Abstract: Disclosed are a structure of multi-layered clad plates and sheets for corrosion resistance and a fabricating method thereof. Provided are clad plates and sheets for corrosion resistance in which Ni, Co, Ti, Ni, V, and Zr having an excellent corrosion resistance, or an alloy thereof are bonded to cheap Fe, Cu, or an alloy thereof: Chemical compositions of the clad metals and structures of the clad plates and sheets are easily modified with service conditions of the clad plates and sheets. Also, this invention provides a more cost-effective method based on a resistance seam welding process for fabricating the corrosion-resistant clad plates and sheets.

Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.

Abstract: A magnetic recording medium includes a substrate, a nonmagnetic seed layer provided on the substrate, and a magnetic layer provided on the nonmagnetic seed layer via one or a plurality of layers. The nonmagnetic seed layer is made of NiAl having an oxygen concentration of approximately 1500 to 4000 ppm.

Abstract: A ceramic thermal barrier coating on a substrate wherein the coating comprises primary columnar grains that extend transversely of a surface of the substrate and that include integral secondary columnar grains extending laterally therefrom relative to a respective column axis. The secondary columnar grains typically extend from the primary columnar grains at an acute angle of less than 90 degrees relative to the column axis of the primary columnar grains. The coating structure exhibits reduced thermal conductivity as compared to a conventional thermal barrier coating.

Abstract: The invention describes a temperature-stable protective coating over a metallic substrate surface (1), which coating includes at least one layer of material (4) consisting of MCrAlY, where M represents at least one of the elements selected from the group of materials consisting of Fe, Co and Ni. The invention also describes a production process for this coating.

Abstract: A magnetic recording medium is constructed to include a substrate, and a magnetic layer disposed above the substrate, wherein the magnetic layer has an initial layer on a side closer to the substrate and a final layer on a side opposite from the substrate with respect to the initial layer. The initial layer is made of a CoCrB-based alloy having a thickness of 1 to 10 nm, and the final layer is made of a Co-based alloy having a thickness of 5 to 30 nm.

Abstract: The invention relates to a product (1), in particular a gas-turbine blade (1), having a metallic basic body (2) to which a protective layer (3, 4) for protecting against corrosion is bonded. The protective layer (3, 4) has an inner layer (3) of a first MCrAlY alloy and an outer layer (45) having a second MCrAlY alloy, which is bonded to the inner layer (3). The second MCrAlY alloy is predominantly in the &ggr;-phase. The invention also relates to a process for producing a protective layer (3, 4) in which the outer layer (4) is produced by re-melting a region of the inner layer (3) or by deposition of an MCrAlY alloy from a liquid phase.

Abstract: A battery case excellent in glossiness of appearance and working efficiency and a surface-plated steel plate which can be used preferably to manufacture the battery case. The battery case is produced by deep-drawing, DI-forming, DTR-forming a surface-treated steel plate having glossy nickel or glossy nickel-cobalt alloy plating on the outermost layer corresponding to the external face of a battery case of a plated original plate consisting of a steel plate. The glossy nickel plating or glossy nickel-cobalt alloy plating layer on the outermost layer has a high glossiness, and therefore the appearance is excellent. The runnability of a formed battery case is high as well as the working efficiency.

Abstract: A metallic component exposed to high temperature steam is provided with a coating comprising a thin primer layer deposited on the surface of the metallic component and a thicker overlay layer on top of the primer layer. The primer layer consists of highly ductile, oxidation resistant material such that it remains free of any defects over a long period of exposure. The overlay layer consists of an oxidation resistant, less ductile, and low-cost material. It protects the thin primer layer from mechanical damage and chemical degradation. The primer layer protects the base material of the metallic component from oxidizing steam that may penetrate through cracks of the overlay layer. Due to suitable choice of coating materials and thicknesses of the layers the coating is low-cost.

