Abstract: A method for producing a coated glass or ceramic article having a surface formed primarily from silicates, comprising the steps of contacting the uncoated glass or ceramic article in a gaseous atmosphere at a pressure of at least 700 Tort with a silane and a carbon source for a sufficient time at a temperature of less than 35.degree. C. to form a coating on and in the glass surface, wherein the coating comprises a silicon-carbide-containing layer having a thickness of at least 100 angstroms and containing 35 to 55 atom % carbon, between 15 and 30% silicon, no more than 10% elements other than silicon, oxygen, and carbon, and the remainder oxygen. Glass and ceramic surfaces having the indicated compositions are also part of the invention.

Abstract: According to the invention, a durable hydrophilic adsorbed film is formed on the surface of a substrate including metals, glass, plastics and the like in which the substrate has a surface layer containing hydroxyl groups or imino groups. The film is formed by covalently bonding chemical absorbents of silane groups containing a pluralilty of chloro groups to the substrate surfaces. The substrate 1 such as glass or nylon is dipped and held in a non-aqueous solution containing fluorocarbon groups and hydrocarbon groups containing chemical absorbents of silane groups containing a plurality of chloro goups including SiCl.sub.4, Cl.sub.3 SiOSiCl.sub.3, HSiCl.sub.3 or Cl.sub.3 SiOSiCl.sub.2 OSiCl.sub.3. After taking out the substrate 1 from the solution, drying it in a low moisture or substantially moistureless atmosphere to remove said non-aqueous solvents, the substrate is exposed to the air. A hydrophilic adsorbed ultra-thin film is thus formed by a dehydrochlorination reaction.

Abstract: The height of protrusions formed during laser texturing a glass or glass-ceramic substrate is controlled by controlling the quench rate of the protrusions during resolidification. In an embodiment, the quench rate is controlled by heating the substrate during laser texturing. Heating can be initiated prior or subsequent to, or simultaneously with, initial exposure of the substrate surface to a pulsed, focused CO.sub.2 laser beam for texturing.

Abstract: A method of producing a cutting tool, comprising a substrate which has a roughened surface that presents a surface roughness of between 15 microinches R.sub.a and 125 microinches R.sub.a. A coating is applied to the roughened surface of the substrate by physical vapor deposition. A coated cutting tool having a low cobalt substrate and experiencing long tool life is also discussed.

Abstract: A process for roughening a metal surface is provided comprising applying a coating to the metal surface wherein the coating is a temporary barrier to an etchant attacking the metal surface and the coating is susceptible to the etchant gradually removing the coating, and then etching the coated metal surface with an aqueous bath containing the etchant effective to produce a roughened metal surface.

Abstract: A fabrication method for a diamond-coated cemented carbide cutting tool includes electrolytically etching the surface of a cemented carbide cutting tool with a NaOH or KOH aqueous solution or chemically etching the surface of the cemented carbide cutting tool with a KMnO.sub.4 +KOH aqueous solution, and depositing a diamond film on the cemented carbide cutting tool. A stronger etching effect than by using a Murakami solution can be achieved, and no poisonous material is included in the etchant. In addition, disposal of the waste etchant is made simpler, and the adhesion between the diamond film coating and the cemented carbide cutting tool can be strengthened.

Abstract: Efflorescence of building material, such as portland cement based building products, masonry, brick, concrete, and mortar, can be retarded by contacting the building material with polyvinylalcohol (PVOH). The PVOH may be dissolved in solvent, preferably water, and either applied to a surface of the building material, or added to the components that form the building material. The PVOH has a hydrolysis percentage above about 90%.

Abstract: A method of preparing electrodes is now described, which electrodes have enhanced adhesion of subsequently applied coatings combined with excellent coating service life. In the method, a substrate metal, such as a valve metal as represented by titanium, is provided with a highly desirable rough surface characteristic for subsequent coating application. This can be achieved by various operations including etching to ensure a roughened surface morphology. In subsequent operations, a barrier layer is provided on the surface of enhanced morphology. This may be achieved by operations including heating, as well as including thermal decomposition of a layer precursor. Subsequent coatings provide enhanced lifetime even in the most rugged commercial environments.

