Metal Base Work, Acid Treating Patents (Class 134/41)
  • Patent number: 8398779
    Abstract: Non-metallic deposits are selectively removed from aluminum containing substrates such as aluminum faceplates using a selective deposition removal (SDR) solution. The SDR solution does not substantially etch the faceplate holes, thereby preserving the hole diameter integrity and increasing the number of times the faceplate may be cleaned or refurbished while remaining within processing hole diameter tolerances. In an embodiment, the SDR solution comprises, in wt % of the solution, 15.5%+/?2% HF or buffered HF acid, 3.8%+/?0.5% NH4F pH buffer, 59.7%+/?5% ethylene glycol, and the balance H2O.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: March 19, 2013
    Assignee: Applied Materials, Inc.
    Inventors: Liyuan Bao, Anbei Jiang, Sio On Lo, Yukari Nishimura, Joseph F. Sommers, Samantha S. H. Tan
  • Patent number: 8377216
    Abstract: A vacuum processing apparatus includes a vacuum chamber for performing a plasma process and a cleaning process unit for performing a cleaning process to apply a plasma process to a wafer on which a single layer or a laminated film containing a metallic film is formed by using a corrosive gas, and a control unit having a sequence to abort the plasma process when an abnormality occurs in the vacuum chamber and transfer the wafer subjecting to the aborting of the plasma process to the cleaning process unit, after elapsing a predetermined time, to perform the cleaning process.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: February 19, 2013
    Assignee: Hitachi High-Technologies Corporation
    Inventors: Masakazu Okai, Kenji Tamai, Toru Ueno
  • Patent number: 8337634
    Abstract: A remover contains an alkaline component, a bivalent zinc ion, a ferric ion, a chelating agent, and a nitrate ion. By using this remover, an anodized film can be selectively removed from an aluminum or aluminum-alloy member.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: December 25, 2012
    Assignee: Kobe Steel, Ltd.
    Inventors: Katsuyuki Iijima, Tetsuo Suzuki
  • Publication number: 20120312331
    Abstract: This invention relates to a method of preprocessing a magnesium alloy for electroplating, including pickling the magnesium alloy with an ethyleneglycol-nitric acid solution.
    Type: Application
    Filed: December 6, 2011
    Publication date: December 13, 2012
    Applicants: Pusan National University Industry-University Cooperation Foundation, HYUNDAI MOTOR COMPANY
    Inventors: Hyung Sop Yoon, Won Sub Chung, Jung Hoon Lee
  • Publication number: 20120308727
    Abstract: The present invention discloses an improved cleaning composition for cleaning metal surfaces such as aluminum and aluminum-containing alloys. The cleaning composition of the present invention comprises water and an ethoxylate of an alcohol having Formula R1—OH wherein R1 is a saturated or unsaturated, straight-chain or branched aliphatic having from 12 to 80 carbon atoms; an inorganic pH adjusting component; and at least one surfactant that is different than the ethoxylate set forth above. The cleaning composition of the present invention also has an average water-break-free percent reduction of less than 50% after 7 days aging of a working composition prepared from the cleaning composition. The present invention also provides a method of cleaning a metal surface with the cleaning composition of the invention.
    Type: Application
    Filed: July 9, 2012
    Publication date: December 6, 2012
    Applicant: Henkel AG & Co. KGaA
    Inventors: Andrew M. Hatch, Gary Rochfort, Richard D. Banaszak
  • Patent number: 8323472
    Abstract: The method of surface treatment, as applied onto a metal base material, of the present invention includes a reduction treatment step of reduction-treating the oxide film formed on the metal base material and an oxidation treatment step of oxidation-treating the oxide film having been subjected to the reduction treatment.
    Type: Grant
    Filed: July 10, 2008
    Date of Patent: December 4, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hajime Hasegawa, Yusuke Watanabe
  • Patent number: 8323415
    Abstract: A method for recovering ruthenium oxide or gold and titanium or titanium oxide from a bipolar plate at the end of the life of a fuel cell stack so as to use these materials in other fuel cell stacks thereafter. The bipolar plate is immersed in a solution including a suitable acid that dissolves the titanium or titanium oxide. The ruthenium oxide or gold will be released from the plate and will float on the solution from which it can be removed. The solution is then heated to evaporate the acid solution leaving a powder of the titanium oxide. The stainless steel of the bipolar plate is thus cleaned of the titanium or titanium oxide, and can be reused.
