode covering the organic emitting layers, wherein a central portion of each of the buffer layers is thicker than its periphery.Type: ApplicationFiled: April 7, 2004Publication date: September 30, 2004Applicant: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Yasushi Mori, Katsuyuki Naito
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Publication number: 20040018386Abstract: There is disclosed an organic electro luminescence display device comprising a two-dimensional array of pixels comprising organic electro luminescence elements capable of emitting a of color or different plural colors, each of the organic electro luminescence elements being provided with an anode, a cathode, a polymeric luminescence layer located between the anode and the cathode, and a hole injection layer. The hole injection layer is constituted by solid matters containing a donor molecule comprising polythiophene and/or a derivative thereof, and an acceptor molecule comprising polystyrenesulfonic acid and/or a derivative thereof, a concentration of sulfate ion in the hole injection layer is 125 ppm or less, and components having a molecular weight of 110,000 or less is 35% or less based on an entire solid matters, the molecular weight being converted as sodium polystyrenesulfonate in an aqueous gel permeation chromatography measured by using UV of 254 nm in wavelength.Type: ApplicationFiled: March 25, 2003Publication date: January 29, 2004Inventors: Katsuyuki Naito, Naoko Kihara, Rei Hasegawa, Shintaro Enomoto, Yutaka Nakai, Kazushige Yamamoto, Hiroki Iwanaga, Kimito Sakai, Yasushi Mori
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Patent number: 6340552Abstract: A photosensitive composition comprising: an acid-decomposable compound having at least one substituent which is decomposed by an acid, forming a product which reacts with alkali solution and forms —COO— or —SO3—; and a compound which generates an acid when exposed to a chemical radiation. If necessary, the composition further comprises an alkali-soluble polymer. The acid-decomposable compound is one which is represented by the following formula (1), and the alkali-soluble polymer has a softening point of 150° C. or more and an average molecular weight of 3000 to 8000. When used as photoresist, the composition can form a fine resist pattern.Type: GrantFiled: May 23, 1994Date of Patent: January 22, 2002Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Fumihiko Yuasa, Tohru Ushirogouchi, Tsukasa Tada, Osamu Sasaki, Takuya Naito, Satoshi Saito
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Publication number: 20010038900Abstract: An optical disk from which recorded data are read out by means of light irradiation has a substrate having recording pits as data on a surface thereof, and stacked films formed on the substrate. The stacked films contain a super-resolution film of a polymer matrix and semiconductor particles having an organic group covalently bonded thereto, and a reflective film reflecting light. The super-resolution film and the reflective film are provided in this order from a light incident side.Type: ApplicationFiled: March 29, 2001Publication date: November 8, 2001Inventors: Kenji Todori, Toshihiko Nagase, Katsutaro Ichihara, Naoko Kihara
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Patent number: 6306553Abstract: A photosensitive composition comprising: an acid-decomposable compound having at least one substituent which is decomposed by an acid, forming a product which reacts with alkali solution and forms —COO− or —SO3−; and a compound which generates an acid when exposed to a chemical radiation. If necessary, the composition further comprises an alkali-soluble polymer. The acid-decomposable compound is one which is represented by the following formula (1), and the alkali-soluble polymer has a softening point of 150° C. or more and an average molecular weight of 3000 to 8000. When used as photoresist, the composition can form a fine resist pattern.Type: GrantFiled: June 7, 1995Date of Patent: October 23, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Fumihiko Yuasa, Tohru Ushirogouchi, Tsukasa Tada, Osamu Sasaki, Takuya Naito, Satoshi Saito
