Silicide Of Refractory Or Platinum Group Metal Patents (Class 257/757)
  • Publication number: 20130320543
    Abstract: A semiconductor device is manufactured by forming, on an insulating base material, a first support element having a side face that extends from a surface of the insulating base material, forming a coating of amorphous silicon on the side face of the first support element, filling an aperture disposed between the first support element and a second support element that extends from a surface of the insulating base material with an insulating film, planarizing the insulating film to expose an exposed portion of the coating and a surface of the first support element, and siliciding the amorphous silicon of the coating to form an interconnect.
    Type: Application
    Filed: March 7, 2013
    Publication date: December 5, 2013
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventor: Masakatsu TSUCHIAKI
  • Patent number: 8546945
    Abstract: A conductive pillar for a semiconductor device is provided. The conductive pillar is formed such that a top surface is non-planar. In embodiments, the top surface may be concave, convex, or wave shaped. An optional capping layer may be formed over the conductive pillar to allow for a stronger inter-metallic compound (IMC) layer. The IMC layer is a layer formed between solder material and an underlying layer, such as the conductive pillar or the optional capping layer.
    Type: Grant
    Filed: October 29, 2012
    Date of Patent: October 1, 2013
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Tin-Hao Kuo, Chen-Shien Chen, Ching-Wen Hsiao
  • Patent number: 8518819
    Abstract: A semiconductor contact structure and method provide contact structures that extend through a dielectric material and provide contact to multiple different subjacent materials including a silicide material and a non-silicide material such as doped silicon. The contact structures includes a lower composite layer formed using a multi-step ionized metal plasma (IMP) deposition operation. A lower IMP film is formed at a high AC bias power followed by the formation of an upper IMP film at a lower AC bias power. The composite layer may be formed of titanium. A further layer is formed as a liner over the composite layer and the liner layer may advantageously be formed using CVD and may be TiN. A conductive plug material such as tungsten or copper fills the contact openings.
    Type: Grant
    Filed: March 16, 2011
    Date of Patent: August 27, 2013
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Shih Chieh Chang, Chih-Chung Chang, Kei-Wei Chen, Ying-Lang Wang
  • Patent number: 8513807
    Abstract: Methods for forming ruthenium films and semiconductor devices such as capacitors that include the films are provided.
    Type: Grant
    Filed: February 28, 2012
    Date of Patent: August 20, 2013
    Assignee: Micron Technology, Inc.
    Inventors: Vishwanath Bhat, Dan Gealy, Vassil Antonov
  • Patent number: 8507996
    Abstract: An integrated circuit structure includes a semiconductor substrate; a gate stack overlying the semiconductor substrate; a gate spacer on a sidewall of the gate stack; a first contact plug having an inner edge contacting a sidewall of the gate spacer, and a top surface level with a top surface of the gate stack; and a second contact plug over and contacting the first contact plug. The second contact plug has a cross-sectional area smaller than a cross-sectional area of the first contact plug.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: August 13, 2013
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Sey-Ping Sun, Chih-Hao Chang, Chao-An Jong, Tsung-Lin Lee, Chung-Ju Lee, Chin-Hsiang Lin
  • Patent number: 8455044
    Abstract: Provided are a semiconductor film including silicon microstructures formed at high density, and a manufacturing method thereof. Further, provided are a semiconductor film including silicon microstructures whose density is controlled, and a manufacturing method thereof. Furthermore, a power storage device with improved charge-discharge capacity is provided. A manufacturing method in which a semiconductor film with a silicon layer including silicon structures is formed over a substrate with a metal surface is used. The thickness of a silicide layer formed by reaction between the metal and the silicon is controlled, so that the grain sizes of silicide grains formed at an interface between the silicide layer and the silicon layer are controlled and the shapes of the silicon structures are controlled. Such a semiconductor film can be applied to an electrode of a power storage device.
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: June 4, 2013
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Tomokazu Yokoi, Takayuki Inoue, Makoto Furuno
  • Patent number: 8456007
    Abstract: A titanium layer is formed on a substrate with chemical vapor deposition (CVD). First, a seed layer is formed on the substrate by combining a first precursor with a reducing agent by CVD. Then, the titanium layer is formed on the substrate by combining a second precursor with the seed layer by CVD. The titanium layer is used to form contacts to active areas of substrate and for the formation of interlevel vias.
