Hydrogenative Patents (Class 208/107)
  • Patent number: 8597498
    Abstract: A process for treating a hydrocarbon-containing feedstock is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a metal-containing catalyst to produce a hydrocarbon-containing product. The hydrocarbon-containing feedstock, the catalyst(s), the hydrogen sulfide, and the hydrogen are provided to a mixing zone and blended in the mixing zone at a temperature of from 375° C. to 500° C. and a total pressure of from 6.9 MPa to 27.5 MPa, where hydrogen sulfide is provided at a mole ratio of hydrogen sulfide to hydrogen of at least 0.5:9.5 and the combined hydrogen sulfide and hydrogen partial pressures provide at least 60% of the total pressure. A vapor comprised of hydrocarbons that are vaporizable at the temperature and pressure within the mixing zone is separated from the mixing zone, and, apart from the mixing zone, the vapor may be condensed to produce a liquid hydrocarbon-containing product.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: December 3, 2013
    Assignee: Shell Oil Company
    Inventors: Stanley Nemec Milam, Michael Anthony Reynolds, Scott Lee Wellington
  • Patent number: 8597497
    Abstract: A process for treating a hydrocarbon-containing feedstock is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and at least one catalyst to produce a hydrocarbon-containing product. The hydrocarbon-containing feedstock, the catalyst(s), and the hydrogen are provided to a mixing zone and blended in the mixing zone at a temperature of from 375° C. to 500° C. A vapor comprised of hydrocarbons that are vaporizable at the temperature and pressure within the mixing zone is separated from the mixing zone, and, apart from the mixing zone, the vapor is condensed to produce a liquid hydrocarbon-containing product containing at least 85% of the atomic carbon initially present in the hydrocarbon-containing feedstock and containing at most 2 wt. % hydrocarbons having a boiling point of at least 538° C.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: December 3, 2013
    Assignee: Shell Oil Company
    Inventors: Stanley Nemec Milam, Michael Anthony Reynolds, Scott Lee Wellington
  • Patent number: 8597496
    Abstract: A process for treating a hydrocarbon-containing feedstock is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and at least one catalyst to produce a hydrocarbon-containing product. The hydrocarbon-containing feedstock, the catalyst(s), and the hydrogen are provided to a mixing zone and blended in the mixing zone at a temperature of from 375° C. to 500° C. A vapor comprised of hydrocarbons that are vaporizable at the temperature and pressure within the mixing zone is separated from the mixing zone, and, apart from the mixing zone, the vapor is condensed to produce a liquid hydrocarbon-containing product. The hydrocarbon-containing feedstock is continuously or intermittently provided to the mixing zone at a rate of at least 350 kg/hr per m3 of the mixture volume in the mixing zone.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: December 3, 2013
    Assignee: Shell Oil Company
    Inventors: Michael Anthony Reynolds, Stanley Nemec Milam, Scott Lee Wellington
  • Patent number: 8586812
    Abstract: Processes for upgrading condensate in a first hydrocarbon stream to provide distillate material may involve ionic liquid catalyzed olefin oligomerization of olefins in the first hydrocarbon stream to provide a first distillate enriched stream, dechlorination of the first distillate enriched stream, hydroprocessing at least one of a second and a third hydrocarbon stream to provide a second distillate enriched stream, and separation of a distillate product from the first and second distillate enriched streams.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: November 19, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Hye-Kyung C. Timken, Bi-Zeng Zhan
  • Patent number: 8574425
    Abstract: The present invention is an improved process for stripping HPNA's from hydroprocessed streams in a fractionation column having a split shell configuration. Only one vapor stripping feed is required to the split shell of the fractionation column. The resulting reduction in steam requirement provides a superior fractionation in the column.
    Type: Grant
    Filed: December 14, 2010
    Date of Patent: November 5, 2013
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Daniel J. Breitenfeldt
  • Publication number: 20130199966
    Abstract: A method of producing an aluminium oxide supported catalyst for use in a Fischer-Tropsch synthesis reaction, which comprises: spray-drying a slurry of ?-alumina and a source of a spinel forming metal to form a solid precursor material; calcining the precursor material to form a modified support material including a metal aluminate spinel; impregnating the modified alumina support material with a source of cobalt; calcining the impregnated support material, and activating the catalyst.
