With Modifying Agents Patents (Class 209/166)
  • Patent number: 11952714
    Abstract: A process (1, 101, 201) for separating a fibrous target component (21) from textile waste (2, 5) is shown, said textile waste (2, 5) containing the target component (21) and at least one ancillary component (22), whereby the target component (21) consists of water-swellable textile fibers (51) with a density higher than the density of water, the process (1, 101, 201) comprising the steps: a) dispersing the comminuted textile waste (5) in an aqueous solution (7) to obtain a suspension (8) containing the textile waste (5), and b) separating the dispersed textile waste (5) into a high-density target fraction (81) comprising the target component (21), and a low-density residual fraction (82) comprising the at least one ancillary component (22), according to the respective density of said components (21, 22).
    Type: Grant
    Filed: January 14, 2019
    Date of Patent: April 9, 2024
    Assignee: LENZING AKTIENGESELLSCHAFT
    Inventors: Christoph Klaus-Nietrost, Richard Herchl, Christian Weilach
  • Patent number: 11697862
    Abstract: A mineral processing method capable of efficiently separating a copper mineral from a molybdenum mineral is provided. The mineral processing method includes: a conditioning step of adding sulfite as a surface treatment agent to a mineral slurry containing a copper mineral and a molybdenum mineral; and a flotation step of performing flotation using the mineral slurry after the conditioning step. The hydrophilicity of the copper mineral can be selectively enhanced by sulfite, so as to be able to produce a difference in hydrophilicity between the copper mineral and the molybdenum mineral. Therefore, the molybdenum mineral can be selectively caused to float, and the copper mineral and the molybdenum mineral can be efficiently separated from each other.
    Type: Grant
    Filed: June 1, 2018
    Date of Patent: July 11, 2023
    Assignees: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, SUMITOMO METAL MINING CO., LTD.
    Inventors: Tsuyoshi Hirajima, Hajime Miki, Gde Pandhe Wisnu Suyantara, Yuji Imaizumi, Yuji Aoki, Eri Takida
  • Patent number: 11685689
    Abstract: The present disclosure concerns an aluminosilicate having a Blaine fineness of about 500 m2/kg to about 3000 m2/kg and/or a specific surface area of about 4 m2/g to about 20 m2/g, as well as the uses thereof. The present disclosure also comprises a dry cementing composition and a mortar or concrete composition, the compositions comprising said aluminosilicate. The present disclosure also comprises a process for the manufacture of aluminosilicate. The process comprises: roasting a spodumene concentrate in an acid medium; leaching the acidic roast spodumene concentrate so as to obtain a mixture comprising a solid comprising the aluminosilicate and a leachate; and separating the aluminosilicate from the leachate in an acid medium, wherein said aluminosilicate contains a calcium concentration of less than about 5%.
    Type: Grant
    Filed: November 27, 2019
    Date of Patent: June 27, 2023
    Assignee: NEMASKA LITHIUM INC.
    Inventors: Jean-François Magnan, David-Nicolas Allen
  • Patent number: 11638923
    Abstract: The flotation reagents from acidic olive oil are made by transesterification of acidic olive oil. Acidic olive oil is olive oil having an acid value high enough to render it unsuitable for consumption, typically greater than 3.3% and/or between 3.3-7%. Transesterification of the olive oil with methanol converts fatty acids in the olive oil to an ester fraction and a glycerol fraction. The ester fraction may be sulfonated and used as the collector in a reverse flotation process, selectively removing the carbonate gangue from phosphate-carbonate rock in the froth, leaving phosphates in the sink. The glycerol fraction may be used without modification as the collector in the reverse flotation process. Both fractions are highly selective for carbonates, substantially reducing loss of phosphates in the froth.
    Type: Grant
    Filed: September 10, 2020
    Date of Patent: May 2, 2023
    Assignee: KING SAUD UNIVERSITY
    Inventors: Saeed Mohammed Al-Zahrani, Arfat Anis, Ranjan Kumar Dwari
  • Patent number: 11612898
    Abstract: The present embodiments generally relate to a technology for improving Cu/Mo grade by the addition of cationic polymers as selective depressants for acid insoluble matters, e.g., silicates and/or clays, in the flotation circuit. Various types of cationic polymers are demonstrated to be effective depressants including polyamine, polyDADMAC, and cationic polyacrylamide. Also disclosed are processes for enriching a desired mineral from an ore comprising the desired mineral and gangue, wherein the process comprises carrying out a flotation process in the presence of one or more cationic polymer depressants.
    Type: Grant
    Filed: August 30, 2017
    Date of Patent: March 28, 2023
    Assignee: KEMIRA OYJ
    Inventors: Marcelo Moreira Costa, Xihui Yin, Sergio Cabo
  • Patent number: 11613716
    Abstract: Provided is a binder for a coal-containing formed product, which contains a macromolecular polymer having an intrinsic viscosity of 2.0 dl/g or higher.
