At Least One Layer Is Nylon Type Patents (Class 428/474.9)
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Patent number: 7133209Abstract: A molding composition which is composed of at least 60% by weight of transparent polyamide, where the molding composition comprises an effective amount of one or more optical brighteners, and where the amount of the optical brightener has been judged in such a way that a) the b value, which is a measure of yellowness, is at most 7, and moreover b) between 370 and 430 nm, at least in a lower part of the range, the transmittance is smaller than 1%, measured at a layer thickness of 4 mm, can be processed to give products which are substantially impermeable to UV light.Type: GrantFiled: February 24, 2004Date of Patent: November 7, 2006Assignee: Degussa AGInventors: Roland Wursche, Dagmar Kaufhold, Berthold Teloeken
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Patent number: 7122255Abstract: Multilayered polyamide composite articles comprising at least three layers that comprise aliphatic and semi-aromatic polyamides and that is better able to retain its mechanical properties at high temperatures and over long times are disclosed. Layers comprising aliphatic polyamides may optionally contain oxidation stabilizers. The articles may be in the form of tubes incorporated into a heat exchanger. Processes for their preparation are also provided.Type: GrantFiled: December 9, 2003Date of Patent: October 17, 2006Assignee: E. I. du Pont Canada CompanyInventor: Shailesh Ratilal Doshi
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Patent number: 7063885Abstract: A multi-layer, thermoplastic film bi-axially oriented at a stretching ratio ? to about 3.0:1 in the machine direction and at a stretching ratio ? about 6.0:1 in the transverse direction, which film comprises a layer a) comprising at least 50 wt. % of a crystalline or partially crystalline co-polyamide characterized by a Tg?100° C. and at least one outer heat-sealing layer b) comprising a polyolefin, said film being further characterized in that it has a % free shrink at 100° C.?3 in each direction.Type: GrantFiled: February 27, 2001Date of Patent: June 20, 2006Assignee: Cryovac, Inc.Inventors: Eugenio Longo, Roberto Forloni, Gregorio Di Cesare
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Patent number: 7063873Abstract: A multiplayer tube comprising: an outer layer formed from a polyamide, a layer formed from a copolyamide, a layer formed from an EVOH, a layer formed from a copolyamide, and an inner layer formed from a polyamide, the layers being successive and adhering to one another in their respective contact region. Advantageously, the inner layer is formed by a compound based on a polyamide and electrically conducting carbon black, producing a surface resistivity of less than 106 ?. The tubes have a very low permeability to petrol, particularly to hydrocarbons and their additives, and in particular to alcohols, such as methanol and ethanol, or to ethers, such as MTBE or ETBE. These tubes also have good resistance to engine lubricating oils as well as fuels.Type: GrantFiled: March 25, 2002Date of Patent: June 20, 2006Assignee: ArkemaInventors: Gaëlle Bellet, Anthony Bonnet, Joachim Merziger
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Patent number: 7049006Abstract: A multilayer structure based on polyamides, comprising: a first layer (1) formed from a polyamide P1 or from a blend of a polyamide P1 and a polyolefin PO1 having a P1 polyamide matrix, optionally, a layer (2a) formed from EVOH; a layer (2) formed from a blend of PA-6/12 copolyamides, one comprising by weight more 6 than 12 and the other more 12 than 6; a layer (3) formed from a polyamide P3, it being possible for P1 and P3 to be identical or different, the layers (1), (2), (2a) and (3) being successive and adhering to one another in their respective contact regions.Type: GrantFiled: November 2, 2004Date of Patent: May 23, 2006Assignee: ArkemaInventor: Christophe Lacroix
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Patent number: 7014920Abstract: An anti-fogging, stretched, multilayer film comprising a layer having an anti-fogging agent incorporated therein, the film having evaluated values for anti-fogging property of 28 mm2 or more at temperatures of ?5° C. and 15° C., respectively.Type: GrantFiled: April 16, 2001Date of Patent: March 21, 2006Assignee: Gunze LimitedInventor: Hiroki Kuriu
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Patent number: 6989198Abstract: A multi-layer structure excellent in the barrier properties against alcohol gasoline, particularly hydrocarbon components, and also excellent in the interlayer adhesion, low-temperature impact resistance, heat resistance and chemical resistance is provided. The stractive is a multi-layer structure comprising two or more layers including at least a layer (a) comprising (A) nylon 11 and/or nylon 12 and a layer (b) comprising (B) a polyamide resin (nylon 9T) consisting of a dicarboxylic acid component and a-diamine component, with 60 to 100 mol % of the dicarboxylic acid component being a terephthalic acid and 60 to 100 mol % of the diamine component being a diamine component selected from 1,9-nonanediamine and 2-methyl-1,8-octanediamine, and preferably further including a layer (c) comprising (A) nylon 11 and/or nylon 12 or (C) nylon 6.Type: GrantFiled: October 14, 2003Date of Patent: January 24, 2006Assignees: Kuraray Co., Ltd., Ube Industries, Ltd.Inventors: Haruhisa Masuda, Yuji Munesawa, Koichi Warino, Tomoharu Nishioka, Yoshio Iwata, Koji Nakamura, Kozo Tamura, Tetsuya Hara