    Type: Grant
    Filed: October 10, 2008
    Date of Patent: June 4, 2013
    Assignee: Round Rock Research, LLC
    Inventors: Gurtej Singh Sandhu, Donald L. Westmoreland
  • Patent number: 8395265
    Abstract: The present invention provides metal silicide nanowires, including metallic, semiconducting, and ferromagnetic semiconducting transition metal silicide nanowires. The nanowires are grown using either chemical vapor deposition (CVD) or chemical vapor transport (CVT) on silicon substrates covered with a thin silicon oxide film, the oxide film desirably having a thickness of no greater than about 5 nm and, desirably, no more than about 2 nm (e.g., about 1-2 nm). The metal silicide nanowires and heterostructures made from the nanowires are well-suited for use in CMOS compatible wire-like electronic, photonic, and spintronic devices.
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: March 12, 2013
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Song Jin, Andrew L. Schmitt, Yipu Song
  • Patent number: 8378490
    Abstract: A method of integrated circuit fabrication is provided, and more particularly fabrication of a semiconductor apparatus with a metallic alloy. An exemplary structure for a semiconductor apparatus comprises a first silicon substrate having a first contact comprising a silicide layer between the substrate and a first metal layer; a second silicon substrate having a second contact comprising a second metal layer; and a metallic alloy between the first metal layer of the first contact and the second metal layer of the second contact.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: February 19, 2013
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chyi-Tsong Ni, I-Shi Wang, Hsin-Kuei Lee, Ching-Hou Su
  • Patent number: 8368219
    Abstract: A buried local interconnect and method of forming the same counterdopes a region of a doped substrate to form a counterdoped isolation region. A hardmask is formed and patterned on the doped substrate, with a recess being etched through the patterned hardmask into the counterdoped region. Dielectric spacers are formed on the sidewalls of the recess, with a portion of the bottom of the recess being exposed. A metal is then deposited in the recess and reacted to form silicide at the bottom of the recess. The recess is filled with fill material, which is polished. The hardmask is then removed to form a silicide buried local interconnect.
    Type: Grant
    Filed: October 26, 2011
    Date of Patent: February 5, 2013
    Assignees: Advanced Micro Devices, Inc., Spansion LLC
    Inventors: Arvind Halliyal, Zoran Krivokapic, Matthew S. Buynoski, Nicholas H. Tripsas, Minh Van Ngo, Mark T. Ramsbey, Jeffrey A. Shields, Jusuke Ogura
  • Patent number: 8349730
    Abstract: An integrated circuit structure and methods for forming the same are provided. The integrated circuit structure includes a semiconductor substrate; a dielectric layer over the semiconductor substrate; an opening in the dielectric layer; a conductive line in the opening; a metal alloy layer overlying the conductive line; a first metal silicide layer overlying the metal alloy layer; and a second metal silicide layer different from the first metal silicide layer on the first metal silicide layer. The metal alloy layer and the first and the second metal silicide layers are substantially vertically aligned to the conductive line.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: January 8, 2013
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chien-Hsueh Shih, Shau-Lin Shue
  • Patent number: 8344511
    Abstract: To provide a semiconductor device which can reduce an electrical resistance between a plug and a silicide region, and a manufacturing method thereof. At least one semiconductor element having a silicide region, is formed over a semiconductor substrate. An interlayer insulating film is formed over the silicide region. A through hole having an inner surface including a bottom surface comprised of the silicide regions is formed in the interlayer insulating film. A Ti (titanium) film covering the inner surface of the hole is formed by a chemical vapor deposition method. At least a surface of the Ti film is nitrided so as to forma barrier metal film covering the inner surface. A plug is formed to fill the through hole via the barrier metal film.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: January 1, 2013
    Assignee: Renesas Electronics Corporation
    Inventors: Kazuhito Ichinose, Yukari Imai
  • Patent number: 8334574
    Abstract: Semiconductor fabricating technology is provided, and particularly, a method of fabricating a semiconductor device improving a contact characteristic between a silicon layer including carbon and a metal layer during a process of fabricating a semiconductor device is provided. A semiconductor device including the silicon layer including carbon and the metal layer formed on the silicon layer is provided. A metal silicide layer is interposed between the silicon layer including carbon and the metal layer.
