Ethanol Patents (Class 203/19)
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Patent number: 7682821Abstract: The invention provides a device for growing genetically enhanced aquatic photoautotrophic organisms in a stable culture, causing said organisms to produce ethanol, and then separating, collecting, and removing the ethanol in situ.Type: GrantFiled: October 30, 2007Date of Patent: March 23, 2010Assignee: Algenol Biofuels Switzerland GmbHInventors: R. Paul Woods, Edward Legere, Benjamin Moll, Carlos Unamunzaga, Eulalia Mantecon
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Publication number: 20100051441Abstract: Processes for removing water from organic solvents, such as ethanol. The processes include distillation in two columns operated at sequentially higher pressure, followed by treatment of the overhead vapor by one or two membrane separation steps.Type: ApplicationFiled: August 27, 2008Publication date: March 4, 2010Applicant: Membrane Technology and Research, Inc.Inventors: Leland M. Vane, Franklin R. Alvarez, Yu Huang, Richard W. Baker
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Patent number: 7666282Abstract: The invention is a process for the purification of ethanol. In one embodiment the process includes boiling a degassed beer feed (106) in a pre-boiler (110) to provide a vapor by-pass fraction (112) that by-passes the conventional beer column and is fed into the rectifier column (124). The process allows free capacity in the rectifier column of new or established plants to be filled by ethanol-water vapor and/or condensate streams that do not originate from the beer column.Type: GrantFiled: December 28, 2005Date of Patent: February 23, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Robert G. Sylvester, Stephen Thomas Breske, David A. Culver, Bruce M. Vrana
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Patent number: 7594981Abstract: A method for concentrating a water-soluble organic material wherein a mixture of the water-soluble organic material with water is distilled in a distillation column (11), and the fraction from the top (11a) of the distillation column (11) is separated by the use of a membrane separator (14) into a permeated vapor (F2) and a non-permeated vapor (F3), which comprises once condensing the fraction to form a condensate, heating the condensate in an evaporator (13) to generate a vapor (F1) having a pressure higher than the operation pressure for the distillation column (11), and introducing the vapor (F1) to the membrane separator (14), thereby separating water from the mixture.Type: GrantFiled: February 20, 2004Date of Patent: September 29, 2009Assignee: Mitsubishi Chemical CorporationInventor: Shiro Ikeda
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Patent number: 7572353Abstract: A process arrangement for distilling fuel grade ethanol include a distillation portion which distills beer to produce thin stillage and hot ethanol vapor. In an evaporation portion, a set of first effect evaporators which are heated either by plant steam or hot ethanol vapor, concentrate thin stillage into mid stillage while producing first effect steam. The first effect steam from the first effect evaporators provides heat to a set of second effect evaporators which concentrate the mid stillage into a syrup for further drying. The second effect evaporators produce second effect steam which is used to heat the distillation portion of the process arrangement. The multiple evaporators of the first and second effects of the evaporation portion can be selectively taken off-line for maintenance while the evaporation portion and the remainder of the process arrangement continue to operate at full capacity.Type: GrantFiled: August 23, 2006Date of Patent: August 11, 2009Assignee: ICM, Inc.Inventor: Dennis Lee Vander Griend
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Publication number: 20090166172Abstract: The present invention conserves water by reducing the heat load placed on a cooling tower during the ethanol fuel production process. An air cooler is placed between the ethanol vapor condenser and the cooling tower thereby minimizing process temperature spikes before water enters the cooling tower. This, in turn, shortens the process cycle thereby increasing ethanol production. During certain climactic conditions, the cooling tower may be completely bypassed, thereby conserving more water and increasing ethanol production.Type: ApplicationFiled: December 28, 2007Publication date: July 2, 2009Inventor: Leonard Ray Casey
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Patent number: 7553397Abstract: A process is described for the recovery of substantially pure ethyl acetate from a feedstock including ethyl acetate, ethanol and water. The process includes supplying the feedstock to a first distillation zone maintained under first distillation conditions effective for distilling from the feedstock a first distillate including ethyl acetate, ethanol, and less than about 10 mol % water. The first distillate is recovered from the first distillation zone and is supplied to a second distillation zone maintained under second distillation conditions, which include use of a higher pressure than that of the first distillation zone. The second distillation conditions are effective for distilling from the first distillate a second distillate including ethanol, water, and a minor proportion of ethyl acetate and yielding a substantially pure ethyl acetate bottom product, which is recovered. The second distillate is returned to the first distillation zone.Type: GrantFiled: September 29, 1999Date of Patent: June 30, 2009Assignee: Davy Process Technology LimitedInventors: Stephen William Colley, Christopher Richard Fawcett, Mohammad Sharif, Michael William Marshall Tuck, David John Watson, Michael Anthony Wood
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Publication number: 20090127092Abstract: The various embodiments of the present invention provide improved systems and methods for producing or collecting fuel grade ethanol from fermentation products. The systems and methods disclosed herein make use of extractive distillation to separate the ethanol from other components, such as water. In producing fuel grade ethanol, the systems and methods are capable of expending less than seven percent of the heating value of the ethanol.Type: ApplicationFiled: November 10, 2008Publication date: May 21, 2009Applicant: Georgia Tech Research CorporationInventor: DANIEL W. TEDDER
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Patent number: 7507273Abstract: A scalable technology for purifying ethanol, wherein the vaporization of ethanol is coupled with a chromatographic rectification process comprising feeding a vaporized ethanol/water mix onto a plurality of molecular sieve beds to produce dehydrated ethanol vapor, which can then be condensed to recover purified dehydrated ethanol liquid. The scalable technology process is suitable for farm-scale production of fuel-grade ethanol, having the added benefit of allowing wet distillers grains to be used on-site as live-stock feed. By reducing energy requirements, costs and pollution, the output can be scaled to produce fuel-grade ethanol at quantities of anywhere from about 1000 gallons per year to upwards of hundreds of millions of gallons per year. Particularly beneficial versions utilize a plurality of smaller molecular sieve beds in series and use heat generated during desorption and regeneration of the molecular sieve beds as an energy source to aid in the vaporization step.Type: GrantFiled: June 20, 2006Date of Patent: March 24, 2009Assignee: 6Solutions, LLCInventor: Cecil T. Massie
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Publication number: 20090057224Abstract: Processes for removing water from organic compounds, especially polar compounds such as alcohols. The processes include a membrane-based dehydration step, using a membrane that has a dioxole-based polymer selective layer or the like and a hydrophilic selective layer, and can operate even when the stream to be treated has a high water content, such as 10 wt % or more. The processes are particularly useful for dehydrating ethanol.Type: ApplicationFiled: August 30, 2007Publication date: March 5, 2009Applicant: Membrane Technology and Research, Inc.Inventors: Yu Huang, Richard W. Baker, Tiem Aldajani, Jennifer Ly
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Publication number: 20090057128Abstract: An improved process for separation of liquid mixtures involves vapor stripping followed by mechanical compression of the vapor which is then exposed to a permeation membrane for separation of the compressed vapor.Type: ApplicationFiled: August 30, 2007Publication date: March 5, 2009Inventors: Leland Vane, Franklin R. Alvarez
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Patent number: 7479227Abstract: A process for separating a component from a low molecular weight organic mixture by pervaporation. The process uses fluorinated membranes and is particularly useful for treating mixtures containing light organic components, such as methane, propylene or n-butane.Type: GrantFiled: August 31, 2005Date of Patent: January 20, 2009Assignee: Membrane Technology and Research, Inc.Inventors: Andre R. Da Costa, Ramin Daniels, Ankur D. Jariwala
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Publication number: 20090014313Abstract: An energy-efficient extractive distillation process for producing anhydrous ethanol from aqueous/ethanol feeds containing any range of ethanol employs an extractive distillation column (EDC) that operates under no or greatly reduced liquid reflux conditions. The EDC can be incorporated into an integrated process for producing anhydrous ethanol used for gasoline blending from fermentation broth. By using a high-boiling extractive distillation solvent, no solvent is entrained by the vapor phase to the EDC overhead stream, even under no liquid reflux conditions. The energy requirement and severity of the EDC can be further improved by limiting ethanol recovery in the EDC. In this partial ethanol recovery design, ethanol which remains in the aqueous stream from the EDC is recovered in a post-distillation column or the aqueous stream is recycled to a front-end pre-distillation column where the ethanol is readily recovered since the VLE curve for ethanol/water is extremely favorable for distillation.Type: ApplicationFiled: July 13, 2007Publication date: January 15, 2009Inventors: Fu-Ming Lee, Kuang-Yeu Wu, Lindsey Vuong, Fong-Cheng Su, Tzong-Bin Lin, Jyh-Haur Hwang, Hung-Chung Shen, Po-Sung Cheng, Tai-Ping Chang