    Type: Application
    Filed: July 29, 2011
    Publication date: August 8, 2013
    Applicant: GTL.F1 AG
    Inventors: Manoj M. Koranne, Erling Rytter, Sigrid Eri, Oyvind Borg
  • Patent number: 8500992
    Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and a catalyst to produce a hydrocarbon-containing product. The catalyst is comprised of a material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Bi, Ag, Mn, Zn, Sn, Ru, La, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: August 6, 2013
    Assignee: Shell Oil Company
    Inventors: Michael Anthony Reynolds, Stanley Nemec Milam, Scott Lee Wellington
  • Patent number: 8496803
    Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product. The catalyst is comprised of a tetrathiometallate material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Pr, Sm, Eu, Yb, Lu, Dy, Pb, and Sb and the second metal is Mo, W, V, Sn, and Sb.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: July 30, 2013
    Assignee: Shell Oil Company
    Inventors: Michael Anthony Reynolds, Stanley Nemec Milam, Scott Lee Wellington
  • Patent number: 8491782
    Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and a catalyst to produce a hydrocarbon-containing product.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: July 23, 2013
    Assignee: Shell Oil Company
    Inventors: Michael Anthony Reynolds, Stanley Nemec Milam, Scott Lee Wellington
  • Patent number: 8491783
    Abstract: A process for treating a hydrocarbon-containing feed in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen, hydrogen sulfide, and a catalyst to produce a hydrocarbon-containing product, where hydrogen sulfide is provided at a mole ratio relative to hydrogen of at least 0.5:9.5. The catalyst is comprised of a bimetallic tetrathiometallate material comprised of a first metal and a second metal, where the first metal is selected from the group consisting of Cu, Fe, Ni, Co, Bi, Ag, Mn, Zn, Sn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Ph, and Sb and the second metal is Mo, W, V, Sn, and Sb.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: July 23, 2013
    Assignee: Shell Oil Company
    Inventors: Stanley Nemec Milam, Michael Anthony Reynolds, Scott-Lee Wellington
  • Patent number: 8491784
    Abstract: A process for treating a hydrocarbon-containing feed is provided in which a hydrocarbon-containing feed comprising at least 20 wt. % of heavy hydrocarbons is mixed with hydrogen and a catalyst to produce a hydrocarbon-containing product. The catalyst is prepared by mixing a first salt and a second salt in an aqueous mixture under anaerobic conditions at a temperature of from 15° C. to 150° C., where the first salt comprises a cationic component in any non-zero oxidation state selected from the group consisting of Cu, Fe, Ag, Co, Mn, Ru, La, Ce, Pr, Sm, Eu, Yb, Lu, Dy, Ni, Zn, Bi, Sn, Pb, and Sb, and where the second salt comprises an anionic component selected from the group consisting of MoS42?, WS42?, SnS44?, and SbS43.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: July 23, 2013
    Assignee: Shell Oil Company
    Inventors: Michael Anthony Reynolds, Stanley Nemec Milam, Scott Lee Wellington
  • Patent number: 8480965
    Abstract: Injection nozzles for use in a gas distribution device are disclosed. In one aspect, the injection nozzle may include: a tube having a fluid inlet and a fluid outlet; wherein the inlet comprises a plurality of flow restriction orifices. In another aspect, embodiments disclosed herein relate to an injection nozzle for use in a gas distribution device, the injection nozzle including: a tube having a fluid inlet and a fluid outlet; wherein the fluid inlet comprises an annular orifice surrounding a flow restriction device. Injection nozzles according to embodiments disclosed herein may be disposed in a gas distribution manifold used in a vessel, for example, for conducting polymerization reactions, spent catalyst regeneration, and coal gasification, among others.
    Type: Grant
    Filed: December 8, 2011
    Date of Patent: July 9, 2013
    Assignee: Lummus Technology Inc.