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Patent number: 6984442Abstract: A multilayer film includes a first layer comprising an amorphous polymer that exhibits a glass transition temperature, and a second layer forming an exterior layer of the multilayer film and comprising a sealant material capable of forming a heat-seal, the sealant material comprising a polymer that exhibits a melting point. The glass transition temperature of the amorphous polymer is greater than the melting point of the sealant material by at least about 45 degrees centigrade.Type: GrantFiled: July 19, 2002Date of Patent: January 10, 2006Assignee: Cryovac, Inc.Inventors: Herve M. Brebion, Frank M. Hofmeister, Ram K. Ramesh, Paul J. Satterwhite
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Patent number: 6979494Abstract: A dual ovenable film having a first layer comprising one or more polyamides and a second layer comprising one or more polyamides. The first layer forms the first outer surface of the film. The second layer has a melting point of at least about 210° C. The film is capable of forming a water-containing package by providing two 4 inch by 6 inch sheets of the film each having four perimeter sides, placing the sheets in superimposed, coextensive arrangement having the first layers of the films in contact with each other, and heat sealing three perimeter sides of the sheets together using a ?-inch wide sealing bar at a temperature of 290° F., a dwell time of 0.5 seconds, and a sealing pressure of 40 psig to form an open pouch having heat seals along three of the four perimeter sides. The open pouch can be filled with 100 milliliters of distilled water at a temperature of 73° F.Type: GrantFiled: August 27, 2002Date of Patent: December 27, 2005Assignee: Cryovac, Inc.Inventors: Arthur Leroy Berrier, Cynthia Louise Ebner
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Patent number: 6908649Abstract: This invention relates to a coextruded biaxially stretched tubular film for the durable and crease-free covering of goods packaged in the liquid or pasty state, in particular foodstuffs such as sausage-meat for boiling or cooking or soft cheese, which are heated during and/or after they are packaged.Type: GrantFiled: September 7, 1994Date of Patent: June 21, 2005Assignee: Wolff Walsrode AGInventors: Michael Hennig-Cardinal von Widdern, Gunter Weber
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Patent number: 6893729Abstract: The present invention is to provide a laminated resin molding comprising a polyamide-based resin composition as an outer layer and being excellent in interlayer adhesion strength, in particular a laminated resin molding comprising a fluorine-containing resin as an inner layer. The present invention is a laminated resin molding which comprises a layer (A) comprising a polyamide-based resin composition and a layer (B) laminated to said layer (A), said layer (B) comprising a fluorine-containing ethylenic polymer having a carbonyl group, and said polyamide-based resin composition having a functional group, in addition to an amide group, selected from the group consisting of hydroxyl group, carboxyl group, ester group and sulfonamide group in a total amount of 0.05 to 80 equivalent percent relative to the amide group.Type: GrantFiled: February 19, 2001Date of Patent: May 17, 2005Assignee: Daikin Industries, Ltd.Inventors: Takeshi Inaba, Taketo Kato, Shigehito Sagisaka, Takuya Arase, Tetsuo Shimizu
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Patent number: 6872459Abstract: This invention relates to the laminated material for food packaging, and its manufacturing process. The laminated material (10) consists of the quality keeping intermediate layer (12) laminated inside the paper core layer (11) and the core layer and the heat sealable innermost layer (13). The quality keeping intermediate layer comprises of an extrusion coatable blend polymer consisting of polymer component A 50-95% of nylon-MXD6 or EVOH and, polymer component B 5-50% of nylon 6, nylon 6, the blends or PET. The quality keeping intermediate layer is extruded and laminated directly in the core layer, the innermost layer contains at least the linear low density polyethylene which has a narrow molecular weight distribution, and has the properties parameter of mean density of 0.910-0.925, 100-122 degrees C. peak melting point, melt flow index of 5-20, swelling ratio (SR) of 1.4-1.6, and 5-50 micrometer layer thickness.Type: GrantFiled: September 18, 1999Date of Patent: March 29, 2005Assignee: Tetra Laval Holdings & Finance S.A.Inventors: Peter Frisk, Norio Kobayashi, Hiroaki Ogita
