Abstract: Green compositions and technologies are provided. In an embodiment, the present invention provides a method of separating a first material from a second material. For example, the method can comprise mixing the first material and the second material in a slurry with a beneficiation composition. The beneficiation composition can comprise one or more glyceride and fatty acid mixtures extracted from an ethanol process. Air bubbles can be provided in the slurry to form bubble-particle aggregates with the first material and the bubble-particle aggregates can be allowed to be separated from the second material.

Abstract: The present invention relates to a flotation reagent for iron ores containing magnetite and/or haematite and to the use of a composition containing A) at least one amine alkoxylate ester of formula (I) or a salt thereof, wherein A and B, independently of one another, represent a C2-C5 alkylene radical, R1 is a C8 to C24 alkyl or alkenyl radical, R2, R3 and R4, independently of one another, are H or a C8 to C24 acyl radical, with the proviso that at least one of the radicals R2, R3 or R4 stands for a C8 to C24 acyl radical, x, y and z, independently of one other, are an integer of from 0 to 50, with the proviso that x+y+z is an integer of from 1 to 100, and B) a compound of formula D-NH2, in which D stands for a hydrocarbon radical having from 1 to 50 carbon atoms, which can contain either an oxygen atom or an oxygen atom and a nitrogen atom, in amounts of 10 to 5.000 g/tonne as a collector in the reverse flotation of iron ore containing magnetite, haematite or both.

Abstract: A flotation method for mineral processing is disclosed. The method for floating includes a first step of using a first carboxymethyl cellulose (CMC) in a first flotation cell, and a subsequent step includes using a second CMC in a subsequent flotation cell, the first and second CMCs having different characteristics. The first flotation cell may be used in at least one rougher stage and/or at least one rougher-scavenger stage of the flotation method, and the subsequent flotation cell may be used in at least one cleaner stage, and/or at least one cleaner scavenger stage, and/or at least one recleaner stage of the flotation method. A product may be obtained, directly or indirectly, by such a method. A mineral processing plant may use at least two CMCs of different characteristics in flotation for mineral processing.

Abstract: The present invention relates to the use of a polymeric quaternary ester product as a collector in a froth flotation process, to a method for froth flotation utilizing the polymeric quaternary ester, to the polymeric quaternary ester as such, and to methods for the production of the polymeric quaternary ester.

Abstract: A method of extracting targeted metallic minerals from ores that contain sulfide metallic minerals along with oxide minerals, carbonate minerals, silicate minerals, halide minerals or combinations thereof. In the method, an ore slurry containing the metallic mineral in oxide, carbonate, silicate or halide form is provided. The slurry is activated by adding sodium thiosulfate and sodium metabisulfite, whereby the targeted metallic mineral forms an intermediary metal complex with the sodium thiosulfate and sodium metabisulfite. One or more metal release components are introduced into the ore slurry; whereby the targeted metallic mineral is released from the intermediary metal complex to form a metal sponge. This metal sponge is then subjected to a flotation process, whereby the targeted metallic mineral is drawn out of the ore slurry and thereby extracted from the ore.

Abstract: Methods and compositions for separating materials are provided. In an embodiment, the present invention provides a method of separating a first material from a second material. For example, the method can comprise mixing the first material and the second material in a slurry with a beneficiation composition. The beneficiation composition can comprise one or more fatty acid by-products derived from a biodiesel manufacturing process. Air bubbles can be provided in the slurry to form bubble-particle aggregates with the first material and the bubble-particle aggregates can be allowed to be separated from the second material.

Abstract: The present invention relates to the beneficiation of coal by the process of froth flotation and specifically relates to a process for the froth flotation of coal using a mixture of fatty acids and rosin acids (and/or certain derivatives of fatty acids and rosin acids) as a collector.

Abstract: This invention relates to particulate and/or liquid droplet separation processes from liquids containing the same and the use of specific chemical additives to control surface wetting, hydrophobicity and surface forces in such processes.