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Publication number: 20090004713Abstract: Processes for removing water from organic solvents, such as ethanol. The processes include distillation in two columns operated at sequentially higher pressure, followed by treatment of the overhead vapor by one or two membrane separation steps.Type: ApplicationFiled: August 27, 2008Publication date: January 1, 2009Applicant: Membrane Technology and Research, Inc.Inventors: Nicholas P. Wynn, Yu Huang, Masakatsu Urairi, Richard W. Baker
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Publication number: 20080251374Abstract: A method and system are disclosed for converting paper mill sludge into ethanol. The method and system include selecting effluent streams within the paper mill having high BOD levels to combine with the sludge to both facilitate the treatment of the sludge and contribute effluent BOD to the production of ethanol.Type: ApplicationFiled: April 16, 2007Publication date: October 16, 2008Applicant: TEAM TEN, LLCInventor: Brent Alan McManigal
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Publication number: 20080245653Abstract: The present invention relates to a method of anhydrous ethanol production using circulation by multiple towers' alternation, the procedure includes the steps of heating, adsorption, internal circulation, vacuum suction, washing and resolving etc. The method can prolong the life of adsorbent, reduce the heat exchanger's surface, cooling water, the equipment investment and energy consumption, provide high ethanol recovery rate and high dehydration, and protect environment.Type: ApplicationFiled: August 29, 2006Publication date: October 9, 2008Inventors: Yaling Zhong, Yuming Zhong
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Publication number: 20080210540Abstract: The present invention provides a system and a process for the recovery of an organic solvent from a mixture of an organic solvent and water. The process comprises subjecting an organic solvent/water mixture to a distillation system whereby a vapor is produced. The output from the distillation process passes through a filtration unit which comprises a hydrophilic membrane filter. The solvent/water mixture passing through the filtration unit is separated into a concentrate and a permeate. The concentrate (containing mostly organic solvent) can be collected, can be routed to the distillation system for further purification, or can be routed to a second filtration system for further purification. The permeate (containing mostly water) is routed from the filtration unit to a condenser where it is condensed and collected.Type: ApplicationFiled: January 17, 2008Publication date: September 4, 2008Inventor: Rex A. Dieterle
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Publication number: 20080047822Abstract: A method for providing ethanol dehydration services is disclosed. A farmer may take advantages of a new service through the use of a resident ethanol production facility and produce hydrous alcohol. An ethanol dehydration service provider may set up a small scale ethanol dehydration service facility adjacent to the farmer, or alternatively, pick up the hydrous alcohol from the farmer. The farmer delivers hydrous ethanol to the ethanol dehydration service facility where dehydration service is performed. After dehydration, dehydrated ethanol is returned to the farmer who can then sell it for a better price to fuel blending companies, or blend it into E-85 or other motor fuel.Type: ApplicationFiled: October 23, 2006Publication date: February 28, 2008Inventor: Michael R. Ling
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Patent number: 7291250Abstract: The present invention relates to a vacuum distillation plant and a process for concentrating organic aqueous solutions, especially spissum extracts, using said plant. The vacuum distillation plant of the invention comprises a flash evaporator, a means for vapor concentration and a multi-stage condenser positioned down-stream of said means for vapor concentration, means for recycling at least part of the condensate from a condensation stage into the bottoms product being provided. In addition, the present invention relates to a process for concentrating organic aqueous solutions such as concentrated extracts using said plant.Type: GrantFiled: October 20, 1999Date of Patent: November 6, 2007Assignee: Bionorica AGInventors: Michael A. Popp, Heinz Walter Joseph, Michael R. Rannow
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Patent number: 7232878Abstract: A process for the separation of volatile material from particulate polymer which has been substantially freed from unreacted monomer in an earlier separation step, comprising (a) feeding the particulate polymer to a purge vessel, optionally causing it to move through the vessel in substantially plug-flow mode, (b) heating the particulate polymer in the purge vessel to a temperature greater than 30° C. but insufficiently high to cause the particles to become agglomerated, and/or maintaining the polymer at a temperature in this range in the purge vessel, (c) feeding air to the purge vessel counter-current to the movement of the particulate polymer to remove volatile material therefrom, (d) removing the particulate polymer from the purge vessel. Preferably the particulate polymer fed to the purge vessel is caused to move through the vessel in substantially plug-flow mode. The process is particularly suitable for polyethylene.Type: GrantFiled: April 18, 2002Date of Patent: June 19, 2007Assignee: BP Chemicals LimitedInventors: Gerald Mulgrew, Gary Lindsay Pitman