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Patent number: 6280897Abstract: A photosensitive composition comprising a polymer having a repeating segment represented by the following general formula (1A) and a compound which is capable of generating an acid by irradiation of an actinic radiation. wherein R11 is a hydrogen atom, an aliphatic hydrocarbon group, an alcoxy group, a halogen atom or a cyano group, R12 is an aliphatic hydrocarbon group or a cyclic olefin, R13 is either one of (a) a straight-chain olefin having 2 to 12 carbon atoms, a cyclic olefin or a heterocyclic group and (b) a hydrocarbon group represented by — (CH2)m—(m is an integer of 3 to 9), and R14 is a hydrophilic group.Type: GrantFiled: December 23, 1997Date of Patent: August 28, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Koji Asakawa, Naoko Kihara, Naomi Shida, Toru Ushirogouchi, Takeshi Okino, Makoto Nakase, Takuya Naito, Satoshi Saito
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Patent number: 6197473Abstract: The objectives of the present invention are to provide a photosensitive composition having high solubility to organic solvents as well as to alkaline developers or water-base developers of pH 11 or less, and to provide a pattern forming process for obtaining a high-resolution resist pattern. These objectives are achieved by means of a photosensitive composition comprising a compound which is glassy at room temperature and has a cyclic structure with three or more aromatic rings containing an acid-decomposable substituent, and a pattern forming process wherein a photosensitive material using said photosensitive composition is exposed to a light pattern and developed with an aqueous solution of an alkali or with a water-base developer of pH 11 or less.Type: GrantFiled: September 17, 1998Date of Patent: March 6, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Satoshi Saito, Toru Ushirogouchi
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Patent number: 6190841Abstract: The present invention provides a pattern forming process. The process comprises the following steps. (1) A photosensitive material is prepared by coating a photosensitive composition onto the surface of a substrate. The photosensitive composition comprises the following components: (a) an acid generator which generates an acid when irradiated with actinic radiation, and (b) a compound containing carboxyl groups, which can decompose upon decarboxylation. (2) The photosensitive material is subjected to pattern-wise exposure to actinic radiation, thereby allowing the acid generator (a) to generate an acid in the exposed area. (3) The acid generated in the exposed area is neutralized with a basic compound (c). (4) The carboxyl groups in the carboxyl-group-containing compound (b) in the unexposed area are decarboxylated by applying conditions under which the basic compound (c) can catalyze decarboxylation. (5) The photosensitive material, and composition used in the above process are developed.Type: GrantFiled: December 21, 1998Date of Patent: February 20, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Satoshi Saito, Toru Ushirogouchi
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Patent number: 6177229Abstract: Disclosed is a positive photosensitive composition, comprising an alkali soluble resin having at least some or all of the alkali soluble groups protected by a substituent which can be decomposed by an acid, a compound which generates an acid upon irradiation with an actinic radiation, and a compound which generates water under action of an acid catalyst.Type: GrantFiled: January 27, 1999Date of Patent: January 23, 2001Assignee: Kabushiki Kaisha ToshibaInventors: Satoshi Saito, Naoko Kihara, Toru Ushirogouchi
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Patent number: 5932391Abstract: A resist for alkali development, which comprises an alicyclic compound attached with an acidic substituent group exhibiting pKa of 7 to 11 in an aqueous solution of 25.degree. C. This alicyclic compound is preferably a copolymer comprising as a comonomer component a vinyl compound and exhibiting a light absorbency of 3 or less per 1 .mu.m to the light of 193 nm in wavelength.Type: GrantFiled: August 16, 1996Date of Patent: August 3, 1999Assignee: Kabushiki Kaisha ToshibaInventors: Toru Ushirogouchi, Koji Asakawa, Naoko Kihara, Makoto Nakase, Naomi Shida, Takeshi Okino
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Patent number: 5853952Abstract: There is disclosed a color developing resin composition comprising a base polymer, a dialdehyde represented by the general formula OHC--R.sup.1' --CHO, a diamine represented by the general formula H.sub.2 N--R.sup.2' --NH.sub.2 (at least one of R.sup.1' and R.sup.2' is an aromatic group), a compound which produces an acid by light irradiating and a resin which is crosslinked with the acid.Type: GrantFiled: August 29, 1996Date of Patent: December 29, 1998Assignee: Kabushiki Kaisha ToshibaInventors: Toru Ushirogouchi, Makoto Nakase, Akira Yoshizumi, Naoko Kihara, Takuya Naito, Naomi Shida, Koji Asakawa
