Inorganic Matrix In Void-containing Component Patents (Class 428/312.2)
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Patent number: 7384693Abstract: The present invention discloses a method including: providing a substrate; and sequentially stacking layers of two or more diamond-like carbon (DLC) films over the substrate to form a composite dielectric film, the composite dielectric film having a k value of about 1.5 or lower, the composite dielectric film having a Young's modulus of elasticity of about 25 GigaPascals or higher. The present invention further discloses a structure including: a substrate; a porous diamond-like carbon (DLC) film located over the substrate; an opening located in the porous DLC film; and a conductor located in the opening.Type: GrantFiled: April 28, 2004Date of Patent: June 10, 2008Assignee: Intel CorporationInventor: Kramadhati V. Ravi
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Patent number: 7381461Abstract: An antireflective transparent zeolite hardcoat and fabrication method thereof. The transparent zeolite hardcoat comprises a zeolite nanostructure made of zeolite nanocrystals vertically stacked into a porous structure on a substrate, wherein the porosity increases with structure height, thereby providing a smooth refractive index transition.Type: GrantFiled: December 15, 2005Date of Patent: June 3, 2008Assignees: Industrial Technology Research Institute, National Central UniversityInventors: Anthony Shiaw-Tseh Chiang, Shih-Ming Chen, Young-Jen Lee
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Patent number: 7357976Abstract: The ceramic molded body of the present invention includes spherical cells of a spherical bubble plurally formed therein: in the ceramic molded body the spherical cells neighboring each other are communicated through communication porosities and form a three-dimensional network structure, and a ratio (Md/MD) of a median (Md) of inner diameters of the communication porosities to a median (MD) of inner diameters of the spherical cells is less than 0.5. In the ceramic molded body used for manufacturing a metal matrix composite, a metal is filled within the spherical cells and the communication porosities.Type: GrantFiled: April 15, 2005Date of Patent: April 15, 2008Assignee: Honda Motor Co., Ltd.Inventors: Satoshi Yamamura, Kazuo Shibata, Tadashi Ohya
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Patent number: 7348054Abstract: This substrate is coated with a composite film based on a mesoporous mineral layer containing nanoparticles formed in situ inside the layer. The composite film has a periodic lattice structure over a major portion of the thickness in which the nanoparticles are present, in which structure the nanoparticles are arranged in a periodic manner on the scale of domains of at least 4 periods in the thickness of the film. This structure can be obtained from a mesoporous mineral layer of periodic structure on the scale of domains of at least 4 periods of pores, forming a matrix on the substrate, by: depositing at least one precursor in the pores of the matrix layer; and growing particles derived from the precursor with the spatial distribution and the dimensions being controlled by the structure of the pores of the matrix. Applications to materials for electronics, nonlinear optics and magnetism.Type: GrantFiled: July 25, 2002Date of Patent: March 25, 2008Assignee: Saint-Gobain Glass FranceInventors: Catherine Jacquiod, Jean-Marc Berquier, Sophie Besson, Jean-Pierre Boilot, Christian Ricolleau, Thierry Gacoin
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Patent number: 7335317Abstract: The present invention relates to methods of preparing a polymer composite using a giant magnetostrictive material, and more particularly, to polymers composite having various improved properties, in which the advantageous structure of the giant magnetostrictive material produced by unidirectional solidification can be maintained by removing the eutectic phase from the magnetostrictive material and filling resulting voids with a polymer resin.Type: GrantFiled: July 26, 2005Date of Patent: February 26, 2008Assignee: Korea Advanced Institute of Science and TechnologyInventors: Soon Hyung Hong, Oh Yeoul Kwon, Won Je Park
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Patent number: 7309523Abstract: The present invention relates to a hybrid material, its use and its production process. The hybrid material comprises a polymer with acid groups. The inorganic part of the said hybrid material is constituted by the combination of at least two metal oxide components, whereof at least one comprises a functional group permitting an interaction and a spatial relationship with the acid groups of the polymer.Type: GrantFiled: July 6, 2001Date of Patent: December 18, 2007Assignee: FuMA-Tech Gesellschaft für funktionelle Membranen und Anlagentechnologie mbHInventors: Jacques Roziere, Deborah Jones, Lydie Tchicaya-Boukary, Bernd Bauer