    Type: Grant
    Filed: June 10, 2010
    Date of Patent: December 18, 2012
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Joo-Sung Park, Se-Keun Park
  • Patent number: 8330234
    Abstract: In a semiconductor device, a gate electrode having a uniform composition prevents deviation in a work function. Controlling a Vth provides excellent operation properties. The semiconductor device includes an NMOS transistor and a PMOS transistor with a common line electrode. The line electrode includes electrode sections (A) and (B) and a diffusion barrier region formed over an isolation region so that (A) and (B) are kept out of contact. The diffusion barrier region meets at least one of: (1) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (A) is lower than the interdiffusion coefficient of the constituent element between electrode section (A) materials; and (2) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (B) is lower than the interdiffusion coefficient of the constituent element between electrode section (B) materials.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: December 11, 2012
    Assignee: NEC Corporation
    Inventor: Takashi Hase
  • Patent number: 8299549
    Abstract: A layer structure for the electrical contacting of a semiconductor component having integrated circuit elements and integrated connecting lines for the circuit elements, which is suitable in particular for use in a chemically aggressive environment and at high temperatures, i.e., in so-called “harsh environments,” and is simple to implement. This layer structure includes at least one noble metal layer, in which at least one bonding island is formed, the noble metal layer being electrically insulated from the substrate of the semiconductor component by at least one dielectric layer, and having at least one ohmic contact between the noble metal layer and an integrated connecting line. The noble metal layer is applied directly on the ohmic contact layer.
    Type: Grant
    Filed: November 23, 2010
    Date of Patent: October 30, 2012
    Assignee: Robert Bosch GmbH
    Inventors: Jochen Reinmuth, Peter Schmollngruber, Hans Artmann
  • Patent number: 8288828
    Abstract: A via contact is provided to a diffusion region at a top surface of a substrate which includes a single-crystal semiconductor region. The via contact includes a first layer which consists essentially of a silicide of a first metal in contact with the diffusion region at the top surface. A dielectric region overlies the first layer, the dielectric region having an outer surface and an opening extending from the outer surface to the top surface of the substrate. A second layer lines the opening and contacts the top surface of the substrate in the opening, the second layer including a second metal which lines a sidewall of the opening and a silicide of the second metal which is self-aligned to the top surface of the substrate in the opening. A diffusion barrier layer overlies the second layer within the opening. A third layer including a third metal overlies the diffusion barrier layer and fills the opening.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: October 16, 2012
    Assignee: International Business Machines Corporation
    Inventors: Michael M. Iwatake, Kevin E. Mello, Matthew W. Oonk, Amanda L. Piper, Yun Y. Wang, Keith K. Wong
  • Publication number: 20120235301
    Abstract: A method of integrated circuit fabrication is provided, and more particularly fabrication of a semiconductor apparatus with a metallic alloy. An exemplary structure for a semiconductor apparatus comprises a first silicon substrate having a first contact comprising a silicide layer between the substrate and a first metal layer; a second silicon substrate having a second contact comprising a second metal layer; and a metallic alloy between the first metal layer of the first contact and the second metal layer of the second contact.
    Type: Application
    Filed: March 15, 2011
    Publication date: September 20, 2012
    Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.
    Inventors: Chyi-Tsong NI, I-Shi WANG, Hsin-Kuei LEE, Ching-Hou SU
  • Patent number: 8247323
    Abstract: A silicide film is formed between a ferroelectric capacitor structure, which is formed by sandwiching a ferroelectric film between a lower electrode and an upper electrode, and a conductive plug (the conductive material constituting the plug is tungsten (W) for example). Here, an example is shown in which a base film of the conductive plug is the silicide film.
    Type: Grant
    Filed: April 15, 2010
    Date of Patent: August 21, 2012
    Assignee: Fujitsu Semiconductor Limited
    Inventors: Hideaki Kikuchi, Kouichi Nagai
  • Publication number: 20120161324
    Abstract: When forming a metal silicide within contact openings in complex semiconductor devices, a silicidation of sidewall surface areas of the contact openings may be initiated by forming a silicon layer therein, thereby reducing unwanted diffusion of the refractory metal species into the laterally adjacent dielectric material. In this manner, superior reliability and electrical performance of the resulting contact elements may be achieved on the basis of a late silicide process.
    Type: Application
    Filed: August 12, 2011
    Publication date: June 28, 2012
    Applicant: GLOBALFOUNDRIES INC.
    Inventors: Jens Heinrich, Kai Frohberg, Katrin Reiche
  • Publication number: 20120135302
    Abstract: Provided are a semiconductor film including silicon microstructures formed at high density, and a manufacturing method thereof. Further, provided are a semiconductor film including silicon microstructures whose density is controlled, and a manufacturing method thereof Furthermore, a power storage device with improved charge-discharge capacity is provided. A manufacturing method in which a semiconductor film with a silicon layer including silicon structures is formed over a substrate with a metal surface is used. The thickness of a silicide layer formed by reaction between the metal and the silicon is controlled, so that the grain sizes of silicide grains formed at an interface between the silicide layer and the silicon layer are controlled and the shapes of the silicon structures are controlled. Such a semiconductor film can be applied to an electrode of a power storage device.