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Patent number: 5756254Abstract: A resist comprising a sulfonyl compound represented by the following general formula (1): ##STR1## wherein R.sup.1 is a hydrogen atom, a halogen atom, nitro group, cyano group or a monovalent organic group, R.sup.2 is a halogen atom, nitro group, cyano group or a monovalent organic group, R.sup.3 is a bivalent organic group, and n is an integer of 2 or more. The R.sup.3 in the general formula (1) is preferably a bivalent organic group represented by the general formula (2): ##STR2## wherein R.sup.21, R.sup.22, R.sup.23, R.sup.24, R.sup.25 and R.sup.26 may be the same or different and are individually a hydrogen atom, a halogen atom, nitro group, cyano group or a monovalent organic group, and Z is a bivalent organic group.Type: GrantFiled: May 28, 1996Date of Patent: May 26, 1998Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Satoshi Saito, Hiromitsu Wakabayashi, Makoto Nakase, Masayuki Oba
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Patent number: 5518864Abstract: Disclosed is a photosensitive resin composition, containing a polyamic acid derivative having a repeating unit represented by general formula (1) given below and a photosensitive agent: ##STR1## where, R.sup.1 represents a tetravalent organic group, R.sup.2 represents a divalent organic group, and R.sup.3 and R.sup.4 represent a monovalent organic group, at least one of R.sup.3 and R.sup.4 being an organic group having at least on hydroxyl group bonded to an aromatic ring. A semiconductor substrate is coated with the photosensitive resin composition, followed by exposing the coated film to light through a patterning mask and subsequently applying a development and a heat treatment so as to form a polyimide film pattern. A baking treatment also be applied immediately after the exposure step. The photosensitive resin composition of the present invention performs the function of a positive or negative photoresist film and the function of a polyimide protective film on a semiconductor substrate.Type: GrantFiled: March 30, 1994Date of Patent: May 21, 1996Assignee: Kabushiki Kaisha ToshibaInventors: Masayuki Oba, Rumiko Hayase, Naoko Kihara, Shuzi Hayase, Yukihiro Mikogami, Yoshihiko Nakano, Naohiko Oyasato, Shigeru Matake, Kei Takano
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Patent number: 5372914Abstract: On a substrate a protective layer is formed which can suppress the diffusion of a contaminant from the substrate. On the protective layer, thus formed, a resin layer is formed. The resin layer comprises a photosensitive composition containing a compound which has a substituent group capable of being decomposed or cross-linked in the presence of an acid, and a compound which can generate an acid when exposed to light. The resin layer is pattern-exposed to light and then baked at a predetermined temperature. The resin layer is developed, whereby the exposed portions of the resin layer are removed or left, thus forming a pattern comprising lines and spaces each having a predetermined width. Each of the lines of the pattern has a cross-section having neither sloped profile nor undercut profile, and the pattern therefore has an improved resolution.Type: GrantFiled: March 24, 1993Date of Patent: December 13, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Takuya Naito, Osamu Sasaki, Tsukasa Tada, Naoko Kihara, Toru Ushirogouchi, Satoshi Saito, Takashi Jonai, Hirokazu Niki
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Patent number: 5348838Abstract: A photosensitive composition comprises an alkali-soluble resin, a compound which has a substituent group decomposable by an acid and generates an alkali-soluble group upon decomposition of the substituent group, or a compound which has a substituent group capable of crosslinking the alkali-soluble resin in the presence of an acid, and a compound which generates an acid upon exposure, which is represented by formula (1) given below: ##STR1## wherein R.sub.11 represents a monovalent organic group or a monovalent organic group into which at least one selected from the group consisting of a halogen atom, a nitro group, and a cyano group is introduced, each of R.sub.12, R.sub.13, and R.sub.14 independently represents hydrogen, a halogen atom, a nitro group, a cyano group, a monovalent organic group, or a monovalent organic group into which at least one selected from the group consisting of a halogen atom, a nitro group, and a cyano group is introduced.Type: GrantFiled: July 30, 1992Date of Patent: September 20, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Toru Ushirogouchi, Naoko Kihara, Osamu Sasaki, Tsukasa Tada, Takuya Naito, Satoshi Saito