    Type: Grant
    Filed: March 25, 2019
    Date of Patent: March 28, 2023
    Assignee: KURITA WATER INDUSTRIES LTD.
    Inventor: Takashi Kikkawa
  • Patent number: 11590514
    Abstract: A process for treating and dewatering tailings comprising fine clay minerals, fine rock-forming minerals and water is provided, comprising treating the tailings with a sufficient amount of a collector to modify the surface properties of both the fine clays and rock-forming minerals; subjecting the treated tailings to froth flotation to form a fine clays and rock-forming minerals froth layer; and recovering the froth layer and subjecting it to dewatering.
    Type: Grant
    Filed: October 25, 2019
    Date of Patent: February 28, 2023
    Assignee: SYNCRUDE CANADA LTD
    Inventors: Simon Yuan, James Lorentz, Ron Siman
  • Patent number: 11505670
    Abstract: This invention relates to rigid polyurethane foams which are co-blown with a mixture of a hydrocarbon blowing agent and a halogenated olefin blowing agent. This invention also relates to a process for preparing these rigid polyurethane foams, and to an isocyanate-reactive component containing a polyol blend and the mixture of blowing agents. Phase stable isocyanate-reactive blends are also described.
    Type: Grant
    Filed: November 17, 2016
    Date of Patent: November 22, 2022
    Assignee: Covestro LLC
    Inventor: Steven L. Schilling
  • Patent number: 11453014
    Abstract: The present application relates to a concentration process of iron minerals from ultrafine tailings (slimes) from iron ore processing through reverse flotation with pH between 8.5 and 10.5 with the addition of amide-amine type collector, or further a mixture thereof with traditional cationic collectors (amines), in the absence of any depressant, alternatively including a step of high field magnetic concentration, which allows to obtain a concentrate with iron content higher than 66% and contents of SiO2+Al2O3 below 4%.
    Type: Grant
    Filed: October 3, 2018
    Date of Patent: September 27, 2022
    Assignee: VALE S.A.
    Inventors: Neymayer Pereira Lima, Klaydison Carlaile Silva, Maurício Curi Segato
  • Patent number: 11420211
    Abstract: A method includes separating, in a first stage of separating, crushed ore material by size into a first fines stream and a first coarse stream; grinding the first coarse stream in a second stage of grinding; feeding the product of the second stage of grinding back to the step of separating; feeding the first fines stream from the step of separating to a recovery circuit; producing a rejected stream from the recovery circuit of crushed ore material that does not meet the target mineral size; separating, in a second stage of separating, the rejected stream from the recovery circuit into a second fines stream and a second coarse stream; grinding the second coarse stream in a third stage of grinding; and feeding the product of the third stage of grinding back to the recovery circuit.
    Type: Grant
    Filed: December 29, 2017
    Date of Patent: August 23, 2022
    Assignee: FLUOR TECHNOLOGIES CORPORATION
    Inventor: Mark Sherman
  • Patent number: 11413629
    Abstract: In one example, a method includes providing a pulp composed of a combination of particulate materials including particles of a target material. The pulp is mixed with a collector composed of anisotropic particles having at least two separate spatial domains that have different physiochemical properties, and the mixture of pulp and collector is fed into an aqueous solution containing air bubbles.
    Type: Grant
    Filed: September 23, 2019
    Date of Patent: August 16, 2022
    Assignee: International Business Machines Corporation
    Inventors: Julia Baldauf, Alexe Bojovschi, Benjamin S. Mashford, Christine Schieber, George Yiapanis
  • Patent number: 11407953
    Abstract: A process for upgrading of a coal product is provided. The process comprising the steps of: (i) providing a purified coal composition, wherein the composition is in the form of solid particles, and wherein at least about 90% by volume (% vol) of the solid particles are no greater than about 500 ?m in diameter; and (ii) combining the purified coal composition with a solid coal feedstock, in order to create a combined solid-solid blend upgraded coal product. Further a process for preparation of a purified coal product is provided.
    Type: Grant
    Filed: September 27, 2019
    Date of Patent: August 9, 2022
    Assignee: Arq IP Limited
    Inventors: Paul Groves, John Francis Unsworth
  • Patent number: 11365127
    Abstract: A large-particle spherical salt with a particle size of 400-950 ?m and a sphericity of 0.5-1.0 is disclosed, which overcomes the existing difficulty in this field for larger particle size as well as higher sphericity. A preparation method of the large-particle spherical salt is also disclosed, wherein in one preparation process, 2% of gum arabic (based on the mass percentage of solute sodium chloride in a sodium chloride saturated solution) is added, and under conditions of an evaporating temperature of 60° C. a stirring rate of 350 rpm, and an evaporating time of 8 hours, a large-particle spherical salt with a particle size of 921.593 ?m and an average sphericity of 0.904 is successfully prepared. The large-particle spherical salt prepared by the method has a uniform particle size distribution and good appearance, can be combined with other substances, adding some extra value to the salt. Meanwhile, the large-particle spherical salt prepared by the method has a high safety grade (e.g.