    Type: Grant
    Filed: August 10, 2006
    Date of Patent: December 4, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Mahmoud H. Abd Elhamid, Youssef M. Mikhail, Richard H. Blunk
  • Patent number: 8298341
    Abstract: A method is used for removing a metal contaminant deposited on a quartz member selected from the group consisting of a reaction tube, wafer boat, and heat-insulating cylinder of a vertical heat processing apparatus for a semiconductor process. The method includes obtaining the quartz member unattached to the vertical heat processing apparatus; then, performing diluted hydrofluoric acid cleaning of cleaning the quartz member by use of diluted hydrofluoric acid; then, performing first purified water cleaning of cleaning the quartz member by use of purified water; then, performing hydrochloric acid cleaning of cleaning the quartz member by use of hydrochloric acid; and then, performing second purified water cleaning of cleaning the quartz member by use of purified water.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: October 30, 2012
    Assignee: Tokyo Electron Limited
    Inventors: Hitoshi Katoh, Tsuneyuki Okabe, Kohichi Orito, Takashi Chiba
  • Patent number: 8263540
    Abstract: A warewashing detergent composition is provided for use for in cleaning of alkaline sensitive metals such as aluminum or aluminum containing alloys. The compositions include alternatives to sodium tripolyphosphate and/or other phosphorous containing raw materials, while retaining cleaning performance and corrosion prevention. According to the invention, a synergistic combination of polyacrylic and polymaleic polymers are used as corrosion inhibitors in traditional alkaline detergent compositions.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: September 11, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Erik Christian Olson, Devon Beau Hammel
  • Patent number: 8241428
    Abstract: The present invention relates to a liquid acidic hard surface cleaning composition having a pH of from 2 to 2.9 and comprising formic acid and an alkaline material.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: August 14, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Laura Cermenati, William Mario Laurent Verstraeten
  • Patent number: 8231733
    Abstract: The present invention relates to a method used to remove post etch organic and inorganic residue as well polymeric residues and contaminants from semiconductor substrates. In one aspect, the method involves contacting the substrate with a composition are comprised of a water soluble organic solvent, a sulfonic acid and water.
    Type: Grant
    Filed: May 27, 2005
    Date of Patent: July 31, 2012
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Matthew I. Egbe, Darryl W. Peters
  • Patent number: 8226773
    Abstract: A cleaning solution and method for removing submicron particles from the surface and/or the bevel of an electronic substrate such as a semiconductor wafer. The cleaning solution comprises a polycarboxylate polymer or an ethoxylated polyamine. The method comprises the step of contacting a surface of the substrate with a cleaning solution comprised of a polycarboxylate polymer or an ethoxylated polyamine. Additional optional steps in the method include applying acoustic energy to the cleaning solution and/or rinsing the surface with a rinsing solution with or without the application of acoustic energy to the rinsing solution.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: July 24, 2012
    Assignee: Fontana Technology
    Inventor: Mark Jonathan Beck
  • Patent number: 8221556
    Abstract: This invention relates to a plumbing device made of a copper alloy containing nickel salt, that includes a valve and a tube coupling having at least a liquid-contacting part washed with a cleaning fluid incorporating therein nitric acid and hydrochloric acid as an inhibitor under conditions of a temperature and a duration permitting effective removal of nickel salt, thereby performing nickel salt-removing treatment and causing the hydrochloric acid to form a coating film on the surface of the liquid-contacting part thereby effectively precluding elution of nickel salt from the surface of the liquid-contacting part in the presence of the coating film, wherein the nitric acid has a concentration c in a range of 0.5 wt %<c<7 wt % and the hydrochloric acid has a concentration d in a range of 0.05 wt %<d<0.7 wt % in the cleaning fluid, wherein the temperature is set to 10° C.?x 50° C., and wherein nickel salt is removed with the cleaning fluid.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: July 17, 2012
    Assignee: Kitz Corporation
    Inventor: Norikazu Sugaya
  • Patent number: 8216383
    Abstract: Disclosed herein is a method and treatment system for rapid cleaning and protecting of automotive cooling systems containing controlled atmosphere brazed aluminum heat exchangers. The method and treatment system can optionally include a conditioning (passivating) step. The treatment system can comprise three different parts: (1) cleaner or cleaning solution; (2) conditioner or conditioning solution; and (3) compatible CAB aluminum protective heat transfer fluid.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: July 10, 2012
    Assignee: Prestone Products Corporation
    Inventors: Bo Yang, Aleksei V. Gershun, Peter M. Woyciesjes
  • Patent number: 8216384
    Abstract: Embodiments of the current invention describe a cleaning solution for the removal of high dose implanted photoresist, along with methods of applying the cleaning solution to remove the high dose implanted photoresist and combinatorially developing the cleaning solution.