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Patent number: 6858313Abstract: A film includes a core layer having an amorphous polyamide; two intermediate layers, disposed on opposite surfaces of the core layer, including a semicrystalline polyamide; two adhesive layers, each disposed on a surface of the respective intermediate layer, including a polymeric adhesive; and two outer layers, each disposed on a surface of a respective adhesive layer, including an ethylene/alpha olefin copolymer, propylene homopolymer, or propylene/alpha olefin copolymer; and a second outer layer, disposed on a surface of a respective adhesive layer, including amorphous polyamide, semicrystalline polyamide, ethylene/alpha olefin copolymer, propylene homopolymer, or propylene/alpha olefin copolymer. The film can alternatively have a core layer including a polymeric adhesive, and two intermediate layers each having an amorphous polyamide. A method of packaging a product using these films, and a package, are also disclosed.Type: GrantFiled: August 2, 2002Date of Patent: February 22, 2005Assignee: Cryovac, Inc.Inventors: Carlo E. Musco, Paul J. Satterwhite, G. Vince Sharps, Frank M. Hofmeister, Thomas D. Kennedy
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Patent number: 6805969Abstract: Novel coating solutions are disclosed that promote desirable adhesion to substrates formed from nylon, polyester, or a combination thereof. These coating solutions include nylons having specific solubility together with select formaldehyde resins and resin mixtures. The solutions provide superior adhesion and are therefore attractive to thread applications as well as formed structures.Type: GrantFiled: March 13, 2002Date of Patent: October 19, 2004Assignee: E. I. du Pont de Nemours and CompanyInventor: Rolando Umali Pagilagan
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Patent number: 6803113Abstract: A multilayered packaging film having good antifog performance that is suitable for use in food packaging. The multilayered film comprises an outer film attached to an inner film, which outer film is a combination of a first nylon layer, an ethylene vinyl alcohol layer attached to a surface of the first nylon layer and a second nylon layer attached to the ethylene vinyl alcohol layer. The inner film is a combination of a third nylon layer having a silicone oil on a first surface of the third nylon layer, and a sealant film on a second surface of the third nylon layer, attached either directly or via an intermediate adhesive layer. An antifog composition is either contained within the sealant film or is coated on a surface of the sealant film opposite the third nylon layer. The silicone oil effectively blocks the migration of the antifog composition into an adjacent nylon layer when the multilayered film is stored in roll form.Type: GrantFiled: September 13, 2002Date of Patent: October 12, 2004Assignee: Honeywell International Inc.Inventors: Simon J. Porter, Jeffrey D. Moulton, Yuan-Ping Robert Ting
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Patent number: 6794048Abstract: A multilayer composite comprising the following layers bound directly to one another: I. a layer I of a polyamide molding composition; II. a layer II of a bonding agent comprising at least 50% by weight of a mixture of a) from 30 to 70 parts by volume of polyamide and b) from 70 to 30 parts by volume of polyolefin, where the sum of the parts by volume is 100 and in addition at least some of the polyamide is present either in the form of a polyamide-polyolefin graft copolymer or as a highly branched polyamine-polyamide copolymer; III. if desired a layer III of a polyolefin molding composition, displays good adhesion between layers which remains largely intact even on prolonged contact with alcohol-containing or aqueous media at elevated temperature.Type: GrantFiled: December 26, 2001Date of Patent: September 21, 2004Assignee: Degussa AGInventors: Guido Schmitz, Harald Haeger
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Patent number: 6783821Abstract: A good layer adhesion can be achieved in a composite having two or more layers wherein a layer I is obtained from a molding composition which has the following components: a) from 0 to 80 parts by weight of a polyamide selected from the group consisting of PA6, PA66, PA6/66 and a mixture thereof; b) from 0.Type: GrantFiled: December 21, 2001Date of Patent: August 31, 2004Assignee: Degussa AGInventors: Hans Ries, Guido Schmitz, Harald Haeger
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Patent number: 6780522Abstract: Described is a single or multi-layered film having at least one polyamide layer (I) containing dispersed nanoscale nucleating particles. The smallest components of the dispersed nanoscale nucleating particles in layer (I) have an extension of less than 100 nm in at least one randomly selected direction for each component, based on a weighted average of all components of the dispersed nanoscale nucleating particles. Crystalline structures emanating from the surface of the dispersed nanoscale nucleating particles are formed after the layer (I) is cooled from the molten state at a rate of from 10 to 20° C. per minute. The dispersed nanoscale nucleating particles are present in the polyamide layer (I) in an amount of from 10 ppm to 3000 ppm, based on the total weight of layer (I).Type: GrantFiled: April 10, 2001Date of Patent: August 24, 2004Assignee: Wolff Walsrode AGInventors: Holger Eggers, Andreas Gasse, Gregor Kaschel, Rainer Brandt, Bernd Eilers