    Type: Grant
    Filed: August 15, 2021
    Date of Patent: June 21, 2022
    Assignee: TIANJIN UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Na Tang, Min Lu, Wei Du, Penggao Cheng, Jun Xiang, Lei Zhang, Songbo Wang, Jianping Zhang
  • Patent number: 11326088
    Abstract: Treatment fluids for use in fluid loss control, diversion, and plugging operations and methods of use are disclosed. The treatment fluids contain a degradable particular langbeinite material that temporarily creates a physical barrier to fluid flow before degrading over time with little to no effect on the environment. This degradable additive can be combined with other traditional downhole additives such as surfactants, viscosifying agents, biocides and the like, allowing for a wide variety of applications in hydrocarbon reservoirs.
    Type: Grant
    Filed: May 28, 2020
    Date of Patent: May 10, 2022
    Assignee: LyondellBasell Advanced Polymers Inc.
    Inventor: Bradley L. Todd
  • Patent number: 11247214
    Abstract: A system for separating mineral particles of interest from an ore features mineral processing operations/stages/circuits configured to receive an ore, or mineral particles or concentrates formed by processing the ore, and provide processed mineral particles or concentrates, or a waste stream, for further enhanced mineral separation downstream processing; an enhanced mineral separation processor having a collection apparatus located therein, the collection apparatus having a collection surface configured with a functionalized polymer including molecules having a functional group configured to attract the mineral particles of interest to the collection surface, the enhanced mineral separation processor receive the processed mineral particles or concentrates, or the waste stream, and provide further enhanced downstream processed mineral particles or concentrates, or a further enhanced downstream processed waste stream; and a high intensity conditioning operation, stage or circuit configured to apply a high inten
    Type: Grant
    Filed: February 28, 2018
    Date of Patent: February 15, 2022
    Assignee: CIDRA CORPORATE SERVICES LLC
    Inventors: Paul J. Rothman, Adam Michael Jordens, Peter A. Amelunxen
  • Patent number: 11180825
    Abstract: A process for the depression of iron sulphides and other disposable elements in the mineral concentration by flotation and electrochemical reactor. The proposed invention represents a method based on the action of electrodes on the mineral, which can replace, compliment or minimise the consumption of chemical reagents, as well as improving the effect thereof.
    Type: Grant
    Filed: August 2, 2017
    Date of Patent: November 23, 2021
    Assignee: LAIN TECHNOLOGIES LTD
    Inventor: Eva Maria Laín Rodríguez
  • Patent number: 11168218
    Abstract: A process is described for manufacturing white pigment containing products. The white pigment containing products are obtained from at least one white pigment and impurities containing material via froth flotation.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: November 9, 2021
    Assignee: OMYA INTERNATIONAL AG
    Inventors: Jörg Sötemann, Jörg Andreas Maier
  • Patent number: 11103882
    Abstract: A separation system is presented that partitions a slurry containing a plurality of particles that are influenced by a fluidization flow (which comprises teeter water and gas bubbles) and a fluidized bed. The separation system comprises a separation tank, a slurry feed distributor, a fluidization flow manifold and a gas introduction system. All of these components are arranged to create the fluidized bed in the separation tank by introducing the slurry through the slurry feed distributor and allowing the slurry to interact with the fluidization flow that enters the separation tank from the fluidization flow manifold. The gas introduction system is configured to optimize the gas bubble size distribution in the fluidization flow. The gas introduction system comprises a gas introduction conduit and a bypass conduit. The gas introduction system can be adjusted by modulating the flow of teeter water through the gas introduction conduit.
    Type: Grant
    Filed: January 27, 2016
    Date of Patent: August 31, 2021
    Assignee: Eriez Manufacturing Co.
    Inventors: Michael J. Mankosa, Jaisen N. Kohmuench, Eric S. Yan
  • Patent number: 11078557
    Abstract: Hydrometallurgical systems, methods, and compositions are described in which amine-based lixiviants are utilized in substoichiometric amounts to recover alkaline earths from raw or waste materials. The lixiviant can be regenerated and recycled for use in subsequent iterations of the process or returned to a reactor in a continuous process. Extraction of the alkaline earth from the raw material and precipitation of the extracted alkaline earth is performed in the same reactor and essentially simultaneously.
    Type: Grant
    Filed: March 8, 2016
    Date of Patent: August 3, 2021
    Assignee: Lixivia, Inc.
    Inventors: Michael D. Wyrsta, Zachary J. A. Komon
  • Patent number: 11040888
    Abstract: The invention provides a low alpha dose barium sulfate particle having a silica content of 0.6% by weight or less, an average particle diameter of 1 ?m or less, a sulfur content of 10 ppm or less, and an alpha dose of 0.07 cph/cm2 or less.