Abstract: At least one froth receiving device may be positioned in a slurry retained in a tank of a flotation cell of a flotation machine. Each of the froth receiving devices may be positioned adjacent to froth formed in the slurry by being positioned in the tank at a height that positions the froth receiving device in the froth or near the froth. Each froth receiving device may receive froth to extract the froth from the tank. In some embodiments, the extracted froth may be sent to at least one particle separation device so at least a portion of solid material in the froth is separated from liquid of the froth. The separated solid material may be moved to another machine for further processing for recovering the desirable material while any remaining solid material and liquid may be sent to another device for being utilized in further material processing.

Abstract: The present invention relates to the beneficiation of coal by the process of froth flotation and specifically relates to a process for the froth flotation of coal using a collector consisting essentially of a fatty acid monoester of a polyol, a fatty acid diester of a polyol, or a mixture thereof.

Abstract: A method of using the synergy of multiple depressants to improve the depression of iron sulphide without compromising the recovery of the valuable sulphide minerals in the flotation of non-ferrous metal sulphides, while reducing or eliminating the use of environmentally problematic chemicals such as polyamines. The method has significant economic and environmental benefits. The multiple depressants comprise at least one organic polymer, at least one sulphur-containing compound and/or at least one nitrogen-containing organic compound.

Abstract: The invention provides methods and compositions for improving a froth flotation type separation. The method involves adding a hydrocarbon reaction product to slurry to enhance the separation. The method is particularly effective with coal separation because it increases yield without increasing ash content of flotation concentrate.

Abstract: A process for concentrating manganese from the tailing of a manganese-carrying mineral including removing a coarse particle size fraction from the tailing, desliming and conducting an acidic or a basic reverse cationic flotation. The manganese-carrying minerals are typically minerals with low manganese content from the lithologies “Tabular Pelite” (or PETB), Pelite Siltite (or PEST), Detritic (or DETR), Rich Pelite (or PERC) and Metallurgical Bioxide (or BXME). In another aspect, the present invention also relates to a reverse cationic flotation used to concentrate manganese which is carried out using depressor agents and collector agents as flotation reagents.

Abstract: The present invention provides a turbulent flow fly ash flotation process and flotation device. The process of the present invention comprises the following steps: 1) adding a flotation agent and/or a collecting agent to fly ash raw material to form a mixture; 2) in the flotation device, allowing the mixture obtained from step 1) to fall from the upper part of the flotation device; 3) forming upwardly blowing gas in the flotation device, the gas having countercurrent contacts with the falling mixture of step 2), and in the process of the upward movement of the gas, the gas being in a turbulent state; 4) collecting particles which are formed by the upward movement of the gas in step 3) and which pass through the flotation plate of the flotation device. In the present invention, the gas for blowing bubbles and particles upward is in a turbulent state to provide improved flotation effect and higher flotation rate.

Abstract: The present invention relates to a process for concentration of silicate-containing minerals and ores by froth flotation, in particular to a reverse flotation process, in the presence of a finely dispersed collecting agent characterized by a specific droplet size distribution.

Abstract: Amine-aldehyde resins are disclosed for removing a wide variety of solids and/or ionic species from the liquids in which they are suspended and/or dissolved. These resins are especially useful as froth flotation depressants, for example in the beneficiation of value materials (e.g., bitumen, coal, or kaolin clay) to remove impurities such as sand. The resins are also useful for treating aqueous liquid suspensions to remove solid particulates, as well as for removing metallic ions in the purification of water.

Abstract: The invention provides methods and compositions for improving a froth flotation type separation. The method uses a thickener to improve the effectiveness of an emulsifier. The improvement allows for low dosages of emulsifier to work well so the emulsifier does not cancel out the effectiveness of other additives in the slurry such as collectors, frothing agents, regulators, depressors, deactivators, and/or activators.

Abstract: Methods of enhancing recovery of value sulfide or precious minerals from an ore containing Mg-silicate, slime forming minerals, and/or clay by crushing the ore, grinding the ore, and subjecting the ground ore to a flotation process, in conjunction with the addition of at least one monovalent ion modifier enhancing agent and/or froth phase modifier agent to the ore, are provided herein.

Abstract: Materials in battery and electrochemical cells are separated in a form suitable for recycling by employing froth flotation techniques. Bulk materials, such as casings, are removed from converted battery scrap and the resultant pulp is subjected to froth flotation. Froth flotation agents, including frothers, collectors and/or depressants, are used to manipulate the hydrophilic and hydrophobic nature of the materials in the scrap. Hydrophobic materials are entrained in the air bubbles of the froth and float out of the froth flotation vessel while those that are hydrophilic remain in the vessel, thereby separating battery grid materials without resort to pyrometallurgical, energy intensive or other environmentally undesirable processes.