    Type: Application
    Filed: November 21, 2011
    Publication date: May 31, 2012
    Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
    Inventors: Tomokazu Yokoi, Takayuki Inoue, Makoto Furuno
  • Publication number: 20120126343
    Abstract: Structures and methods of forming self aligned silicided contacts are disclosed. The structure includes a gate electrode disposed over an active area, a liner disposed over the gate electrode and at least a portion of the active area, an insulating layer disposed over the liner. A first contact plug is disposed in the insulating layer and the liner, the first contact plug disposed above and in contact with a portion of the active area, the first contact plug including a first conductive material. A second contact plug is disposed in the insulating layer and the liner, the second contact plug disposed above and in contact with a portion of the gate electrode, the second contact plug includes the first conductive material. A contact material layer is disposed in the active region, the contact material layer disposed under the first contact plug and includes the first conductive material.
    Type: Application
    Filed: February 3, 2012
    Publication date: May 24, 2012
    Applicant: Infineon Technologies AG
    Inventor: Roland Hampp
  • Patent number: 8129844
    Abstract: Electronic devices and design structures of electronic devices containing metal silicide layers. The devices include: a thin silicide layer between two dielectric layers, at least one metal wire abutting a less than whole region of the silicide layer and in electrical contact with the silicide layer.
    Type: Grant
    Filed: June 20, 2008
    Date of Patent: March 6, 2012
    Assignee: International Business Machines Corporation
    Inventors: Felix Patrick Anderson, Zhong-Xiang He, Thomas Leddy McDevitt, Eric Jeffrey White
  • Patent number: 8101871
    Abstract: An electronic device bond pad includes an Al layer located over an electronic device substrate. The Al layer includes an intrinsic group 10 metal located therein.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: January 24, 2012
    Assignee: LSI Corporation
    Inventors: Frank A. Baiocchi, John M DeLucca, John W. Osenbach
  • Publication number: 20110278726
    Abstract: In one embodiment, a lower interlayer dielectric layer, and first and second landing pads penetrating the lower interlayer dielectric layer are formed on a substrate. Interconnection patterns covering the second landing pads are formed on the lower interlayer dielectric layer. An etch stop layer is formed over the interconnection patterns. An upper interlayer dielectric layer filling a gap region between the interconnection patterns is formed on the etch stop layer. The upper interlayer dielectric layer is patterned to form a preliminary contact hole between the interconnection patterns, where the etch stop layer is exposed at the bottom of the preliminary contact hole. The preliminary contact hole is extended and the etch stop layer exposed by the extended preliminary contact hole is removed to form a first contact hole exposing the first landing pad. A buried contact plug is then formed within the first contact hole.
    Type: Application
    Filed: July 29, 2011
    Publication date: November 17, 2011
    Applicant: Samsung Electronics Co., Ltd.
    Inventor: Si-Youn KIM
  • Patent number: 8049334
    Abstract: A buried local interconnect and method of forming the same counterdopes a region of a doped substrate to form a counterdoped isolation region. A hardmask is formed and patterned on the doped substrate, with a recess being etched through the patterned hardmask into the counterdoped region. Dielectric spacers are formed on the sidewalls of the recess, with a portion of the bottom of the recess being exposed. A metal is then deposited in the recess and reacted to form silicide at the bottom of the recess. The recess is filled with fill material, which is polished. The hardmask is then removed to form a silicide buried local interconnect.
    Type: Grant
    Filed: July 26, 2010
    Date of Patent: November 1, 2011
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Arvind Halliyal, Zoran Krivokapic, Matthew S. Buynoski, Nicholas H. Tripsas, Minh Van Ngo, Mark T. Ramsbey, Jeffrey A. Shields, Jusuke Ogura
  • Patent number: 8039378
    Abstract: To provide a technique capable of improving the reliability of a semiconductor element and its product yield by reducing the variations in the electrical characteristic of a metal silicide layer. After forming a nickel-platinum alloy film over a semiconductor substrate 1, by carrying out a first thermal treatment at a thermal treatment temperature of 210 to 310° C. using a heater heating device, the technique causes the nickel-platinum alloy film and silicon to react with each other to form a platinum-added nickel silicide layer in a (PtNi)2Si phase. Subsequently, after removing the unreacted nickel-platinum alloy film, the technique carries out a second thermal treatment having the thermal treatment temperature higher than that of the first thermal treatment to form the platinum-added nickel silicide layer in a PtNiSi phase. The temperature rise rate of the first thermal treatment is set to 10° C./s or more (for example, 30 to 250° C.
