Having Utility As A Reactive Material In An Electrochemical Cell; E.g., Battery, Etc. Patents (Class 252/182.1)
  • Patent number: 9219275
    Abstract: An active material for a nonaqueous electrolyte secondary battery includes a lithium transition metal composite oxide which has an ?-NaFeO2-type crystal structure, is represented by the compositional formula Li1+?Me1??O2 (Me is a transition metal element containing Mn, Ni and Co; and 0<?<1) and satisfies the requirement of 1.250 ?(1+?)/(1??)?1.425. The half-width of a diffraction peak at 2?=18.6°±1° is 0.20° to 0.27° and/or the half-width of a diffraction peak at 2?=44.1°±1° is 0.26° to 0.39° in X-ray diffraction measurement using a CuK? radiation. The lithium transition metal composite oxide is observed as a single phase indexed a hexagonal crystal (space group R3-m) on the X-ray diffraction patterns when electrochemically oxidized to a potential of 5.0 V (vs. Li/Li+).
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: December 22, 2015
    Assignee: GS Yuasa International Ltd.
    Inventor: Daisuke Endo
  • Patent number: 9209453
    Abstract: A negative electrode active material for an electric device includes an alloy containing silicon in a range from 25% to 54% exclusive, carbon in a range from 1% to 47% exclusive, zinc in a range from 13% to 69% exclusive in terms of mass ratio, and inevitable impurities as a residue. For example, the negative electrode active material can be obtained with a multi DC magnetron sputtering apparatus by use of silicon, carbon and zinc as targets. An electric device using this negative electrode active material can improve the initial charge-discharge efficiency while keeping the cycle property.
    Type: Grant
    Filed: March 6, 2012
    Date of Patent: December 8, 2015
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Manabu Watanabe, Osamu Tanaka, Masao Yoshida
  • Patent number: 9190665
    Abstract: Provided are a crystalline iron phosphate doped with metals (MFePO4), which is used as a precursor of olivine-structured LiMFePO4 (LMFP) used as a cathode active material for lithium secondary batteries, and a method of preparing the crystalline iron phosphate, in which a crystalline iron phosphate doped with metals has the following Formula I obtained by crystallizing amorphous iron phosphate and doping the latter with a different type of a metal. Formula I: MFePO4, where M is selected from the group consisting of Ni, Co, Mn, Cr, Zr, Nb, Cu, V, Ti, Zn, Al, Ga, Mg, and B. The preparation of olivine-structured LMFP, which is used as a cathode active material for lithium secondary batteries, using the crystalline iron phosphate doped with metals as a precursor can increase efficiency and reduce processing costs as compared to another method of preparing the same by mixing different types of metals in a solid state.
    Type: Grant
    Filed: December 14, 2012
    Date of Patent: November 17, 2015
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Hyun A Song, Woo Young Yang
  • Patent number: 9190186
    Abstract: Providing a negative-electrode active material for nonaqueous-electrolyte secondary battery, the negative-electrode active material enabling an output characteristic to upgrade, a production process for the same, a negative electrode for nonaqueous-electrolyte secondary battery, and a nonaqueous-electrolyte secondary battery. The negative-electrode active material includes an Si-metal-carbon composite composed of: a metal/carbon composite matrix including at least one metal selected from the group consisting of Cu, Fe, Ni, Ti, Nb, Zn, In and Sn, at least one member selected from the group consisting of N, O, P and S, and amorphous carbon; and nanometer-size Si particles dispersed in the metal/carbon composite matrix.
    Type: Grant
    Filed: April 10, 2013
    Date of Patent: November 17, 2015
    Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Yusuke Sugiyama, Tomohiro Niimi, Masataka Nakanishi, Hirotaka Sone, Kazuhito Kawasumi, Masakazu Murase
  • Patent number: 9172082
    Abstract: The present disclosure relates to an electrode composite material. The electrode composite material includes a number of electrode composite material particles. Each of the plurality of electrode composite material particles includes an electrode active material particle and a doped aluminum phosphate layer coated on a surface of the electrode active material particle. A material of the doped aluminum phosphate layer is a semiconducting doped aluminum phosphate.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: October 27, 2015
    Assignees: Tsinghua University, HON HAI PRECISION INDUSTRY CO., LTD.