Abstract: A method of providing a protective, corrosion-resistant thin coating of a MCrX alloy on a carbon or low-alloy steel pipe or tube where M is one of nickel, cobalt or iron or combination thereof and X is one of molybdenum, silicon, tungsten or combination thereof, and heat treating the coating to metallurgically bond the coating onto a steel substrate of the pipe or tube. The coating may be deposited in one or two layers by plasma transferred arc deposition or may be deposited as a slurry coating or thermal spray coating with sintering of the coating. The steel substrate is prepared for coating by at least one of boring, honing, bright finishing, grit blasting, grinding, chemical pickling or electro-polishing of the substrate.

Abstract: An abradable coating composition for use on shrouds in gas turbine engines (or other hot gas path metal components exposed to high temperatures) containing an initial porous coating phase created by adding a “fugitive polymer” (such as polyester or polyimide) to the base metal alloy, together with a brittle intermetallic phase such as &bgr;-NiAl that serves to increase the brittle nature of the metal matrix, thereby increasing the abradability of the coating at elevated temperatures, and to improve the oxidation resistance of the coating at elevated temperatures. Coatings having about 12 wt % polyester has been found to exhibit excellent abradability for applications involving turbine shroud coatings. An abradable coating thickness in the range of between 40 and 60 ml provides the best performance for turbine shrouds exposed to gas temperatures between 1380° F. and 1850° F.

Abstract: A magnetoresistive thin-film magnetic element including a composite comprising an antiferromagnetic layer, a pinned magnetic layer, a nonmagnetic conductive layer, a free magnetic layer; hard bias layers for orienting the magnetic vectors of the free magnetic layer in a direction substantially orthogonal to the magnetization vector of the pinned magnetic layer; and a conductive layer for supplying a sense current is provided. The hard bias layers are provided at the two sides of the free magnetic layer. The hard bias layers and the free magnetic layers are in contact with each other at least partly. Bias underlayers are provided at the bottom of the hard bias layers.

Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.

Abstract: A method of single crystal welding is provided for the production of a single crystal region (1) on a surface (2) of a moncrystalline substrate (3) by means of an energy beam (4). The method of single crystal welding includes the supply of a coating material (5), the formation of a melt (6) by melting the coating material (5) by means of the energy beam (4) and the melting of a surface layer (71, 72) of the single crystal substrate (3) by the energy beam (4). The characteristic (8) of the energy distribution in the energy beam (4) is set, in this connection, such that the lateral thermal flow (H1) from the melt into the single crystal substrate (3) is minimised.

Abstract: A protective layer has the composition 0.5 to 2% of rhenium, 15 to 21% of chromium, 9 to 11.5% of aluminum, 0.05 to 0.7% of yttrium and/or at least one equivalent metal from the group consisting of scandium and the rare earths, 0 to 1% of ruthenium, remainder cobalt and/or nickel and production-related impurities, and is scarcely subject to any embrittlement from Cr/Re precipitations.

Abstract: Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

Abstract: A Zn—Al—Mg—Si alloy-plated steel material with excellent corrosion resistance, characterized by comprising, in terms of wt %, Al: at least 45% and no greater than 70%, Mg: at least 3% and less than 10%, Si: at least 3% and less than 10%, with the remainder Zn and unavoidable impurities, wherein the Al/Zn ratio is 0.89-2.75 and the plating layer contains a bulky Mg2Si phase; also, a Zn—Al—Mg—Si alloy-plated steel material with excellent corrosion resistance, characterized by comprising, in terms of wt %, Al: at least 45% and no greater than 70%, Mg: at least 1% and less than 5%, Si: at least 0.5% and less than 3%, with the remainder Zn and unavoidable impurities, wherein the Al/Zn ratio is 0.89-2.75 and the plating layer contains a scaly Mg2Si phase.