    Type: Grant
    Filed: November 6, 2009
    Date of Patent: July 10, 2012
    Assignee: Intermolecular, Inc.
    Inventors: Nitin Kumar, Guizhen Zhang
  • Patent number: 8211239
    Abstract: A method for cleaning used beer kegs employing an aqueous solution of phosphoric acid, nitric acid and one or more surfactants, e.g., a detergent and/or wetting agent. Preferably, the aqueous cleaning solution has a total nitric acid content of 12 wt % or less. Complete cleaning can be achieved without using any caustic. The cleaning solution can be recycled repeatedly to clean multiple kegs on numerous occasions over a period of time, e.g., several weeks.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: July 3, 2012
    Assignee: Birko Corporation
    Inventor: Dana J. Johnson
  • Patent number: 8197605
    Abstract: The present invention relates to the use of at least one alkanesulfonic acid of formula R—SO3H, in which R represents a saturated, linear or branched, hydrocarbon chain containing 1 to 4 carbon atoms, as agent for cleaning cement, mortar, concrete, lime, laitance and other derived products. The invention also relates to a method of cleaning cement, mortar, concrete, lime, laitance and other derived products using at least one alkanesulfonic acid.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: June 12, 2012
    Assignee: Arkema France
    Inventors: Jean-Alex Laffitte, Bernard Monguillon
  • Patent number: 8192556
    Abstract: The use of complex fluoride ions of elements of groups 4, 13, or 14 of the periodic table of the chemical elements (preferably selected from complex fluoride ions of the elements B, Si, Ti, and Zr) in concentrations from 30 t 500 millimoles per liter in process solutions for pickling steel or for bleaching and/or passivating pickled surfaces of stainless steel; a process solution for pickling steel or bleaching and/or passivating pickled surfaces of stainless steel comprising: a) one or more strong acids, b) one or more oxidizing agents in the bleaching/passisvating process, c) complex fluoride ions of elements of groups 4, 13 or 14 of the periodic table of the chemical elements in concentrations from 50 to 500 mmoles per liter; replenisher or concentrate containing a combination of active substances thereof; a process for pickling steel or for brightening and/or passivating of pickled surfaces of stainless steel, wherein the surfaces are brought into contact with such a process solution.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: June 5, 2012
    Assignee: Henkel KGaA
    Inventors: Paolo Giordani, Valentino Gasparetto, Mauro Rigamonti
  • Patent number: 8163101
    Abstract: A method for cleaning contaminated surfaces of surgical waste management equipment. The method includes rinsing surfaces of the equipment with water to remove water soluble contaminants and waste material. A rinse solution is applied to the surfaces of the equipment to provide a residual film thereon. The rinse solution includes a first nonionic alkoxylated alcohol surfactant having an HLB value ranging from about 12 to about 15, a second nonionic alkoxylated alcohol surfactant having an HLB value ranging from about 16 to 20, an aqueous solvent, and a bio-film permeation agent. A total of the first surfactant and the second surfactant in the composition ranges from about 2 to about 20 percent by weight of a total weight of the composition.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: April 24, 2012
    Assignee: Stryker Corporation
    Inventors: Joseph B. Dooley, Jeffrey G. Hubrig, Richard H. Devault, Rodney D. Parker, John M. Izenbaard
  • Patent number: 8147713
    Abstract: A method and composition for scale removal and leak detection is disclosed. The composition comprises a scale-removal agent and a fluorescing agent.