    Type: Grant
    Filed: December 23, 2016
    Date of Patent: June 22, 2021
    Assignee: SAKAI CHEMICAL INDUSTRY CO., LTD.
    Inventors: Satoru Sueda, Hironobu Ogata
  • Patent number: 11014096
    Abstract: The present invention concerns a process for manufacturing white pigment containing products. The white pigment containing products are obtained from at least one white pigment and impurities containing material via froth flotation.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: May 25, 2021
    Assignee: OMYA INTERNATIONAL AG
    Inventors: Jorg Sotemann, Jorg Maier, David Gilbert, Tomi Matti Juhani Niitti
  • Patent number: 10961382
    Abstract: Improved sparge compositions for reverse froth flotation separation and uses thereof, and methods of reverse froth flotation are described. The sparge compositions comprise sulfonated polymeric modifiers which can act as dispersants and depressants, and the compositions are suitably used in the reverse froth flotation of particulate material containing ultrafine particles. For example, the compositions and methods can be used in the separation of iron oxide beneficiary from iron ores comprising silica, silicates, and the like.
    Type: Grant
    Filed: August 25, 2017
    Date of Patent: March 30, 2021
    Assignee: Ecolab USA Inc.
    Inventors: Jianjun Liu, Kevin O'Brien, Daniel N. T. Hay
  • Patent number: 10934191
    Abstract: Methods of making various capillary foams are provided. The foams can include liquid foams having a plurality of particles connected by a network of a secondary fluid at the interface between the discontinuous and continuous phase. The foams can also include solid foams where the continuous phases (bulk fluid) is removed to produce the solid foam having high overall porosities and low densities. Densities as low as 0.3 g cm?3 and porosities as high as 95% or higher can be achieved. The secondary fluid can be polymerized to further strengthen the solid foam. Methods and devices are also provided for oil recovery from water using a capillary foam. The methods can include forming a capillary foam wherein the oil is the secondary fluid, and wherein the foam can transport the oil to the surface of the water.
    Type: Grant
    Filed: September 6, 2016
    Date of Patent: March 2, 2021
    Assignee: Georgia Tech Research Corporation
    Inventors: Sven Holger Behrens, James Carson Meredith, III, Jie Wu, Yi Zhang
  • Patent number: 10927248
    Abstract: Improved sparge compositions for reverse froth flotation separation and uses thereof, and methods of reverse froth flotation are described. The sparge compositions comprise sulfonated polymeric modifiers which can act as dispersants and depressants, and the compositions are suitably used in the reverse froth flotation of particulate material containing ultrafine particles. For example, the compositions and methods can be used in the separation of phosphate beneficiary from ores comprising phosphates, dolomite, calcite, clay, silica, silicates, carbonates, and mixtures thereof.
    Type: Grant
    Filed: August 25, 2017
    Date of Patent: February 23, 2021
    Assignee: Ecolab USA Inc.
    Inventors: Jianjun Liu, Kevin O'Brien, Paul Wiatr, Daniel N.T. Hay
  • Patent number: 10919048
    Abstract: A process of phosphate flotation comprising: pulping phosphate ore with water to about 55% to 75% solids to produce an ore slurry; conditioning the ore slurry with a new reagent scheme to produce a conditioned slurry; subjecting the conditioned slurry to flotation to produce an underflow and an overflow; and collecting the overflow as phosphate concentrate. The new reagent scheme may comprise a combination of fatty acid, fuel oil, and fatty acid soap, and may not comprise a pH modifier. The process may also work effectively at a lower percent solids than conventional reagent schemes.
    Type: Grant
    Filed: October 31, 2018
    Date of Patent: February 16, 2021
    Assignee: ARR-MAZ PRODUCTS, L.P.
    Inventors: Guoxin Wang, Yu Xiong, Zhengxing Gu
  • Patent number: 10865110
    Abstract: Processes for removing/recovering heavy metal ions in solutions containing phosphoric acid by adding reagents having at least one organothiophosphorus compound and at least one surfactant to the solution during the wet-process phosphoric acid production process to form heavy metal complexes, and separating the heavy metal complexes from the solution are provided herein.
    Type: Grant
    Filed: October 5, 2018
    Date of Patent: December 15, 2020
    Assignee: Cytec Industries Inc.
    Inventors: Lei Zhang, Xueping Qiu, Rajesh Raitani
  • Patent number: 10744517
    Abstract: Provided is a method of beneficiating an ore including contacting an ore with a compound represented by formula (1): where the structural variables are defined herein.