    Type: Grant
    Filed: January 23, 2009
    Date of Patent: October 18, 2011
    Assignee: Renesas Electronics Corporation
    Inventors: Shigenari Okada, Takuya Futase, Yutaka Inaba
  • Patent number: 8039391
    Abstract: A method of forming a contact in a semiconductor device provides a titanium contact layer in a contact hole and a MOCVD-TiN barrier metal layer on the titanium contact layer. Impurities are removed from the MOCVD-TiN barrier metal layer by a plasma treatment in a nitrogen-hydrogen plasma. The time period for plasma treating the titanium nitride layer is controlled so that penetration of nitrogen into the underlying titanium contact layer is substantially prevented, preserving the titanium contact layer for subsequently forming a titanium silicide at the bottom of the contact.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: October 18, 2011
    Assignees: Spansion LLC, Globalfoundries Inc.
    Inventors: Jinsong Yin, Wen Yu, Connie Pin-Chin Wang, Paul Besser, Keizaburo Yoshie
  • Publication number: 20110227227
    Abstract: A method for fabricating integrated circuit (ICs) having through substrate vias (TSVs) includes forming active circuit elements on a semiconductor wafer and then forming a plurality of embedded vias through the top side of the wafer. A metal filler layer including a filler metal is deposited to fill the embedded vias. Chemical mechanical polishing (CMP) then forms a plurality of embedded TSVs that have polished top TSV surfaces having exposed filler metal. An electrically conductive hillock suppression structure is formed by forming a silicon or germanium doped region, or a silicide or germanicide at the polished top TSV surface or by forming a metal layer on the polished top TSV surface having a composition different from the filler metal. A dielectric layer is deposited on the semiconductor wafer including over the hillock suppression structure. The dielectric layer is removed over the polished top TSV surface to allow metal contact thereto.
    Type: Application
    Filed: March 17, 2010
    Publication date: September 22, 2011
    Applicant: Texas Instruments Incorporated
    Inventor: Jeffrey Alan West
  • Patent number: 8021944
    Abstract: A method for fabricating a semiconductor device is disclosed. The method includes: forming a photoresist film on a semiconductor substrate including a silicide forming region and non-silicide forming region; forming a photoresist pattern as a non-salicide pattern by patterning the photoresist film, so as to cover the non-silicide forming region and open the silicide forming region, with an overhang structure that a bottom is removed more compared to a top; forming a metal film on a top of the photoresist pattern and overall the semiconductor substrate in the silicide forming region; stripping the photoresist pattern and the metal film on the photoresist pattern; and forming a silicide metal film by annealing the metal film remaining on the semiconductor substrate. Therefore, the present invention simplifies a salicide process of a semiconductor device, making it possible to improve yields.
    Type: Grant
    Filed: November 29, 2008
    Date of Patent: September 20, 2011
    Assignee: Dongbu HiTek Co., Ltd.
    Inventor: In-Cheol Baek
  • Patent number: 8022482
    Abstract: A trenched semiconductor power device includes a trenched gate insulated by a gate insulation layer and surrounded by a source region encompassed in a body region above a drain region disposed on a bottom surface of a semiconductor substrate. The source region surrounding the trenched gate includes a metal of low barrier height to function as a Schottky source. The metal of low barrier height further may include a PtSi or ErSi layer. In a preferred embodiment, the metal of low barrier height further includes an ErSi layer. The metal of low barrier height further may be a metal silicide layer having the low barrier height. A top oxide layer is disposed under a silicon nitride spacer on top of the trenched gate for insulating the trenched gate from the source region. A source contact disposed in a trench opened into the body region for contacting a body-contact dopant region and covering with a conductive metal layer such as a Ti/TiN layer.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: September 20, 2011
    Assignee: Alpha & Omega Semiconductor, Ltd
    Inventors: Yongzhong Hu, Sung-Shan Tai
  • Publication number: 20110198702
    Abstract: A semiconductor device manufacturing method which achieves a contact of a low resistivity is provided. In a state where a first metal layer in contact with a semiconductor is covered with a second metal layer for preventing oxidation, only the first metal layer is silicided to form a silicide layer with no oxygen mixed therein. As a material of the first metal layer, a metal having a work function difference of a predetermined value from the semiconductor is used. As a material of the second metal layer, a metal which does not react with the first metal layer at an annealing temperature is used.
    Type: Application
    Filed: October 23, 2009
    Publication date: August 18, 2011
    Inventors: Tadahiro Ohmi, Akinobu Teramoto, Tatsunori Isogai, Hiroaki Tanaka
  • Patent number: 7919845
    Abstract: Formation of a hybrid integrated circuit device is described. A design for the integrated circuit is obtained and separated into at least two portions responsive to component sizes. A first die is formed for a first portion of the hybrid integrated circuit device using at least in part a first minimum dimension lithography. A second die is formed for a second portion of the device using at least in part a second minimum dimension lithography, where the second die has the second minimum dimension lithography as a smallest lithography used for the forming of the second die. The first die and the second die are attached to one another via coupling interconnects respectively thereof to provide the hybrid integrated circuit device.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: April 5, 2011
    Assignee: Xilinx, Inc.
    Inventors: James Karp, Steven P. Young, Bernard J. New, Scott S. Nance, Patrick J. Crotty
  • Patent number: 7884477
    Abstract: A hard mask is formed on an interconnect structure comprising a low-k material layer and a metal feature embedded therein. A block polymer is applied to the hard mask layer, self-assembled, and patterned to form a polymeric matrix of a polymeric block component and containing cylindrical holes. The hard mask and the low-k material layer therebelow are etched to form cavities. A conductive material is plated on exposed metallic surfaces including portions of top surfaces of the metal feature to form metal pads. Metal silicide pads are formed by exposure of the metal pads to a silicon containing gas. An etch is performed to enlarge and merge the cavities in the low-k material layer. The metal feature is protected from the etch by the metal silicide pads. An interconnect structure having an air gap and free of defects to surfaces of the metal feature is formed.
    Type: Grant
    Filed: December 3, 2007
    Date of Patent: February 8, 2011
    Assignee: International Business Machines Corporation
    Inventors: Griselda Bonilla, Daniel C. Edelstein, Satyanarayana V. Nitta, Takeshi Nogami, Shom Ponoth, David L. Rath, Chih-Chao Yang
  • Publication number: 20110024864
    Abstract: A semiconductor device includes a through electrode penetrating a semiconductor substrate, a conductor pad formed on the through electrode and made of a conductor electrically connected to the through electrode, and an interconnection layer formed on a surface of the semiconductor substrate and electrically connected to the conductor pad.
    Type: Application
    Filed: August 10, 2010
    Publication date: February 3, 2011
    Applicant: PANASONIC CORPORATION
    Inventors: Noboru KOKUSENYA, Toshihiro KURIYAMA
  • Patent number: 7875976
    Abstract: In one aspect of the present invention, a semiconductor device may include a semiconductor substrate, a silicide layer provided on the semiconductor substrate, a dielectric layer provided on the semiconductor substrate, a contact layer provided on the silicide layer, a metal layer provided in the dielectric layer and electrically connected to the silicide layer via the contact layer, a diffusion barrier layer provided between the dielectric layer and the metal layer, wherein the contact layer includes a first metal element provided in the metal layer, a second metal element provided in the diffusion barrier layer and at least one of a third metal provided in the silicide layer and Si element.
    Type: Grant
    Filed: October 5, 2007
    Date of Patent: January 25, 2011
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Makoto Wada, Takamasa Usui, Kazuya Ohuchi
  • Patent number: 7875939
    Abstract: In an ohmic layer and methods of forming the ohmic layer, a gate structure including the ohmic layer and a metal wiring having the ohmic layer, the ohmic layer is formed using tungsten silicide that includes tungsten and silicon with an atomic ratio within a range of about 1:5 to about 1:15. The tungsten silicide may be obtained in a chamber using a reaction gas including a tungsten source gas and a silicon source gas by a partial pressure ratio within a range of about 1.0:25.0 to about 1.0:160.0. The reaction gas may have a partial pressure within a range of about 2.05 percent to about 30.0 percent of a total internal pressure of the chamber. When the ohmic layer is employed for a conductive structure, such as a gate structure or a metal wiring, the conductive structure may have a reduced resistance.
    Type: Grant
    Filed: May 1, 2009
    Date of Patent: January 25, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Hee-Sook Park, Gil-Heyun Choi, Chang-Won Lee, Byung-Hak Lee, Sun-Pil Youn, Dong-Chan Lim, Jae-Hwa Park, Jang-Hee Lee, Woong-Hee Sohn
  • Patent number: 7861406
    Abstract: Methods and associated structures of forming a microelectronic device are described. Those methods may include amorphizing at least one contact area of a source/drain region of a transistor structure by implanting through at least one contact opening, forming a first layer of metal on the at least one contact area, forming a second layer of metal on the first layer of metal, selectively etching a portion of the second metal layer, annealing the at least one contact area to form at least one silicide, and removing the unreacted first metal layer and second metal layer from the transistor structure and forming a conductive material in the at least one contact opening.