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Patent number: 6740422Abstract: Described is a flexible, multilayered film comprising, (i) an outer layer composed substantially of polyamide containing nanodispersed filing material (e.g., in an amount of from 0.1 and 3 wt. %), and (ii) at least one additional polyamide layer. The multilayered film of the present invention may be produced by flat film or blown film methods. Also described is a method of using the multilayered film of the present invention as a packaging for foodstuff.Type: GrantFiled: April 9, 2001Date of Patent: May 25, 2004Assignee: Wolff Walsrode AGInventors: Holger Eggers, Gregor Kaschel
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Patent number: 6726999Abstract: A molding composition comprises from 80 to 99.9 parts by weight of thermoplastic polyester and from 0.1 to 20 parts by weight of a polyamide-polyamine graft copolymer, where the sum of the parts by weight of the polyester and of the graft copolymer is 100. The molding composition has improved flowability.Type: GrantFiled: December 21, 2001Date of Patent: April 27, 2004Assignee: Degussa AGInventors: Ralf Schueler, Heinz Peirick, Harald Haeger, Ralf Richter
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Patent number: 6677015Abstract: A molding composition of at least 50% by weight of a polyamine-polyamide copolymer obtained from 0.05 to 2.5% by weight of a polyamine having at least 4 nitrogen atoms and having a viscosity of at least 5 000 Pa•s at 250° C. and at a shear rate of 0.1 l/s, and having a viscosity ratio of at least 7 at 250° C., when the melt viscosities at shear rates of 0.1 l/s and 100 l/s are compared with one another, has high melt stiffness and is easy to cut, and performs well in blow molding.Type: GrantFiled: December 19, 2001Date of Patent: January 13, 2004Assignee: Degussa AGInventors: Martin Himmelmann, Wilfried Bartz, Franz-Erich Baumann, Guido Schmitz, Georg Oenbrink, Harald Haeger, Ralf Richter
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Patent number: 6670004Abstract: A laminated nylon air brake tubing is formed from outer and inner layers of nylon 11 or nylon 12 with inner layers of nylon 6. The nylon 6 and nylon 11 or 12 layers are adhered together by a tie layer. The tie layer is preferably a nylon 6-12 or an anhydride modified polyolefin. The air brake tubing has improved high temperature strength and low temperature impact resistance characteristics.Type: GrantFiled: August 2, 2000Date of Patent: December 30, 2003Assignee: Saint-Gobain Performance Plastics CorporationInventor: Edward A. Green
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Patent number: 6670047Abstract: A stretched polyamide film obtained by melt-kneading and extruding a mixed resin (Z) containing a polyamide resin (X) and a modified resin (Y) into a film followed by biaxial stretching, wherein the polyamide resin (X) is obtained from a diamine component containing not less than 70 mol % of a metaxylylenediamine and from a dicarboxylic acid component containing not less than 70 mol % of an &agr;, &ohgr;-aliphatic dicarboxylic acid having 6 to 12 carbon atoms; the modified resin (Y) is obtained by graft-modifying an ethylene-ethyl acrylate copolymer resin with a maleic anhydride; and the mixed resin (Z) contains from 80 to 99% by weight of the polyamide and from 20 to 1% by weight of the modified resin. The stretched film exhibits not only excellent transparency and gas-barring property but also excellent flexibility and shock resistance.Type: GrantFiled: January 24, 2002Date of Patent: December 30, 2003Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Hiroyuki Nanba, Koji Yamamoto
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Patent number: 6627324Abstract: Described is a film having at least a single layer and at least one copolyamide layer (I) containing dispersed nanoscale nucleating particles. Crystalline structures extending from the dispersed particle surfaces are formed after the layer (I) is cooled from a molten state at a cooling rate of from 10° C. to 20° C. per minute. The dispersed nanoscale nucleating particles are present in layer (I) in an amount of from 10 ppm to 2000 ppm, based on the total weight of layer (I). Also described is a method of using the film of the present invention in packaging foodstuffs.Type: GrantFiled: April 10, 2001Date of Patent: September 30, 2003Assignee: Wolff Walsrode AGInventors: Holger Eggers, Gregor Kaschel, Claudia Müller, Andreas Gasse, Rainer Brandt, Dieter Neubauer, Bernd Eilers
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Publication number: 20030170473Abstract: A multilayer structure based on polyamides, comprising:Type: ApplicationFiled: January 29, 2003Publication date: September 11, 2003Applicant: ATOFINAInventor: Christophe Lacroix