    Inventors: Xian-Kun Huang, Xiang-Ming He, Chang-Yin Jiang, Dan Wang, Jian Gao, Jian-Jun Li
  • Patent number: 9172099
    Abstract: A fibrous sheet for fuel cell or battery applications is formed by electrospinning a fluorinated ion-conducting polymer solution to form an agglomeration of fibers.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: October 27, 2015
    Assignee: GM Global Technology Operations LLC
    Inventors: Lijun Zou, Timothy J. Fuller, Michael R. Schoeneweiss
  • Patent number: 9172124
    Abstract: A photoelectric conversion material is obtained through easy processing from a substance containing silicon oxide, which is inexpensive, imposes no burden on the environment, and is stable, as a component. This material can be used in a photocell and a secondary photocell. Any of synthetic quartz, fused quartz glass, soda-lime glass, non-alkali glass, and borosilicate glass, which are compositions containing silicon oxide, is pulverized, immersed in an aqueous solution of halogen acid, washed with water, and dried. The resultant material is deposited on an electrode plate and this electrode plate is placed in water where an appropriate electrolyte is mixed. This electrode plate is electrically connected to an opposite electrode to provide a photoelectrode. The material may be enclosed in a container, mixed with an organic electrolyte, having an extraction electrode and an opposite electrode, to provide a photocell.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: October 27, 2015
    Assignee: IFTL-SOLAR INC.
    Inventors: Nobuaki Komatsu, Tomoko Ito, Hiroki Nagai
  • Patent number: 9159991
    Abstract: This invention relates generally to electrode materials, electrochemical cells employing such materials, and methods of synthesizing such materials. The electrode materials have a crystal structure with a high ratio of Li to metal M, which is found to improve capacity by enabling the transfer of a greater amount of lithium per metal, and which is also found to improve stability by retaining a sufficient amount of lithium after charging. Furthermore, synthesis techniques are presented which result in improved charge and discharge capacities and reduced particle sizes of the electrode materials.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: October 13, 2015
    Assignee: Massachusetts Institute of Technology
    Inventors: Gerbrand Ceder, Anubhav Jain, Geoffroy Hautier, Jae Chul Kim, Byoungwoo Kang, Robert Daniel
  • Patent number: 9136525
    Abstract: A negative-electrode active material characterized by containing a silicon oxide represented by a general formula SiOx (0<x<2) and a silicate compound represented by a composition formula MaSibOc-m(OH)-n(H20), and a method for the production of a negative-electrode active material which includes a mixing step of mixing a silicon oxide that is represented by a general formula SiOy (0<y<2) and a metal oxide, and a heat treatment step of performing a heat treatment on the mixture that is obtained in the mixing step in a non-oxidizing atmosphere and in which the negative absolute value of the standard Gibbs energy of the oxidation reaction of the metal oxide at the heating temperature in the heat treatment step is smaller than the negative absolute value of the standard Gibbs energy of the oxidation reaction of Si at the heating temperature in the heat treatment step.
    Type: Grant
    Filed: June 19, 2012
    Date of Patent: September 15, 2015
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventor: Hideyuki Yamamura
  • Patent number: 9136533
    Abstract: This invention provides a lithium nickel manganese cobalt composite oxide having a composition of LiaNixMnyCozO2 (x+y+z=1, 1.05<a<1.3), wherein, in the data obtained by measuring a Raman spectrum of the composite oxide, the peak intensity of an Eg oscillation mode of a hexagonal crystal structure located at 480 to 495 cm?1 and the peak intensity of an F2g oscillation mode of a spinel structure located at 500 to 530 cm?1 in relation to the peak intensity of an A1g oscillation mode having a hexagonal crystal structure in which the main peak is located at 590 to 610 cm?1 are respectively 15% or higher and 40% or lower than the peak intensity of the A1g oscillation mode of a hexagonal crystal structure as the main peak. Thereby, the Raman spectrum can be used for the identification of the crystal structure to clarify the characteristics of a positive electrode precursor composed of lithium nickel manganese cobalt composite oxide.
    Type: Grant
    Filed: December 8, 2006
    Date of Patent: September 15, 2015
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Ryuichi Nagase, Yoshio Kajiya, Hiroshi Tasaki
  • Patent number: 9123959
    Abstract: A composition for use in a battery electrode comprising a compound including lithium, manganese, nickel, and oxygen. The composition is characterized by a powder X-ray diffraction pattern having peaks including 18.6±0.2, 35.0±0.2, 36.4±0.2, 37.7±0.2, 42.1±0.2, and 44.5±0.2 degrees 2? as measured using Cu K? radiation.
    Type: Grant
    Filed: February 10, 2014
    Date of Patent: September 1, 2015
    Assignee: WILDCAT DISCOVERY TECHNOLOGIES, INC.
    Inventors: Bin Li, Marissa Caldwell, Wei Tong, Steven Kaye, Vinay Bhat
  • Patent number: 9093678
    Abstract: Provided is an electrode active material comprising a nickel-based lithium transition metal oxide (LiMO2) wherein the nickel-based lithium transition metal oxide contains nickel (Ni) and at least one transition metal selected from the group consisting of manganese (Mn) and cobalt (Co), wherein the content of nickel is 50% or higher, based on the total weight of transition metals, and has a layered crystal structure and an average primary diameter of 3 ?m or higher, wherein the amount of Ni2+ taking the lithium site in the layered crystal structure is 5.0 atom % or less.
    Type: Grant
    Filed: August 15, 2014
    Date of Patent: July 28, 2015
    Assignee: LG CHEM, LTD.
    Inventors: Sinyoung Park, Sung kyun Chang, Hong-Kyu Park, Seung Tae Hong, Youngsun Choi
  • Patent number: 9083042
    Abstract: A negative electrode active material mainly contains silicon and silicon oxide. In the negative electrode active material, an Ar-laser Raman spectrum thereof includes a peak A corresponding to 950±30 cm?1 and a peak B corresponding to 480±30 cm?1, and an intensity ratio of the peak B to the peak A (B/A) is in the range of 1 to 10.
    Type: Grant
    Filed: March 18, 2013
    Date of Patent: July 14, 2015
    Assignee: TDK CORPORATION
    Inventors: Yasuhiro Ikeda, Atsushi Sano, Masaki Sobu, Tetsuo Takaishi
  • Patent number: 9077023
    Abstract: A cathode active material including: a lithium manganese oxide of which primary particles has a diameter of 1 ?m or more and which has a spinel structure in which an X-ray diffraction (XRD) peak intensity ratio of I(111)/I(311) is 1.0 or more; and a boron element disposed at least one position selected from the group consisting of inside the primary particles and on surfaces of the primary particles.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: July 7, 2015
    Assignee: SAMSUNG SDI CO., LTD.
    Inventors: Min-Ju Kim, Yong-Chul Park, Gyeong-Jae Heo, Hyun-Deok Lee, Mi-Ran Song, Jin-Hyoung Seo, Na-Leum Yoo
  • Patent number: 9054381
    Abstract: A negative electrode active material for a lithium ion battery having the composition formula SiaSnbNicTiyMmCz, wherein a, b, c, y, m and z represent atomic % values, wherein M is either one of more of Fe, Cr and Co, and wherein a>0, b>0, z>0, y?0, 0?m?1, c>5, z+0.5*b>a and c+y>0.75*b. The process for preparing the active material comprises the steps of:—providing a mixture of elemental and/or alloyed powders of the elements in the composition SiaSnbNicTiyMmCz, and—high energy milling under non-oxidizing conditions of the powder mixture.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: June 9, 2015
    Assignee: Umicore
    Inventors: Michael Gilles, Kris Driesen, Stijn Put
  • Patent number: 9048492
    Abstract: A negative electrode active material for an electric device includes an alloy containing silicon in a range from 33% by mass to 50% by mass, zinc in a range of greater than 0% by mass and less than or equal to 46% by mass exclusive, vanadium in a range from 21% by mass to 67% by mass, and inevitable impurities as a residue. The negative electrode active material can be obtained with a multi DC magnetron sputtering apparatus by use of, for example, silicon, zinc, and vanadium as targets. An electric device using the negative electrode active material can achieve long cycle life and ensure a high capacity and cycle durability.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: June 2, 2015
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Manabu Watanabe, Osamu Tanaka, Masao Yoshida
  • Publication number: 20150147658
    Abstract: Providing a silicon-containing material having a novel structure being distinct from the structure of conventional silicon oxide disproportionated to use. A silicon-containing material according to the present invention includes at least the following: a continuous phase including silicon with Si—Si bond, and possessing a bubble-shaped skeleton being continuous three-dimensionally; and a dispersion phase including silicon with Si—O bond, and involved in an area demarcated by said continuous phase to be in a dispersed state.
    Type: Application
    Filed: June 25, 2013
    Publication date: May 28, 2015
    Applicant: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Yoshihiro Nakagaki, Nobuhiro Goda, Manabu Miyoshi, Yushi Kondo, Kensuke Yotsumoto
  • Publication number: 20150147652
    Abstract: Provided is a new 5 V class spinel exhibiting an operating potential of 4.5 V or more (5 V class), which can suppress the amount of gas generation during high temperature cycles. Suggested is a manganese spinel-type lithium transition metal oxide represented by formula: Li[NiyMn2-(a+b)-y-zLiaTibMz]O4 (wherein 0?z?0.3, 0.3?y<0.6, and M=at least one or more metal elements selected from the group consisting of Al, Mg, Fe and Co), in which in the above formula, the following relationships are satisfied: a>0, b>0, and 2?b/a?8.
    Type: Application
    Filed: April 25, 2013
    Publication date: May 28, 2015
    Applicant: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Natsumi Shibamura, Yanko Marinov Todorov, Shinya Kagei, Yoshimi Hata
  • Publication number: 20150147653
    Abstract: A positive active material is disclosed that includes a lithium nickel composite oxide represented by the following Chemical Formula 1, wherein a full width at half maximum (FWHM003) at a (003) plane in X-ray diffraction ranges from about 0.12 to about 0.155, and a rechargeable lithium ion battery including the same.
    Type: Application
    Filed: November 13, 2014
    Publication date: May 28, 2015
    Inventors: Keisuke Nomura, Yuki Takei, Masatsugu Nakano
  • Publication number: 20150147650
    Abstract: An antimony based anode material for a rechargeable battery comprises nanoparticles of composition SbMxOy where M is a further element selected from the group consisting of Sn, Ni, Cu, In, Al, Ge, Pb, Bi, Fe, Co, Ga, with 0?x<2 and 0?y?2.5+2x. The nanoparticles form a substantially monodisperse ensemble with an average size not exceeding a value of 30 nm and by a size deviation not exceeding 15%. A method for preparing the antimony based anode material is carried out in situ in a non-aqueous solvent and starts by reacting an antimony salt and an organometallic amide reactant and oleylamine.
    Type: Application
    Filed: November 20, 2014
    Publication date: May 28, 2015
    Inventors: Maksym V. KOVALENKO, He MENG, Kostiantyn KRAVCHYK, Marc WALTER
  • Publication number: 20150147654
    Abstract: Provided is a lithium mixed transition metal oxide having a composition represented by Formula I of LixMyO2 (M, x and y are as defined in the specification) having mixed transition metal oxide layers (“MO layers”) comprising Ni ions and lithium ions, wherein lithium ions intercalate into and deintercalate from the MO layers and a portion of MO layer-derived Ni ions are inserted into intercalation/deintercalation layers of lithium ions (“reversible lithium layers”) thereby resulting in the interconnection between the MO layers. The lithium mixed transition metal oxide of the present invention has a stable layered structure and therefore exhibits improved stability of the crystal structure upon charge/discharge. In addition, a battery comprising such a cathode active material can exhibit a high capacity and a high cycle stability.
    Type: Application
    Filed: February 5, 2015
    Publication date: May 28, 2015
    Applicant: LG Chem, Ltd.
    Inventors: Hong-Kyu Park, Sun Sik Shin, Sin Young Park, Ho Suk Shin, Jens M. Paulsen
  • Publication number: 20150147655
    Abstract: Provided are lithium transition metal composite particle including a lithium transition metal oxide particle, a metal-doped layer formed by doping the lithium transition metal oxide particle, and LiF formed on the lithium transition metal oxide particle including the metal-doped layer, a preparation method thereof, and a lithium secondary battery including the lithium transition metal composite particles.
    Type: Application
    Filed: November 25, 2014
    Publication date: May 28, 2015
    Applicant: LG CHEM, LTD.
    Inventors: Sung Bin Park, Ji Hye Kim, Wang Mo Jung, Sang Seung Oh, Byung Chun Park
  • Patent number: 9039926
    Abstract: A production process for composite oxide expressed by a compositional formula: LiMn1-xAxO2, where “A” is one or more kinds of metallic elements other than Mn; and 0?“x”<1, obtained by preparing a raw-material mixture by mixing a metallic-compound raw material and a molten-salt raw material with each other, the metallic-compound raw material at least including an Mn-containing nitrate that includes one or more kinds of metallic elements in which Mn is essential, the molten-salt raw material including lithium hydroxide and lithium nitrate, and exhibiting a proportion of the lithium nitrate with respect to the lithium hydroxide (Lithium Nitrate/Lithium Hydroxide) that falls in a range of from 1 or more to 3 or less by molar ratio; reacting the raw-material mixture at 500° C. or less by melting it; and recovering the composite oxide being generated from the raw-material mixture that has undergone the reaction.
    Type: Grant
    Filed: February 7, 2011
    Date of Patent: May 26, 2015
    Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Ryota Isomura, Hitotoshi Murase, Naoto Yasuda
  • Publication number: 20150140424
    Abstract: Provided are an active electrode material composition for a lithium-ion secondary battery, an electrode for a lithium-ion secondary battery, and a lithium-ion secondary battery using the active electrode material composition. The active electrode material composition includes an active electrode material and a binder. The binder is characterized by existing in the form of a polyamide-amic acid compound in an electrode paste, and forming a polyamide-imide compound with excellent stability by means of high-temperature curing. The electrode paste is a water-based paste, which can avoid the use of an organic solvent in the electrode paste making process, and the obtained electrode has excellent structural stability and the battery performance is improved.
    Type: Application
    Filed: October 8, 2012
    Publication date: May 21, 2015
    Inventors: Zifeng Ma, Zhengwei Zhao, Zhenguo Miao
  • Publication number: 20150137032
    Abstract: The present invention relates to a process for producing a vinylidene fluoride polymer solution, which involves dissolving heat-treated vinylidene fluoride polymer powder into an aprotic polar solvent. The heat-treated vinylidene fluoride polymer powder is obtained by heat treating raw vinylidene fluoride polymer powder at such a temperature that the temperature of the vinylidene fluoride polymer powder is not less than 125° C. to less than a crystal melting temperature (Tm) of the polymer.
    Type: Application
    Filed: January 30, 2015
    Publication date: May 21, 2015
    Inventors: Tamito Igarashi, Shintarou Mutou, Hiroshi Sakabe, Emi Sugawara
  • Publication number: 20150137030
    Abstract: The purpose of the present invention is to provide: an aqueous binder having high adhesiveness, that in particular does not exhibit oxidative degradation in an electrode environment, and having little environmental load; and an electrode and a battery that use same. Disclosed is a battery electrode binder containing: (A) a constituent unit derived from a monomer having a hydroxyl group; and (B) a constituent unit derived from a polyfunctional (meth)acrylate having no more than 5 functions. An electrode is prepared using this binder and is used in a battery such as a lithium-ion secondary battery.
    Type: Application
    Filed: May 28, 2013
    Publication date: May 21, 2015
    Applicant: Daiso Co., Ltd.
    Inventors: Takashi Matsuo, Tomoyuki Yano, Yasushi Miki, Katsuhito Miura
  • Publication number: 20150140432
    Abstract: To provide an electric storage device that has excellent charging characteristics, particularly at a low temperature. Provided is a nonaqueous solvent-based electric storage device containing as positive electrode active materials, at least one of a lithium nickel aluminum complex oxides and a spinel-type lithium manganese oxide active material having LiMn2O4 as a basic structure, and lithium vanadium phosphate.
    Type: Application
    Filed: April 8, 2013
    Publication date: May 21, 2015
    Inventors: Hideo Yanagita, Kazuki Takimoto
  • Publication number: 20150137031
    Abstract: The invention relates to novel materials of the formula: A1-?M1vM2wM3xM4yM5zO2 wherein A comprises either lithium or a mixed alkali metal in which lithium is the major constituent; M1 is nickel in oxidation state +2 M2 comprises a metal in illation state +4 selected from one or more of manganese, titanium and zirconium; M3 comprises a metal in oxidation state +2, selected from one or more of magnesium, calcium, copper, zinc and cobalt; M4 comprises a metal in oxidation state +4, selected from one or more of titanium, manganese and zirconium; M5 comprises a metal in oxidation state +3, selected from one or more of aluminium, iron, cobalt, molybdenum, chromium, vanadium, scandium and yttrium; wherein 0???0.1; V is in the range 0<V<0.5; W is in the range 0<W?0.5; X is in the range 0?X<0.5; Y is in the range 0?Y<0.5; Z is ?0; wherein when M5=cobalt then X?0.1; and further wherein V+W+X+Y+Z=1. Such materials are useful, for example, as electrode materials in lithium ion battery applications.
    Type: Application
    Filed: July 10, 2013
    Publication date: May 21, 2015
    Inventors: Jeremy Barker, Richard Heap
  • Publication number: 20150137029
    Abstract: The present invention aims to provide an electrode mixture which shows little change in viscosity even after 24 hours from the preparation of the mixture and enables production of an electrode having a high electrode density and excellent flexibility and is capable of giving excellent electric properties to the resulting cell. The present invention relates to an electrode mixture including a powdery electrode material; a binder; and an organic solvent, the binder including a fluorine-containing polymer including a polymer unit based on vinylidene fluoride and a polymer unit based on tetrafluoroethylene, the fluorine-containing polymer including the polymer unit based on vinylidene fluoride in an amount of 80.0 to 89.0 mol % based on all the polymer units, and the organic solvent being N-methyl-2-pyrolidone and/or N,N-dimethylacetamide.
    Type: Application
    Filed: May 20, 2013
    Publication date: May 21, 2015
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Toshiki Ichisaka, Takashi Iguchi, Tomoyuki Fukatani, Kazunobu Uchida, Takuji Ishikawa, Norimasa Uesugi, Takahiro Kitahara
  • Publication number: 20150137028
    Abstract: The present invention aims to provide an electrode mixture which shows little change in viscosity even after 24 hours from the preparation of the mixture and enables production of an electrode having a high electrode density and excellent flexibility and is capable of giving excellent electric properties to the resulting cell. The present invention relates to an electrode mixture including a powdery electrode material; a binder; and an organic solvent, the binder including polyvinylidene fluoride and a fluorine-containing polymer including a polymer unit based on vinylidene fluoride and a polymer unit based on tetrafluoroethylene, the fluorine-containing polymer including the polymer unit based on vinylidene fluoride in an amount of 80.0 to 90.0 mol % based on all the polymer units, the polyvinylidene fluoride having a number average molecular weight of 150,000 to 1,400,000.
    Type: Application
    Filed: May 20, 2013
    Publication date: May 21, 2015
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Toshiki Ichisaka, Takashi Iguchi, Tomoyuki Fukatani, Kazunobu Uchida, Takuji Ishikawa, Norimasa Uesugi, Takahiro Kitahara
  • Patent number: 9034521
    Abstract: Provided is an anode material for an electrode mix comprising a carbon material and a lithium titanium oxide (LTO), wherein a ratio of an average particle size of LTO relative to that of the carbon material is in a range of 0.1 to 20%, and LTO is distributed mainly on a surface of the carbon material. The anode material of the present invention can prevent excessive formation of a SEI film, and is of a high capacity due to a high energy density and exhibits excellent output characteristics and rate characteristics. Further, it has superior electrolyte wettability which consequently results in improved battery performance and life characteristics.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: May 19, 2015
    Assignee: LG CHEM, LTD.
    Inventors: Eun Ju Lee, Ji Heon Ryu, Inchul Kim, HanHo Lee
  • Publication number: 20150129810
    Abstract: A method is described for manufacturing a polyacrylonitrile-sulfur composite material, including the following method steps: a) providing a matrix material; b) optionally adding sulfur to the matrix material; c) adding polyacrylonitrile to the matrix material to produce a mixture made of sulfur and polyacrylonitrile; and d) reacting sulfur and polyacrylonitrile. A composite material manufactured in this way may be used in particular as an active material of a cathode of a lithium-ion battery and offers a particularly high rate capacity. In addition, methods are provided for manufacturing an active material for an electrode.
    Type: Application
    Filed: April 26, 2013
    Publication date: May 14, 2015
    Applicant: Robert Bosch GmbH
    Inventors: Martin Tenzer, Jean Fanous
  • Publication number: 20150132623
    Abstract: According to one embodiment, a non-aqueous electrolyte battery is provided. The non-aqueous electrolyte battery includes a negative electrode contained a negative electrode active material. The negative electrode active material includes a monoclinic ?-type titanium-based oxide or lithium titanium-based oxide. The monoclinic ?-type titanium-based oxide or lithium titanium-based oxide has a peak belonging to (011), which appears at 2?1 in a range of 24.40° or more and 24.88° or less, in an X-ray diffraction pattern obtained by wide angle X-ray diffractometry using CuK? radiation as an X-ray source.
    Type: Application
    Filed: January 23, 2015
    Publication date: May 14, 2015
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Hiroki INAGAKI, Norio Takami
  • Publication number: 20150132652
    Abstract: [Summary] A positive electrode active material is provided to contain: a solid solution lithium-containing transition metal oxide (A) represented by Li1.5[NiaCobMnc[Li]dO3 (where a, h, c and d satisfy the relations of a+b+c+d=1.5, 0.1<d?0.4, 1.1?a+b+c<1.4, 0.2?a?0.7 and 0<b/a<1); and a lithium-containing transition metal oxide (B) represented by LiMXMn2-XO4 (where M represents Cr or Al, and x satisfies the relation of 0?x<2).
    Type: Application
    Filed: March 6, 2013
    Publication date: May 14, 2015
    Applicant: NISSAN MOTOR CO., LTD.
    Inventors: Atsushi Ito, Shinji Yamamoto
  • Publication number: 20150132644
    Abstract: Provided is a negative electrode slurry composition including a binder resin, a water-soluble polymer, and a negative electrode active material, wherein the binder resin including (A) a styrene-butadiene copolymer latex having a gel amount of 70 to 98% and having a glass transition temperature in dynamic viscoelasticity measurement with a single peak at ?30° C. to 60° C. and (B) a polymer latex formed of a hetero-phase structure having a glass transition temperature in dynamic viscoelasticity measurement with at least one peak at ?100° C. to 10° C. and having a glass transition temperature in dynamic viscoelasticity measurement with at least one peak at 10° C. to 100° C., and the negative electrode active material including a carbon-based active material and a silicon-based active material.
    Type: Application
    Filed: June 6, 2013
    Publication date: May 14, 2015
    Applicant: ZEON CORPORATION
    Inventors: Kenya Sonobe, Naoki Takahashi, Norikazu Yamamoto, Yusuke Adachi
  • Publication number: 20150132647
    Abstract: [Problem] Provided is a slurry composition which has an excellent viscosity stability and thus, after being applied to a current collector for an electrode and drying, has an excellent adhesion with the current collector. [Solving Means] A slurry composition which is used for manufacturing an electrode for an electrochemical cell contains a lithium ion, comprising a polymer binder resin, a pH adjusting agent, and an active material, wherein the pH is from 2.0 to 9.0.
    Type: Application
    Filed: November 12, 2014
    Publication date: May 14, 2015
    Applicant: TAIYO INK MFG. CO., LTD.
    Inventor: Fumitaka KATO
  • Publication number: 20150132656
    Abstract: [Problem] Provided is a slurry composition which has an excellent viscosity stability and thus, after being applied to a current collector for an electrode and drying, has an excellent adhesion with the current collector. [Solving Means] A slurry composition which is used for manufacturing an electrode for an electrochemical cell contains a lithium ion, comprising a polymer binder resin, an acid, and an active material.
    Type: Application
    Filed: November 12, 2014
    Publication date: May 14, 2015
    Applicant: TAIYO INK MFG. CO., LTD.