Abstract: A composite member includes a ceramic base and a metallic member which are bonded to each other. An active metal foil is disposed on the surface of the ceramic base and a solder material including Au or a solder material including an Au—Ag alloy is disposed on the active metal foil. The active metal foil and the solder material are heated to form a bonding layer and the metallic member is disposed on the surface of the bonding layer, and these are pressed and heated to bond the bonding layer and the metallic member through solid phase bonding. Since in this composite member the bonding layer and the metallic member are bonded by solid phase bonding, the composite members can be effectively inhibited from breakage caused by residual stress at the time of bonding and, moreover, is excellent in thermal cycle characteristics and thermal shock characteristics.

Abstract: Materials including alternating magnetic layers and spacer layers for use as a hard magnetic recording layer of a magnetic recording media are disclosed. The spacer layers as well as the magnetic layers are exchange decoupled. The spacer and magnetic layers include additives which are present in grain boundary regions throughout the layers. In a particular embodiment, the magnetic layers comprise Co, the spacer layers comprise Pd, and the additives comprise Cr, Pt, B, Ta, Nb or combinations thereof. In addition to forming grain boundaries that exchange decouple the magnetic and spacer layers, the additives may act as grain refiners.

Abstract: A spin valve structure is described that has greater pinned layer robustness than is found in spin valves of the existing known art, making it well suited for use in high density recording. This has been achieved by a using a modified pinned layer that is a laminate of five layers—a first layer of cobalt-iron, a layer of ruthenium, a second layer of cobalt-iron, a layer of nickel-chromium, and a third layer of cobalt-iron. The second layer of cobalt-iron should be about twice the thickness of the third cobalt-iron layer. The sum of the second and third cobalt-iron layer thicknesses may be greater or smaller than the thickness of the first cobalt-iron layer. A process for manufacturing the structure is also described.

Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.

Abstract: A method for forming a thermal barrier coating system on a turbine engine component includes forming a bondcoat on the turbine engine component and depositing a thermal barrier coating so as to overlie the bondcoat. The bondcoat is formed by thermally co-spraying first and second distinct alloy powders on the turbine engine component forming an oxidation-resistant region, and thermally spraying a third alloy powder on the oxidation-resistant region to form a bonding region.

Abstract: The present invention provides for a method to reduce the strength of the honeycomb of a jet turbine stator, increasing its machinability, with a resultant reduction in measured peak tooth temperature, while maintaining or even improving its high temperature capability, so as not to limit its operating environment. The air seal functionality is unaffected, and even improved in some instances. The machinability of the honeycomb is increased by using a light element diffused into the honeycomb ribbon to produce the effect of reducing its strength and ductility while maintaining the environmental resistance needed. The present invention also includes the stator honeycomb produced by the foregoing method.

Abstract: The present invention provides amorphous non-laminar nickel phosphorous alloys, amorphous non-laminar nickel cobalt phosphorous alloys, or amorphous non-laminar cobalt phosphorous alloys. These alloys are useful in the formation of metal articles and metal-coated articles, including high precision devices and molds for plastics. In addition, the alloys of the present invention are useful in repairing damaged metal surfaces.

Abstract: The thin film disk includes a pre-seed layer of amorphous or nanocrystalline structure which may be AlTi or AlTa, and that is deposited upon a disk substrate. The pre-seed layer is followed by the RuAl seed layer, a Cr alloy underlayer, an onset layer composed essentially of CoCr and a magnetic layer. The onset layer has an optimal concentration of 28-33 at. % Cr and an optimal thickness of 0.5 to 2.5 nm and it increases coercivity and improves the Signal-to-Noise Ratio (SNR) of the disk. The magnetic layer is comprised of CoPtxCrBy, wherein x is the at. % concentration of Pt, y is the at. % concentration of boron, and x>4+y.

Abstract: A method is provided for repairing a surface portion of an article including a metallic environmental resistant coating on a substrate. The coating includes a coating outer portion bonded with the substrate through a diffusion zone that includes at least one feature, for example Al and/or an intermetallic phase, in an amount detrimental to application of a metallic replacement coating and/or repair of the article. The method comprises removing the coating outer portion to expose a surface of the diffusion zone. The substrate and the diffusion zone are heated at a temperature and for a time sufficient to diffuse and/or dissolve at least a portion of the at least one feature in the exposed surface and in a portion of the diffusion zone beneath the exposed surface to a level below the detrimental amount. This provides a replacement surface portion integral with diffusion zone. Then a metallic replacement coating outer portion is applied to the replacement surface portion.