    Inventors: Leonce Francis Castagnos, Jr., Ting Yee Chan, Norman Paul Kolb, Ronald Eugene Pieper
  • Patent number: 8471083
    Abstract: A reforming process using a medium pore zeolite under conditions to facilitate the conversion of C8 paraffinic compounds to para-xylene is provided. Para-xylene is produced at greater than thermodynamic equilibrium concentrations using the process.
    Type: Grant
    Filed: January 11, 2013
    Date of Patent: June 25, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Cong-Yan Chen, Ann Jia-Bao Liang, Stephen Joseph Miller, James Nathan Ziemer
  • Patent number: 8435452
    Abstract: A circulating fluid bed reactor such as that used in fluid coking processes has a circular dense bed reaction section above the reactor base where the fluidizing gas is injected and a plurality of frusto-conical baffles in the dense bed reaction section, each of which depends downwardly and radially inwards from the reactor wall to a lower, inner edge defining a central aperture. The baffles are preferably provided with downcomers which permit downward flow of solids and upward flow of gas through the baffles.
    Type: Grant
    Filed: February 17, 2011
    Date of Patent: May 7, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: John T. Wyatt, Jr., E. Nicholas Jones, Alvin U. Chen, Clay R. Sutton, Timothy M. Healy, Ronald Suryo, Len Lampert, Jonathan Miller
  • Patent number: 8419812
    Abstract: A reactor for the recovery of carbon and hydrocarbons from organic input material through pyrolysis includes a vessel with a chamber that is limited outwardly by an outer jacket and by an upper and a lower end-wall section, and in which chamber input material in fragmented form is to be placed; an inlet which for the introduction of heated inert gas into the chamber for passage through the input material comprises several inlet units arranged in areas in the chamber; and an outlet which for the passage out from the chamber of gas that has passed through the input material that has been placed in the chamber comprises number of outlet units arranged in areas in the chamber.
    Type: Grant
    Filed: November 26, 2007
    Date of Patent: April 16, 2013
    Assignee: SES IP AB
    Inventor: Bengt-Sture Ershag
  • Patent number: 8404912
    Abstract: A process for making a high VI lubricating base oil from a blend of (1) a heavy wax derived from pyrolyzing a plastic feed and (2) a lube oil feedstock is disclosed. The process comprises the steps of hydrocracking the blend and dewaxing at least a portion of the hydrocracked stream under hydroisomerization conditions to produce a lubricating base oil.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: March 26, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen Joseph Miller
  • Patent number: 8288599
    Abstract: Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
    Type: Grant
    Filed: June 29, 2009
    Date of Patent: October 16, 2012
    Assignee: KiOR, Inc.
    Inventors: Steve Yanik, Paul O'Connor, Robert Bartek
  • Publication number: 20120149789
    Abstract: An apparatus for the electrolytic splitting of water into hydrogen and/or oxygen, the apparatus comprising: (i) at least one lithographically-patternable substrate having a surface; (ii) a plurality of microscaled catalytic electrodes embedded in said surface; (iii) at least one counter electrode in proximity to but not on said surface; (iv) means for collecting evolved hydrogen and/or oxygen gas; (v) electrical powering means for applying a voltage across said plurality of microscaled catalytic electrodes and said at least one counter electrode; and (vi) a container for holding an aqueous electrolyte and housing said plurality of microscaled catalytic electrodes and said at least one counter electrode. Electrolytic processes using the above electrolytic apparatus or functional mimics thereof are also described.
    Type: Application
    Filed: December 9, 2010
    Publication date: June 14, 2012
    Applicant: UT-BATTELLE, LLC
    Inventor: Elias Greenbaum
  • Patent number: 8147677
    Abstract: The invention provides a method and apparatus for introducing a high-density hydrocarbon liquid into a hydrocracking reactor. The method comprises atomizing the high-density hydrocarbon liquid and injecting the atomized liquid into the hydrocracking reactor. The method may also comprise mixing hydrogen with the high-density hydrocarbon liquid prior to atomizing the high-density hydrocarbon liquid. The apparatus comprises an injection valve for introducing a high-density hydrocarbon liquid into a hydrocracking reactor comprises an atomizer coupled to receive the high-density hydrocarbon liquid. The atomizer comprises a nozzle configured to atomize the high-density hydrocarbon liquid and inject the high-density hydrocarbon liquid into the hydrocracking reactor. The injection valve may also comprise a mixer coupled to receive hydrogen and the high-density hydrocarbon liquid. The mixer may be configured to mix the hydrogen and high-density hydrocarbon liquid and deliver the mixture to the atomizer.