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Publication number: 20070287001Abstract: An airborne sound-absorbing engine compartment lining for motor vehicles comprises an open-cell, air-permeable foam material layer made from plastic and having a front side and a rear side. The foam material layer is provided on its rear side with a fiber layer made from mineral fibers, the foam material layer having a thickness of less than 6 mm and a specific flow resistivity in the range from about 100 to 1,200 Ns/m3. The fiber layer has a thickness of more than 6 mm and a mass per unit area of less than 800 g/m2.Type: ApplicationFiled: January 16, 2007Publication date: December 13, 2007Applicant: Carcoustics Tech Center GmbHInventors: Larry Carlson, Gordon Ebbitt
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Patent number: 7307343Abstract: Low dielectric materials and films comprising same have been identified for improved performance when used as interlevel dielectrics in integrated circuits as well as methods for making same. These materials are characterized as having a dielectric constant (?) a dielectric constant of about 3.7 or less; a normalized wall elastic modulus (E0?), derived in part from the dielectric constant of the material, of about 15 GPa or greater; and a metal impurity level of about 500 ppm or less. Low dielectric materials are also disclosed having a dielectric constant of less than about 1.95 and a normalized wall elastic modulus (E0?), derived in part from the dielectric constant of the material, of greater than about 26 GPa.Type: GrantFiled: May 30, 2002Date of Patent: December 11, 2007Assignee: Air Products and Chemicals, Inc.Inventors: John Francis Kirner, James Edward MacDougall, Brian Keith Peterson, Scott Jeffrey Weigel, Thomas Alan Deis, Martin Devenney, C. Eric Ramberg, Konstantinos Chondroudis, Keith Cendak
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Publication number: 20070269646Abstract: A porous diamond dielectric material having a low dielectric constant and a method of forming such a material are described herein. A porous diamond dielectric material demonstrates high mechanical strength and has a low dielectric constant because of the presence of the pores. The dielectric constant is further decreased by the conversion of the sp2 type carbon bond terminations of the interior surface of the pores to sp3 type carbon bond terminations. This is accomplished by hydrogenation of the porous diamond dielectric material.Type: ApplicationFiled: May 18, 2006Publication date: November 22, 2007Inventors: Michael G. Haverty, K. V. Ravi, Sadasivan Shankar
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Patent number: 7285323Abstract: An optical multilayer film comprising a hard coat layer and a low refractive index layer comprising aerogel, which layers are laminated, in this order, directly or with another intervening layer on one surface of a base film comprising a transparent resin, wherein the refractive index nH of the hard coat layer and the refractive index nL of the low refractive index layer satisfy the following three formulae [1], [2] and [3], 1.25?nL?1.37 Formula [1] nH?1.53 Formula [2] (nH)1/2?0.2<nL<(nH)1/2+0.2. Formula [3.Type: GrantFiled: June 28, 2004Date of Patent: October 23, 2007Assignee: Zeon CorporationInventors: Atsushi Sone, Tetsuya Toyoshima, Kohei Arakawa
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Patent number: 7282265Abstract: A composite material having a high thermal conductivity and a small thermal expansion coefficient, which is obtained by impregnating a porous graphitized extrudate with a metal; the composite material having such anisotropy that the thermal conductivity and the thermal expansion coefficient are 250 W/mK or more and less than 4×10?6/K, respectively, in an extrusion direction; and that the thermal conductivity and the thermal expansion coefficient are 150 W/mK or more and 10×10?6/K or less, respectively, in a direction perpendicular to the extrusion direction.Type: GrantFiled: May 14, 2004Date of Patent: October 16, 2007Assignee: Hitachi Metals, Ltd.Inventor: Hideko Fukushima
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Patent number: 7252876Abstract: A laminated zeolite composite is provided, including a MFI membrane constituted by a MFI type zeolite having a SiO2/Al2O3 (molar ratio) of 40 to 100, and a porous substrate constituted by a MFI type zeolite having a SiO2/Al2O3 (molar ratio) of 20 to 400, wherein the MFI membrane is formed on the porous substrate. The composite has high separation characteristics and high permeability.Type: GrantFiled: March 10, 2004Date of Patent: August 7, 2007Assignee: NGK Insulators, Ltd.Inventors: Nobuhiko Mori, Toshihiro Tomita, Hitoshi Sakai
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Patent number: 7220475Abstract: The present invention provides a polishing sheet that can secure a flatness of a material to be polished and can improve a polishing efficiency. A polishing pad 1 has a polyurethane sheet 2 made of polyurethane resin. The polyurethane sheet 2 has large cells 3 with a generally triangular sectional configuration rounded along a thickness direction thereof. Polyurethane resin exists in the polyurethane sheet 2 in a partition wall manner and fine foams 4 are formed in the polyurethane resin. Fine particles 5 added during manufacture of the polyurethane sheet 2 exist inside some of the fine foams 4 and the fine particles 5 are separable from the fine foams. By separating off fine particles positioned at a polishing face P by dummy polishing or the like, fine foams which evenly reserve a polishing liquid containing abrasive particles are formed at the polishing face P.Type: GrantFiled: August 18, 2003Date of Patent: May 22, 2007Assignee: Fuji Spinning Co., Ltd.Inventors: Takahiro Kume, Hidenori Takeda