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Patent number: 5348835Abstract: Disclosed is a photosensitive resin composition, containing a polyamic acid derivative having a repeating unit represented by general formula (1) given below and a photosensitive agent: ##STR1## where, R.sup.1 represents a tetravalent organic group, R.sup.2 represents a divalent organic group, and R.sup.3 and R.sup.4 represent a monovalent organic group, at least one of R.sup.3 and R.sup.4 being an organic group having at least on hydroxyl group bonded to an aromatic ring. A semiconductor substrate is coated with the photosensitive resin composition, followed by exposing the coated film to light through a patterning mask and subsequently applying a development and a heat treatment so as to form a polyimide film pattern. A baking treatment also be applied immediately after the exposure step. The photosensitive resin composition of the present invention performs the function of a positive or negative photoresist film and the function of a polyimide protective film on a semiconductor substrate.Type: GrantFiled: September 27, 1991Date of Patent: September 20, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Masayuki Oba, Rumiko Hayase, Naoko Kihara, Shuzi Hayase, Yukihiro Mikogami, Yoshihiko Nakano, Naohiko Oyasato, Shigeru Matake, Kei Takano
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Patent number: 5340684Abstract: A photosensitive composition contains a polyimide constituted by a repeating unit having a hydroxyl group and a repeating unit having a siloxane bond, or a repeating unit having a hydroxyl group, a repeating unit having a siloxane bond, and a repeating unit other than these two repeating units, and a photosensitive agent consisting of an ester compound or an amide-ester compound of naphthoquinonediazidesulfonic acid or benzoquinonediazidesulfonic acid. The photosensitive composition is used as a passivation film of a semiconductor device or a photoresist.Type: GrantFiled: November 29, 1993Date of Patent: August 23, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Rumiko Hayase, Masayuki Oba, Naoko Kihara, Yukihiro Mikogami
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Patent number: 5332648Abstract: A photosensitive composition comprising: an acid-decomposable compound having at least one substituent which is decomposed by an acid, forming a product which reacts with alkali solution and forms --COO.sup.- or --SO.sub.3.sup.- ; and a compound which generates an acid when exposed to a chemical radiation. If necessary, the composition further comprises an alkali-soluble polymer. The acid-decomposable compound is one which is represented by the following formula (1), and the alkali-soluble polymer has a softening point of 150.degree. C. or more and an average molecular weight of 3000 to 8000. When used as photoresist, the composition can form a fine resist pattern. ##STR1## where R.sub.1 and R.sub.2 are either the same or different, each of which represents at least one selected from the group consisting of hydrogen, halogen atom, cyano group, nitro group, silyl group, and monovalent organic group; X represents >C.dbd.O or --SO.sub.2 --; Y represents a divalent organic group; R.sub.1 and R.sub.Type: GrantFiled: December 27, 1991Date of Patent: July 26, 1994Assignee: Kabushiki Kaisha ToshibaInventors: Naoko Kihara, Fumihiko Yuasa, Tohru Ushirogouchi, Tsukasa Tada, Osamu Sasaki, Takuya Naito, Satoshi Saito
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Patent number: 5216077Abstract: A rubber-modified phenolic resin composition contains a novolak-type phenolic resin in which at least one modifying agent selected from the group consisting of an ABS resin and an MBS resin is homogeneously dispersed. The composition has good impact resistance and thermal shock resistance. The composition is prepared by adding at least one modifying agent described above to a novolak-type phenolic resin which is heated and melted at its softening point or more, so that the modifying agent is homogeneous dispersed in the resin. The resin composition is suitably used as a curing agent for an epoxy resin encapsulant for sealing electronic devices.Type: GrantFiled: April 27, 1992Date of Patent: June 1, 1993Assignees: Kabushiki Kaisha Toshiba, Toshiba Chemical CorporationInventors: Akira Yoshizumi, Shinetsu Fujieda, Ken Uchida, Naoko Kihara, Kazuhiro Sawai, Tsutomu Nagata, Shinji Murakami, Shigeyuki Kouchiyama