    Type: Grant
    Filed: February 18, 2009
    Date of Patent: April 3, 2012
    Assignee: Genoil Inc.
    Inventor: Paul Costinel
  • Patent number: 8142644
    Abstract: A process for hydrocracking and hydro-isomerization of a paraffinic feedstock obtained by Fischer-Tropsch hydrocarbon synthesis comprising at least 50 wt % of components boiling above 370° C. to obtain a hydro-isomerized feedstock, the process comprising contacting the feedstock, in the presence of hydrogen, at elevated temperature and pressure with a catalyst comprising a hydrogenating compound supported on a carrier comprising amorphous silica-alumina, the carrier having a pore volume of at least 0.8 ml/g, wherein at most 40% of the pore volume comes from pores having a pore diameter above 35 nm and wherein at most 20% of the pore volume comes from pores having a pore diameter below 50 ? and above 37 ?, the carrier having a median pore diameter of at least 85 ?, wherein the product of (surface area per pore volume) and (median pore diameter as measured by mercury intrusion porosimetry) of the carrier is at least 34,000 ?·m2/ml.
    Type: Grant
    Filed: September 10, 2008
    Date of Patent: March 27, 2012
    Assignee: Shell Oil Company
    Inventors: Focco Kornelis Bijlsma, Jan Lodewijk Maria Dierickx, Arend Hoek
  • Patent number: 8133446
    Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: March 13, 2012
    Assignee: UOP LLC
    Inventors: James F. McGehee, Lorenz J. Bauer
  • Patent number: 8071833
    Abstract: A process (or steam cracking a hydrocarbon feedstock containing olefins to provide increased light olefins in the steam cracked effluent, the process comprising passing a first hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate to produce an intermediate effluent with an olefin content of lower molecular weight than that of the feedstock, fractionating the intermediate effluent to provide a lower carbon fraction and a higher carbon fraction, and passing the higher carbon fraction, as a second hydrocarbon feedstock, through a stream cracker to produce a steam cracked effluent.
    Type: Grant
    Filed: May 22, 2003
    Date of Patent: December 6, 2011
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Jacques Grootjans, Valérie Vanrysselberghe, Walter Vermeiren
  • Patent number: 8025790
    Abstract: A process for upgrading heavy oil by mixing the heavy oil with water fluid using an ultrasonic wave generator prior to increasing the temperature and pressure of the mixture to values near to or exceeding the critical point of water, to produce low pour point, high value oil having low sulfur, low nitrogen, and low metallic impurities for use as hydrocarbon feedstock.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: September 27, 2011
    Assignee: Saudi Arabian Oil Company
    Inventors: Ki-Hyouk Choi, Ali Al-Shareef
  • Patent number: 8002970
    Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10?10 m to 24.15×10?10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
    Type: Grant
    Filed: December 13, 2005
    Date of Patent: August 23, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Patrick Euzen, Patrick Bourges, Christophe Gueret, Carole Bobin, Alexandra Chaumonnot, Hugues Dulot
  • Patent number: 8002969
    Abstract: A method for upgrading a petroleum oil by a hydroprocessing reaction in which the oil is hydrogenated, includes the steps of: a. forming a liquid reaction mixture of the oil with water and an amphiphilic liquid in predetermined proportions to thereby render the oil and water miscible; b. introducing the liquid reaction mixture into an electrolytic reactor having one or more cathodic elements formed from a porous high surface area, conductive material; c. operating the reactor to form reactive hydrogen atoms whereby the oil is hydrogenated by the hydrogen atoms; d. removing the liquid mixture from the reactor; and e. separating the hydrogenated upgraded oil from the amphiphilic liquid and any remaining water, e.g., by distillation, recovering and recycling the amphiphilic liquid for use.