    Type: Grant
    Filed: June 30, 2006
    Date of Patent: April 3, 2012
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jeffrey A. Greene, Ronald A. Koehler
  • Patent number: 8133854
    Abstract: The present invention relates to a liquid acidic hard surface cleaning composition comprising an acid system, wherein the acid system comprises formic acid and acetic acid.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: March 13, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Laura Cermenati, Christopher Andrew Morrison, William Mario Laurent Verstraeten
  • Patent number: 8133327
    Abstract: Provided is a substrate processing method that prevents generation of watermarks on a substrate and can be performed at a low cost. The method controls the ambient humidity around the substrate depending on the kind of the chemical liquid, when the substrate is processed with the chemical liquid. The control of the humidity is performed at least in a drying step that dries the substrate W. In one embodiment, the ambient humidity around the substrate is controlled when a fluid containing IPA as a drying fluid is supplied to the substrate W after processing the substrate W with the chemical liquid.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: March 13, 2012
    Assignee: Tokyo Electron Limited
    Inventors: Yoshichika Tokuno, Hiroshi Nagayasu
  • Patent number: 8128754
    Abstract: The pickling process designed for pickling electrical steel strip in a continuous fashion comprising immersing the strip in at least one pickling tub. The pickling tub contains a mixture of HCl, Fe2+, and Fe3+ and a low concentration of HF. Upon exiting the final pickling tub, the strip may be brushed or scrubbed to loosen any residual scale to form a clean strip.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: March 6, 2012
    Assignee: AK Steel Properties, Inc.
    Inventors: Vijay N. Madi, Amanda Glass, Ronald Rodabaugh
  • Patent number: 8118945
    Abstract: A substrate processing method includes a cleaning processing step, a mixed organic solvent supplying step, and a fluorine organic solvent supplying step. The cleaning processing step is a step of cleaning a main surface of a substrate by supplying deionized water to the substrate. The mixed organic solvent supplying step is a step of supplying a fluid of a mixed organic solvent to the main surface of the substrate after the cleaning processing step. The fluid of the mixed organic solvent contains a fluid of a water-soluble organic solvent and a fluid of a fluorine organic solvent having a smaller surface tension than that of the deionized water and a lower water solubility than that of the fluid of the water-soluble organic solvent. The fluorine organic solvent supplying step is a step of supplying the fluid of the fluorine organic solvent to the main surface of the substrate without supplying the fluid of the water-soluble organic solvent after the mixed organic solvent supplying step.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: February 21, 2012
    Assignee: Dainippon Screen Mfg. Co., Ltd.
    Inventor: Atsuro Eitoku
  • Patent number: 8080508
    Abstract: A chelating composition suitable for low-temperature use or storage is disclosed. The chelating compositions include 20 to 70 wt. percent of a polar solvent and 30 to 80 wt. percent of a first component of the formula: wherein R is a hydroxyalkyl group and each R? is individually selected from the group consisting of hydrogen, unsubstituted or inertly substituted alkyl groups, carbonyl-containing alkyl groups, carboxylate-containing alkyl groups, hydroxyalkyl groups and alkoxy groups; R? is selected from the group consisting of hydrogen, unsubstituted or inertly substituted alkyl groups; carbonyl-substituted alkyl groups, carboxylate-containing alkyl groups, hydroxyalkyl groups and alkoxy groups; M1 and M2 are alkali metal ions, wherein the M1 has a higher atomic weight than M2; wherein x+y=n and the mole fraction of M1 is greater than 0.70 to 1. Methods of suppressing crystallization and methods of cleaning surfaces employing the compositions described herein are also disclosed.
    Type: Grant
    Filed: July 26, 2011
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Druce K. Crump, David A. Wilson
  • Patent number: 8052800
    Abstract: A method and aqueous composition are provided for removing at least a portion of a coating from the surface of a substrate. The coating comprises an insulative material, and is contacted with an aqueous composition. The aqueous composition comprises dimethyl formamide.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: November 8, 2011
    Assignee: General Electric Company
    Inventors: Lawrence Bernard Kool, Brock Matthew Lape
  • Patent number: 8038798
    Abstract: A substrate cleaning apparatus is capable of individually setting a threshold value for use in making a check of a resistivity during a rinsing process on a recipe setting screen in each process step. Thus, by setting each threshold value depending on the type of liquid chemical to be used immediately before the rinsing process, the substrate cleaning apparatus can use an optimum threshold value during the rinsing process in each process step to make a check of the resistivity. This allows the proper completion of the rinsing process in each process step.
    Type: Grant
    Filed: May 21, 2008
    Date of Patent: October 18, 2011
    Assignees: Sony Corporation, Dainippon Screen Mfg. Co., Ltd.