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Patent number: 7070694Abstract: Apparatus and processes are disclosed for economical separation of fluid mixtures. Broadly, apparatus of the invention is an integrated fractional distillation and perm-selective membrane separation apparatus. More particularly, the integrated apparatus comprises a fractional distillation column and one or more membrane device utilizing solid perm-selective membranes. Processes of the invention are particularly useful for simultaneous recovery of a very pure permeate product, a desired non-permeate stream, and one or more distillate products from a fluid mixture containing at least two compounds of different boiling point temperatures.Type: GrantFiled: March 20, 2003Date of Patent: July 4, 2006Assignee: BP Corporation North America Inc.Inventors: Craig W. Colling, George A. Huff, Jr., Stephen J. Pietsch
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Patent number: 6964728Abstract: Bisphenol-A-bis(neopentylglycolphosphate) products of enhanced properties and processes for preparing them are described. One of the processes includes (a) mixing and reacting neopentyl glycol and bisphenol-A-bis(dichlorophosphate) in an inert polar organic solvent which (1) if mixed by itself with an equal volume of water at 25° C., will form a separate phase, (2) the solvent by itself will dissolve at least about 10 wt % of bisphenol-A-bis(neopentylglycolphosphate) at a temperature in the range of 25 to 50° C., and optionally but preferably (3) the solvent by itself can be completely vaporized at a temperature below about 180° C.; (b) washing bisphenol-A-bis(neopentylglycolphosphate) product formed in a) while dissolved in inert organic solvent having such characteristics at least once with an aqueous alkaline washing solution; and (c) optionally but preferably, recovering bisphenol-A-bis(neopentylglycolphosphate) product from organic solvent having such characteristics.Type: GrantFiled: May 16, 2002Date of Patent: November 15, 2005Inventors: Bonnie G. McKinnie, Robert E. Williams, Gary L. Sharp, Alireza M. Dadgar
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Patent number: 6755975Abstract: A process for treating liquids containing organic compounds and water. The process includes a pervaporation step in conjunction with a dephlegmation step to treat at least a portion of the permeate vapor from the pervaporation step. The process yields a membrane residue stream, a stream enriched in the more volatile component (usually the organic) as the overhead stream from the dephlegmator and a condensate stream enriched in the less volatile component (usually the water) as a bottoms stream from the dephlegmator. Any of these may be the principal product of the process. The membrane separation step may also be performed in the vapor phase, or by membrane distillation.Type: GrantFiled: June 12, 2002Date of Patent: June 29, 2004Assignees: Membrane Technology and Research, Inc., The United States of America as represented by the Environmental Protection AgencyInventors: Leland M. Vane, Anurag P. Mairal, Alvin Ng, Franklin R. Alvarez, Richard W. Baker
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Publication number: 20030019736Abstract: The present invention provides a system and method for utilizing DDGS by-products from an ethanol plant. In one embodiment, the DDGS is burned to release thermal energy, which is used to produce steam needed for the operation of the ethanol plant. This method can realize approximate 67% savings in the fuel cost over the conventional propane-fueled ethanol plant.Type: ApplicationFiled: June 6, 2002Publication date: January 30, 2003Inventor: Daniel T. Garman
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Patent number: 6414205Abstract: A process for the selective hydrogenation of the methyl acetylene and propadiene (MAPD) in a propylene rich stream is disclosed wherein the selective hydrogenation is carried out stepwise (a) first in a single pass fixed bed reactor and then (b) in a distillation column reactor containing a supported PdO hydrogenation catalyst which serves as a component of a distillation structure. Conversion and selectivity to propylene in improved over the use of the single pass fixed bed reactor alone.Type: GrantFiled: March 24, 2000Date of Patent: July 2, 2002Assignee: Catalytic Distillation TechnologiesInventors: Stephen J. Stanley, Gary R. Gildert
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Patent number: 6375807Abstract: A method of separating ethanol and ethyl acetate, and ethanol and water involves distilling a mixture of the components by an extractive distillation process in the presence of an extractive distillation solvent. The extractive distillation solvent may be an amine, an alkylated thiopene, and paraffins.Type: GrantFiled: September 28, 2000Date of Patent: April 23, 2002Inventors: Izak Nieuwoudt, Braam Van Dyk
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Patent number: 6093845Abstract: This invention relates to a process for the simultaneous co-production of ethyl acetate and n-butyl acetate. The process involves reacting a reaction mixture of ethanol, n-butanol and acetic acid in the liquid phase, in the presence of an acidic catalyst. The process is carried out in a series of reactor and distillation columns. The process is capable of using relatively impure reactants and provides for removing some of the aldehyde type impurities by the use of resin guard beds.Type: GrantFiled: November 25, 1998Date of Patent: July 25, 2000Assignee: BP Chemicals LimitedInventors: Patrick Eduard van Acker, Olivier Mathieu, Russell James Milner, Witold Franciszek Pacynko
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Patent number: 5932182Abstract: Reactor for containing high pressure, high temperature, corrosive reactions, especially supercritical water reactions. The reactor comprises an inner reactor vessel which houses the corrosive reaction, an outer containment vessel which contains a substantial level of the pressure, and insulating means to contain the high temperature of the inner reactor, which prevents the outer containment vessel from rising above a specified maximum temperature. Using this reactor, the lifetime and reliability of the materials of construction are increased because the outer pressure-containing vessel does not experience the high temperatures which tend to cause metals and alloys to lose ductility, and the inner reactor vessel does not experience a high pressure drop across its walls and, therefore, can be made of temperature and corrosive-resistant materials which are not required to sustain high stress without failure.Type: GrantFiled: February 23, 1998Date of Patent: August 3, 1999Assignee: Kimberly-Clark Worldwide, Inc.Inventor: Carol Ann Blaney
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Patent number: 5800681Abstract: Ethanol, isopropanol and water cannot be separated from each other by distillation or rectification because of minimum azeotropes. They are readily separated by extractive distillation. Effective agents are: dimethylsulfoxide for ethanol, phenol for isopropanol.Type: GrantFiled: April 21, 1997Date of Patent: September 1, 1998Inventor: Lloyd Berg
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Patent number: 5766895Abstract: The invention describes a method for the economic production of ethyl alcohol involving dehydration of the alcohol in an adsorption-desorption process using ion exchange resins which have been swollen in water from about 50 to 300 times their weight.Type: GrantFiled: July 19, 1996Date of Patent: June 16, 1998Assignee: Innoval Management LimitedInventors: George N. Valkanas, Nicolas P. Valkanas, Apostolos G. Vlyssides, Athanassios G. Theodoropoulos
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Patent number: 5762765Abstract: Ethanol, isopropanol and water cannot be separated from each other by rectification because of the presence of minimum azeotropes. They are readily separated by azeotropic distillation. Effective agents are cyclopentane for ethanol from water, methyl acetate for isopropanol from water.Type: GrantFiled: April 14, 1997Date of Patent: June 9, 1998Inventor: Lloyd Berg
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Patent number: 5624534Abstract: An apparatus and method for stripping volatiles from a feed stream and concentrating the volatiles in the overhead vapors forming a condensate product and simultaneously producing a low percent volatiles outlet stream as a concentrate product. The volatiles separator and concentrator, ("VSC"), unit has many applications in the reduction and the concentration of voiatiles in the beverage, fuel, and industrial alcohol industries, as well as in chemical applications for removing or stripping volatiles from heat sensitive feed substrates which require low temperatures and a short residence time to prevent degradation of the product. For heat sensitive applications, the VSC unit utilizes a short feed stream preheat contact time in combination with turbulent high velocity flow to separate and concentrate volatile and nonvolatile components at temperatures below 100.degree. F. utilizing flash vaporization for volatiles separation with reboil capability to adjust volatiles concentration in the residue and product.Type: GrantFiled: June 7, 1995Date of Patent: April 29, 1997Inventors: Armand R. Boucher, Philip N. Hambrick
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Patent number: 5458739Abstract: An apparatus and method for stripping volatiles from a feed stream and concentrating the volatiles in the overhead vapors forming a condensate product and simultaneously producing a low percent volatiles outlet stream as a concentrate product. The volatiles separator and concentrator, ("VSC"), unit has many applications in the reduction and the concentration of volatiles in the beverage, fuel, and industrial alcohol industries, as well as in chemical applications for removing or stripping volatiles from heat sensitive feed substrates which require low temperatures and a short residence time to prevent degradation of the product.The preferred embodiment of the VSC unit utilizes a short feed stream preheat contact time in combination with turbulent high velocity flow at temperatures below 100.degree. F. to provide flash aporization for volatiles separation with reboil capability to adjust volatiles concentration in the residue and product. The application of high vacuum in the range of 27" to 28.Type: GrantFiled: February 4, 1994Date of Patent: October 17, 1995Assignee: Vendome Copper & Brass WorksInventors: Armand R. Boucher, Philip N. Hambrick
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Patent number: 5348624Abstract: For separating ETBE and ethanol the following principal stages are employed:(1) Extraction of ethanol by water, the raffinate being ETBE saturated in water and the extract an ethanol/water mixture containing a small proportion of ETBE;(2) Concentration of the above mixture, the distillate being a mixture close to the ethanol/water azeotrope in composition and containing a very small proportion of ETBE;(3) Heteroazeotropic distillation of this distillate in two coupled columns with an overhead decanter, this distillation using ETBE as azeotroping agent; the residue of the first column being ethanol which is ca. 99% by mole and the residue of the second column being practically pure water, this water and the water recovered during the concentration stage being used as extraction solvent in stage (1).Stage (3) may be an ethanol dehydration unit using ETBE as dehydrating agent.Type: GrantFiled: November 12, 1992Date of Patent: September 20, 1994Assignee: Institut Francais du PetroleInventors: Annick Pucci, Paul Mikitenko, Massimo Zuliani
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Patent number: 5294304Abstract: This invention relates to a process for the production of absolute alcohol from aqueous alcohol, whereby saving of energy to a greater extent is rendered possible in a more simple process, as compared with the prior art azeotropic distillation method using benzene or cyclohexane. That is, aqueous alcohol is subjected to extractive distillation in a first distillation column under such a condition that a liquid and gas of a solvent simultaneously coexist using low pressure propane, propylene and butane as the solvent, absolute alcohol substantially free from water is recovered from the bottom of the distillation column and subjected to stripping of hydrocarbons in a second distillation column, during which the gaseous phases of the first and second distillation columns are mixed and compressed, utilized through recompression as a heat source of a reboiler of the first distillation column, subjected to separation of water content and recycled to the upper parts of the first and second distillation columns.Type: GrantFiled: March 9, 1993Date of Patent: March 15, 1994Assignee: Ministry of International Trade and IndustryInventors: Yoshikazu Kano, Hirotoshi Horizoe, Tetsuya Tanimoto, Itsuo Yamamoto
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Patent number: 5124004Abstract: A method of distillation employing a heat pump (which may be driven by a compressor) using a vapor stream from within the distillation system as a heat source and a liquid stream from within the distillation system as a heat sink. The selection of heat-source vapors and heat-sink liquid is such that at least one is withdrawn from the phase-contracting region of the distillation system. The return of streams withdrawn from the phase-contacting region of the distillation system to the distillation system is such that at least one of the streams is returned at a temperature different from that of the point from which it was withdrawn, and all withdrawn streams are returned in manner such that a stream removed as vapor is returned at a point with a temperature at most that at the point it was withdrawn, and a stream removed as liquid is returned at a point with a temperature at least that at which it was withdrawn.Type: GrantFiled: February 6, 1990Date of Patent: June 23, 1992Assignee: Trustees of Dartmouth CollegeInventors: Hans E. Grethlein, Lee R. Lynd
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Patent number: 5059327Abstract: A preparation membrane for pervaporation which comprises a crosslinked reaction mixture of a polyvinyl alcohol or polyvinyl alcohol copolymer and a polystyrene sulfonic acid or polystyrene sulfonic acid copolymer. A method for separating a mixture of water and an organic compound by using the membrane is also disclosed.Type: GrantFiled: August 25, 1987Date of Patent: October 22, 1991Assignee: Director-General, Agency of Industrial Science and TechnologyInventor: Shinsuke Takegami
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Patent number: 5035776Abstract: A thermally-integrated extractive distillation process for recovering anhydrous ethanol from fermentation or synthetic feedstocks has a distillation train of four columns. Two columns are preconcentrators operated in parallel. The remaining columns are an extractive distillation dehydrating tower, and an entrainer-recovery column. The two preconcentrators and the dehydrating tower are operated at three successively increasing pressures so that the condensing vapors of the overhead product of the dehydrating tower supply the necessary heat to the reboiler of the intermediate-pressure preconcentrator. The overhead vapors of this preconcentrator are, in turn, used to supply the required heat to the reboiler of the lowest-pressure preconcentrator. The bottom product from each preconcentrator is used to preheat the dilute feed. Additional energy savings are accomplished by the appropriate heat exchange between the various feeds, overheads, and bottoms.Type: GrantFiled: March 29, 1990Date of Patent: July 30, 1991Assignee: University of MassachusettsInventor: Jeffrey P. Knapp
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Patent number: 4983303Abstract: A novel method of separating a particular component from its liquid solution by the use of a vessel divided into a solution chamber receiving the liquid solution and a vacuum chamber by a permeable membrane having selective permeability. The method is characterized to evacuate the vacuum chamber while keeping the liquid solution out of direct contact with the permeable membrane such that the permeation of the particular component through the permeable membrane can be effected in vapor-to-vapor phase environment, which is found to give a superior separation result for the liquid solution.Type: GrantFiled: December 9, 1987Date of Patent: January 8, 1991Assignee: Lignyte Co., Ltd.Inventor: Tadashi Uragami
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Patent number: 4978430Abstract: An improved method for dehydration and concentration of an aqueous solution containing an organic compound is disclosed. The solution is evaporated to produce a gaseous mixture comprising an organic compound vapor and a water vapor. The water vapor is selectively removed from the gaseous mixture by permeation through an aromatic polyimide gas separation membrane while the gaseous mixture being kept in contact with a surface on one side of the gas separation membrane at a temperature of 70.degree. C. or higher to obtain a gaseous mixture comprising the organic compound vapor and a reduced amount of a water vapor.Type: GrantFiled: July 24, 1989Date of Patent: December 18, 1990Assignee: UBE Industries, Ltd.Inventors: Kanji Nakagawa, Yoshio Asakura, Shigeru Yamamoto, Kohei Ninomiya, Masayuki Kinouchi
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Patent number: 4961826Abstract: A method of distillation employing a heat pump (which may be driven by a compressor) using a vapor stream from within the distillation system as a heat source and a liquid stream from within the distillation system as a heat sink. The selection of heat-source vapors and heat-sink liquid is such that at least one is withdrawn from the phase-contacting region of the distillation system. The return of streams withdrawn from the phase-contacting region of the distillation system to the distillation system is such that at least one of the streams is returned at a temperature different from that of the point from which it was withdrawn, and all withdrawn streams are returned in manner such that a stream removed as vapor is returned at a point with a temperature at most that at the point it was withdrawn, and a stream removed as liquid is returned at a point with a temperature at least that at which it was withdrawn.Type: GrantFiled: August 19, 1986Date of Patent: October 9, 1990Assignee: Trustees of Dartmouth CollegeInventors: Hans E. Grethlein, Lee H. Lynd
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Patent number: 4956052Abstract: A process for separation of components of a mixture of more than one organic substance or of a mixture of at least one organic substance and water by extraction using a supercritical fluid as an extractant. During the extraction an extraction aid having a higher affinity with an unextractable component of the mixture than with an extractable component of the mixture is present. Also disclosed is an apparatus for carrying out this process.Type: GrantFiled: September 13, 1989Date of Patent: September 11, 1990Assignee: Suntory LimitedInventors: Mitsuho Hirata, Takeshi Ishikawa, Hiroshi Shiraishi
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Patent number: 4952503Abstract: In the production of ethanol by continuous fermentation in a fermentor (4) with continuous stillage recirculation (19, 20) to the fermentor, the fermentation liquid (6) continuously withdrawn from the fermentor is first sieved in a straining step (7) for separation of coarse solid particles. Then the fermentation liquid (11) is separated in a yeast separation step (12), from which a yeast stream (13) is recirculated to the fermentor (4) and a yeast-free stream (14) is fed to a primary distillation step (9). From the bottom stream (16) from the distillation step (9) a part (19, 20) is recirculated to the fermentor and another part is subjected to final stripping in a secondary distillation step (10).Type: GrantFiled: June 19, 1986Date of Patent: August 28, 1990Inventor: Jurgen Granstedt
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Patent number: 4944881Abstract: A liquid separation membrane for pervaporation composed of a polymeric substance having in the main chain a glycosidic skeleton containing cationic groups and/or anionic groups at least some of which form a salt with counter anions and/or counter cations; and a method for pervaporation, which comprises separating a water-organic liquid mixture or an organic liquid-organic liquid mixture by pervaporation using a separation membrane, said membrane being composed of a polymeric substance having in the main chain a glycosidic skeleton containing cationic groups and/or anionic groups at least some of which form a salt with counter anions and/or counter cations and being dried so as to have a water content of not more than 25% by weight.Type: GrantFiled: November 29, 1988Date of Patent: July 31, 1990Assignee: Agency of Industrial Science and TechnologyInventors: Akira Michizuki, Yoshio Sato, Hisashi Ogawara, Syuzo Yamashita
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Patent number: 4900402Abstract: A pervaporation process for separating at least one component from a mixture of liquids, for example for separating ethanol from a fermentation mass, by a series of three separation steps: separating the mixture by a first pervaporation to form a first permeate vapor enriched in the component to be separated; fractionating the first permeate vapor, for example by temperature condensation, to form a high concentration fraction twice enriched in the component to be separated; and either distilling the high concentration fraction or a second pervaporation to form a distillate or retentate liquid thrice enriched in the component to be separated.Type: GrantFiled: March 25, 1987Date of Patent: February 13, 1990Assignee: Kernforschungszentrum Karlsruhe GmbHInventors: Jurgen Kaschemekat, Frank Schutt, Axel Wenzlaff
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Patent number: 4895989Abstract: A process is described for the production of alcoholates from alkali metal hydroxides and aliphatic alcohol which in their molecule contain 1 to 6 carbon atoms. The alcoholates are produced in that alkali metal hydroxide is mixed with an alcohol and is reacted with said alcohol at a temperature from 80.degree. to 110.degree. C., preferably from 80.degree. to 100.degree. C., and under a pressure from 0.3 to 1.2 bars, the alcohol water mixture which evaporates during the reaction is separated into its components by at least one membrane, the alcohol vapor and the water vapor are condensed and the condensed alcohol is recycled to the reaction.Type: GrantFiled: July 11, 1988Date of Patent: January 23, 1990Assignee: Metallgesellschaft AktiengesellschaftInventors: Ulrich Sander, Pavel Soukup, Harald Helmrich, Wilfried Weiss
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Patent number: 4877533Abstract: Water is separated from a less hydrophilic fluid by contacting the mixture with one face of a membrane having an active layer which consists essentially only of polymers of an unsaturated organic acid with a ratio of carbon atoms to acid groups (not counting any carbon atoms in the acid groups) of not more than six. Water is removed as a vapor from the other side of the membrane.Type: GrantFiled: December 29, 1987Date of Patent: October 31, 1989Assignee: British Petroleum Company p.l.c.Inventors: Ian G. Meldrum, Timothy d. Naylor
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Patent number: 4875980Abstract: Disclosed is a method for separating and concentrating an organic component having a lower boiling point than water from an aqueous solution containing the organic component which comprises the steps of (1) bringing an aqueous solution containing an organic component having a lower boiling point than water into contact with one surface of a hydrophobic porous membrane, continuously or intermittently evacuating the side of the porous membrane opposite to the aqueous solution to obtain a concentrated vapor of the organic component, and liquefying the vapor; and (2) bringing the resulting concentrated aqueous solution into contact with one surface of a hydrophobic nonporous membrane, evacuating the side of the non-porous membrane opposite to the concentrated aqueous solution to obtain a further concentrated vapor of the organic component, and liquefying the vapor.Type: GrantFiled: August 26, 1987Date of Patent: October 24, 1989Assignees: Mitsubishi Rayon Engineering Co., Ltd., Mitsubishi Rayon Co., Ltd.Inventors: Masujiro Arita, Yukinobu Sugimoto
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Patent number: 4834841Abstract: The improved method and apparatus treats the stack gases from a commercial bakery oven to remove and recover pollutants, specifically ethyl alcohol. The method includes the steps of cooling the stack gases and passing the cooled gases through a packed column to condense the water and ethyl alcohol and if the ethyl alcohol is to be recovered drying the ethyl alcohol by distillation and by absorption of the water therefrom by a molecular sieve. The apparatus includes blowers and controls to maintain the normal flow of gases from the oven so that the removal and recovery of the ethyl alcohol from the stack gases does not interfere or change the baking conditions of the oven. This may be accomplished by a system of dampers or by controlling the discharge rate of the blowers used.Type: GrantFiled: October 1, 1987Date of Patent: May 30, 1989Inventor: Kenneth W. Peck
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Patent number: 4784868Abstract: A method of producing a potable spirit comprises removing water from a fermented wash containing ethanol, water and congeners to produce a substantially water-free mixture of ethanol and congeners, and then fractionally distilling this water-free mixture of ethanol and congeners in the absence of water to produce a fraction containing substantially pure water-free potable ethanol. Preferably the fractional distillation is carried out in separate topping and tailing columns. This method provides an energy efficient separation of the ethanol and congeners.Type: GrantFiled: January 20, 1987Date of Patent: November 15, 1988Assignee: United Distillers P.L.C.Inventor: Albert T. Young