    Type: Grant
    Filed: December 5, 2007
    Date of Patent: August 23, 2011
    Assignee: Saudi Arabian Oil Company
    Inventor: Esam Zaki Hamad
  • Patent number: 7976696
    Abstract: One aspect of the present invention relates to mesostructured zeolites. The invention also relates to a method of preparing mesostructured zeolites, as well as using them as cracking catalysts for organic compounds and degradation catalysts for polymers.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: July 12, 2011
    Assignee: Massachusetts Institute of Technology
    Inventors: Jackie Y. Ying, Javier García-Martínez
  • Publication number: 20110163005
    Abstract: Methods, systems and other embodiments associated with upgrading heavy oil by hydrocracking are presented. A method of upgrading heavy oil includes mixing raw heavy oil with hydrogen to produce a mixed heavy oil. The mixed heavy oil is heated to produce heated heavy oil. High pressure pulses are created in the heated heavy oil to crack the heated heavy oil to produce cracked oil with a lower viscosity than the raw heavy oil.
    Type: Application
    Filed: January 7, 2010
    Publication date: July 7, 2011
    Inventors: Jose J. P. Lourenco, John Gordon Murphy
  • Publication number: 20110163004
    Abstract: Methods, systems and other embodiments associated with upgrading heavy oil are presented. A method of upgrading heavy oil comprising heating heavy oil to produce heated heavy oil. The method further comprises creating high pressure pulses in the heated heavy oil to crack the heated heavy oil to produce an oil with a lower viscosity than the heavy oil.
    Type: Application
    Filed: January 7, 2010
    Publication date: July 7, 2011
    Inventors: Jose J. P. Lourenco, John Gordon Murphy
  • Publication number: 20110155641
    Abstract: The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
    Type: Application
    Filed: May 13, 2009
    Publication date: June 30, 2011
    Applicant: IFP ENERGIES NOUVELLES
    Inventors: Audrey Bonduelle, Alexandra Chaumonnot
  • Publication number: 20110139680
    Abstract: The invention relates to the integration of a process for hydrotreatment of distillates (light and/or middle), that operates under a hydrogen partial pressure of 0.5 to 6.0 MPa, with a process for hydrotreatment/hydroconversion of middle and/or heavy distillates that operates at a hydrogen partial pressure that is at least 4.0 MPa higher than the hydrogen partial pressure of the process for hydrotreatment of distillates (light and/or middle). The integration resides in the use of the hydrogen-rich gas, obtained from the hydrotreatment/hydroconversion effluents, in the process for hydrotreatment of distillates (light and/or middle) and in the adjustment of the pressure level of this hydrogen-rich gas removed from the hydrotreatment/hydroconversion. This invention makes it possible to considerably reduce the net consumption of make-up hydrogen in the process for hydrotreatment of distillates (light and/or middle).
    Type: Application
    Filed: December 10, 2009
    Publication date: June 16, 2011
    Applicant: IFP
    Inventors: Antoine Fournier, Jean Luc Nocca
  • Patent number: 7951290
    Abstract: A process is provided to produce high cetane quality and low or preferably ultra low sulfur diesel and a fluid catalytic cracker (FCC) quality feedstock from a processing unit including at least a hydrotreating zone and a hydrocracking zone. In one aspect, the processing unit includes reactor severity requirements in both the hydrotreating zone and the hydrocracking zone effective to produce the FCC feed quality and the diesel sulfur quality to permit a high quality hydrocracked product to be formed at lower pressures and conversion rates without overtreating the FCC quality feedstock stream. In another aspect, a portion of the hydrotreated effluent is selected for conversion in the hydrocracking and the remaining portion of the hydrotreated effluent is directed to subsequent processing, such as fluid catalytic cracking.