Abstract: A process for treating cutting tools to extend the useful duty cycles of the tools by immersing the tools to be treated in a bath of a solvent in sufficient amounts and at a temperature to remove contamination from the surface of the tools and to coat the tool surfaces with perfluoroethylene. The solvent and perfluoroethylene resin are circulated throughout the immersed tools for a time sufficient to coat the surfaces with polyfluoroethylene resin.

Abstract: This invention presents diamond coated tool member of high toughness exhibiting excellent diamond adhesion to the substrate. The green compacts of the usual Co and WC composition are subjected to primary sintering in a vacuum or in an inert gas atmosphere, followed by secondary sintering in a vacuum or in an inert gas atmosphere at a pressure in the range of 10-200 atmospheres at a temperature between the liquid formation temperature of Co and 1,500.degree. C. The as-sintered surfaces are subjected to chemical etching, followed by fine polishing in an ultrasonic bath held at room temperature or a temperature just below the boiling point. The cutting tool substrate having the polished surface is placed in a CVD reactor to deposit a diamond coating. The concentration profile of Co in the diamond coated tool member hus formed has a Co-deficient layer and a Co-gradient layer.

Abstract: The invention relates to methods of making an improved stimulation electrode for cardiac pacing and defibrillating. Specifically, the electrodes of the invention by virtue of the methods of manufacturing and using, demonstrate improved capabilities of stimulating and sensing neuromuscular tissues. The electrodes have enhanced electrically-accessible surface areas which are coated with oxides of valve and noble metals.

Abstract: The invention relates to a process for producing a strong bond between copper layers, which have been applied by means of thermal spraying of pulverulent copper or copper alloys, and ceramic. Fine copper powder having a mean particle diameter of .ltoreq.20 .mu.m is applied to the ceramic surface by means of thermal spraying.

Abstract: A method is described for grading the electrical field at the surface of an electrode by depositing a semiconductive coating thereon. An electrode substrate is powered at a preselected temperature and power. A mixture of gases is then passed through an electrical discharge to ionize at least a portion thereof to form the semiconductive coating on the surface of the electrode. Also described is the plasma enhanced chemical vapor deposition of a diamondlike carbon (DLC) film onto a substrate. A substrate is maintained at a preselected DLC forming temperature and is negatively biased at a first preselected voltage. A first gaseous mixture of hydrocarbons and argon is then passed through an electrical discharge to at least partially ionize the hydrocarbons to form DLC film on the substrate. The substrate is then negatively biased at a second preselected voltage lower than the first preselected voltage.

Abstract: The coated substrate product finds particular application in eyeglass and sunglass lenses, architectural glass, analytical instrument windows, automotive windshields and laser bar code scanners for use in retail stores and supermarkets. The product has greatly improved wear resistance for severe abrasive environments and comprises a substantially optically transparent substrate, a chemically vapor deposited first interlayer bonded to the substrate and a chemically vapor deposited outer layer of substantially optically transparent diamond-like carbon bonded to the interlayer and away from the substrate.

Abstract: The coated substrate product finds particular application in eyeglass and sunglass lenses, architectural glass, analytical instrument windows, automotive windshields and laser bar code scanners for use in retail stores and supermarkets. The product has greatly improved wear resistance for severe abrasive environments and comprises a substantially optically transparent substrate, one or more chemically vapor deposited interlayers bonded to the substrate and a chemically vapor deposited outer layer of optically transparent or substantially optically transparent hard and low friction material bonded to the interlayer and away from the substrate.

Abstract: A texture treatment for a carbon substrate of a magnetic disk or for a carbon overcoat layer of a magnetic disk is effective to prevent the generation of a stiction phenomenon between a magnetic head and the surface of a magnetic disk. The texture treatment for a carbon substrate or carbon overcoat of a magnetic disk involves the steps of: preparing the carbon disk surface; forming a catalytic material layer on the surface; and performing a heat treatment of the disks in an oxidizing atmosphere. Preferably, islands of catalytic material are formed on the surface by sputtering, and a laser heat treatment is used in an oxidizing atmosphere.