Abstract: A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.

Abstract: The thin film disk includes a pre-seed layer of amorphous or nanocrystalline structure which may be AlTi or Alta, and that is deposited upon a disk substrate. The pre-seed layer is followed by the RuAl seed layer, a Cr alloy underlayer, an onset layer composed essentially of CoCr and a magnetic layer. The magnetic layer is comprised of CoPtxCrBy, wherein x is the at. % concentration of Pt, y is the at. % concentration of boron, and x>4+y.

Abstract: A method of producing an ohmic contact to p-type silicon carbide comprising two layers, the first one comprising nickel silicide and the second one comprising titanium carbide is disclosed. The deposited layers are annealed to convert at least a part of deposited metals to nickel silicide and titanium carbide. The contact is formed by reaction between the metals and the semiconductor, and thus the in-situ simultaneous formation of metal silicide and carbide suppress the release of excess carbon at the contact interface. Noble metals may be deposited preferably in between titanium and nickel to improve the contact morphology.

Abstract: The thin film disk includes a pre-seed layer of amorphous or nanocrystalline structure which may be CrTa or AlTi or AlTa, and that is deposited upon a disk substrate. The pre-seed layer is followed by the RuAl seed layer, a Cr alloy underlayer, an onset layer composed essentially of CoCr and a magnetic layer. The onset layer has an optimal concentration of 28-33 at. % Cr and an optimal thickness of 0.5 to 2.5 nm and it increases coercivity and improves the Signal-to-Noise Ratio (SNR) of the disk.

Abstract: A method of welding articles formed of single-crystal superalloys, particularly single-crystal nickel-base superalloys containing 10 weight percent or more of refractory metals, and welded assemblies formed thereby. A shim is positioned between the articles, and a backing strip is preferably positioned to contact both articles and bridge the gap between the articles. The articles are then welded together using a high energy beam with a low current pulse frequency and low travel speed.

Abstract: A spin-valve thin-film magnetic element includes a substrate; an antiferromagnetic layer; a pinned magnetic layer in contact with the antiferromagnetic layer, the magnetization direction of the pinned magnetic layer being pinned by an exchange coupling magnetic field with the antiferromagnetic layer; a nonmagnetic conductive layer in contact with the pinned magnetic layer; a free magnetic layer in contact with the nonmagnetic conductive layer, the magnetization direction of the free magnetic layer being aligned in a direction perpendicular to the magnetization direction of the pinned magnetic layer; and a back layer composed of a nonmagnetic conductive material formed in contact with the free magnetic layer at the opposite side of the nonmagnetic conductive layer. The back layer is composed of at least one metal selected from the group consisting of Ru, Pt, Ir, Rh, Pd, Os, and Cr.

Abstract: A magnetic recording medium is provided with a dual layer protective overcoat system comprising a SiN corrosion barrier layer, as at a thickness of about 25Å to about 50 Å, and a protective carbon-containing overcoat layer thereon, as at a thickness of about 25 Å to about 50 Å,. The SiN layer effectively prevents or significantly reduces Co and Ni diffusion to the medium surface. Embodiments include magnetic recording media comprising a SiN corrosion barrier layer over a magnetic layer and a protective layer of amorphous hydrogenated carbon, amorphous nitrogenated carbon, amorphous hydrogen-nitrogenated carbon, ion-beam deposited carbon or cathodic-arc-deposited carbon on the SiN corrosion barrier layer, with solid and mobile lube layers are sequentially deposited on the protective carbon layer.