    Type: Grant
    Filed: March 29, 2007
    Date of Patent: January 4, 2011
    Assignee: Intel Corporation
    Inventors: Saurabh Lodha, Pushkar Ranade, Christopher Auth
  • Patent number: 7863191
    Abstract: A first structure is formed, having a contact plug formed on the bottom of a first opening in an interlayer insulating film, a second opening formed through the interlayer insulating film to reach a semiconductor substrate, and a third opening formed through the interlayer insulating film to reach a polymetal gate electrode. A cobalt layer is deposited on the surface of the structure, and thermally treated to form a cobalt silicide layer on the surface of the contact plug and on the bottom face of the second opening. The structure is then treated to remove the cobalt, in the state in which the cobalt silicide layer is formed, with the use of a chemical solution capable of dissolving cobalt but not the polymetal.
    Type: Grant
    Filed: September 25, 2007
    Date of Patent: January 4, 2011
    Assignee: Elpida Memory, Inc.
    Inventor: Kenji Tanaka
  • Patent number: 7858518
    Abstract: A process for the in situ formation of a selective contact and a local interconnect on a semiconductor substrate. The exposed semiconductor substrate regions of a semiconductor device structure may be treated in a plasma to enhance the adhesiveness of a selective contact thereto. The semiconductor device structure is positioned within a reaction chamber, wherein a selective contact is deposited onto the exposed semiconductor substrate regions. Any residual selective contact material may be removed from oxide surfaces either intermediately or after selective contact deposition. While the semiconductor device remains in the reaction chamber, a local interconnect is deposited over the semiconductor device structure. The local interconnect may then be patterned. Subsequent layers may be deposited over the local interconnect. The present invention also includes semiconductor device structures formed by the inventive process.
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: December 28, 2010
    Assignee: Micron Technology, Inc.
    Inventors: Christopher W. Hill, Weimin Li, Gurtej S. Sandhu
  • Patent number: 7847401
    Abstract: A method (100) of forming semiconductor structures (202) including high-temperature processing steps (step 118), incorporates the use of a high-temperature nitride-oxide mask (220) over protected regions (214) of the device (202). The invention has application in many different embodiments, including but not limited to, the formation of recess, strained device regions (224).
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: December 7, 2010
    Assignee: Texas Instruments Incorporated
    Inventors: P R Chidambaram, Haowen Bu, Rajesh Khamankar, Douglas T Grider
  • Patent number: 7847410
    Abstract: An interconnect of the group III-V semiconductor device and the fabrication method for making the same are described. The interconnect includes a first adhesion layer, a diffusion barrier layer for preventing the copper from diffusing, a second adhesion layer and a copper wire line. Because a stacked-layer structure of the first adhesion layer/diffusion barrier layer/second adhesion layer is located between the copper wire line and the group III-V semiconductor device, the adhesion between the diffusion barrier layer and other materials is improved. Therefore, the yield of the device is increased.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: December 7, 2010
    Assignee: National Chiao Tung University
    Inventors: Cheng-Shih Lee, Edward Yi Chang, Huang-Choung Chang
  • Patent number: 7800226
    Abstract: A method for forming a metal silicide region in a silicon region of a semiconductor substrate. The method comprises forming a metal layer over the silicon region, then in succession forming a titanium and a titanium nitride layer thereover. As the substrate is heated to form the silicide, the titanium getters silicon dioxide on the surface of the silicon region and the titanium nitride promotes the formation of a smooth surface at the interface between the silicide layer and the underlying silicon region.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: September 21, 2010
    Assignee: Agere Systems Inc.
    Inventors: Yuanning Chen, Maxwell Walthour Lippitt, III, William M. Moller
  • Patent number: 7799682
    Abstract: By performing a silicidation process on the basis of a patterned dielectric layer, such as an interlayer dielectric material, the respective metal silicide portions may be provided in a highly localized manner at the respective contact regions, while the overall amount of metal silicide may be significantly reduced. In this way, a negative influence of the stress of metal silicide on the channel regions of field effect transistors may be significantly reduced, while nevertheless maintaining a low contact resistance.
    Type: Grant
    Filed: April 9, 2007
    Date of Patent: September 21, 2010
    Assignee: GlobalFoundries Inc.
    Inventors: Sven Beyer, Patrick Press, Thomas Feudel
  • Patent number: 7795690
    Abstract: The invention relates to a thin film transistor substrate for use in a liquid crystal display device and a method of fabricating the same, and an object is to provide a thin film transistor substrate which can ensure high reliability even though a low resistance metal is used in a material for a gate electrode and a predetermined wiring and a method of fabricating the same. A TFT substrate has a gate electrode in a multilayer structure configured of an AlN film as a nitrogen containing layer, an Al film as a main wiring layer and an upper wiring layer formed of an MoN film and an Mo film. On the gate electrode whose side surface inclines gently, a gate insulating film of excellent film quality is formed.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: September 14, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Katsunori Misaki
  • Patent number: 7786004
    Abstract: A method of manufacturing a semiconductor device includes forming a first conductive film on a semiconductor substrate via a first insulating film; forming a second conductive film on the first conductive film via a second insulating film; patterning the first and the second conductive films and the second insulating film to form a plurality of gate electrodes; filling a third insulating film between the plurality of gate electrodes; exposing an upper portion of the second conductive film by removing the third insulating film; covering surfaces of the exposed upper portion of the second conductive film with fluoride (F) or carbon (C) or oxygen (O); and forming a metal film on an upper surface of the second conductive film; and forming silicide layers on the upper portion of the second conductive films by thermally treating the metal film.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: August 31, 2010
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Jota Fukuhara
  • Patent number: 7777344
    Abstract: An integrated circuit structure and methods for forming the same are provided. The integrated circuit structure includes a semiconductor substrate; a dielectric layer over the semiconductor substrate; an opening in the dielectric layer; a conductive line in the opening; a metal alloy layer overlying the conductive line; a first metal silicide layer overlying the metal alloy layer; and a second metal silicide layer different from the first metal silicide layer on the first metal silicide layer. The metal alloy layer and the first and the second metal silicide layers are substantially vertically aligned to the conductive line.
    Type: Grant
    Filed: April 11, 2007
    Date of Patent: August 17, 2010
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chien-Hsueh Shih, Shau-Lin Shue
  • Patent number: 7755191
    Abstract: A semiconductor device includes a first copper-containing conductive film formed on a substrate, insulating films formed on the first copper-containing conductive film with a concave portion reaching the first copper-containing conductive film, a second barrier insulating film formed to cover the side wall of the concave portion of these insulating films, a second adhesive alloy film made of copper and a dissimilar element other than copper, and coming in contact with the first copper-containing conductive film at the bottom surface of the concave portion and in contact with the second barrier insulating film at the side wall of the concave portion to cover the inside wall of the concave portion, and a second copper-containing conductive film containing copper as a main component, and formed on the second adhesive alloy film in contact with the second adhesive alloy film to fill the concave portion.
    Type: Grant
    Filed: March 20, 2007
    Date of Patent: July 13, 2010
    Assignee: NEC Electronics Corporation
    Inventor: Akira Furuya
  • Patent number: 7750471
    Abstract: Methods and apparatus relating to a single silicon wafer having metal and alloy silicides are described. In one embodiment, two different silicides may be provided on the same wafer. Other embodiments are also disclosed.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: July 6, 2010
    Assignee: Intel Corporation
    Inventor: Pushkar Ranade
  • Publication number: 20100164110
    Abstract: The present invention provides metal silicide nanowires, including metallic, semiconducting, and ferromagnetic semiconducting transition metal silicide nanowires. The nanowires are grown using either chemical vapor deposition (CVD) or chemical vapor transport (CVT) on silicon substrates covered with a thin silicon oxide film, the oxide film desirably having a thickness of no greater than about 5 nm and, desirably, no more than about 2 nm (e.g., about 1-2 nm). The metal silicide nanowires and heterostructures made from the nanowires are well-suited for use in CMOS compatible wire-like electronic, photonic, and spintronic devices.
    Type: Application
    Filed: August 17, 2006
    Publication date: July 1, 2010
    Inventors: Song Jin, Andrew L. Schmitt, Yipu Song
  • Patent number: 7737557
    Abstract: In the present invention, a wiring layer comprises wirings respectively having different sheet resistance values, or a contact for connecting opposing wiring layers comprises contacts having different sheet resistance values respectively.
    Type: Grant
    Filed: October 3, 2006
    Date of Patent: June 15, 2010
    Assignee: Panasonic Corporation
    Inventor: Keisuke Kishishita