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Publication number: 20030165699Abstract: A multilayer structure based on polyamides, comprising:Type: ApplicationFiled: January 29, 2003Publication date: September 4, 2003Applicant: ATOFINAInventor: Christophe Lacroix
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Patent number: 6576312Abstract: A fuel transporting tube including an inner layer which contacts a fuel being transported and which is formed of a polybutylene naphthalate resin, an outer layer which is provided radially outwardly of the inner layer and which is formed of a polyamide resin or a polyolefin resin, and an intermediate layer which is provided between the inner layer and the outer layer and which is formed of a resin to adhere the inner and outer layers to each other.Type: GrantFiled: November 12, 1999Date of Patent: June 10, 2003Assignee: Tokai Rubber Industries, Ltd.Inventors: Hiroaki Ito, Shinji Iio
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Patent number: 6548181Abstract: The invention relates to a flexible polyamide composition containing at least 50 parts by weight of non-cross-linked rubber per 50 parts by weight of polyamide and the production thereof. The polyamide has a molecular weight such that the melt viscosity at the processing temperature is at most 300 pa.s, preferably at most 200 pa.s. The rubber's Mooney viscosity is at least 40, most preferable is a rubber with a Mooney viscosity of at least 60. The rubber has been functionalized. Preferably a combination of a functionalized and a non-functionalized rubber is used. The rubber particles in the polyamide matrix have a particle size of at most 5 &mgr;m, preferably at most 3 &mgr;m.Type: GrantFiled: September 26, 2001Date of Patent: April 15, 2003Assignee: DSM N.V.Inventor: Guido P. C. Beusen
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Patent number: 6534137Abstract: A two-component laminated multilayer film suitable for use in packaging articles such as pet food comprises a first component and a non-heat-shrinkable second component. The first component comprise an outer first film layer, an optional second film layer, and an optional third film layer. The first and third film layers comprise ethylene/alpha-olefin copolymer, while the second film layer is a modified ethylene copolymer. The second component comprises an outer fourth layer, an oxygen barrier fifth layer, sixth and seventh layers which serve as tie layers and are positioned on either side of the barrier layer. The multilayer film is heat sealable to itself and another film. The multilayer film has a total thickness of at least 2 mils, an impact strength of at least about 3 ft-lbs, an elongation at break of less than 300%, a tear propagation of at least 50 grams, a tensile modulus of at least 45,000 psi, total free shrink at 180° F. of from less than 50 percent.Type: GrantFiled: October 12, 1999Date of Patent: March 18, 2003Assignee: Cryovac, Inc.Inventor: Parimal M. Vadhar
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Patent number: 6524719Abstract: The present invention relates to a laminate film where on at least one face of a substrate layer selected from polyester film and aliphatic polyamide film, there is provided a polyamide layer in which the chief component is an aromatic polyamide of glass transition temperature at least 60° C., as a layer to undergo vapour deposition, and (1) the centre-line average roughness (Ra) of the face which is to undergo vapour deposition is in the range 0.005 to 0.03 &mgr;m, or (2) between the substrate layer and the polyamide layer, a layer comprising a single polymer or a plurality of polymers of SP value 10 to 15 is interposed between the substrate A layer and the polyamide C layer; and the invention offers film for vapour-deposition which is outstanding in its processability in vapour-deposition, and in its gas barrier properties.Type: GrantFiled: April 26, 2001Date of Patent: February 25, 2003Assignee: Toray Industries, Inc.Inventors: Nobuhisa Yamane, Kokichi Hashimoto, Masahiro Kimura
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Patent number: 6524671Abstract: Coextruded layers of polyamide and fluoropolymer adhere to one another without an intervening tie layer by adhesive activation of polyamide of the polyamide layer, e.g. by incorporating into the polyamide layer a dispersed phase of maleic anhydride-grafted ethylene/propylene/diene copolymer. The fluoropolymer is a copolymer of ethylene with perhalogenated comonomer or a copolymer of tetrafluoroethylene with perfluorinated comonomer.Type: GrantFiled: March 12, 1998Date of Patent: February 25, 2003Assignee: E. I. du Pont de Nemours and CompanyInventor: Peter Dwight Spohn
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Publication number: 20030035946Abstract: The present invention provides a cover tape for packaging electronic components, which can prevent troubles associated with the peeling strength or appearing during mounting of the electronic components, which can be produced at a low cost, and which is transparent; that is, a cover tape which has a peeling strength not too high and not too low and small in difference between the maximum value and the minimum value and which has high transparency. Specifically, the present invention provides a cover tape for packaging electronic components, which can be heat-sealed to a plastic-made carrier tape having pockets capable of storing electronic components, formed regularly therein and which comprises (A) a biaxially oriented film layer made of a polyester, a polypropylene or a nylon and (B) a thermoplastic resin layer composed of 100 parts by weight of an ethylene copolymer and 10 to 100 parts by weight of a polystyrene, laminated to one side of the layer A.Type: ApplicationFiled: June 26, 2002Publication date: February 20, 2003Inventors: Hisao Nakanishi, Masayuki Hiramatsu
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Patent number: 6500559Abstract: A film includes a core layer having an amorphous polyamide; two intermediate layers, disposed on opposite surfaces of the core layer, including a semicrystalline polyamide; two adhesive layers, each disposed on a surface of the respective intermediate layer, including a polymeric adhesive; and two outer layers, each disposed on a surface of a respective adhesive layer, including an ethylene/alpha olefin copolymer, propylene homopolymer, or propylene/alpha olefin copolymer; and a second outer layer, disposed on a surface of a respective adhesive layer, including amorphous polyamide, semicrystalline polyamide, ethylene/alpha olefin copolymer, propylene homopolymer, or propylene/alpha olefin copolymer. The film can alternatively have a core layer including a polymeric adhesive, and two intermediate layers each having an amorphous polyamide. A method of packaging a product using these films, and a package, are also disclosed.Type: GrantFiled: May 4, 1998Date of Patent: December 31, 2002Assignee: Cryovac, Inc.Inventors: Frank M. Hofmeister, Thomas D. Kennedy, Carlo E. Musco, Paul J. Satterwhite, G. Vince Sharps
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Patent number: 6491994Abstract: A multi-layer fuel tube comprising at least three thermoplastic resin layers, said at least three thermoplastic resin layers comprising (A) a layer of polyamide 11 resin and/or polyamide 12 resin, (B) layer of polyamide 6, and (C) a layer of polyamide containing 0.05 to 30% by weight of a layered silicate uniformly dispersed therein.Type: GrantFiled: April 14, 2000Date of Patent: December 10, 2002Assignee: Ube Industries, Ltd.Inventors: Satoshi Kito, Shigetarou Miyano
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Patent number: 6455118Abstract: The present invention relates to a reinforced flexible pipeline for conveying an effluent, the pipeline having a sheath (2, 3) of polymer, the internal surface of which is in contact with the effluent and the external surface of which is in contact with reinforcing wires (4) when under pressure. The sheath has an internal layer (2) of polymer or copolymer with no external plasticizer and an external layer (3) of polymer possibly containing plasticizers so as to obtain given mechanical characteristics. Application of the pipeline proposed by the invention for conveying an effluent under pressure and at high temperature.Type: GrantFiled: December 10, 1998Date of Patent: September 24, 2002Assignee: Institut Francais du PetroleInventors: Bernard Dewimille, Jean Hardy, Jacques Jarrin, Alain Driancourt
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Publication number: 20020119335Abstract: Polyamide composition are provided that exhibit desirable flow properties and excellent burst strength, and are well suited for friction-weldable molding applications. Such compositions comprise a polyamide mixture of polyamide 6 together with aliphatic polyamide copolymers and/or terpolymers, and inorganic reinforcement. Other compositions, including plasticizers, are disclosed.Type: ApplicationFiled: February 15, 2002Publication date: August 29, 2002Inventor: Masahiro Nozaki
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Publication number: 20020119272Abstract: A good layer adhesion can be achieved in a composite having two or more layers whereinType: ApplicationFiled: December 21, 2001Publication date: August 29, 2002Applicant: DEGUSSA AGInventors: Hans Ries, Guido Schmitz, Harald Haeger
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Patent number: 6440546Abstract: The flexible, weatherable decorative sheet material provided by the present invention comprises a thermoformable decorative paint film having an inner surface and a weatherable, low gloss outer surface suitable for forming an exterior finish for a part, such as an automobile body part. The sheet material further includes an extensible mask layer releasably adhered to the outer surface of the paint film to form a protective film overlying the paint film. The mask layer comprises a film-forming polymer component and a particulate filler, such as silica, dispersed in the polymer component. A method of constructing the decorative sheet material, a method of controlling the gloss appearance of a paint film, and a composite shaped part including the decorative sheet material are also provided.Type: GrantFiled: October 13, 1999Date of Patent: August 27, 2002Assignee: Ream Industries Corp.Inventors: Thomas Randall Fields, Scott William Huffer
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Patent number: 6420045Abstract: The present invention relates to a multilayer structure comprising a material covered with a copolymer having polyamide blocks and hydrophilic blocks where the copolymer has a melting point of less than 135° C.Type: GrantFiled: June 23, 2000Date of Patent: July 16, 2002Assignee: AtofinaInventors: Heike Faulhammer, Yves Aubert, Thierry Briffaud, Hermann Josef Hilgers, Didier Roumilhac
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Patent number: 6416832Abstract: The invention provides a single-layer or multi-layer packaging film or sheet having at least one layer formed of a polyamide resin composition, wherein the layer formed of the polyamide resin composition is a layer (A) formed of a polyamide resin composition comprising a copolymer nylon (c) composed of an aliphatic nylon (co)polymer component (1) and an aromatic nylon (co)polymer component (2) in a proportion of at least 5 wt. %.Type: GrantFiled: June 22, 1999Date of Patent: July 9, 2002Assignee: Kureha Kagaku Kogyo K.K.Inventors: Tsutomu Uehara, Hitoshi Ishii, Hajime Tsukamoto
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Publication number: 20020082352Abstract: Good adhesion between layers is achieved in a multilayer composite having the following layers:Type: ApplicationFiled: December 26, 2001Publication date: June 27, 2002Applicant: Degussa AGInventors: Guido Schmitz, Harald Haeger
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Patent number: 6379812Abstract: A multilayer film, comprising, in the following order: a. a first layer consisting essentially of amorphous polyamide; b. a second layer adhered to a surface of the first layer; and c. a third layer adhered to a surface of the second layer, the third layer comprising at least one member selected from ethylene/vinyl alcohol copolymer, polyamide MXD6, polyamide MXD6/MXDI, polyvinylidene chloride, and polyacrylonitrile.Type: GrantFiled: May 31, 2000Date of Patent: April 30, 2002Assignee: Cryovac, Inc.Inventors: Frank M. Hofmeister, Paul J. Satterwhite, Thomas D. Kennedy
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Patent number: 6376093Abstract: A polyamide film satisfying (a) a haze value of not more than 5.0%, (b) a coefficient of kinetic friction (A) of not more than 1.0 under 50% humidity, the coefficient (A) being measured with regard to fiction between the same two polyamide films, and (c) a ratio of coefficients of kinetic friction (B)/(A) of not more than 1.5, the (B) being a coefficient of kinetic friction at 65% humidity, a billy oriented polyamide film showing an average dimensional change of not more than 3.0% and a difference between the smallest dimensional change and the largest dimensional change of not more than 2.0%, between before immersion in hot water at 95° C. and during the immersion, and an average dimensional change of not more than 4.0% and a difference between the smallest dimensional change and the largest dimensional change of not more than 2.0%, between the film without treatment and the film after withdrawal from said hot water; and a polyamide laminate film containing the film as a substrate layer.Type: GrantFiled: May 24, 1999Date of Patent: April 23, 2002Assignee: Toyo Boseki Kabushiki KaishaInventors: Shinji Fujita, Masaki Sugimoto, Shigeru Komeda, Masazumi Iwanishi, Masayoshi Satoh, Chikao Morishige, Kiyoshi Iseki, Seiichiro Yokoyama
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Patent number: 6376036Abstract: The present invention relates to a composite flexible hose, preferably for use in automotive air conditioning systems, with improved thermal resistance. The hose consists of an innermost core layer, a friction rubber layer, an intermediate reinforcement layer, and an external cover layer. The innermost layer is a non-plasticized polyamide mixed with a minor portion of polyolefin corresponding to the main rubber constituent of the friction coat layer. The friction coating is formed of a rubber composite of two EPDM rubbers at a weight ratio of 50/50 and 75 parts by weight of carbon black. The intermediate fibrous reinforcement layer is formed of aramid. The external layer is an acrylate rubber comprising a blend of two ethylene acrylates at a weight ratio of 50/50 and 80 parts by weight of carbon black.Type: GrantFiled: March 26, 1998Date of Patent: April 23, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Pradeep Dattatraya Nadkarni, John Patrick Thomas, Thomas Alan Brown
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Publication number: 20020018905Abstract: The present invention provides polyamide layered films suitable for packaging applications, each film having a base layer made of a polyamide polymer and an easy-sliding layer made of a polyamide polymer containing inorganic fine particles at 0.15 to 3.00 wt %, the easy-sliding layer being formed on at least one surface of the base layer, and the first static friction coefficient between the easy-sliding layer side surfaces of the layered films at 23° C. in a 65% RH atmosphere being 0.70 or lower, or the second static friction coefficient between the easy-sliding layer side surfaces of the layered films at 23° C. in a 80% RH atmosphere being 0.95 or lower.Type: ApplicationFiled: June 15, 2001Publication date: February 14, 2002Inventors: Haruo Okudaira, Keiji Mori, Yukinobu Miyazaki