Abstract: A method for applying, in a non-oxidizing atmosphere, a diffusion aluminide coating to a metallic surface of an article combines use of a relatively low aluminide coating temperature in the range of about 1650-1800° F. with a relatively high Al activity Al source material including Al of at least about 40 weight %. Such combination results in an as-deposited aluminide coating comprising a diffusion portion bonded between a metallic substrate and a coating outer portion of a thickness of no greater than about 60% of the thickness of the coating outer portion, typically less than about 1 mil.

Abstract: The present invention relates to articles, having an extended useful life, which are used in contact with high temperature molten aluminum or molten zinc baths. One aspect of the invention encompasses articles, such as bearings, bushings, couplings or rollers, used in contact with molten aluminum or molten zinc which is coated with a high density coating consisting of a metal selected from Groups Vb, VIb, or VIIb metals (preferably molybdenum or tungsten), in pure or alloyed form. These coatings generally have a thickness of from about 0.06 to about 0.30 inch. Another aspect of the present invention encompasses a roll for guiding steel strip through a high temperature aluminizing bath, which utilizes a multi-layer structure, the first primer layer being a Group Vb, VIb or VIIb metal, preferably tungsten or molybdenum (in pure or alloyed form), the second layer comprising MCrAlY in which M is either nickel or cobalt, and the third layer comprising a refractory metal oxide of Al, Zr, Si or Cr.

Abstract: A high temperature resistant article with improved protective coating bonding and method of manufacturing the article is provided. In one embodiment, the high temperature resistant article comprises a base body having a surface at least partly coated with an oxidation and corrosion protective coating containing a carbide forming element, wherein said base body is made from a metallic alloy having a medium carbon content and wherein the carbon content in a depth of 50 &mgr;m or deeper from said coated surface is less than 0.3% of said medium carbon content.

Abstract: A magnetic recording medium is provided with a dual layer protective overcoat system comprising an AlN corrosion barrier layer and a protective carbon layer thereon. The AlN layer effectively prevents or significantly reduces Co diffuision to the medium surface. Embodiments include magnetic recording media comprising an AlN corrosion barrier layer over a magnetic layer and a layer of amorphous hydrogenated carbon, amorphous nitrogenated carbon, amorphous hydrogen-nitrogenated carbon, ion-beam deposited carbon or cathodic-arc-deposited carbon on the AlN corrosion barrier layer.

Abstract: The present invention relates to a method for forming an article having a protective ceramic coating which reduces radiation heat transport through the ceramic coating. The protective ceramic coating includes one or more embedded reflective metallic layers for reducing the radiation heat transport. The method for forming the protective coating broadly comprises the steps of forming a ceramic coating on a substrate and embedding at least one reflective metallic layer within the ceramic coating.

Abstract: A turbine engine component includes a substrate and a wear coating on the substrate. The wear coating includes wear-resistant particles in a matrix phase, the wear-resistant particles being formed of chrome carbide or a cobalt alloy. Methods for forming a turbine engine component are also disclosed.

Abstract: A method for producing a spallation-resistant aluminum oxide layer on the surface of a superalloy article is described. An aluminum oxide layer is produced, typically under tensile stress, by chemical vapor deposition at low temperatures on a metal aluminide layer that has been deposited on the surface of the article. The aluminum oxide layer is then heated to induce cracking therein, which imparts spallation-resistance thereto. If desired, a thermal barrier layer may be deposited on the aluminum oxide layer.

Abstract: A thermal barrier coating for nickel based superalloy articles such as turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a columnar grained ceramic layer applied to a platinum modified Ni3Al gamma prime phase bond coat having a high purity alumina scale. The preferred composition of the bond coat is 5 to 16% by weight of aluminum, 5 to 25% by weight of platinum with the balance, at least 50% by weight, nickel. A method for making the bond coat is also disclosed.

Abstract: A device having an improved thermal barrier coating (46) and a process for manufacturing the same. A support structure (28) for retaining a ceramic insulating material (46) on a substrate (16) is formed by the deposition of a support structure material through a patterned masking material (14). The support structure can define cells into which the ceramic insulating material is deposited following removal of the masking material. The masking material may be patterned by known photolithographic techniques (22,24) or by laser etching (48).