Abstract: A method for forming thin films of cubic boron nitride on substrates at low pressures and temperatures. A substrate is first coated with polycrystalline diamond to provide a uniform surface upon which cubic boron nitride can be deposited by chemical vapor deposition.The cubic boron nitride film is useful as a substitute for diamond coatings for a variety of applications in which diamond is not suitable. any tetragonal or hexagonal boron nitride.The cubic boron nitride produced in accordance with the preceding example is particularly well-suited for use as a coating for ultra hard tool bits and abrasives, especially those intended to use in cutting or otherwise fabricating iron.

Abstract: Selected portions of the orifice plate surfaces are formed to have wetting and non-wetting surface characteristics for minimizing the accumulation of residual ink on the outer surface of the plate and for enhancing the flow of supply ink to the orifices of the plate.

Abstract: The present invention provides highly durable electrodes for electrolysis, which are platinum group metal oxide-coated or composite oxide-coated Ti electrodes, comprising a sputtered film of a metal or an alloy consisting of at least one selected from the group of Ti, Zr, Nb and Ta to be transformed the metastable .beta. phase to the .alpha. phase in crystal structure by the heat treatment to prepare the active layer carried on the surface, as an intermediate layer at the interface between Ti substrate and electrocatalytic active layer, and method for preparation thereof. The electrodes allow stable electrolysis at low electrode potentials for long periods of time as highly durable electrodes for electrolysis, especially electrodes for oxygen evolution at high current density.

Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. An aqueous composition for forming the conditioner by contact with metal surfaces includes a water-soluble organic material selected from a phosphate ester, alcohol, fatty acid including mono-, di-, tri-, and polyacids; fatty acid derivatives such as salts, hydroxy acids, amides, esters, ethers and derivatives thereof; and mixtures thereof and at least one of the elements selected from zirconium, titanium, cerium, aluminum, iron, tin, vanadium, tantalum, niobium, molybdenum, tungsten, and hafnium in metallic or ionic form. In order to avoid formation of sludge in the aqueous lubricant and surface conditioner forming composition, the composition should contain as little as possible of materials containing phenanthrene rings, such as conventional surfactants made by ethoxylating rosin.

Abstract: A process for applying a uniformly adherent protective tantalum oxide coating on a portion of a ceramic glow plug for protecting the glow plug against the corrosive/erosive environment generated by the burning of alternative fuels in a diesel engine. The coating is tantalum oxide deposited on a silicon nitride glow plug by plasma spray deposition techniques.

Abstract: A method and composition for coating an automotive brake rotor to render it corrosion resistant without impeding the braking function of the rotor, includes cleaning the rotor and thereafter applying a coating composition thereto which composition includes an inorganic alkali metal-silicate binder and a finely divided metal admixed therewith.

Abstract: A method of making varistor chips is disclosed. A workpiece of varistor material is sliced into slices of varistor material. The slices are in turn diced to make the varistor chips. The chips are etched in an etchant such as dilute citric acid to remove from their surfaces varistor material damaged during the slicing and/or dicing operations. Otherwise, the damaged varistor material adversely affects the leakage current characteristics of the varistor chips.

Abstract: In a plasma-CVD method and apparatus, plasma is formed from a film material gas in a process chamber and, in the plasma, a film is deposited on a substrate disposed in the process chamber. Formation of the plasma from the material gas is performed by application of an rf-power prepared by effecting an amplitude modulation on a basic rf-power having a frequency in a range from 10 MHz to 200 MHz. A modulation frequency of the amplitude modulation is in a range from 1/1000 to 1/10 of the frequency of the basic rf-power. Alternatively, the rf-power is prepared by effecting on the basic rf-power a first amplitude modulation at a frequency in a range from 1/1000 to 1/10 of the frequency of the basic rf-power, and additionally effecting a second amplitude modulation on the modulated rf-power. A modulation frequency of the second amplitude modulation is in a range from 1/100 to 100 times the modulation frequency of the first amplitude modulation.