    Inventor: Fumitaka KATO
  • Publication number: 20150129797
    Abstract: A production method of a battery active material of the present embodiment includes a step of obtaining a coprecipitated product containing Ti and Nb by mixing a solution with a pH of 5 or lower, in which a Ti compound is dissolved, and a solution with a pH of 5 or lower, in which a Nb compound is dissolved, such that molar ratio of Ti and Nb (Nb/Ti) is adjusted within a range of 1?Nb/Ti?28, and then further mixing with an alkali solution with a pH of 8 or higher; and a step of burning the coprecipitated product under condition of 635° C. or higher and 1200° C. or lower.
    Type: Application
    Filed: November 6, 2014
    Publication date: May 14, 2015
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Kazuki ISE, Yasuhiro HARADA, Norio TAKAMI
  • Patent number: 9029014
    Abstract: An anode includes an anode active material including a lithium titanium oxide, a binder, and 0 to about 2 parts by weight of a carbon-based conductive agent based on 100 parts by weight of the lithium titanium oxide.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: May 12, 2015
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Min-sang Song, Kyu-sung Park, Gue-sung Kim, Soo-an Song, Jae-hyung Kim, Ji-yong Eom, Seung-goo Baek
  • Patent number: 9028711
    Abstract: An inexpensive negative electrode material for a nonaqueous electrolyte secondary battery includes three types of powder materials: alloy material A; alloy material B; and a conductive material. Alloy material A includes a CoSn2 structure containing Co, Sn, and Fe and has an Sn content of at least 70.1 mass % and less than 82.0 mass %. Alloy material B includes Co3Sn2 and has a lower discharge capacity than alloy material A. The proportion RB of the mass of alloy material B based on the total mass of alloy material A and B is greater than 5.9% and less than 27.1%. The content of the conductive material is at least 7 mass % and at most 20 mass % based on the total mass of alloy material A and B, and the conductive material. The exotherm starting temperature for the negative electrode material is less than 375.4° C.
    Type: Grant
    Filed: April 25, 2011
    Date of Patent: May 12, 2015
    Assignees: Nippon Steel & Sumitomo Metal Corporation, Chuo Denki Kogyo Co., Ltd.
    Inventors: Noriyuki Negi, Tatsuo Nagata, Sukeyoshi Yamamoto
  • Patent number: 9028710
    Abstract: The invention is directed to a pulverulent compound of the formula NiaM1bM2cOx(OH)y where M1 is at least one element selected from the group consisting of Fe, Co, Zn, Cu and mixtures thereof, M2 is at least one element selected from the group consisting of Mn, Al, Cr, B, Mg, Ca, Sr, Ba, Si and mixtures thereof, 0.3?a?0.83, 0.1?b?0.5, 0.01?c?0.5, 0.01?x?0.99 and 1.01?y?1.99, wherein the ratio of tapped density measured in accordance with ASTM B 527 to the D50 of the particle size distribution measured in accordance with ASTM B 822 is at least 0.2 g/cm3·?m. The invention is also directed to a method for the production of the pulverulent compound and the use as a precursor material for producing lithium compounds for use in lithium secondary batteries.
    Type: Grant
    Filed: July 23, 2008
    Date of Patent: May 12, 2015
    Assignee: H.C. Starck GmbH
    Inventors: Matthias Jahn, Gerd Maikowske, Stefan Malcus, Juliane Meese-Marktscheffel, Armin Olbrich, Rüdiger Zertani
  • Publication number: 20150125751
    Abstract: To simply manufacture a lithium-containing oxide at lower manufacturing cost. A method for manufacturing a lithium-containing composite oxide expressed by a general formula LiMPO4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)). A solution containing Li and P is formed and then is dripped in a solution containing M (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) to form a mixed solution. By a hydrothermal method using the mixed solution, a single crystal particle of a lithium-containing composite oxide expressed by the general formula LiMPO4 (M is one or more of Fe (II), Mn (II), Co (II), and Ni (II)) is manufactured.
    Type: Application
    Filed: January 13, 2015
    Publication date: May 7, 2015
    Inventor: Tomoya FUTAMURA
  • Publication number: 20150123029
    Abstract: The present invention provides a positive electrode active material for lithium ion batteries, which realizes a lithium ion battery that is, while satisfying fundamental characteristics of a battery (capacity, efficiency, load characteristics), low in the resistance and excellent in the lifetime characteristics. In the positive electrode active material for lithium ion batteries, the variation in the composition of transition metal that is a main component inside of particles of or between particles of the positive electrode active material, which is defined as a ratio of the absolute value of the difference between a composition ratio inside of the particles of or in a small area between the particles of the transition metal and a composition ratio in a bulk state to the composition ratio in a bulk state of the transition metal, is 5% or less.
    Type: Application
    Filed: December 23, 2014
    Publication date: May 7, 2015
    Inventors: Ryuichi Nagase, Yasuhiro Kawahashi
  • Publication number: 20150123028
    Abstract: The invention provides electrode active materials comprising lithium or other alkali metals, manganese, a +3 oxidation state metal ion, and optionally other metals, and a phosphate moiety. Such electrode active materials include those of the formula: AaMnbMIcMIIdMIIIePO4 wherein (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0<a<1; (b) 0<b<1; (c) MI is a metal ion in the +3 oxidation state, and 0<c<0.5; (d) MII is metal ion, a transition metal ion, a non-transition metal ion or mixtures thereof, and 0<d<0.5; (e) MIII is a metal ion in the +1 oxidation state and 0<e<0.5; and wherein A, Mn, MI, MII, MIII, PO4, a, b, c, d and e are selected so as to maintain electroneutrality of said compound.
    Type: Application
    Filed: November 5, 2013
    Publication date: May 7, 2015
    Applicant: VALENCE TECHNOLOGY INC
    Inventors: Haitao Huang, M. Yazid Saidi
  • Publication number: 20150125746
    Abstract: Provided is a negative electrode slurry composition including a binder resin, a water-soluble polymer, and a negative electrode active material, wherein the binder resin including (A) a styrene-butadiene copolymer latex having a gel amount of 70 to 98% and a glass transition temperature of ?30° C. to 60° C. in dynamic viscoelasticity measurement and (B) an acryl polymer latex having a gel amount of 70 to 98% and a glass transition temperature of ?100° C. to 0° C. in dynamic viscoelasticity measurement, and the negative electrode active material including a carbon-based active material and a silicon-based active material.
    Type: Application
    Filed: June 21, 2013
    Publication date: May 7, 2015
    Applicant: ZEON CORPORATION
    Inventors: Kenya Sonobe, Naoki Takahashi, Norikazu Yamamoto, Yusuke Adachi
  • Publication number: 20150125747
    Abstract: The present disclosure relates to a binder solution for an anode, comprising a thermally cross-linkable polymer binder that is cross-linked by heat, and a solvent for dissolving the thermally cross-linkable polymer binder, and exhibiting a concentration of hydrogen ions corresponding to pH 2.5 to pH 4.5; an active material slurry for an anode, comprising the binder solution; an anode using the slurry; and an electrochemical device comprising the anode. The binder solution for an anode according to one aspect of the present disclosure can relieve the volume expansion of an anode active material by the intercalation and disintercalation of lithium during cycles of electrochemical devices to improve the durability of an anode active material layer, thereby enhancing the life characteristics of the electrochemical devices, and also can provide good dispersibility to the active material slurry for an anode, thereby improving the coating stability of an anode active material layer.
    Type: Application
    Filed: January 7, 2015
    Publication date: May 7, 2015
    Applicant: LG CHEM, LTD.
    Inventors: Ji-Hye Yang, Jang-Bae Kim, Byoung-Bae Lee
  • Publication number: 20150125755
    Abstract: Composite particles for electrochemical device electrode comprising a first particle-shaped binder with a glass transition temperature of 5° C. or less, a second particle-shaped binder with a glass transition temperature of 10 to 80° C. and with a gel content of 70 wt % or more, and an electrode active material, wherein a ratio of content of said second particle-shaped binder is 30 to 95 wt % in the total binder which is contained in said composite particles for electrochemical device electrode, are provided.
    Type: Application
    Filed: May 29, 2013
    Publication date: May 7, 2015
    Applicant: ZEON CORPORATION
    Inventor: Takuya Ishii
  • Publication number: 20150125753
    Abstract: A battery active material according to an embodiment includes a niobium composite oxide and a phosphorus compound being present in at least a part of the surface of the niobium composite oxide. A nonaqueous electrolyte battery according to the embodiment includes a negative electrode including the battery active material according to the embodiment, a positive electrode, and a nonaqueous electrolyte. A battery pack according to the embodiment includes at least one nonaqueous electrolyte battery according to the embodiment.
    Type: Application
    Filed: October 30, 2014
    Publication date: May 7, 2015
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Hiroki INAGAKI, Takuya Iwasaki, Norio Takami
  • Patent number: 9023526
    Abstract: A positive active material for a rechargeable lithium battery includes pores having an average diameter of about 10 nm to about 60 nm and a porosity of about 0.5% to about 20%. Also disclosed is a method of preparing the positive active material, and a rechargeable lithium battery including the positive active material.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: May 5, 2015
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Yu-Mi Song, Do-Hyung Park, Seon-Young Kwon, Min-Han Kim, Ji-Hyun Kim, Kyoung-Hyun Kim
  • Patent number: 9023523
    Abstract: The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bMb1Fe1-cMc2Pd-eMe3Ox, wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state 0, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: May 5, 2015
    Assignee: BASF SE
    Inventors: Kirill Bramnik, Hartmut Hibst, Jordan Keith Lampert