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Patent number: 6346285Abstract: An article, such as a bag, pouch, or casing, is made from a multilayer film which has: (a) a first layer, which is an outer film layer, comprising a polyamide having a melting point of from about 250° F. to 400° F., the first layer having a thickness of less than about 18 percent, based on a total thickness of the multilayer film; (b) a second layer comprising at least one member selected from the group consisting of polyamide 6, polyamide 9, polyamide 10, polyamide 11, polyamide 12, polyamide 66, polyamide 610, polyamide 612, polyamide 6I, polyamide 6T, polyamide 69, and copolymers thereof, the second layer having a thickness of from about 3 to 30 percent of the total thickness of the multilayer film; and (c) a third layer which serves as an O2-barrier layer and comprises at least one member selected from the group consisting of ethylene/vinyl alcohol copolymer, and polyvinylidene chloride. The first layer of the film is sealed to itself.Type: GrantFiled: October 30, 1997Date of Patent: February 12, 2002Assignee: Cryovac, Inc.Inventor: Ram K. Ramesh
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Patent number: 6346328Abstract: A composite article is provided which includes a fluoropolymer intimately bonded to a component including a substantially non-fluorinated thermoplastic having pendant phenolic groups in combination with a base. Increased adhesion is observed by a greater peel strength value between the fluoropolymer component and a non-fluorinated thermoplastic having pendant phenolic groups.Type: GrantFiled: June 10, 1999Date of Patent: February 12, 2002Assignee: Dyneon LLCInventors: Edward E. Parsonage, Attila A. Molnar, Thomas J. Blong, Robert E. Kolb
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Publication number: 20020012806Abstract: Thermoplastic multilayer composite, particularly in the form of a multilayer hose, a multilayer pipe or a multilayer container, containing at least one intermediate layer made of a molding compound on the basis of ethylene/vinyl alcohol copolymers between layers made of molding compounds on the basis of polyamide, the intermediate layer being bonded via at least one adhesion-promoting layer made of a molding compound on the basis of polyamide selected from the group of copolyamide 6/12, block copolyamide 6/12, polyamide 612, polyamide 610, a mixture of polyamide 6 and polyamide 12 with compatibilizer, a mixture of polyamide 6 and polyamide 11 with compatibilizer, with at least one neighboring layer made of a molding compound on the basis of polyamide 12, polyamide 11, polyamide 1010, polyamide 1012, or polyamide 1212.Type: ApplicationFiled: May 23, 2001Publication date: January 31, 2002Applicant: EMS-CHEMIE AGInventors: Albert Flepp, Michael Hoffman
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Patent number: 6340530Abstract: Book covers and a substantially transparent, coextruded matte, bilayer nylon film which is contact transparent to a paper stock to form a soft book cover having high scratch, abrasion and mar resistance, a soft feel and good moisture curl properties. A substantially transparent, coextruded film which has a first nylon layer attached adjacent to a second nylon layer, the first nylon layer has from about 20 weight percent to about 70 weight percent of a refractory filler based on the weight of the first nylon layer.Type: GrantFiled: April 28, 2000Date of Patent: January 22, 2002Assignee: Honeywell International Inc.Inventors: Simon J. Porter, Jeffrey D. Moulton, Lance R. Altizer
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Patent number: 6294263Abstract: The present invention is to provide a polyamide laminated film comprising a resin layer A and a resin layer B formed on at least one surface of the resin layer A, the resin layer A being composed mainly of a m-xylylene group-containing polyamide polymer (a-1) which is one prepared from monomer components containing a xylylenediamine compound as a main diamine component and an &agr;,&ohgr;-aliphatic dicarboxylic acid having from 6 to 12 carbon atoms as a main dicarboxylic acid component, the xylylenediamine compound being m-xylylenediamine alone or a mixture of m-xylylenediamine and p-xylylenediamine, and the resin layer B being mainly composed of a mixed polymer (b-3) which is a mixture of from 99 to 80% by weight of an aliphatic polyamide (b-1) and from 1 to 20% by weight of an elastomer (b-2). The laminated film is good in a gas barrier property and also in a flexural fatigue resistance and a transparency.Type: GrantFiled: March 5, 1999Date of Patent: September 25, 2001Assignee: Toyo Boseki Kabushiki KaishaInventors: Haruo Okudaira, Akira Matsuda, Sinitiro Okumura, Kazumoto Imai, Tsutomu Oko