    Type: Grant
    Filed: February 13, 2017
    Date of Patent: August 18, 2020
    Assignee: Arkema France
    Inventors: Eric Jorda, Alain Baloche, Nathalie Gibert, Isabelle Birken, Gilles Barreto, Jean-Paul Gamet
  • Patent number: 10737280
    Abstract: The present invention relates to an azolethione flotation collector and application thereof. According to the application, an azolethione compound such as a 1,3,4-thiadiazole-2-thione compound, a 1,3,4-oxadiazole-2-thione compound, a 1,2,4-triazole-3-thione compound or a 1,2,4,5-tetrazole-3-thione compound is used as a mineral flotation collector to be applied to ores containing copper, zinc, lead, nickel, cobalt, platinum, palladium, silver or gold minerals to realize flotation recovery of valuable metal minerals. Compared with common flotation collectors in the existing technologies, the flotation collector of the present invention can effectively improve enrichment and recovery of copper, zinc, lead, nickel, cobalt, platinum, palladium, silver or gold minerals.
    Type: Grant
    Filed: March 21, 2019
    Date of Patent: August 11, 2020
    Assignee: CENTRAL SOUTH UNIVERSITY
    Inventors: Guangyi Liu, Yaoguo Huang, Longqun Ma, Xiaoxue Niu, Jun Liu, Hong Zhong, Zhe Hu
  • Patent number: 10669201
    Abstract: A method of making a structural lightweight and thermal insulating concrete is described. The concrete has a coarse aggregate partly replaced by recycled plastic pieces. This enables the concrete to maintain a high compressive strength, low thermal conductivity, and low weight, while providing a use for waste plastic. The waste plastic pieces may comprise polyethylene in the form of flakes, fibers, or granules. Due to its low unit weight, adequate compressive strength and high thermal resistance the developed concrete can be used as a structural lightweight and thermal insulating concrete. The use of this concrete leads to economic and environmental benefits.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: June 2, 2020
    Assignee: King Fahd University of Petroleum and Minerals
    Inventors: Mohammed Rizwan Ali, Jobin Jose, Salah U. Al-Dulaijan, Shaik Inayath Basha, Mohammed Maslehuddin
  • Patent number: 10596578
    Abstract: A process for producing an iron ore having a sulfur content reduced to 0.08% or less, which includes a step of subjecting an iron ore containing sulfur in an amount of more than 0.08% and 2% or less to a flotation. The flotation satisfies any one of the following (1) to (3): (1) a xanthate-based compound and a salt of an amine compound are used as collectors, (2) a xanthate-based compound is used as a collector and a substance which releases a sulfur ion in water is used as an activator, or (3) a xanthate-based compound and a salt of an amine compound are used as collectors and a substance which releases a sulfur ion in water is used as an activator.
    Type: Grant
    Filed: June 23, 2014
    Date of Patent: March 24, 2020
    Assignee: KOBE STEEL, LTD.
    Inventors: Eishi Kusaka, Katsuyuki Iijima, Takayasu Fujiura
  • Patent number: 10589293
    Abstract: Depressants comprising a moderately oxidized polysaccharide having about 0.05 to about 4.5 mmol of anionic charge per gram at a pH of about 6 to about 7, or about 0.2 to about 5 mmol of anionic charge per gram at a pH of about 10 to about 11.2, are provided. Also disclosed are processes for enriching a desired mineral from an ore comprising the desired mineral and gangue, wherein the process comprises carrying out a flotation process in the presence of one or more of the depressants.
    Type: Grant
    Filed: September 26, 2016
    Date of Patent: March 17, 2020
    Assignee: Kemira OYJ
    Inventor: Duane C. Wilson
  • Patent number: 10543493
    Abstract: The present invention relates to a compound obtainable by reacting an N-acyl neutral amino acid or a salt thereof, or an N-acyl neutral amino acid oligopeptide or a salt thereof with a monohydroxy monocarboxylic acid or a salt thereof. This compound is useful as a collector in a process for froth flotation of non-sulfidic ores, especially phosphate ores. The invention also relates to a method which comprises the steps of a) conditioning a pulped phosphate ore, wherein the phosphate ore comprises a calcium phosphate mineral or a mixture of such minerals, and gangue minerals, with an effective amount of a calcium phosphate mineral collector reagent, which is the above-mentioned compound, and optionally other flotation aids and b) performing a froth flotation process to recover the calcium phosphate mineral(s).
    Type: Grant
    Filed: July 2, 2014
    Date of Patent: January 28, 2020
    Assignee: NOURYON CHEMICALS INTERNATIONAL B.V.
    Inventors: Natalija Smolko-Schvarzmayr, Anders Klingberg
  • Patent number: 10472525
    Abstract: Use of dithiophosphinic acids of the general formula HS2P(R1)(R2) and/or salts thereof for producing chrome-free, polymer-containing corrosion control layers on metallic surfaces, R1 and R2 independently of one another each being organic radicals having 1 to 30 C atoms.