Abstract: An article includes turbulation material bonded to a surface of a substrate via a bonding agent, such as a braze alloy. In an embodiment, the turbulation material includes a particulate phase of discrete metal alloy particles having an average particle size within a range of about 125 microns to about 4000 microns. Other embodiments include methods for applying turbulation and articles for forming turbulation.

Abstract: A magnetic recording medium using a nonmagnetic interlayer in between a Cr-base underlayer and a Co magnetic layer is disclosed. The nonmagnetic interlayer comprises Co1−&agr;−&bgr;−&ggr;−&zgr;Cr&agr;X&bgr;Y&ggr;Z&zgr;. X is a material selected from Ni or Fe so as to substitute a portion of Cr composition. Y is a material selected from materials which can form a solid solution with at least one of list materials consisting of Ni, Fe, Co, and Cr. The Y materials added in the interlayer is to adjust the lattice mismatch of interface between the interlayer and the underlayer to a magnitude so that the interlayer formed on the underlayer at least is a texture layer, an epitaxial layer is best preferred. However, Z is a material which is insoluble with any of above list materials, Cr, Co, X, and Y in a solid state so as to form precipitates, thereby inhibiting the grain growth. In a preferred embodiment, the &agr;, &bgr;, &ggr;, and &zgr; are about 25-41%, 0.1-5%, 0.1-5%, and 0.

Abstract: A method for protecting high temperature stainless steel from coking and corrosion at elevated temperatures in corrosive environments, such as during ethylene production by pyrolysis of hydrocarbons or the reduction of oxide ores, by coating the stainless steel with a coating of MCrAlX in which M is nickel, cobalt, iron or a mixture thereof and X is yttrium, hafnium, zirconium, lanthanum or combination thereof deposited onto and metallurgically bonded to the stainless steel by plasma transferred arc deposition of atomized powder of MCrAlX. The coating has a thick, dense, continuous and smooth transition region providing an effective metallurgically bond of the coating with the stainless steel. The coating retains a relatively high aluminum content which permits generation of an adherent alumina layer on the surface, providing good resistance to high temperature oxidation together with good anti-coking and hot erosion resistance properties.

Abstract: Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

Abstract: A nickel-base superalloy article has a surface protective layer comprising nickel, from about 20 to about 35 weight percent aluminum, and from about 0.5 to about 10 weight percent rhenium. The protective layer, which is preferably an overlay coating of the beta (&bgr;) phase NiAl form, is formed by depositing nickel, aluminum, rhenium, and modifying elements onto the substrate surface. A ceramic layer may be deposited overlying the protective layer.

Abstract: The present invention relates to articles, having an extended useful life, which are used in contact with high temperature molten aluminum or molten zinc baths. One aspect of the invention encompasses articles, such as bearings, bushings, couplings or rollers, used in contact with molten aluminum or molten zinc which is coated with a high density coating consisting of a metal selected from Groups Vb, VIb, or VIb metals (preferably molybdenum or tungsten), in pure or alloyed form. These coatings generally have a thickness of from about 0.06 to about 0.30 inch. Another aspect of the present invention encompasses a roll for guiding steel strip through a high temperature aluminizing bath, which utilizes a multi-layer structure, the first primer layer being a Group Vb, VIb or VIIb metal, preferably tungsten or molybdenum (in pure or alloyed form), the second layer comprising MCrAlY in which M is either nickel or cobalt, and the third layer comprising a refractory metal oxide of Al, Zr, Si or Cr.

Abstract: A tunnel junction having a topography and/or interface layers that enhance its magneto-resistance. The topography of the tunnel junction maximizes spin tunneling from areas of ferromagnetic crystalline grains having high polarization and minimizes the effects of defect scattering at grain boundaries. The interface layers enhance magnetic polarization properties of ferromagnetic layers near interfaces to an insulating layer in a tunnel junction.

Abstract: A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.