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Patent number: 7169465Abstract: A low CTE metal-ceramic composite material featuring carbon fibers reinforcing a matrix featuring silicon metal or silicon alloy. The fibers have a low coefficient of thermal expansion (CTE) in the axial direction, and preferably negative. The principles of making Si/SiC composites can be adapted to produce the instant Si matrix composites. The CTE of the composite body depends not only upon the relative CTE's of the fibers and matrix, and their relative amounts (e.g., loadings), but also upon the relative elastic moduli of the fibers and matrix. Thus, Si/SiC matrices produced by a reaction-bonding process inherently possess low CTE, but the instant inventors prefer to make such composites having relatively large fractions of unreacted silicon, thereby driving composite CTE lower still. Here, the carbon fibers are protected from reaction with the silicon infiltrant with one or more materials disposed between the fibers and the infiltrant.Type: GrantFiled: February 11, 2002Date of Patent: January 30, 2007Inventors: Prashant G. Karandikar, Jai R. Singh, Clarence A. Andersson
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Patent number: 7144533Abstract: The invention is directed to a microbiological interception enhanced filter medium, preferably having an adsorbent prefilter located upstream from the filter medium. Preferably, the prefilter is adapted to remove natural organic matter in an influent prior to the influent contacting the microbiological interception enhanced filter medium, thereby preventing loss of charge on the filter medium. The microbiological interception enhanced filter medium is most preferably comprised of fibrillated cellulose fibers, in particular, lyocell fibers. At least a portion of the surface of the at least some of the fibers have formed thereon a microbiological interception enhancing agent comprising a cationic metal complex. A filter medium of the present invention provides greater than about 4 log viral interception, and greater than about 6 log bacterial interception.Type: GrantFiled: May 20, 2003Date of Patent: December 5, 2006Assignee: Koslow Technologies CorporationInventor: Evan E. Koslow
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Patent number: 7144522Abstract: A curable coating composition for forming a thermal insulating layer, the composition comprising: (a) highly porous particles of a material obtained by drying a wet sol-gel, the particles having a porosity of at least 80% and a particle size in the range from 5 ?m to 4.Type: GrantFiled: November 12, 2004Date of Patent: December 5, 2006Inventors: G. Stuart Burchill, Jr., Peter Wachtel
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Patent number: 7132156Abstract: A preform for the composite material and an aluminum composite material which can form a composite material has excellent abrasion resistant property and high strength and a manufacturing method of the same are disclosed. A pre-mixture 9 comprising aluminum borate whisker 3 and potassium titanate whisker 4 in the range of 5% to 20% by volume was sintered at certain temperature. The titanium oxide 11 produced by the whisker reaction was bound to the surface of aluminum borate whisker 3, and the preform having high strength was obtained accordingly. Aluminum composite material 10 having excellent abrasion resistant property and high strength was obtained by impregnating aluminum alloy 6 to preform 1 for composite material.Type: GrantFiled: April 28, 2005Date of Patent: November 7, 2006Assignee: Central Motor Wheel Co., Ltd.Inventor: Makoto Fujita
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Patent number: 7128963Abstract: A ceramic composite body includes at least two layers: material layer A and material layer B. Material layer A contains phases of a metal and the carbide of this metal. Material layer B contains silicon carbide that has been loosely bound by sintering. A method for fabricating the composite body is included and a protective armor against projectiles.Type: GrantFiled: July 10, 2003Date of Patent: October 31, 2006Assignee: SGL Carbon AGInventor: Bodo Benitsch
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Patent number: 7074480Abstract: A nanostructure is a porous body comprising a plurality of pillar-shaped pores and a region surrounding them, said region being an oxide amorphous region formed so as to contain C, Si, Ge or a material of a combination of them. Such a nanostructure can be used as functional material that can be used for light emitting devices, optical devices and microdevices. It can also be used as filter.Type: GrantFiled: August 14, 2003Date of Patent: July 11, 2006Assignee: Canon Kabushiki KaishaInventors: Kazuhiko Fukutani, Tohru Den
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Patent number: 7070855Abstract: There are provided a porous material and a process for producing the same. The porous material has a plurality of columnar pores and an area surrounding the pores, and the area is an amorphous area containing C, Si, Ge or a combination thereof.Type: GrantFiled: September 4, 2003Date of Patent: July 4, 2006Assignee: Canon Kabushiki KaishaInventors: Kazuhiko Fukutani, Tohru Den
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Patent number: 7067187Abstract: A spherical porous ceramic body and the production method thereof are provided. As to the porous ceramic body, the total volume of the pores having a pore radius of from 1.8 nm to 100 ?m is about 0.25 cm3/g or more, the mode of pore radius of the pores is from about 1 ?m to about 6 ?m and the packing density is from about 0.7 g/cm3 to about 1 g/cm3. The porous ceramic body is suitably used as a carrier for a catalyst and has high mechanical strength.Type: GrantFiled: March 14, 2002Date of Patent: June 27, 2006Assignee: Sumitomo Chemical Company, LimitedInventors: Hidekatsu Kawazu, Osamu Yamanishi
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Patent number: 7048996Abstract: A temperature resistant material, comprising a temperature resistant matrix and a set of short metal fibers, which characterized in that the set of short metal fibers represents at least 0.5% by weight of the temperature resistant material. The set of short metal fibers has an equivalent diameter D in the range of 1 to 150 ?, and comprising curved fibers and entangled fibers. The curved fibers have an average length L in the range of 10 to 2000 ?.Type: GrantFiled: December 10, 2001Date of Patent: May 23, 2006Assignee: N.V. Bekaert S.A.Inventors: Ronny Losfeld, Lieven Anaf
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Patent number: 7045219Abstract: The present invention relates to short metal fibers. A set of short metal fibers, with an equivalent diameter ranging from 1 to 150 $(m)m, comprises entangled and curved fibers. At least 10% of the short metal fibers are entangled, whereas the length of the curved fibers is distributed according to a gamma-distribution, having an average length preferably between 10 and 2000 $(m)m.Type: GrantFiled: December 10, 2001Date of Patent: May 16, 2006Assignee: N.V. Bekaert S.A.Inventors: Ronny Losfeld, Lieven Anaf
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Patent number: 7045207Abstract: Friction bodies made of a fiber-reinforced porous carbon material in which the reinforcing fibers are present in the form of woven fabrics, short fibers and/or long fibers and whose pores are filled with metals, wherein carbides of the metals filling the pores are present in the material in a mass fraction of not more than 10%, a process for their production and the use thereof in brake and clutch systems.Type: GrantFiled: May 26, 2004Date of Patent: May 16, 2006Assignee: SGL Carbon AGInventors: Ronald Hüner, Xaver Rothmair
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Patent number: 7041366Abstract: The invention provides porous silicon nitride ceramics that having uniform, fine closed pores and a manufacturing method thereof. Metal Si powder is mixed with a sintering additive, followed by thermal treatment, which is a pre-process for forming a specific grain boundary phase. Two-stage thermal treatment is thereafter performed by microwave heating at a temperature of 1000° C. or more. The metal Si powder is thereafter subjected to a nitriding reaction from its surface, the metal Si is thereafter diffused to nitride formed on the outer shell thereof such that porous silicon nitride ceramics having uniform, fine closed pores can be produced. Having a high ratio of closed pores and being superior in electrical/mechanical characteristics, the porous silicon nitride ceramics can display excellent characteristics if used, for example, for an electronic circuit board that requires an anti-hygroscopicity, a low dielectric constant, a low dielectric loss, and mechanical strength.Type: GrantFiled: March 22, 2002Date of Patent: May 9, 2006Assignee: Sumitomo Electric Industries, Ltd.Inventors: Michimasa Miyanaga, Osamu Komura
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Patent number: 7018707Abstract: A porous ceramic laminate has a porous silicon nitride substrate and a porous silicon nitride separation film supported thereon and having minute pores of sizes capable of Knudsen separation or molecular sieve by sintering a porous silicon nitride substrate supporting a formed layer containing polysilazane at 800° C. in a nitrogen atmosphere.Type: GrantFiled: March 2, 2001Date of Patent: March 28, 2006Assignees: Noritake Co., Limited, Chubu Electric Power Co., Inc.Inventors: Shigekazu Mase, Shigeo Nagaya, Junichiro Tsubaki, Kiyoshi Komura
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Patent number: 7001679Abstract: A xenotime phosphate protective overlayer (22) for protecting a ceramic material (24) from a high temperature, moisture-containing environment. Yttrium phosphate may be used as a protective overlayer to protect an underlying mullite layer to temperatures in excess of 1,500° C. The coating may have porosity of greater than 15% for improved thermal shock protection. To prevent the ingress of oxygen to an underlying ceramic non-oxide material, such as silicon carbide or silicon nitride, an oxygen barrier layer (34) is disposed between the xenotime phosphate coating and the non-oxide material. Such a protective overlayer may be used for an article having a ceramic matrix composite substrate.Type: GrantFiled: August 8, 2002Date of Patent: February 21, 2006Assignee: Siemens Westinghouse Power CorporationInventors: Christian X. Campbell, Jay E. Lane
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Patent number: 6998173Abstract: A coated cemented carbide tool, and a method for making the same, wherein the as-sintered substrate is formed by sintering in an atmosphere having at least a partial pressure and for a part of the time a nitrogen partial pressure.Type: GrantFiled: November 13, 2002Date of Patent: February 14, 2006Assignee: Kennametal Inc.Inventors: Yixiong Liu, Donald A. Botbyl, George P. Grab, Mark S. Greenfield
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Patent number: 6974640Abstract: A contiguous duplex microstructured material comprises a nanostructured material having two structural states, for example, a duplex microstructured coating. One state comprises substantially nanostructured features, while the second state substantially comprises microstructured features. A duplex nanostructured coating can be made by thermal spraying a reconstituted nanostructured material onto a substrate under conditions effective to form a coating comprising more than one structural state.Type: GrantFiled: July 9, 2002Date of Patent: December 13, 2005Assignee: The University of ConnecticutInventors: Maurice Gell, Tongsan D. Xiao, Leon Shaw, Eric Jordan, Xiangliang Jiang
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Patent number: 6960386Abstract: An object of the invention is to provide a holding and sealing mat material of a catalytic converter for purifying an exhaust gas which can prevent inorganic fibers from flying in all directions from a surface of the holding and sealing mat material, and can keep a working environment at a time of assembling good. In the holding and sealing mat material of a catalytic converter for purifying an exhaust gas, which is arranged between a catalyst carrier and a shell covering the catalyst carrier from the outside thereof, the holding and sealing mat material includes a mat-like material consisting of inorganic fibers and being formed in a mat shape and a binder of 0.5 to 20 weight % of an organic binder or an inorganic binder, which is attached to the mat-like material, wherein a filling bulk density of the holding and sealing mat material after being assembled is within a range between 0.1 and 0.Type: GrantFiled: June 19, 2001Date of Patent: November 1, 2005Assignee: Ibiden Co., Ltd.Inventor: Masanao Agata
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Patent number: 6960389Abstract: This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding “gluing” agents and/or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.Type: GrantFiled: June 7, 2002Date of Patent: November 1, 2005Assignee: Hyperion Catalysis International, Inc.Inventors: Howard Tennent, David Moy, Chun-Ming Niu
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Patent number: 6958480Abstract: Mesoporous silica is shown to be a sample holder for laser desorption/ionization of mass spectrometry. Supported mesoporous silica was prepared by coating an ethanolic silicate solution having a removable surfactant onto a substrate to produce a self-assembled, ordered, nanocomposite silica thin film. The surfactant was chosen to provide a desired pore size between about 1 nanometer diameter and 50 nanometers diameter. Removal of the surfactant resulted in a mesoporous silica thin film on the substrate. Samples having a molecular weight below 1000, such as C60 and tryptophan, were adsorbed onto and into the mesoporous silica thin film sample holder and analyzed using laser desorption/ionization mass spectrometry.Type: GrantFiled: June 25, 2004Date of Patent: October 25, 2005Assignee: The Regents of the University of CaliforniaInventors: Srinivas Iyer, Andrew M. Dattelbaum
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Patent number: 6951682Abstract: Articles comprising substantially uniform porous coatings, which may be photopatterned, are provided. The use of such porous coatings increases the surface density of attached compounds within, for example, ligand arrays prepared by methods such as regionally selective solid-phase chemical synthesis. Arrays prepared using the porous coatings may be used within a variety of diagnostic and drug discovery assays.Type: GrantFiled: September 17, 1999Date of Patent: October 4, 2005Assignee: Syntrix Biochip, Inc.Inventor: John A. Zebala
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Patent number: 6936565Abstract: Compositions including modified carbide-containing nanorods and/or modified oxycarbide-containing nanorods and/or modified carbon nanotubes bearing carbides and oxycarbides and methods of making the same are provided. Rigid porous structures including modified oxycarbide-containing nanorods and/or modified carbide containing nanorods and/or modified carbon nanotubes bearing modified carbides and oxycarbides and methods of making the same are also provided. The compositions and rigid porous structures of the invention can be used either as catalyst and/or catalyst supports in fluid phase catalytic chemical reactions. Processes for making supported catalyst for selected fluid phase catalytic reactions are also provided.Type: GrantFiled: October 29, 2001Date of Patent: August 30, 2005Assignee: Hyperion Catalysis International, Inc.Inventors: Jun Ma, David Moy
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Patent number: 6933531Abstract: Graphite is placed in a case, and the case is set in a furnace. The interior of the furnace is subjected to sintering to produce a porous sintered member of graphite. After that, the case with the porous sintered member therein is taken out of the furnace, and is set in a recess of a press machine. Subsequently, molten metal of metal is poured into the case, and then a punch is inserted into the recess to forcibly press the molten metal in the case downwardly. Open pores of the porous sintered member are infiltrated with the molten metal of the metal by the pressing treatment with the punch.Type: GrantFiled: December 22, 2000Date of Patent: August 23, 2005Assignee: NGK Insulators, Ltd.Inventors: Shuhei Ishikawa, Tsutomu Mitsui, Ken Suzuki, Nobuaki Nakayama, Hiroyuki Takeuchi, Seiji Yasui
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Patent number: 6924040Abstract: A ceramic material has particular utility as a thermal insulating or thermal barrier coating on metallic substrates. The ceramic material includes gadolinia and hafnia, preferably forming gadolinia-hafnia. This material exhibits chemical stability, thermal stability and thermal insulating properties superior to those of currently used thermal barrier ceramics, and also provides resistance to sintering and erosion comparable to currently used ceramics. A preferred material has between about 3-70 mol. % hafnia, balance hafnia.Type: GrantFiled: December 21, 2001Date of Patent: August 2, 2005Assignee: United Technologies CorporationInventor: Michael J. Maloney
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Patent number: 6916529Abstract: An abradable coating composition for use on shrouds in gas turbine engines or other hot gas path metal components exposed to high temperatures containing an initial porous coating phase created by adding an amount of inorganic microspheres, preferably alumina-ceramic microballoons, to a base metal alloy containing high Al, Cr or Ti such as ?-NiAl or, alternatively, MCrAlY that serves to increase the brittle nature of the metal matrix, thereby increasing the abradability and oxidation resistance of the coating at elevated temperatures. Coatings having a total open and closed porosity of between 20% and 55% by volume due to the presence of ceramic microballoons ranging in size from about 10 microns to about 200 microns have been found to exhibit excellent abradability for applications involving turbine shroud coatings. An abradable coating thickness in the range of between 40 and 60 ml provides improved performance for turbine shrouds exposed to gas temperatures between 1380° F. and 1800° F.Type: GrantFiled: January 9, 2003Date of Patent: July 12, 2005Assignee: General Electric CompanyInventors: Surinder Singh Pabla, Farshad Ghasripoor, Yuk-Chiu Lau, Liang Jiang, Canan Uslu Hardwicke, William Emerson Martinez Zegarra
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Patent number: 6890878Abstract: Provided is a catalyst formulation which exhibits extended catalyst life. The formulation comprises a mixture of a ceramic foam material uniformly interspersed between the solid catalyst particles, with the volume percent of ceramic material in the mixture preferably ranging from 20 to 60 volume %. The catalyst formulation is particularly applicable to solid catalyst particles comprised of a phosphoric acid impregnated substrate, and is particularly useful for processes such as catalytic hydrocarbon condensation processes.Type: GrantFiled: December 28, 2001Date of Patent: May 10, 2005Assignee: United Refining CompanyInventor: John H. Moore
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Patent number: 6878434Abstract: A composite construction 1 is obtained by coating the outer periphery of a core material 2 with a shell layer 3. The core material 2 is composed of a first sintered body that is obtained by bonding, with a binder metal, a first hard particle composed of one or more of carbides, nitrides and carbonitrides of metals of Groups 4a, 5a and 6a of the Periodic Table, or a first ceramics obtained by bonding, with a sintering additive, a first ceramic particle composed of at least one of oxides, carbides, nitrides and carbonitrides selected from the group consisting of metals of Groups 4a, 5a and 6a of the Periodic Table, Al, Si and Zn. The shell layer 3 is composed of a second hard sintered body or second ceramics having a different composition from the first hard sintered body. The ratio of the residual free carbon amount Cin in the core material 2 to the residual free carbon amount Cout in the shell layer 3, Cin/Cout, is 0.5 to 2.Type: GrantFiled: March 14, 2003Date of Patent: April 12, 2005Assignee: Kyocera CorporationInventors: Hiromi Fujioka, Daisuke Shibata, Tatsuyuki Nakaoka
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Patent number: 6869671Abstract: A thin film based nanoporous alumina template has been developed which allows the in situ removal of an electrically insulating alumina barrier layer at the pore bases. This barrier free nanoporous system has great utility for electrodeposition of a wide variety of nanowire materials. An exemplary multilayer thin film precursor is provided comprising Al (anodization layer), Ti (diffusion barrier) and Pt (active electrode) on a Si substrate. Aluminum anodization in sulfuric acid with a subsequent applied voltage ramping program produces a Pt electrode at the base of the nanopores without the additional steps of alumina removal, barrier layer dissolution, and metal deposition onto the pore bottoms.Type: GrantFiled: June 2, 2003Date of Patent: March 22, 2005Assignee: University of Notre DameInventors: Michael M. Crouse, Albert E. Miller, Juan Jiang, David T. Crouse, Subash C. Basu
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Patent number: 6866925Abstract: The invention concerns a heat-stable ordered mesoporous or mesostructured material comprising a mineral phase wherein are dispersed particles of nanometric dimension at least partly crystaline, the global crystallinity index of said mesostructured or ordered mesoporous material being less than 10% in volume. The invention also concern a method for obtaining such a material.Type: GrantFiled: November 2, 2000Date of Patent: March 15, 2005Assignee: Rhodia ChimieInventor: Jean-Yves Chane-Ching
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Patent number: 6866921Abstract: A coated cemented (binder alloy, e.g., cobalt-chromium alloy) tungsten carbide cutting insert that comprises a substrate and a coating. The substrate contains at least about 70 weight percent tungsten and carbon, between about 3 weight percent and about 12 weight percent cobalt, and at least 0.09 weight percent chromium. The substrate presents a surface zone of binder alloy enrichment that begins near (or at) and extends inwardly from a peripheral surface of the substrate. The coating includes a base layer that contains chromium.Type: GrantFiled: March 7, 2003Date of Patent: March 15, 2005Assignee: Kennametal Inc.Inventors: George P. Grab, Mark S. Greenfield, Anakkavur T. Santhanam
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Patent number: 6858302Abstract: A composite structure is formed by depositing a one or more coatings on an open-cell foam skeleton to form a higher-density composite foam. In accordance with one aspect of the invention, the composite foam can be a carbon/carbon composite formed by a rapid densification process. The composite structure is suitable for use, for example, as a friction material employed in clutch and brake devices.Type: GrantFiled: September 30, 2003Date of Patent: February 22, 2005Assignee: Messier-Bugatti, Inc.Inventor: Raymond C. Loszewski
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Patent number: 6855408Abstract: A composite metallic material 1 according to the invention is used for, e.g., electrolytic capacitors, and includes a metallic material substrate 10 and a high polymer thin layer 11 having a fine pattern 12 formed on at least one surface of the substrate 10 by self-organization. This high polymer thin film 11 is formed by, for example, drying hydrophobic organic solvent solution of high polymer compound. By subjecting this composite metallic material 1 to etching processing, etching pits are formed uniformly with high density based on the fine pattern.Type: GrantFiled: January 27, 2003Date of Patent: February 15, 2005Assignee: Showa Denko K.K.Inventors: Masatsugu Shimomura, Masaru Tanaka, Hiroshi Yabu, Masafumi Takebayashi, Ryuji Monden, Tamami Koyama, Yoshikazu Hosoda, Masashi Sakaguchi
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Patent number: 6846558Abstract: A dense or porous coating of material is deposited onto a substrate by forcing a colloidal suspension through an ultrasonic nebulizer and spraying a fine mist of particles in a carrier medium onto a sufficiently heated substrate. The spraying rate is essentially matched to the evaporation rate of the carrier liquid from the substrate to produce a coating that is uniformly distributed over the surface of the substrate. Following deposition to a sufficient coating thickness, a single sintering step may be used to produce a dense ceramic coating. Using this method, coatings ranging in thickness from about one to several hundred microns can be obtained. By using a plurality of compounds in the colloidal suspension, coatings of mixed composition can be obtained. By using a plurality of solutions and separate pumps and a single or multiple ultrasonic nebulizer(s), and varying the individual pumping rates and/or the concentrations of the solutions, a coating of mixed and discontinuously graded (e.g.Type: GrantFiled: January 28, 2002Date of Patent: January 25, 2005Assignee: The Regents of the University of CaliforniaInventors: Ai-Quoc Pham, Robert S. Glass, Tae H. Lee