    Inventors: Hayato Iwamoto, Noriaki Adachi
  • Patent number: 8029623
    Abstract: Embodiments of the present disclosure include cleaning processes, cleaning machines, and methods of preventing acidification of a cleaning composition in a cleaning process. The cleaning process includes contacting an article having contaminants with a cleaning composition to remove the contaminants from the article, where the cleaning composition comes to have acidic components as a result of contacting the article with the cleaning composition, and where at least 85 percent by weight, based on a total weight of the cleaning composition, of the cleaning composition is an organic solvent, collecting the cleaning composition with the contaminants and the acidic components, separating the contaminants from the cleaning composition (114), and passing the cleaning composition with the acidic components over an ion exchange resin (125) to remove the acidic components from the cleaning composition.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: October 4, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Konrad Geissler, Marius Kuemin
  • Patent number: 8025736
    Abstract: Semiconductor device fabrication equipment performs a PEOX (physical enhanced oxidation) process, and includes a remote plasma generator for cleaning a process chamber of the equipment. After a PEOX process has been preformed, a purging gas is supplied into the process chamber to purge the process chamber, and the remote plasma generator produces plasma using a first cleaning gas. Accordingly, a reactor of the remote plasma generator is cleaned by the first cleaning gas plasma. Subsequently, the purging gas is supplied to purge the process chamber, and the remote plasma generator produces plasma using a second cleaning gas to remove the first cleaning gas plasma from the remote plasma generator and the process chamber. Finally, full flush operations are performed to remove any gases remaining in the process chamber.
    Type: Grant
    Filed: November 20, 2007
    Date of Patent: September 27, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Kyoung-Hwan Chin, Kyoung-In Kim, Hak-Su Jung, Kyoung-Min An
  • Patent number: 8021491
    Abstract: A method for selectively removing an aluminum-poor overlay coating from a substrate of a component, which as a result of its low aluminum content is highly resistant to a selective stripping solution. The method entails diffusing aluminum into the overlay coating to form an aluminum-infused overlay coating having an increased aluminum level in at least an outer surface thereof. The diffusion step is carried out so that the increased aluminum level is sufficient to render the aluminum-infused overlay coating removable by selective stripping. The outer surface of the aluminum-infused overlay coating is then contacted with an aqueous composition to remove the aluminum-infused overlay coating from the substrate. The aqueous composition includes at least one acid having the formula HxAF6, and/or precursors thereof, wherein A is Si, Ge, Ti, Zr, Al, and/or Ga, and x is from 1 to 6.
    Type: Grant
    Filed: June 15, 2009
    Date of Patent: September 20, 2011
    Inventors: Lawrence Bernard Kool, Michael Howard Rucker, David Edwin Budinger
  • Patent number: 8016948
    Abstract: Disclosed herein is a cleaning method useful in removing contaminants from a surface of a coating which comprises an oxide or fluoride of a Group III B metal. Typically the coating overlies an aluminum substrate which is present as part of a semiconductor processing apparatus. The coating typically comprises an oxide or a fluoride of Y, Sc, La, Ce, Eu, Dy, or the like, or yttrium-aluminum-garnet (YAG). The coating may further comprise about 20 volume % or less of Al2O3.
    Type: Grant
    Filed: September 22, 2008
    Date of Patent: September 13, 2011
    Assignee: Applied Materials, Inc.
    Inventors: Xikun Wang, Li Xu, Jennifer Y. Sun
  • Patent number: 8007593
    Abstract: A remover composition containing 1,3-propanediamine (a), 1-hydroxyethylidene-1, 1-diphosphonic acid (b) and water, wherein the remover composition contains the component (a) in an amount of from 0.2 to 30% by weight, the component (b) in an amount of from 0.05 to 10% by weight, and the water in an amount of from 60 to 99.75% by weight, and wherein the composition has a pH at 20° C. of from 9 to 13; and a remover composition containing an organic amine (A), an organic phosphonic acid (B), a linear sugar alcohol (C) and water, wherein the remover composition contains the component (A) in an amount of from 0.2 to 30% by weight, the component (B) in an amount of from 0.05 to 10% by weight, the component (C) in an amount of from 0.1 to 10% by weight, and the water in an amount of from 50 to 99.65% by weight, and wherein the composition has a pH at 20° C. of from 9 to 13.