Abstract: The present invention relates to a process for enriching an iron mineral from a silicate-containing iron ore by reverse froth flotation of the ore using a collecting composition comprising: a) a compound of formula R1O-A-NH(CH2)nNH2 (I), wherein R1 is a straight or branched hydrocarbyl group with 12-15 carbon atoms, A is a group —CH2CHXCH2—, wherein X is hydrogen or a hydroxyl group, and n is a number 2-6; b) a compound of formula R2NH2 (II), where R2 is a hydrocarbyl group having 12-14 carbon atoms; c) a compound of formula R3NH2 (III), wherein R3 is a straight or branched, saturated or unsaturated hydrocarbyl group having 16-22 carbon atoms; and d) optionally a depressing agent for the iron mineral, wherein the amount of a) is at least 65% by weight, based on the total weight of a), b) and c), and at most 90% by weight, based on the total weight of a), b) and c), and wherein the weight ratio between c) and b) is 4:1 to 1:1.

Abstract: Disclosed herein is a method for separating an arsenic mineral from a copper-bearing material, including the steps of grinding a copper-bearing material containing arsenic, adding water to the copper-bearing material to prepare a slurry, and adding a flotation agent including a depressant, a frother, and a collector to the slurry and blowing air into the slurry for performing flotation to obtain a copper concentrate, wherein the depressant is a chelator. As the chelator, a polyethyleneamine or the like is used. Particularly, when triethylenetetramine is used as the chelator, the amount of triethylenetetramine to be added is preferably 1 to 10 equivalents relative to the amount of soluble copper generated by oxidation of the copper-bearing material, and the pH of the slurry is more preferably adjusted to 7 or more but 8 or less before the slurry is subjected to the flotation.

Abstract: A pneumatic flotation machine (100) has a housing (1) with a flotation chamber (3), at least one nozzle arrangement (4) for feeding gas and a suspension into the flotation chamber as well as at least one gassing arrangement (5) for feeding further gas into the flotation chamber (3), which arrangement is disposed within the flotation chamber (3) and below the at least one nozzle arrangement (4), wherein there is furthermore at least one adjusting device (9) for changing a position of the at least one gassing arrangement (5) in the flotation chamber (3).

Abstract: A depressor in iron ore flotation comprises sugar cane bagasse and caustic soda so as to assist in the iron ore flotation. Sugar cane bagasse is used as a depressor in iron ore flotation, and a process of preparing depressor comprising sugar cane bagasse is disclosed.

Abstract: The invention refers to a process to separate silicates and alkaline earth metal carbonates implementing at least one hydrophobically modified polyalkyleneimine, wherein: i) the polyalkyleneimine is hydrophobically modified by replacement of all or part of the hydrogens of their primary and/or secondary amino groups by functional group R, where R comprises a linear or branched or cyclic alkyl and/or aryl group and contains 1 to 32 carbon atoms; ii) prior to modification, the polyalkyleneimine has at least 3 alkyleneimine repeat units and a molecular weight of between 140 and 100 000 g/mol; iii) modification of the polyalkyleneimine results in an increase in the atomic C amount, relative to the unmodified polyalkyleneimine, of between 1 and 80%.

Abstract: The invention relates to a collector for the separation by flotation of carbonates contained in non-sulfurous minerals, particularly phosphoric rock, comprising at least one phosphoric ester of formula (I) wherein, R1 represents H, CH3 or C2H5, R2 represents a linear or branched alkyl or alkenyl group containing between 4 and 10 carbon atoms, R3 represents H or a suitable cation, selected from an alkali metal, an alkaline earth metal, ammonium, alkyl ammonium, alkanol ammonium or glucammonium, k represents a number comprised between 1 and 2, and n represents a number comprised between 0 and 4.