    Type: Grant
    Filed: February 19, 2016
    Date of Patent: November 12, 2019
    Assignee: BASF COATINGS GMBH
    Inventors: Monica Fernandez Gonzalez, Markus Hickl, Cordula Mock-Knoblauch, Manfred Essig, Wolfgang Schrepp, Manfred Biehler
  • Patent number: 10434520
    Abstract: The invention is related to a flotation process using an improved collector to remove alkaline earth metal carbonate impurities from phosphate ores. The flotation feed may be conditioned with the improved carbonate collector at acidic pH, and subjected to a reverse flotation. The cell overflow may be collected as waste in which carbonate minerals dominate, and the cell underflow may be the phosphate concentrate. The collector may be a combination of chemicals, comprising: (1) any kind of fatty acids, either conventional fatty acid, saponified fatty acid, or modified fatty acid; (2) chemicals with sulfonate or sulfate groups, such as dodecylbenzene sulfonic acid (DDBSA) or its salt, sodium dodecyl sulfate (SDS), sodium lauryl sulfate (SLS), sodium coco sulfate (SCS), etc.; and (3) phosphorous-bearing chemicals, such as sodium tripolyphosphate (STPP), sodium hexametaphosphate (SFMP), trisodium phosphate (TSP), Tetrasodiumpyrophosphate (TSPP), etc.
    Type: Grant
    Filed: August 9, 2017
    Date of Patent: October 8, 2019
    Assignee: Arr-Maz Products, L.P.
    Inventors: Zhengxing Gu, Guoxin Wang, Yu Xiong
  • Patent number: 10384958
    Abstract: The invention provides methods and compositions for green compositions and technologies. In an embodiment, the present invention provides a method of separating a first material from a second material. For example, the method can comprise mixing the first material and the second material in a slurry with a beneficiation composition. The beneficiation composition can comprise one or more glyceride and fatty acid mixtures extracted from a fuel ethanol process. Air bubbles can be provided in the slurry to form bubble-particle aggregates with the first material and the bubble-particle aggregates can be allowed to be separated from the second material.
    Type: Grant
    Filed: January 30, 2015
    Date of Patent: August 20, 2019
    Assignee: ECOLAB USA INC.
    Inventors: Bo L. Tran, Kerem Eraydin, Jianjun Liu, Royce D. Mullins, Jinming Zhang, James A. Counter
  • Patent number: 10376901
    Abstract: The present invention relates to the use of branched fatty alcohol-based compounds selected from the group of fatty alcohols with 12-16 carbon atoms having a degree of branching of 1-3, and their alkoxylates with a degree of ethoxylation of up to 3, as secondary collectors for the froth flotation of non-sulfidic ores, in combination with a primary collector selected from the group of amphoteric and anionic surface active compounds.
    Type: Grant
    Filed: September 15, 2015
    Date of Patent: August 13, 2019
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Natalija Smolko-Schvarzmayr, Anders Klingberg, Elisabeth Henriksson, Henrik Nordberg
  • Patent number: 10344353
    Abstract: Methods of recovering metals from metal-bearing materials, and more particularly, methods for improving leaching efficiency in extraction processes by employing a surfactant composition in the extraction process, as well as slurries useful in the methods of recovering metals are provided.
    Type: Grant
    Filed: April 7, 2016
    Date of Patent: July 9, 2019
    Assignee: Ecolab USA Inc.
    Inventors: Vladimir Mujicic, Kim Coleman, Kevin O'Brien
  • Patent number: 10315202
    Abstract: A method of recovering particles from a liquid, a froth flotation apparatus, and a method of recovering particles in a flotation cell are disclosed. In an embodiment, the method comprises a technique of exposing the particles to first-size bubbles having a first predetermined size; the first-size bubbles adhering to the particles; and exposing the particles in a liquid, with the first-size bubbles adhering to the particles, to second-size bubbles having a second predetermined size, the second predetermined size being at least approximately ten times larger than the first predetermined size. The method further comprises the second-size bubbles adhering to the particles and engulfing the first-size bubbles on the particles; and using the second-size bubbles adhering to the particles to recover the particles from the liquid. In one embodiment a first surfactant is used to form the first-size bubbles, and a second surfactant is used to form the second-size bubbles.
    Type: Grant
    Filed: July 14, 2015
    Date of Patent: June 11, 2019
    Assignee: International Business Machines Corporation
    Inventors: Julia Baldauf, Alexe Bojovschi, Stephen Moore
  • Patent number: 10307770
    Abstract: The present invention relates to the beneficiation of coal by the process of froth flotation and specifically relates to a process for the froth flotation of coal using a mixture of fatty acids and rosin acids (and/or certain derivatives of fatty acids and rosin acids) as a collector.