    Type: Grant
    Filed: June 5, 2006
    Date of Patent: August 30, 2011
    Assignee: Kao Corporation
    Inventors: Sadaharu Miyamoto, Yasushi Sasaki
  • Patent number: 8007594
    Abstract: A method for manufacturing a semiconductor device includes the step of conducting a cleaning process for a wafer formed with copper wiring lines to remove contaminations produced on a back surface of the wafer. The cleaning process is conducted by injecting onto the back surface of the wafer an etchant for removing contaminations and simultaneously injecting onto a front surface of the wafer a reductant containing hydrogen.
    Type: Grant
    Filed: July 12, 2010
    Date of Patent: August 30, 2011
    Assignee: Hynix Semiconductor Inc.
    Inventors: Young Bang Lee, Kwang Kee Chae, Ok Min Moon
  • Patent number: 7976641
    Abstract: A method of extending storage time prior to cleaning a component of a plasma chamber is provided. The method comprises removing the component from the chamber, covering a thermal spray coating on the component while the surface is exposed to atmospheric air, storing the component, optionally removing the covering, and optionally wet cleaning reaction by-products from the thermal spray coating. Alternatively, instead of, or in addition to covering a thermal spray coating on the component, the component can be placed into a desiccator or dry-box.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: July 12, 2011
    Assignee: Lam Research Corporation
    Inventors: Hong Shih, Qian Fu, Tuochuan Huang, Raphael Casaes, Duane Outka
  • Patent number: 7964042
    Abstract: After the rinsing processing is completed, the rotation speed of the substrate is reduced from 600 rpm to 10 rpm to form a puddle-like DIW liquid film. After the supply of DIW is stopped, the control unit waits for a predetermined time (0.5 seconds) so that the film thickness t1 of the puddle-like liquid film becomes approximately uniform. Then, IPA is discharged to a central part of the surface of the substrate at a flow rate of 100 (mL/min) for instance. By the supply of IPA, DIW is replaced with IPA at the central part of the surface of the substrate to form a replaced region. Further, after three seconds of IPA supply, the rotation speed of the substrate is accelerated from 10 rpm to 300 rpm. This causes the replaced region to expand in a radial direction of the substrate so that the entire surface of the substrate is replaced with the low surface-tension solvent.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: June 21, 2011
    Assignee: Dainippon Screen Mfg. Co., Ltd.
    Inventors: Tomonori Kojimaru, Katsuhiko Miya
  • Patent number: 7959739
    Abstract: A cleaning solution and method for removing submicron particles from the surface and/or the bevel of an electronic substrate such as a hard disk media substrate, or an imprint mold used in the manufacturing of the hard disk media or a read/write head assembly part. The cleaning solution comprises a polycarboxylate polymer or an ethoxylated polyamine. The method comprises the step of contacting a surface of the substrate with a cleaning solution comprised of a polycarboxylate polymer or an ethoxylated polyamine. Additional optional steps in the method include applying acoustic energy to the cleaning solution and/or rinsing the surface with a rinsing solution with or without the application of acoustic energy to the rinsing solution.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: June 14, 2011
    Assignee: Fontana Technology
    Inventor: Mark Jonathan Beck
  • Patent number: 7955440
    Abstract: After a water film is formed on a wafer front surface in a chamber, the water film is supplied sequentially with an oxidizing component of an oxidation gas, an organic acid component of an organic acid mist, an HF component of an HF gas, the organic acid mist, and the oxidizing component of the oxidation gas. As a result, the HF component and the organic acid component provide cleaning effect on the wafer surface, and a concentration of the cleaning components in the water film within a wafer surface can be even.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: June 7, 2011
    Assignee: Sumco Corporation
    Inventors: Shigeru Okuuchi, Kazushige Takaishi
  • Patent number: 7947130
    Abstract: Semiconductor processing compositions for use with silicon wafers having an insulating layers and metallization layers on the wafers comprising water and one or more Troika acids which is also referred to as ?,?-disubstituted trifunctional oximes or ?-(Hydroxyimino) Phosphonoacetic acids, their salts, and their derivatives.
    Type: Grant
    Filed: September 24, 2010
    Date of Patent: May 24, 2011
    Inventor: Wai Mun Lee
  • Patent number: 7942980
    Abstract: Starch is removed from the surface of an article using a multi-step method that includes presoaking the article in an acidic solution to remove the starch from the surface of the article and washing the article in an alkaline solution to clean the article.