Abstract: Compounds of the formulae: RO—X—NH2 (Ia); RO—X—NH3+Y? (Ib); RO—X—NH—Z—NH2 (IIa); and RO—X—NH—Z—NH3+Y? (IIb), in which X is an aliphatic alkylene group containing 2 to 6 carbon atoms; Z is an aliphatic alkylene group containing 2 to 6 carbon atoms; Y? is an anion; and R is an aliphatic iso C13H27? group with average branching degree ranging from 1.5 to 3.5. The compounds are particularly suitable as flotation collectors for enriching an iron mineral from a silicate-containing iron ore.

Abstract: The present invention relates to fatty amido amine collectors for the beneficiation by flotation of aqueous suspensions of ores, the use of said fatty amido-amine collectors in flotation processes for the beneficiation of ores, more particularly in reverse flotation processes for the beneficiation of silicates containing-ores.

Abstract: The present invention relates to fatty alkoxylated polyamine collectors for the beneficiation by flotation of aqueous suspensions of ores, the use of said fatty alkoxylated polyamine collectors in flotation processes for the beneficiation of ores, more particularly in reverse flotation processes for the beneficiation of silicates containing-ores.

Abstract: The invention concerns a process for enriching an iron mineral from a silicate containing iron ore by inverse flotation comprising the addition of a collector or collector composition comprising at least one of the compounds of formulae RC(O)N(Z—O—X-NH2)2 (Ia); RC(O)N(Z-O-X-NH2)2H+ Y? (Ib); in which X is an aliphatic alkylene group containing 2 to 6 carbon atoms; Z is an aliphatic alkylene group containing 2 to 6 carbon atoms; Y? is an anion; and R is a saturated or unsaturated, linear or branched, aliphatic or aromatic moiety having between 7 and 23 carbon atoms. The invention also relates to the novel compounds according to formulae (Ia) and (Ib), compositions comprising said compounds and the use of compounds and formulations as collectors for enriching of iron mineral.

Abstract: The invention relates to a process for enriching an iron mineral from a silicate containing iron ore by inverse flotation comprising the addition of a collector or collector composition comprising at least one of the compounds of formulae RO—X—NH2 (Ia); RO—X—NH3+Y? (Ib); RO—X—NH—Z—NH2 (IIa); and RO—X—NH—Z—NH3+Y? (IIb), in which X is a linear or branched aliphatic alkylene group containing 2 to 6 carbon atoms; Z is a linear or branched aliphatic alkylene group containing 2 to 6 carbon atoms; Y? is an anion; and R is an aliphatic group of the formula (I) C5H11CH(C3H7)CH2— (I) wherein the C5H11 moeity of the aliphatic group of the formula (I) comprises 70 to 99% by weight n-C5H11—, and 1 to 30% by weight C2H5CH(CH3)CH2— and/or CH3CH(CH3)CH2CH2—.

Abstract: A process for improving mined coal includes comminuting the coal to a particle size at which individual macerals are available. Reactive macerals are extracted from the comminuted coal as froth from the top of a deep-column flotation cell. The extracted macerals are then de-watered.

Abstract: The present invention relates to a process for enriching an iron mineral from a silicate-containing iron ore by reverse froth flotation of the ore using a collecting composition comprising: a) a compound of formula R1O-A-NH(CH2)nNH2 (I), wherein R1 is a straight or branched hydrocarbyl group with 12-15 carbon atoms, A is a group —CH2CHXCH2—, wherein X is hydrogen or a hydroxyl group, and n is a number 2-6; b) a compound of formula R2NH2 (II), where R2 is a hydrocarbyl group having 12-14 carbon atoms; c) a compound of formula R3NH2 (III), wherein R3 is a straight or branched, saturated or unsaturated hydrocarbyl group having 16-22 carbon atoms; and d) optionally a depressing agent for the iron mineral, wherein the amount of a) is at least 65% by weight, based on the total weight of a), b) and c), and at most 90% by weight, based on the total weight of a), b) and c), and wherein the weight ratio between c) and b) is 4:1 to 1:1.

Abstract: Unburned carbon is efficiently removed from fly ash, and effective utilization of the fly ash and removed unburned carbon is attained. Water is added to fly ash to thereby obtain a slurry. A collector is added to the slurry, and shearing force is applied to the slurry and collector to thereby attain a surface modification. The mixture is subjected to flotation operation at which unburned carbon of fly ash is attached to froths and surfaced. The application of shearing force to the slurry and collector can be carried out by means of a submerged agitator whereby an agitation power of 0.7 to 10 kWh/m3 is applied per unit quantity of slurry. The fly ash concentration of the slurry is in the range of 3 to 50 wt. %, and the amount of collector added is in the range of 5 to 100 wt. % based on the amount of unburned carbon of fly ash. The unburned carbon separated by flotation can be used as fuel, and the fly ash (product) having its unburned carbon content reduced to 1 wt.

Abstract: The invention relates to a method for separating insoluble components of sylvinite, in that the sylvinite is suspended in a saturated salt solution, a coagulating agent is added to the suspension, and a foaming agent comprising a hydrocarbon radical having from 6 to 16 carbon atoms is added to the composition so obtained.

Abstract: A biodegradable floatation aid for use in the froth floatation process for ore beneficiation has been developed to replace the current petroleum based hydrocarbons. The product described is an ester of C-8 through C-20 alcohols and C-2 through C-12 diols or triols, reacted with C-12 through C-22 carboxylic acids or C-2 through C-36 dicarboxylic acids.

Abstract: The invention relates to a method for separating insoluble components from sylvinite, wherein the sylvinite is suspended in a saturated salt brine, a coagulating agent is added to the suspension, and a foaming agent is then added to the composition thus obtained, said foaming agent comprising and ether and/or ester, wherein a) the ethers of formula 1 correspond to R—O—R? (1), where R is a linear or branched alkyl or alkenyl groups having 2 to 30 carbon atoms and R? is a linear or branched alkyl or alkenyl groups having 1 to 30 carbon atoms; b) the esters are derived from monovalent or multivalent alcohols having 1 to 30 carbon atoms (alcohol radicals); or c) the ethers and/or esters are cyclic, wherein the ring size is 6 to 30 carbon atoms.

Abstract: Embodiments related to recycling alkaline batteries are disclosed. In one disclosed embodiment, a method for recycling a battery having a basic electrolyte comprises rupturing the battery under anaerobic conditions and flooding the interior of the battery with carbon dioxide in an anaerobic chamber.

Abstract: A process for the flotation of non-sulfidic minerals or ores, is disclosed in which crushed crude minerals or ores are mixed with water and a collector to form a suspension, air is introduced into the suspension in the presence of a reagent system, and a floated foam containing the non-sulfidic mineral or ores is formed therein along with a flotation residue comprising the gangue polymeric esterquats as the collector polymeric esterquats. The polymeric esterquats are obtained by reacting alkanolamines with a mixture of monocarboxylic acids and dicarboxylic acids and quaternizing the resulting esters, optionally after alkoxylation.

Abstract: The invention refers to a process to separate silicates and alkaline earth metal carbonates implementing at least one hydrophobically modified polyalkyleneimine, wherein: i) the polyalkyleneimine is hydrophobically modified by replacement of all or part of the hydrogens of their primary and/or secondary amino groups by functional group R, where R comprises a linear or branched or cyclic alkyl and/or aryl group and contains 1 to 32 carbon atoms; ii) prior to modification, the polyalkyleneimine has at least 3 alkyleneimine repeat units and a molecular weight of between 140 and 100 000 g/mol; iii) modification of the polyalkyleneimine results in an increase in the atomic C amount, relative to the unmodified polyalkyleneimine, of between 1 and 80%. The invention additionally refers to a silicate-containing product and an alkaline earth metal carbonate-containing product obtained by the process of the invention, and to their uses.

Abstract: An improved frothing agent adaptable to froth flotation process to enhance coal selectivity for separation and efficiency of the froth flotation process comprises: A blended mixture of Ketone (2,6-Dimethyl-4-Heptanone) 85-89% (Wt %) Ester molecule(Tetrahydrofurfuryl acetate) 10-12% (Wt %) Epoxide conditioner (1,2-Epoxydodecane) 0.25-0.30% (Wt %) Water 4.75-5.

Abstract: Froth flotation processes that include adding a beneficiating amount of a value mineral collector composed of an organic ammonium salt of a sulfur-containing acid to at least one stage of a froth flotation process to recover value minerals from mineral ore bodies are disclosed herein.

Abstract: Froth flotation processes that include adding a beneficiating amount of a value mineral collector composed of an organic ammonium salt of a sulfur-containing acid to at least one stage of a froth flotation process to recover value minerals from mineral ore bodies are disclosed herein.