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Patent number: 6841508Abstract: Compositions including oxycarbide-based nanorods and/or carbide-based nanorods and/or carbon nanotubes bearing carbides and oxycarbides and methods of making the same are provided. Rigid porous structures including oxycarbide-based nanorods and/or carbide based nanorods and/or carbon nanotubes bearing carbides and oxycarbides and methods of making the same are also provided. The compositions and rigid porous structures of the invention can be used either as catalyst and/or catalyst supports in fluid phase catalytic chemical reactions. Processes for making supported catalyst for selected fluid phase catalytic reactions are also provided. The fluid phase catalytic reactions catalyzed include hydrogenation, hydrodesulfurisation, hydrodenitrogenation, hydrodemetallisation, hydrodeoxigenation, hydrodearomatization, dehydrogenation, hydrogenolysis, isomerization, alkylation, dealkylation and transalkylation.Type: GrantFiled: June 11, 2002Date of Patent: January 11, 2005Assignee: Hyperion Catalysis International, Inc.Inventors: David Moy, Chunming Niu, Jun Ma, James M. Willey
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Patent number: 6824866Abstract: Methods are provided for making and using thin films of porous silica substrates to synthesize arrays of polymers. Methods are also provided for assaying such polymers on porous silica substrates. The porous silica substrates offer an increase in array density and signal enhancement over conventional flat glass substrates. Examples of polymers that can be synthesized and assayed include biological polymers such as nucleic acids, polynucleotides, polypeptides, and polysaccharides. Arrays of nucleic acids or polynucleotides can be used for a variety of hybridization-based experiments such as nucleic acid sequence analysis, nucleic acid expression monitoring, nucleic acid mutation detection, speciation, effects of drug therapy on nucleic acid expression, among others.Type: GrantFiled: April 7, 2000Date of Patent: November 30, 2004Assignee: Affymetrix, Inc.Inventors: Marc I. Glazer, Jacqueline A. Fidanza, Glenn McGall, Curtis W. Frank, Richard Vinci
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Patent number: 6818289Abstract: A process provides a ceramic film, such as a mesoporous silica film, on a substrate, such as a silicon wafer. The process includes preparing a film-forming fluid containing a ceramic precursor, a catalyst, a surfactant and a solvent, depositing the film-forming fluid on the substrate, and removing the solvent from the film-forming fluid on the substrate to produce the ceramic film on the substrate. The ceramic film has a dielectric constant below 2.3, a halide content of less than 1 ppm and a metal content of less than 500 ppm, making it useful for current and future microelectronics applications.Type: GrantFiled: October 2, 2002Date of Patent: November 16, 2004Assignee: Air Products and Chemicals, Inc.Inventors: James Edward MacDougall, Kevin Ray Heier, Scott Jeffrey Weigel, Timothy W. Weidman, Alexandros T. Demos, Nikolaos Bekiaris, Yunfeng Lu, Michael P Nault, Robert Parkash Mandal
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Patent number: 6815052Abstract: A diamond foam article comprises diamond deposited material on a substrate having an open contiguous structure at least partially filled with a filler material. Methods for forming a diamond foam article comprise providing a foam substrate; preparing the foam substrate for diamond deposition; depositing diamond material on the foam substrate by one of several diamond deposition methods; and at least partially filling the diamond foam article with a filler material. Diamond foam articles are bonded to other components.Type: GrantFiled: December 1, 2000Date of Patent: November 9, 2004Assignee: P1 Diamond, Inc.Inventor: John M. Pinneo
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Patent number: 6815049Abstract: A composition including, but not limited to, a mixture of a calcium sulfate material, water, and a tetrametaphosphate compound is disclosed. Desirably, the inclusion of the tetrametaphosphate compound (e.g., salt or ion) in a pre-set treatment of a calcium sulfate material enhances the resistance to permanent deformation (e.g., sag), dimensional stability, and/or compressive strength of the composition while also preferably avoiding any significant retardive effect on the rate of hydration of calcined gypsum to calcium sulfate dihydrate. A set gypsum-containing product and a method for producing a set gypsum-containing product having increased resistance to permanent deformation are also disclosed.Type: GrantFiled: December 11, 2001Date of Patent: November 9, 2004Assignee: United States Gypsum CompanyInventors: Srinivas Veeramasuneni, Qiang Yu, William A. Frank