    Type: Grant
    Filed: December 30, 2014
    Date of Patent: June 4, 2019
    Assignee: INGEVITY SOUTH CAROLINA, LLC
    Inventors: John B. Hines, Dennis L. Kennedy, Phillip W. Hurd
  • Patent number: 10258996
    Abstract: The present invention relates to flotation of sulfidic copper-molybdenum- and gold-containing minerals. More specifically, the invention relates to sulfoxy reagent-assisted floatation for separating of sulfides of copper, molybdenum and gold from pyrite, marcasite, pyrrhotite, arsenopyrite, and other gangue minerals following aerating by an oxidizing gas and contacting by a sulfoxy reagent. To promote collection and flotation the feed mineral materials are preferably not contacted with an externally generated non-oxidizing gas to lower the dissolved molecular oxygen content prior to flotation.
    Type: Grant
    Filed: March 22, 2016
    Date of Patent: April 16, 2019
    Assignee: Barrick Gold Corporation
    Inventor: Barun Gorain
  • Patent number: 10207275
    Abstract: The present invention discloses an advantageous and effective process for the concentration of iron ores, which can be fully dry or mixed, part of the process being dry, part wet. The invention thereby improves process efficiency as a whole by increasing recovery of concentrators and increasing the useful life of the mines.
    Type: Grant
    Filed: October 25, 2013
    Date of Patent: February 19, 2019
    Assignee: VALE S.A.
    Inventor: Joaquim Donizetti Donda
  • Patent number: 10195614
    Abstract: This invention relates to a collector composition for the direct froth flotation of nonsulfide ores comprising a) 50-99 wt.-% of a mixture of fatty acids and b) 1-50 wt.-% of an N-acyl derivative of sarcosine of the formula (I) wherein R is a saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, wherein the mixture of comprises 10.0-35.0 wt.-% of fatty acid having a saturated C11 hydrocarbon group, 2.5-15.0 wt.-% of fatty acid having a saturated C13 hydrocarbon group, 10.0-25.0 wt.-% fatty acid having a monounsaturated C17 hydrocarbon group and 20.0-45.0 wt.-% fatty acid having a bisunsaturated C17 hydrocarbon group.
    Type: Grant
    Filed: March 1, 2016
    Date of Patent: February 5, 2019
    Assignee: Clariant International Ltd.
    Inventors: Klaus-Ulrich Pedain, Jesús Pitarch López, Gunter Lipowsky, Jacques Collin Bezuidenhout
  • Patent number: 10150839
    Abstract: Amine-aldehyde resins are disclosed for removing a wide variety of solids and/or ionic species from the liquids in which they are suspended and/or dissolved. These resins are especially useful as froth flotation depressants, for example in the beneficiation of value materials (e.g., bitumen, coal, or kaolin clay) to remove impurities such as sand. The resins are also useful for treating aqueous liquid suspensions to remove solid particulates, as well as for removing metallic ions in the purification of water.
    Type: Grant
    Filed: June 23, 2014
    Date of Patent: December 11, 2018
    Assignee: INGEVITY SOUTH CAROLINA, LLC
    Inventors: James T. Wright, John B. Hines, Lisa M. Arthur, Carl R. White, Kurt D. Gabrielson, Michael J. Cousin
  • Patent number: 10147913
    Abstract: The invention relates to a process for the production of a recyclable product (1, 8, 9) made from a first material, wherein before or during the production of the product (1, 8, 9) a first marking material is added to the first material and the product (1, 8, 9) is produced from the first material with the admixed marking material, wherein the first marking material can be automatically detected in a recycling plant in the first material of the product (1, 8, 9) after the production thereof.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: December 4, 2018
    Assignee: Johnson Controls Autobatterie GmbH & Co. KGaA
    Inventors: Eberhard Meissner, Anne-Laure Ledoux, Jurgen Bauer
  • Patent number: 10144012
    Abstract: Methods of increasing the rate of separating hydrophobic and hydrophilic particles by flotation have been developed. They are based on using appropriate reagents to enhance the hydrophobicity of the particles to be floated, so that they can be more readily collected by the air bubbles used in flotation. The hydrophobicity-enhancing reagents include low HLB surfactants, naturally occurring lipids, modified lipids, and hydrophobic polymers. These methods can greatly increase the rate of flotation for the particles that are usually difficult to float, such as ultrafine particles, coarse particles, middlings, and the particles that do not readily float in the water containing large amounts of ions derived from the particles. In addition, new collectos for the flotation of phosphate minerals are disclosed.
    Type: Grant
    Filed: January 14, 2008
    Date of Patent: December 4, 2018
    Assignee: MINERAL AND COAL TECHNOLOGIES, INC.