    Type: Grant
    Filed: October 16, 2009
    Date of Patent: May 31, 2011
    Assignee: UOP LLC
    Inventors: Vasant P. Thakkar, Douglas W. Kocher-Cowan
  • Patent number: 7919054
    Abstract: Disclosed are a process and an installation for treatment of a heavy petroleum feedstock, of which at least 80% by weight has a boiling point of greater than 340° C., wherein the process includes (a) hydroconversion in a boiling-bed reactor operating with a rising flow of liquid producing a hydroconversion effluent; (b) separation of hydroconversion effluent into a gas containing hydrogen and H2S, a fraction comprising gas oil, and a naphtha fraction; c) hydrotreatment, by contact with at least one catalyst, of at least said fraction comprising gas oil, producing a hydrotreatment effluent; and d) separation of hydrotreatment effluent into a gas containing hydrogen and at least one gas oil fraction having a sulfur content of less than 50 ppm, wherein the hydrogen supply for the hydroconversion and hydrotreatment is delivered by a single compression system.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: April 5, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: John E. Duddy, Lawrence I. Wisdom, Andrea Gragnani
  • Patent number: 7872165
    Abstract: A hydrotreating method (HDT) utilizes two plants working under different operating conditions with an intermediate stripping for co-treating a mixture made up of oils of vegetable or animal origin and petroleum cuts (gas oil cuts (GO) and middle distillates) in order to produce gas oil fuel bases meeting specifications. The first plant (HDT1) is more particularly dedicated to the reactions concerning oils of vegetable or animal origin in comixture while pretreating the hydrocarbon feed, whereas the second plant (HDS2) works under more severe conditions to obtain diesel fuel according to standards, in particular in terms of effluent sulfur content, density and cold properties.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: January 18, 2011
    Assignee: IFP Energies Nouvelles
    Inventors: Fabrice Bertoncini, Karin Marchand
  • Patent number: 7862893
    Abstract: A granular solid wax particle, comprising a) a highly paraffinic wax having a T10 boiling point less than 427° C. and comprising at least 40 weight percent n-paraffins, and b) an inorganic powder coating on the wax particle. Also, a process for making a fuel or a base oil, comprising transporting the granular solid wax particles in a transport vessel to a distant location where the granular solid wax particles are processed into the fuel or the base oil.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: January 4, 2011
    Assignee: Chevron U.S.A., Inc.
    Inventors: Dennis J. O'Rear, Gunther H. Dieckmann
  • Patent number: 7863341
    Abstract: The present invention discloses a process for the preparation of syngas from two sources with different hydrogen: carbon ratios, the first source having a low hydrogen:carbon ratio including any one or a combination of coal, brown coal, peat, bitumen and tar sands, and the second source having a high hydrogen:carbon ratio including any one or a combination of natural gas, associated gas and coal bed methane. The sources are converted to syngas and then combined to provide syngas with an optimum hydrogen:carbon monoxide ratio for use in a Fischer-Tropsch process.
    Type: Grant
    Filed: July 18, 2006
    Date of Patent: January 4, 2011
    Assignee: Shell Oil Company
    Inventor: Arold Marcel Albert Routier
  • Publication number: 20100326887
    Abstract: A process is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a particulate solid material to form a heavy hydrocarbon slurry and hydrocracked in a slurry hydrocracking unit to produce vacuum gas oil (VGO) and pitch. A first vacuum column separates VGO from pitch, and a second vacuum column further separates VGO from pitch. As much as 15 wt-% of VGO can be recovered by the second vacuum column and recycled to the slurry hydrocracking unit. A pitch composition is obtained which can be made into particles and transported without sticking together.
    Type: Application
    Filed: June 25, 2009
    Publication date: December 30, 2010
    Inventors: James F McGehee, David N. Myers, Mark Van Wees, Paul R. Zimmerman, Ruth Buskus Kleinworth
  • Patent number: 7842180
    Abstract: A hydrocracking process wherein a liquid phase stream comprising a hydrocarbonaceous feedstock and a liquid phase effluent from a hydrocracking zone and a sufficiently low hydrogen concentration to maintain a liquid phase continuous system into a hydrotreating zone. A portion of the effluent from the hydrotreating zone comprising unconverted hydrocarbons is introduced into the hydrocracking zone with a sufficiently low hydrogen concentration to maintain a liquid phase continuous system.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: November 30, 2010
    Assignee: UOP LLC
    Inventors: Laura E. Leonard, Peter Kokayeff
  • Patent number: 7837864
    Abstract: An integrated process for extracting and refining bitumen comprises hydroconverting bitumen in a reactor to provide valuable products and light oil by-product; separating the light oil by-product from the valuable products; transporting the light oil to oil sands reserves; producing steam in steam generators at the oil sands reserves using a portion of the light oil transported to the oil sands reserves; extracting bitumen from the oil sands reserves using steam produced in the steam generators; blending bitumen extracted from the oil sands reserves and a portion of the light oil transported to the oil sands reserves to form a transport blend; and transporting the transport blend to the reactor.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: November 23, 2010
    Assignee: Chevron U. S. A. Inc.