Abstract: Formulations for value mineral collector compositions composed of at least one first collector selected from an organic ammonium salt of an organic sulfur-containing acid; and at least one second collector selected from neutral collectors and/or organic ammonium salts of an organic sulfur-containing acids, such that the second collector is different from said first collector, are provided herein, along with methods for making and using same.

Abstract: The invention provides a method of improving a flotation separation process. The method involves PAPEMP, a material previously thought to only be of use in controlling scale deposit on surfaces of equipment used in cyanide leaching. In the invention the PAPEMP is added to the flotation separation process for improved sulfide mineral separation. Not only does the addition of PAPEMP improve the overall recovery of sulfide complexed metals in flotation, but by doing so it also reduces the energy requirements and adds other efficiencies to other downstream ore processing and refining steps. This has the added benefit of helping to preserve the environment.

Abstract: Collectors for froth flotation including oxidized fatty acid compositions and oxidized and maleated compositions. In particular, use of oxidized tall oil compositions and oxidized and maleated fatty acid compositions are disclosed.

Abstract: A flotation process for recovering feldspar from a feldspar containing feed material, comprising the following steps: (1) forming an aqueous suspension of a feldspar containing feed material, in the absence of hydrofluoric acid, wherein the suspension comprises from 0.004 to 0.3% wt. of a flotation reagent comprising: (a) one or more amines, containing at least one aliphatic hydrocarbon chain, linear or branched, saturated or unsaturated, comprising 8 to 50 carbon atoms, or a salt thereof; and (b) one or more primary, secondary or tertiary alcohols, containing at least one aliphatic hydrocarbon chain, linear or branched, saturated or unsaturated, comprising 8 to 50 carbon atoms; the ratio of (a) to (b) ranging from 500:1 to 1:40 by weight; (2) agitating the obtained suspension to produce a feldspar containing fraction, and (3) separating the feldspar containing fraction.

Abstract: The invention relates to a flotation process for removal of slimes from potash ores which includes a step in said process wherein a collector is used which is a mixture of ethoxylated fatty amines having the formulae (I) wherein R1 and R2 are, independently, a hydrocarbyl group having 1-22 C-atoms, and n is on average above 15 and less than 100, and (II) wherein R3 is a hydrocarbyl group having 8-22 carbon atoms; z is a number 1-3; X, Y and Y? are, independently, an alkyl group with 1-4 carbon atoms or the group -(EO)sH, wherein EO is an ethyleneoxy unit and s is on average 5-50, and the sum of all s is on average 15 or more, and less than 100; provided that at least one of X, Y and Y? is a group -(EO)sH; and where the molar ratio of I to II is 1:5 to 5:1. The invention also relates to said mixtures of collectors where the molar ratio of I to II is 1:5 to 5:1.

Abstract: The invention relates to a flotation process for removal of slimes from potash ores wherein a collector is used selected from the group of ethoxylated fatty amines having the formulae (formula I) wherein R1 and R2 are, independently, a hydrocarbyl group having 1-22 C-atoms, and n is on average above 15 and less than 100, and (formula II) wherein R3 is a hydrocarbyl group having 8-22 carbon atoms; z is a number 1-3; X, Y and Y? are, independently, an alkyl group with 1-4 carbon atoms or the group -(EO)sH, wherein EO is an ethyleneoxy unit and s is on average 5-50, and the sum of all s is on average 15 or more, and less than 100; provided that at least one of X, Y and Y? is a group -(EO)sH. The invention further relates to a process wherein the step of flotation of slime is followed by a step of flotation of KCl using a different type of collector.

Abstract: The invention concerns a process for purification of calcium carbonate-comprising minerals comprising at least one flotation step, characterized in that this step implements at least one quaternary imidazoline methosulfate compound as collector agent.

Abstract: A method for separating and recovering silicon debris from sawing waste is characterized in that it includes the following steps: —treating the sawing waste so as to deoxidize the silicon debris in a manner that reduces their surface energy, —applying to the sawing waste thus treated a flotation method using a flotation liquid and a nonoxidizing flotation gas, and —recovering the silicon debris at the surface of the flotation liquid.