Abstract: Methods for producing an adherent diamond film on a cemented metal carbide substrate are disclosed. Particularly, the present invention discloses methods of preparing the surface of a cemented metal carbide surface such that an adherent polycrystalline diamond coating may be deposited thereon using CVD techniques. Cutting tool inserts produced from such adherent diamond film coated cemented metal carbide articles are also disclosed.

Abstract: A substrate free single crystal pyroelectric film particularly suited for use in rapid thermal response sensors is made from a single crystal substrate by a method including the steps of:(A) etching a pattern into the substrate;(B) epitaxially growing a highly oriented superconducting material into the etched pattern to fill the etched pattern,(C) epitaxially growing a highly oriented crystalline film of a pyroelectric material over the entire surface of the substrate, and(D) dissolving away the highly oriented superconducting material.

Abstract: A metal surface is now described having enhanced adhesion of subsequently applied coatings. The substrate metal of the article, such as a valve metal as represented by titanium, is provided with a highly desirable surface characteristic for subsequent coating application. This can be initiated by selection of a metal of desirable metallurgy and heat history, including prior heat treatment to provide surface grain boundaries which may be most readily etched. In subsequent etching operation, the surface is made to exhibit well defined, three dimensional grains with deep grain boundaries. Subsequently applied coatings, by penetrating into the etched intergranular valleys, are desirably locked onto the metal substrate surface and provide enhanced lifetime even in rugged commercial environments.

Abstract: A coating of resin and photoactive functionality is autodeposited from an emulsion onto a metallic substrate in order to selectively protect the substrate from corrosive environments such as etchant processes. An acid and oxidizing agent are included in the emulsion so that when the substrate is immersed in the emulsion the resin and photoactive functionality autodeposits. The resulting coating can be exposed to actinic radiation in an image-wise fashion and developed in an alkaline solution to develop the image created. In instances where the emulsion and process are used to make circuit boards, the metallic surface uncovered during developing is then etched away, leaving only the coated sections of the surface. The resulting coated surfaces will be the circuit traces of the circuit board.

Abstract: Cement compositions and processes for improving the bond between new hydrating cement-based materials and the surface of "old" cement-based substrates are disclosed. A mechanically and chemically integral bond is created between the surfaces of the cement-based materials by moistening the old cement-based surface, exposing the moist surface to carbon or carbonate sources (such as with carbon dioxide) and then applying a new hydrating cement-based material thereon. The treatment of the surface of the cement-based substrate as described above creates an aqueous phase chemistry thereon which is compatible to the aqueous phase chemistry of the hydrating cement-based materials applied thereafter. The compatibility of the aqueous phase chemistries results in a mechanically and chemically integral bond formed between the surface of the old cement-based surface and the hydrating cement-based materials.

Abstract: A method and apparatus for continuous galvanizing of a linear element wherein controlled flow of molten zinc onto the linear element is effected through one or more nozzles, whereby galvanizing may be accomplished without immersion of the linear element in molten zinc. In a preferred embodiment, the apparatus of the invention comprises an annular nozzle having a central opening through which the linear element is axially advanced. The nozzle is configured to provide a converging, generally frustoconical curtain of molten zinc flowing continuously onto the exterior surface of the linear element.

Abstract: Metal bonded carbon fiber-reinforced composites are disclosed in which the metal and the composite are strongly bound by (1) providing a matrix-depleted zone in the composite of sufficient depth to provide a binding site for the metal to be bonded and then (2) infiltrating the metal into the matrix-free zone to fill a substantial portion of the zone and also provide a surface layer of metal, thereby forming a strong bond between the composite and the metal. The invention also includes the metal-bound composite itself, as well as the provision of a coating over the metal for high-temperature performance or for joining to other such composites or to other substrates.

Abstract: The surface of a partially manufactured integrated circuit is cleaned by successive immersions in a series of specially formulated baths. Metallic films deposited on surfaces that have been cleaned in this manner do not exhibit subsequent peeling or blistering and have low electrical contact resistance to the surface onto which they were deposited.

Abstract: The present invention relates to methods for producing self-supporting ceramic and ceramic composite bodies having a protective surface region on at least a portion of the surface of the formed bodies, and bodies produced thereby. The protective surface region is formed upon reaction of at least two components of the ceramic or ceramic composite body.

Abstract: A lubricant and surface conditioner for formed metal surfaces, particularly aluminum and tin beverage containers, reduces the coefficient of static friction of said metal surfaces and enables drying said metal surfaces at a lower temperature. The conditioner includes a water-soluble organic material selected from alkoxylated or non-alkoxylated castor oil triglycerides and hydrogenated castor oil derivatives; alkoxylated and nonoalkoxylated amine salts of a fatty acid including mono-, di-, tri-, and poly-acids; alkoxylated and non-alkoxylated amino fatty acids; alkoxylated and non-alkoxylated fatty amine N-oxides, alkoxylated and non-alkoxylated quaternary ammonium salts, oxa-acid esters, and water-soluble alkoxylated and non-alkoxylated polymers.

Abstract: A method of manufacturing a silicon single crystal substrate with the back surface thereof having deposited polycrystalline silicon. The method includes steps of depositing polycrystalline silicon on a coarsely polished silicon single crystal substrate, mirror surface finish polishing one substrate surface and carrying out a high temperature thermal treatment. The thermal treatment is carried out either prior or subsequent to the polycrystalline silicon deposition step. The thermal treatment has the effects of causing diffusion of interstitial oxygen Oi from the substrate surface to the outside and also causing contraction and vanishing of Oi precipitation nuclei in the substrate.

Abstract: A water- and oil-repelling adsorbing film formed on a material having active hydrogen such as hydroxyl group, imino group and amino group at the surface. This film is a chemically adsorbed film having surface irregularities exceeding 10 nanometers. It is directly or indirectly covalently bonded to the material surface and includes a monomolecular film or a polymer film with the molecules thereof containing a fluorocarbon group and a --Si-- bond. The surface irregularities which exceed the molecular level are at least either those formed on the material surface itself, those due to particles formed on the substrate surface or those due to particles present in the chemically adsorbed film.

Abstract: A process is disclosed for coating a ceramic composite in which the composite has a pattern of grooves cut into the surface followed by coating to increase adhesion and inhibit cracking of the coating.

Abstract: A method and product for improved ceramic fiber reinforced and/or filled thermoplastic and/or thermosetting resin systems utilizes ceramic fiber material which is first etched and then silanated using an organo-functional silane. The etching of the ceramic fiber may be performed utilizing hydrofluoric acid, acidulated phosphate fluoride or the equivalent thereof. The term ceramic fibers is used broadly to include all types of fibers which are made from substantially pure or pure silica, various silicates, metal oxides and other fibers, such as carbon, which are coated or provided with a silica treatment on their surface.

Abstract: A process is disclosed for coating fiber reinforced ceramic composites which has particular application for high temperature resistant composite materials for use in applications such as the aerospace industry. The process involves etching the surface to be coated with an etchant to expose the fiber in the ceramic composite while leaving the fiber intact and bound to the ceramic composite, followed by coating the etched surface with a coating composition.

Abstract: An improved process for improving the adhesion between a cemented carbide substrate and a diamond layer deposited thereon by removing the binder phase of the cemented material from the surface of the substrate prior to diamond coating. For this purpose, the process of the invention uses an apparatus as is conventionally used in various technologies for the CVD process of diamond layers. The process parameters are here altered from those of the conventional diamond coating in such a way that binder metal is evaporated from a very narrow boundary zone of the substrate surface, utilizing the reaction heat from the recombination of previously dissociated hydrogen gas directly at the substrate surface.

Abstract: The present invention relates to a method for the interconnection/repair of circuits on a transparent substrate at ambient temperature using laser induced chemical vapor deposition.

Abstract: A micromachine is lubricated in a fluid-based process. The known fluid-based process of releasing a sacrificial layer from a micromachine is followed by a fluid-based hydrophilic processing of the micromachine surfaces. A lubricating monolayer surface is then formed on the resultant hydrophilic micromachine surfaces. Afterwards, the surfaces are dried through conventional means.

Abstract: A silicon-base ceramic substrate is provided with a mullite coating by flame-spraying heated crystalline mullite powders onto a substrate that is preheated to a temperature in excess of 800.degree. C. The mullite immediately crystallizes as it solidifies.

Abstract: A highly reliable electrical component, a plurality of such electrical components, and a method for manufacturing the electrical component and the plurality thereof with high productivity are provided. The plurality involves a dielectric substrate including multiple separable chips. Each of the chips is provided with two parallel winding grooves, into which pasted copper is filled under a reduced pressure, dried and solidified to form electrical conductors. By connecting pins to ends of the electrical conductors, capacitors or noise filters are obtained. The plurality is manufactured, tested, packaged and transported, before being divided into separate chips for use.

Abstract: A method for treating orthopedic implants subject to wear and fatigue, and an orthopedic implant device treated in accordance with the described method. The orthopedic implant device is initially located in a reaction vessel. The outer surface of the orthopedic implant device is then subject to plasma nitriding so as to form a nitrogen enriched layer on the outer surface of the orthopedic implant device.

Abstract: A bath for pre-treatment of light metals that form oxide layers, before electroless (chemical) metal deposition is an aqueous bath containing phosphorous acid. The bath is used in the following process for electroless deposition of nickel: (1) Degreasing by boiling (2) Rinsing (3) Pickling (4) Rinsing (5) Treatment in aqueous bath containing phosphoric acid (6) Rinsing with water (7) Chemically nickel plating (8) Rinsing. The light metal articles are packed in a drum that is immersed and rotated in the pre-treatment bath. Current and voltage are applied to a light metal bar that is attached to a non-rotating place on the drum.

Abstract: Members with excellent water- and oil-repelling, and anti-contaminating properties are provided by exposing fillers partially protruding from the surfaces of fiber reinforced plastics or fiber reinforced metals and chemically adsorbing a chlorosilane-based chemical adsorbent to the rough surface of the fiber reinforced plastic or metal substrate. A siloxane-based chemically adsorbed monomolecular film or a polysiloxane chemically adsorbed film is formed on the substrate by chemically adsorbing a chemical adsorbent having numerous chlorosilane groups to the substrate surface. Following that, a chlorosilane-based chemical adsorbent having fluorocarbon groups is chemically adsorbed to the film, thus forming a chemically adsorbed monomolecular or polymer film with water- and oil-repelling properties.

Abstract: A method for manufacturing a composite material comprises the steps of furnishing a layer of a matrix material, forming a groove in the matrix-material layer using a laser to remove material from the layer of matrix material in the form of a groove, and placing a reinforcement into the groove. Preferably, the surface of the layer of matrix material is smoothed with a laser beam prior to formation of the groove. In most instances, more than one layer is desired, and the steps of furnishing, forming, and placing are repeated, using the same or different materials, to build up a multilayer composite material. Cylindrical, flat, or curved panel composite materials can be readily prepared, using metal, intermetallic, or ceramic materials for the matrix.

Abstract: A thin film, intagliated phosphor screen structure includes an optical fiber bundle in which each of the fibers has its glass core etched below the level of its cladding sheath at the internal surface of the screen, and a phosphor layer is deposited as a thin film which fills in the core recesses. Preferably, the upper surfaces of the phosphor layers are formed with a spherical or parabolic shape, which is obtained by surface tension when the phosphor film is annealed. The upper surfaces of the phosphor layers may also be finished by polishing. An aluminum reflective layer may also be coated on the phosphor layer. The bottom walls of the cores are preferably etched to be convex or concave to provide a lens effect. The intagliated phosphor screen can transmit 90% to 95% or more of the light generated in the phosphor layers, for an output gain factor of 5 or more over conventional phosphor screens.

Abstract: A thin layer of Class 1B, IIB, IIIA, IVB, VB, VIB, VIIB or VIIIB metal is deposited on silicon or a silicon-based compound by immersion in a buffered metallic salt bath containing a hydrofluoric acid etchant followed by an electroless plating bath to build up the metal thickness. This process can also be used to pattern deposited metal on silicon or a silicon-based compound. An additional use of this process is to form metal silicides out of the deposited metal.