    Inventor: Bruce E. Reynolds
  • Patent number: 7837860
    Abstract: A process for the production of low sulfur diesel and high octane naphtha. Separate high pressure vapor liquid separators serve to maintain and isolate the high octane naphtha produced in the hydrocracking zone thereby maximizing the value of the hydrocarbon streams produced.
    Type: Grant
    Filed: December 12, 2005
    Date of Patent: November 23, 2010
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Srinivasa G. Varadarajan, Douglas W. Kocher-Cowan
  • Patent number: 7803334
    Abstract: A hydrocracking process and apparatus wherein the feedstock is hydrotreated and the liquid and gaseous effluent from the hydrotreater is directly introduced into the upper end of a hydrocracking vessel which provides a liquid seal to prevent the passage of the gaseous stream containing hydrogen sulfide and ammonia from the hydrotreater to enter the hydrocracking zone containing hydrocracking catalyst. Fresh hydrogen is then introduced into the hydrocracking zone.
    Type: Grant
    Filed: July 11, 2006
    Date of Patent: September 28, 2010
    Assignee: UOP LLC
    Inventors: Richard K. Hoehn, Vasant P. Thakkar, Vedula K. Murty, Douglas W. Kocher-Cowan, Jennifer L. Anderson
  • Patent number: 7799212
    Abstract: A method which controls sedimentation occurring at a heat exchanger for cooling hydrodesulfurization/hydrocracking residue containing asphaltenes at a high content and thereby prevents fouling of the heat exchanger is disclosed. A method for preventing fouling of a heat exchanger for cooling hydrodesulfurization/hydrocracking residue, which injects flux oil into hydrodesulfurization/hydrocracking residue containing asphaltenes at 1% by mass or more, wherein the flux oil is at least one species of residue selected from the group consisting of crude vacuum distillation residue and fluidized catalytic cracking residue, and injected into the hydrodesulfurization/hydrocracking residue to control its actual sediment content at 0.2% by mass or less, determined in accordance with IP-375 is also disclosed.
    Type: Grant
    Filed: February 27, 2006
    Date of Patent: September 21, 2010
    Assignees: Tonen General Sekiyu K.K., Showa Shell Sekiyu K.K., Research Association of Refinery Integration for Group Operation
    Inventors: Norihiro Nakashima, Masayoshi Kuwbara, Manabu Higo, Hiroyuki Kobayashi
  • Publication number: 20100206773
    Abstract: This is a unique way of upgrading an existing refinery to process heavy sour crude. The system does not significantly modify an existing sweet refinery. Rather, a hydrocracker is used at the existing light sweet refinery location to create light sweet crudes from heavy sour crudes prior to processing in an existing sweet refinery.
    Type: Application
    Filed: February 18, 2009
    Publication date: August 19, 2010
    Inventors: Calvin T. Case, Dennis W. Keppers, Vernon W. Mark
  • Patent number: 7754067
    Abstract: Heavy hydrocarbons are upgraded more efficiently to lighter, more valuable, hydrocarbons with lower amounts of solid carbonaceous by-products in supercritical water using two heating stages, the first stage at a temperature up to about 775K and the second stage at a temperature from about 870K to about 1075K. The temperature is preferably raised from the first temperature to the second temperature by internal combustion using oxygen.
    Type: Grant
    Filed: February 20, 2008
    Date of Patent: July 13, 2010
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Rodney John Allam
  • Patent number: 7754066
    Abstract: Method for making base oil, comprising transporting a height of greater than 7.5 meters of granular solid wax particles comprising a highly paraffinic wax with defined boiling points and a powder coating to a distant location, and hydroprocessing the transported wax. Also, a method comprising: a) selecting a Fischer-Tropsch wax having a broad boiling range, b) powder coating the wax, and c) transporting and d) hydroprocessing the wax. Also, a method comprising forming inorganic powder coated granular solid wax particles that withstand heavy loads without clumping or sticking together from highly paraffinic wax, wherein the amount of powder is between 0.1 and 5 wt %, transporting, and hydroprocessing the solid wax particles.