    Inventor: Roe-Hoan Yoon
  • Patent number: 10118183
    Abstract: The invention relates to a process for selective flotation of kainite from crushed crude potash salts or, for example, from crystallized salt mixtures obtained by evaporation processes, which in addition to kainite may contain further minerals such as halite, sylvine and other salt minerals, for example, in order to produce a kainite concentrate fraction and a residues fraction. The separation process is characterized in that the crushed or crystallized salt mixture is intensively mixed as a crystallizate suspension with a combination of conditioning agents consisting of a sulfated fatty acid or its alkali metal salt as collecting reagent and a frothing agent known for flotation (for example, glycol ether, monohydric aliphatic alcohols, terpene alcohols, polyglycol ethers, etc.) and is then separated by agitator-driven or pneumatic flotation into a kainite concentrate fraction and a residues fraction. The resulting fractions may be further processed in downstream processes.
    Type: Grant
    Filed: December 1, 2015
    Date of Patent: November 6, 2018
    Assignee: K+S AKTIENGESELLSCHAFT
    Inventors: Uwe Wachsmuth, Jochen Brod
  • Patent number: 10105714
    Abstract: The present invention relates to a process for treating an earth contaminated by at least one radionuclide such as cesium 137Cs comprising at least one step of separating said radionuclide by dispersed air flotation foam produced by blowing air bubbles in a suspension comprising said earth and at least one collector. The present invention also relates to the flotation foam obtained by implementing such a process.
    Type: Grant
    Filed: May 10, 2013
    Date of Patent: October 23, 2018
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sylvain Faure, Marc Messalier
  • Patent number: 10105713
    Abstract: The instant invention relates to a composition in form of a stable aqueous emulsion comprising a) 1-50 wt.-% of at least one water insoluble thionocarbamate collector selected from the group consisting of dialkyl thionocarbamates, alkyl alkoxycarbonyl thionocarbamates and alkyl allyl thionocarbamates, b) 1-50 wt.-% of one or a mixture of surface active agents of the general formula wherein R1 is a saturated or unsaturated, branched or linear C3 to C30 aliphatic or aromatic hydrocarbon group, R2 and R3 are independently from each other hydrogen or a C1 to C4 alkyl group, R4 is hydrogen or —CH2—COOX where X is hydrogen or sodium salt or potassium salt or ammonium salt, and n and m are independently from each other 0 to 50, c) 0.1-20 wt.-% of a mixture of at least one alcohol and at least one ether and/or ester, e) 1-90 wt.-% of water.
    Type: Grant
    Filed: April 22, 2015
    Date of Patent: October 23, 2018
    Assignees: CLARIANT INTERNATIONAL LTD., CLARIANT S.A, CLARIANT (CHILE) LTDA.
    Inventors: Antonio Pedro De Oliveira Filho, Jesus Pitarch López, Wagner Claudio Da Silva, Gunter Lipowsky, Jacques Collin Bezuidenhout, Jaime Osvaldo Gomez Becerra, Rodrigo Alexis Caris Andrade, Franco Aurelio Constanzo Yanez
  • Patent number: 10052637
    Abstract: What is presented is a material processing system for processing tailings discharged from an ore processing system. The tailings comprise coarse waste rock, the fine waste rock, coarse valuable product, and the fine valuable product. The material processing system comprises a classification element, a coarse flotation element, and a fines flotation element arranged to separate the coarse valuable product, the coarse waste rock, the fine valuable product, and the fine waste rock. The classification element separates the coarse waste rock and/or the coarse valuable product from the fine waste rock and/or the fine valuable product. The coarse flotation element separates the coarse waste rock from the coarse valuable product, the fine waste rock, and/or the fine valuable product. The fines flotation element separates the fine valuable product from the coarse waste rock, the fine waste rock, and/or the coarse valuable product.
    Type: Grant
    Filed: January 2, 2014
    Date of Patent: August 21, 2018
    Assignee: Eriez Manufacturing Co.
    Inventors: Michael J. Mankosa, Jaisen N. Kohmuench, Eric S. Yan, Reginaldo Sérgio Liberato
  • Patent number: 10046302
    Abstract: The present invention relates to an apparatus for manufacturing a potassium compound and a method of recovering a potassium compound from a brine, and provides the apparatus for manufacturing the potassium compound, including: a continuous pre-treatment apparatus including a crushing portion, a pulverization portion, and a particle size separation portion for processing a mixed raw material salt obtained after lithium, magnesium, and calcium are extracted from a brine to have a particle size for easy separation and sorting; a continuous potassium compound lump recovering apparatus continuously separating and recovering the potassium compound from the pre-treated mixed raw material salt; a continuous potassium compound separating and sorting apparatus continuously separating and sorting potassium chloride and a glaserite (Na2SO4.3K2SO4) from the recovered potassium compound; and a continuous potassium sulfate conversion apparatus extracting potassium sulfate from the separated glaserite.
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: August 14, 2018
    Assignees: RESEARCH INSTITUTE OF INDUSTRIAL SCIENCE & TECHNOLOGY, POSCO, MPPLY CO., LTD.
    Inventors: Uong Chon, Gi-Chun Han, Im Chang Lee, Ki Young Kim, Woon kyoung Park