    Type: Grant
    Filed: February 9, 2006
    Date of Patent: May 17, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Helmut Maier, Tomoaki Nakasone
  • Patent number: 7943563
    Abstract: A method of removing metallic copper from a steel surface defining a bore or cylinder of a gun is provided. The method involves contacting the surface with a composition comprising a polyphosphonic acid, a hydroxyl-substituted primary amine, and water.
    Type: Grant
    Filed: March 22, 2010
    Date of Patent: May 17, 2011
    Assignee: Bulk Chemicals, Inc.
    Inventor: Ted M. Schlosser
  • Patent number: 7909935
    Abstract: The present invention is directed to a method of cleaning an interior surface of a fluid delivery system. The method comprises introducing a first liquid into the fluid delivery system and contacting the interior surface with the first liquid; forming a slurry by introducing a particulate into the first liquid and contacting the interior surface with the slurry; introducing a second liquid into the fluid delivery system and contacting the interior surface with the second liquid; and introducing a third liquid into the fluid delivery system and contacting the interior surface with the third liquid. The first liquid is substantially soluble or substantially insoluble in the second liquid, the second liquid is substantially insoluble in the third liquid, and the particulate is substantially insoluble in the first and second liquids and substantially soluble in the third liquid.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: March 22, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan N. Warren, Phillip J. Beauchamp, Finn Bergishagen, Denise A. Palumbo
  • Patent number: 7902137
    Abstract: An alkaline concentrated detergent composition for use in cleaning hard surfaces, medical instruments and other metal components (parts, tools, utensils, vessels, equipment) having superior cleaning efficacy at much lower alkali content than traditional alkaline cleaners and enhanced scale control properties even when diluted to about 1/40 ounce per gallon to about 1/10 ounce per gallon in potable water and even in exceptionally hard water. The inventive composition maintains its superior cleaning efficacy and scale control properties during use.
    Type: Grant
    Filed: May 28, 2009
    Date of Patent: March 8, 2011
    Assignee: American Sterilizer Company
    Inventors: Ann Maria Kneipp, Nancy-Hope Elizabeth Kaiser
  • Publication number: 20110030738
    Abstract: This invention relates to a plumbing device made of a copper alloy containing nickel salt, that includes a valve and a tube coupling having at least a liquid-contacting part washed with a cleaning fluid incorporating therein nitric acid and hydrochloric acid as an inhibitor under conditions of a temperature and a duration permitting effective removal of nickel salt, thereby performing nickel salt-removing treatment and causing the hydrochloric acid to form a coating film on the surface of the liquid-contacting part thereby effectively precluding elution of nickel salt from the surface of the liquid-contacting part in the presence of the coating film, wherein the nitric acid has a concentration c in a range of 0.5 wt %<c<7 wt % and the hydrochloric acid has a concentration d in a range of 0.05 wt %<d<0.7 wt % in the cleaning fluid, wherein the temperature is set to 10° C.?x 50° C., and wherein nickel salt is removed with the cleaning fluid.
    Type: Application
    Filed: October 22, 2010
    Publication date: February 10, 2011
    Inventor: Norikazu Sugaya
  • Patent number: 7879153
    Abstract: It relates to a method for removing a surfactant, organic materials and chlorine ions remained on the surface of metal nanoparticles, prepared on an organic solvent phase including a surfactant. The method for cleaning metal nanoparticles herein is efficient to remove organic materials or chlorine ions remained on the surface of the nanoparticles. Not less than 90% of impurities may be removed by this method. As a result, the thickness of a multi layer ceramic capacitor (MLCC) can be reduced and a packing factor can be improved so that it allows thinner multi layer ceramic capacitors and improved utilities of metal nanoparticles as fuel cell catalysts, hydrogenation reaction catalysts, alternative catalysts of platinum (Pt) in chemical reactions and the like.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: February 1, 2011
    Assignee: Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jung-Wook Seo, Hyo-Seung Nam, Young-Ku Lyu, Kyung-Mi Kim, Jong-Sik Kim, Tae-Ho Kim
  • Patent number: 7875349
    Abstract: A polymer inactivation method for a polycrystalline silicon manufacturing device, wherein humidified gas such as water vapor and humidified nitrogen gas is supplied into a reacting furnace for manufacturing polycrystalline silicon to hydrolyze polymers adhered to an inner surface of the reacting furnace. It is preferable that a furnace wall of the reacting furnace is heated when the humidified gas is supplied.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: January 25, 2011
    Assignee: Mitsubishi Materials Corporation
    Inventors: Toshihide Endoh, Masayuki Tebakari, Toshiyuki Ishii, Masaaki Sakaguchi
  • Patent number: 7850786
    Abstract: Described is a space-conserving integrated fluid delivery system particularly useful for gas distribution in semiconductor processing equipment. The system includes integrated fluid flow network architecture, and may include, in addition to a layered substrate containing fluid flow channels, various fluid handling and monitoring components. The layered substrate is diffusion bonded. Subsequent to diffusion bonding, a stainless steel diffusion bonded part may advantageously be treated to enhance corrosion resistance using a series of steps designed to bring more chromium to the surface of the steel.
    Type: Grant
    Filed: October 17, 2006
    Date of Patent: December 14, 2010
    Assignee: Applied Materials, Inc.
    Inventors: Mark Crockett, John W. Lane, Micahel DeChellis, Chris Melcer, Erica Porras, Aneesh Khullar, Balarabe N. Mohammed
  • Patent number: 7846267
    Abstract: The invention is generally related to cleaning compositions and methods of using same. More particularly, the invention is related to cleaning compositions which are substantially free of volatile organic chemicals.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: December 7, 2010
    Assignee: United Laboratories, Inc.
    Inventors: Nancy Sherrel, David Rogel
  • Patent number: 7828908
    Abstract: A biodegradable acid cleaning composition for cleaning stainless steel, and other surfaces is disclosed. The composition comprises urea sulfate in combination with gluconic acid which serves as a corrosion inhibitor. The composition retains the cleaning and corrosion prevention properties of similar phosphoric acid solutions but is safe for the environment and is less expensive to produce. Applicants have surprisingly found that the traditionally alkaline corrosion inhibitor, gluconic acid, can work effectively in an acidic cleaning composition.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: November 9, 2010
    Assignee: Ecolab USA, Inc.
    Inventor: Altony Miralles
  • Patent number: 7824503
    Abstract: The invention pertains to an aqueous composition having a pH of 3 or less and comprising the following ingredients, based on the total weight of the composition: a) 0.05-40 wt % of a polymeric thickener having —COOR groups, wherein R is independently chosen from H, OH, and a carbon-containing group, and b) 0.05-60 wt % of hydrogen peroxide, wherein the active oxygen content attributable to ingredient a) is at least 0.02 wt %, based on the total weight of the composition, with the proviso that (co)polymers prepared from (meth)acrylate monomers are absent.
    Type: Grant
    Filed: April 12, 2007
    Date of Patent: November 2, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Wasil Maslow, René Gerritsen, Bernhard De Vries, John Meijer, Paul Albert Iacobucci
  • Patent number: 5236960
    Abstract: The invention relates to water blown integral skin polyurethane foams made with a particular isocyanate quasi-prepolymer and resin side ingredients to yield a foam having good overall mechanical properties. The isocyanate quasi-prepolymer component of the present invention comprises from 0.5 weight percent to 30.0 weight percent or less uretonimine-carbodiimide-modified diphenylmethane diisocyanate, from 50 weight percent to 80 weight percent 4,4'-diphenylmethane diisocyanate and reacted with from 15 weight percent to 40 weight percent of a polyether polyol containing predominately secondary hydroxyl groups and having an average molecular weight from about 2,000 to 10,000, an average functionality from 1.5 to about 3.2, and a hydroxyl number from about 20 to 60, and optionally with a low molecular weight diol in an amount of from 1.0 weight percent to 10 weight percent, the weight percentages based on the weight of the quasi-prepolymer reactants.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: August 17, 1993
    Assignee: BASF Corporation
    Inventors: Richard P. Harrison, Michael Scarpati, Thirumurti Narayan, Blair J. Zagata
  • Patent number: RE42136
    Abstract: A cleaning composition which may be a stainless steel cleaning composition comprising a branched ester and an organic solute. The use and a method of using the cleaning composition is also included within the scope of the present invention.
    Type: Grant
    Filed: May 30, 2005
    Date of Patent: February 15, 2011
    Assignee: Brilliance Intellectual Property Limited
    Inventors: Judith Helen Blyth, Fadil Al-Alawi