    Type: Grant
    Filed: February 13, 2008
    Date of Patent: July 13, 2010
    Assignee: Chevron U.S.A. Inc
    Inventors: Gunther H. Dieckmann, Dennis J. O'Rear
  • Patent number: 7741377
    Abstract: A process to prepare a paraffinic hydrocarbon from a solid carbonaceous feedstock, preferably coal by performing the following steps, (a) feeding an oxygen comprising gas and the carbonaceous feedstock to a burner positioned horizontal and firing into a reactor vessel, (b) performing a partial oxidation of the carbonaceous feedstock in said burner to obtain a stream of hot synthesis gas which flows upwardly relative to the burner and a liquid slag which flows downwardly relative to the burner, (c) cooling the hot synthesis gas by first cooling the gas to a temperature of between 500 and 900° C. by injecting a gaseous or liquid cooling medium into the synthesis gas and subsequently second cooling the gas in to below 500° C.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: June 22, 2010
    Assignee: Shell Oil Company
    Inventors: Robert Erwin Van Den Berg, Franciscus Gerardus Van Dongen, Thomas Paul Von Kossak-Glowczewski, Hendrik Jan Van Der Ploeg, Pieter Lammert Zuideveld
  • Patent number: 7741241
    Abstract: The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: June 22, 2010
    Assignees: Total Raffinage Marketing, IFP
    Inventors: Thierry Cholley, Jean-Pierre Dath, Claude Brun, Georges Fremy, Francis Humblot
  • Patent number: 7727376
    Abstract: A process to prepare base oils from a Fischer-Tropsch synthesis product by (a) separating the Fischer-Tropsch synthesis product into a fraction (i) boiling in the middle distillate range and below, a heavy ends fraction (iii) and an intermediate base oil precursor fraction (ii) boiling between fraction (i) and fraction (iii), (b) subjecting the base oil precursor fraction (ii) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades, (c) subjecting the heavy ends fraction (iii) to a conversion step to yield a fraction (iv) boiling below the heavy ends fraction (iii) and (d) subjecting the high boiling fraction (v) of fraction (iv) to a catalytic hydroisomerisation and catalytic dewaxing process to yield one or more base oil grades.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: June 1, 2010
    Assignee: Shell Oil Company
    Inventors: Nicholas James Adams, Michiel Cramwinckel, Jan Lodewijk Maria Dierickx
  • Patent number: 7704377
    Abstract: Disclosed are a process and an installation for treatment of a heavy petroleum feedstock, of which at least 80% by weight has a boiling point of greater than 340° C., wherein the process includes (a) hydroconversion in a boiling-bed reactor operating with a rising flow of liquid producing a hydroconversion effluent; (b) separation of hydroconversion effluent into a gas containing hydrogen and H2S, a fraction comprising gas oil, and a naphtha fraction; c) hydrotreatment, by contact with at least one catalyst, of at least said fraction comprising gas oil, producing a hydrotreatment effluent; and d) separation of hydrotreatment effluent into a gas containing hydrogen and at least one gas oil fraction having a sulfur content of less than 50 ppm, wherein the hydrogen supply for the hydroconversion and hydrotreatment is delivered by a single compression system.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: April 27, 2010
    Assignee: Institut Francais du Petrole
    Inventors: John E. Duddy, Lawrence I. Wisdom, Andrea Gragnani
  • Publication number: 20100078355
    Abstract: We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at ?25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.
    Type: Application
    Filed: June 10, 2009
    Publication date: April 1, 2010
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Steve K. Lee, Ryan J. Schexnaydre
  • Patent number: 7682500
    Abstract: A process for the conversion of a feedstock containing light cycle oil and vacuum gas oil to produce naphtha boiling range hydrocarbons and a higher boiling range hydrocarbonaceous stream having a reduced concentration of sulfur.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: March 23, 2010
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes